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Characterizing Hydraulic Properties and Ground-Water Chemistry in Fractured-Rock Aquifers: A User's Manual for the Multifunction Bedrock-Aquifer Transportable Testing Tool (BAT3)

A borehole testing apparatus has been designed to isolate discrete intervals of a bedrock borehole and conduct hydraulic tests or collect water samples for geochemical analyses. This borehole testing apparatus, referred to as the Multifunction Bedrock-Aquifer Transportable Testing Tool (BAT3), includes two borehole packers, which when inflated can form a pressure-tight seal against smooth borehole walls; a pump apparatus to withdraw water from between the two packers; a fluid-injection apparatus to inject water between the two packers; pressure transducers to monitor fluid pressure between the two packers, as well as above and below the packers; flowmeters to monitor rates of fluid withdrawal or fluid injection; and data-acquisition equipment to record and store digital records from the pressure transducers and flowmeters. The generic design of this apparatus was originally discussed in United States Patent Number 6,761,062 (Shapiro, 2004). The prototype of the apparatus discussed in this report is designed for boreholes that are approximately 6 inches in diameter and can be used to depths of approximately 300 feet below land surface. The apparatus is designed to fit in five hard plastic boxes that can be shipped by overnight freight car-riers. The equipment can be assembled rapidly once it is removed from the shipping boxes, and the length of the test interval (the distance between the two packers) can be adjusted to account for different borehole conditions without reconfiguring the downhole components. The downhole components of the Multifunction BAT3 can be lowered in a borehole using steel pipe or a cable; a truck mounted winch or a winch and tripod can be used for this purpose. The equipment used to raise and lower the downhole components of the Multifunction BAT3 must be supplied on site, along with electrical power, a compressor or cylinders of compressed gas to inflate the packers and operate downhole valves, and the proper length of tubing to connect the packers, the submersible pump, and other downhole components to land surface. Borehole geophysical logging must be conducted prior to deploying the Multifunction BAT3 in bedrock boreholes. In particular, it is important to identify the borehole diameter as a function of depth to avoid placing the packers over rough sections of the borehole, where they may be damaged during inflation. In addition, it is advantageous to identify the location of fractures intersecting the borehole wall, for example, using an acoustic televiewer log or a borehole camera. A knowledge of fracture locations is helpful in designing the length of the test interval and the locations where hydraulic tests and geochemical sampling are to be conducted. The Multifunction BAT3 is configured to conduct both fluid-injection and fluid-withdrawal tests. Fluid-injection tests are used to estimate the hydraulic properties of low-permeability fractures intersecting the borehole. The lower limit of the transmissivity that can be estimated using the configuration of the Multifunction BAT3 described in this report is approximately 10-3 square feet per day (ft2/d). Fluid-withdrawal tests are used to collect water samples for geochemical analyses and estimate the hydraulic properties of high-permeability fractures intersecting the borehole. The Multifunction BAT3 is configured with a submersible pump that can support pumping rates ranging from approximately 0.05 to 2.5 gallons per minute, and the upper limit of the of the transmissivity that can be estimated is approximately 104 ft2/d. The Multifunction BAT3 also can be used to measure the ambient hydraulic head of a section of a bedrock borehole, and to conduct single-hole tracer tests by injecting and later withdrawing a tracer solution.

Open-File Report

Water chemistry of the Redwood Creek and Mill Creek basins, Redwood National Park, Humboldt and Del Norte Counties, California

A 2-year study was made in the Redwood Creek and Mill Creek drainage basins of Redwood National Park to determine existing chemical water-quality conditions and to identify the effects of logging on water quality in the main stems and tributaries of the two basins. Overall, the chemical water quality of the main stems and the tributaries is excellent, suitable for most beneficial uses. Dissolved-solids concentrations range from 25 milligrams per liter in the Redwood Creek basin and 21 milligrams per liter in the Mill Creek basin during the rainy season to 139 and 49 during the dry season. Water shifts from a mixed calcium-sodium bicarbonate-chloride type toward a calcium bicarbonate type from the end of the wet season to the end of the dry season. It shifts back toward a mixed calcium-sodium bicarbonate-chloride type from the end of the dry season to the end of the wet season. The pH shifts with the water type from a median value of 6.80 in the rainy season to 7.37 in the dry season. Nitrogen and phosphorus concentrations are generally too low to support nuisance algae but are high enough, in some streams, to support modest populations, particularly in the main stem where light levels are high. Trace-metal concentrations are low, typical of clean streams. Evidence suggests that dissolved calcium and bicarbonate in stream water is produced by weathering of the Franciscan assemblage underlying the basins but that chlorides are transported inland from the ocean as dry fallout and spray and in rain. Exposure of the surface soils to the elements, either by logging or by natural causes such as sparse vegetation, seems to accelerate weathering, which leads to a calcium bicarbonate water type. Logging accelerates weathering most in the tributary watersheds with regoliths derived from sandstone and least in those with regoliths derived from schist; however, the data suggest that the rate of weathering in a schistose watershed can increase dramatically if soil disruption is extensive. Studies during storms indicated that specific conductance and alkalinity were two to three times as likely to decrease at the discharge peak in logged watersheds as in forested ones. This suggests that overland flow containing lower concentrations of soil-derived dissolved solids than flow from other sources is a larger component of peak flow in logged watersheds than in forested watersheds. Comparing a storm in November 1974 to one in February 1975, nitrate concentration increased significantly from November to February in a stream draining a logged watershed and decreased significantly in a stream draining a forested watershed. Then from the rainy season to the dry season, nitrate decreased in both logged and forested watersheds. This pattern suggests that soil nitrate produced by fixation and organic decomposition early in the rainy season tends to wash out of logged watersheds but be taken up in tree growth in forested watersheds. As the dry season progresses, base flow containing little nitrate enters the streams, causing a decrease in nitrate concentration. By contrast, the other plant nutrients--phosphorus, Kjeldahl nitrogen, ammonium, and dissolved organic carbon--all decreased in streams from the November 1974 storm to the February 1975 storm and changed little from the rainy season through the dry season. This pattern suggests that these materials tend to accumulate in the soil during the dry season and be washed out and diluted as the rainy season progresses. Very little reaches the water table due to soil absorption so that little appears in the base flow during the dry season.

California

Water chemistry and electrical conductivity database for rivers in Yellowstone National Park, Wyoming

Chloride flux has been used to estimate heat flow in volcanic environments since the method was developed in New Zealand by Ellis and Wilson (1955). The method can be applied effectively at Yellowstone, because nearly all of the water discharged from its thermal features enters one of four major rivers (the Madison, Yellowstone, Snake, and Falls Rivers) that drain the park, and thus integration of chloride fluxes from all these rivers provides a means to monitor the total heat flow from the entire Yellowstone volcanic system (Fournier and others, 1976; Fournier, 1979). Fournier (1989) summarized the results and longterm heat-flow trends from Yellowstone, and later efforts that applied the chloride inventory method to estimate heat flow were described by Ingebritsen and others (2001) and Friedman and Norton (2007). Most recently, the U.S. Geological Survey (USGS), in conjunction with the National Park Service, has provided publicly accessible reports on solute flux, based on periodic sampling at selected locations (Hurwitz and others, 2007a,b). While these studies have provided a wealth of valuable data, winter travel restrictions and the great distances between sites present significant logistical challenges and have limited collection to a maximum of 28 samples per site annually. This study aims to quantify relations between solute concentrations (especially chloride) and electrical conductivity for several rivers in Yellowstone National Park (YNP), by using automated samplers and conductivity meters. Norton and Friedman (1985) found that chloride concentrations and electrical conductivity have a good correlation in the Falls, Snake, Madison, and Yellowstone Rivers. However, their results are based on limited sampling and hydrologic conditions and their relation with other solutes was not determined. Once the correlations are established, conductivity measurements can then be used as a proxy for chloride concentrations, thereby enabling continuous heat-flow estimation on a much finer timescale and at lower cost than is currently possible with direct sampling. This publication serves as a repository for all data collected during the course of the study from May 2010 through July 2011, but it does not include correlations between solutes and conductivity or recommendations for quantification of chloride through continuous electrical conductivity measurements. This will be the object of a future document.

Wyoming

Temporal trends of bulk precipitation and stream water chemistry (1977-1997) in a small forested area, Krusne hory, northern Bohemia, Czech Republic

The Krusne hory (Erzgebirge or Ore Mountains) has been heavily affected by high atmospheric pollutant deposition caused by fossil fuel combustion in an adjacent Tertiary coal basin. Long-term routine sampling of bulk precipitation (1977-1996) and stream water (1977-1998) in a forested area on the south-eastern slope of the mountains were used to evaluate trends and patterns in solute concentration and flux with respect to controlling processes. From 1977 to 1996, the annual volume-weighted Ca 2+ and SO4 2- concentrations decreased in bulk precipitation. However, after 1989, when a pronounced and continuous decrease occurred in coal production, annual volume-weighted concentrations decreased for most solutes, except H+. The concentration decreases were marked, with 1996 levels at or below 50% of those in 1989. The lack of a trend in H + is attributed to similar decreases in both acid anions and neutralizing base cations. Stream water concentrations of most solutes, i.e. H + , Ca 2+ , Mg 2+ , SO4 2- and NO 3- , were highest at the onset of sampling in 1977, decreased markedly from 1977 to 1983 and decreased more gradually from 1983 to 1998. The spruce forest die-back and removal reduced dry deposition of these solutes by reducing the filtering action, which was provided by the forest canopy. A notable decrease in stream water Ca 2+ concentrations occurred after 1995 and may be due to the depletion of Ca 2+ , which was provided by catchment liming in 1986, 1988 and 1989. Solute flux trends in bulk atmospheric deposition and stream water generally were not significant and the lack of trend is attributed to the large interannual variability in precipitation quantity and runoff, respectively. All solutes except Na + varied seasonally. The average seasonal concentrations varied between the solutes, but for most solutes were highest in winter and spring and lowest in summer, correlating with the seasonal trend and runoff. For Ca 2+ , Mg 2+ and SO 4 2- , the concentration minimum occurs in September and the maximum occurs in February or March, correlating with the seasonal baseflow. These solutes are primarily controlled by the contribution of soil water and groundwater to stream flow. During snowmelt, the meltwater generally causes concentrations to decrease as soil water and groundwater are diluted. For NO3, average minimum concentrations occur in August at the end of the growing season concurrent with the lowest stream flow, and the maximum occurs in February and March with high stream flow during snowmelt. Seasonal stream water NO3- concentration variations are large compared with the long-term decrease.The Krusne hory (Erzgebirge or Ore Mountains) has been heavily affected by high atmospheric pollutant deposition caused by fossil fuel combustion in an adjacent Tertiary coal basin. Long-term routine sampling of bulk precipitation (1977-1996) and stream water (1977-1998) in a forested area on the south-eastern slope of the mountains were used to evaluate trends and patterns in solute concentration and flux with respect to controlling processes. From 1977 to 1996, the annual volume-weighted Ca2+ and SO42- concentrations decreased in bulk precipitation. However, after 1989, when a pronounced and continuous decrease occurred in coal production, annual volume-weighted concentrations decreased for most solutes, except H+. The concentration decreases were marked, with 1996 levels at or below 50% of those in 1989. The lack of a trend in H+ is attributed to similar decreases in both acid anions and neutralizing base cations. Stream water concentrations of most solutes, i.e. H + , Ca 2+ , Mg 2+ , SO 4 2- and NO 3- , were highest at the onset of sampling in 1977, decreased markedly from 1977 to 1983 and decreased more gradually from 1983 to 1998. The spruce forest die-back and removal reduced dry deposition of these solutes by reducing the filtering action, which was provided by the forest canopy. A notable decrease in stream water Ca2+ concentrations occurred after 1995 an

Hydrological Processes

Hydrogeology, hydrologic budget, and water chemistry of the Medina Lake area, Texas

A three-phase study of the Medina Lake area in Texas was done to assess the hydrogeology and hydrology of Medina and Diversion Lakes combined (the lake system) and to determine what fraction of seepage losses from the lake system might enter the regional ground-water-flow system of the Edwards and (or) Trinity aquifers. Phase 1 consisted of revising the geologic framework for the Medina Lake area. Results of field mapping show that the upper member of the Glen Rose Limestone underlies Medina Lake and the intervening stream channel from the outflow of Medina Lake to the midpoint of Diversion Lake, where the Diversion Lake fault intersects Diversion Lake. A thin sequence of strata consisting primarily of the basal nodular and dolomitic members of the Kainer Formation of the Edwards Group, is present in the southern part of the study area. On the southern side of Medina Lake, the contact between the upper member of the Glen Rose Limestone and the basal nodular member is approximately 1,000 feet above mean sea level, and the contact between the basal nodular member and the dolomitic member is approximately 1,050 feet above mean sea level. The most porous and permeable part of the basal nodular member is about 1,045 feet above mean sea level. At these altitudes, Medina Lake is in hydrologic connection with rocks in the Edwards aquifer recharge zone, and Medina Lake appears to lose more water to the ground-water system along this bedding plane contact. Hydrologic budgets calculated during phase 2 for Medina Lake, Diversion Lake, and Medina/Diversion Lakes combined indicate that: (1) losses from Medina and Diversion Lakes can be quantified; (2) a portion of those losses are entering the Edwards aquifer; and (3) losses to the Trinity aquifer in the Medina Lake area are minimal and within the error of the hydrologic budgets. Hydrologic budgets based on streamflow, precipitation, evaporation, and change in lake storage were used to quantify losses (recharge) to the ground-water system from Medina Lake, Diversion Lake, and Medina/Diversion Lakes combined during October 1995–September 1996. Water losses from Medina Lake to the Edwards/Trinity aquifers ranged from -14.0 to 135 acre-feet per day; Diversion Lake ranged from -1.2 to 93.1 acre-feet per day; and Medina/Diversion Lakes combined ranged from 36.1 to 119 acre-feet per day. Monthly average recharge during December 1995–July 1996 was estimated using an alternative method developed during this study (current study method) and compared to monthly average recharge during December 1995–July 1996 estimated using the existing USGS method and the Trans-Texas method. Recharge to the Edwards aquifer estimated using the current study method was about 69 and 73 percent of the recharge estimated using the USGS and Trans-Texas methods, respectively. The USGS and Trans-Texas methods overestimated recharge from Medina Lake compared to the recharge estimated with the current study method when Medina Lake stage was between about 1,027 and 1,032 feet above mean sea level and underestimated recharge from Medina Lake when lake stage was between about 1,036 and 1,045 feet above mean sea level. The USGS and Trans-Texas methods underestimated recharge from Diversion Lake compared to the recharge estimated with the current study method when Diversion Lake stage was greater than 913 feet above mean sea level and overestimated recharge from Diversion Lake when lake stage was less than 913 feet above mean sea level. The water quality of Medina Lake and Medina River and in selected wells and springs in the Edwards and Trinity aquifers was characterized during phase 3 of the study. Environmental isotope analyses and geochemical modeling also were used to determine where water losses from the lake system might be entering the ground-water-flow system. Isotopic ratios of deuterium, oxygen, and strontium were analyzed in selected surface-water, lake-water, and ground-water samples to trace the isotopic “signature” of the lake water as it mixes with the ground water and to determine the fraction of lake water and ground water in selected Edwards aquifer wells. Isotopic data and geochemical modeling were used to show that lake water is moving into the Edwards aquifer in two fault blocks in the eastern Medina storage unit. One fault block is bounded on the north by the Vandenburg School fault and on the south by the Haby Crossing fault, and the second fault block is bounded on the north by the Diversion Lake fault and on the south by the Haby Crossing fault. In selected Edwards aquifer wells located southwest of Medina Lake and west of Diversion Lake, the proportion of lake water ranged from about 10 to 45 percent. Geochemical modeling using NETPATH confirms the degree of mixing between lake water and aquifer water shown by the isotopes.

Texas

Effect of agricultural practices on hydrology and water chemistry in a small irrigated catchment, Yakima River Basin, Washington

The role of irrigation and artificial drainage in the hydrologic cycle and the transport of solutes in a small agricultural catchment in central Washington's Yakima Valley were explored using hydrologic, chemical, isotopic, age-dating, and mineralogical data from several environmental compartments, including stream water, ground water, overland flow, and streambed pore water. A conceptual understanding of catchment hydrology and solute transport was developed and an inverse end-member mixing analysis was used to further explore the effects of agriculture in this small catchment. The median concentrations of major solutes and nitrates were similar for the single field site and for the catchment outflow site, indicating that the net effects of transport processes for these constituents were similar at both scales. However, concentrations of nutrients were different at the two sites, suggesting that field-scale variations in agricultural practices as well as nearstream and instream biochemical processes are important components of agricultural chemical transformation and transport in this catchment. This work indicates that irrigation coupled with artificial drainage networks may exacerbate the ecological effects of agricultural runoff by increasing direct connectivity between fields and streams and minimizing potentially mitigating effects (denitrification and dilution, for example) of longer subsurface pathways.

Washington

Assessment of water chemistry of the Coconino aquifer in northeastern Arizona

The Coconino aquifer was investigated as a potential groundwater resource for the Hopi Tribe and Navajo Nation in northeastern Arizona. Basic groundwater chemistry, including major ions, total dissolved solids, and selected trace metal concentrations, are presented and analyzed to characterize the Coconino aquifer. The geochemical compositions of groundwater are associated with changes in geology and groundwater movement and are compared to drinking-water standards to determine suitable areas for potential groundwater resource development. Dissolved-solids concentrations in much of the Coconino aquifer water were higher than the U.S. Environmental Protection Agency’s secondary drinking-water standard of 500 milligrams per liter (mg/L) due to a buried halite body in the southeastern part of the study area. However, trace metal concentrations were generally low. Groundwater may need to be treated for high dissolved-solids concentrations before it is suitable for use as a resource for the Hopi Tribe and Navajo Nation.

Arizona

Results of hydrologic tests and water-chemistry analyses, wells H-5A, H-5B, and H-5C, at the proposed Waste Isolation Pilot Plant site, southeastern New Mexico

Data were collected during hydrologic testing at wells H-5A, H-5B, and H-5C in the northeastern part of the proposed Waste Isolation Pilot Plant site in southeastern New Mexico. The three water-bearing zones tested, the Magenta and Culebra Dolomite Members of the Rustler Formation and the Rustler Formation-Salado Formation contact, yield water to wells at rates less than 0.6 gallon per minute. Throughout the testing, water-pressure response in the tested zone was monitored by a pressure-transducer system. Shut-in and slug tests were conducted to acquire data from which the following values were derived. Dissolved-solids concentrations In water samples were: (1) Magenta Dolomite Member, 6,090 milligrams per liter; (2) Culebra Dolomite Member, 144,000 milligrams per liter; and (3) Rustler Formation-Salado Formation contact, 412,000 milligrams per liter. The major chemical constituents of water samples from the Magenta Dolomite Member were sodium and sulfate; from the Culebra Dolomite Member, sodium and chloride; and from the Rustler Formation-Salado Formation contact, magnesium and chloride. Radium-226, a naturally occurring radioactive element, was present in samples from all three zones.

New Mexico

Results of hydrologic tests and water-chemistry analyses, Wells H-6A, H-6B, and H-6C, at the proposed Waste Isolation Pilot Plant site, southeastern New Mexico

Hydrologic testing was conducted at wells H-6A, H-6B, and H-6C in the northwestern part of the proposed Waste Isolation Pilot Plant site in southeastern New Mexico to define hydraulic properties of three water-bearing zones. The zones tested were the Magenta and Culebra Dolomite Members of the Rustler Formation and the Rustler Formation-Salado Formation contact. The Magenta Dolomite and the Rustler-Salado contact yield water to wells at rates less than 0.5 gallon per minute as determined from shut-in and slug tests. A transmissivity value for the Culebra Dolomite Member was obtained by conducting conventional pumping and recovery tests in well H-6B; this well was pumped at a rate of approximately 11 gallons per minute. Water samples from the Magenta Dolomite Member of the Rustler Formation had a dissolved-solids concentration of 5,760 milligrams per liter. The major chemical constituents of water samples from this zone were sulfate, sodium, and chloride. Water samples from the Culebra Dolomite Member of the Rustler Formation had dissolved-solids concentration of 52,600 milligrams per liter, and samples from the Rustler Formation-Salado Formation contact had 316,000 milligrams per liter; chloride and sodium were the major constituents in the water samples. Radium-266, a naturally occurring radioactive element, was present in samples from all three zones.

New Mexico

Biotic and abiotic processes controlling water chemistry during snowmelt at rabbit ears pass, Rocky Mountains, Colorado, U.S.A.

The chemical composition of snowmelt, groundwater, and streamwater was monitored during the spring of 1991 and 1992 in a 200-ha subalpine catchment on the western flank of the Rocky Mountains near Steamboat Springs, Colorado. Most of the snowmelt occurred during a one-month period annually that began in mid-May 1991 and mid-April 1992. The average water quality characteristics of individual sampling sites (meltwater, streamwater, and groundwater) were similar in 1991 and 1992. The major ions in meltwater were differentially eluted from the snowpack, and meltwater was dominated by Ca2+, SO4/2-, and NO3/-. Groundwater and streamwater were dominated by weathering products, including Ca2+, HCO3/- (measured as alkalinity), and SiO2, and their concentrations decreased as snowmelt progressed. One well had extremely high NO3/- concentrations, which were balanced by Ca2+ concentrations. For this well, hydrogen ion was hypothesized to be generated from nitrification in overlying soils, and subsequently exchanged with other cations, particularly Ca2+. Solute concentrations in streamwater also decreased as snowmelt progressed. Variations in groundwater levels and solute concentrations indicate thai most of the meltwater traveled through the surficial materials. A mass balance for 1992 indicated that the watershed retained H+, NH4/+, NO3/-, SO4/2- and Cl- and was the primary source of base cations and other weathering products. Proportionally more SO4/2- was deposited with the unusually high summer rainfall in 1992 compared to that released from snowmelt, whereas NO3/- was higher in snowmelt and Cl- was the same. The sum of snowmelt and rainfall could account for greater than 90% of the H+ and NH4/+ retained by the watershed and greater than 50% of the NO3/-.The chemical composition of snowmelt, groundwater, and streamwater was monitored during the spring of 1991 and 1992 in a 200-ha subalpine catchment on the western flank of the Rocky Mountains near Steamboat Springs, Colorado. The major ions in meltwater were differentially eluted from the snowpack, and meltwater was dominated by Ca2+, SO42-, and NO3-. Groundwater and streamwater were dominated by weathering products and their concentrations decreased as snowmelt progressed. Solute concentrations in streamwater also decreased as snowmelt progressed. A mass balance for 1992 showed that the watershed retained H+, NH4+, NO3-, SO42- and Cl- and was the primary source of base cations and other weathering products.

Conference Paper

Links between climate change, water-table depth, and water chemistry in a mineralized mountain watershed

Recent studies suggest that climate change is causing rising solute concentrations in mountain lakes and streams. These changes may be more pronounced in mineralized watersheds due to the sensitivity of sulfide weathering to changes in subsurface oxygen transport. Specific causal mechanisms linking climate change and accelerated weathering rates have been proposed, but in general remain entirely hypothetical. For mineralized watersheds, a favored hypothesis is that falling water tables caused by declining recharge rates allow an increasing volume of sulfide-bearing rock to become exposed to air, thus oxygen. Here, we test the hypothesis that falling water tables are the primary cause of an increase in metals and SO4 (100-400%) observed since 1980 in the Upper Snake River (USR), Colorado. The USR drains an alpine watershed geologically and climatologically representative of many others in mineralized areas of the western U.S. Hydrologic and chemical data collected from 2005 to 2011 in a deep monitoring well (WP1) at the top of the USR watershed are utilized. During this period, both water table depths and groundwater SO4 concentrations have generally increased in the well. A numerical model was constructed using TOUGHREACT that simulates pyrite oxidation near WP1, including groundwater flow and oxygen transport in both saturated and unsaturated zones. The modeling suggests that a falling water table could produce an increase in metals and SO4 of a magnitude similar to that observed in the USR (up to 300%). Future water table declines may produce limited increases in sulfide weathering high in the watershed because of the water table dropping below the depth of oxygen penetration, but may continue to enhance sulfide weathering lower in the watershed where water tables are shallower. Advective air (oxygen) transport in the unsaturated zone caused by seasonally variable recharge and associated water table fluctuations was found to have little influence on pyrite oxidation rates near WP1. However, this mechanism could be important in the case of a shallow dynamic water table and more abundant/reactive sulfides in the shallow subsurface. Data from WP1 and numerical modeling results are thus consistent with the falling water table hypothesis, and illustrate fundamental processes linking climate and sulfide weathering in mineralized watersheds.

Applied Geochemistry

Hydrologic variability, water chemistry, and phytoplankton biomass in a large flood plain of the Sacramento River, CA, U.S.A.

The Yolo Bypass, a large, managed floodplain that discharges to the headwaters of the San Francisco Estuary, was studied before, during, and after a single, month-long inundation by the Sacramento River in winter and spring 2000. The primary objective was to identify hydrologic conditions and other factors that enhance production of phytoplankton biomass in the floodplain waters. Recent reductions in phytoplankton have limited secondary production in the river and estuary, and increased phytoplankton biomass is a restoration objective for this system. Chlorophyll a was used as a measure of phytoplankton biomass in this study. Chlorophyll a concentrations were low (<4 μg l −1 ) during inundation by the river when flow through the floodplain was high, but concentrations rapidly increased as river inflow decreased and the floodplain drained. Therefore, hydrologic conditions in the weeks following inundation by river inflow appeared most important for producing phytoplankton biomass in the floodplain. Discharges from local streams were important sources of water to the floodplain before and after inundation by the river, and they supplied dissolved inorganic nutrients while chlorophyll a was increasing. Discharge from the floodplain was enriched in chlorophyll a relative to downstream locations in the river and estuary during the initial draining and later when local stream inflows produced brief discharge pulses. Based on the observation that phytoplankton biomass peaks during drainage events, we suggest that phytoplankton production in the floodplain and biomass transport to downstream locations would be higher in years with multiple inundation and draining sequences.

California

Sediment and water chemistry of the San Juan River and Escalante River deltas of Lake Powell, Utah, 2010-2011

Recent studies have documented the presence of trace elements, organic compounds including polycyclic aromatic hydrocarbons, and radionuclides in sediment from the Colorado River delta and from sediment in some side canyons in Lake Powell, Utah and Arizona. The fate of many of these contaminants is of significant concern to the resource managers of the National Park Service Glen Canyon National Recreation Area because of potential health impacts to humans and aquatic and terrestrial species. In 2010, the U.S. Geological Survey began a sediment-core sampling and analysis program in the San Juan River and Escalante River deltas in Lake Powell, Utah, to help the National Park Service further document the presence or absence of contaminants in deltaic sediment. Three sediment cores were collected from the San Juan River delta in August 2010 and three sediment cores and an additional replicate core were collected from the Escalante River delta in September 2011. Sediment from the cores was subsampled and composited for analysis of major and trace elements. Fifty-five major and trace elements were analyzed in 116 subsamples and 7 composited samples for the San Juan River delta cores, and in 75 subsamples and 9 composited samples for the Escalante River delta cores. Six composited sediment samples from the San Juan River delta cores and eight from the Escalante River delta cores also were analyzed for 55 low-level organochlorine pesticides and polychlorinated biphenyls, 61 polycyclic aromatic hydrocarbon compounds, gross alpha and gross beta radionuclides, and sediment-particle size. Additionally, water samples were collected from the sediment-water interface overlying each of the three cores collected from the San Juan River and Escalante River deltas. Each water sample was analyzed for 57 major and trace elements. Most of the major and trace elements analyzed were detected at concentrations greater than reporting levels for the sediment-core subsamples and composited samples. Low-level organochlorine pesticides and polychlorinated biphenyls were not detected in any of the samples. Only one polycyclic aromatic hydrocarbon compound was detected at a concentration greater than the reporting level for one San Juan composited sample. Gross alpha and gross beta radionuclides were detected at concentrations greater than reporting levels for all samples. Most of the major and trace elements analyzed were detected at concentrations greater than reporting levels for water samples.

Utah