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USGS2025

Review: The hydrogeology of critical mineral resources relevant to the energy transition

Attaining the goals of the international treaty on climate change (the Paris Agreement) will greatly increase the demand for the critical minerals required to implement clean-energy technologies. This poses both challenges and opportunities to the hydrogeologic community from several perspectives. Here, important insights that the hydrogeological sciences have to offer for mineral exploration, mineral production, and addressing environmental issues related to mining and mine decommissioning are summarized. This study focuses on copper, cobalt, lithium, and rare earths to represent the broad spectrum of critical minerals and illustrate their relevance by referring to projected demands and production rates. The current understanding of the hydrogeologic processes that form major deposits of these minerals are then summarized. Ore is defined as the naturally occurring material from which minerals of economic value can be extracted, where most ore deposits are the products of complex hydrogeologic couplings between fluid flow, heat transport, solute transport, chemical reactions, and mechanical deformation. Exploration models for the discovery of deeper, hidden deposits are potentially informed by hydrogeologic theory and hydrogeochemical processes. Hydrogeologic understanding and methods are also essential to production and recovery. Longstanding challenges are mine dewatering and (conversely) mine water supply, as well as mineral-extraction practices such as spoil heap leaching and in situ mining. New challenges arise from element extraction from subsurface brines. Finally, the quantity of water use and potential environmental impacts of mining on water quality are at the core of ‘social license’: the approval and acceptance of society to mining activities.

Hydrogeology Journal↗
USGS2025

Stable isotope composition and geochemistry of calcite and dolomite in the Mountain Pass carbonatite: A lens into petrogenesis

Carbonatites host most of the global rare earth element (REE) deposits. The petrogenesis of these rocks, including magmatic and post-magmatic processes, are poorly understood but critical in forming and upgrading these deposits. The Mountain Pass carbonatite, which hosts the only active REE mine in North America, is lithologically variable but consistently contains >50% calcite and/or dolomite. Multiple generations of carbonates are evident, suggesting bulk analysis of carbonate minerals would generate a mixed isotopic and geochemical signature. In-situ stable carbon and oxygen isotopes, combined with geochemical analysis and petrography, distinguish carbonate generations, trace the source region of the carbonatite magma, and link carbonate genesis to REE mineralization throughout the intrusion. Primary carbon and oxygen isotope values outside the accepted mantle range may suggest a subduction-related carbon and oxygen source in the mantle. Deformation textures in primary calcite indicate syn- or post-crystallization ductile flow. Carbonates with secondary textures and heavy δ 13 C and δ 18 O values are associated with ore mineralization, suggesting fluid mobilization was important in concentrating REE and upgrading of the Mountain Pass deposit.

California↗
USGS2025

Geochemistry and radiogenic isotopes constrain the mantle source region of the Mountain Pass Intrusive Suite, California

The Mountain Pass carbonatite stock is the largest rare earth element (REE) deposit and only active REE mine in the United States. The carbonatite intrusion and spatially associated alkaline silicate intrusions constitute the Mountain Pass Intrusive Suite, which is located within the Mojave Province in California. Both the carbonatite and the alkaline silicate rocks are enriched in large ion lithophile elements and light REEs, and less enriched to depleted in high field strength elements, indicating the mantle source region was metasomatically enriched in incompatible trace elements. The cause of this metasomatic mantle enrichment and the genetic relationship between the carbonatite and the alkaline silicate stocks are poorly understood. In this study, major and trace element geochemical data and isotopic (Rb-Sr, Sm-Nd, and Lu-Hf) data are presented to constrain genesis of the Mountain Pass Intrusive Suite, from mantle source region to the intrusion of the stocks. Our geochemical data are consistent with derivation of the alkaline silicate and carbonatite melts through partial melting from a shared mantle source region rather than through liquid immiscibility or fractional crystallization and separation of a carbothermal fluid. Although the Rb-Sr isotopic system in the Mountain Pass Intrusive Suite is disturbed at the whole-rock scale, the isotopic systems for whole-rock Sm-Nd (εNd i = ‐2.2 ± 0.8) and zircon Lu-Hf (εHf i = 0.1 ± 1.1) are robust and support mantle derivation of the magmas. Geochemical modeling using experimentally derived partition coefficients was used to identify possible causes of enrichment in incompatible elements through metasomatism in the mantle source region. Modeling of metasomatism by melts derived by partial melting of deeply subducted carbonated sediments approximates observed Mountain Pass Intrusive Suite trace element chemistry. Scattered εHf i in inherited zircon (2.8 ± 2.6) is consistent with derivation from an arc-related environment with substantial crustal contamination. Paleotectonic studies in the Mojave Province indicate that regional subduction preceded emplacement of the Mountain Pass Intrusive Suite by ∼300 Ma. Melting of the Mountain Pass source region may have been caused by post-collisional thermal relaxation and extension.

California↗
USGS2025

Critical Minerals in Ores (CMiO) database

Critical minerals are commodities essential to modern industrial and strategic technologies and are highly vulnerable to supply chain disruption. The Critical Minerals Mapping Initiative (CMMI) is a collaboration among the U.S. Geological Survey (USGS), the Geological Survey of Canada, and Geoscience Australia that aims to deepen global understanding of where critical minerals are located. A key output of this initiative is the Critical Minerals in Ores (CMiO) database that is advancing our collective understanding of critical minerals distributions. For instance, publicly available data on the concentrations of many critical minerals are sparse because these commodities can only be produced in small, yet essential, quantities compared to the primary commodities like copper and zinc. The CMiO database helps bridge this gap by offering high-quality, multielement geochemical data from a wide variety of critical mineral-bearing deposits around the world. Importantly, it uses a novel consensus deposit environment, group, and type classification scheme developed by the agencies that allows comparisons among ore deposits from different regions. The CMiO database contains geochemical data for more than 20,000 samples from more than 100 deposit types comprising 10 deposit environments.

Fact Sheet↗
USGS2000

Biodegradation of chlorinated ethenes at a karst site in middle Tennessee

This report presents results of field and laboratory investigations examining the biodegradation of chlorinated ethenes in a karst aquifer contaminated with trichloroethylene (TCE). The study site, located in Middle Tennessee, was selected because of the presence of TCE degradation byproducts in the karst aquifer and available site hydrologic and chlorinated-ethene information. Additional chemical, biological, and hydrologic data were gathered to evaluate whether the occurrence of TCE degradation byproducts in the karst aquifer was the result of biodegradation within the aquifer or simply transport into the aquifer. Geochemical analysis established that sulfate-reducing conditions, essential for reductive dechlorination of chlorinated solvents, existed in parts of the contaminated karst aquifer. Other areas of the aquifer fluctuated between anaerobic and aerobic conditions and contained compounds associated with cometabolism, such as ethane, methane, ammonia, and dissolved oxygen. A large, diverse bacteria population inhabits the contaminated aquifer. Bacteria known to biodegrade TCE and other chlorinated solvents, such as sulfate-reducers, methanotrophs, and ammonia-oxidizers, were identified from karst-aquifer water using the RNA-hybridization technique. Results from microcosms using raw karst-aquifer water found that aerobic cometabolism and anaerobic reductive-dechlorination degradation processes were possible when appropriate conditions were established in the microcosms. These chemical and biological results provide circumstantial evidence that several biodegradation processes are active in the aquifer. Additional site hydrologic information was developed to determine if appropriate conditions persist long enough in the karst aquifer for these biodegradation processes to be significant. Continuous monitoring devices placed in four wells during the spring of 1998 indicated that pH, specific conductance, dissolved oxygen, and oxidation-reduction potentials changed very little in areas isolated from active ground-water flow paths. These stable areas in the karst aquifer had geochemical conditions and bacteria conducive to reductive dechlorination of chlorinated ethenes. Other areas of the karst aquifer were associated with active ground-water flow paths and fluctuated between anaerobic and aerobic conditions in response to rain events. Associated with this dynamic environment were bacteria and geochemical conditions conducive to cometabolism. In summary, multiple lines of evidence developed from chemical, biological, and hydrologic data demonstrate that a variety of biodegradation processes are active in this karst aquifer.

Tennessee↗
USGS2026

Deaf, deafblind, and hard of hearing university student experiences with earthquake early warning in the United States: Evaluating language planning and technology access

The growing literature on deaf and hard of hearing (DHH+) populations and disasters demonstrates that emergency communication (including alerts) is not reaching global DHH + individuals with dangerous impacts for morbidity and mortality. This is the first research study in the U.S. to qualitatively explore the experiences of DHH + persons with earthquake early warning (EEW) through group-based dialogue sessions. The study investigates eight DHH + university students'past earthquake experiences, access to EEW alerts, and perceptions of ShakeAlert Ⓡ , an EEW system for detecting earthquakes and alerting residents of California, Oregon, and Washington. Findings highlight key gaps in disaster alert usability within four thematic areas: lack of messaging in participants' language(s), unclear alert messaging, deficient message delivery mechanisms for deafblind persons, and insufficient access to earthquake information and training that leads to dependence on informal information networks. Weaknesses identified in these four themes reduce DHH + trust in EEW systems and compromise the capacity of alert recipients to take swift protective action or to mentally prepare before shaking starts. The study also underscores structural factors such as insufficient linguistic representation in disaster language planning and technology design, which ignores the linguistic and sensory access needs of DHH + individuals. Building on disaster language planning frameworks, we recommend involving DHH + populations to co-develop EEW alerts. By centering DHH + perspectives, this research contributes to ongoing efforts to ensure that EEW systems reach everyone.

California↗
USGS2025

Ecohydrological response of a forested headwater catchment to a flash drought in the Southeastern U.S.

Flash droughts differ from traditionally defined droughts in their rapidity of intensification and often associated high vapor-pressure deficit. These droughts can lead to declines in streamflow and water table depth and induce water stress to vegetation at a greater rate than droughts that manifest over longer periods. However, little is known regarding the response of forested environments to flash drought because most studies of impacts have been conducted in agricultural settings. In this study we investigated water-use patterns of riparian trees using sap flow methods and examined the role of groundwater as a source of moisture over three periods that were delimited by antecedent soil moisture conditions. For a longer-term perspective we also examine monthly streamflow over the 35-year record. We observed that trees at only one monitoring plot showed a decrease in water use relative to evaporative demand during a flash drought. Total reverse sap flow (flow toward the roots rather than the canopy) greatly increased during the flash drought period, suggesting the likely occurrence of hydraulic redistribution to the excessively dry soils. Over the drought period groundwater became a more dominant source of moisture for sustaining forest water use. Monthly mean streamflow during the flash drought approached levels observed in past multiyear droughts. This is the first study, to our knowledge, to specifically investigate the response of multiple water budget components to flash drought in a humid forest. As more studies are conducted, a better understanding of the range of expected responses are likely to emerge.

Georgia↗
USGS2024

Temporal, spatial, and chemical evolution of Quaternary high-silica rhyolites in the Mineral Mountains, Utah

The Mineral Mountains in southwestern Utah are a structurally controlled core complex at the confluence of the Colorado Plateau and the Basin and Range physiographic provinces. Aside from hosting Utah’s largest batholith, the Mineral Mountains host some of the State’s youngest high-silica rhyolites, which have been linked to a magma source that is presently being utilized as an enhanced geothermal system. The high-silica rhyolites take the form of effusive lavas and domes, and explosive products are rare. Previous K-Ar dating of these Pleistocene rhyolites placed eruptions between about 790 and 500 kilo-annum (ka) with contemporaneous basalts erupting in the valley to the east of the Mineral Mountains. Large uncertainties on these ages obscured the tempo of eruptions and thus hindered attempts to constrain the timescales of the petrogenetic processes that produced the rhyolites. In this study, we build on previous studies conducted in the 1970s and 1980s by using new geochronologic and geochemical data to investigate the temporal and spatial evolution of the youngest phase of volcanism in the Mineral Mountains. We identify two major eruptive periods, from approximately 850 to 750 ka and from approximately 590 to 480 ka. The older phase is characterized by the eruption of several basaltic lavas, two obsidian flows, and a series of coalescing porphyritic rhyolite domes. The younger phase included the eruption of six evolved high-silica rhyolite domes and one pyroclastic deposit, followed by the eruption of trachyandesite in the adjacent valley to the east. Whole-rock geochemical data indicate that the rhyolites can be divided into three chemical groups, with more evolved compositions erupting through time. The youngest rhyolites along the range crest have the lowest total iron and TiO 2 concentrations and the highest incompatible element concentrations, indicative of increasing differentiation with time and elevation. Improved precision on the eruption ages indicates a recurrence interval of approximately 20 thousand years. The eruptive flux for both periods of rhyolitic volcanism is about 0.01 cubic kilometers per thousand years, which is less than the magma resurgence flux rates for syn-caldera and post-caldera eruptions of the Valles Caldera and Yellowstone Caldera volcanic systems. Collectively, these geochemical, geochronological, and volumetric data may facilitate a better understanding of heat flux and the longevity of magmatic sources related to geothermal resources in similar small-volume, silicic systems.

Utah↗
USGS2025

Drone-based radiometric surveys provide high-resolution mine waste characterization

Airborne radiometric surveys use passive geophysical techniques to characterize geochemical variations at or near earth’s surface. These methods have been used for a variety of mapping applications, including mineral resource evaluation. However, detailed characterization of smaller geologic targets, including mine waste features, requires flying at lower altitudes and with tighter line spacing than is feasible with traditional aircraft. Here, a small uncrewed aircraft system (sUAS) equipped with a radiometric sensor was used to acquire high-resolution gamma-spectrometry over small mine waste features and a low-grade stockpile in southwestern New Mexico. The sUAS radiometric system mapped local variability within each survey area and revealed ~2–10 m wide zones where radioelements K, Th, and U may be elevated 2–10× the surrounding material. Additionally, the sUAS radiometric data revealed radioelement variability across survey sites, which correlated reasonably well with variability seen in geochemical samples at each survey site, even though samples collected from individual sites showed high local variability. The sUAS data characterized local heterogeneity within mine waste and other small geologic targets at scales of a few meters to tens of meters, which is not possible with traditional crewed aircraft, and with continuity of coverage that is not possible with ground surveys, thus filling a key gap in geophysical survey spatial resolution.

New Mexico↗
USGS2025

VIPER site analysis

We needed to evaluate available orbital data of NASA’s Volatiles Investigating Polar Exploration Rover (VIPER) mission area in order to derive a variety of maps to help the science team identify scientifically interesting places for the rover to visit and to provide scientific context for our mission. Some of these maps also fulfilled engineering and mission design needs to enable safe and efficient landing and roving. We incorporated data from the Lunar Reconnaissance Orbiter Camera, the Lunar Orbital Laser Altimeter, the Mini-RF instrument, the Chandrayaan-2 Orbital High Resolution Camera, the Korean Pathfinder Lunar Orbiter’s Shadowcam, the Kaguya Spectral Profiler and Multiband Imager, and the Chandrayaan-1 Moon Mineralogy Mapper. We used a variety of techniques to build these maps, including stereogrammetry, shape-from-shading, ice stability depth and surface temperature calculations, and the horizon method for solar illumination and direct-to-Earth communications maps. Altogether, these maps allowed us to survey for boulders, evaluate features in permanently shadowed regions that VIPER might explore, provide mineralogic context for what VIPER’s instruments may learn, estimate the ages and radar properties of craters in the VIPER mission area, and evaluate the potential for gravity traverses with the rover. These data and techniques provided a rich set of information from which both the VIPER science team and engineering teams were able to draw in order to plan a safe landing and to plan a VIPER surface mission that will be both scientifically valuable and robust from an operational perspective.

The Planetary Science Journal↗
USGS1976

Uranium and trace elements in stream sediments as an exploration tool

More than 45 trace elements have been reported in anomalous amounts in the uranium ores. The specific suite of elements associated with any one uranium deposit varies according to deposit type and geologic province. The primary geochemical halo of uranium and associated trace elements in the host rock, together with secondary dispersion halo in soils and alluvium, offers a potential geochemical exploration target. Sediment from streams near low-grade uranium occurrences in arkosic sandstone of the Denver basin, Colorado, and sediment from streams in the igneous and metamorphic terrace near the Midnite mine of eastern Washington have been analyzed for acid-extractable U, Cu,Pb, Zn, Ni, Co, Fe, Mn, Mo, Cd, Cr, Ag, V, and Se, and for total Fe, Mn, Hg, As, and organic C. The -80 mesh fraction of the alluvium downstream from a small uraniferous limonite occurrence in the Denver basin shows anomalous concentrations of U, Pb, As, Ni, Mo, V, Zn, and Se. Anomalous concentrations of U persist farther downstream (as much as 1,000 m) than any of the trace elements. In another stream system southeast of Denver, above-background levels of U, Pb, As, Zn, V, Fe, and Mn occur near a uranium anomaly (defined by other methods) which has no surface mineralization. In the Midnite mine area, sediments of streams draining prospect areas showed anomalous concentrations of uranium (as much as 10 times background), but no accompanying anomalous trace-element concentrations, although analyses of Midnite mine ores show that a broad suite of trace elements are associated with uranium.

Open-File Report↗
USGS2026

High-resolution magnetic survey using an unoccupied aerial vehicle to constrain buried lava flow geometry, volume, and eruptive history of Little Cones, Crater Flat, Nevada

Magnetic surveys are an important tool used to augment geologic mapping in distributed volcanic fields. Using magnetic anomalies, it is possible to model the geometry of shallowly buried volcanic features, such as conduits, sills, and lava flows. This subsurface mapping is important for understanding eruption dynamics and emplacement of lava flows, and it sometimes reveals buried volcanoes no longer visible at the surface. These data are critical to better interpret the numbers, styles, and magnitudes of eruptions in distributed volcanic fields and their associated volcanic hazards. New advances in unoccupied aerial vehicles (UAVs) offer an attractive middle range of resolution and aerial coverage between ground-based magnetic surveys and aeromagnetic surveys. Here, we present the results of a UAV fluxgate magnetic survey of the Little Cones, Nevada, scoria cones, which have been the target of previous ground and aeromagnetic surveys. The magnetic anomalies at Little Cones are of interest because the surrounding alluvium conceals lava flows that erupted from Little Cones, making it very difficult to understand the volume and morphology of lava flows from geologic mapping alone. Nonlinear inversion of UAV-collected magnetic data were used to model the thickness and morphology of buried Little Cones’ lava flows with higher precision than achieved previously. The sequence of events and calculated flow characteristics are then interpreted. The total volume of Little Cones, including concealed lava flows, is approximately 0.016 cubic kilometer, and the initial sheet flow erupted in less than 24 hours. The findings presented herein demonstrate that UAV-based magnetic surveys are a reliable method of data collection and an efficient alternative to other survey methods, facilitating development of a three-dimensional perspective of distributed volcanic fields.

Nevada↗
USGS2026

Assessing environmental drivers of denitrification in restored riverine floodplains

Restoration of impaired floodplains is an increasingly prevalent strategy for alleviating water quality concerns and reducing downstream flooding at watershed scales. Floodplains temporarily store water and slow flow velocity to promote sedimentation during overbank flooding and remove inorganic nitrogen from floodwater and groundwater via denitrification. Evaluating the impacts of different restoration strategies on denitrification can inform more strategic investments into floodplain modifications that improve water quality outcomes. Our research investigates how denitrification rates in floodplains respond to environmental factors that are actionable from an engineering perspective through design and water resources management. We seasonally measured soil denitrification enzyme activity and various environmental characteristics in 4 floodplains with different restoration design and management approaches at the confluence of the Wabash and Tippecanoe Rivers in Indiana, United States. Our results showed that denitrification rates in an agricultural floodplain were significantly lower than in restored floodplains with native vegetation. Certain soil conditions characteristic of floodplain wetlands were associated with higher denitrification, particularly elevated total nitrogen, moisture, silt, and organic matter contents. Vegetation species composition was correlated with denitrification rates. This link may reflect the direct effects of vegetation on soil conditions, such as supplying labile organic carbon, or indirect effects, such as vegetation acting as an indicator of hydrologic regime and land use. Denitrification seasonally varied, peaking in winter when nitrate supply from rivers draining agricultural watersheds in the region is also high. Substrate limitation of soil denitrification enzyme activity was most significant during the summer when overbank flooding, which replenishes soil nitrogen stocks, rarely occurs. Our findings indicate that denitrification capacity will likely be maximized in riverine floodplains that are restored as wetlands with diverse native vegetation and enhanced hydrologic connectivity. Such restoration activities promote higher denitrification rates via elevated moisture, fine sediment deposition, and soil organic matter.

Tippecanoe River, Wabash River↗
USGS2024

Models no not provide proof: An example of model ambiguity and application of isotopic data in a mine pit lake

Geochemical and hydrologic models of pit lakes are commonly used in environmental regulatory decisions to predict future water quality and hydrologic conditions and to understand existing pit lakes. Models may be used to quantify sulfide oxidation, predict thermal/chemical stratification and mixing, and better understand connections between pit lakes and aquifers. One concern related to the hydrologic character of pit lakes is if they are terminal (a groundwater sink with no outflow) or flowthrough (both receiving groundwater inflow and discharging to groundwater). This question was pertinent to the Liberty pit lake, a small acidic pit lake formed in a former Cu deposit in south-central Nevada where potentiometric and geochemical data potentially indicate pit-lake outflow. Potential discharge to groundwater from the pit lake was evaluated using a water-balance model, but uncertainty in hydraulic parameters led to ambiguity in the hydrologic character. Stable isotopes of water were then sampled from the pit lake and adjacent groundwater wells, which unambiguously indicated the lack of an evaporative signature in downgradient groundwater because the groundwater did not plot on a hypothetical mixing line between evaporated pit lake water and observed meteoric recharge. This methodology provided a more effective and more data-driven approach for understanding pit-lake hydrology. Although predictive models are required to quantify reasonable bounds on future conditions, many models contain substantial uncertainty and are not well suited in some environments. Datasets that provide more clear lines of evidence could be collected from existing pit lakes whenever possible to inform water-rock interaction, limnological behavior, and connectivity to adjacent groundwater.

Nevada↗
USGS2026

Site response models based on geometric parameters for southern California sedimentary basins

Site response in sedimentary basins is influenced by complex three-dimensional (3D) features, including trapping of seismic waves, focusing of seismic energy and basin resonance. Current ground motion models (GMMs) incorporate basin effects using one-dimensional parameters like V S30 and shear wave velocity isosurface depths, which are limited in capturing lateral and 3D effects. To address these limitations, we develop seismic site response models based on novel parameters that represent multi-dimensional properties of the Los Angeles Basin (LAB) geometry and shear wave velocity. We define a basin shape for the LAB using depth to subsurface geologic interfaces associated with the oldest sedimentary deposits (depth to a particular shear wave velocity horizon, i.e., 1.5 km/s - z 1.5 ) and the depth to the crystalline basement ( z cb ) which are determined using geologic cross sections and community seismic velocity model profiles. We explore a suite of geometric descriptors computed for the LAB and southern California, from which three parameters with the greatest predictive potential are selected and evaluated using empirical ground motion residual analyses in combination with the Boore et al. GMM. The results demonstrate that the zonal heterogeneity index ( ), standard deviation of the absolute difference between z 1.5 and z cb ( ) and standard deviation of z cb ( ) each provide a reduction in site-to-site variability ( ϕ S2S ) of empirical GMMs. The reduction in ϕ S2S is period-dependent, with average decreases of 3%, 26% and 6% for , , and , respectively. Although these reductions are modest from an engineering application perspective, they are statistically significant, underscoring the inherent difficulty in fully characterising complex basin effects. Collectively, these findings indicate that the inclusion of basin-specific geometric parameters yields measurable, albeit incremental, improvements in site response prediction and establishes a framework for the progressive refinement of seismic hazard characterisation within sedimentary basins.

California↗
USGS2025

Pre-eruptive characteristics of “suspect” silicic magmas in Carlin-type Au-forming systems

World-class Carlin-type Au deposits hosted in sedimentary rock were formed when profuse Eocene silicic magmatism swept across northern Nevada in response to arc migration. Carlin-type Au deposits formed along with porphyry/skarn Cu-Mo-W-Au deposits, epithermal Ag-Au deposits, and distal disseminated Ag-Au deposits. But unlike these other Au-bearing deposits that have clear associations with igneous intrusions, Carlin-type ore deposits appear to have formed distant from concealed plutons, and their origin remains controversial. Despite decades of abundant geophysical, geochronological, and geochemical studies suggesting the involvement of magmas, concrete evidence for magmatic involvement is still lacking. Consequently, the involvement of contemporaneous igneous systems remains inferred based on age, proximity, and variable isotopic, geochemical, and geophysical clues. A recent synthesis of deposit models postulates that Carlin-type Au deposits are intrusion-related, but that the causative magmas reside deeper (∼6–12 km) than in typical porphyry and peripheral systems (∼3–5 km), meaning that Carlin-type deposits are perhaps more distal expressions of igneous intrusions. We investigate a collection of “suspect” magmatic systems over a ∼7 m.y. timespan (∼41–34 Ma) that are contemporaneous with and near known Carlin-type ore deposits. We report results of a multifaceted array of in situ geochemical analyses (FTIR, EMP, SHRIMP-RG, LA-ICP-MS) of quartz-hosted melt inclusions, biotite, and quartz to better characterize the pre-eruptive characteristics of these magmas. We also report results of thermobarometry and thermodynamic phase equilibria modeling to help place constraints on magmatic reservoir depths and processes. Rather than a single “flavor” of silicic magma, we observe a surprisingly broad compositional spectrum of rhyolites, with one end of the spectrum exhibiting more arc-like (I-type) characteristics and the other end displaying more post-subduction, thick-crust extensional (A-type) characteristics. This broad compositional spectrum suggests a more complex picture of silicic crustal magmatism operating over a narrow span of time during slab rollback. Despite this spectrum, magmatic systems in this study are consistently ferroan and generally peraluminous, which we interpret as an expression of the relatively elevated geotherm at the time and incorporation of variable amounts of highly peraluminous metasedimentary crustal components. The silicic magma spectrum encompasses a range of mineralization associations, including subduction-related Cu-Mo-W-Au-Ag and post-subduction, thick-crust extensional rare-metal Mo-Sn-W-F-Be-Ag-Au, consistent with the prolific and diverse array of ore deposits that formed during this time. Carlin-type Au deposition appears to be associated with nearly the entire magmatic spectrum. This apparent indifference to silicic magma “flavor” would seem to imply that if magmas are involved in Carlin-type Au deposit genesis, they perhaps do not need to be compositionally specialized and/or possibly are only relevant as heat sources driving circulation to remobilize and redistribute metals.

Nevada↗
USGS2025

Relations of groundwater quality to long-term surface disposal of produced water near the Midway-Sunset and Buena Vista Oil Fields, California, USA

Contamination of groundwater by oil-field fluids in proximity to oil and gas development has been an issue of concern to water users and regulators given long histories of development and legacy disposal practices. A robust set of geochemical tracers including petroleum hydrocarbon compounds, thermogenic gases, inorganic ion concentrations, stable isotopes, radioactive isotopes, and noble gases were used to assess if oil-field fluids mixed with groundwater near the Midway-Sunset and Buena Vista Oil Fields in California, USA. Results show evidence of mixing of oil-field fluids with groundwater within the study area from either anthropogenic or natural processes. Produced water plumes associated with modern surface disposal facilities, used since the late 1950s, extend up to 1.5 km and currently remain within the boundaries of the oil fields. Plumes associated with earlier routing of produced water down natural drainages and in large retention structures (Midway Basin and Sunset Basin) near the Buena Vista Lake Bed are present in groundwater east of the oil fields. Based on geochemical tracer evidence, aerial imagery, and aerial electromagnetic surveys, these legacy plumes reach the western portion of the Central Valley aquifer system, an important groundwater resource for agricultural and domestic supply. The legacy plume associated with Sunset Basin may further be detected downgradient in deeper groundwater beneath the southern extent of the Buena Vista Lake Bed based on the presence of thermogenic gases and petroleum hydrocarbon compounds.

California↗
USGS2025

Concentration-discharge relations and transient metal loads reveal spatiotemporal variability in solute-generation mechanisms in a mine-affected watershed

Concentration-discharge (CQ) relations are commonly used to understand geochemical and hydrologic controls on the generation of solutes in watersheds. Despite the widespread application of CQ relations, this technique has been infrequently applied to acid mine drainage (AMD) sites, but the CQ framework may allow mechanistic understanding of remedial outcomes such as impoundment of water within underground mines. Results of CQ analyses and changes in metal loads in an AMD affected watershed in Colorado, USA indicate that dissolved loads increased at many individual locations following water impoundment within mine workings. Although increased loads were observed at most individual locations, these increases were offset by a large decrease in loading from the largest mine. A loading analysis that included data from an instream monitoring location showed a statistically significant decrease in Fe and Zn after bulkhead emplacement, indicating a net positive effect of bulkheads. Streams generally displayed dilution CQ patterns whereas mines and springs showed either flushing or chemostatic patterns prior to bulkheading, which transitioned to chemostatic patterns following bulkheading, indicating a transition from dynamic to equilibrium geochemical processes. Saturation indices for sulfide and secondary minerals indicated that mines and springs were near equilibrium for phases including schwertmannite, fluorite, and gypsum. Saturation indices vary through time for mines suggesting progressive leaching of sulfide minerals as the mass of available minerals in the mine workings decreases. Together, these diverse analyses provide an integrated understanding of the variability in solute generating processes in this watershed and may inform remediation plans for similarly affected sites by indicating the nature of mineralogic controls on water quality.

Colorado↗