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Geochemical modeling of water-rock interactions in mining environments

Geochemical modeling is a powerful tool for evaluating geochemical processes in mining environments. Properly constrained and judiciously applied, modeling can provide valuable insights into processes controlling the release, transport, and fate of contaminants in mine drainage. This chapter contains 1) an overview of geochemical modeling, 2) discussion of the types of models and computer programs used, 3) description of a procedure for screening water analyses for modeling input, and 4) examples of the application of modeling for interpreting geochemical processes in mining environments. Three general strategies in current use to interpret water-rock interactions are statistical analysis, “inverse” modeling, and “forward” modeling. Multivariate correlation analysis, factor analysis, cluster analysis, and other statistical techniques can group water-chemistry data into sets that may relate to hydrogeochemical processes (Drever, 1988; Puckett and Bricker, 1992). In the field of geochemical exploration, statistical analysis is used widely to treat large data sets of rock and sediment chemistry (e.g., Garrett, 1989). No physical or chemical principles are involved directly in these statistical treatments, hence they are not considered further in this chapter. Nevertheless, statistical analysis can be a useful tool in organizing complex geochemical data for interpretation.

Book chapter↗

Petroleum and individual polycyclic aromatic hydrocarbons

Crude petroleum, refined-petroleum products, and individual polycyclic aromatic hydrocarbons (PAHs) contained within petroleum are found throughout the world. their presence has been detected in living and nonliving components of ecosystems. Petroleum can be an environmental hazard for wild animals and plants. Individual PAHs are also hazardous to wildlife, but they are most commonly associated with human illnesses. Because petroleum is a major environmental source of these PAHs, petroleum and PAHs are jointly presented in this chapter. Composition, sources, environmental fate, and toxic effects on all living components of aquatic and terrestrial environments are addessed.

Book chapter↗

Geologic sources of energy

This chapter describes the exploration, development, and geologic setting of petroleum resources (including tar sands), coal resources (including coalbed methane), and geothermal energy resources of the Northern Cordillera.For petroleum resources, the chapter describes: (1) the history of petroleum development and production, first for Alaska and then for the Canadian Cordillera; and (2) generalized basin analysis geologic settings for the six major petroleum basins that are illustrated in summary maps and cross sections. Subsequent sections of the chapter describe the nature and geologic setting of tar sand resources, geothermal energy resources, and coal resources. The area distribution of the energy resources of the region are depicted in the Energy Resources Map that has multiple layers that can be displayed in various arrangements. Employing this map in a separate window while reading the text will be greatly beneficial. Many geographic names are employed in the descriptions throughout this chapter. While reading this chapter, viewing the Geographic Regions Layer of the Energy Resources Map, as needed, will be valuable.

Book chapter↗

Land surface phenology

Certain vegetation types (e.g., deciduous shrubs, deciduous trees, grasslands) have distinct life cycles marked by the growth and senescence of leaves and periods of enhanced photosynthetic activity. Where these types exist, recurring changes in foliage alter the reflectance of electromagnetic radiation from the land surface, which can be measured using remote sensors. The timing of these recurring changes in reflectance is called land surface phenology (LSP). During recent decades, a variety of methods have been used to derive LSP metrics from time series of reflectance measurements acquired by satellite-borne sensors. In contrast to conventional phenology observations, LSP metrics represent the timing of reflectance changes that are driven by the aggregate activity of vegetation within the areal unit measured by the satellite sensor and do not directly provide information about the phenology of individual plants, species, or their phenophases. Despite the generalized nature of satellite sensor-derived measurements, they have proven useful for studying changes in LSP associated with various phenomena. This chapter provides a detailed overview of the use of satellite remote sensing to monitor LSP. First, the theoretical basis for the application of satellite remote sensing to the study of vegetation phenology is presented. After establishing a theoretical foundation for LSP, methods of deriving and validating LSP metrics are discussed. This chapter concludes with a discussion of major research findings and current and future research directions.

Book chapter↗

Laser-induced breakdown spectroscopy

Laser-Induced Breakdown Spectroscopy (LIBS) is the remote elemental analysis technique used by the ChemCam instrument on the Curiosity rover. LIBS involves remotely ablating material from rocks and soils with a focused high-energy laser, which generates an optically excited plasma from which the elements in the rock or soil sample are quantitatively determined. The LIBS technique offers many advantages for remote chemical analysis. LIBS provides very rapid analyses without the need for any sample preparation. LIBS is capable of detecting all elements present above the detection limits independent of the atomic mass. LIBS quantitative analysis continues to evolve and produce accurate compositions with decreasing uncertainties. Furthermore, the matrix effects that tend to complicate most elemental analysis techniques like LIBS are increasingly exploited to extract more sample details. The focus of this chapter is to describe the current state of LIBS chemical analysis for remote planetary science.

Book chapter↗

Heat tracer methods

The flow of heat in the subsurface is closely linked to the movement of water (Ingebritsen et al ., 2006). As such, heat has been used as a tracer in groundwater studies for more than 100 years (Anderson, 2005). As with chemical and isotopic tracers (Chapter 7), spatial or temporal trends in surface and subsurface temperatures can be used to infer rates of water movement. Temperature can be measured accurately, economically, at high frequencies, and without the need to obtain water samples, facts that make heat an attractive tracer. Temperature measurements made over space and time can be used to infer rates of recharge from a stream or other surface water body (Lapham, 1989; Stonestrom and Constantz, 2003); measurements can also be used to estimate rates of steady drainage through depth intervals within thick unsaturated zones (Constantz et al ., 2003; Shan and Bodvarsson, 2004). Several thorough reviews of heat as a tracer in hydrologic studies have recently been published (Constantz et al ., 2003; Stonestrom and Constantz, 2003; Anderson, 2005; Blasch et al ., 2007; Constantz et al ., 2008). This chapter summarizes heat-tracer approaches that have been used to estimate recharge. Some clarification in terminology is presented here to avoid confusion in descriptions of the various approaches that follow. Diffuse recharge is that which occurs more or less uniformly across large areas in response to precipitation, infiltration, and drainage through the unsaturated zone. Estimates of diffuse recharge determined using measured temperatures in the unsaturated zone are referred to as potential recharge because it is possible that not all of the water moving through the unsaturated zone will recharge the aquifer; some may be lost to the atmosphere by evaporation or plant transpiration. Estimated fluxes across confining units in the saturated zone are referred to as interaquifer flow (Chapter 1). Focused recharge is that which occurs directly from a point or line source, such as a stream, on land surface. Focused recharge may vary widely in space and time. If the water table intersects a stream channel, estimates of stream loss are called actual recharge, or just recharge. If the water table lies below the stream channel, estimates are referred to as potential recharge. For simplicity, all vertical water fluxes are referred to as drainage throughout this chapter. Whether the estimated quantity represents actual or potential recharge or drainage depends on the circumstances of each individual study.

Book chapter↗

Structural equation modeling

This chapter introduces background and historical information on how structural equation modeling (SEM) came to be developed. Then, the main differences between SEM and earlier multivariate methods are explained. The chapter describes three main applications of SEM: path analysis, factor analysis, and hybrid models. Some computer programs are recommended for these applications. The step-by-step section goes over how to estimate structural models with AMOS and R. The chapter concludes with two example applications of SEM in the planning field.

Book chapter↗

Saltcedar and Russian olive control demonstration act science assessment [Executive summary]

The primary intent of this document is to provide the science assessment called for under The Saltcedar and Russian Olive Control Demonstration Act of 2006 (Public Law 109–320; the Act). A secondary purpose is to provide a common background for applicants for prospective demonstration projects, should funds be appropriated for this second phase of the Act. This document synthesizes the state-of-the-science on the following topics: the distribution and abundance (extent) of saltcedar (Tamarix spp.) and Russian olive (Elaeagnus angustifolia) in the Western United States, potential for water savings associated with controlling saltcedar and Russian olive and the associated restoration of occupied sites, considerations related to wildlife use of saltcedar and Russian olive habitat or restored habitats, methods to control saltcedar and Russian olive, possible utilization of dead biomass following removal of saltcedar and Russian olive, and approaches and challenges associated with revegetation or restoration following control efforts. A concluding chapter discusses possible long-term management strategies, needs for additional study, potentially useful field demonstration projects, and a planning process for on-the-ground projects involving removal of saltcedar and Russian olive. The principal findings and conclusions from each of these chapters are summarized below.

Book chapter↗

Golden Eagle (Aquila chysaetos)

The golden eagle ( Aquila chrysaetos ) is commonly recognized as an indicator of ecosystem health and was selected as an important indicator species for the ecological health of lands owned and managed by East Bay Stewardship Network (Network) partner agencies within the area of focus for this project (See map, Chapter 1). Based on national conservation goals and past and current golden eagle research in the area of focus, the desired condition and trend for this indicator species are to: (1) maintain or improve site occupancy by territorial pairs (i.e., the proportion of sites surveyed with at least 1 pair of eagles), (2) maximize reproductive rate (i.e., the proportion of sites surveyed with at least 1 pair of productive eagles), and (3) minimize the occurrence of territorial subadults in the local breeding population. The condition and trend in these three primary metrics were assessed for golden eagles in the area of focus using data from a large-scale demographic study conducted in 2014–2021 by the U.S. Geological Survey (USGS) and others. Overall, we found a condition of “caution” and an “unchanging” trend for golden eagles in the area of focus. Analyses of site occupancy and reproductive rate indicated that the local breeding population was unchanging (i.e., no evidence of increasing or decreasing time trends in these metrics during 2014–2021). However, a consistently high occurrence of territorial subadults (22%–35%) has been observed at breeding territories near the Altamont Pass Wind Resource Area (APWRA) relative to occupied territories monitored in surrounding regions (~3%). The heightened occurrence of territorial subadults suggested a possible increase in the adult mortality rate of territorial eagles occupying the Mt. Diablo Range and Mt. Hamilton subregions in the area of focus. Thus, although no trends were detected in site occupancy or reproductive rate, caution is warranted given the high observed frequency of territorial subadults, which was predominately associated with pairs monitored near the APWRA. The USGS golden eagle study was conducted during a period of prolonged and severe drought in the area of focus, which has been shown elsewhere to reduce the reproductive rate of golden eagles. Although we detected no trends in reproductive rate, we identified a condition of “caution” for this metric in the area of focus given that annual estimates were relatively low during the study period, which primarily included years of severe drought conditions in west-central California. A primary goal of the analysis was to provide a benchmark against which managers can measure future changes and understand the likely trajectory of this species. Baseline data and analyses provided here can be used to identify projects that could help support golden eagle conservation. Given the constraint of using only existing and available data, this evaluation also identified areas where not enough was known to draw meaningful conclusions. Gaps in our understanding include the long-term effects of repeated, extreme climate events (e.g., drought and wildfire) on golden eagle demographics and population sustainability, refined estimates of eagle survivorship and sources of mortality, and whether the APWRA represents a population sink for golden eagles within the northern Diablo Range and surrounding regions. These are described as data gaps at the end of this chapter and may be areas to focus on for future research and collaborations among land managers.

Book chapter↗

Estuarine Geomorphology, Circulation, and Mixing

To understand the processes affecting the distribution and cycles of particulates, pollutants, nutrients, and organisms in estuaries, it is insufficient to focus solely on the biological and chemical aspects of the processes. Water sources and movements (e.g. evaporation, precipitation, riverine discharge, submarine ground water discharge, wetland hydrology, and tidal exchange) as well as other hydrodynamic aspects of coastal systems, including circulation patterns, stratification, mixing and flushing, must also be considered. When hydrodynamic changes occur quickly relative to biological, geological, and chemical transformations, they become the dominant controlling factors of many ecological processes in estuaries (Officer 1980), and it is now widely recognized that a thorough understanding of the marine estuarine ecology requires comprehensive knowledge and integration of physical processes affecting the system. Using the terminology of a shallow-water oceanographer, this chapter aims to organize, classify, and describe some of these important physical characteristics and processes.

Book chapter↗

Geomorphic change and vegetation development on the Muddy River Mudflow Deposit

Geomorphic disturbances are widely recognized as important processes that influence plant-community development and landscape-scale vegetation patterns [e.g., Veblen and Ashton (1978), Garwood et al. (1979), Swanson et al. (1988), and Malanson (1993)]. In volcanically active areas such as the Pacific Northwest, mudflows are locally important geomorphic disturbance events governing short- and long-term ecological conditions. Volcanic mudflows can scour and inundate river valleys with large volumes of debris (Janda et al. 1981; Pierson 1985; Vallance and Scott 1997; Scott 1988; Vallance 2000; Kovanen et al. 2001) and influence plant succession tens of kilometers downstream from their points of origin (Halpern and Harmon 1983; Adams and Dale 1987;Wood and del Moral 1987; Frenzen et al. 1988). In addition to altering plant succession, large volcanic mudflows can initiate a cascading chain of secondary disturbances that further modify the landscape and affect subsequent ecological responses (see Swanson and Major, Chapter 3, this volume).

Book chapter↗

The complexity of reversals

This chapter contains sections titled: Introduction Some Illustrative Polarity Transition Records The Case for Complexity Conclusions

Geophysical Monograph Series↗

Ecotoxicology of organic contaminants to amphibians

The effects of organic contaminants on amphibians are poorly known but of considerable interest. These contaminants include the highly toxic dioxins and furans as well as PCBs, PAHs and organochlorine pesticides. Although these compounds may have lower acute toxicity than dioxins and furans, they have been implicated in several problems associated with genotoxicity, endocrine disruption, malformations and reduced growth. There is evidence that amphibian tadpoles bioaccumulate these organic compounds and may have biological concentrating factors ranging in the hundreds. This chapter reviews what is known about the effects and concentrations of organic contaminants in amphibians and provides recommendations for further research

Book chapter↗

Mesozoic magmatism in Montana

From crystalline batholiths with footprints larger than 4,500 km 2 to beds of micron-sized ash particles, a record of Mesozoic magmatism is found throughout Montana. Mesozoic igneous rocks are an important natural resource in the state because of their association with precious metal ores and industrial mineral deposits. Mesozoic magmatism in Montana is a tale of volcanic arc eruptions, pluton emplacement, crustal magma differentiation, melting, and assimilation. Explosive caldera-forming eruptions, magmatic hydrothermal and metamorphic mineralization, tectonic uplift, fluvial erosion, and redeposition of igneous rocks and mineral resources are all chronicled by Mesozoic igneous rocks. This article offers a summary of the types, locations, extents, and ages of Mesozoic igneous rocks in Montana. Then follows a discussion of the generation and emplacement of magmas and intrusive rocks, their geometries, and the style and timing of magmatism. The chapter ends with a summary of what remains unknown and offers suggestions for future research.

Montana↗

Biodegration of chlorinated ethenes

Biodegradation of chlorinated ethenes by naturally occurring or artificially enhanced processes is an important component of current site remediation strategies. At this writing, several microbial mechanisms for chlorinated ethene transformation and degradation have been identified. The purpose of this chapter is to briefly summarize the current understanding of those processes that lead to the biodegradation of chlorinated ethenes.

Book chapter↗

Groundwater regulation and integrated planning

The complex nature of groundwater and the diversity of uses and environmental interactions call for emerging groundwater problems to be addressed through integrated management and planning approaches. Planning requires different levels of integration dealing with: the hydrologic cycle (the physical process) including the temporal dimension; river basins and aquifers (spatial integration); socioeconomic considerations at regional, national and international levels; and scientific knowledge. The great natural variation in groundwater conditions obviously affects planning needs and options as well as perceptions from highly localised to regionally-based approaches. The scale at which planning is done therefore needs to be carefully evaluated against available policy choices and options in each particular setting. A solid planning approach is based on River Basin Management Planning (RBMP), which covers: (1) objectives that management planning are designed to address; (2) the way various types of measures fit into the overall management planning; and (3) the criteria against which the success or failure of specific strategies or interventions can be evaluated (e.g. compliance with environmental quality standards). A management planning framework is to be conceived as a “living” or iterated document that can be updated, refined and if necessary changed as information and experience are gained. This chapter discusses these aspects, providing an insight into European Union (EU), United States and Australia groundwater planning practices.

Book chapter↗

The changing southwest

This chapter describes important geographical and socio-economic characteristics and trends in the Southwest—such as population and economic growth and changes in land ownership, land use, and land cover—that provide the context for how climate change will likely affect the Southwest. The chapter also describes key laws and institutions relevant to adaptive management of resources.

Southwest United States↗

Diseases of tadpoles

This chapter is devoted to the diseases of anuran larvae that cause morbidity( illness) and mortality (death). The purpose of this chapter is to describe diseases that may be encountered in free-living tadpoles of the United States and Canada. Much of the information in this chapter comes from unpublished diagnostic examinations of amphibians done at the U.S. Geological Survey, National Wildlife Health Center (NWHC). Many parasites infect amphibians, and with very few exceptions, these are clinically silent infections (produce no overt evidence of illness or death); accordingly, readers are referred to parasitology texts for a review of protozoan, helminthic and ectoparasitic organisms of amphibians (Flynn, 1973; Poynton and Whitaker, 2001). Diseases presented in this chapter are Ranaviral (iridovirus) infection Adenovirus infection Lucke frog herpesvirus Chytrid fungal infection Watermold infection (saprolegniasis) Coccidiosis Leeches Anchorworms

Book chapter↗