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USGS1996

Level II scour analysis for Bridge 14 (FFIETH00010014) on Town Highway 1, crossing the Fairfield River, Fairfield, Vermont

This report provides the results of a detailed Level II analysis of scour potential at structure FFIETH00010014 on Town Highway 1 crossing the Fairfield River, Fairfield, Vermont (figures 1–8). A Level II study is a basic engineering analysis of the site, including a quantitative analysis of stream stability and scour (U.S. Department of Transportation, 1993). Results of a Level I scour investigation also are included in Appendix E of this report. A Level I investigation provides a qualitative geomorphic characterization of the study site. Information on the bridge, gleaned from Vermont Agency of Transportation (VTAOT) files, was compiled prior to conducting Level I and Level II analyses and is found in Appendix D. The site is in the Green Mountain section of the New England physiographic province in northwestern Vermont. The 7.84-mi 2 drainage area is in a predominantly rural and forested basin. In the vicinity of the study site, the surface cover on the upstream left and downstream right is row crops. The surface cover on the upstream right and downstream left is pasture. In the study area, the Fairfield River has a sinuous channel with a slope of approximately 0.006 ft/ft, an average channel top width of 33 ft and an average channel depth of 3 ft. The channel bed material ranges from silt to gravel with a median grain size (D 50 ) of 15.4 mm (0.0505 ft). The geomorphic assessment at the time of the Level I and Level II site visit on July 11, 1995, indicated that the reach was laterally unstable. The Town Highway 1 crossing of the Fairfield River is a 26-ft-long, two-lane bridge consisting of one 23-foot concrete span (Vermont Agency of Transportation, written communication, March 9, 1995). The bridge is supported by vertical, concrete abutments with wingwalls. The channel is skewed approximately 27 degrees to the opening while there is no opening-skew-to-roadway. The bridge is located on a sharp channel bend. Th e left abutment is impacted due to this bend. A scour hole 1.5 ft deeper than the mean thalweg depth was observed along the left abutment during the Level I asse ssment. Scour protection measures at the site include type- 3 stone fill (less than 48 inches diameter ) along the immediate upstream banks and along the base of the upstream left wi ngwall. Type-2 stone fill (le ss than 36 inches diameter) was present along the downstream left wingwall. A dditional details describing conditions at the site are included in the Level II Summary and Appendices D and E. Scour depths and rock rip-rap sizes were computed using the general guidelines described in Hydraulic Engineering Circular 18 (Richardson and others, 1995). Total scour at a highway crossing is comprised of three components: 1) long-term streambed degradation; 2) contraction scour (due to accelerated flow caused by a reduction in flow area at a bridge) and; 3) local scour (caused by accelerated flow around piers and abutments). Total scour is the sum of the three components. Equations are available to compute depths for contraction and local scour and a summary of the results of these computations follows. Contraction scour for all modelled flows ranged from 5.4 to 8.0 ft. The worst-case contraction scour occurred at the 500-year discharge. Abutment scour ranged from 3.0 to 8.3 ft. The worst-case abutment scour also occurred at the 500-year discharge. Additional information on scour depths and depths to armoring are include d in the section titled “Scour Results”. Scoured-streambed elevations, based on the calculated scour depths, are presented in tables 1 and 2. A cross-section of the scour computed at the bridge is presented in figure 8. Scour depths were calculated assuming an infinite depth of erosive material and a homogeneous particle-size distribution. It is generally accepted that the Froehlich equation (abutment scour ) gives “excessively conservative estimates of scour depths” (Richardson and others, 1995, p. 47). Usually, computed scour depths are evaluated in combination with other information including (but not limited to) historical performance during flood events , the geomorphic stability assessment, existing scour protection measures, and the results of the hydraulic analyses. Therefore, scour depths adopted by VTAOT may differ from the computed values documented herein.

Vermont↗

USGS1997

Level II scour analysis for Bridge 12 (FFIETH00030012) on Town Highway 3, crossing the Fairfield River, Fairfield, Vermont

This report provides the results of a detailed Level II analysis of scour potential at structure FFIETH00030012 on Town Highway 3 crossing the Fairfield River, Fairfield, Vermont (figures 1–8). A Level II study is a basic engineering analysis of the site, including a quantitative analysis of stream stability and scour (U.S. Department of Transportation, 1993). Results of a Level I scour investigation also are included in Appendix E of this report. A Level I investigation provides a qualitative geomorphic characterization of the study site. Information on the bridge, gleaned from Vermont Agency of Transportation (VTAOT) files, was compiled prior to conducting Level I and Level II analyses and is found in Appendix D. The site is in the Green Mountain section of the New England physiographic province in north-western Vermont. The 7.34-mi 2 drainage area is in a predominantly rural basin with forest on the valley walls and pasture/row crops on the valley bottom. In the vicinity of the study site, the surface cover is row crops with a few trees on the immediate banks. In the study area, the Fairfield River has a meandering channel with a slope of approximately 0.005 ft/ft, an average channel top width of 37 ft and an average channel depth of 6 ft. The predominant channel bed materials are sand and gravel with a median grain size (D 50 ) of 32.5 mm (0.107 ft). The geomorphic assessment at the time of the Level I and Level II site visit on June 16, 1995, indicated that the reach was stable. The Town Highway 3 crossing of the Fairfield River is a 24-ft-long, one-lane bridge consisting of one 20-foot concrete span (Vermont Agency of Transportation, written communication, March 8, 1995). The bridge is supported by vertical, concrete abutments with wingwalls. The channel is skewed approximately 40 degrees to the opening. Although bridge records show an opening-skew-to-roadway of 45 degrees, the skew measured from surveyed points was 30 degrees. At the time of the level I assessment, the left abutment had been undermined and settled into a scour hole at the upstream end. The right abutment footing was exposed but not undermined. The scour protection measures at the site were type-1 stone fill (less than 12 inches diameter) on the downstream right bank, and type-2 stone fill (less than 36 inches diameter) along the entire base of the upstream right wingwall, the upstream banks, and downstream left bank. The type-2 stone fill on the left bank downstream changes to type-1 about 55 feet downstream of the bridge. Additional details describing conditions at the site are included in the Level II Summary and Appendices D and E. Scour depths and rock rip-rap sizes were computed using the general guidelines described in Hydraulic Engineering Circular 18 (Richardson and others, 1995). Total scour at a highway crossing is comprised of three components: 1) long-term streambed degradation; 2) contraction scour (due to accelerated flow caused by a reduction in flow area at a bridge) and; 3) local scour (caused by accelerated flow around piers and abutments). Total scour is the sum of the three components. Equations are available to compute depths for contraction and local scour and a summary of the results of these computations follows. Contraction scour for all modelled flows ranged from 1.6 to 3.0 ft. The worst-case contraction scour occurred at the 500-year discharge. Abutment scour ranged from 3.2 to 4.0 ft. at the left abutment and 9.7 to 11.7 feet at the right abutment. The worst-case left abutment scour occurred at the incipient over-topping discharge, which was less than the 100-year discharge. The worst-case right abutment scour occurred at the 500-year discharge. Additional information on scour depths and depths to armoring are included in the section titled “Scour Results”. Scoured-streambed elevations, based on the calculated scour depths, are presented in tables 1 and 2. A cross-section of the scour computed at the bridge is presented in figure 8. Scour depths were calculated assuming an infinite depth of erosive material and a homogeneous particle-size distribution. It is generally accepted that the Froehlich equation (abutment scour) gives “excessively conservative estimates of scour depths” (Richardson and others, 1995, p. 47). Usually, computed scour depths are evaluated in combination with other information including (but not limited to) historical performance during flood events, the geomorphic stability assessment, existing scour protection measures, and the results of the hydraulic analyses. Therefore, scour depths adopted by VTAOT may differ from the computed values documented herein.

Vermont↗

USGS2016

California State Waters Map Series — Offshore of Monterey, California

Introduction In 2007, the California Ocean Protection Council initiated the California Seafloor Mapping Program (CSMP), designed to create a comprehensive seafloor map of high-resolution bathymetry, marine benthic habitats, and geology within the 3-nautical-mile limit of California’s State Waters. The CSMP approach is to create highly detailed seafloor maps through collection, integration, interpretation, and visualization of swath bathymetry data, acoustic backscatter, seafloor video, seafloor photography, high-resolution seismic-reflection profiles, and bottom-sediment sampling data. The map products display seafloor morphology and character, identify potential marine benthic habitats, and illustrate both the surficial seafloor geology and shallow subsurface geology. The Offshore of Monterey map area in central California is located on the Pacific Coast, about 120 km south of San Francisco. Incorporated cities in the map area include Seaside, Monterey, Marina, Pacific Grove, Carmel-by-the-Sea, and Sand City. The local economy receives significant resources from tourism, as well as from the Federal Government. Tourist attractions include the Monterey Bay Aquarium, Cannery Row, Fisherman’s Wharf, and the many golf courses near Pebble Beach, and the area serves as a gateway to the spectacular scenery and outdoor activities along the Big Sur coast to the south. Federal facilities include the Army’s Defense Language Institute, the Naval Postgraduate School, and the Fleet Numerical Meteorology and Oceanography Center (operated by the Navy). In 1994, Fort Ord army base, located between Seaside and Marina, was closed; much of former army base land now makes up the Fort Ord National Monument, managed by the U.S. Bureau of Land Management as part of the National Landscape Conservation System. In addition, part of the old Fort Ord is now occupied by California State University, Monterey Bay. The offshore part of the map area lies entirely within the Monterey Bay National Marine Sanctuary, one of the nation’s largest marine sanctuaries. State beaches and parks within the map area include Fort Ord Dunes State Park and the Marina, Monterey, and Asilomar State Beaches, as well as Carmel River State Beach, which includes the Carmel River Lagoon and Wetland Natural Preserve. The map area also includes all or part of several State Marine Protected Areas, including the Carmel Pinnacles, Asilomar, and Lovers Point–Julia Platt State Marine Reserves, as well as the Carmel Bay, Pacific Grove Marine Gardens, Edward F. Ricketts, and Portuguese Ledge State Marine Conservation Areas. The coastal zone in the map area is characterized by two distinct physiographies. From Marina to Monterey, sandy beaches are backed by a belt of sand dunes, as much as 30 to 40 m high and as wide as 8 km. The Salinas River supplies the sand for the beaches and dunes. Nearshore sediment transport is primarily to the south, in the southern Monterey littoral cell. Along the Monterey peninsula, which lies at the north end of the rugged Santa Lucia Range, coastal relief is very different. The peninsula is characterized largely by low marine terraces that formed mostly on hard and relatively stable granitic bedrock. Carmel Beach in Carmel-by-the-Sea is the longest continuous beach in this area; bedrock points and small pocket beaches characterize most of the rest of the peninsula. The Carmel River littoral cell extends along the coast from Point Pinos to Point Lobos (just south of the map area), including Carmel Beach; sediment transport is primarily to the south. The granitic rocks that crop out so prominently along the Monterey peninsula make up part of the Salinian block, a crustal terrane that in this area lies west of the San Andreas Fault and east of the San Gregorio Fault. The strike-slip San Andreas Fault Zone, which lies just 26 km east of the map area, is the most important structure within the Pacific–North American transform plate boundary. The San Gregorio Fault, a secondary fault within the distributed plate boundary, cuts through (and is roughly aligned with) Carmel Canyon, a submarine canyon in the southwest corner of the map area that is part of the Monterey Canyon system. The San Gregorio Fault Zone is part of a fault system that is present predominantly in the offshore for about 400 km, from Point Conception in the south (where it is known as the Hosgri Fault) to Bolinas and Point Reyes in the north. The offshore part of the map area primarily consists of relatively flat continental shelf, bounded on the west by the steep flanks of Carmel Canyon. Shelf width varies from 2 to 3 km in the southern part of the map area, near the mouth of Carmel Canyon, to 14 km in Monterey Bay. Bedrock beneath the shelf is overlain in many areas by variable amounts (0 to 16 m) of upper Quaternary shelf and nearshore sediments deposited as sea level fluctuated in the late Pleistocene. “Soft-induration,” unconsolidated sediment is the dominant (about 63 percent) habitat type on the continental shelf, followed by “hard-induration” rock and boulders (about 34 percent) and “mixed-induration” substrate (about 3 percent). At water depths of about 100 to 130 m, the shelf break approximates the shoreline during the sea-level lowstand of the Last Glacial Maximum, about 21,000 years ago. Carmel Canyon and other parts of the Monterey Canyon system in the map area extend from the shelf break to water depths that reach 1,600 m. Most of the extensive incision of the shelf break and canyon flanks probably occurred during repeated Quaternary sea-level lowstands. The relatively straight floor of Carmel Canyon notably is aligned with the San Gregorio Fault Zone. Mixed hard-soft substrate is the most common (about 51 percent) habitat type in Carmel Canyon; hard bedrock and soft, unconsolidated sediment cover about 40 percent and 9 percent of canyon habitat, respectively. This part of the central California coast is exposed to large North Pacific swells from the northwest throughout the year. Wave heights range from 2 to 10 m, the larger swells occurring from October to May. During El Niño–Southern Oscillation (ENSO) events, winter storms track farther south than they do in normal (non-ENSO) years, thereby impacting the map area more frequently and with waves of larger heights. Benthic species observed in the map area are natives of the cold-temperate biogeographic zone that is called either the “Oregonian province” or the “northern California ecoregion.” This biogeographic province is maintained by the long-term stability of the southward-flowing California Current, the eastern limb of the North Pacific subtropical gyre that flows from southern British Columbia to Baja California. Biological productivity resulting from coastal upwelling supports populations of Sooty Shearwater, Western Gull, Common Murre, Cassin’s Auklet, and many other less populous bird species. An observable recovery of Humpback and Blue Whales has occurred in the area; both species are dependent on coastal upwelling to provide nutrients. The large extent of exposed inner shelf bedrock supports large forests of “bull kelp,” which is well adapted for high-wave-energy environments. The kelp beds are well-known habitat for the population of southern sea otters. Common fish species found in the kelp beds and rocky reefs include lingcod and various species of rockfish and greenling.

California↗

USGS2003

Development and testing of method for assessing and mapping agricultural areas susceptible to atrazine leaching in the state of Washington

In a joint effort by the Washington State Department of Agriculture, the Washington Department of Ecology, and the U.S. Geological Survey, the Environmental Protection Agency's Pesticide Root Zone Model and a Geographic Information System were used to develop and test a method for screening and mapping the susceptibility of ground water in agricultural areas to pesticide contamination. The objective was to produce a map that would be used by the Washington State Department of Agriculture to allocate resources for monitoring pesticide levels in ground water. The method was tested by producing a map showing susceptibility to leaching of the pesticide atrazine for the Columbia Basin Irrigation Project, which encompasses an area of intensive agriculture in eastern Washington. The reliability of the atrazine map was assessed by using statistical procedures to determine whether the median of the percentage of atrazine simulated to leach below the root zone in wells where atrazine was detected was statistically greater than the median percentage at wells where atrazine was not detected (at or above 0.001 microgram per liter) in 134 wells sampled by the U.S. Geological Survey. A statistical difference in medians was not found when all 134 wells were compared. However, a statistical difference was found in medians for two subsets of the 134 wells that were used in land-use studies (studies examining the quality of ground water beneath specific crops). The statistical results from wells from the land-use studies indicate that the model potentially can be used to map the relative susceptibility of agricultural areas to atrazine leaching. However, the distinction between areas of high and low susceptibility may not yet be sufficient to use the method for allocating resources to monitor water quality. Several options are offered for improving the reliability of future simulations.

Water-Resources Investigations Report↗

USGS1921

Surface waters of Kansas, 1895-1919

Kansas is preeminently an agricultural state. According to the United States census of 1910, the area in farms was 43,384,799 acres, or 67,789 square miles, 83 per cent of the total area of the state —82,158 square miles. The products of these farms rank high in value among those of farms in other states, as shown by comparative statistics compiled by the United States Department of Agriculture, Bureau of Crop Estimates. For the period from 1913 to 1917 Kansas ranked ninth of the states of the United States in the value of all crops raised, exclusive of livestock; in 1919 Kansas ranked fifth. In livestock Kansas ranked sixth in 1918 and eighth in 1919. Climatic conditions have largely dominated agricultural development in Kansas. Early ventures in dry farming in western Kansas, encouraged by a succession of rainy seasons, resulted in disheartening disasters, due to the dry seasons that followed. Throughout that region the farmers have gradually utilized the surface and underground waters for irrigation to provide against this deficiency of rainfall. The floods that have occurred in the valleys of eastern" Kansas at frequent intervals during the past twenty years have been the subject of much investigation by state and Federal organizations. In 1844 and 1903 exceptionally disastrous floods occurred in the Kansas (Kaw) valley. Floods that were of lesser magnitude, but that caused widespread loss and injury to property, have occurred in other years, the most recent being the flood of 1915. Much of the cultivated land in these valleys lies along fertile river bottoms that are annually liable to overflow, and the control of the flood waters on these rivers and their tributaries is therefore one of the problems arising from unfavorable climate that demand early solution. In view of the increasing demand for water for domestic service and fire protection, the need of determining whether the supply is adequate for rapidly growing centers of population throughout the state has recently been impressed very strongly upon a great many communities. The dependability of available sources of water supply during seasons of drought is fully as important as investigations of flood problems. Practical solutions of the many local and statewide water problems, such as flood protection, flood prevention, domestic water supply, drainage, irrigation, and water power, depend largely on a thorough knowledge of certain physical data relating to water resources. Hydrologic conditions differ widely in the different drainage basins, so that long-time investigations of stream-flow phenomena in each basin, as well as long-time investigations of meteorologic conditions over the state, are essential in the formulation of comprehensive plans to meet specific water problems. The collection of long-time records of stream-flow in Kansas which is published in this volume has been prepared for the use of those who are concerned with the different phases of the utilization of water in the state.

Kansas↗

USGS1991

Hydrology and the hypothetical effects of reducing nutrient applications on water quality in the Bald Eagle Creek Headwaters, southeastern Pennsylvania prior to implementation of agricultural best-management practices

The report characterizes a 0.43-square-mile agricultural watershed in York County, underlain by albite-chlorite and oligoclase-mica schist in the Lower Susquehanna River basin, that is being studied as part of the U.S. Environmental Protection Agency's Chesapeake Bay Program. The water quality of Bald Eagle Creek was studied from October 1985 through September 1987 prior to the implementation of Best-Management Practices to reduce nutrient and sediment discharge into Muddy Creek, a tributary to the Chesapeake Bay. About 88 percent of the watershed is cropland and pasture, and nearly 33 percent of the cropland is used for corn. The animal population is entirely dairy cattle. About 85,640 pounds of nitrogen (460 pounds per acre) and 21,800 pounds of phosphorus (117 pounds per acre) were applied to fields; 52 percent of the nitrogen and 69 percent of the phosphorus was from commercial fertilizer. Prior to fertilization, nitrate nitrogen in the soil ranged from 36 to 136 pounds per acre and phosphorus ranged from 0.89 to 5.7 pounds per acre in the top 4 feet of soil. Precipitation was about 18 percent below normal and streamflow about 35 percent below normal during the 2-year study. Eighty-four percent of the 20.44 inches of runoff was base flow. Median concentrations of total nitrogen and dissolved phosphorous in base flow were 0.05 and 0.04 milligrams per liter as phosphorus, respectively. Concentrations of dissolved nitrate in base flow increased following wet periods after crops were harvested and manure was applied. During the growing season, concentrations decreased similarly to those observed in carbonate-rock areas as nutrient uptake and evapotranspiration by corn increased. About 4,550 pounds of suspended sediment, 5,250 pounds of nitrogen, and 66.6 pounds of phosphorus discharged in base flow during the 2-year period. The suspended sediment load was about 232,000 pounds in stormflow from 26 storms that contributed 51 percent of the total stormflow. The nitrogen load was about 651 pounds and the phosphorus load was about 74 pounds in stormflow from 16 storms that contributed 28 percent of the total stormflow. It is estimated that concentrations of total nitrogen and phosphorus in base flow need to be reduced by 12 and 48 percent, respectively, to detect changes during the nutrient-management phase. Likewise, loads to total nitrogen and phosphorus in base flow need to be reduced by 62 and 57 percent.

Pennsylvania↗

USGS2009

Analytical Results for Agricultural Soils Samples from a Monitoring Program Near Deer Trail, Colorado (USA)

Since late 1993, Metro Wastewater Reclamation District of Denver (Metro District, MWRD), a large wastewater treatment plant in Denver, Colorado, has applied Grade I, Class B biosolids to about 52,000 acres of nonirrigated farmland and rangeland near Deer Trail, Colorado, USA. In cooperation with the Metro District in 1993, the U.S. Geological Survey (USGS) began monitoring groundwater at part of this site. In 1999, the USGS began a more comprehensive monitoring study of the entire site to address stakeholder concerns about the potential chemical effects of biosolids applications to water, soil, and vegetation. This more comprehensive monitoring program has recently been extended through 2010. Monitoring components of the more comprehensive study include biosolids collected at the wastewater treatment plant, soil, crops, dust, alluvial and bedrock groundwater, and stream bed sediment. Soils for this study were defined as the plow zone of the dry land agricultural fields - the top twelve inches of the soil column. This report presents analytical results for the soil samples collected at the Metro District farm land near Deer Trail, Colorado, during three separate sampling events during 1999, 2000, and 2002. Soil samples taken in 1999 were to be a representation of the original baseline of the agricultural soils prior to any biosolids application. The soil samples taken in 2000 represent the soils after one application of biosolids to the middle field at each site and those taken in 2002 represent the soils after two applications. There have been no biosolids applied to any of the four control fields. The next soil sampling is scheduled for the spring of 2010. Priority parameters for biosolids identified by the stakeholders and also regulated by Colorado when used as an agricultural soil amendment include the total concentrations of nine trace elements (arsenic, cadmium, copper, lead, mercury, molybdenum, nickel, selenium, and zinc), plutonium isotopes, and gross alpha and beta activity (Colorado Department of Public Health and Environment, Hazardous Materials and Waste Management Division, 1997; Colorado Department of Public Health and Environment,1998; U.S. Environmental Protection Agency, 1993). Since these were the identified priority parameters for the biosolids, the soils have the same set of priority parameters. Although the composite soils' priority analytes have been reported earlier to Metro District, the remaining elemental datasets for both the composite soils samples and selected fields' individual subsamples' data are presented here for the first time. More information about the other monitoring components is presented elsewhere in the literature (http://co.water.usgs.gov/projects/CO406/CO406.html). In general, the objective of each component of the study was to determine whether concentrations of priority parameters (1) were higher than regulatory limits, (2) were increasing with time, and(or) (3) were significantly higher in biosolids-applied areas than in a similar farmed area where biosolids were not applied. The method chosen for sampling the soils proved to be an efficient and reliable representation of the average composition of each field. This was shown by analyzing individual subsamples, averaging the resulting values, and then comparing the values to the composited samples' values. The soil chemistry shows distinct differences between the two sites, most likely due to the different underlying parent material. Biosolids data were used to compile an inorganic-chemical biosolids signature that can be contrasted with the geochemical signature of the agricultural soils for this site. The biosolids signature and an understanding of the geology and hydrology of the site can be used to separate biosolids effects from natural geochemical effects. Elements of particular interest for a biosolids signature after application in the soils include bismuth, copper, silver, mercury, and phosphorus. This signat

Open-File Report↗

USGS1993

Water resources of Big Horn County, Wyoming

Groundwater in unconsolidated aquifers is the most reliable and accessible source of potable water in Big Horn County, Wyoming. Well yields generally ranged from 25 to 200 gal/min; however, yields of 1600 gal/min are reported from wells in the gravel, pediment, and fan deposits. Bedrock aquifers that yield the most abundant water supplies are the Tensleep Sandstone, Madison Limestone, Bighorn Dolomite, and Flathead Sandstone. The aquifers with the most potential for development as a water supply, predominately composed of sandstone, are the Lance, Mesaverde, and Frontier Formations. The Madison Limestone, the Darby Formation, and the Bighorn Dolomite form the Madison Bighorn aquifer. Reported yields from the aquifer ranged from 40 to 14,000 gal/min. Flowing wells from the Madison-Bighorn aquifer had shut-in pressures ranging from 41 to 212 pounds per square inch (95 to 490 feet above land surface). Shut-in pressures from flowing wells in bedrock indicate declines, from the time the wells were completed to 1988, as much as 390 feet. Flows have also decreased over time. Water samples from wells completed in unconsolidated aquifers have concentrations of dissolved solids less than 2,000 mg/L (milligrams per liter). Water from unconsolidated aquifers are classified as a calcium sulfate type, a sodium sulfate type, and sodium-calcium sulfate type. Water samples from wells completed in aquifers in Paleozoic and Precambrian rocks had median concentrations of dissolved solids ranging from 111 to 275 mg/L. Water samples from wells in Tertiary and Cretaceous rocks had a median concentration of dissolved solids ranging from 1,107 to 3,320 mg/L. Water types for these aquifers were usually sodium sulfate. Perennial streams originate in the mountains and ephemeral streams originate in the Bighorn Basin. Irrigation return-flow to streams maintains perennial flow in what would otherwise be ephemeral streams. Streams that originate in the Bighorn Basin have specific conductance values generally greater than 1,000 mg/L, whereas streams that originate in the Bighorn Mountains have specific conductance values generally less than 1,000 mg/L. The predominant dissolved constituents are calcium or sodium and bicarbonate or sulfate. Concentrations of pesticides detected in surface-water samples were less than the U.S. Environmental Protection Agency (USHPA) maximum contaminant levels. The detected concentrations of pesticides in streambed material in the organochlorine insecticide class ranged from 0.1 to 8.0 micrograms per kilogram. Pesticides detected in ground-water samples included dicamba and picloram at a concentration of 0.40 jig/L (micrograms per liter), atrazines (0.40 jig/L), aldicarb sulfone (1.44 |ig/L), aldicarb sulfoxide (0.52 |ig/L), and malathion (0.02 jig/L). Analyses of ground-water samples for radionuclides indicate that concentrations from four municipal wells exceeded the maximum contaminant level established by the USEPA. Of these four wells, concentrations in water samples from the municipal well at Frannie consistently exceeded the USEPA maximum contaminant level for dissolved gross alpha activity of 15 pCi/L (picocuries per liter) and radium-226 plus radium-228 (5 pCi/L). The source of the radioactivity is postulated to be the Madison Limestone. Surface water accounts for 96 percent and ground water accounts for 4 percent of total offstream water use in Big Horn County, Wyoming. Irrigation is the largest offstream use of both surface and ground water. About 99 percent of offstream surface water and 55 percent of ground water is used for irrigation. Eighty-two percent of the water used for irrigation is consumed, which includes a 37-percent conveyance loss and 45 percent consumed by the irrigated crops. Ground water supplies 89 percent of water used for domestic purposes and about 16 percent of water used for public supplies, which shows that ground water is a primary domestic water supply in rural areas where public supplies are not available.

Wyoming↗

USGS2000

Ground-water quality and vulnerability to contamination in selected agricultural areas of southeastern Michigan, northwestern Ohio, and northeastern Indiana

Ground-water quality was assessed in the northeastern part of the Corn Belt, where tile-drained row crops are underlain by fractured glacial till. Data were collected from 30 shallow monitor wells and 18 co-located domestic wells as part of the U.S. Geological Survey’s National Water- Quality Assessment in the Lake Erie-Lake St. Clair Basin. Pesticides or pesticide degradates were detected in 41 percent of the monitor wells and 6 percent of the domestic wells. The pesticides detected closely correspond to those most heavily applied—herbicides used on corn and soybeans. Pesticide degradates were detected three times more frequently, and at higher concentrations, than were parent compounds. No pesticide concentration exceeded a USEPA Maximum Contaminant Level (MCL), but MCL’s have not been established for 9 of the 11 compounds detected. Thirty-seven percent of monitor-well samples had nitrate concentrations indicative of human influences such as fertilizer, manure or septic systems. Nitrate was the only chemical constituent detected at a concentration greater than an MCL. The MCL was exceeded in 7 percent of samples from monitor wells which were too shallow to be used as a source of drinking water. Pesticide and nitrate concentrations in the study area are low relative to other agricultural areas of the Nation. Several authors have suggested that ground water in parts of the Upper Midwest is minimally contaminated because it is protected by the surficial glacial till or tile drains. These ideas are examined in light of the relations between concentration, well depth, and groundwater age in the study area. Most of the shallow ground water is hydraulically connected to the land surface, based on the observations that 83 percent of waters from monitor wells were recharged after 1953, and 57 percent contained a pesticide or an elevated nitrate concentration. Fractures or sand-and-gravel stringers within the till are the probable pathways. In some areas, deeper parts of the groundwater- flow system are also hydraulically connected to the land surface. Almost half the waters from wells 50 to 100 feet deep were recharged after 1953. Anthropogenic constituents were detected in samples from three domestic wells 60 to 121 feet deep, in areas where the till is relatively coarse-grained. The hydrogeologic system has several geochemical characteristics conducive to transformations or sorption of nitrate or pesticides: (1) the till is clay-rich, has a high organic-carbon content, and contains an abundance of pyrite-rich shale fragments, (2) the ground water has low dissolved- oxygen concentrations, and (3) iron and manganese oxides and oxyhyroxides line the faces of fractures in the unsaturated zone. Although the aquifer system appears be protected from contamination in some areas, the fact that the surficial till is heterogeneous and of variable thickness suggests that the protection is not uniform. The protection can be breached by fractures or sand-and-gravel stringers, which are apparent in core samples but not noted on domestic-well logs.

Indiana, Michigan, Ohio↗

USGS2022

Both real-time and long-term environmental data perform well in predicting shorebird distributions in managed habitat

Highly mobile species, such as migratory birds, respond to seasonal and inter-annual variability in resource availability by moving to better habitats. Despite the recognized importance of resource thresholds, species distribution models typically rely on long-term average habitat conditions, mostly because large-extent, temporally-resolved, environmental data are difficult to obtain. Recent advances in remote sensing make it possible to incorporate more frequent measurements of changing landscapes; however, there is often a cost in terms of model building and processing and the added value of such efforts is unknown. Our study tests whether incorporating real-time environmental data increases the predictive ability of distribution models, relative to using long-term average data. We developed and compared distribution models for shorebirds in California's Central Valley based on high temporal resolution (every 16-days), and 17-year long-term average, surface water data. Using abundance-weighted boosted regression trees, we modeled monthly shorebird occurrence as a function of surface water availability, crop type, wetland type, road density, temperature, and bird data source. While modeling with both real-time and long-term average data provided good fit to withheld validation data (0.79 < AUC < 0.89 across taxa), there were small differences in model performance. The best models incorporated long-term average conditions and spatial pattern information for real-time flooding (e.g. perimeter-area ratio of real-time water bodies). There was not a substantial difference in the performance of real-time and long-term average data models within time periods when real-time surface water differed substantially from the long-term average (specifically during drought years 2013-2016) and in intermittently flooded months or locations. Spatial predictions resulting from the models differed most in the southern region of the study area where there is lower water availability, fewer birds, and lower sampling density. Prediction uncertainty in the southern region of the study area highlights the need for increased sampling in this area. Because both sets of data performed similarly, the choice of which data to use may depend on the management context. Real-time data may ultimately be best for guiding dynamic, adaptive conservation actions whereas models based on long-term averages may be more helpful for guiding permanent wetland protection and restoration.

Ecological Applications↗

USGS1995

Pesticides in near-surface aquifers: An assessment using highly sensitive analytical methods and tritium

In 1992, the U.S. Geological Survey (USGS) determined the distribution of pesticides in near-surface aquifers of the midwestern USA to be much more widespread than originally determined during a 1991 USGS study. The frequency of pesticide detection increased from 28.4% during the 1991 study to 59.0% during the 1992 study. This increase in pesticide detection was primarily the result of a more sensitive analytical method that used reporting limits as much as 20 times lower than previously available and a threefold increase in the number of pesticide metabolites analyzed. No pesticide concentrations exceeded the U.S. Environmental Protection Agency's (USEPAs) maximum contaminant levels or health advisory levels for drinking water. However, five of the six most frequently detected compounds during 1992 were pesticide metabolites that currently do not have drinking water standards determined. The frequent presence of pesticide metabolites for this study documents the importance of obtaining information on these compounds to understand the fate and transport of pesticides in the hydrologic system. It appears that the 56 parent compounds analyzed follow similar pathways through the hydrologic system as atrazine. When atrazine was detected by routine or sensitive analytical methods, there was an increased likelihood of detecting additional parent compounds. As expected, the frequency of pesticide detection was highly dependent on the analytical reporting limit. The number of atrazine detections more than doubled as the reporting limit decreased from 0.10 to 0.01 µg/L. The 1992 data provided no indication that the frequency of pesticide detection would level off as improved analytical methods provide concentrations below 0.003 µg/L. A relation was determined between groundwater age and the frequency of pesticide detection, with 15.8% of the samples composed of pre-1953 water and 70.3% of the samples of post-1953 water having a detection of at least one pesticide or metabolite. Pre-1953 water is less likely to contain pesticides because it tends to predate the use of pesticides to increase crop production in the Midwest. Pre-1953 water was more likely to occur in the near-surface bedrock aquifers (50.0%) than in the near-surface unconsolidated aquifers (9.1%) sampled.

Journal of Environmental Quality↗

USGS2024

Results of 2018–19 water-quality and hydraulic characterization of aquifer intervals using packer tests and preliminary geophysical-log correlations for selected boreholes at and near the former Naval Air Warfare Center Warminster, Bucks County, Pennsylvania

The U.S. Geological Survey (USGS) collected data on the vertical distribution of hydraulic head, specific capacity, and water quality using aquifer-interval-isolation tests and other vertical profiling methods in 15 boreholes completed in fractured sedimentary bedrock in Northampton, Warminster, and Warwick Townships, Bucks County, Pennsylvania during 2018–19. This work was done, in cooperation with the U.S. Navy, to support detailed investigations at and near the former Naval Air Warfare Center (NAWC) Warminster, where groundwater contamination with per- and polyfluoroalkyl substances (PFAS) had become a concern since 2014. Two PFAS compounds, perfluorooctanesulfonic acid (PFOS) and perfluorooctanoic acid (PFOA), have been measured in groundwater samples from supply and monitoring wells at or near NAWC Warminster in concentrations above U.S. Environmental Protection Agency health advisory levels for drinking water. The area is underlain by the Triassic Stockton Formation, which predominantly consists of sandstone interbedded with shale and siltstone beds and forms a layered fractured-rock aquifer used for private, industrial, and public drinking water supply. The vertical distribution of aquifer properties and water quality was assessed through hydraulic tests and sampling of aquifer intervals using a straddle-packer system (13 boreholes) or depth-discrete point sampling under known borehole-flow conditions (2 boreholes). Geophysical and video logs collected by USGS during 2017–19 were used to identify potential water-bearing fractures in 15 boreholes, which ranged in depth from 210 to 604 feet (ft) and included 6 boreholes drilled in 2018 and 9 existing wells on or near the former NAWC Warminster. Measured borehole flow was predominantly downward in most of the deepest boreholes (greater than 400 ft), which were commonly located at the highest land-surface elevations, with inflow from fractures at relatively shallow depths and outflow through fractures near or below depths of 500 ft below land surface. Hydraulic head differences measured during packer tests were up to about 60 ft between shallow and deep intervals. Borehole flow was predominantly upward in most boreholes less than 400 ft in depth and farther from, and at lower land-surface elevations than, the former NAWC Warminster. Total borehole specific capacity ranged from about 0.07 to 41 gallons per minute per foot [(gal/min)/ft]. Specific-capacity values for individual intervals ranged from 0.02 to 40.0 (gal/min)/ft, with a median of 1.14 (gal/min)/ft and a large range in values at most depths. Differences in water quality of samples as indicated by field properties (pH, dissolved oxygen, and specific conductance) and concentrations of dissolved major ions, PFOA, and PFOS were apparent among isolated intervals in the boreholes. Summed concentrations of PFOA and PFOS ranged from about 11 to 10,780 nanograms per liter (ng/L) and were greater than the 2016 U.S. Environmental Protection Agency health advisory of 70 ng/L for summed PFOA and PFOS concentrations in 62 of 104 intervals and discrete depths tested. The mass ratio of PFOS to PFOA was generally higher than 1.0 in samples with summed PFOA and PFOS concentrations greater than 70 ng/L, with ratio values as high as 8.7. In many boreholes, summed concentrations of PFOA and PFOS were positively related to chloride concentrations, which were elevated above natural-background values [less than 10 milligrams per liter] in most samples and as high as 717 milligrams per liter. Sources of the elevated chloride other than, or in addition to, common rock salt (sodium chloride) were indicated by chloride to sodium molar ratios greater than 1.0. Water-quality data indicated that sampled water from some intervals with lower hydraulic heads may be affected by water from intervals with higher hydraulic heads because of vertical flow in open boreholes; samples from these intervals with lower hydraulic heads may not be fully representative due to some component of cross contamination and should be interpreted with caution. Through a preliminary correlation of natural gamma and resistivity logs of boreholes drilled at and near the former NAWC Warminster, 11 lithologic units were identified and interpreted to strike northeast and dip to the northwest. Hydraulic heads were generally highest in isolated intervals that intercepted beds which, when projected up dip, crop out at the highest land-surface elevation on the former NAWC Warminster, indicating that the dipping-bed structure and topography are factors affecting the distribution of hydraulic head in the aquifer. The hydrogeologic framework in conjunction with the vertical distribution of hydraulic heads and water quality may assist in evaluating the locations of various PFAS sources and potential migration pathways of PFAS in groundwater at and near NAWC Warminster.

Pennsylvania↗

USGS2004

Effects of surface applications of biosolids on soil, crops, ground water, and streambed sediment near Deer Trail, Colorado, 1999-2003

The U.S. Geological Survey, in cooperation with Metro Wastewater Reclamation District and North Kiowa Bijou Groundwater Management District, studied natural geochemical effects and the effects of biosolids applications to the Metro Wastewater Reclamation District properties near Deer Trail, Colorado, during 1999 through 2003 because of public concern about potential contamination of soil, crops, ground water, and surface water from biosolids applications. Parameters analyzed for each monitoring component included arsenic, cadmium, copper, lead, mercury, molybdenum, nickel, selenium, and zinc (the nine trace elements regulated by Colorado for biosolids), gross alpha and gross beta radioactivity, and plutonium, as well as other parameters. Concentrations of the nine regulated trace elements in biosolids were relatively uniform and did not exceed applicable regulatory standards. All plutonium concentrations in biosolids were below the minimum detectable level and were near zero. The most soluble elements in biosolids were arsenic, molybdenum, nickel, phosphorus, and selenium. Elevated concentrations of bismuth, mercury, phosphorus, and silver would be the most likely inorganic biosolids signature to indicate that soil or streambed sediment has been affected by biosolids. Molybdenum and tungsten, and to a lesser degree antimony, cadmium, cobalt, copper, mercury, nickel, phosphorus, and selenium, would be the most likely inorganic 'biosolids signature' to indicate ground water or surface water has been affected by biosolids. Soil data indicate that biosolids have had no measurable effect on the concentration of the constituents monitored. Arsenic concentrations in soil of both Arapahoe and Elbert County monitoring sites (like soil from all parts of Colorado) exceed the Colorado soil remediation objectives and soil cleanup standards, which were determined by back-calculating a soil concentration equivalent to a one-in-a-million cumulative cancer risk. Lead concentrations in soil slightly exceed the U.S. Environmental Protection Agency toxicity-derived ecological soil-screening levels for avian wildlife. Plutonium concentration in the soil was near zero. Wheat-grain data were insufficient to determine any measurable effects from biosolids. Comparison with similar data from other parts of North America where biosolids were not applied indicates similar concentrations. However, the Deer Trail study area had higher nickel concentrations in wheat from both the biosolids-applied fields and the control fields. Plutonium content of the wheat was near zero. Ground-water levels generally declined at most wells during 1999 through 2003. Ground-water quality did not correlate with ground-water levels. Vertical ground-water gradients during 1999 through 2003 indicate that bedrock ground-water resources downgradient from the biosolids-applied areas are not likely to be contaminated by biosolids applications unless the gradients change as a result of pumping. Ground-water quality throughout the study area varied over time at each site and from site to site at the same time, but plutonium concentrations in the ground water always were near zero. Inorganic concentrations at well D6 were relatively high compared to other ground-water sites studied. Ground-water pH and concentrations of fluoride, nitrite, aluminum, arsenic, barium, chromium, cobalt, copper, lead, mercury, nickel, silver, zinc, and plutonium in the ground water of the study area met Colorado standards. Concentrations of chloride, sulfate, nitrate, boron, iron, manganese, and selenium exceeded Colorado ground-water standards at one or more wells. Nitrate concentrations at well D6 significantly (alpha = 0.05) exceeded the Colorado regulatory standard. Concentrations of arsenic, cadmium, chromium, lead, mercury, nickel, and zinc in ground water had no significant (alpha = 0.05) upward trends. During 1999-2003, concentrations of nitrate, copper, molybdenum, and selenium

Scientific Investigations Report↗

USGS1997

Nitrate and selected pesticides in ground water of the Mid-Atlantic region

Data from more than 850 sites were compiled and analyzed to document the occurrence of nitrate and pesticides in ground water of the Mid-Atlantic region as part of the Mid-Atlantic Integrated Assessment program of the U.S. Environmental Protection Agency. Only those data collected by the U.S. Geological Survey as part of regional networks between October 1985 and September 1996 (inclusive) were used in the analyses, and the data were examined to ensure analytical results are not biased toward sites at the same location or sites sampled multiple times during this period. Regional data are available for most of the Mid-Atlantic region but large spatial gaps in available data do exist. Nitrate was detected in nearly three-quarters of the samples for which it was analyzed, commonly at levels that suggest anthropogenic sources. Ten percent of samples contained nitrate at concentrations exceeding the Federal Maximum Contaminant Level (MCL) of 10 milligrams per liter as nitrogen. Pesticide compounds (including atrazine, metolachlor, prometon, simazine, and desethylatrazine, an atrazine degradate) were detected in about half of the samples for which they were analyzed, but rarely at concentrations exceeding established MCL?s. The most commonly detected pesticide compounds were desethylatrazine and atrazine. The occurrence of nitrate and pesticides in ground water of the Mid-Atlantic region is related to land cover and rock type. Likely sources of nitrate and pesticides to ground water include agricultural and urban land-use practices; rock type affects the movement of these compounds into and through the ground-water system. Nitrate concentrations in the compiled data set are significantly higher in ground water in agricultural areas than in urban or forested areas, but concentrations in areas of row crops are statistically indistinguishable from those in areas of pastures. Detection frequencies of atrazine, desethylatrazine, and simazine are indistinguishable among urban areas, row crops, and pastures. Prometon was most commonly detected in ground water in urban areas. Ground-water samples from forested areas typically contained the lowest concentrations of nitrate and detection frequencies of pesticides. Concentrations of nitrate and detection frequencies of pesticides were significantly higher in samples from carbonate rocks than in those from any other rock type. Most areas of the Mid-Atlantic region that are underlain by carbonate rocks have been developed for agricultural or urban use and the solution channels that are typical of carbonate rocks allow for relatively rapid transport of surficial contaminants throughout the ground-water system. Nitrate concentrations in unconsolidated aquifers were among the lowest for all rock types, possibly because of denitrification in organic-rich subsoils and shallow sediments.

Water-Resources Investigations Report↗

USGS2001

Occurrence, distribution, and transport of nutrients in Eastern Iowa Rivers

Eleven streams in the Wapsipinicon, Cedar, Iowa, and Skunk River basins in eastern Iowa were sampled monthly from March 1996 through September 1998 to assess the occurrence, distribution, and transport of nitrogen, phosphorus, and suspended sediment as part of the U.S. Geological Survey's National Water-Quality Assessment Program. At least one form of dissolved nitrogen and phosphorus was detected in every sample collected. Nitrate accounted for 92 percent of the dissolved nitrogen. About 22 percent of the samples contained nitrate that exceeded the U.S. Environmental Protection Agency's Maximum Contaminant Level of 10 milligrams per liter (mg/L) as nitrogen in drinking water. The median concentration of total nitrogen for surface water in the study area was 7.2 mg/L. Dissolved phosphorus was predominately in the form of orthophosphate. The median total phosphorus concentration for the study area was 0.22 mg/L. About 75 percent of the total phosphorus concentrations exceeded the U.S. Environmental Protection Agency recommended total phosphorus concentration of 0.10 mg/L or less to minimize algal growth in streams not discharging directly into lakes or impoundments. Median suspended-sediment concentration for the study area was 82 mg/L. Nitrogen, phosphorus, and suspended-sediment concentrations varied annually and seasonally. Nitrogen, phosphorus, and suspended-sediment concentrations increased each year of the study due to increased precipitation and runoff. Concentrations were typically higher in the spring after fertilizer application and runoff. In winter, nitrogen concentrations typically increased when there was little instream assimilation by aquatic plants and algae. Nitrogen and phosphorus concentrations decreased in late summer when there was less runoff and instream assimilation of nitrogen and phosphorus by aquatic plants and algae was high. Suspended-sediment concentrations were highest in early summer during runoff and lowest in January when there was ice cover with very little overland flow contributing to rivers and streams. Streams draining small- to medium-sized watersheds that have uniform land use and geology had significantly (p < 0.05) higher total dissolved-nitrogen concentrations (median, 8.2 mg/L) than did samples from large rivers (median, 6.2 mg/L) that drain basins with mixed land use and geology. Samples from large rivers typically had significantly (p< 0.05) higher total phosphorus and suspended-sediment concentrations than did samples from small rivers and streams. Concentrations varied between drainage basins due to land use and physiography. Basins that are located in areas with a higher percentage of row-crop agriculture typically had samples with higher nitrogen concentrations than did basins with less row-crop agriculture. In addition, basins that drain the Southern Iowa Drift Plain and the Des Moines Lobe typically had samples with higher total phosphorus and suspended-sediment concentrations than did basins that drain other landform regions. Total nitrogen and total phosphorus loads were typically proportional to the size of the drainage basin. Total nitrogen loads increased each year from 1996 through 1998 in conjunction with increased concentrations and runoff. However, total phosphorus loads in the Skunk River Basin decreased in 1997 due to less runoff. Total phosphorus loads followed the same pattern as total nitrogen loads with increases in 1998. Total nitrogen and total phosphorus loads varied seasonally and the highest loads typically occurred in early spring and summer after fertilizer application and runoff. Loads were lowest in January and September when there was little runoff to transport nitrogen and phosphorus to the rivers and streams. Total nitrogen loads contributed to the Mississippi River from the Eastern Iowa Basins during 1996, 1997, and 1998 were 97,000, 120,000, and 230,000 metric tons respectively. Total phosphorus loads contributed to the Mississippi River from the Eastern Iowa Basins during 1996, 1997, and 1998 were 6,900, 4,600, and 8,800 metric tons, respectively. The highest nitrogen and phosphorus yields typically occurred in streams draining small watersheds that were dominated by a single land use and geology. Sampling sites located in drainage basins with higher row-crop percentage typically had higher nitrogen and phosphorus yields. Sites that were located in the Des Moines Lobe and the Southern Iowa Drift Plain typically had higher phosphorus yields probably due to more erodible soils and steeper slopes.

Iowa↗

USGS1997

Water-quality assessment of the Rio Grande Valley, Colorado, New Mexico, and Texas -- Shallow ground-water quality and land use in the Albuquerque area, central New Mexico, 1993

This report describes the quality of shallow ground water and the relations between land use and the quality of that shallow ground water in an urban area in and adjacent to Albuquerque, New Mexico. Water samples were collected from 24 shallow wells. Samples were analyzed for selected common constituents, nutrients, trace elements, radionuclides, volatile organic compounds, and pesticides. The study area, which is in the Albuquerque Basin in central New Mexico, was limited to the Rio Grande flood plain; depth to water in this area generally is less than 25 feet. The amount and composition of recharge to the shallow ground-water system are important factors that affect shallow ground-water composition in this area. Important sources of recharge that affect shallow ground-water quality in the area include infiltration of surface water, which is used in agricultural land-use areas to irrigate crops, and infiltration of septic-system effluent in residential areas. Agricultural land use represents about 28 percent of the area, and residential land use represents about 35 percent of the total study area. In most of the study area, agricultural land use is interspersed with residential land use and neither is the dominant land use in the area. Land use in the study area historically has been changing from agricultural to urban. The composition of shallow ground water in the study area varies considerably. The dissolved solids concentration in shallow ground water in the study area ranges from 272 to 1,650 milligrams per liter, although the relative percentages of selected cations and anions do not vary substantially. Calcium generally is the dominant cation and bicarbonate generally is the dominant anion. Concentrations of nutrients generally were less than 1 milligram per liter. The concentration of many trace elements in shallow ground water was below or slightly above 1 microgram per liter and there was little variation in the concentrations. Barium, iron, manganese, molybdenum, and uranium were the only trace elements analyzed for that had median concentrations greater than 5 micrograms per liter. Volatile organic compounds were detected in 5 of 24 samples. Cis-1,2-dichloroethene and 1,1-dichloroethane were the most commonly detected volatile organic compounds (detected in two samples each). Pesticides were detected in 8 of 24 samples. Prometon was the most commonly detected pesticide (detected in 5 of 24 samples). Concentrations of volatile organic compounds and pesticides detected were much smaller than any U.S. Environmental Protection Agency standards that have been established. Infiltration of surface water and the evaporation or transpiration of this water, which partially is the result of past and present agricultural land use, seem to affect the concentrations of common constituents in shallow ground water in the study area. The small excess chloride in shallow ground water relative to surface water that has been affected by evaporation or transpiration could be due to mixing of shallow ground water with small amounts of precipitation/bulk deposition or septic-system effluent. Infiltration of septic-system effluent (residential land use) has affected the shallow ground-water composition in parts of the study area on the basis of the small dissolved oxygen concentrations, large dissolved organic carbon concentrations, and excess chloride. Despite the loading of nitrogen to the shallow ground-water system as the result of infiltration of septic-system effluent, the small nitrogen concentrations in shallow ground water probably are due to the small dissolved oxygen concentrations and relatively large dissolved organic carbon concentrations. The small concentrations and lack of variation of most trace elements indicate that land use has not substantially affected the concentration

New Mexico↗

USGS2004

Herbicides and their transformation products in source-water aquifers tapped by public-supply wells in Illinois, 2001-02

During 2001-02, ground-water samples were collected from 117 public-supply wells distributed throughout Illinois to evaluate the occurrence of herbicides and their transformation products in the State?s source-water aquifers. Wells were selected using a stratified-random method to ensure representation of the major types of source-water aquifers in the State. Samples were analyzed for 18 herbicides and 18 transformation products, including 3 triazine and 14 chloroacetanilide products. Herbicide compounds (field-applied parent herbicides and their transformation products) were detected in 34 percent of samples. A subset of samples was collected unfiltered to determine if analytical results for herbicides in unfiltered samples are similar to those in paired filtered samples and, thus, can be considered equally representative of herbicide concentrations in ground water supplied to the public. The study by the U.S. Geological Survey was done in cooperation with the Illinois Environmental Protection Agency. Parent herbicides were detected in only 4 percent of all samples. The six most frequently detected herbicide compounds (from 5 to 28 percent of samples) were chloroacetanilide transformation products. The frequent occurrence of transformation products and their higher concentrations relative to those of most parent herbicides confirm the importance of obtaining information on transformation products to understand the mobility and fate of herbicides in ground-water systems. No sample concentrations determined during this study exceeded current (2003) Federal or State drinking-water standards; however, standards are established for only seven parent herbicides. Factors related to the occurrence of herbicide compounds in the State?s source-water aquifers include unconsolidated and unconfined conditions, various hydrogeologic characteristics and well-construction aspects at shallow depths, and proximity to streams. Generally, the closer an aquifer (or well location) is to a recharge area and (or) the stronger the hydraulic connection between an aquifer and a recharge area, the younger the ground water and the more vulnerable the aquifer will be to contamination by herbicide compounds. The weak relation between current (2001) statewide application rates of herbicides and current (2001-02) occurrence of herbicide compounds in source-water aquifers indicates that additional factors must be considered when relating herbicide-application rates to occurrence. These factors include historical application rates and the mobility and persistence of the various herbicide compounds in ground-water systems. Frequency of detection and concentrations of herbicides compounds in the State?s source-water aquifers are indicated to be highest during the spring, when crops are planted and herbicides primarily are applied. Excess nitrate (concentrations of nitrate, as nitrogen, higher than 3 milligrams per liter) in ground water strongly indicates the co-occurrence of herbicide compounds. However, nitrate concentrations are not a reliable indicator of herbicide-compound concentrations. The inverse relation found between current use of land for corn and soybean production and current occurrence of herbicide compounds in underlying aquifers indicates that various factors, along with current agricultural land use, contribute to herbicide occurrence. These factors include, among others, land-use history, ground-water age, ground-water-flow patterns, geology, soil microbiology, and chemistry and persistence of the herbicide compounds. Detection of agriculture-specific herbicide compounds in 71 percent of samples from urban areas with no current or recent agricultural land use near the sampled wells indicates that recharge to certain high-capacity supply wells may originate at considerable distances (up to about 10 miles) from the wells. Essentially no difference was found between the analytical results for herbicides in paired unfiltered and filtered samples,

Water-Resources Investigations Report↗

USGS2008

Regional nitrate and pesticide trends in ground water in the eastern San Joaquin Valley, California

Protection of ground water for present and future use requires monitoring and understanding of the mechanisms controlling long-term quality of ground water. In this study, spatial and temporal trends in concentrations of nitrate and pesticides in ground water in the eastern San Joaquin Valley, California, were evaluated to determine the long-term effects of agricultural and urban development on regional ground-water quality. Trends in concentrations of nitrate, the nematocide 1,2-dibromo-3-chloropropane, and the herbicide simazine during the last two decades are generally consistent with known nitrogen fertilizer and pesticide use and with the position of the well networks in the regional ground-water flow system. Concentrations of nitrate and pesticides are higher in the shallow part of the aquifer system where domestic wells are typically screened, whereas concentrations are lower in the deep part of the aquifer system where public-supply wells are typically screened. Attenuation processes do not seem to significantly affect concentrations. Historical data indicate that concentrations of nitrate have increased since the 1950s in the shallow and deep parts of the aquifer system. Concentrations of nitrate and detection of pesticides in the deep part of the aquifer system will likely increase as the proportion of highly affected water contributed to these wells increases with time. Because of the time of travel between the water table and the deep part of the aquifer system, current concentrations in public-supply wells likely reflect the effects of 40- to 50-yr-old management practices. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Conference Paper↗