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IOOS modeling subsystem: vision and implementation strategy

Numerical modeling is vital to achieving the U.S. IOOS® goals of predicting, understanding and adapting to change in the ocean and Great Lakes. In the next decade IOOS should cultivate a holistic approach to coastal ocean prediction, and encourage more balanced investment among the observing, modeling and information management subsystems. We believe the vision of a prediction framework driven by observations, and leveraging advanced technology and understanding of the ocean and Great Lakes, would lead to a new era for IOOS that would not only produce more powerful information, but would also capture broad community support, particularly from the general public, thus allowing IOOS to develop into the comprehensive information system that was envisioned at the outset.

Book

Chemical dissolution of sulfide minerals

Chemical dissolution treatments involving the use of aqua regia, 4 N HNO 3 , H 2 O 2 -ascorbic acid, oxalic acid, KClO 3 +HCl, and KClO 3 +HCl followed by 4 N HNO 3 were applied to specimens of nine common sulfide minerals (galena, chalcopyrite, cinnabar, molybdenite, orpiment, pyrite, stibnite, sphalerite, and tetrahedrite) mixed individually with a clay loam soil. The resultant decrease in the total sulfur content of the mixture, as determined by using the Leco induction furnace, was used to evaluate the effectiveness of each chemical treatment. A combination of KClO 3 +HCl followed by 4 N HNO 3 boiling gently for 20 min has been shown to be very effective in dissolving all the sulfide minerals. This treatment is recommended to dissolve metals residing in sulfide minerals admixed with secondary weathering products, as one step in a fractionation scheme whereby metals in soluble and adsorbed forms, and those associated with organic materials and secondary oxides, are first removed by other chemical extractants.

Journal of Research of the U.S. Geological Survey

Geologic implications of the Apollo 14 Fra Mauro breccias and comparison with ejecta from the Ries Crater, Germany

On the basis of petrographic and laboratory and active seismic data for the Fra Mauro breccias, and by comparison with the nature and distribution of the ejecta from the Ries crater, Germany, some tentative conclusions regarding the geologic significance of the Fra Mauro Formation on the moon can be drawn. The Fra Mauro Formation, as a whole, consists of unwcldcd, porous ejecta, slightly less porous than the regolith. It contains hand-specimen and larger size clasts of strongly annealed complex breccias, partly to slightly annealed breccias, basalts, and perhaps spherule-rich breccias. These clasts are embedded in a matrix of porous aggregate dominated by mineral and breccia fragments and probably largely free of undevitrified glass. All strongly annealed hand-specimen-size breccias are clasts in the Fra Mauro Formation. To account for the porous, unwelded state of the Fra Mauro Formation, the ejecta must have been deposited at a temperature below that required for welding and annealing. Large boulders probably compacted by the Cone crater event occur near the rim of the crater. They probably consist of a similar suite of fragments, but are probably less porous than the formation. The geochronologic clocks of fragments in the Fra Mauro Formation, with textures ranging from unannealed to strongly annealed, were not reset or strongly modified by the Imbrian event. Strongly annealed breccia clasts and basalt clasts are pre-Imbrian, and probably existed as ejecta mixed with basalt flows in the Imbrium Basin prior to the Imbrian event. The Imbrian event probably occurred between 3.90 or 3.88 and 3.65 b.y. ago.

Ries Crater

Atomic absorption spectrophotometric determination of microgram levels of Co, Ni, Cu, Pb, and Zn in soil and sediment extracts containing large amounts of Mn and Fe

An atomic absorption spectrophotometric method has been developed for the determination of seven metal ions in the hydroxylamine extract of soils and sediments. Mn, Fe, and Zn are directly determined in the aqueous extract upon dilution. Co, Ni, Cu, and Pb in a separate aliquot of the extract are chelated with APDC (ammonium pyrrolidine dithiocarbamate) and extracted into MIBK (methyl isobutyl ketone) before determination. Data are presented to show the quantitative recovery of microgram levels of Co, Ni, Cu, and Pb by APDC-MIBK chelation-extraction from synthetic solutions containing as much as 2,000 ug/ml (micrograms per milliliter) Mn or 50 ug/ml Fe. Recovery of known amounts of the metal ions from sample solutions is equally satisfactory. Reproducible results are obtained by replicate analyses of two sediment samples for the seven metals.

Journal of Research of the U.S. Geological Survey

Disruption and restoration of en route habitat, a case study: The Chenier Plain

Cheniers (relict beach ridges) and other habitats adjacent to ecological barriers may be critical linkages in the migratory pathways of long-distance migratory birds. It is important that these wooded habitats provide enough food and cover at the right time to support these birds’ requirements. To date, little attention has been given to the conservation of coastal woodlands, habitats in which en route migrants tend to concentrate in large numbers during migration. Because about one-third of North Americas ’ human population lives within 80 km of the coast, many forest-dwelling landbird migrants now depend on degraded native woodlands and urbanized environments for survival during migration. Restoration or rehabilitation of coastal woodlands, such as the cheniers of southwest Louisiana and southeast Texas, is of particular importance because of historic anthropogenic modifications, their limited geographic extent, and the extraordinary abundance and species richness of migratory birds using them during migration. In this paper, we use the Chenier Plain as a case study to discuss the issue of land use changes and their consequences for maintaining suitable stopover habitat. Results from an ongoing field study in this ecosystem indicate that most forest-dependent migratory birds are tolerant of at least some degradation of chenier forest during migration. However, these results reveal that subtle differences in vegetation composition and structure beneath the canopy of these forests, primarily as a result of livestock grazing and white-tailed deer overbrowsing, can result in differential use by some en route migrants. Species that were most affected by disturbance to the forest understory were early-arriving migrants, dead-leaf foragers, frugivores, and nectarivores. Given that the understory structure and regeneration of chenier forests has been so greatly reduced, and that high densities of nearctic-neotropical migrants tend to concentrate in cheniers during migration, restoration and re-habilitation should be conservation priorities in the Chenier Plain.

Louisiana, Texas

Origin of lunar light plains

Most Cayley-type Imbrian-age plains deposits and adjacent mantled slopes, including those at the Apollo 16 site, may be composed at least near the surface of ejecta from the Orientale basin, the youngest multiringed impact basin on the Moon. The distribution and apparent age of the plains deposits and preliminary data on the highly feldspathic breccias collected by the Apollo 16 crew indicate that these surficial materials are neither locally derived nor part of the Imbrium ejecta. Stratigraphic relations, crater size-frequency distributions, and dating by erosional morphology of superposed craters have established Cayley light-plains deposits as younger than the Imbrium basin and older than mare material. All such crater-dated Cayley-type plains on both the near and far sides of the Moon are contemporaneous within the limits of the technique. Furthermore, comparisons of the crater size-frequency distributions of the Hevelius Formation (Orientale ejecta) and the plains show that the Cayley and Hevelius Formations are indistinguishable in age. The surface and near-surface materials of the Apollo 16 plains, therefore, are contemporaneous with Orientale basin ejecta not with Imbrium ejecta, in which both crater densities and crater degradation are greater than in the light plains. Imbrium ejecta may, however, be present on the surface at the Apollo 16 site where excavated by craters from depth. Limited age data now available on the Apollo 16 samples are consistent with this interpretation. We conclude that rocks of Orientale provenance may be predominant on and near the surface at the Apollo 16 site. This hypothesis implies that the catastrophic Orientale impact struck a highland area underlain by highly feldspathic material and spread it over much of the Moon. Thus, much of the lunar highlands crust need not consist of anorthositic materials to any significant depth. These conclusions apply to the plains at the Apollo 16 site and most of the other Cayley-type plains, but we do not exclude the possibility that, moonwide, the plains may be polygenetic.

Journal of Research of the U.S. Geological Survey