SEARCH · Search USGS

Results for “Scientific Investigations Report”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,567 records · Page 87Linked to original sources

USGS2016

Regional chloride distribution in the Northern Atlantic Coastal Plain aquifer system from Long Island, New York, to North Carolina

The aquifers of the Northern Atlantic Coastal Plain are the principal source of water supply for the region’s nearly 20 million residents. Water quality and water levels in the aquifers, and maintenance of streamflow, are of concern because of the use of this natural resource for water supply and because of the possible effects of climate change and changes in land use on groundwater. The long-term sustainability of this natural resource is a concern at the local community scale, as well as at a regional scale, across state boundaries. In 2010, the U.S. Geological Survey (USGS) began a regional assessment of the Northern Atlantic Coastal Plain aquifers. An important part of this assessment is a regional interpretation of the extent of saltwater and the proximity of saltwater to fresh-groundwater resources and includes samples and published interpretations of chloride concentrations newly available since the last regional chloride assessment in 1989. This updated assessment also includes consideration of chloride samples and refined interpretations that stem from the 1994 discovery of the buried 35 million year old Chesapeake Bay impact structure that has substantially altered the understanding of the hydrogeologic framework and saltwater distribution in eastern Virginia. In this study, the regional area of concern for the chloride samples and interpretations extends from the Fall Line in the west to the outer edge of the Continental Shelf in the east and from the eastern tip of Long Island in the north to about halfway down the North Carolina coast in the south. Discussions of chloride distribution are presented for each of the 10 regional aquifer layers of the Northern Atlantic Coastal Plain, including the offshore extents. Maps of interpreted lines of equal concentration or isochlors were manually prepared for nine of the regional aquifers; a map was not prepared for the surficial regional aquifer. The isochlor interpretations include the offshore extent of the nine regional aquifers and are presented on a 1:2,000,000 scale base map. Vertically, the chloride samples and interpretations range from deepest (oldest) to shallowest (youngest)—Potomac-Patuxent, Potomac-Patapsco, Magothy, Matawan, Monmouth-Mount Laurel, Aquia, Piney Point, Lower Chesapeake, and Upper Chesapeake regional aquifers. The approach of this study maximizes the overall density of chloride information and data by assessing relevant published interpretations, all USGS chloride samples, and all relevant offshore samples in one comprehensive interpretation. Published isochlors, where they were interpreted by regional aquifer, were used as much as possible for this regional isochlor assessment. Publication dates for the isochlors used range from 1982 to 2015, and the scales for the isochlors range from local (county or municipality) to state (sub-regional) to regional. The USGS National Water Information System database provided well sample data for the parts of aquifers that are mainly beneath the land areas and yielded 37,517 water-quality records for 1903 through 2011. Published data reports from four phases of research-related offshore coring (1976, 1993, 1997, 2009) were the main source of water-quality data for the parts of aquifers from the shoreline to the outer edge of the Continental Shelf and yielded samples from multiple depths of each of 13 cores. This study also used interpretations and offshore core data from the last regional chloride assessment (1989) which, in addition to 7 offshore cores, included water-quality data from about 500 wells, and borehole geophysics interpretations from a subset of 11 wells. All published information and data that were used in this study were considered time independent and did not assess the published interpretations or data for temporal trends. The approach used here examined only published interpretations and available chloride data, and did not directly use supplemental techniques that can provide insight into the distribution of saltwater, such as geochemical characterization, borehole geophysical information, and geochronology. Isochlor maps for this study are limited to manual interpretations of the 250-milligram per liter (mg/L) and 10,000-mg/L boundaries developed for 9 of the 10 regional aquifers that constitute the regional hydrogeologic framework of the Northern Atlantic Coastal Plain. For a given aquifer, the approach was to initially consider published isochlor interpretations, where available, then to modify the published interpretations, if necessary, to the extent indicated by the well and core samples. The final step was to interpolate isochlors to the full extent of each aquifer layer in areas with sufficient samples or cited interpretations, or to extrapolate isochlors in areas with no samples or where samples were sparse. The principal limitation of this study is that, because of its regional extent, data and information density can vary greatly, and thus confidence in interpretations can vary widely for onshore and offshore areas across the study area. In areas of sparse data, some samples of elevated chloride could be misinterpreted as being part of a regional elevated chloride trend, and in other cases, an elevated concentration could be misinterpreted as being of only local importance. The interpretive work of this study was applied to a 1:2,000,000 scale base map. Locations of isochlors, wells, cores, political boundaries, and shorelines are meant to be considered approximate. The isochlors presented in this study were manually interpreted for each aquifer unit as a conceptual representation of an equal concentration line approximately in the middle of an aquifer’s thickness. Differences in chloride concentration lines between the top and bottom of an aquifer could be substantial, especially for the thick parts of aquifers, but that information is not presented in this regional assessment. Although additional offshore chloride data are available compared to 27 years ago (1989), the offshore information remains sparse, resulting in less confidence in the offshore interpretations than in the onshore interpretations. Regionally, the 250- and 10,000-mg/L isochlors tend to map progressively eastward from the deepest to the shallowest aquifers across the Northern Atlantic Coastal Plain aquifer system but with some exceptions. The additional data, conceptual understanding, and interpretations in the vicinity of the buried Chesapeake Bay impact structure in eastern Virginia resulted in substantial refinement of isochlors in that area. Overall, the interpretations in this study are updates of the previous regional study from 1989 but do not comprise major differences in interpretation and do not indicate regional movement of the freshwater-saltwater interface since then.

Delaware, Maryland, New Jersey, New York, North Ca↗

USGS2016

Estimating selected low-flow frequency statistics and harmonic-mean flows for ungaged, unregulated streams in Indiana

Information on low-flow characteristics of streams is essential for the management of water resources. This report provides equations for estimating the 1-, 7-, and 30-day mean low flows for a recurrence interval of 10 years and the harmonic-mean flow at ungaged, unregulated stream sites in Indiana. These equations were developed using the low-flow statistics and basin characteristics for 108 continuous-record streamgages in Indiana with at least 10 years of daily mean streamflow data through the 2011 climate year (April 1 through March 31). The equations were developed in cooperation with the Indiana Department of Environmental Management. Regression techniques were used to develop the equations for estimating low-flow frequency statistics and the harmonic-mean flows on the basis of drainage-basin characteristics. A geographic information system was used to measure basin characteristics for selected streamgages. A final set of 25 basin characteristics measured at all the streamgages were evaluated to choose the best predictors of the low-flow statistics. Logistic-regression equations applicable statewide are presented for estimating the probability that selected low-flow frequency statistics equal zero. These equations use the explanatory variables total drainage area, average transmissivity of the full thickness of the unconsolidated deposits within 1,000 feet of the stream network, and latitude of the basin outlet. The percentage of the streamgage low-flow statistics correctly classified as zero or nonzero using the logistic-regression equations ranged from 86.1 to 88.9 percent. Generalized-least-squares regression equations applicable statewide for estimating nonzero low-flow frequency statistics use total drainage area, the average hydraulic conductivity of the top 70 feet of unconsolidated deposits, the slope of the basin, and the index of permeability and thickness of the Quaternary surficial sediments as explanatory variables. The average standard error of prediction of these regression equations ranges from 55.7 to 61.5 percent. Regional weighted-least-squares regression equations were developed for estimating the harmonic-mean flows by dividing the State into three low-flow regions. The Northern region uses total drainage area and the average transmissivity of the entire thickness of unconsolidated deposits as explanatory variables. The Central region uses total drainage area, the average hydraulic conductivity of the entire thickness of unconsolidated deposits, and the index of permeability and thickness of the Quaternary surficial sediments. The Southern region uses total drainage area and the percent of the basin covered by forest. The average standard error of prediction for these equations ranges from 39.3 to 66.7 percent. The regional regression equations are applicable only to stream sites with low flows unaffected by regulation and to stream sites with drainage basin characteristic values within specified limits. Caution is advised when applying the equations for basins with characteristics near the applicable limits and for basins with karst drainage features and for urbanized basins. Extrapolations near and beyond the applicable basin characteristic limits will have unknown errors that may be large. Equations are presented for use in estimating the 90-percent prediction interval of the low-flow statistics estimated by use of the regression equations at a given stream site. The regression equations are to be incorporated into the U.S. Geological Survey StreamStats Web-based application for Indiana. StreamStats allows users to select a stream site on a map and automatically measure the needed basin characteristics and compute the estimated low-flow statistics and associated prediction intervals.

Indiana↗

USGS2016

Streamflow and estimated loads of phosphorus and dissolved and suspended solids from selected tributaries to Lake Ontario, New York, water years 2012–14

This report presents results of the evaluation and interpretation of hydrologic and water-quality data collected as part of a cooperative program between the U.S. Geological Survey and the U.S. Environmental Protection Agency. Streamflow, phosphorus, and solids dissolved and suspended in stream water were the focus of monitoring by the U.S. Geological Survey at 10 sites on 9 selected tributaries to Lake Ontario during the period from October 2011 through September 2014. Streamflow yields (flow per unit area) were the highest from the Salmon River Basin due to sustained yields from the Tug Hill aquifer. The Eighteenmile Creek streamflow yields also were high as a result of sustained base flow contributions from a dam just upstream of the U.S. Geological Survey monitoring station at Burt. The lowest streamflow yields were measured in the Honeoye Creek Basin, which reflects a decrease in flow because of withdrawals from Canadice and Hemlock Lakes for the water supply of the City of Rochester. The Eighteenmile Creek and Oak Orchard Creek Basins had relatively high yields due in part to groundwater contributions from the Niagara Escarpment and seasonal releases from the New York State Barge Canal. Annual constituent yields (load per unit area) of suspended solids, phosphorus, orthophosphate, and dissolved solids were computed to assess the relative contributions and allow direct comparison of loads among the monitored basins. High yields of total suspended solids were attributed to agricultural land use in highly erodible soils at all sites. The Genesee River, Irondequoit Creek, and Honeoye Creek had the highest concentrations and largest mean yields of total suspended solids (165 short tons per square mile [t/mi 2 ], 184 t/mi 2 , and 89.7 t/mi 2 , respectively) of the study sites. Samples from Eighteenmile Creek, Oak Orchard Creek at Kenyonville, and Irondequoit Creek had the highest concentrations and largest mean yields of phosphorus (0.27 t/mi 2 , 0.26 t/mi 2 , and 0.20 t/mi 2 , respectively) and orthophosphate (0.17 t/mi 2 , 0.13 t/mi 2 , and 0.04 t/mi 2 , respectively) of the study sites. These results were attributed to a combination of sources, including discharges from wastewater treatment plants, diversions from the New York State Barge Canal, and manure and fertilizers applied to agricultural land. Yields of phosphorus also were high in the Genesee River Basin (0.17 t/mi 2 ) and were presumably associated with nutrient and sediment transport from agricultural land and from streambank erosion. The Salmon and Black Rivers, which drain a substantial amount of forested land and are influenced by large groundwater discharges, had the lowest concentrations and yields of phosphorus and orthophosphate of the study sites. Mean annual yields of dissolved solids were the highest in Irondequoit Creek due to a high percentage of urbanized area in the basin and in Oak Orchard Creek at Kenyonville and in Eighteenmile Creek due to groundwater contributions from the Niagara Escarpment. High yields of dissolved solids of 840 t/mi 2 , 829 t/mi 2 , and 715 t/mi 2 , respectively, from these basins can be attributed to seasonal chloride yields associated with use of road deicing salts. The Niagara Escarpment can produce large amounts of dissolved solids from the dissolution of minerals (a continual process reflected in base flow samples). Groundwater inflows in the Salmon River have very low concentrations of dissolved solids due to minimal bedrock interaction along the Tug Hill Plateau and discharge from the Tug Hill sand and gravel aquifer, which has minimal mineralization.

New York↗

USGS2016

Budgets and chemical characterization of groundwater for the Diamond Valley flow system, central Nevada, 2011–12

The Diamond Valley flow system consists of six hydraulically connected hydrographic areas in central Nevada. The general down-gradient order of the areas are southern and northern Monitor Valleys, Antelope Valley, Kobeh Valley, Stevens Basin, and Diamond Valley. Groundwater flow in the Diamond Valley flow system terminates at a large playa in the northern part of Diamond Valley. Concerns relating to continued water-resources development of the flow system resulted in a phased hydrologic investigation that began in 2005 by the U.S. Geological Survey in cooperation with Eureka County. This report presents the culmination of the phased investigation to increase understanding of the groundwater resources of the basin-fill aquifers in the Diamond Valley flow system through evaluations of groundwater chemistry and budgets. Groundwater chemistry was characterized using major ions and stable isotopes from groundwater and precipitation samples. Groundwater budgets accounted for all inflows, outflows, and changes in storage, and were developed for pre-development (pre-1950) and recent (average annual 2011–12) conditions. Major budget components include groundwater discharge by evapotranspiration and groundwater withdrawals; groundwater recharge by precipitation, and interbasin flow; and storage change. Groundwater in the basin-fill aquifer of the Diamond Valley flow system was mostly a calcium or sodium bicarbonate water type and generally within acceptable drinking-water standards. The general water type was similar among the individual hydrographic areas. Stable isotopes of oxygen-18 and deuterium from precipitation varied seasonally, such that enrichment from evaporation was greater during warmer months than cooler months. The isotopic signature of shallow groundwater was similar to cool season precipitation, indicating recharge was relatively recent (similar to recent climatic conditions) and was derived from cool season precipitation. Site-scale groundwater evapotranspiration was estimated from eddy-covariance and micrometeorological measurements collected at four sites and ranged from 0.15 feet per year in sparse, undisturbed shrubland to 1.13 feet per year in a grassland meadow. Vegetation indices calculated from satellite imagery and field mapping were used to define three evapotranspiration units (shrubland, grassland, and playa) and to extrapolate site-scale groundwater evapotranspiration rates to basin-scale estimates. Annual pre-development groundwater evapotranspiration for individual hydrographic areas ranged from 2,900 acre-feet per year (acre-ft/yr) in northern Monitor Valley to 35,000 acre-ft/yr in Diamond Valley. Total groundwater evapotranspiration from the Diamond Valley flow system under pre-development conditions was about 70,000 acre-ft/yr. Areas of irrigated land in the Diamond Valley flow system increased from less than 5,000 acres in the early 1960s to more than 25,000 acres in 2012 and are mostly for growing alfalfa in southern Diamond Valley. Annual (2011–12) net groundwater withdrawals for irrigation, assumed to be the volume of groundwater consumed by crops and pastureland, ranged from about 420 acre-ft/yr in Antelope Valley to 67,000 acre-ft/yr in Diamond Valley. Total net groundwater withdrawals for irrigation in the Diamond Valley flow system were about 69,000 acre-ft/yr (2011–12). Groundwater recharge, the largest inflow component to the Diamond Valley flow system, was determined as the sum of groundwater evapotranspiration and net subsurface outflow (subsurface outflow minus subsurface inflow). Annual groundwater recharge estimates ranged from 200 acre-ft/yr in Stevens Basin to 35,000 acre-ft/yr in Diamond Valley. Subsurface flow between hydrographic basins was evaluated using estimated transmissivity, groundwater-flow sections derived from remotely sensed imagery, and hydraulic gradients determined from 2012 water-level data. Subsurface outflow ranged from 0 acre-ft/yr for Diamond Valley to 3,400 acre-ft/yr for northern Monitor Valley into western Kobeh Valley. Subsurface inflow ranged from 0 acre-ft/yr for southern Monitor Valley to 4,200 acre-ft/yr for Kobeh Valley from northern Monitor and Antelope Valleys. The pre-development, steady state, groundwater budget for the Diamond Valley flow system was estimated at about 70,000 acre-ft/yr of inflow and outflow. During years 2011–12, inflow components of groundwater recharge from precipitation and subsurface inflow from adjacent basins totaled 70,000 acre-ft/yr for the DVFS, whereas outflow components included 64,000 acre-ft/yr of groundwater evapotranspiration and 69,000 acre-ft/yr of net groundwater withdrawals, or net pumpage. Spring discharge in northern Diamond Valley declined about 6,000 acre-ft/yr between pre-development time and years 2011–12. Assuming net groundwater withdrawals minus spring flow decline is equivalent to the storage change, the 2011–12 summation of inflow and storage change was balanced with outflow at about 133,000 acre-ft/yr.

Nevada↗

USGS2008

Ground-Water Flow, 2004-07, and Water Quality, 1992-2007, in McBaine Bottoms, Columbia, Missouri

The U.S. Geological Survey, in cooperation with the city of Columbia, Missouri, and the Missouri Department of Conservation, collected ground-water quality data, surface-water quality data, and water-level data in McBaine Bottoms, southwest of Columbia. McBaine Bottoms, adjacent to the Missouri River, is the location of the municipal-supply well field for the city of Columbia, the city of Columbia wastewater-treatment wetlands, and the Missouri Department of Conservation Eagle Bluffs Conservation Area. This report describes the ground-water flow and water quality of McBaine Bottoms and provides information to better understand the interaction between treated effluent from the wetlands used on the Eagle Bluffs Conservation Area and the water in the alluvial aquifer that is pumped from the city of Columbia municipal-supply well field. Changes in major chemical constituent concentrations have been detected at several sampling sites between pre- and post-effluent application data. Analysis of post-effluent data indicates substantial changes in calcium, potassium, sodium, chloride, and sulfate concentrations in ground water. These changes became apparent shortly after the beginning of the operation of the wastewater-treatment wetland in 1994 and the formation of the Eagle Bluffs Conservation Area, which uses the treated effluent as a water source for the management of migratory water fowl. The changes have continued throughout the 15 years of sample collection. The concentrations of these major chemical constituents are on the mixing continuum between pre-effluent ground water as one end member and the treated wastewater effluent as the other end member. For monitoring wells that had changes in major chemical constituent concentrations, the relative percentage of treated effluent in the ground water, assuming chloride is conservative, ranged from 6 to 88 percent. Twenty-two monitoring wells throughout McBaine Bottoms have been affected by effluent based on chloride concentrations larger than 40 milligrams per liter. The chloride concentration of ground water in the alluvial aquifer reflects several sources, including precipitation, water from the Missouri River, water in the aquifer, and the treated effluent. Chloride concentrations from precipitation, the Missouri River, and water in the alluvial aquifer were less than 40 milligrams per liter. These monitoring wells affected by effluent are located in two general areas - adjacent to treatment wetland unit 1 and near the ground-water high on and north of the Eagle Bluffs Conservation Area. The probable source of the large chloride concentrations in well samples adjacent to treatment wetland unit 1 is leakage from the unit. The source for the large chloride concentrations in the other monitoring well samples is the effluent mixed with ground water and Missouri River water that is used to fill pools on the Eagle Bluffs Conservation Area. One monitoring well had a single sample with a chloride concentration larger than 40 milligrams per liter. That sample may have been affected by the use of road salt because of the presence of ice and snow immediately before the sample was collected. Lateral ground-water flow was dominated by the presence of a persistent ground-water high beneath the Eagle Bluffs Conservation Area and the presence of a cone of depression centered around the city of Columbia well field in the northern part of the study area. Ground-water flow was radially away from the apex of the ground-water high; west and south of the high, flow was toward the Missouri River, east of the high, flow was toward Perche Creek, and north of the high, flow was to the north toward the cone of depression around the city of Columbia well field. Another permanent feature on the water-level maps was a ground-water high beneath treatment wetland unit 1. Although the ground-water high was present throughout the study period, the subsurface expression of the high changed depending on hydrolo

Scientific Investigations Report↗

USGS2007

Ground-Water Conditions and Studies in Georgia, 2004-2005

The U.S. Geological Survey (USGS) collects ground-water data and conducts studies to monitor hydrologic conditions, better define ground-water resources, and address problems related to water supply, water use, and water quality. During 2004-2005, ground-water levels were monitored continuously in a network of 183 wells completed in major aquifers throughout the State. Because of missing data or the short period of record for a number of these wells (less than 3 years), a total of 171 wells from the network are discussed in this report. These wells include 19 in the surficial aquifer system, 20 in the Brunswick aquifer system and equivalent sediments, 69 in the Upper Floridan aquifer, 17 in the Lower Floridan aquifer and underlying units, 10 in the Claiborne aquifer, 1 in the Gordon aquifer, 10 in the Clayton aquifer, 12 in the Cretaceous aquifer system, 2 in Paleozoic-rock aquifers, and 11 in crystalline-rock aquifers. Data from the network indicate that generally water levels rose after the end of a drought (fall 2002), with water levels in 152 of the wells in the normal or above-normal range by 2005. An exception to this pattern of water-level recovery is in the Cretaceous aquifer system where water levels in 7 of the 12 wells monitored were below normal during 2005. In addition to continuous water-level data, periodic synoptic water-level measurements were collected and used to construct potentiometric-surface maps for the Upper Floridan aquifer in the Camden County-Charlton County area during September 2004 and May 2005, in the Brunswick area during June 2004 and June 2005, and in the City of Albany-Dougherty County area during October 2004 and during October 2005. In general, the configuration of the potentiometric surfaces showed little change during 2004-2005 in each of the areas. Ground-water quality in the Upper Floridan aquifer is monitored in the Albany, Savannah, and Brunswick areas, and in Camden County; and the Lower Floridan aquifer, monitored in the Savannah and Brunswick areas and in Camden County. In the Albany area, nitrate concentrations generally increased since the end of the drought during 2002. Concentrations increased in water collected from 13 of the 16 wells sampled during 2004-2005 and by November 2005, water from 2 wells had nitrate as N concentrations that were above the U.S. Environmental Protection Agency's (USEPA) 10-milligram-per-liter (mg/L) drinking-water standard. In the Savannah area, measurement of fluid conductivity and chloride concentration in water samples from discrete depths in three wells completed in the Upper Floridan aquifer and one well in the Lower Floridan aquifer were used to assess changes in water quality in the Savannah area. At Tybee Island, chloride concentrations in samples from the Lower Floridan aquifer increased during 2004-2005 and were above the 250-mg/L USEPA drinking-water standard. At Skidaway Island, water in the Upper Floridan aquifer is fresh, and chloride concentrations did not appreciably change during 2004-2005. However, chloride concentrations in samples collected from the Lower Floridan aquifer during 2004-2005 showed disparate changes; whereby, chloride concentration increased in the deepest sampled interval (1,070 feet) and decreased in a shallower sampled interval (900 feet). At Fort Pulaski, water samples collected from the Upper Floridan aquifer are fresh and did not appreciably change during 2004-2005. In the Brunswick area, maps showing the chloride concentration of water in the Upper Floridan aquifer were constructed using data collected from 41 wells during June 2004 and from 39 wells during June 2005. Analyses indicate that concentrations remained above the USEPA drinking-water standard in an approximate 2-square-mile area. During 2004-2005, chloride concentrations increased in samples from 18 wells and decreased in samples from 11 wells. In the Camden County area, chloride concentrations during 2004-2005 were analyzed in water

Georgia↗

USGS2012

Occurrence of pharmaceuticals, hormones, and organic wastewater compounds in Pennsylvania waters, 2006-09

Concern over the presence of contaminants of emerging concern, such as pharmaceutical compounds, hormones, and organic wastewater compounds (OWCs), in waters of the United States and elsewhere is growing. Laboratory techniques developed within the last decade or new techniques currently under development within the U.S. Geological Survey now allow these compounds to be measured at concentrations in nanograms per liter. These new laboratory techniques were used in a reconnaissance study conducted by the U.S. Geological Survey, in cooperation with the Pennsylvania Department of Environmental Protection, to determine the occurrence of contaminants of emerging concern in streams, streambed sediment, and groundwater of Pennsylvania. Compounds analyzed for in the study are pharmaceuticals (human and veterinary drugs), hormones (natural and synthetic), and OWCs (detergents, fragrances, pesticides, industrial compounds, disinfectants, polycyclic aromatic hydrocarbons, fire retardants and plasticizers). Reconnaissance sampling was conducted from 2006 to 2009 to identify contaminants of emerging concern in (1) groundwater from wells used to supply livestock, (2) streamwater upstream and downstream from animal feeding operations, (3) streamwater upstream from and streamwater and streambed sediment downstream from municipal wastewater effluent discharges, (4) streamwater from sites within 5 miles of drinking-water intakes, and (5) streamwater and streambed sediment where fish health assessments were conducted. Of the 44 pharmaceutical compounds analyzed in groundwater samples collected in 2006 from six wells used to supply livestock, only cotinine (a nicotine metabolite) and the antibiotics tylosin and sulfamethoxazole were detected. The maximum concentration of any contaminant of emerging concern was 24 nanograms per liter (ng/L) for cotinine, and was detected in a groundwater sample from a Lebanon County, Pa., well. Seven pharmaceutical compounds including acetaminophen, caffeine, carbamazepine, and the four antibiotics tylosin, sulfadimethoxine, sulfamethoxazole, and oxytetracycline were detected in streamwater samples collected in 2006 from six paired stream sampling sites located upstream and downstream from animal-feeding operations. The highest reported concentration of these seven compounds was for the antibiotic sulfamethoxazole (157 ng/L), in a sample from the downstream site on Snitz Creek in Lancaster County, Pa. Twenty-one pharmaceutical compounds were detected in streamwater samples collected in 2006 from five paired stream sampling sites located upstream or downstream from a municipal wastewater-effluent-discharge site. The most commonly detected compounds and maximum concentrations were the anticonvulsant carbamazepine, 276 ng/L; the antihistamine diphenhydramine, 135 ng/L; and the antibiotics ofloxacin, 329 ng/L; sulfamethoxazole, 1,340 ng/L; and trimethoprim, 256 ng/L. A total of 51 different contaminants of emerging concern were detected in streamwater samples collected from 2007 through 2009 at 13 stream sampling sites located downstream from a wastewater-effluent-discharge site. The concentrations and numbers of compounds detected were higher in stream sites downstream from a wastewater-effluent-discharge site than in stream sites upstream from a wastewater-effluent-discharge site. This finding indicates that wastewater-effluent discharges are a source of contaminants of emerging concern; these contaminants were present more frequently in the streambed-sediment samples than in streamwater samples. Antibiotic compounds were often present in both the streamwater and streambed-sediment samples, but many OWCs were present exclusively in the streambed-sediment samples. Compounds with endocrine disrupting potential including detergent metabolites, pesticides, and flame retardants, were present in the streamwater and streambed-sediment samples. Killinger Creek, a stream where wastewater-effluent discharges contribute a large percentage of the total flow, stands out as a stream with particularly high numbers of compounds detected and detected at the highest concentrations measured in the reconnaissance sampling. Nineteen contaminants of emerging concern were detected in streamwater samples collected quarterly from 2007 through 2009 at 27 stream sites within 5 miles of a drinking-water intake. The number of contaminants and the concentrations detected at the stream sites within 5 miles of drinking-water intakes were generally very low (concentrations less than 50 ng/L), much lower than those at sites downstream from a wastewater-effluent discharge. The most commonly detected compounds and maximum concentrations were caffeine, 517 ng/L; carbamazepine, 95 ng/L; sulfamethoxazole, 146 ng/L; and estrone, 3.15 ng/L. The concentrations and frequencies of detection of some of the contaminants of emerging concern appear to vary by season, which could be explained by compound use, flow regime, or differences in degradation rates. Concentrations of some contaminants were associated with lower flows as a result of decreased in-stream dilution of wastewater effluents or other contamination sources. Twenty-two contaminants of emerging concern were detected once each in streamwater samples collected in 2007 and 2008 from 16 fish-health stream sites located statewide. The highest concentrations were for the OWCs, including flame retardants tri(2-butoxyethyl)phosphate (604 ng/L) and tri(2-chloroethyl)phosphate (272 ng/L) and the fragrance isoquinoline (330 ng/L). Far fewer numbers of contaminants of emerging concern were detected at the fish-health sites than at the wastewater-effluent-discharge sites. Most of the fish-health sites were not located directly downstream from a wastewater-effluent discharge, but there were multiple wastewater-effluent discharges in the drainage basins upstream from the sampling sites. No distinct pattern of contaminant occurrence could be discerned for the fish-health stream sites

Pennsylvania↗

USGS2011

Groundwater conditions and studies in Georgia, 2008-2009

The U.S. Geological Survey collects groundwater data and conducts studies to monitor hydrologic conditions, better define groundwater resources, and address problems related to water supply, water use, and water quality. In Georgia, water levels were monitored continuously at 179 wells during 2008 and 181 wells during 2009. Because of missing data or short periods of record (less than 3 years) for several of these wells, a total of 161 wells are discussed in this report. These wells include 17 in the surficial aquifer system, 19 in the Brunswick aquifer and equivalent sediments, 66 in the Upper Floridan aquifer, 16 in the Lower Floridan aquifer and underlying units, 10 in the Claiborne aquifer, 1 in the Gordon aquifer, 11 in the Clayton aquifer, 12 in the Cretaceous aquifer system, 2 in Paleozoic-rock aquifers, and 7 in crystalline-rock aquifers. Data from the well network indicate that water levels generally rose during the 2008-2009 period, with water levels rising in 135 wells and declining in 26. In contrast, water levels declined over the period of record at 100 wells, increased at 56 wells, and remained relatively constant at 5 wells. In addition to continuous water-level data, periodic water-level measurements were collected and used to construct potentiometric-surface maps for the Upper Floridan aquifer in Camden, Charlton, and Ware Counties, Georgia, and adjacent counties in Florida during September 2008 and May 2009; in the Brunswick, Georgia area during July 2008 and July-August 2009; and in the City of Albany-Dougherty County, Georgia area during November 2008 and November 2009. In general, water levels in these areas were higher during 2009 than during 2008; however, the configuration of the potentiometric surfaces in each of the areas showed little change. Groundwater quality in the Floridan aquifer system is monitored in the Albany, Savannah, Brunswick, and Camden County areas of Georgia. In the Albany area, nitrate as nitrogen concentrations in the Upper Floridan aquifer during 2008-2009 generally increased, with concentrations in two wells above the U.S. Environmental Protection Agency (USEPA) 10-milligrams-per-liter (mg/L) drinking-water standard. In the Savannah area, measurement of specific conductance and chloride concentration in water samples from discrete depths in three wells completed in the Upper Floridan aquifer indicate that chloride concentrations in the Upper Floridan aquifer showed little change and remained below the 250 mg/L USEPA secondary drinking-water standard. Chloride concentrations in the Lower Floridan aquifer increased slightly at Tybee Island and Skidaway Island, remaining above the drinking-water standard. In the Brunswick area, maps showing the chloride concentration of water in the Upper Floridan aquifer were constructed using data collected from 28 wells during July 2008 and from 29 wells during July-August 2009, indicate that chloride concentrations remained above the USEPA secondary drinking-water standard in an approximately 2-square-mile area. During 2008-2009, chloride concentrations decreased, with a maximum decrease of 160 mg/L, in a well located in the northern part of the Brunswick area. In the Camden County area, chloride concentration during 2008-2009 was analyzed in water samples collected from eight wells, six of which were completed in the Upper Floridan aquifer and two in the Lower Floridan aquifer. In most of the wells sampled during this period, chloride concentrations did not appreciably change; however, since the closure of the Durango Paper Company in October 2002, chloride concentrations in the Upper Floridan aquifer near the paper mill decreased from a high of 184 mg/L in May 2002 to 41 mg/L in September 2009. Groundwater studies conducted in Georgia during 2008-2009 include the following: * evaluation of groundwater flow, water-quality, and water-level monitoring in the Augusta-Richmond County area; * evaluation of groundwater flow, water-quality, and water

Georgia↗

USGS2004

Potentiometric surfaces in the Cockfield and Wilcox aquifers of southern and northeastern Arkansas, 2003

This report presents the results of water-level measurements made at wells in the Cockfield Formation and Wilcox Group of southern and northeastern Arkansas during 2003, and the water levels are displayed in potentiometric-surface maps and hydrographs. During March and April 2003, the water level was measured at 55 wells completed in the Cockfield aquifer, 13 wells completed in the Wilcox aquifer of southern Arkansas, and 43 wells completed in the Wilcox aquifer of northeastern Arkansas. The Cockfield Formation generally consists of discontinuous sand units interbedded with silt, clay, and lignite in southeastern Arkansas. Sand beds near the base of the Cockfield Formation constitute most of the Cockfield aquifer. Withdrawals from the Cockfield aquifer in the study area during 2000 totaled about 9 million gallons per day. The potentiometric surface of the Cockfield aquifer constructed from the 2003 water levels shows that regional direction of ground-water flow generally is towards the east and southeast, away from the outcrop, except in areas of intense ground-water withdrawals. Some local ground-water flow in the outcrop area is toward rivers that have eroded into the Cockfield Formation and deposited alluvium in south Bradley and Calhoun Counties (Ouachita River), and in north Dallas County (Saline River). An evaluation of 20 wells with water-level data from 1983 to 2003 shows that water levels in 15 wells have declined at a rate of -0.04 to -0.97 feet per year, and water levels in 5 wells have risen at a rate of 0.07 to 0.32 feet per year. An evaluation of the same 20 wells from 2000 to 2003 shows that water levels have declined in only 8 wells, and water levels have risen in 12 wells. The Wilcox Group is distributed throughout most of southern and eastern Arkansas. There are two study areas in southern and northeastern Arkansas. The Wilcox Group of the southern study area consists of interbedded clay, sandy clay, sand, and lignite. Thin discontinuous sand units constitute the Wilcox aquifer in the southern study area. Withdrawals from the aquifer in the southern study area were about 1 million gallons per day during 2000. The potentiometric surface of the Wilcox aquifer in the southern study area shows that regional ground-water flow generally is south and east, except in Clark County where flow is towards the Ouachita River. The Wilcox Group in the northeastern study area consists of thin interbedded lignitic sand and clays. A sand bed of about 200 feet thick in the middle to lower part of the Wilcox Group constitutes the major producing unit of the Wilcox aquifer in the northeastern study area. Withdrawals from the aquifer in the northeastern study area were about 23 million gallons per day during 2000. The potentiometric surface of the Wilcox aquifer in the northeastern study area shows that ground-water flow generally is south and east, except where ground-water withdrawals may have altered the natural direction of flow near the centers of pumping at Paragould and West Memphis. An evaluation of 27 wells with water-level data from 1983 to 2003 in the northeastern study area shows that water levels in all 27 wells have been declining at a rate of -0.17 to -1.73 feet per year. An evaluation of the same 27 wells from 2000 to 2003 shows that water levels in 18 wells have risen and in 9 wells have declined.

Scientific Investigations Report↗

USGS2017

Preliminary assessment of a water-quality monitoring program for total maximum daily loads in Johnson County, Kansas, January 2015 through June 2016

Municipalities in Johnson County in northeastern Kansas are required to implement stormwater management programs to reduce pollutant discharges, protect water quality, and comply with applicable water-quality regulations in accordance with National Pollutant Discharge Elimination System permits for stormwater discharge. To this end, municipalities collect grab samples at streams entering and leaving their jurisdiction to determine levels of excessive nutrients, sediment, and fecal bacteria to characterize pollutants and understand the factors affecting them. In 2014, the U.S. Geological Survey and the Johnson County Stormwater Management Program, with input from the Kansas Department of Health and Environment, initiated a 5-year monitoring program to satisfy minimum sampling requirements for each municipality as described by new stormwater permits issued to Johnson County municipalities. The purpose of this report is to provide a preliminary assessment of the monitoring program. The monitoring program is described, a preliminary assessment of the monitoring program design is provided using water-quality data collected during the first 2 years of the program, and the ability of the current monitoring network and sampling plan to provide data sufficient to quantify improvements in water quality resulting from implemented and planned best management practices is evaluated. The information in this initial report may be used to evaluate changes in data collection methods while data collection is still ongoing that may lead to improved data utility. Discrete water-quality samples were collected at 27 sites and analyzed for nutrients, Escherichia coli ( E. coli ) bacteria, total suspended solids, and suspended-sediment concentration. In addition, continuous water-quality data (water temperature, pH, dissolved oxygen, specific conductance, turbidity, and nitrate plus nitrite) were collected at one site to characterize variability and provide a basis for comparison to discrete data. Base flow samples indicated that point sources are likely affecting nutrient concentrations and E. coli bacteria densities at several sites. Concentrations of all analytes in storm runoff samples were characterized by substantial variability among sites and samples. About one-half of the sites, representing different watersheds, had storm runoff samples with nitrogen concentrations greater than 10 milligrams per liter. About one-third of the sites, representing different watersheds, had storm runoff samples with total phosphorus concentrations greater than 3 milligrams per liter. Six sites had samples with E. coli densities greater than 100,000 colonies per 100 milliliters of water. Total suspended solids concentrations of about 12,000 milligrams per liter or greater occurred in samples from three sites. Data collected for this monitoring program may be useful for some general assessment purposes but may also be limited in potential to fully inform stormwater management activities. Valuable attributes of the monitoring program design included incorporating many sites across the county for comparisons among watersheds and municipalities, using fixed-stage samplers to collect multiple samples during single events, collection of base flow samples in addition to storm samples to isolate possible point sources from stormwater sources, and use of continuous monitors to characterize variability. Limiting attributes of the monitoring program design included location of monitoring sites along municipal boundaries to satisfy permit requirements rather than using watershed-based criteria such as locations of tributaries, potential pollutant sources, and implemented management practices. Additional limiting attributes include having a large number of widespread sampling locations, which presented logistical challenges for predicting localized rainfall and collecting and analyzing samples during short timeframes associated with storms, and collecting storm samples at fixed-stage elevations only during the rising limb of storms, which does not characterize conditions over the storm hydrograph. The small number of samples collected per site resulted in a sample size too small to be representative of site conditions, including seasonal and hydrologic variability, and insufficient for meaningful statistical analysis or site-specific modeling. Several measures could be taken to improve data utility and include redesigning the monitoring network according to watershed characteristics, incorporating a nested design in which data are collected at different scales (watershed, subwatershed, and best management practices), increasing sampling frequency, and combining different methods to allow for flexibility to focus on areas and conditions of particular interest. A monitoring design that would facilitate most of these improvements would be to focus efforts on a limited number of watersheds for several years, then cycle to the next set of watersheds for several years, eventually returning to previously monitored watersheds to document changes. Redesign of the water-quality monitoring program requires considerable effort and commitment from municipalities of Johnson County. However, the long-term benefit likely is a monitoring program that results in improved stream conditions and more effective management practices and efficient expenditure of resources.

Kansas↗

USGS2023

Hydrogeology, karst, and groundwater availability of Monroe County, West Virginia

Monroe County is in southeastern West Virginia, encompassing an area of 474 square miles. The area consists of karst and siliciclastic aquifers of Ordovician, Silurian, Devonian, and Mississippian age and is in parts of two physiographic provinces: the Valley and Ridge Province to the east of Peters Mountain, and the Appalachian Plateau Province to the west of Peters Mountain. This study was developed in response to inquiries from the Monroe County Commission requesting assessment of the water resources of the county to better understand the quantity of the county’s groundwater resources, for both current [2023] and future demand, and to provide information to support protection and management of the county’s valuable groundwater resources. Various products were developed for this study that provide knowledge with respect to water availability and contamination susceptibility of the karst aquifers within the county. U.S. Geological Survey (USGS) geologists conducted extensive geologic mapping in support of the project, producing (1) a countywide bedrock geologic map, (2) a countywide hydrogeologic map, and (3) a light detection and ranging (lidar)-derived countywide digital elevation model and associated sinkhole map. A significant part of this work was to map in detail the Greenbrier Group at the formation level, which prior to this study had only partially been completed. The report also includes (4) a description of the lithologic units identified as part of the geologic mapping process. U.S. Geological Survey hydrologists completed several additional products for the hydrology part of the effort, including development of (1) a countywide potentiometric surface (water-table) map, (2) a countywide base-flow stream assessment, (3) countywide water-budget estimates, (4) well log surveys for 15 wells to better understand subsurface controls on groundwater flow within the study area, (5) two groundwater tracer tests to better refine the groundwater divide from the northern and southern parts of the karst aquifer in Monroe County; and finally, based on all available data collected for the study including the potentiometric surface map, geologic map, current [2023] and legacy fluorometric groundwater tracer tests, and base-flow stream assessments, (6) groundwater-basin delineations were reassessed for principal groundwater basins within the Greenbrier aquifer. In Monroe County, four principal hydrogeologic settings produce large yields of water for residential, agricultural, and other uses. The most relied upon water-bearing zone with respect to current [2023] public water supply is from springs along Peters Mountain. These springs are derived from intervals of fractured sandstone and resultant alluvial deposits. Groundwater flows downslope through these permeable alluvial deposits and discharges at the contact with less permeable strata, such as the Reedsville Shale. The second most relied upon water-bearing zone in Monroe County is within the karstic Greenbrier Group aquifer, in which the basal Hillsdale Limestone overlies the less permeable Maccrady Shale. This geologic contact between the Hillsdale Limestone and Maccrady Shale is not only targeted as a source of water for agricultural supply but also is targeted as a source of water for residential supply. The third most relied upon water-bearing zone is composed of shallow perched aquifers within the Greenbrier Group. The discontinuous nature of these perched aquifers makes mapping their extent impossible, but they are related to permeable geologic strata, such as karstified limestones with solutionally enhanced permeability that overlies less permeable shale or chert bedrock. During geologic mapping of the county, several of these perched aquifers were documented in the Pickaway, Union, and Alderson Limestones. A fourth zone consists of springs from Ordovician carbonates at the base of Peters Mountain, which are influenced by sinking streams as well as upwelling along faults. In terms of water quantity, the most sustainable springs are those having deeper-sourced flows. Public supplies are a principal source of water used for residential and commercial supply in the region, accounting for 0.49 million gallons per day (Mgal/d) of fresh-water withdrawals (0.14 Mgal/d of groundwater and 0.35 Mgal/d of surface water) for residential and commercial use and serving 6,645 individuals (49.2 percent of the population). An estimated 6,861 people, (50.8 percent of the population) primarily rely on private wells or other unregulated sources, such as springs, and withdraw 0.55 Mgal/d of groundwater for their residential use. Public water supply in the region is primarily (71.4 percent) derived from springs and augmented by stream withdrawals (backup sources mainly during low-flow periods), with the remaining portion (28.6 percent) derived from groundwater withdrawals from wells. For rural residents, however, 100 percent of their withdrawals are derived from groundwater (wells or springs).

West Virginia↗

USGS2007

Status of Water Levels and Selected Water-Quality Conditions in the Sparta-Memphis Aquifer in Arkansas and the Status of Water Levels in the Sparta Aquifer in Louisiana, Spring 2005

The U.S. Geological Survey in cooperation with the Arkansas Natural Resources Commission, the Arkansas Geological Commission, and the Louisiana Department of Transportation and Development has monitored water levels in the Sparta Sand of Claiborne Group and Memphis Sand of Claiborne Group since the 1920's. Ground-water withdrawals have increased while water levels have declined since monitoring was initiated. This report has been produced to describe ground-water levels in the aquifers in the Sparta Sand and Memphis Sand and provide information for the management of this valuable resource. The 2005 potentiometric-surface map of the aquifers in the Sparta Sand and Memphis Sand was constructed using water-level data collected in 333 wells in Arkansas and 120 wells in Louisiana during the spring of 2005. The highest water-level altitude measured in Arkansas was 327 feet above National Geodetic Vertical Datum of 1929 located in Grant County in the outcrop at the western boundary of the study area; the lowest water-level altitude was 189 feet below National Geodetic Vertical Datum of 1929 in Union County. The highest water-level altitude measured in Louisiana was 246 feet above National Geodetic Vertical Datum of 1929 located in Bossier Parish in the outcrop area near the western boundary of the study area; the lowest water-level altitude was 226 feet below National Geodetic Vertical Datum of 1929 in central Ouachita Parish. Three large depressions centered in Columbia, Jefferson, and Union Counties in Arkansas are the result of large withdrawals for industrial and public supplies. In Louisiana, three major pumping centers are in Ouachita, Jackson, and Lincoln Parishes. Water withdrawals from these major pumping centers primarily is used for industrial and public-supply purposes. Withdrawals from Ouachita and Lincoln Parishes and Union County, Arkansas, primarily for industrial purposes, have caused the resulting cones of depression to coalesce so that the -40 foot potentiometric contour encircles the three pumping centers. Seven smaller depressions are evident on the 2005 Sparta-Memphis potentiometric-surface map located in Webster and Winn Parishes, Louisiana, and Calhoun, Cleveland, western Columbia, Desha, and Lafayette Counties, Arkansas. The depression in Calhoun County initially was shown in the 1996-1997 potentiometric surface. The depression in Desha County initially was shown in the 1999 potentiometric surface. The depressions in Webster and Winn Parishes were shown as early as 1975. The depressions in Cleveland, western Columbia, and Lafayette Counties initially were shown in the 2003 potentiometric surface. A map of differences in water-level measurements between 2001 and 2005 was constructed using the difference between water-level measurements from 294 wells in Arkansas and 29 wells in Louisiana. The difference in water levels between 2001 and 2005 ranged from -30.1 to 44.6 feet. The largest rise of 44.6 feet in water level measured was in Union County in Arkansas. The largest decline of 30.1 feet in water level measured was in Columbia County in Arkansas. Areas with a general rise in water levels in Arkansas are shown in Arkansas, Columbia, Craighead, Jefferson, Prairie, and the western half of Union Counties. The area around west-central Union County had rises as much as 44.6 feet, with seven wells showing a rise of 20 feet or greater, which is an annual rise of 5 feet or greater. Areas in Arkansas with a general decline in water level are shown in western Bradley, eastern Calhoun, Cleveland, Cross, Desha, Drew, Lafayette, Lee, Lincoln, Lonoke, Poinsett, and the eastern half of Union Counties. In Louisiana, the water-level difference map showed a general rise in water levels in northern Claiborne, northern Webster, and northwestern Union Parishes mainly because of a decrease in industrial withdrawals in southern Arkansas, particularly Union County. Another rise in water level was indicated in western

Scientific Investigations Report↗

USGS2010

Biological water-quality assessment of selected streams in the Milwaukee Metropolitan Sewerage District Planning Area of Wisconsin, 2007

Changes in the water quality of stream ecosystems in an urban area may manifest in conspicuous ways, such as in murky or smelly streamwater, or in less conspicuous ways, such as fewer native or pollution-sensitive organisms. In 2004, and again in 2007, the U.S. Geological Survey sampled stream organisms—algae, invertebrates, and fish—in 14 Milwaukee area streams to assess water quality as part of the ongoing Milwaukee Metropolitan Sewerage District (MMSD) Corridor Study. In addition, passive-sampling devices (SPMDs, “semipermeable membrane devices”) were deployed at a subset of sites in order to evaluate the potential exposure of stream organisms to certain toxic chemicals. Results of the 2007 sampling effort are the focus of this report. Results of sampling from 2007 are compared with results from 2004. The water quality of sampled streams was assessed by evaluating biological-assemblage data, metrics computed from assemblage data, and an aggregate bioassessment ranking method that combined data for algae, invertebrates, and fish. These data contain information about the abundance (number) of different species in each group of stream organisms and the balance between species that can or cannot tolerate polluted or disturbed conditions. In 2007, the highest numbers of algal, invertebrate, and fish species were found at the Milwaukee River at Milwaukee, the largest sampled site. Algal results indicated water quality concerns at 10 of the 14 sampled sites due to the occurrence of nuisance algae or low percentages of pollution-sensitive algae. When compared to 2004, total algal biovolume was higher in 2007 at 12 of 14 sites, due mostly to more nuisance green algae from unknown causes. Results of several metrics, including the Hilsenhoff Biotic Index (HBI-10), suggest that invertebrate assemblages in the Little Menomonee River, Underwood Creek, and Honey Creek were poorer quality in 2007 compared to 2004. Six sites received “very poor” quality ratings for fish in 2007, mostly because inadequate numbers of fish were collected at five sites to allow computation of an Index of Biotic Integrity (IBI); this resulted in three additional sites receiving “very poor” ratings compared to 2004. Some signs of potential improvement in the fish assemblage were evident at Lincoln Creek, possibly reflecting delayed effects of the restoration of stream habitat, completed in 2002; however, algae and invertebrates did not show signs of improvement. Aggregate bioassessment rankings across all groups of organisms for 2004 and 2007 indicated that water quality at the two Milwaukee River main stem sites (at Milwaukee and near Cedarburg), Jewel Creek, and the Menomonee River at Menomonee Falls was the least-degraded among all sampled sites. Rankings for Oak Creek and Little Menomonee suggested water quality was worse in 2007 compared to 2004 and placed these two sites together with Kinnickinnic River and Underwood Creek, two concrete-line sites, indicating the most-degraded water quality among all sampled sites. The aggregate ranking for Lincoln Creek in 2007 would have placed it in the most-degraded category but for the positive influence of the fish ranking when compared to poor algal and invertebrate rankings. Potential toxicity due to certain manmade chemicals, such as polycyclic aromatic hydrocarbons (PAHs), was found at all six sites where SPMDs were deployed. As was found in 2004, the highest potential toxicity in 2007 was observed at Lincoln Creek where chemical screening in 2007 also showed the highest total PAHs of all six sites; however, potential toxicity at Little Menomonee River, Honey Creek, and Kinnickinnic River was relatively high compared to Milwaukee River near Cedarburg. Although toxicity and chemical results in 2007 did not agree with aggregate rankings for Lincoln Creek because of fish, nor for Honey Creek, the results did agree with aggregate rankings at four of the six sites. In addition to toxicological and chemical influences, the more urbanized sites have high percentages of impervious surface area, resulting in frequent high stream flows that can adversely affect algal, invertebrate, and fish assemblages. Assessments of the ecological status of different groups of organisms and of potential chemical and physical stressors to organisms are important tools in evaluating streamwater quality.

Wisconsin↗

USGS2024

An update of hydrologic conditions and distribution of selected constituents in water, eastern Snake River aquifer and perched groundwater zones, Idaho National Laboratory, Idaho, emphasis 2019–21

Since 1952, wastewater discharged to infiltration ponds (also called “percolation ponds”) and disposal wells at the Idaho National Laboratory (INL) has affected water quality in the eastern Snake River Plain (ESRP) aquifer and perched groundwater zones underlying the INL. The U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Energy (DOE), maintains groundwater-monitoring networks at the INL to determine hydrologic trends and to delineate the movement of radiochemical and chemical wastes in both the aquifer and perched groundwater zones. This report presents an analysis of water-level and water-quality data collected from the ESRP aquifer and perched groundwater wells from the USGS groundwater monitoring networks during 2019–21. From March–May 2018 to March–May 2021, water levels in wells completed in the ESRP aquifer increased in the northern part of the INL and decreased in the southwestern part. Water-level increases ranged from 0.02 to 1.04 feet in the northern part and decreases ranged from 0.03 to 2.94 feet in the southwestern part of the INL. Detectable concentrations of radiochemical constituents in water samples from wells in the ESRP aquifer at the INL generally decreased or remained constant during 2019–21. Decreases in concentrations were attributed to radioactive decay, changes in waste-disposal methods, and dilution from recharge and underflow. In 2021, tritium was detected above reporting levels in water samples collected from 46 of 105 aquifer wells and ranged from 150±50 to 4,280±150 picocuries per liter (pCi/L). Tritium concentrations from eight wells completed in deep perched groundwater near the Advanced Test Reactor Complex (ATRC) generally were greater than or equal to the reporting level during at least one sampling event during 2019–21, and concentrations ranged from 160±50 to 2,097±107 pCi/L. Concentrations of strontium-90 in water from 12 of 45 aquifer wells sampled in 2021 exceeded the reporting level, and concentrations ranged from 2.5±0.7 to 299±6 pCi/L. During 2021, concentrations of strontium-90 from five wells completed in deep perched groundwater at the ATRC equaled or exceeded the reporting levels, and concentrations ranged from 3±0.9 pCi/L to 27.8±1.3 pCi/L. Concentrations of cesium-137 were less than the reporting level in all but one aquifer well, and concentrations of plutonium-238, plutonium-239, -240 (undivided), and americium-241 were less than the reporting level in water samples from all aquifer wells sampled during this study period. Dissolved chromium concentrations in water samples from 64 ESRP aquifer wells ranged from less than (<) 0.5 to 76.4 micrograms per liter (μg/L). During 2019–21, dissolved chromium was detected in water from wells completed in deep perched groundwater above the ESRP aquifer at the ATRC, and concentrations ranged from <1 to 82.1 μg/L. In 2021, concentrations of dissolved sodium in water from most ESRP aquifer wells in the southern part of the INL were greater than the western tributary groundwater background concentration of 8.3 milligrams per liter (mg/L). During 2021, dissolved sodium concentrations in water from 15 wells completed in deep perched groundwater ranged from 11.7 to 122.5 mg/L. Variations in sodium concentrations in aquifer wells and perched groundwater zones are attributed to either migration of remnant water from the former chemical-waste ponds or disposal volume and composition variability in percolation ponds installed in 2008. In 2021, concentrations of chloride in most water samples from ESRP aquifer wells south of the Idaho Nuclear Technology and Engineering Center (INTEC) and at the Central Facilities Area (CFA) exceeded background concentrations. Chloride concentrations in water from wells south of the INTEC have generally decreased because of discontinued chloride disposal to the legacy percolation ponds since 2002 when the discharge of wastewater was discontinued. During 2019–21, dissolved chloride concentrations in deep perched groundwater above the ESRP aquifer from 18 wells at the ATRC ranged from 8.15 to 231 mg/L. In 2021, sulfate concentrations in water samples from ESRP aquifer wells in the south-central part of the INL that exceeded the background concentration of sulfate, ranged from 21 to 141 mg/L. The greater-than-background concentrations in water from these wells are attributed to sulfate disposal at the ATRC infiltration ponds or the legacy INTEC percolation ponds. In 2021, sulfate concentrations in water samples from aquifer wells near the Radioactive Waste Management Complex (RWMC) were mostly greater than background concentrations. The maximum dissolved sulfate concentration in shallow perched groundwater near the ATRC was 575 mg/L in 2021. During 2021, dissolved sulfate concentrations in water from wells completed in deep perched groundwater near the cold waste ponds at the ATRC ranged from 22.3 to 519 mg/L. In 2021, concentrations of nitrate in water from most ESRP aquifer wells at and near the INTEC exceeded the western tributary groundwater background concentration of 0.655 mg/L. Concentrations of nitrate in aquifer wells southwest of INTEC and farther away from the influence of disposal areas and the Big Lost River, in intermittent source of surface water recharge to the aquifer, show a general decrease in nitrate concentration over time. Two aquifer wells south of INTEC show increasing trends that could result from wastewater beneath the INTEC tank farm being mobilized to the aquifer. During 2019–21, water samples from several ESRP aquifer wells were collected and analyzed for volatile organic compounds (VOCs). Twelve VOCs were detected, and 1–4 VOCs were detected in water samples from 10 wells. The most frequently detected VOCs include carbon tetrachloride (tetrachloromethane), trichloromethane, tetrachloroethene, 1,1,1-trichloroethane, and trichloroethene. In 2019–21, concentrations for all VOCs were less than their respective maximum contaminant levels (MCLs) for drinking water, except carbon tetrachloride in one well, trichloroethene in two wells, and vinyl chloride in one well. During 2019–21, variability and bias were evaluated from 34 replicate and 14 blank quality-assurance samples. Results from replicate analyses were investigated to evaluate sample variability. Constituents with acceptable reproducibility were major ions, trace elements, nutrients, and VOCs. All radiochemical constituents including gross alpha- and beta- radioactivity, strontium-90, cesium-137, and tritium, had acceptable reproducibility. Bias from sample contamination was evaluated from equipment, field, and source-solution blanks. Chloride and sulfate were detected slightly above their respective method detection limits in equipment and field blanks, but at concentrations well below the co-collected sample for that well. These chloride and sulfate detections in the field and equipment blanks were inconsequential because they weren’t detected above the analysis-specific variability for those constituents as determined by replicate sample result evaluation. None of the detections of nutrients and trace inorganic constituents were high enough to indicate environmental sample or analytical procedure bias.

Idaho↗

USGS2008

Private Domestic-Well Characteristics and the Distribution of Domestic Withdrawals among Aquifers in the Virginia Coastal Plain

A comprehensive analysis of private domestic wells and self-supplied domestic ground-water withdrawals in the Coastal Plain Physiographic Province of Virginia indicates that the magnitudes of these withdrawals and their effects on local and regional ground-water flow are larger and more important than previous reports have stated. Self-supplied ground-water withdrawals for domestic use in the Virginia Coastal Plain are estimated to be approximately 40 million gallons per day, or about 28 percent of all ground-water withdrawals in the area. Contrary to widely held assumptions, only 22 percent of domestic wells in the Virginia Coastal Plain are completed in the shallow, unconfined surficial aquifer to which the water is returned directly by home septic systems. Fifty-three percent of the wells are completed in six deeper confined aquifers, and the remaining 25 percent are completed in the Potomac aquifer and confining zone, the deepest units in the confined system. Assuming an equal rate of withdrawal per well, 78 percent of domestic ground-water withdrawal, or about 30 million gallons per day, is removed from the regional confined ground-water system. Domestic ground-water withdrawal from an estimated 200,000 private wells supplies more than 15 percent of the population of the area and provides almost the entire source of water in some rural counties. The geographic distribution of these withdrawals is dependent on the self-supplied population and is highly variable. Domestic-well characteristics vary spatially as well, primarily because of geographic differences in depths to particular aquifers, but also because of well-drilling practices that are influenced by geographic, regulatory, and socioeconomic factors. Domestic ground-water withdrawals in the Virginia Coastal Plain were characterized as part of a larger study to analyze the regional ground-water flow system. Characterizing the withdrawals required differentiation of the withdrawals among the aquifers in the area in addition to determination of the geographic distribution of the withdrawals. Because of a lack of comprehensive data on private-well construction and distribution, a sample of private domestic-well records was used to estimate well characteristics and approximate the proportion of wells and withdrawals associated with each aquifer. Construction data on 2,846 private domestic wells were collected from 29 counties and independent cities (localities) having appreciable self-supplied populations and representing private domestic withdrawals of about 31 million gallons per day. Within each locality, geographically stratified random sampling of well records by tax plat characterized details of well construction for the population of domestic wells. Because neither specific location data nor aquifer elevations were available for individual wells, the primary aquifer in which each well is completed was estimated by cross-referencing the screen elevation estimated from the well record with a generalized configuration of hydrogeologic units underlying the locality in which the well is located. For each locality, summarizing the results of this process allowed the determination of the proportion of wells and withdrawals associated with each aquifer. Additional evaluation of spatial data was used to apply the domestic withdrawal rates developed for each aquifer in each locality to a detailed ground-water study of the portion of the Virginia Coastal Plain east of the Chesapeake Bay, which is known as the Eastern Shore Peninsula. Because domestic withdrawal estimates are based on the self-supplied population, the geographic distribution of withdrawals within each of the Eastern Shore counties was estimated by using population data from the 2000 U.S. Census at the resolution of census block groups and further refining the distribution based on road density. The allocation of withdrawals among aquifers was then determined by cross-referencing the spatial distribut

Scientific Investigations Report↗

USGS2023

Interaction of a legacy groundwater contaminant plume with the Little Wind River from 2015 through 2017, Riverton Processing site, Wyoming

The Riverton Processing site was a uranium mill 4 kilometers southwest of Riverton, Wyoming, that prepared uranium ore for nuclear reactors and weapons from 1958 to 1963. The U.S. Department of Energy completed surface remediation of the uranium tailings in 1989; however, groundwater below and downgradient from the tailings site and nearby Little Wind River was not remediated. Beginning in 2010, a series of floods along the Little Wind River began to mobilize contaminants in the unsaturated zone, resulting in substantial increases of uranium and other contaminants of concern in monitoring wells completed inside the contaminant plume. In 2011, the U.S. Department of Energy started a series of university and Government agency retrospective and field investigations to understand the processes controlling contaminant increases in the groundwater plume. The goals of the field investigations described in this report were to (1) identify and quantify the contaminant flux and potential associated biological effects from groundwater associated with the legacy plume as it enters a perennial stream reach, and (2) assess chemical exposure and potential effects to biological receptors from the interaction of the contaminant plume and the river. Field investigations along the Little Wind River were completed by the U.S. Geological Survey during 2015–17 in cooperation with the U.S. Department of Energy Office of Legacy Management to characterize: (1) seepage areas and seepage rates; (2) pore-water and bed sediment chemistry and hyporheic exchange and reactive loss; and (3) exposure pathways and biological receptors. All data collected during the study are contained in two U.S. Geological Survey data releases, available at https://doi.org/10.5066/F7BR8QX4 and https://doi.org/10.5066/P9J9VJBR . A variety of tools and methods were used during the field characterizations. Streambed temperature mapping, electrical resistivity tomography, electromagnetic induction, fiber-optic distributed temperature sensing, tube seepage meters, vertical thermal sensor arrays, and an environmental tracer (radon) were used to identify areas of groundwater seepage and associated seepage rates along specific sections of the study reach of the river. Drive points, minipiezometers, diffusive equilibrium in thin-film/diffusive gradients in thin-film probes, bed-sediment samples, and equal discharge increment sampling methods were used to characterize pore-water chemistry, estimate hyporheic exchange and reactive loss of selected chemical constituents, and quantify contaminant loadings entering the study reach. Sampling and analysis of surface sediments, filamentous algae, periphytic algae, and macroinvertebrates were used to characterize biological exposure pathways, metal uptake, and receptors. Areas of focused groundwater discharge identified by the fiber-optic distributed temperature sensing surveys corresponded closely with areas of elevated electrical conductivity identified by the electromagnetic induction survey results in the top 5 meters of sediment. During three monitoring periods in 2016, the mean vertical seepage rate measured with tube seepage meters was 0.45 meter per day, ranging from −0.02 to 1.55 meters per day. Five of the 11 locations where vertical thermal profile data were collected along the study reach during August 2017 indicated mean upwelling values ranging from 0.11 to 0.23 meter per day. Radon data collected from the Little Wind River during June, July, and August 2016 indicated a consistent inflow of groundwater to the central part of the study reach, in the area congruous with the center of the previously mapped groundwater plume discharge zone. During August 2017, the greatest attenuation of uranium from reactive loss in pore-water samples was observed at three locations along the study reach, at depths between 6 and 15 centimeters, and similar trends in molybdenum attenuation were also observed. Bed-sediment concentration profiles collected during 2017 also indicated attenuation of uranium and molybdenum from groundwater during hyporheic mixing of surface water with the legacy plume during groundwater upwelling into the river. Streamflow measurements combined with equal discharge increment water sampling along the study reach indicated an increase in dissolved uranium concentrations in the downstream direction during 2016 and 2017. Net uranium load entering the Little Wind River study reach was about 290 and 435 grams per day during 2016 and 2017, respectively. Biological samples indicated that low levels of uranium and molybdenum exposure were confined to the benthos in the Little Wind River within and immediately downstream from the perimeter of the groundwater plume. Concentrations of molybdenum and uranium in filamentous algae were consistently low at all sites in the study reach with no indication of increased exposure of dissolved bioavailable molybdenum or uranium at sites next to or downstream from the groundwater plume. Comparison of the August 2017 results from electromagnetic induction, tube seepage meters, vertical thermal profiling, and pore-water chemistry surveys were in general agreement in identifying areas with upwelling groundwater conditions along the study reach. However, the electroconductivity values measured with electromagnetic induction in the top 100 centimeters of sediment did not agree with sodium concentrations measured in pore-water samples collected at similar streambed depths. Differences and similarities between multiple methods can result in additional insights into hydrologic and biogeochemical processes that may be occurring along a reach of a river system interacting with shallow groundwater inputs. It may be advantageous to apply a variety of geophysical, geochemical, hydrologic, and biological tools at other Uranium Mill Tailings Remedial Action ( https://www.energy.gov/sites/prod/files/2014/10/f19/UMTRCA.pdf ) sites during the investigation of legacy contaminant plume interactions with surface-water systems.

Wyoming↗

USGS2009

Ecological assessment of streams in the Powder River Structural Basin, Wyoming and Montana, 2005-06

Energy and mineral development, particularly coalbed natural gas development, is proceeding at a rapid pace in the Powder River Structural Basin (PRB) in northeastern Wyoming. Concerns about the potential effects of development led to formation of an interagency working group of primarily Federal and State agencies to address these issues in the PRB in Wyoming and in Montana where similar types of resources exist but are largely undeveloped. Under the direction of the interagency working group, an ecological assessment of streams in the PRB was initiated to determine the current status (2005–06) and to establish a baseline for future monitoring. The ecological assessment components include assessment of stream habitat and riparian zones as well as assessments of macroinvertebrate, algal, and fish communities. All of the components were sampled at 47 sites in the PRB during 2005. A reduced set of components, consisting primarily of macroinvertebrate and fish community assessments, was sampled in 2006. Related ecological data, such as habitat and fish community data collected from selected sites in 2004, also are included in this report. The stream habitat assessment included measurement of channel features, substrate size and embeddedness, riparian vegetation, and reachwide characteristics. The width-to-depth ratio (bankfull width/bankfull depth) tended to be higher at sites on the main-stem Powder River than at sites on the main-stem Tongue River and at sites on tributary streams. The streambed substrate particle size was largest at sites on the main-stem Tongue River and smallest at sites on small tributary streams such as Squirrel Creek and Otter Creek. Total vegetative cover at the ground level, understory, and canopy layers ranged from less than 40 percent at a few sites to more than 90 percent at many of the sites. A bank-stability index indicated that sites in the Tongue River drainage were less at risk of bank failure than sites on the main-stem Powder River. Macroinvertebrate communities showed similarity at the river-drainage scale. Macroinvertebrate communities at sites with mountainous headwaters and snowmelt-driven hydrology, such as Clear Creek, Crazy Woman Creek, and Goose Creek, showed similarity with communities from the main-stem Tongue River. The data also indicated similarity among sites on the main-stem Powder River and among small tributaries of the Tongue River. Data analyses using macroinvertebrate observed/expected models and multimetric indices developed by the States of Wyoming and Montana indicated a tendency toward declining biological condition in the downstream direction along the Tongue River. Biological condition for the main-stem Powder River generally improved downstream, from below Salt Creek to near the Wyoming/Montana border, followed by a general decline downstream from the border to the confluence with the Yellowstone River. The biological condition generally was not significantly different between 2005 and 2006, although streamflow was less in 2006 because of drought. Algal communities showed similarity at the river-drainage scale with slight differences from the pattern observed in the macroinvertebrate communities. Although the algal communities from Clear Creek and Goose Creek were similar to those from the main-stem Tongue River, as was true of the macroinvertebrate communities, the algal communities from Crazy Woman Creek had more similarity to those of main-stem Powder River sites than to the Tongue River sites, contrary to the macroinvertebrates. Ordination of algal communities, as well as diatom metrics including salinity and dominant taxa, indicated substantial variation at two sites along the main stem of the Powder River. Fish communities of the PRB were most diverse in the Tongue River drainage. In part due to the effects of Tongue River Reservoir, 15 species of fish were found in the Tongue River drainage that were not found in the Cheyenne, Belle Fourche, or Little Powder River drainages. The number of introduced species and relative abundance of introduced species of fish were higher in the Tongue River and other drainages than at sites on the main-stem Powder River. Although non-native species were identified in the Powder River, the native fish community is largely intact. Western silvery minnow and sturgeon chub—species of special concern—were identified only at sites on the main-stem Powder River and were most common in the Montana segment of the main stem. Fish and habitat sampling on the main-stem Powder River indicated affinity of some species for certain habitats such as pools, runs, riffles, backwaters, or shoals.

Montana, Wyoming↗

USGS2021

Discharge and dissolved-solids characteristics of Blacks Fork above Smiths Fork, Wyoming, April 2018 through September 2019

The Colorado River Basin Salinity Control Forum was formed in 1973 to coordinate salinity control efforts among the States in the Colorado River Basin, including Wyoming. The Colorado River Salinity Control Act of 1974 (Public Law 93–320) authorized “the construction, operation, and maintenance of certain works in the Colorado River Basin to control the salinity of water delivered to users in the United States and Mexico.” Water-quality standards for salinity in the lower Colorado River Basin were adopted in 1975. To help meet these standards, the Bureau of Reclamation, Natural Resource Conservation Service, and States within the Colorado River Basin have implemented salinity control projects that focus on reducing salt loading associated with irrigated agriculture by improving water delivery systems and water management practices. The term salinity is synonymous with dissolved solids in this report. The Bureau of Reclamation, in conjunction with the Colorado River Basin Salinity Control Forum, was interested in determining the contribution of dissolved solids from Blacks Fork above Smiths Fork to the Colorado River and initiated a study of Blacks Fork above Smiths Fork in 2018. In early 2018, the U.S. Geological Survey installed a streamgage at the most downstream location on the Blacks Fork, upstream from the convergence with Smiths Fork, to characterize the stream. The Blacks Fork above Smiths Fork, near Lyman, Wyoming, streamgage (U.S. Geological Survey identifier 09219200) was operated from April 4, 2018, through September 30, 2019, collecting continuous stream stage and specific-conductance data, from which continuous discharge, dissolved-solids concentrations, and dissolved-solids loads were calculated. Seven sites were selected on Blacks Fork and a tributary to describe a snapshot of the discharge and dissolved-solids characteristics. These sites were sampled during July, August, and September 2018 and June, July, August, and September 2019 report. Discharge at the Blacks Fork above Smiths Fork, near Lyman, Wyo., streamgage (09219200) from April through September in 2018 was lower and less variable than during the same period in 2019. The mean daily (mean of the daily means) discharge during those 6 months in 2018 (15.1 cubic feet per second [ft 3 /s]) was about one-tenth of the discharge during the same period in 2019 (152 ft 3 /s). The cumulative monthly discharge during April through September in 2018 was 5,360 acre-feet, about one-tenth of the discharge during the same period in 2019 which was 54,700 acre-feet. Similar differences in discharge between the 2018 and 2019 periods also are noted at other Blacks Fork streamgages in the area. Continuous specific conductance data and the statistical relation between specific conductance and dissolved-solids concentrations were used to calculate the daily mean dissolved-solids concentrations. Dissolved solids often have an inverse relation with discharge because higher discharges typically have a diluting effect that lowers the dissolved-solids concentrations. In general, when discharges at the Blacks Fork above Smiths Fork streamgage (09219200) are higher, dissolved-solids concentrations are generally lower. However, the high dissolved-solids concentrations that are measured during high discharges indicate that the system has natural variability and the dissolved-solids concentrations are determined by more factors than just discharge. The mean daily dissolved-solids concentration during April through September 2018 was 1,630 milligrams per liter and during the same period in 2019 was 1,100 milligrams per liter. Dissolved-solids loads were calculated as the product of the discharge and dissolved-solids concentration. The daily mean dissolved-solids loads during 2018 were typically lower than during 2019. This result is primarily because the discharge was much lower in 2018 than in 2019. Therefore, although the daily mean dissolved-solids concentrations tended to be higher in 2018, the substantially higher discharges in 2019 had more of an effect on the dissolved-solids loads than the dissolved-solids concentrations. The cumulative dissolved-solids load at the Blacks Fork above Smiths Fork, near Lyman, Wyo., streamgage (09219200) during the 18-month study was 81,200 tons, with a mean daily load of 149 tons per day. During the 6-month period from April through September 2018, the cumulative dissolved-solids load at the streamgage was estimated to be 8,740 tons and, during the same 6 months in 2019, the cumulative dissolved-solids load was estimated to be 60,900 tons. During the fall and winter between the two periods, the cumulative dissolved-solids load was 11,600 tons. Discharge and dissolved-solids concentrations from samples collected during the synoptic sampling events were highly variable among most sites during most synoptic sampling events and also highly variable at most sites among different sampling events. The two sites upstream from the tributary input from Threemile Creek had lower dissolved-solids concentrations than sites including and downstream from the tributary. Sites including and downstream from the tributary had similar values and variability of dissolved-solids loads, with the exception of the farthest downstream site at the Blacks Fork above Smiths Fork, near Lyman, Wyo., streamgage (09219200) that tended to have larger dissolved-solids loads and higher variability among synoptic sampling events.

Scientific Investigations Report↗