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At least 1,567 records · Page 87Linked to original sources

USGS2008

Water Resources of the Basin and Range Carbonate-Rock Aquifer System, White Pine County, Nevada, and Adjacent Areas in Nevada and Utah

INTRODUCTION This report summarizes results of a water-resources study for White Pine County, Nevada, and adjacent areas in east-central Nevada and western Utah. The Basin and Range carbonate-rock aquifer system (BARCAS) study was initiated in December 2004 through Federal legislation (Section 301(e) of the Lincoln County Conservation, Recreation, and Development Act of 2004; PL108-424) directing the Secretary of the Interior to complete a water-resources study through the U.S. Geological Survey, Desert Research Institute, and State of Utah. The study was designed as a regional water-resource assessment, with particular emphasis on summarizing the hydrogeologic framework and hydrologic processes that influence ground-water resources. The study area includes 13 hydrographic areas that cover most of White Pine County; in this report however, results for the northern and central parts of Little Smoky Valley were combined and presented as one hydrographic area. Hydrographic areas are the basic geographic units used by the State of Nevada and Utah and local agencies for water-resource planning and management, and are commonly defined on the basis of surface-water drainage areas. Hydrographic areas were further divided into subbasins that are separated by areas where bedrock is at or near the land surface. Subbasins are the subdivisions used in this study for estimating recharge, discharge, and water budget. Hydrographic areas are the subdivision used for reporting summed and tabulated subbasin estimates.

Scientific Investigations Report↗

USGS2023

Yellowstone Volcano Observatory 2022 annual report

The Yellowstone Volcano Observatory (YVO) monitors volcanic and hydrothermal activity associated with the Yellowstone magmatic system, carries out research into magmatic processes occurring beneath Yellowstone Caldera, and issues timely warnings and guidance related to potential future geologic hazards. This report summarizes the activities and findings of YVO during the year 2022, focusing on the Yellowstone volcanic system. Highlights of YVO research and related activities during 2022 include deployments of seismometers in Norris Geyser Basin and Upper Geyser Basin to investigate interactions between hydrothermal features and influences from external influences, geological studies of post-glacial hydrothermal activity, refining the ages of Yellowstone volcanic units and updating existing maps of geologic deposits, new mapping of ash-flow deposits on the Sour Creek dome, installation of a new continuous gas monitoring station near Mud Volcano, sampling of gas emissions and thermal waters around Yellowstone National Park to monitor water chemistry over space and time, research into the age and history of Steamboat Geyser in Norris Geyser Basin, and assessment of thermal output based on satellite imagery and chloride flux in rivers. The most noteworthy event of the year was not geophysical, but meteorological. Combined runoff from rain and snowmelt caused substantial flooding in Yellowstone National Park, which caused damage to park roads and infrastructure. Steamboat Geyser, in Norris Geyser Basin, continued the pattern of frequent eruptions that began in 2018 with 11 water eruptions in 2022, the lowest number of annual eruptions in the current eruptive sequence. Total seismicity—2,429 located earthquakes—was slightly less than the 2,773 earthquakes located in 2021 and at the upper end of the historical average range of about 1,500–2,500 earthquakes per year. Overall subsidence of the caldera floor, ongoing since late 2015 or early 2016, continued at rates of a few centimeters (1–2 inches) per year. Satellite deformation measurements indicated the possibility of slight uplift amounting to about 1 centimeter (less than 1 inch) along the north caldera rim in 2021, but satellite data spanning 2022 show no uplift in that area. Throughout 2022, the aviation color code for Yellowstone Caldera remained at “green” and the volcano alert level remained at “normal.”

Wyoming↗

USGS1984

U. S. GEOLOGICAL SURVEY MARINE-MINERALS RESEARCH.

Summary form only given. The US Exclusive Economic Zone is an area approximately one and two-thirds the size of the land area of the United States. In this frontier area, US Geological Survey (USGS) research in marine minerals is aimed at three objectives: (1) defining geologic settings of potential mineral resources; (2) understanding the processes by which seafloor nonliving resources form; and (3) estimating the resource potential. Potential resources of primary interest are cobalt-rich manganese seafloor crusts, polymetallic sulfides in hydrothermal vent areas on the seafloor, and heavy-mineral placer deposits. Research activities include studies of manganese-crust samples from oceanographic-institution archives and a USGS research cruise through the central and southern Pacific. Preliminary results confirm that cobalt is concentrated by as much as 2. 5% in the manganese crusts at water depths of 1000-2600 m; further research on the precipitation processes and patterns of crust formation will be needed to understand the origin, occurrence patterns, and resource potential of these crusts. Research cruises have revealed a zone of polymetallic sulfide vent deposits a few hundred meters long in the Juan de Fuca spreading center.

Conference Paper↗

USGS2008

High-Resolution Digital Terrain Models of the Sacramento/San Joaquin Delta Region, California

The U.S. Geological Survey (USGS) Western Region Geographic Science Center, in conjunction with the USGS Water Resources Western Branch of Regional Research, has developed a high-resolution elevation dataset covering the Sacramento/San Joaquin Delta region of California. The elevation data were compiled photogrammically from aerial photography (May 2002) with a scale of 1:15,000. The resulting dataset has a 10-meter horizontal resolution grid of elevation values. The vertical accuracy was determined to be 1 meter. Two versions of the elevation data are available: the first dataset has all water coded as zero, whereas the second dataset has bathymetry data merged with the elevation data. The projection of both datasets is set to UTM Zone 10, NAD 1983. The elevation data are clipped into files that spatially approximate 7.5-minute USGS quadrangles, with about 100 meters of overlap to facilitate combining the files into larger regions without data gaps. The files are named after the 7.5-minute USGS quadrangles that cover the same general spatial extent. File names that include a suffix (_b) indicate that the bathymetry data are included (for example, sac_east versus sac_east_b). These files are provided in ESRI Grid format.

Data Series↗

USGS2016

Potential effects of drought on carrying capacity for wintering waterfowl in the Central Valley of California

We used the bioenergetics model TRUEMET to evaluate potential effects of California's recent drought on food supplies for waterfowl wintering in the Central Valley under a range of habitat and waterfowl population scenarios. In nondrought years in the current Central Valley landscape, food supplies are projected to be adequate for waterfowl from fall through early spring (except late March) even if waterfowl populations reach North American Waterfowl Management Plan goals. However, in all drought scenarios that we evaluated, food supplies were projected to be exhausted for ducks by mid- to late winter and by late winter or early spring for geese. For ducks, these results were strongly related to projected declines in winter-flooded rice fields that provide 45% of all the food energy available to ducks in the Central Valley in nondrought water years. Delayed flooding of some managed wetlands may help alleviate food shortages by providing wetland food resources better timed with waterfowl migration and abundance patterns in the Central Valley, as well as reducing the amount of water needed to manage these habitats. However, future research is needed to evaluate the impacts of delayed flooding on waterfowl hunting, and whether California's existing water delivery system would make delayed flooding feasible. Securing adequate water supplies for waterfowl and other wetland-dependent birds is among the greatest challenges facing resource managers in coming years, especially in the increasingly arid western United States.

Journal of Fish and Wildlife Management↗

USGS2007

Soil moisture sensors for continuous monitoring

Certain physical and chemical properties of soil vary with soil water content. The relationship between these properties and water content is complex and involves both the pore structure and constituents of the soil solution. One of the most economical techniques to quantify soil water content involves the measurement of electrical resistance of a dielectric medium that is in equilibrium with the soil water content. The objective of this research was to test the reliability and accuracy of fiberglass soil-moisture electrical resistance sensors (ERS) as compared to gravimetric sampling and Time Domain Reflectometry (TDR). The response of the ERS was compared to gravimetric measurements at eight locations on the USDA-ABS Walnut Gulch Experimental Watershed. The comparisons with TDR sensors were made at three additional locations on the same watershed. The high soil rock content (>45 percent) at seven locations resulted in consistent overestimation of soil water content by the ERS method. Where rock content was less than 10 percent, estimation of soil water was within 5 percent of the gravimetric soil water content. New methodology to calibrate the ERS sensors for rocky soils will need to be developed before soil water content values can be determined with these sensors. (KEY TERMS: soil moisture; soil water; infiltration; instrumentation; soil moisture sensors.)

Arizona↗

USGS2023

Bioavailability of dissolved organic matter varies with anthropogenic landcover in the Upper Mississippi River Basin

Anthropogenic conversion of forests and wetlands to agricultural and urban landcovers impacts dissolved organic matter (DOM) within streams draining these catchments. Research on how landcover conversion impacts DOM molecular level composition and bioavailability, however, is lacking. In the Upper Mississippi River Basin (UMRB), water from low-order streams and rivers draining one of three dominant landcovers (forest, agriculture, urban) was incubated for 28 days to determine bioavailable DOC (BDOC) concentrations and changes in DOM composition. The BDOC concentration averaged 0.49 ± 0.30 mg L −1 across all samples and was significantly higher in streams draining urban catchments (0.72 ± 0.34 mg L −1 ) compared to streams draining agricultural (0.28 ± 0.15 mg L −1 ) and forested (0.47 ± 0.17 mg L −1 ) catchments. Percent BDOC was significantly greater in urban (10% ± 4.4%) streams compared to forested streams (5.6% ± 3.2%), corresponding with greater relative abundances of aliphatic and N-containing aliphatic compounds in urban streams. Aliphatic compound relative abundance decreased across all landcovers during the bioincubation (average -4.1% ± 10%), whereas polyphenolics and condensed aromatics increased in relative abundance across all landcovers (average of +1.4% ± 5.9% and +1.8% ± 10%, respectively). Overall, the conversion of forested to urban landcover had a larger impact on stream DOM bioavailability in the UMRB compared to conversion to agricultural landcover. Future research examining the impacts of anthropogenic landcover conversion on stream DOM composition and bioavailability needs to be expanded to a range of spatial scales and to different ecotones, especially with continued landcover alterations.

Minnesota, Iowa, North Dakota, South Dakota, Wisco↗

USGS2018

Contaminants of emerging concern in urban stormwater: Spatiotemporal patterns and removal by iron-enhanced sand filters (IESFs)

Numerous contaminants of emerging concern (CECs) typically occur in urban rivers. Wastewater effluents are a major source of many CECs. Urban runoff (stormwater) is a major urban water budget component and may constitute another major CEC pathway. Yet, stormwater-based CEC field studies are rare. This research investigated 384 CECs in 36 stormwater samples in Minneapolis-St. Paul, Minnesota, USA. Nine sampling sites included three large stormwater conveyances (pipes) and three paired iron-enhanced sand filters (IESFs; untreated inlets and treated outlets). The 123 detected compounds included commercial-consumer compounds, veterinary and human pharmaceuticals, lifestyle and personal care compounds, pesticides, and others. Thirty-one CECs were detected in ≥50% of samples. Individual samples contained a median of 35 targeted CECs (range: 18–54). Overall, median concentrations were ≥10 ng/L for 25 CECs and ≥100 ng/L for 9 CECs. Ranked, hierarchical linear modeling indicated significant seasonal- and site type-based concentration variability for 53 and 30 CECs, respectively, with observed patterns corresponding to CEC type, source, usage, and seasonal hydrology. A primarily warm-weather, diffuse, runoff-based profile included many herbicides . A second profile encompassed winter and/or late summer samples enriched with some recalcitrant, hydrophobic compounds (e.g., PAHs), especially at pipes, suggesting conservative, less runoff-dependent sources (e.g., sediments). A third profile, indicative of mixed conservative/non-runoff, runoff, and/or atmospheric sources and transport that collectively affect a variety of conditions, included various fungicides, lifestyle, non-prescription, and commercial-consumer CECs. Generally, pipe sites had large, diverse land-use catchments, and showed more frequent detections of diverse CECs, but often at lower concentrations; while untreated sites (with smaller, more residential-catchments) demonstrated greater detections of “pseudo-persistent” and other ubiquitous or residentially-associated CECs. Although untreated stormwater transports an array of CECs to receiving waters, IESF treatment significantly removed concentrations of 14 (29%) of the 48 most detected CECs; for these, median removal efficiencies were 26%–100%. Efficient removal of some hydrophobic (e.g., PAHs, bisphenol A) and polar-hydrophilic (e.g., caffeine, nicotine) compounds indicated particulate-bound contaminant filtration and for certain dissolved contaminants, sorption.

Minnesota↗

USGS2011

Forecast Mekong: navigating changing waters

The U.S. Geological Survey (USGS) is using research and data from the Mekong River Delta in Southeast Asia to compare restoration, conservation, and management efforts there with those done in other major river deltas, such as the Mississippi River Delta in the United States. The project provides a forum to engage regional partners in the Mekong Basin countries to share data and support local research efforts. Ultimately, Forecast Mekong will lead to more informed decisions about how to make the Mekong and Mississippi Deltas resilient in the face of climate change, economic stresses, and other impacts.

General Information Product↗

USGS2001

Methods of analysis by the U.S. Geological Survey Organic Geochemistry Research Group--Update and additions to the determination of chloroacetanilide herbicide degradation compounds in water using high-performance liquid chromatography/mass spectrometry

An analytical method using high-performance liquid chromatography/mass spectrometry (HPLC/MS) was developed by the U.S. Geological Survey in 1999 for the analysis of selected chloroacetanilide herbicide degradation compounds in water. These compounds were acetochlor ethane sulfonic acid (ESA), acetochlor oxanilic acid (OXA), alachlor ESA, alachlor OXA, metolachlor ESA, and metolachlor OXA. The HPLC/MS method was updated in 2000, and the method detection limits were modified accordingly. Four other degradation compounds also were added to the list of compounds that can be analyzed using HPLC/MS; these compounds were dimethenamid ESA, dimethenamid OXA, flufenacet ESA, and flufenacet OXA. Except for flufenacet OXA, good precision and accuracy were demonstrated for the updated HPLC/MS method in buffered reagent water, surface water, and ground water. The mean HPLC/MS recoveries of the degradation compounds from water samples spiked at 0.20 and 1.0 g/L (microgram per liter) ranged from 75 to 114 percent, with relative standard deviations of 15.8 percent or less for all compounds except flufenacet OXA, which had relative standard deviations ranging from 11.3 to 48.9 percent. Method detection levels (MDL's) using the updated HPLC/MS method varied from 0.009 to 0.045 ?g/L, with the flufenacet OXA MDL at 0.072 g/L. The updated HPLC/MS method is valuable for acquiring information about the fate and transport of the parent chloroacetanilide herbicides in water.

Open-File Report↗

USGS2015

Water data to answer urgent water policy questions: Monitoring design, available data and filling data gaps for determining the effectiveness of agricultural management practices for reducing tributary nutrient loads to Lake Erie -- Addendum describing new, expanded, and planned monitoring sites

This Addendum describes new, expanded, and planned water monitoring sites in the Lake Erie drainage basin that were initiated subsequent to the preparation of Betanzo et al. (2015), the primary report with which this Addendum is associated. In addition to the new water monitoring sites, new programs have been initiated that focus on expansion of agricultural management practices to reduce nutrient transport to Lake Erie and facilitate data sharing between researchers involved with agricultural management and water-quality monitoring. This Addendum evaluates the applicability of these new monitoring sites and programs for answering the case-study policy question explored in Betanzo et al. (2015), “How effective are agricultural management practices at reducing nutrients from nonpoint sources at the watershed scale in the Lake Erie drainage basin?” The water monitoring data needs for answering the case-study policy question identified in Table 18 of Betanzo et al. (2015) were used to identify relevant monitoring sites in this Addendum, specifically focusing on total phosphorus (TP), dissolved reactive phosphorus (DRP)1 , and streamflow data (the complete list of parameters needed appears in Table 3 of Betanzo et al. (2015)). The new information summarized in this Addendum consists of water monitoring and agricultural management activities conducted by agencies and organizations whose data were compiled in the nutrient data set described in Betanzo et al. (2015), and programs identified in public news releases. Although this information is considered to be comprehensive and complete as of February 2015, there may be other new or planned water monitoring programs, of which we are not aware, that are not included here.

Indiana, Michigan, New York, Ohio, Pennsylvania↗

USGS1997

Southern Laurentide ice lobes were created by ice streams: Des Moines Lobe in Minnesota, USA

Regional mapping in southern Minnesota has illuminated a suite of landforms developed by the Des Moines Lobe that delimit the position of the lobe at its maximum and at lesser readvances. The ice lobe repeatedly advanced, discharged its subglacial water, and subsequently stagnated. Recent glaciological research on Antarctic ice streams has led some glacial geologists to postulate that ice streams drained parts of the marine-based areas of the Laurentide Ice Sheet. I postulate that such ice streams may develop in land-based areas of an ice sheet as well, and that the Des Moines Lobe, 200 km wide and 900 km long, was an outlet glacier of an ice stream. It appears to have been able to advance beyond the Laurentide Ice Sheet as long as adequate water pressure was maintained. However, the outer part of the lobe stagnated because subglacial water that facilitated the flow was able to drain away through tunnel valleys. Stagnation of the lobe is not equivalent to stoppage of the ice stream, because ice repeatedly advanced into and onto the stagnant margins, stacking ice and debris. Similar landforms are also seen in other lobes of the upper midwestern United States.

Minnesota↗

USGS2021

Consequences of changing water clarity on the fish and fisheries of the Laurentian Great Lakes

Human-driven environmental change underlies recent changes in water clarity in many of the world’s great lakes, yet our understanding of the consequences of these changes on the fish and fisheries they support remains incomplete. Herein, we offer a framework to organize current knowledge, guide future research, and help fisheries managers understand how water clarity can affect their valued populations. Emphasizing Laurentian Great Lakes findings where possible, we describe how changing water clarity can directly affect fish populations and communities by altering exposure to ultraviolet radiation, foraging success, predation risk, reproductive behavior, or territoriality. We also discuss how changing water clarity can affect fisheries harvest and assessment through effects on fisher behavior and sampling efficiency (i.e., catchability). Finally, we discuss whether changing water clarity can affect understudied aspects of fishery performance, including economic and community benefits. We conclude by identifying generalized predictions and discuss their implications for priority research questions for the Laurentian Great Lakes. Even though the motivation for this work was regional, the breadth of the review and generality of the framework are readily transferable to other freshwater and marine habitats.

Great Lakes↗

USGS2003

Heat as a tool for studying the movement of ground water near streams

Stream temperature has long been recognized as an important water quality parameter. Temperature plays a key role in the health of a stream’s aquatic life, both in the water column and in the benthic habitat of streambed sediments. Many fish are sensitive to temperature. For example, anadromous salmon require specific temperature ranges to successfully develop, migrate, and spawn [see Halupka and others, 2000]. Metabolic rates, oxygen requirements and availability, predation patterns, and susceptibility of organisms to contaminants are but a few of the many environmental responses regulated by temperature. Hydrologists traditionally treated streams and ground water as distinct, independent resources to be utilized and managed separately. With increasing demands on water supplies, however, hydrologists realized that streams and ground water are parts of a single, interconnected resource [see Winter and others, 1998]. Attempts to distinguish these resources for analytical or regulatory purposes are fraught with difficulty because each domain can supply (or drain) the other, with attendant possibilities for contamination exchange. Sustained depletion of one resource usually results in depletion of the other, propagating adverse effects within the watershed. An understanding of the interconnections between surface water and ground water is therefore essential. This understanding is still incomplete, but receiving growing attention from the research community. Exchanges between streams and shallow ground-water systems play a key role in controlling temperatures not only in streams, but also in their underlying sediments. As a result, analyses of subsurface temperature patterns provide information about surface-water/ground-water interactions. Chemical tracers are commonly used for tracing flow between streams and ground water. Introduction of chemical tracers in near-stream environments is, however, limited by real and perceived issues regarding introduced contamination and practical constraints. As an alternative, naturally occurring variations in temperature can be used to track (or trace) the heat carried by flowing water. The hydraulic transport of heat enables its use as a tracer. Differences between temperatures in the stream and surrounding sediments are now being analyzed to trace the movement of ground water to and from streams. As shown in the subsequent chapters of this circular, tracing the transport of heat leads to a better understanding of the magnitudes and mechanisms of stream/ground-water exchanges, and helps quantify the resulting effects on stream and streambed temperatures. Chapter 1 describes the general principals and procedures by which the natural transport of heat can be utilized to infer the movement of subsurface water near streams. This information sets the foundation for understanding the advanced applications in chapters 2 through 8. Each of these chapters provides a case study, using heat tracing as a tool, of interactions between surface water and ground water for a different location in the western United States. Technical details of the use of heat as an environmental tracer appear in appendices.

Circular↗

USGS1987

Some aspects of U.S. Geological Survey activities related to the effects of contaminants on water resources

The U.S. Geological Survey 's water resources programs are supported by direct annual appropriations from Congress, the Federal-State Cooperative Program (50:50 matching of funds), and by funds provided by other Federal agencies. For fiscal year 1987, total obligations exceeded $250 million for activities in every State, Puerto Rico, and several territories in cooperation with nearly 1,000 local, State, regional, and other Federal agencies. The quality of the ground and surface waters has been of concern to the Geological Survey from the time it was established. During the past few years, water resources contamination has received highest priority consideration and a variety of investigations and research are ongoing to obtain an improved understanding of the Nation 's water quality and the factors affecting it. This report presents information on program priorities and discusses the coordinated activities focusing on the effects of contaminants on water resources. The report also describes a number of investigations and research activities in progress during fiscal years of 1986 and 1987, and provides guidance on how to obtain additional details. (Author 's abstract)

Open-File Report↗

USGS1996

Hydrology and geochemistry of aquifer and stream contamination related to acidic water in Pinal Creek basin near Globe, Arizona

Hydrologic and geochemical research has identified and characterized the physical and chemical processes that control the evolution and movement of metal contaminants in ground water beneath Miami Wash and lower Pinal Creek. The dissolution of calcite in the alluvial aquifer has slowed and neutralized part of the acidic plume, and the sorption of some metals such as nickel and copper to other solids in the subsurface has lowered concentrations of these metals in the ground water.

Arizona↗

USGS2011

Shifting species interactions in terrestrial dryland ecosystems under altered water availability and climate change

Species interactions play key roles in linking the responses of populations, communities, and ecosystems to environmental change. For instance, species interactions are an important determinant of the complexity of changes in trophic biomass with variation in resources. Water resources are a major driver of terrestrial ecology and climate change is expected to greatly alter the distribution of this critical resource. While previous studies have documented strong effects of global environmental change on species interactions in general, responses can vary from region to region. Dryland ecosystems occupy more than one-third of the Earth's land mass, are greatly affected by changes in water availability, and are predicted to be hotspots of climate change. Thus, it is imperative to understand the effects of environmental change on these globally significant ecosystems. Here, we review studies of the responses of population-level plant-plant, plant-herbivore, and predator-prey interactions to changes in water availability in dryland environments in order to develop new hypotheses and predictions to guide future research. To help explain patterns of interaction outcomes, we developed a conceptual model that views interaction outcomes as shifting between (1) competition and facilitation (plant-plant), (2) herbivory, neutralism, or mutualism (plant-herbivore), or (3) neutralism and predation (predator-prey), as water availability crosses physiological, behavioural, or population-density thresholds. We link our conceptual model to hypothetical scenarios of current and future water availability to make testable predictions about the influence of changes in water availability on species interactions. We also examine potential implications of our conceptual model for the relative importance of top-down effects and the linearity of patterns of change in trophic biomass with changes in water availability. Finally, we highlight key research needs and some possible broader impacts of our findings. Overall, we hope to stimulate and guide future research that links changes in water availability to patterns of species interactions and the dynamics of populations and communities in dryland ecosystems.

Biological Reviews↗

USGS2006

Response to comment on “Persistence of pharmaceutical compounds and other organic wastewater contaminants in a conventional drinking-water-treatment plant”

The U.S. Geological Survey (USGS) and the Centers for Disease Control thank Dr. Till for her comments concerning our research ( Till, 2005 ) and welcome the opportunity to respond. The primary objective of our study was to evaluate the potential for organic wastewater-related contaminants (OWCs), including pharmaceuticals, to survive a conventional drinking-water-treatment process and persist in potable-water supplies ( Stackelberg et al., 2004 ). Our study was supported by two USGS laboratories: the National Water Quality Laboratory (NWQL), which provided the HPLC/ESI-MS and CLLE GC/MS data and the Ocala Water Quality and Research Laboratory (OWQRL), which provided the LC/MS data ( Stackelberg et al., 2004 ). Although discussed as distinct techniques by Dr. Till and indicated by differing acronyms to distinguish the laboratories producing the data, as described in our paper, the two LC/MS methods are very similar; they consist of a solid-phase extraction method with analysis of the extract produced using high-performance liquid chromatography coupled to an electrospray ionization mass spectrometer operated in the positive mode. The NWQL and OWQRL report ‘trace’ and ‘ultratrace’ determinations of analytes that provide significant benefit for describing the presence and fate of low-level contaminants. For mass spectral methods, an analyte is qualitatively identified by its retention time on the chromatographic column as well as the presence of two or more confirming ions with area ratios that match that of the reference standard compounds. Because of a recognized increased risk of false positives, these qualitative identification criteria are used in conjunction with abundant quality-control samples (detailed below) to confirm detection prior to making an estimate of the concentration. These qualitative identification criteria must be met before a compound is considered present (or detected) in a sample ( Oblinger Childress et al., 1999 ). When a compound has been qualitatively identified in an environmental sample (whether above or below its reporting level [RL]), it is assessed in context with associated field and laboratory blanks, field and laboratory replicates, and other data, such as appropriate laboratory reagent spikes. An environmental concentration is calculated only after determining that field and laboratory procedures did not contaminate the samples. The concentrations are then calculated from 5- to 8-point calibration curves using internal standard quantitation. Our lowest calibration standard is intentionally much lower than the RL, typically 10 times lower. The most abundant molecular or fragment ion is used for quantitation, and, for the two LC/MS methods, at least one, and where possible two, qualifier ions are used for confirmation. For the GC/MS method, with its greater degree of fragmentation, one quantitation and two qualifier ions are used. When any of the abovementioned qualitative identification criteria are not met, the analyte is considered not present and is reported as “less than” the RL.

Science of the Total Environment↗