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At least 1,585 records · Page 88Linked to original sources
USGS1918

Baked shale and slag formed by the burning of coal beds

The baking and reddening of large masses of strata caused by the burning of coal beds is a striking feature of the landscape in most of the great western coal-bearing areas. The general character and broader effects of the burning have been described by many writers, but the fact that in places enough heat is generated to fuse and thoroughly recrystallize the overlying shale and sandstone has received less attention. Some of the natural slags thus formed simulate somewhat abnormal igneous rocks, but others consist largely of rare and little known minerals. A wide range in the mineral composition of such slags is to be expected, depending on the composition of the original sediment and the conditions of fusion and cooling. These products of purely thermal metamorphism offer a fertile field for petrologic investigation. The writer has observed the effects produced by the burning of coal beds in several localities in Montana, particularly along upper Tongue River in the southern part of the State, in the district lying southeast of the mouth of Bighorn River, and in the Little Sheep Mountain coal field north of Miles City. A number of specimens of the rock formed have been examined under the microscope, though time has not been available for a systematic examination. The writer is greatly indebted to Mr. E. S. Larsen for assistance in the study of some of the minerals.

Montana↗
USGS1994

Lead isotope compositions as guides to early gold mineralization: The North Amethyst vein system, Creede district, Colorado

The North Amethyst vein system, which is hosted by approximately 27 Ma Carpenter Ridge Tuff and approximately 26 Ma Nelson Mountain Tuff, has two mineral associations separated by brecciation and sedimentation in the veins. The early association consists of quartz, rhodonite, hematite, magnetite, electrum (Au (sub 0.3-0.5) Ag (sub 0.7-0.5)) , and Mn carbonate, Au-Ag sulfide, Ag sulfosalt, and base metal sulfide minerals. The later mineral association cuts the Mn- and Au-bearing assemblages and consists of quartz, calcite, sericite, chlorite, hematite, adularia, fluorite, base metal sulfides, and Ag-bearing tetrahedrite.Our detailed studies show that the Pb isotope compositions of paragenetically early galenas associated with Au-rich mineralization in the North Amethyst vein system are relatively unradiogenic ( 206 Pb/ 204 Pb: 18.826-18.881, 207 Pb/ 204 Pb: 15.588-15.602, and 208 Pb/ 204 Pb: 37.790-37.926) compared to Pb isotope compositions of galenas formed later at about 25 Ma during Ag and base metal mineralization ( 206 Pb/ 204 Pb: 19.041-19.115, 207 Pb/ 204 Pb: 15.627- 15.672, and 208 Pb/ 204 Pb: 37.829-38.057). New Pb isotope data for the central and southern parts of the Creede district, which are located 5 to 7 km south of the North Amethyst area, agree with the results of a regional study by Doe et al. (1979) that included five samples from the main part of the Creede district. Galenas and adularia from the central and southern Creede district and galenas from the Bondholder district, 7 km north of the North Amethyst area, are similar to the Pb isotope compositions of galenas formed later in the North Amethyst area during Ag and base metal mineralization. Galenas from the Alpha-Corsair vein, which was mined for Ag prior to 1910, are isotopically similar to galenas associated with North Amethyst Au-stage mineralization. This isotopic similarity suggests that unexplored segments of the Alpha-Corsair structure may have the same mineralogy as the North Amethyst Au stage; thus, the Alpha-Corsair structure has the potential for high gold contents.Pb isotope compositions from the late stage of the North Amethyst vein system and from the Bondholder and central and southern Creede mining districts are more radiogenic than the host volcanic rocks of the central cluster of the San Juan volcanic field. Our Pb isotope results indicate that early Au mineralization of the North Amethyst area may represent the product of an older and relatively local hydrothermal system distinct from that of the younger base metal and Ag mineralization found throughout the region. Fluids that deposited Au minerals may have derived their Pb isotope composition by a greater degree of interaction with shallow, relatively less radiogenic volcanic wall rocks. The younger, base metal and Ag-rich mineralization that overprints the Au mineralization in the North Amethyst area clearly has a more radiogenic isotopic signature, which implies that the later mineralization derived a greater component of its Pb from Proterozoic source rocks, or sediments derived from them.Paragenetically early sulfide-rich vein assemblages have the least radiogenic galenas and generally also have the highest Au contents. Thus, identification of paragenetically early vein assemblages with relatively unradiogenic Pb isotope compositions similar to those of the North Amethyst area provides an additional exploration tool for Au in the central San Juan Mountains area.

Colorado↗
USGS1954

Thorium and rare earth minerals in the Powderhorn district, Gunnison County, Colorado

Thorium has been found since 1949 in at least 33 deposits in an area 6 miles wide and 20 miles long in the Powderhorn district, Gunnison County, Colo. The district is composed largely of pre-Jurassic metamorphic and igneous rocks, which are chiefly if not entirely pre-Cambrian in age. The metamorphic and igneous rocks are overlain by sandstone of the Morrison formation of Jurassic age, and by volcanic rocks of the Alboroto group and Hinsdale formation of Miocene and Pliocene (?) age, respectively. The thorium deposits occur in or near alkalic igneous rocks in which such elements as titanium, rare earths, barium, strontium, and niobium occur in greater-than-average amounts. The greatest mass of the alkalic igneous rocks the Iron Hill composite stoc,- occupies an area of 12 square miles in the southeastern part of the district. The age of the thorium deposits, like that of the alkalic igneous rocks, is not known other than pre-Jurassic. The thorium veins and mineralized shear zones range from a few inches to 18 feet in thickness and from a few feet to 3,500 feet in length. The veins are composed of calcite,.dolomite, siderite, ankerite, quartz, barite, pyrite, sphalerite, galena, goethite,. apatite, alkali feldspar, and many other minerals. The thorium occurs at least partly in thorite or hydrothorite. Sparse xenotime has been tentatively identified in one deposit. Several minerals containing rare earths of the cerium group as major constituents are found in carbonate veins near Iron Hill. Bastnaesite has been identified by X-ray methods, and cerite and synchisite are probably present also.The fluorapatite in some veins and in parts of the carbonate rock mass that occupies 2 square miles in the central part of the Iron Hill complex contains rare earths of the cerium group, generally in amounts of a fraction of a percent of the rock. The radioactivity of the deposits appears to be due almost entirely to thorium and its daughter products The ThO 2 content of selected highgrade samples from the Little Johnnie vein is as much as 4 percent. The ThO 2 content of the veins is generally less than 1 percent, however, and is only 0.05 to 0.1 percent in many of the veins studied. The little Johnnie vein, which was mapped in detail, can be traced discontinuously for a distance of more than 3,500 feet. The thoriumbearing material occurs as irregular veinlets and thin films introduced into the fault zone. The mineralized shear zone ranges from less than 6 inches to 5 feet in thickness. Near its west end the vein is broken by many faults in a zone that marks the edge of a roughly circular fault block, 1 1/2. miles in diameter, that has dropped 1,000 feet or more since the deposition of Miocene volcanic-rocks that now floor the Milkranch basin.

Colorado↗
USGS2014

The Rôle of volatiles in the formation of Virginia titanium deposits

The feldspathic rock with which the titanium deposits of Virginia are associated appears to be an anorthosite, although the plagioclase is somewhat more sodic than in normal anorthosites. That is, this rock shows evidence of having been introduced as a mush‐like mass of crystals and intersititial magma, and of undergoing very thorough crushing during introduction. This rook was later very thoroughly altered by hydrothermal solutions which migrated through the fractures in the feldspar rook and new minerals including the titanium minerals—rutile and ilmenite—were introduced. The elements introduced into the feldspathic rock ware TiO 2 FeO, MgO, P 2 O 5 , and F. The other elements that went into the formation of new minerals were derived from the feldspar originally present. There was a distinct order in the abstraction of the introduced elements from the carrying solutions, as shown by the zonal relatione of the secondary minerals. Ferrous iron was abstracted first in the formation of the ferromagnesian silicates and ilmenite. Magnesium and titanium, in the absence of iron, traveled farther from the source of the solutions and deposited rutile and magnesian silicates. At greater distances most of the introduced elements had been abstracted from the solutions but notwithstanding this the feldspar was extensively altered, but without any marked changes between the chemical composition of the original feldspar rook and the resulting altered rook. ©1934. American Geophysical Union. All Rights Reserved.

Virginia↗
USGS1955

Reconnaissance examination of the uranium deposits northeast of Winston, Broadwater County, Montana

Anomalous radioactivity and a yellow secondary uranium mineral tentatively identified as carnotite have been found in Tertiary sedimentary rocks about 3 miles northeast of Winston, Mont. The uranium is in tuffs and tuffaceous shales and particularly in beds rich in organic matter. Carnotite(?) was identified from three localities, principally coating fractures but in places part replacing organic material, and anomalous radioactivity without recognizable uranium minerals has been detected at four localities. Six of the seven localities are at approximately the same stratigraphic horizon. The deposits are virtually unexplored and consequently their size and grade are not known. Selected specimens assay as high as 0.36 percent eU. Exploitable deposits of uranium may be found in this area, as well as in similar areas of western Montana that are underlain by Tertiary tuffaceous rocks.

Trace Elements Memorandum↗
USGS1976

Carbon, hydrogen, and oxygen isotope studies of the regional metamorphic complex at Naxos, Greece

At Naxos, Greece, a migmatite dome is surrounded by schists and marbles of decreasing metamorphic grade. Sillimanite, kyanite, biotite, chlorite, and glaucophane zones are recognized at successively greater distances from the migmatite dome. Quartz-muscovite and quartz-biotite oxygen isotope and mineralogie temperatures range from 350 to 700°C. The metamorphic complex can be divided into multiple schist-rich (including migmatites) and marblerich zones. The δ 18 O values of silicate minerals in migmatite and schist units and quartz segregations in the schist-rich zones decrease with increase in metamorphic grades. The calculated δ 18 O H2O values of the metamorphic fluids in the schist-rich zones decrease from about 15‰ in the lower grades to an average of about 8.5‰ in the migmatite. The δD values of OH-minerals (muscovite, biotite, chlorite, and glaucophane) in the schist-rich zones also decrease with increase in grade. The calculated δD H2O values for the metamorphic fluid decrease from −5‰ in the glaucophane zone to an average of about −70‰ in the migmatite. The δD values of water in fluid inclusions in quartz segregations in the higher grade rocks are consistent with this trend. Theδ 18 O values of silicate minerals and quartz segregations in marble-rich zones are usually very large and were controlled by exchange with the adjacent marbles. The δD values of the OH minerals in some marble-rich zones may reflect the value of water contained in the rocks prior to metamorphism. Detailed data on 20 marble units show systematic variations of δ 18 O values which depend upon metamorphic grade. Below the 540°C isograd very steep δ 18 O gradients at the margins and large δ 18 O values in the interior of the marbles indicate that oxygen isotope exchange with the adjacent schist units was usually limited to the margins of the marbles with more exchange occurring in the stratigraphic bottom than in the top margins. Above the 540°C isograd lower δ 18 O values occur in the interior of the marble units reflecting a greater degree of recrystallization and the occurrence of Ca-Mg-silicates. Almost all the δ 13 C values of the marbles are in the range of unaltered marine limestones. Nevertheless, the δ 13 C values of most marble units show a general correlation with δ 18 O values. The CO 2 H 2 O "> CO 2 H 2 O mole ratio of fluid inclusions in quartz segregations range from 0.01 to 2. Theδ 13 C values of the CO 2 range from −8.0 to 3.6‰ and indicate that at some localities CO 2 in the metamorphic fluid was not in carbon isotopic equilibrium with the marbles.

Geochimica et Cosmochimica Acta↗
USGS1944

"Ribbon rock", an unusual beryllium-bearing tactite

The beryllium deposits at Iron Mountain, near the northern end of the Sierra Cuchillo in Sierra and Socorro Counties, New Mexico, are unusual products of contact metamorphism. They occur in irregular bodies of tactile formed by replacement of Paleozoic limestone, generally at or near contacts with small intrusive masses of rhyolite, aplite, and fine-grained granite. The metamorphism took place in mid-Tertiary time. Beryllium is present chiefly in the complex silicate minerals helvite and danalite, and is a minor constituent of the garnet grossularite, a boron-bearing idocrase, and chlorite. These minerals are known to occur in noteworthy concentrations in only one type of rock, a peculiar rhythmically layered variety of tactile to which the name "ribbon rock" is given. The structure of such tactite is very conspicuous, and appears in section as thin, finely crenulated bands of magnetite alternating with similar bands of silicate minerals and finely crystalline fluorite. Concentric banding about fluorite-rich pod-like masses is common. Bodies of "ribbon rock" range in size from inch-thick lenses to large masses amounting to thousands of tons; most appear to have been formed along contacts between re-crystallized limestone and massive magnetite-andradite tactite, chiefly by replacing fluids penetrating the limestone from fractures. The layered structure is interpreted as a diffusion effect.The formation of massive and "ribbon rock" tactites can be traced through a range of falling temperature from a stage characterized by deposition from iron-rich vapors to a stage in which hydrothermal solutions were dominant. Both vapors and liquids appear to have been acid. Reducing conditions undoubtedly existed during the latter part of the hydrothermal stage. The occurrence of beryllium in "ribbon rock," but not in typical massive tactite, may signify that its compounds in deposits at or near intrusive contacts are confined to rocks of hydrothermal origin. The occurrence of "ribbon rock" is suggested as a potentially useful clue for recognition of beryllium-bearing contact deposits elsewhere; at least two other occurrences of what apparently is "ribbon rock" have been described in the literature.

New Mexico↗
USGS1971

Evolution of thought on ore controls in east Tennessee

All early students of the zinc and barite deposits of East Tennessee, noting the geographic coincidence of the principal mining area with complex late Paleozoic geologic structure, concluded that (1) the ore-bearing breccias were produced by Appalachian tectonic forces and that (2) mineralizing solutions gained access through fault-produced channelways. In 1931, Ulrich suggested that the breccias were produced by collapse and fragmentation resulting from solution of the carbonate rocks. This idea was promptly rejected by most geologists, and for the next 15 years nearly all papers on these deposits contained refutations of Ulrich's hypothesis and "proof" of the late Paleozoic tectonic origin of the breccias. Recognition by Odell in 1950 of a spatial association between thinning of the lime-stone zone of the Kingsport Formation and the presence of ore bodies, plus the observation that all identifiable blocks in the breccias were displaced downward as much as 30 to 50 feet, led him to suggest that foundering of the rocks over solution-thinned zones produced the breccias. Hydrothermal fluids, rather than ordinary ground water, were thought to be the dissolving agent.Kendall, in 1960, described a stratified "varved" matrix with detrital sphalerite grains in many breccias at Jefferson City, in which lamination is parallel to bedding of the host Kingsport Formation, indicating that both brecciation and mineralization occurred while the rocks were horizontal. Ruskell about 1960 pointed out the similarity between cross sections of southwest Wisconsin ore bodies and those of East Tennessee when the latter were rotated to a horizontal position. Detailed studies of the post-Knox unconformity led to recognition of a paleokarst topography of considerable relief developed on this surface. Regional stratigraphic studies of the Knox Group by Harris demonstrated the probability of pre-Middle Ordovician exposure of the Kingsport somewhere to the north or northwest, providing a recharge area for ground waters at that time. Detailed mapping of ore bodies, barren areas, and related structures by the mining-company geologists, plus application of the principles of ground-water hydrology and rock mechanics, has led to the theory, generally accepted in the district, of solution-collapse origin of the breccias, probably during Ordovician time.

Tennessee↗
USGS2005

"Sour gas" hydrothermal jarosite: Ancient to modern acid-sulfate mineralization in the southern Rio Grande Rift

As many as 29 mining districts along the Rio Grande Rift in southern New Mexico contain Rio Grande Rift-type (RGR) deposits consisting of fluorite-barite??sulfide-jarosite, and additional RGR deposits occur to the south in the Basin and Range province near Chihuahua, Mexico. Jarosite occurs in many of these deposits as a late-stage hydrothermal mineral coprecipitated with fluorite, or in veinlets that crosscut barite. In these deposits, many of which are limestone-hosted, jarosite is followed by natrojarosite and is nested within silicified or argillized wallrock and a sequence of fluorite-barite??sulfide and late hematite-gypsum. These deposits range in age from ???10 to 0.4 Ma on the basis of 40Ar/39Ar dating of jarosite. There is a crude north-south distribution of ages, with older deposits concentrated toward the south. Recent deposits also occur in the south, but are confined to the central axis of the rift and are associated with modern geothermal systems. The duration of hydrothermal jarosite mineralization in one of the deposits was approximately 1.0 my. Most ??18OSO4-OH values indicate that jarosite precipitated between 80 and 240 ??C, which is consistent with the range of filling temperatures of fluid inclusions in late fluorite throughout the rift, and in jarosite (180 ??C) from Pen??a Blanca, Chihuahua, Mexico. These temperatures, along with mineral occurrence, require that the jarosite have had a hydrothermal origin in a shallow steam-heated environment wherein the low pH necessary for the precipitation of jarosite was achieved by the oxidation of H2S derived from deeper hydrothermal fluids. The jarosite also has high trace-element contents (notably As and F), and the jarosite parental fluids have calculated isotopic signatures similar to those of modern geothermal waters along the southern rift; isotopic values range from those typical of meteoric water to those of deep brine that has been shown to form from the dissolution of Permian evaporite by deeply circulating meteoric water. Jarosite ??34S values range from -24??? to 5???, overlapping the values for barite and gypsum at the high end of the range and for sulfides at the low end. Most ??34S values for barite are 10.6??? to 13.1???, and many ??34S values for gypsum range from 13.1??? to 13.9??? indicating that a component of aqueous sulfate was derived from Permian evaporites (??34 S=12??2???). The requisite H2SO4 for jarosite formation was derived from oxidation of H2S which was likely largely sour gas derived from the thermochemical reduction of Permian sulfate. The low ??34S values for the precursor H2S probably resulted from exchange deeper in the basin with the more abundant Permian SO42- at ???150 to 200 ??C. Jarosite formed at shallow levels after the pH buffering capacity of the host rock (typically limestone) was neutralized by precipitation of earlier minerals. Some limestone-hosted deposits contain caves that may have been caused by the low pH of the deep basin fluids due to the addition of deep-seated HF and other magmatic gases during periods of renewed rifting. Caves in other deposits may be due to sulfuric acid speleogenesis as a result of H2S incursion into oxygenated groundwaters. The isotopic data in these "sour gas" jarosite occurrences encode a record of episodic tectonic or hydrologic processes that have operated in the rift over the last 10 my. ?? 2004 Elsevier B.V. All rights reserved.

Chemical Geology↗
USGS2017

Using mineral geochemistry to decipher slab, mantle, and crustal input in the generation of high-Mg andesites and basaltic andesites from the northern Cascade Arc

To better understand the role of slab melt in the petrogenesis of North Cascades magmas, this study focuses on petrogenesis of high-Mg lavas from the two northernmost active volcanoes in Washington. High-Mg andesites (HMA) and basaltic andesites (HMBA) in the Cascade Arc have high Mg# [molar Mg/(Mg+Fe 2+ )] relative to their SiO 2 contents, elevated Nd/Yb, and are Ni- and Cr-enriched. The rock units examined here include the Tarn Plateau HMBA (51.8–54.0 wt% SiO 2 , Mg# 68–70) and Glacier Creek HMA (58.3–58.7 wt% SiO 2 , Mg# 63–64) from the Mount Baker Volcanic Field, and the Lightning Creek HMBA (54.8–54.6 SiO 2 , Mg# 69–73) from Glacier Peak. This study combines major and trace element compositions of minerals and whole rocks to test several petrogenetic hypotheses and to determine which, if any, are applicable to North Cascades HMA and HMBA. In the Tarn Plateau HMBA, rare earth element (REE) equilibrium liquids calculated from clinopyroxene compositions have high Nd/Yb that positively correlates with Mg#. This correlation suggests an origin similar to that proposed for Aleutian adakites, where intermediate, high Nd/Yb slab-derived melts interact with the overlying mantle to become Mg-rich, and subsequently mix with low Nd/Yb, mantle-derived mafic magmas with lower Mg#. In the Glacier Creek HMA, elevated whole-rock MgO and SiO 2 contents resulted from accumulation of xenocrystic olivine and differentiation processes, respectively, but the cause of high Nd/Yb is less clear. However, high whole-rock Sr/P (fluid mobile/fluid immobile) values indicate a mantle source that was fluxed by an enriched, hydrous slab component, likely producing the observed high Nd/Yb REE signature. The Lightning Creek HMBA is a hybridized rock unit with at least three identifiable magmatic components, but only one of which has HMA characteristics. Cr and Mg contents in Cr-spinel and olivine pairs in this HMA component suggest that its source is a strongly depleted mantle, and high whole-rock Sr/P values indicate mantle melting that was induced through hydration, likely adding the component responsible for the observed high Nd/Yb REE pattern. The elevated SiO 2 contents (54.6 wt%) of the HMA component resulted from differentiation or high degrees of partial melting of ultramafic material through the addition of H 2 O. Therefore the Lightning Creek HMBA is interpreted to have originated from a refractory mantle source that underwent melting through interaction with an enriched slab component. Our results indicate that in addition to slab-derived fluids, slab-derived melts also have an important role in the production of HMA and HMBA in the north Cascade Arc.

American Mineralogist↗
USGS2014

Succession of Laramide magmatic and magmatic-hydrothermal events in the Patagonia Mountains, Santa Cruz County, Arizona

This investigation of the space-time progression of magmatism and hydrothermal activity in the Patagonia Mountains of southern Arizona is based on field and paragenetic relationships, and on U-Pb and 40 Ar/ 39 Ar geochronology of igneous and hydrothermal minerals. The Patagonia Mountains consist of Precambrian, Paleozoic, and Mesozoic sedimentary, granitic, and volcanic rocks, Laramide volcanic rocks, and a core of Laramide intrusions that comprise the Patagonia Mountains batholith. Laramide igneous rocks and adjacent Paleozoic and Mesozoic rocks contain significant porphyry Cu-Mo deposits, Mo-Cu breccia pipes, Ag replacement deposits, and numerous other Cu-Pb-Zn-Ag replacement and vein deposits. Ages of igneous and hydrothermal minerals from 20 U-Pb and 52 40 Ar/ 39 Ar determinations define four magmatic and magmatic-hydrothermal events that formed the batholith and altered parts of it and adjacent rocks; cumulatively the events span at least 16 m.y., from ~74 to 58 Ma. The oldest event of this succession includes the 74 Ma Washington Camp stock and spatially associated Cu-Pb-Zn-Ag replacement deposits in Paleozoic carbonate rocks of the Washington Camp-Duquesne district. Eruption of 73 to 68 Ma volcanic rocks in the northern part of the range was the next youngest event, which coincides temporally with replacement and vein deposits in Paleozoic carbonate rocks at the Flux mine (~71 Ma). An event at 65 to 62 Ma is marked by emplacement of small-volume quartz monzonite, granodiorite, and diorite intrusions, formation of the Ventura breccia deposit in Jurassic granite at 65 to 64 Ma, and formation of other Pb-Zn-Ag-Cu replacement and vein deposits (~62 Ma; Blue Nose and Morning Glory). The Red Mountain porphyry Cu-Mo system is hosted by ~62 Ma granodiorite and Laramide volcanic rocks (73–68 Ma) at the northern end of the batholith. It includes a deep, chalcopyrite-bornite resource (~60 Ma) that is associated with potassic and sericitic alteration and a near-surface chalcocite-enargite resource (60 Ma) that is associated with advanced, supergene-enriched argillic alteration. The youngest event includes the Sunnyside porphyry Cu-Mo system and a Cu-Mo breccia deposit at Red Hill (Four Metals mine), both of which formed in large-volume quartz monzonite, granodiorite, quartz monzonite porphyry, and quartz feldspar porphyry (~61–59 Ma). Similar to the Red Mountain system, the Sunnyside system consists of a deep chalcopyrite resource that occurs in ~60 to 59 Ma quartz feldspar porphyry, and a near-surface, slightly younger (~59–58 Ma) enargite-chalcocite-tennantite resource that occurs in quartz feldspar porphyry, quartz monzonite porphyry, and Mesozoic rocks. The Red Hill Cu-Mo breccia deposit is hosted by large-volume quartz monzonite, granodiorite, and quartz monzonite porphyry (~61–59 Ma). Discrepancies between field and paragenetic relationships and some analytic ages at Sunnyside and Red Hill preclude precise dating of mineralization stages, and may reflect disturbance of isotope systems by multiple, co-spatial to juxtaposed intrusive and hydrothermal events, and/or by unrecognized intrusions. Numerous vein and replacement deposits at the northern end of the batholith, including the Hardshell Ag resource and the Three R supergene chalcocite resource, are distal deposits of the Sunnyside and Red Mountain systems. Small, ~61 to 59 Ma Cu-Mo deposits in large-volume intrusions in the southern part of the batholith consist of hydrothermal quartz, biotite, K-feldspar, muscovite, chalcopyrite, and molybdenite. The age span of magmatic and magmatic-hydrothermal events in the Patagonia Mountains, minimally 16 m.y., is comparable to that of certain other magmatic-hydrothermal successions that contain porphyry Cu-Mo systems. Magmatic-hydrothermal events of the Wasatch-Oquirrh igneous trend, Utah, and the Boulder batholith, Montana, both span ~17 m.y. and include the Bingham and Butte porphyry Cu-Mo, vein and replacement deposits, respectively. Plutons and mineral deposits in the Pima district, Arizona, which includes the porphyry Cu-Mo deposits at Sierrita-Esperanza, Mission-Pima-San Xavier North, and Twin Buttes, formed over an interval of ~14 m.y. The diversity of igneous and hydrothermal products likely reflects evolutionary processes occurring at multiple sites in the lithosphere and at different time scales from >10 m.y. to less than the geochronologic precision currently achievable.

Arizona↗
USGS2022

Perspectives on premetamorphic stratabound tourmalinites

Stratabound tourmalinites are metallogenically important rocks that locally show a close spatial association with diverse types of mineralization, especially volcanogenic massive sulfides (VMS) and clastic-dominated (CD) Zn-Pb deposits. These tourmalinite occurrences pan the geologic record from Eoarchean to Jurassic. Host lithologies are dominated by clastic metasedimentary rocks but in some areas include metavolcanic rocks, marble, or metaevaporites. Stratabound and stratiform (conformable) tourmalinites commonly display sedimentary structures such as graded beds, cross-beds, and rip-up clasts. In most cases, field and microtextural relationships are consistent with a synsedimentary to the early diagenetic introduction of boron as a precursor to tourmaline formation. Whole-rock geochemical data for major, trace, and rare earth elements (REE) provide valuable insights into tourmalinite origins. Al-normalized values relative to those for least-altered host metasedimentary rocks suggest that tourmalinites in proximal settings at or near hydrothermal vent sites characterized by high fluid/rock regimes (e.g., Sullivan Pb-Zn-Ag deposit, Canada) have very different signatures than those in low fluid/rock, distal settings (e.g., Broken Hill Pb-Zn-Ag deposit, Australia). The high fluid/rock regimes at Sullivan show large mass changes of +60 % for Mg and +180 % for Mn, as well as large variations in abundances of light and middle REE. In contrast, tourmalinite formation in low fluid/rock regimes yields minimal Al-normalized changes in major elements, trace elements, and REE. Boron isotope values of tourmalinite-hosted tourmaline vary widely from -26.1 to +27.5 ‰, and are attributed mainly to boron sources (e.g., sediments, evaporites) with generally minor influence from processes such as formational temperature, fluid/rock ratio, and secular variation in seawater δ 11 B values. Laterally extensive stratiform tourmalinites formed mainly by syngenetic or early diagenetic processes on or beneath the seafloor. The syngenetic process is attributed to the interaction of vented B-rich brines with aluminous minerals in sediments, whereas the diagenetic process involves the selective replacement of aluminous sediments by B-rich fluids. Modern examples of tourmalinites, as yet undiscovered, may exist in metalliferous sediments of the Red Sea and the eastern Pacific Ocean, in altered volcaniclastic sediments within active seafloor-hydrothermal systems of the South Pacific, and in hydrothermal mounds and vents associated with mafic sill complexes in extensional basins as in the North Sea and South China Sea. Stratabound tourmalinites that contain base-metal sulfides, high Mn concentrations (>1 wt. % MnO), or positive Eu anomalies can be valuable exploration guides for base-metal sulfide deposits in sedimentary and volcanic terranes.

Journal of Geosciences↗
USGS1983

Mineral resource potential map of the Benton Range Roadless Area, Mono County, California

Tungsten-bearing rocks in the Benton Range Roadless Area occur in tactite lenses within the Paleozoic metasedimentary units that surround and are intruded by Triassic granodiorite of the Benton Range. High anomalous tungsten values were found in the southern part of the study area. Quartz-vein deposits with copper, lead, zinc, and silver may occur within the Jurassic granitic rock in the northwestern part of the area. Stream-sediment and panned-concentrate samples from the northwestern part of the roadless area, reveal anomalous values in a number of elements. Some of these elements are indicative of mineral suites that form by hydrothermal alteration and are potential metallic-ore producers. Metals having anomalous values are antimony, copper, lead, molybdenum, tin, and zinc; their presence suggests the potential for deposits of the lead-zinc-silver or copper-molybdenum type. Molybdenum and lead were identified by geochemical sampling as having low to moderate potential in the roadless area. An estimated 190,000 tons (172,000 t) of subeconomic gold and silver resources are inside the roadless area at the Gold Crown, Gold Webb, and Gold Wedge mines; another 60,000 tons (54,000 t) of subeconomic gold and silver resources are just outside the area at the Tower, Gold Webb, and Gold Wedge mines (table 1). Most of the lode gold and silver deposits are in quartz veins and shear zones. Minor amounts of copper, lead, and zinc occur in some gold deposits. About 2,240 oz (70 kg) of gold, 8,450 oz (260 kg) of silver, and 4,600 lb of lead (2,090 kg) have been produced from the roadless area. In addition, 7,257 oz (226 kg) of gold and 350 oz (11 kg) silver were produced at the Tower mine, near the area.

California↗
USGS1979

The Yellow Dog peridotite and a possible buried igneous complex of lower Keweenawan age in the northern peninsula of Michigan

Partly serpentinized peridotite of early Keweenawan age crops out in two places along a 20-kilometer-long zone of positive aeromagnetic anomalies in northern Marquette County, Michigan. Most of the area is mantled by Pleistocene drift with few bedrock exposures. Petrographic and electron microprobe studies show that the peridotite was originally a plagioclase lherzolite containing 40 to 50 percent olivine (Fo8 0 ) and approximately 10 to 15 percent each of enstatite (En 78 Wo 04 Fs 18 ) and diopsidic augite (En 47 Wo 42 Fs 11 ). The plagioclase varies from 5 to 10 percent, and according to Morris (1977) is labradorite with a composition of An 57-65 . Major oxide minerals (4 to 6 percent) are ilmenite and magnetite. Sulfides comprise 1 to 2 percent of the peridotite and are chiefly pyrrhotite, pentlandite, and chalcopyrite. Ground magnetic, gravity, and very low frequency electro-magnetic (VLF-EM) surveys have refined the location and magnitude of anomalies previously known only from aeromagnetic studies. These surveys together with soil geochemical studies suggest that peridotite, and possibly other mafic rocks forming a differentiated igneous complex, may occur throughout a belt 20 kilometers long (east-west) and 1 to 2 kilometers wide (north-south). Differentiated igneous complexes in many parts of the world are hosts for copper, nickel, chromium, or precious-metal deposits. The peridotite in the area of this study is anomalously rich in copper and sulfur compared to world-wide averages for peridotite. Positive electro-magnetic anomalies found near the peridotite outcrops may be caused by sulfide-rich zones in the igneous rocks and should be explored further for copper-nickel mineralization.

Michigan↗
USGS1999

Determination of chemical-constituent loads during base-flow and storm-runoff conditions near historical mines in Prospect Gulch, upper Animas River watershed, southwestern Colorado

Prospect Gulch is a major source of iron, aluminum, zinc, and other metals to Cement Creek. Information is needed to prioritize remediation and develop strategies for cleanup of historical abandoned mine sites in Prospect Gulch. Chemical-constituent loads were determined in Prospect Gulch, a high-elevation alpine stream in southwestern Colorado that is affected by natural acid drainage from weathering of hydro-thermally altered igneous rock and acidic metal-laden discharge from historical abandoned mines. The objective of the study was to identify metal sources to Prospect Gulch. A tracer solution was injected into Prospect Gulch during water-quality sampling so that loading of geochemical constituents could be calculated throughout the study reach. A thunderstorm occurred during the tracer study, hence, metal loads were measured for storm-runoff as well as for base flow. Data from different parts of the study reach represents different flow conditions. The beginning of the reach represents background conditions during base flow immediately upstream from the Lark and Henrietta mines (samples PG5 to PG45). Other samples were collected during storm runoff conditions (PG100 to PG291); during the first flush of metal runoff following the onset of rainfall (PG303 to PG504), and samples PG542 to PG700 were collected during low-flow conditions. During base-flow conditions, the percentage increase in loads for major constituents and trace metals was more than an order of magnitude greater than the corresponding 36 % increase in stream discharge. Within the study reach, the highest percentage increases for dissolved loads were 740 % for iron (Fe), 465 % for aluminum (Al), 500 % for lead (Pb), 380 % for copper (Cu), 100 % for sulfate (SO4), and 50 % for zinc (Zn). Downstream loads near the mouth of Prospect Gulch often greatly exceeded the loads generated within the study reach but varied by metal species. For example, the study reach accounts for about 6 % of the dissolved-Fe load, 13 % of the dissolved-Al load, and 18 % of the dissolved-Zn load; but probably contributes virtually all of the dissolved Cu and Pb. The greatest downstream gains in dissolved trace-metal loads occurred near waste-rock dumps for the historical mines. The major sources of trace metals to the study reach were related to mining. The major source of trace metals in the reach near the mouth is unknown, however is probably related to weathering of highly altered igneous rocks, although an unknown component of trace metals could be derived from mining sources The late-summer storm dramatically increased the loads of most dissolved and total constituents. The effects of the storm were divided into two distinct periods; (1) a first flush of higher metal concentrations that occurred soon after rainfall began and (2) the peak discharge of the storm runoff. The first flush contained the highest loads of dissolved Fe, total and dissolved Zn, Cu, and Cd. The larger concentrations of Fe and sulfate in the first flush were likely derived from iron hydroxide minerals such as jarosite and schwertmanite, which are common on mine dumps in the Prospect Gulch drainage basin. Peak storm runoff contained the highest measured loads of total Fe, and of total and dissolved calcium, magnesium, silica and Al, which were probably derived from weathering of igneous rocks and clay minerals in the drainage basin.

Colorado↗
USGS2011

Ages and sources of components of Zn-Pb, Cu, precious metal, and platinum group element deposits in the goodsprings district, Clark County, Nevada

The Goodsprings district, Clark County, Nevada, includes zinc-dominant carbonate replacement deposits of probable late Paleozoic age, and lead-dominant carbonate replacement deposits, copper ± precious metal-platinum group element (PGE) deposits, and gold ± silver deposits that are spatially associated with Late Triassic porphyritic intrusions. The district encompasses ~500 km 2 although the distribution of all deposits has been laterally condensed by late Mesozoic crustal contraction. Zinc, Pb, and Cu production from about 90 deposits was ~160,000 metric tons (t) (Zn > Pb >> Cu), 2.1 million ounces (Moz) Ag, 0.09 Moz Au, and small amounts of PGEs—Co, V, Hg, Sb, Ni, Mo, Mn, Ir, and U—were also recovered. Zinc-dominant carbonate replacement deposits (Zn > Pb; Ag ± Cu) resemble Mississippi Valley Type (MVT) Zn-Pb deposits in that they occur in karst and fault breccias in Mississippian limestone where the southern margin of the regional late Paleozoic foreland basin adjoins Proterozoic crystalline rocks of the craton. They consist of calcite, dolomite, sphalerite, and galena with variably positive S isotope compositions ( δ 34 S values range from 2.5–13‰), and highly radiogenic Pb isotope compositions ( 206 Pb/ 204 Pb >19), typical of MVT deposits above crystalline Precambrian basement. These deposits may have formed when southward flow of saline fluids, derived from basinal and older sedimentary rocks, encountered thinner strata and pinch-outs against the craton, forcing fluid mixing and mineral precipitation in karst and fault breccias. Lead-dominant carbonate replacement deposits (Pb > Zn, Ag ± Cu ± Au) occur among other deposit types, often near porphyritic intrusions. They generally contain higher concentrations of precious metals than zinc-dominant deposits and relatively abundant iron oxides after pyrite. They share characteristics with copper ± precious metal-PGE and gold ± silver deposits including fine-grained quartz replacement of carbonate minerals in ore breccias and relatively low S and Pb isotope values ( δ 34 S values vary from 0–~4‰; 206 Pb/ 204 Pb <18.5). Copper ± precious metal-PGE deposits (Cu, Co, Ag, Au, Pd, and Pt) consist of Cu carbonate minerals (after chalcocite and chalcopyrite) and fine-grained quartz that have replaced breccia clasts and margins of fissures in Paleozoic limestones and dolomites near porphyritic intrusions. Gold ± silver deposits occur along contacts and within small-volume stocks and dikes of feldspar porphyry, one textural variety of porphyritic intrusions. Lead isotope compositions of copper ± precious metal-PGE, gold ± silver, and lead-dominant carbonate replacement deposits are similar to those of Mojave crust plutons, indicating derivation of Pb from 1.7 Ga crystalline basement or from Late Proterozoic siliciclastic sedimentary rocks derived from 1.7 Ga crystalline basement. Four texturally and modally distinctive porphyritic intrusions are exposed largely in the central part of the district: feldspar quartz porphyry, plagioclase quartz porphyry, feldspar biotite quartz porphyry, and feldspar porphyry. Intrusions consist of 64 to 70 percent SiO 2 and variable K 2 O/Na 2 O (0.14–5.33) that reflect proportions of K-feldspar and albite phenocrysts and megacrysts as well as partial alteration to K-mica; quartz and biotite phenocrysts are present in several subtypes. Albite may have formed during emplacement of magma in brine-saturated basinal strata, whereas hydrothermal alteration of matrix, phenocrystic, and megacrystic feldspar and biotite to K-mica, pyrite, and other hydrothermal minerals occurred during and after intrusion emplacement. Small volumes of garnet-diopside-quartz and retrograde epidote-mica-amphibole skarn have replaced carbonate rocks adjacent to one intrusion subtype (feldspar-quartz porphyry), but alteration of carbonate rocks at intrusion contacts elsewhere is inconspicuous. Uranium-lead ages of igneous zircons vary inconsistently from ~ 180 to 230 Ma and are too imprecise to distinguish age differences among intrusion subtypes; most ages are 210 to 225 Ma, yielding a mean of 217 ± 1 Ma. K-Ar and 40 Ar/ 39 Ar ages of magmatic (plagioclase, biotite) and hydrothermal (K-mica) minerals span a similar range (183–227 Ma), demonstrating broadly contemporaneous intrusion emplacement and hydrothermal alteration but allowing for multiple Late Triassic magmatic-hydrothermal events. Imprecision and range of isotopic ages may have resulted from burial beneath Mesozoic and Tertiary strata and multiple intrusion of magmas, causing thermal disturbance to Ar systems and Pb loss from zircons in intrusions. Separate late Paleozoic (zinc-dominant carbonate replacement deposits) and Late Triassic (all other deposits) mineralizing events are supported by form, distribution, and host rocks of metal deposits, by hydrothermal mineral assemblages, isotope compositions, metal abundances, and metal diversity, and by small intrusion volumes. These characteristics collectively distinguish the Goodsprings district from larger intrusion related carbonate replacement districts in the western United States. They can be used to evaluate proximity to unexposed porphyritic intrusions associated with PGE and gold ± silver mineralization.

Nevada↗
USGS1979

Detection and mapping of hydrothermally altered rocks in the vicinity of the Comstock Lode, Virginia Range, Nevada, using enhanced Landsat images

The Virginia Range, immediately southeast of Reno, Nev., consists mainly of flows, breccias, and turfs of Miocene age. Most of these volcanic rocks are of intermediate composition; rhyodacite is the most common rock type. Basalt, rhyolite and rhyolite tuff, and tuffaceous sedimentary rocks of Miocene and Pliocene age also cover substantial areas in the range. Pre-Tertiary metasedimentary, metavolcanic, and granitic rocks are exposed in scattered inliers, mostly along the southern and eastern margins of the range. Several large areas and many small areas within the volcanic pile were subjected to hydrothermal alteration during and after the period of intermediate volcanic activity. Economic precious metal mineralization is spatially and temporally associated with the hydrothermal alteration in several areas. The most important deposit is the Comstock Lode, which produced 192 million troy ounces of silver and 8.3 million troy ounces of gold from epithermal veins (Bonham, 1969). The hydrothermally altered rocks include silicified, advanced argillic, montmorillonite-bearing argillic, and propylitic types. The first three types typically contain pyrite, and some propylitic rocks contain pyrite as well. Supergene oxidation of these pyritic rocks produces limonitic bleached rocks. The term 'limonite,' as used here, refers to any combination of the minerals hematite, goethite, and Jarosite. Where vegetation cover is sparse to moderate, these limonitic rocks are readily identified on Landsat images enhanced by the color-ratio composite technique developed by Rowan and others (1974), so the altered areas can be mapped. About 30 percent tree cover (here mainly pinyon pine) is sufficient to change the spectral signature of individual picture elements (pixels) enough so that limonitic materials can no longer be uniquely identified. As in all other areas where this technique has been applied, limonitic unaltered rocks with intermediate to high albedos have the same appearance on the color-ratio composite as limonitic altered rocks. This problem represents the most important limitation to the use of enhanced Landsat images for detection and mapping of hydrothermally altered rocks. Reflectance spectra of altered and unaltered rocks taken in the field in the Virginia Range show that most altered rocks have a conspicuous absorption band near 2.2 ?m produced by clay minerals or alunite, whereas unaltered rocks have no features in this spectral region. Thus spectral information for selected bands in the 1.1-2.5 ?m region may allow discrimination between limonitic altered and limonitic unaltered rocks (Rowan and others, 1977; Abrams and others, 1977; Rowan and Abrams, 1978). Another potential limitation is loss of spectral information on slopes with low effective sun angle. Although a minor problem in the Virginia Range, loss of information sufficient to preclude identification of limonitic altered rocks occurs with effective sun angle lower than 20-25 degrees. Thus, even at moderate latitudes substantial parts of areas with high topographic relief may be lost to observation.

Open-File Report↗
USGS2021

Hydrothermal alteration can result in pore pressurization and volcano instability

The collapse of a volcanic flank can be destructive and deadly. Hydrothermal alteration is common to volcanoes worldwide and is thought to promote volcano instability by decreasing rock strength. However, some laboratory studies have shown that not all alteration reduces rock strength. Our new laboratory data for altered rhyodacites from Chaos Crags (Lassen volcanic center, California, USA) show that pore- and crack-filling mineral precipitation can reduce porosity and permeability and increase strength, Young's modulus, and cohesion. A significant reduction in permeability, by as much as four orders of magnitude, will inhibit fluid circulation and create zones of high pore fluid pressure. We explored the consequences of pore fluid pressurization on volcano stability using large-scale numerical modeling. Upscaled physical and mechanical properties for hydrothermally altered rocks were used as input parameters in our modeling. Results show that a high-pore-pressure zone within a volcano increases volcano deformation and that increasing the size of this zone increases the observed deformation. Hydrothermal alteration associated with mineral precipitation, and increases to rock strength, can therefore promote pore pressurization and volcano deformation, increasing the likelihood of volcano spreading, flank collapses, and phreatic/phreatomagmatic explosions. We conclude that porosity-decreasing alteration, explored here, and porosity-increasing alteration can both promote volcano instability and collapse, but by different mechanisms. Hydrothermal alteration should therefore be monitored at volcanoes worldwide and incorporated into hazard assessments.

Geology↗