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A geospatial analysis of water-quality threats from orphan wells in principal and secondary aquifers of the United States

Throughout the history of oil and gas production in the United States, millions of wells have been drilled for exploration and energy production. Hundreds of thousands of unplugged wells are no longer actively producing and are currently under orphan status, with no responsible party obligated for plugging. Orphan wells can pose threats to water resources by providing pathways for contaminants such as hydrocarbons and brines to migrate into water-supply aquifers. In this study, we investigate the potential threats to groundwater resources posed by orphan wells at the national scale. Water-quality data is extremely sparse in relation to orphan wells nationally and may not be suitable for identifying contamination from oil and gas development. We used geospatial and statistical methods to evaluate which principal and secondary aquifer systems may be most susceptible to contamination from orphan wells. Analysis involved three sets of susceptibility factors including: 1) factors related to the number and density of orphan wells; 2) factors that can threaten well integrity and contribute to transport of contaminants; and 3) factors related to groundwater withdrawal rates and the affected populations/communities in the event of water quality disturbances. From a dataset of 117,672 documented orphan wells, 64,203 fall within a principal aquifer system, while the remainder fall within a secondary aquifer system. By assessing the combination of well integrity and hydrogeologic factors within these aquifer systems, five groupings of principal aquifers were identified, where groups ranged from aquifer systems with high numbers of orphan wells, multiple well integrity threats and high withdrawals, to aquifers with a relatively low number of orphan wells, limited well integrity threats and minimal water use. Three regions of the country emerge containing aquifers with higher susceptibility to contamination from orphan oil and gas wells. These regions include 1) The Appalachian Basin (including the Pennsylvanian Aquifer System), 2) The Gulf Coast Aquifers (including the Coastal Lowlands Aquifer system) and 3) The California Aquifers (including the California Coastal Basin Aquifer system). This work is the first multivariate geospatial investigation of orphan wells and groundwater resources on a national scale, and sheds light on which aquifers are most susceptible to groundwater contamination from orphan wells.

Science of the Total Environment

U.S. Geological Survey global seabed mineral resources

The U.S. Geological Survey (USGS) provides science and data on seabed mineral resources and ecosystems, as well as on the potential hazards associated with extraction. The Nation relies on minerals for infrastructure, technology, manufacturing, and energy production. Critical minerals are essential to the economic and national security of the United States and have a supply chain vulnerable to disruption. For decades, USGS scientific innovation has contributed to the delineation of seabed mineral resources, the mechanisms of seabed mineral formation, and the environmental impacts of resource extraction. Since 1962, the USGS has also led scientific inquiries into the potential for deep sea mining. By providing impartial science on seabed minerals and their environmental setting in the deep oceans, the USGS enables decision-makers to evaluate the best practices for mineral resource development.

Fact Sheet

Probabilistic assessment of postfire debris-flow inundation in response to forecast rainfall

Communities downstream of burned steep lands face increases in debris-flow hazards due to fire effects on soil and vegetation. Rapid postfire hazard assessments have traditionally focused on quantifying spatial variations in debris-flow likelihood and volume in response to design rainstorms. However, a methodology that provides estimates of debris-flow inundation downstream of burned areas based on forecast rainfall would provide decision-makers with information that directly addresses the potential for downstream impacts. We introduce a framework that integrates a 24 h lead-time ensemble precipitation forecast with debris-flow likelihood, volume, and runout models to produce probabilistic maps of debris-flow inundation. We applied this framework to simulate debris-flow inundation associated with the 9 January 2018 debris-flow event in Montecito, California, USA. When the observed debris-flow volumes were used to drive the probabilistic forecast model, analysis of the simulated inundation probabilities demonstrates that the model is both reliable and sharp. In the fully predictive model, however, in which debris-flow likelihood and volume were computed from the atmospheric model ensemble's predictions of peak 15 min rainfall intensity, I 15 , the model generally under-forecasted the inundation area. The observed peak I 15 lies in the upper tail of the atmospheric model ensemble spread; thus a large fraction of ensemble members forecast lower I 15 than observed. Using these I 15 values as input to the inundation model resulted in lower-than-observed flow volumes which translated into under-forecasting of the inundation area. Even so, approximately 94 % of the observed inundated area was forecast to have an inundation probability greater than 1 %, demonstrating that the observed extent of inundation was generally captured within the range of outcomes predicted by the model. Sensitivity analyses indicate that debris-flow volume and two parameters associated with debris-flow mobility exert significant influence on inundation predictions, but reducing uncertainty in postfire debris-flow volume predictions will have the largest impact on reducing inundation outcome uncertainty. This study represents a first step toward a near-real-time hazard assessment product that includes probabilistic estimates of debris-flow inundation and provides guidance for future improvements to this and similar model frameworks by identifying key sources of uncertainty.

California

ECCOE Landsat quarterly Calibration and Validation report—Quarter 1, 2024

Executive Summary The U.S. Geological Survey Earth Resources Observation and Science Calibration and Validation (Cal/Val) Center of Excellence (ECCOE) focuses on improving the accuracy, precision, calibration, and product quality of remote-sensing data, leveraging years of multiscale optical system geometric and radiometric calibration and characterization experience. The ECCOE Landsat Cal/Val Team continually monitors the geometric and radiometric performance of active Landsat missions and makes calibration adjustments, as needed, to maintain data quality at the highest level. This report provides observed geometric and radiometric analysis results for Landsats 8 and 9 for quarter 1 (January–March), 2024. All data used to compile the Cal/Val analysis results presented in this report are freely available from the U.S. Geological Survey EarthExplorer website: https://earthexplorer.usgs.gov . This quarterly report is the third to include analysis results for Landsat 9, which was launched in September 2021. The inclusion of Landsat 9 analysis results was dependent on two factors: a complete reprocessing of the Landsat 9 data archive and enough time elapsing to begin formulating lifetime trends. In April 2023, all Landsat 9 image data acquired since the satellite’s launch were reprocessed to take advantage of calibration updates identified by the ECCOE Landsat Cal/Val Team. Additional information about the Landsat 9 reprocessing effort is available at https://www.usgs.gov/landsat-missions/news/upcoming-reprocessing-all-landsat-9-data . Additional information about Landsat 9 prelaunch, commissioning, and early on-orbit imaging performance is available at https://www.mdpi.com/journal/remotesensing/special_issues/15B4V2K92K . This quarterly report is the first to not include analysis results for Landsat 7 because Enhanced Thematic Mapper Plus imaging was suspended on January 19, 2024, after the satellite transitioned into full sunlight. The satellite has been drifting since early 2022 after being lowered from the nominal orbit altitude, and the transition into full sunlight is a result of the satellite operating in its extended science mission. Additional information about the imaging suspension is available at https://www.usgs.gov/landsat-missions/news/landsat-7-imaging-suspended . Additional information about the Landsat 7 extended science mission is available at https://www.usgs.gov/landsat-missions/landsat-7-extended-science-mission .

Open-File Report

ECCOE Landsat quarterly Calibration and Validation report—Quarter 2, 2024

Executive Summary The U.S. Geological Survey Earth Resources Observation and Science Calibration and Validation (Cal/Val) Center of Excellence (ECCOE) focuses on improving the accuracy, precision, calibration, and product quality of remote-sensing data, leveraging years of multiscale optical system geometric and radiometric calibration and characterization experience. The ECCOE Landsat Cal/Val Team continually monitors the geometric and radiometric performance of active Landsat missions and makes calibration adjustments, as needed, to maintain data quality at the highest level. This report provides observed geometric and radiometric analysis results for Landsats 8 and 9 for quarter 2 (April–June) of 2024. All data used to compile the Cal/Val analysis results presented in this report are freely available from the U.S. Geological Survey EarthExplorer website: https://earthexplorer.usgs.gov . This is the fourth quarterly report to include analysis results for Landsat 9, which was launched in September 2021. The inclusion of Landsat 9 analysis results was dependent on two factors: a complete reprocessing of the Landsat 9 data archive and enough time elapsing to begin formulating lifetime trends. In April 2023, all Landsat 9 image data acquired since the satellite’s launch were reprocessed to take advantage of calibration updates identified by the ECCOE Landsat Cal/Val Team. Additional information about the Landsat 9 reprocessing effort is available at https://www.usgs.gov/landsat-missions/news/upcoming-reprocessing-all-landsat-9-data . Additional information about Landsat 9 prelaunch, commissioning, and early on-orbit imaging performance is available at https://www.mdpi.com/journal/remotesensing/special_issues/15B4V2K92K . This is the second quarterly report that does not include analysis results for Landsat 7 because Enhanced Thematic Mapper Plus imaging was suspended on January 19, 2024, after the satellite transitioned into full sunlight. The satellite has been drifting since early 2022 when it was lowered from the nominal orbit altitude, and the transition into full sunlight is a result of the satellite operating in its extended science mission. Additional information about the imaging suspension is available at https://www.usgs.gov/landsat-missions/news/landsat-7-imaging-suspended . Additional information about the Landsat 7 extended science mission is available at https://www.usgs.gov/landsat-missions/landsat-7-extended-science-mission .

Open-File Report

Estimation of dynamic geologic CO2 storage resources in the Illinois Basin, including effects of brine extraction, anisotropy, and hydrogeologic heterogeneity

Since the vast majority of carbon dioxide (CO 2 ) storage resources in the United States are in deep saline aquifers, optimizing the use of these saline storage resources could be crucial for efficient development of geologic CO 2 storage (GCS) resources and basin- or larger-scale deployment of GCS in the country. Maximum CO 2 injection rates can be enhanced by extracting brine from the CO 2 storage unit. However, disposal of the extracted brine is both a technological and economic challenge. The lowest-cost option would likely be reinjection of the extracted brine into another formation above or below the CO 2 storage unit. Therefore, it is important to estimate brine injectivity as it will constrain the potential to increase CO 2 injectivity at an injection site that has access to multiple geologic storage units where either CO 2 or brine can be injected. Using a simulation-optimization framework, coupled with a non-isothermal, multiphase CO 2 -water-salt equation-of-state module, we developed a computationally efficient method for evaluating optimization of simultaneous CO 2 injection, brine extraction, and brine (re)injection at hypothetical injection sites deployed across a geologic basin. The Illinois basin is ideal for testing our methodology because it contains multiple geologic storage units with seals in between them to isolate injection of CO 2 in one unit from interfering with the injection of either brine or CO 2 in another unit above or below it. In addition, we investigated the relative effects of variation in key geologic parameters as well as two reservoir structures (hydrogeologic heterogeneity/anisotropy and homogeneity/isotropy) on CO 2 injectivities and enhancement of CO 2 injectivity through extracting brine. Results suggest that permeability, depth, and especially thickness of the storage unit could be the most influential parameters determining CO 2 injectivity. They also suggest that only injecting CO 2 into the storage unit with the greatest injectivity, enhancing that unit’s injectivity by extracting brine, and disposing of the produced brine in other suitable units could maximize total CO 2 injectivity in limited regions of the basin. At the majority of simulated injection sites, however, we found that injecting CO 2 into all of the accessible and suitable storage units was more likely to maximize the CO 2 storage resource.

Illinois, Kentucky, Indiana

Editorial: From cold seeps to hydrothermal vents: Geology, chemistry, microbiology, and ecology in marine and coastal environments

This Research Topic compiles contemporary studies on cold seeps, hydrothermal vents, mud volcanoes, and related seafloor features that are associated with focused fluid emissions and the transfer of carbon, other chemical species, and sometimes heat from the geosphere to the ocean. Because these features sometimes tap fluids and gas originating kilometers below the seafloor, they provide an important window into deep processes that are otherwise inaccessible to scientists. At the shallow portion of their journey, migrating fluids nearing the seafloor contribute to a range of unique biological, physical, and chemical processes within the sediments themselves and at the sediment-water interface. Seafloor fluid emissions play a critical role in global biogeochemical cycles, ocean chemistry, and possibly even climate change. Seafloor leakage points often emit hydrocarbon gases (especially methane and CO 2 ) and are sometimes the loci for deposition of seafloor minerals that have economic value. A burgeoning area of research focuses on natural products generated at these features, seeking compounds with potential pharmaceutical or other applications. Multidisciplinary studies have become routine for characterization of seafloor fluid emission sites, attesting to the inseparability of geologic, physical, chemical, and biological processes in these settings. It is increasingly common for researchers to combine in a single research cruise: subbottom imaging and seafloor mapping; porewater and water column geochemistry and gas sampling; sediment retrieval for lithologic, biostratigraphic, and solid phase analyses; and studies of benthic and subseafloor communities at the microbial to macrofaunal scales. This multidisciplinary approach has the advantage of ensuring the spatial and temporal coincidence of surveys and samples, an important factor at highly dynamic seafloor fluid emission sites. In addition, researchers often use remotely operated vehicles (ROVs), autonomous underwater vehicles (AUVs), or human-occupied vehicles (HOVs) to record video of the seafloor, compile photomosaics, collect targeted samples, and survey with high-resolution geophysical near-seafloor systems, providing a degree of detail about seafloor fluid emission sites that is unprecedented compared to most areas of the deep ocean. While rarer, long-term cabled observatories or shorter-term deployments of portable observatories are also used at some loci for seafloor fluid flux and are particularly helpful for capturing temporal variations at these dynamic features. Here we summarize the Research Topic’s contribution to multidisciplinary seafloor emission studies in the categories of cold seeps, mud volcanoes, and hydrothermal vents. Figure 1 shows the geographic distribution of the studies in this Research Topic and key features referred to in this Introduction.

Frontiers in Earth Science

Four-band image mosaic of the Colorado River Corridor downstream of Glen Canyon Dam in Arizona, derived from the May 2021 airborne image acquisition

In May 2021, the U.S. Geological Survey’s Grand Canyon Monitoring and Research Center acquired airborne multispectral high-resolution data for the Colorado River in the Grand Canyon, Arizona. The image data, which consist of four spectral bands (red, band 1; green, band 2; blue, band 3; and near infrared, band 4) with a ground resolution of 20 centimeters, are available as 16-bit unsigned-integer GeoTIFF files in Sankey and others (2024) (available online at https://doi.org/10.5066/P9BBGN6G ). The image files are projected in the State Plane Coordinate System, using the central Arizona zone (202) with the North American Datum of 1983 National Adjustment of 2011. The assessed spatial accuracy for these data is based on 47 ground-control points that were independent from the ground-control points used by the contractor for aerotriangulation and is reported at the 95-percent confidence level as 0.514 meter (m) and a root mean square error of 0.297 m. The intended uses of this dataset are primarily in support of scientific research and monitoring applications. Examples of these applications include high-resolution spatial and temporal change detection of the river channel, geomorphic landforms, riparian vegetation, and backwater and nearshore habitat, as well as other ecosystem-wide mapping. These imagery data also serve as reference material for field science mission planning, as base data for field data collection including community science activities, and as a highly detailed guide for technical boat operation during science activities such as reconnaissance for nighttime missions and navigating rapids during low flows.

Arizona, Nevada, Utah

On-demand global Landsat evapotranspiration product: Development, evaluation, and dissemination

Global actual evapotranspiration (ET) is one of the essential climate variables needed to understand and manage the relationships among food, energy, and water resources. The U.S. Geological Survey Earth Resources Observation and Science (EROS) Center launched a provisional ET product in 2020, offering on-demand, field-scale global coverage derived from Landsat data through the EROS Science Processing Architecture (ESPA) platform. The ESPA interface provides ET data for cloud-free Landsat overpasses starting in 1982 with Landsat 4 through the current Landsat 9. The ET data are delivered as a Provisional Level-3 Science product created using the Operational Simplified Surface Energy Balance (SSEBop) model. Landsat surface temperature and reference ET are the main model drivers along with vegetation index and net radiation for model parameterization. A large volume of Landsat-based ET orders (e.g., over 1,200,000 images from June 2020 through December 2025) around the world indicate increasing awareness and application of the ET data. The ESPA platform enables land and water resource managers and researchers to access a first-order ET product without requiring advanced knowledge of remote sensing technology or evapotranspiration modeling. We present the methodology and workflow of the on-demand Landsat ET product and its performance evaluations over diverse hydro-climatic settings. The product can help estimate field-scale consumptive water use and thus quickly and consistently assess historical water use, allocation, and budget to inform water management under changing environments. Future ET data aggregated to monthly and seasonal time scales are expected to enhance integration with decision-making tools and procedures.

Remote Sensing of Environment

Constraining landslide frequency across the United States to inform county-level risk reduction

Informative landslide hazard estimates are needed to support landslide mitigation strategies to reduce landslide risk across the United States. Whereas existing national-scale landslide susceptibility products assess where landslides are likely to occur, they do not address how often , which is a critical element of landslide hazard and risk assessments. In particular, the U.S. Federal Emergency Management Agency's National Risk Index (NRI) requires landslide frequency estimates to inform expected annual loss estimates. We present county-level landslide frequency (landslides per area per year) estimates for the 50 US states. We applied Bayesian negative binomial regression to estimate both the expected (average) reported landslide frequency and full distribution of annual landslide counts for each county. We compared a suite of models that used combinations of landslide-susceptible area, probability of potentially triggering earthquakes, frequency of potentially triggering precipitation, and ecological region as predictors. We trained our models with landslide inventory data from counties with the most comprehensive records available nationwide and used zero-inflated negative binomial distributions as an incompleteness model to correct for temporal reporting gaps. We selected a preferred frequency model to inform the NRI based on information criteria and physically plausible parameter estimates. The model showed that average annual reported landslide frequencies vary by 5 orders of magnitude across US counties, ranging from 0.002 (0.00015–0.05) landslides 1000 km −2 yr −1 in Kusilvak Census Area, Alaska, to 29 (19–46) landslides 1000 km −2 yr −1 in Lake County, California, reflecting the country's strong variations in landslide susceptibility, earthquake probability, and other factors for which ecological region serves as a proxy. Counties with estimated frequencies in the top 20 % of all counties are predominately along the West Coast of the continental United States, in mountainous regions of the Pacific Northwest and Intermountain West, in locally steep or earthquake-prone regions of the Midwest and Southeast, along the Appalachians, in southern and southeastern Alaska, and on some Hawaiian islands. By examining the number of landslides predicted in 99th percentile years for each county, we identified that 26 % of US counties likely have potential for widespread landsliding with more than 10 landslides 1000 km −2 yr −1 , even when such large events have not been reported in the training data for that county. Overall, our results better represent the range of possible landslide frequencies and spatial variations than previous national-scale estimates reported in the NRI, and our approach can inform other risk-reduction and loss-mitigation efforts across the United States and globally.

Natural Hazards and Earth System Sciences

Permafrost–wildfire interactions: active layer thickness estimates for paired burned and unburned sites in northern high latitudes

As the northern high-latitude permafrost zone experiences accelerated warming, permafrost has become vulnerable to widespread thaw. Simultaneously, wildfire activity across northern boreal forest and Arctic/subarctic tundra regions impacts permafrost stability through the combustion of insulating organic matter, vegetation, and post-fire changes in albedo. Efforts to synthesis the impacts of wildfire on permafrost are limited and are typically reliant on antecedent pre-fire conditions. To address this, we created the FireALT dataset by soliciting data contributions that included thaw depth measurements, site conditions, and fire event details with paired measurements at environmentally comparable burned and unburned sites. The solicitation resulted in 52 466 thaw depth measurements from 18 contributors across North America and Russia. Because thaw depths were taken at various times throughout the thawing season, we also estimated end-of-season active layer thickness (ALT) for each measurement using a modified version of the Stefan equation. Here, we describe our methods for collecting and quality-checking the data, estimating ALT, the data structure, strengths and limitations, and future research opportunities. The final dataset includes 48 669 ALT estimates with 32 attributes across 9446 plots and 157 burned–unburned pairs spanning Canada, Russia, and the United States. The data span fire events from 1900 to 2022 with measurements collected from 2001 to 2023. The time since fire ranges from 0 to 114 years. The FireALT dataset addresses a key challenge: the ability to assess impacts of wildfire on ALT when measurements are taken at various times throughout the thaw season depending on the time of field campaigns (typically June through August) by estimating ALT at the end-of-season maximum. This dataset can be used to address understudied research areas, particularly algorithm development, calibration, and validation for evolving process-based models as well as extrapolating across space and time, which could elucidate permafrost–wildfire interactions under accelerated warming across the high-northern-latitude permafrost zone. The FireALT dataset is available through the Arctic Data Center ( https://doi.org/10.18739/A2RN3092P , Talucci et al., 2024).

Arctic

Performance analysis of oil recovery and CO2 retention in a greenfield residual oil zone: CO2-EOR in Tall Cotton Field (Permian Basin, West Texas, USA)

Residual oil zones (ROZs) can offer significant oil resources via enhanced oil recovery (EOR) as well as subsurface carbon dioxide (CO 2 ) retention during injection. If injected CO 2 is anthropogenic, the ROZs can offer a substantial geologic storage potential. The ROZs below the oil/water contact (OWC) of main pay zones (MPZ) in conventional reservoirs or brownfields, are more commonly developed for CO 2 injection and oil production and reported in the literature. However, CO 2 -EOR in greenfield ROZs, reservoirs without a MPZ present, have rarely been developed for CO 2 -EOR operation. The Tall Cotton Field of West Texas, Permian Basin, which started production in 2015 (Phase 1) and expanded in 2017 (Phase 2) from the San Andres Limestone, is one of the first examples of greenfield ROZs developed for EOR by injecting CO 2 . This paper analyses EOR and CO 2 retention performance of Tall Cotton Field using allocated injection and production data from inverted 5-spot well patterns of Phase-1 and -2 developments. Production and injection data allocated to each of the 28 identified patterns (nine 20-acre patterns for Phase-1, three 20-acre and sixteen 10-acre patterns for Phase-2) were analyzed for historical and forecasted oil recovery using ratio-trend decline analysis, and for CO 2 retention performance of the patterns. The allocated data were further used to calculate injected reservoir pore volume and void replacement ratios (VRR) for the analysis period. Quantitative results indicated that oil recovery factors of the 5-spot patterns varied between 4–10 %, and 5–30 % between the end of injection and the forecast periods, respectively. Storage of CO 2 , on the other hand, increased to a mean value of ∼7130 MMscf per pattern in Phase-1 and to a mean storage of 3700 MMscf per pattern in Phase-2 until the end of injection, followed by a decline after the end of injection and into the forecast period. Resulting CO 2 utilization factors ∼6–50 Mscf/bbl were estimated at the end of injection. Overall, presented results suggested that developing greenfield ROZs for CO 2 -EOR can be as promising as brownfield ROZs and mature MPZs for EOR and underground storage of injected CO 2 . For Tall Cotton Field, results suggest that Phase-2 patterns generally outperformed Phase-1 for oil recovery factors, while Phase-1 performed better in CO 2 retention performance metrics. This is the first study in the literature that reports a detailed CO 2 -EOR performance analysis of a greenfield ROZ in the Permian Basin, which can potentially allow for comparison with MPZs and brownfield ROZs.

Texas

Monitoring and assessment of urban stormwater best management practices at selected Chicago public schools in Chicago, Illinois, from September 1, 2016, to July 1, 2017

The Space to Grow program helps transform aging and neglected schoolyards of Chicago Public Schools into outdoor community spaces with the goal of promoting health and learning while addressing neighborhood flooding issues. Virgil I. Grissom Elementary School and Donald L. Morrill Math and Science School were selected in 2014 for schoolyard upgrades and the installation of various green infrastructure (GI) improvements. The U.S. Geological Survey installed sensors to measure precipitation, groundwater levels, and stormwater runoff volumes from September 1, 2016, to July 1, 2017. At Virgil I. Grissom Elementary School, about 933,000 gallons of water fell on the schoolyard during the monitoring period. No discharge was recorded coming from the GI sewer lines, but backflow indicated water was flowing from the sewer line draining the impervious running track into the combined manhole structure and backwards into the GI retention basins (as designed). This design allowed for a 100-percent capture rate. Native soil at Virgil I. Grissom Elementary School also was conducive to rapid infiltration. Soil borings at Virgil I. Grissom Elementary School indicated about 10.5 feet (ft) of fine sand overlying silty clay to a depth of at least 16 ft. At Donald L. Morrill Math and Science School, about 1,120,000 gallons of water fell on the schoolyard during the monitoring period. About 72.5 precent of this water was discharged into the sewer system, and the other 27.5 percent was captured by the GI. Unlike Virgil I. Grissom Elementary School, the soil profile at Donald L. Morrill Math and Science School consisted of about 5 ft of clay loam overlying stiff blue clay to a depth of at least 12 ft. The sewer line coming from the GI under the football field was at the bottom of the reservoir. This design seemed to allow water to flow out of the line before being absorbed by the retention basin.

Illinois

Critical minerals in mine waste

Introduction Critical minerals are commodities with vulnerable supply chains that play a vital role in supporting the United States’ economy, national defense and security, emerging technologies, and energy independence. The prosperity of our Nation depends on generating a resilient supply of domestic critical minerals; mine waste may be an untapped source of these commodities. Mine waste from centuries of legacy mining persist on the landscape and may contain critical minerals and other valuable commodities previously deemed uneconomic to recover. At modern mines, the financial viability of recovering byproduct critical minerals, which are not the primary target, may be marginal and can ultimately destine them to mine waste. Further, mine waste can be a liability for the mining company or, at legacy mines, the taxpayer because of its effect on the landscape. The U.S. Geological Survey (USGS) has several initiatives to evaluate critical mineral resources in various types of waste. This factsheet highlights studies of mine waste carried out by USGS scientists at the Geology, Energy & Minerals Science Center in collaboration with other science centers funded through the USGS Mineral Resources Program. Recovery of critical minerals from mine waste can aid in remediation efforts and increase domestic supply of vital mineral resources.

Fact Sheet

Refining the earthquake history of south-central Alaska through lake records

The Alaska–Aleutian subduction zone (AASZ) is one of the world's most seismically active plate boundaries and the source of the 1964 M w 9.2 Great Alaska earthquake–the second largest instrumentally recorded earthquake in the world. Understanding the nature and frequency of such earthquakes is necessary for seismic and tsunami hazard assessment, but instrumental and historical records that span less than 150 years are too short to allow a statistically reliable analysis of earthquake recurrence times. This calls for studies of evidence of past earthquakes, extending the earthquake catalog further back in time. Subduction-zone paleoseismology in south-central Alaska is predominantly based on coastal evidence of land-level changes and tsunamis generated by megathrust earthquakes and preserved in the geological record. A complementary approach is lacustrine paleoseismology, which is still a relatively young discipline in Alaska. However, globally, lake basins are well-established high-resolution and continuous recorders of paleoseismic activity along subduction zones, relying on the identification of underwater landslide deposits and turbidites generated by seismic shaking. As a result, lake basins not only register ground shaking from megathrust earthquakes, but also from intraslab and crustal earthquakes, which are typically not accompanied by significant land-level changes. In this review paper, we combine coastal and lacustrine paleoseismology approaches to refine the south-central Alaskan earthquake history by comparing the paleoseismic records from two lakes (i.e., Eklutna Lake, located in the Chugach Mountain Range, and Skilak Lake, situated on the Kenai Peninsula) with the coastal and crustal earthquake catalog in Alaska. The resulting age ranges of all known megathrust earthquakes involving the Alaskan megathrust between the Kodiak and Prince William Sound (PWS) sections are more precise and accurate for the last 1.3 kyrs BP than the previously published age ranges from coastal records. As a result, this study supports the following key conclusions: (1) The 1964 CE earthquake was an exceptionally strong and unique event in the last 2000 years, rupturing the PWS, Kenai, Barren Islands, and Kodiak sections simultaneously. (2) The high-resolution and seasonal markings of the varved lake records now disentangle for the first time closely timed earthquakes, which was not possible based on the coastal evidence alone. (3) No persistent megathrust rupture boundaries exist. So, the possibility of a full rupture of the entire eastern AASZ, from PWS to Semidi cannot be excluded. (4) The rupture pattern in the eastern AASZ reveals superimposed cycles of multi-asperity ruptures (1964 earthquake) and clustered complementary partial ruptures, or rupture cascades. (5) The PWS section hosts the largest asperity in the eastern AASZ. (6) The shaking record of megathrust earthquakes indicates a time-dependent (quasiperiodic) behavior for the study area, but the observation of complementary clusters means that the hazards will not drop to zero but instead may even increase for a neighboring section. (7) The time-independent behavior of intraplate earthquakes implies that the intraslab hazard did not decrease following the 2016 and 2018 earthquakes. This study utilizes an integrated approach for subduction zone paleoseismology as a solution for unraveling recurrence and rupture patterns in Alaska, which can be applied worldwide.

Alaska

Foundational uncertainties in terminal Ediacaran chronostratigraphy revealed by high-precision zircon U-Pb geochronology of the Nama Group, Namibia

The Nama Group of southern Namibia and northwestern South Africa hosts the best-dated mixed carbonate-siliciclastic foreland basin succession of the terminal Ediacaran [ca. 551 million years (Ma) ago to <538 Ma] and is key for resolving the chronology of early metazoan evolution. Numerous silicified volcanic tuff interbeds are present, but differing interpretations regarding the fidelity of their ages lead to different regional stratigraphic correlations, especially for the Urusis Formation of the Schwarzrand Subgroup. An expanded record of the Urusis Formation is found in the Swartpunt area of southern Namibia, which has yielded an important metazoan biota. But the succession in this area is preserved as a series of thrusts at the leading edge of the Gariep orogenic belt and zircon U-Pb data show systematic age repetition. We use regional stratigraphic and structural mapping, integrated with carbonate carbon isotope (δ 13 C carb ) chemostratigraphy and high-precision radioisotope U-Pb zircon geochronology from outcrop and recently acquired drill core to develop a temporally calibrated basin-wide depositional model. This integrated dataset either reflects complex zircon reworking, inheritance, or potential analytical biases (Scenario 1) or the presence of a Gariep-related cryptic décollement within the Spitskop Member that has resulted in stratigraphic repetition (Scenario 2). We investigate the evidence for and against both scenarios and consider their implications for stratigraphic and δ 13 C carb correlations between the Swartpunt area and coeval exposures along the Orange River border with South Africa. Given that these issues are in an area that hosts numerous silicified ash beds and extensive exposure, an inability to confidently discount either scenario highlights a level of compounding uncertainty in zircon U-Pb geochronology that must be considered when attempting to build global chronostratigraphic frameworks. Scenario 1 implies that some of the weighted mean ages and Bayesian eruption ages from the Swartpunt area may be >1 Myr older than the depositional age of their respective ash beds when assuming existing stratigraphic correlations. If this scenario is preferred, then a cautious approach would be to consider all weighted mean zircon U-Pb ages from ash beds to reflect maximum depositional ages. Both scenarios support deposition of the Huns Member >540 Ma in the Swartpunt area if the oldest weighted mean age reported here represents a near-depositional age, which has significant implications for the temporal calibration of important terminal Ediacaran ichnofossil assemblages and future cyclostratigraphic studies. Stratigraphic correlations common to both scenarios allow us to temporally calibrate a basin evolution model for the Nama Group. Temporal trends in initial hafnium isotope (εHf) compositions of zircon grains from ash beds throughout the succession may support progressive crustal thickening associated with underplating of the Damara orogenic belt along the northern periphery of the Kalahari craton from ca. 547 Ma to ca. 538 Ma. The compilation of new and published zircon U-Pb ages may also imply that the locus of carbonate platform development migrated from north to south (present co-ordinates), tracking the migration of foredeep subsidence.

Earth-Science Reviews

Understanding the resource potential of natural hydrogen on Earth: Scientific gaps, uncertainties and recommendations

A comprehensive scientific research roadmap is essential to bridge knowledge gaps and deepen the understanding of key geological, geochemical, and geophysical aspects of natural hydrogen (H 2 ) as a potential new energy resource. This paper reviews major scientific uncertainties on natural H 2 , suggesting research priorities, as a guide for defining exploration strategies, techniques, and data interpretation. The uncertainties concern all phases of the natural H 2 cycle, from generation (source rocks) through migration (advection and diffusion) and accumulation (reservoir and cap rocks) to the application and interpretation of subsurface and surface geochemical and geophysical exploration techniques. Understanding H 2 sources and generation rates (the amount of H 2 generated by a given volume of rock over time) is crucial for determining whether a geological H 2 system operates as a short-term dynamic system with rapid H 2 production and release, or as a conventional gas system with long-term accumulations, analogous to petroleum reservoirs. Preliminary estimates for serpentinisation, radiolysis, and organic matter degradation suggest that H 2 generation is not inherently fast, especially for non-hydrothermal continental systems (crystalline basement of shields, ophiolites, peridotite massifs, sedimentary basins), and long-term accumulations, like those of fossil natural gas systems, represent the most likely scenario. The mechanisms of H 2 migration through geological formations require application of fundamental principles of fluid-flow physics, distinguishing advection and diffusion, as well as their forms (from gas-phase, bubble flows to aqueous solutions). Additional studies of H 2 accumulation and retention in subsurface reservoirs could improve understanding of mechanisms of H 2 migration by focusing on the rock fluid-bearing properties and the factors affecting H 2 preservation, such as the presence of cap rocks impermeable to H 2 , pressure conditions, residence times, and microbial or abiotic consumption. Advanced techniques, including reservoir modelling, flow simulations, 3D imaging (micro-CT) of H 2 -bearing rocks, and extraction and analysis of gas occluded in rocks, can provide insights into the stability and potential recoverability of H 2 accumulations. The interpretation of surface exploration techniques, including gas geochemistry, geophysics, and remote sensing, long employed in mineral and energy resource exploration, is now being adapted for natural H 2 studies, but challenges remain in the data interpretation. Distinguishing H 2 seepage due to geological degassing from H 2 produced near the surface by modern microbial processes or artificial sources, such as hammering or drilling for soil-gas sampling, drilling into aquifers, and corrosion in boreholes, is an essential step in exploration. The simple detection of H 2 in soils, even in morphological structures like sub-circular depressions or “fairy circles”, cannot be cursorily interpreted as a signal of natural H 2 seepage from a deep source. A holistic geochemical approach, including isotopic analyses of gases associated with H 2 , is recommended to distinguish among the variety of possible H 2 origins. Observations of H 2 in wells should be interrogated to rule out possible artifacts such as corrosion and drill bit metamorphism. The integration of multiple geophysical methods, including seismic, gravimetric, magnetic, and electro-magnetic surveys, is recommended to mitigate interpretation ambiguities regarding the structure of a subsurface H 2 system (source and reservoir rocks, including fluid and gas storage), due to the non-uniqueness of rock-specific physical properties.

Earth-Science Reviews

System characterization report on the Earth Surface Mineral Dust Source Investigation (EMIT) sensor

Executive Summary This report addresses system characterization of the Earth Surface Mineral Dust Source Investigation (EMIT) sensor, an imaging spectrometer developed by the National Aeronautics and Space Administration. This report is part of a series of system characterization reports produced and delivered by the U.S. Geological Survey Earth Resources Observation and Science Cal/Val Center of Excellence. These reports present and detail the methodology and procedures for characterization; present technical and operational information about the specific sensing system being evaluated; and provide a summary of test measurements, data retention practices, data analysis results, and conclusions. The Earth Resources Observation and Science Cal/Val Center of Excellence system characterization team completed data analyses to characterize the geometric (interior and exterior) and radiometric performances. Results of these analyses indicate that the EMIT sensor has a band-to-band geometric performance in the range of −0.355 to 0.210 pixel with a few exceptions of shortwave infrared channels. Geometric offset relative to the Landsat 8 Operational Land Imager ranged from −15.966 meters (−0.266 pixel) to 43.844 meters (0.731 pixel). Offset of a radiometric comparison ranged from −0.016 to 0.025, and slope of a radiometric comparison ranged from 0.837 to 0.985. EMIT agreed with Radiometric Calibration Network measurements within 5 percent across most of the spectral channels.

Open-File Report