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Quality-control results for ground-water and surface-water data, Sacramento River Basin, California, National Water-Quality Assessment, 1996-1998

Evaluating the extent that bias and variability affect the interpretation of ground- and surface-water data is necessary to meet the objectives of the National Water-Quality Assessment (NAWQA) Program. Quality-control samples used to evaluate the bias and variability include annual equipment blanks, field blanks, field matrix spikes, surrogates, and replicates. This report contains quality-control results for the constituents critical to the ground- and surface-water components of the Sacramento River Basin study unit of the NAWQA Program. A critical constituent is one that was detected frequently (more than 50 percent of the time in blank samples), was detected at amounts exceeding water-quality standards or goals, or was important for the interpretation of water-quality data. Quality-control samples were collected along with ground- and surface-water samples during the high intensity phase (cycle 1) of the Sacramento River Basin NAWQA beginning early in 1996 and ending in 1998. Ground-water field blanks indicated contamination of varying levels of significance when compared with concentrations detected in environmental ground-water samples for ammonia, dissolved organic carbon, aluminum, and copper. Concentrations of aluminum in surface-water field blanks were significant when compared with environmental samples. Field blank samples collected for pesticide and volatile organic compound analyses revealed no contamination in either ground- or surface-water samples that would effect the interpretation of environmental data, with the possible exception of the volatile organic compound trichloromethane (chloroform) in ground water. Replicate samples for ground water and surface water indicate that variability resulting from sample collection, processing, and analysis was generally low. Some of the larger maximum relative percentage differences calculated for replicate samples occurred between samples having lowest absolute concentration differences and(or) values near the reporting limit. Surrogate recoveries for pesticides analyzed by gas chromatography/mass spectrometry (GC/MS), pesticides analyzed by high performance liquid chromatography (HPLC), and volatile organic compounds in ground- and surface-water samples were within the acceptable limits of 70 to 130 percent and median recovery values between 82 and 113 percent. The recovery percentages for surrogate compounds analyzed by HPLC had the highest standard deviation, 20 percent for ground-water samples and 16 percent for surface-water samples, and the lowest median values, 82 percent for ground-water samples and 91 percent for surface-water samples. Results were consistent with the recovery results described for the analytical methods. Field matrix spike recoveries for pesticide compounds analyzed using GC/MS in ground- and surface-water samples were comparable with published recovery data. Recoveries of carbofuran, a critical constituent in ground- and surface-water studies, and desethyl atrazine, a critical constituent in the ground-water study, could not be calculated because of problems with the analytical method. Recoveries of pesticides analyzed using HPLC in ground- and surface-water samples were generally low and comparable with published recovery data. Other methodological problems for HPLC analytes included nondetection of the spike compounds and estimated values of spike concentrations. Recovery of field matrix spikes for volatile organic compounds generally were within the acceptable range, 70 and 130 percent for both ground- and surface-water samples, and median recoveries from 62 to 127 percent. High or low recoveries could be related to errors in the field, such as double spiking or using spike solution past its expiration date, rather than problems during analysis. The methodological changes in the field spike protocol during the course of the Sacramento River Basin study, which included decreasing the amount of spike solu

Water-Resources Investigations Report↗

Apparent chlorofluorocarbon age of ground water of the shallow aquifer system, Naval Weapons Station Yorktown, Yorktown, Virginia

Apparent ages of ground water are useful in the analysis of various components of flow systems, and results of this analysis can be incorporated into investigations of potential pathways of contaminant transport. This report presents the results of a study in 1997 by the U.S. Geological Survey (USGS), in cooperation with the Naval Weapons Station Yorktown, Base Civil Engineer, Environmental Directorate, to describe the apparent age of ground water of the shallow aquifer system at the Station. Chlorofluorocarbons (CFCs), tritium ( 3 H), dissolved gases, stable isotopes, and water-quality field properties were measured in samples from 14 wells and 16 springs on the Station in March 1997. Nitrogen-argon recharge temperatures range from 5.9°C to 17.3°C with a median temperature of 10.9°C, which indicates that ground-water recharge predominantly occurs in the cold months of the year. Concentrations of excess air vary depending upon geohydrologic setting (recharge and discharge areas). Apparent ground-water ages using a CFC-based dating technique range from 1 to 48 years with a median age of 10 years. The oldest apparent CFC ages occur in the upper parts of the Yorktown-Eastover aquifer, whereas the youngest apparent ages occur in the Columbia aquifer and the upper parts of the discharge area setting, especially springs. The vertical distribution of apparent CFC ages indicates that groundwater movement between aquifers is somewhat retarded by the leaky confining units, but the elapsed time is relatively short (generally less than 35 years), as evidenced by the presence of CFCs at depth. The identification of binary mixtures by CFC-based dating indicates that convergence of flow lines occurs not only at the actual point of discharge, but also in the subsurface. The CFC-based recharge dates are consistent with expected 3 H concentrations measured in the water samples from the Station. The concentration of 3H in ground water ranges from below the USGS laboratory minimum reporting limit of 0.3 to 15.9 tritium units (TU) with a median value of 10.8 TU. Water-quality field properties are highly variable for ground water with apparent CFC ages less than 15 years because of geochemical processes within local flow systems. Ground water with apparent CFC ages greater than 15 years represents more stable conditions in subregional flow systems. The range of apparent CFC ages is slightly greater than the ranges in time of travel of ground water calculated for shallow wells (less than 60- feet deep) from flow-path analysis. Calculated travel times to springs can be up to two orders of magnitude greater than the CFC-based apparent ages. Reasonable assumptions of values for hydraulic parameters can result in substantial overestimates for time of travel to springs. Recharge rates computed from apparent CFC ages range from 0.29 to 0.89 feet per year (ft/ yr) with an average value of 0.54 ft/yr. The analysis of apparent CFC ages in conjunction with geohydrologic data indicates that young water (less than 50 years) is present at depth (nearly 120 feet) and that both local and subregional flow systems occur in the shallow aquifer system at the Station. The addition of the dimension of time to the three-dimensional framework of Brockman and others (1997) will benefit current (2001) and future remediation activities by providing estimates of advective transport rates and how these rates vary depending upon geohydrologic setting and position within the ground-water-flow system. Estimated ground-water apparent ages and recharge rates can be used as calibration criteria in simulations of ground-water flow on the Station to refine and constrain future ground-water-flow models of the shallow aquifer system.

Virginia↗

Water-quality assessment of the Cook Inlet Basin, Alaska — Summary of data through 1997

Among the first activities undertaken in each National Water-Quality Assessment (NAWQA) investigation are the compilation, screening, and statistical summary of available data concerning water-quality conditions in the study unit. The water-quality conditions of interest are those that are representative of the general ambient water quality of a given stream reach or area of an aquifer. This report identifies which existing water-quality data are suitable for characterizing general conditions in a nationally consistent manner and describes, to the extent possible, general water-quality conditions in the Cook Inlet Basin in southcentral Alaska. The study unit consists of all lands that drain into Cook Inlet, but not the marine environment itself. Surface-water-quality data are summarized for 31 sites on streams. Ground-water quality data are summarized for four regions using analyses from about 550 wells that yield water from unconsolidated glacial and alluvial deposits and analyses from 17 wells in western Cook Inlet, some of which may yield water from coal or weakly consolidated sandstone or conglomerate. The summaries focus on the central tendencies and typical variations in the data and use nonparametric statistics such as frequencies and percentile values. Few surface- and ground-water sites have long-term water-quality records and very few data are available for dissolved oxygen, nutrients, metals, trace elements, organic compounds, and radionuclides. In general, most waters in streams and wells have small concentrations of major inorganic constituents, nutrients, trace elements, and organic compounds. Most streams have water that is generally suitable for drinking-water supply, the growth and propagation of cold-water anadromous fish, and water-contact recreation. However, suspended-sediment concentrations in glacier-fed streams are naturally high and can make water from glacier-fed streams unsuitable for many uses unless the water is treated to remove the suspended sediment. Several streams and lakes in Anchorage have fecal coliform bacteria concentrations higher than allowed for drinking or water-contact recreation. Ground water in the major withdrawal regions is generally suitable for drinking and most other purposes, but some wells yield water having nitrate, iron, or arsenic concentrations higher than drinking-water criteria. Ground-water quality has been degraded in several areas as the result of leaks or spills of petroleum products.

Alaska↗

Geologic and well-construction data for the H-8 borehole complex near the proposed Waste Isolation Pilot Plant site, southeastern New Mexico

The H-8 complex, a group of three closely-spaced boreholes, is located 9 miles south of the proposed Waste Isolation Pilot Plant site in southeastern Eddy County, New Mexico. The holes were drilled during July, August, and September of 1979 to obtain geologic and hydrologic data to better define the regional ground-water-flow system. The geologic data presented in this report are part of a site-characterization study for the possible disposal of defense-associated radioactive wastes within salt beds of the Salado Formation of Permian age. The geologic data include detailed descriptions of cores, cuttings, and geophysical logs. Each borehole was designed to penetrate a distinct water-bearing zone: H-8a (total depth 505 feet) was completed just below the Magenta Dolomite Member of the Rustler Formation of Permian Age; H-8b (total depth 624 feet) was completed just belows the Culebra Dolomite Member of the Rustler Formation; and H-8c (total depth 808 feet) was completed just below the Rustler Formation-Salado Formation contact. The geologic units penetrated in borehole H-8c are surficial alluvium and eolian sand of Holocene age (0-4 feet); the Mescalero caliche (4-10 feet) and Gatuna Formation (10-153 feet) , both of Pleistocene age; and the Dewey Lake Red Beds (153-399 feet), the Rustler Formation (399-733 feet), and part of the Salado Formation penetrated by borehole H-8c is composed of residue from dissolution of halite and associated rocks, and the hydration of anhydrite to gypsum, indicating that the eastward-moving dissolution front on top of the Salado, found just to the west of the WIPP site, has reached the H-8 site. (USGS)

Water-Resources Investigations Report↗

Benthic invertebrates of fixed sites in the western Lake Michigan drainages, Wisconsin and Michigan, 1993-95

This report describes the variability in family-level benthic-invertebrate population data and the reliability of the data as a water-quality indicator for 11 fixed surface-water sites in the Western Lake Michigan Drainages study area of the National Water-Quality Assessment Program. Benthic-invertebrate-community measures were computed for the following: number of individuals, Hilsenhoff’s Family-Level Biotic Index, number and percent EPT (Ephemeroptera, Plecoptera, and Tricoptera), Margalef’s Diversity Index, and mean tolerance value. Relations between these measures and environmental setting, habitat, and of chemical water quality are examined. Benthic-invertebrate communities varied greatly among fixed sites and within individual streams among multiple-reach and multiple-year sampling. The variations between multiple reaches and years were sometimes larger than those found between different fixed sites. Factors affecting benthic invertebrates included both habitat and chemical quality. Generally, fixed-site streams with the highest diversity, greatest number of benthic invertebrates, and those at which community measures indicated the best water quality also had the best habitat and chemical quality. Variations among reaches are most likely related to differences in habitat. Variations among years are most likely related to climatic changes, which create variations in flow and/or chemical quality. The variability in the data analyzed in this study shows how benthic invertebrates are affected by differences in both habitat and water quality, making them useful indicators of stream health; however, a single benthic-invertebrate sample alone cannot be relied upon to accurately describe water quality of the streams in this study. Benthic-invertebrate data contributed valuable information on the biological health of the 11 fixed sites when used as one of several data sources for assessing water quality.

Michigan, Wisconsin↗

Hydrology of, and water quality in, the open burning area and vicinity, Picatinny Arsenal, New Jersey, 1989-90

This report presents the results of a study to determine whether shallow ground water at Picatinny Arsenal Morris County, New Jersey, has been con- taminated as a result of operations at the open burning area, which is used for burning of waste explosives and materials contaminated with explosives. Results of previous investigations indicate that the soil in this area is contaminated with metals and organic compounds. Twenty-seven wells were sampled for analysis for inorganic constituents, nutrients, and explosive compounds. Selected wells also were sampled for analysis for base/neutral- and acid-extractable compounds, pesticides, volatile organic compounds, and dioxin and furan compounds. Surface-water and streambed- material samples were collected at three sites in Green Pond Brook. Water-level measurements indicate that ground-water flow generally is nearly horizontal and toward Green Pond Brook. The average velocity of the ground water is estimated to be 0.03 to 1.8 feet per day. Concentrations of iron and manganese in ground-water samples from the unconfined aquifer were consistently greater than U.S. Environmental Protection Agency secondary drinking-water regulations. Because similarly high concentrations of these constituents have been found in ground-water samples at the arsenal, they are not considered to be a consequence of activities at the open burning area. Contaminants from the open burning area appear to be contributing to elevated concentratons of lead, zinc, and explosive com- pounds found in the streambed material. Other trace element and polynuclear aromatic hydrocarbons probably are derived from both the open burning area and upstream sources. Volatile organic compounds were detected in surface-water samples at low concentrations, although most were found upstream from the open burning area. No inorganic or organic constituents were detected in ground-water or surface-water samples in concentrations that exceeded U.S. Environmental Protection Agency primary drinking-water regulations.

New Jersey↗

Cost-effectiveness of the streamflow-gaging program in Wyoming

This report documents the results of a cost-effectiveness study of the streamflow-gaging program in Wyoming. Regression analysis or hydrologic flow-routing techniques were considered for 24 combinations of stations from a 139-station network operated in 1984 to investigate suitability of techniques for simulating streamflow records. Only one station was determined to have sufficient accuracy in the regression analysis to consider discontinuance of the gage. The evaluation of the gaging-station network, which included the use of associated uncertainty in streamflow records, is limited to the nonwinter operation of the 47 stations operated by the Riverton Field Office of the U.S. Geological Survey. The current (1987) travel routes and measurement frequencies require a budget of $264,000 and result in an average standard error in streamflow records of 13.2%. Changes in routes and station visits using the same budget, could optimally reduce the standard error by 1.6%. Budgets evaluated ranged from $235,000 to $400,000. A $235,000 budget increased the optimal average standard error/station from 11.6 to 15.5%, and a $400,000 budget could reduce it to 6.6%. For all budgets considered, lost record accounts for about 40% of the average standard error. (USGS)

Water-Resources Investigations Report↗

A modular finite-element model (MODFE) for areal and axisymmetric ground-water-flow problems, Part 2: Derivation of finite-element equations and comparisons with analytical solutions

MODFE, a modular finite-element model for simulating steady- or unsteady-state, area1 or axisymmetric flow of ground water in a heterogeneous anisotropic aquifer is documented in a three-part series of reports. In this report, part 2, the finite-element equations are derived by minimizing a functional of the difference between the true and approximate hydraulic head, which produces equations that are equivalent to those obtained by either classical variational or Galerkin techniques. Spatial finite elements are triangular with linear basis functions, and temporal finite elements are one dimensional with linear basis functions. Physical processes that can be represented by the model include (1) confined flow, unconfined flow (using the Dupuit approximation), or a combination of both; (2) leakage through either rigid or elastic confining units; (3) specified recharge or discharge at points, along lines, or areally; (4) flow across specified-flow, specified-head, or head-dependent boundaries; (5) decrease of aquifer thickness to zero under extreme water-table decline and increase of aquifer thickness from zero as the water table rises; and (6) head-dependent fluxes from springs, drainage wells, leakage across riverbeds or confining units combined with aquifer dewatering, and evapotranspiration. The matrix equations produced by the finite-element method are solved by the direct symmetric-Doolittle method or the iterative modified incomplete-Cholesky conjugate-gradient method. The direct method can be efficient for small- to medium-sized problems (less than about 500 nodes), and the iterative method is generally more efficient for larger-sized problems. Comparison of finite-element solutions with analytical solutions for five example problems demonstrates that the finite-element model can yield accurate solutions to ground-water flow problems.

Techniques of Water-Resources Investigations↗

Bacteriological quality of ground water used for household supply, Lower Susquehanna River basin, Pennsylvania and Maryland

This report describes the bacteriological results of a ground-water study conducted from 1993 to 1995 as part of the U.S. Geological Survey's National Water-Quality Assessment Program in the Lower Susquehanna River Basin study unit. Water samples collected from 146 household supply wells were analyzed for fecal-indicator organisms including total coliform, fecal coliform, Escherichia coli ( E. coli ), and fecal streptococcus concentrations. Supporting data used in the interpretations are selected water-quality constituents, well-construction information, and the environmental setting at the well site including land use, physiography, and bedrock type. Water from nearly 70 percent of the wells sampled had total coliform present and thus was not suitable for drinking without treatment. Fecal coliforms were found in water from approximately 25 percent of the sampled wells. E. coli testing was not conducted in 1993. Approximately 30 percent of the 88 sampled wells had waters with E. coli . Fecal streptococcus bacteria was present in water from about 65 percent of the wells sampled. Bacteriological contamination was more likely to occur in water from wells in agricultural areas than in water from wells in forested areas. Water from wells sampled in the Ridge and Valley Physiographic Province was more likely to have bacteria than water from wells in the Piedmont Physiographic Province. Differences in bacterial concentrations among bedrock types are only statistically significant for E. coli . Bacterial concentrations are weakly related to well-age but not to other well characteristics such as the total well depth or the casing length. Relations exist between bacterial concentrations and selected water-quality constituents. Most wells from which water was sampled did not have sanitary seals and very few were grouted. This may have contributed to the number of detections of bacteria. It is uncertain whether the bacteria detected are the result of widespread aquifer contamination or site-specific factors.

Maryland, Pennsylvania↗

Magnitude and frequency of floods in small drainage basins in Idaho

A method is presented in this report for determining magnitude and frequency of floods on streams with drainage areas between 0.5 and 200 square miles. The method relates basin characteristics, including drainage area, percentage of forest cover, percentage of water area, latitude, and longitude, with peak flow characteristics. Regression equations for each of eight regions are presented for determination of QIQ/ the peak discharge, which, on the average, will be exceeded once in 10 years. Peak flows, Q25 and Q 50 , can then be estimated from Q25/Q10 and Q-50/Q-10 ratios developed for each region. Nomographs are included which solve the equations for basins between 1 and 50 square miles. The regional regression equations were developed using multiple regression techniques. Annual peaks for 303 sites were analyzed in the study. These included all records on unregulated streams with drainage areas less than about 500 square miles with 10 years or more of record or which could readily be extended to 10 years on the basis of nearby streams. The log-Pearson Type III method as modified and a digital computer were employed to estimate magnitude and frequency of floods for each of the 303 gaged sites. A large number of physical and climatic basin characteristics were determined for each of the gaged sites. The multiple regression method was then applied to determine the equations relating the floodflows and the most significant basin characteristics. For convenience of the users, several equations were simplified and some complex characteristics were deleted at the sacrifice of some increase in the standard error. Standard errors of estimate and many other statistical data were computed in the analysis process and are available in the Boise district office files. The analysis showed that QIQ was the best defined and most practical index flood for determination of the Q25 and 0,50 flood estimates. Regression equations are not developed because of poor definition for areas which total about 20,000 square miles, most of which are in southern Idaho. These areas are described in the report to prevent use of regression equations where they do not apply. They include urbanized areas, streams affected by regulation or diversion by works of man, unforested areas, streams with gaining or losing reaches, streams draining alluvial valleys and the Snake Plain, intense thunderstorm areas, and scattered areas where records indicate recurring floods which depart from the regional equations. Maximum flows of record and basin locations are summarized in tables and maps. The analysis indicates deficiencies in data exist. To improve knowledge regarding flood characteristics in poorly defined areas, the following data-collection programs are recommended. Gages should be operated on a few selected small streams for an extended period to define floods at long recurrence intervals. Crest-stage gages should be operated in representative basins in urbanized areas, newly developed irrigated areas and grasslands, and in unforested areas. Unusual floods should continue to be measured at miscellaneous sites on regulated streams and in intense thunderstorm-prone areas. The relationship between channel geometry and floodflow characteristics should be investigated as an alternative or supplement to operation of gaging stations. Documentation of historic flood data from newspapers and other sources would improve the basic flood-data base.

Idaho↗

U.S. Geological Survey Toxic Substances Hydrology Program: Proceedings of the technical meeting, Charleston, South Carolina, March 8-12, 1999: Volume 1 (Part A)

This report contains papers presented at the seventh Technical Meeting of the U.S. Geological Survey (USGS), Toxic Substances Hydrology (Toxics) Program. The meeting was held March 8-12, 1999, in Charleston, South Carolina. Toxics Program Technical Meetings are held periodically to provide a forum for presentation and discussion of results of recent research activities. The objectives of these meetings are to: Present recent research results to essential stakeholders, Encourage synthesis and integrated interpretations among scientists with different expertise who are working on a contamination issue, and Promote exchange of ideas among scientists working on different projects and issues within the Toxics Program. The Proceedings is published in three volumes. Volume 1 contains papers that report on results of research on contamination from hard-rock mining. Results include research on contamination from hard rock mining in arid southwest alluvial basins, research on hard rock mining in mountainous terrain, and progress from the USGS Abandoned Mine Lands Initiative. This Initiative is designed to develop a watershed-based approach to characterize and remediate contamination from abandoned mine lands and transfer technologies to Federal land management agencies and stakeholders. Volume 2 contains papers on contamination of hydrologic systems and related ecosystems. The papers discuss research on the response of estuarine ecosystems to contamination from human activities. They include research on San Francisco Bay; mercury contamination of aquatic ecosystems; and investigation of the occurrence, distribution, and fate of agricultural chemicals in the Mississippi River Basin. This volume also contains results on development and reconnaissance testing of new methods to detect emerging contaminants in environmental samples. Volume 3 contains papers on subsurface contamination from point sources. The papers discuss research on: hydrocarbons and fuel oxygenates at gasoline release sites; ground-water contamination by crude oil; complex contaminant mixtures from treated wastewater discharges; waste disposal and subsurface transport of contaminants in arid environments; ground water and surface water affected by municipal landfill leachate; natural attenuation of chlorinated solvents; and characterizing flow and transport in fractured rock aquifers. In all, the more than 175 papers contained in this proceedings reflect the contributions of more than 350 scientists who are co-authors. These scientists are from across the USGS, as well as from universities, other Federal and State agencies, and industry.

Water-Resources Investigations Report↗

U.S. Geological Survey Toxic Substances Hydrology Program: Proceedings of the technical meeting, Charleston, South Carolina, March 8-12, 1999: Volume 2 (Part B)

This report contains papers presented at the seventh Technical Meeting of the U.S. Geological Survey (USGS), Toxic Substances Hydrology (Toxics) Program. The meeting was held March 8-12, 1999, in Charleston, South Carolina. Toxics Program Technical Meetings are held periodically to provide a forum for presentation and discussion of results of recent research activities. The objectives of these meetings are to: Present recent research results to essential stakeholders, Encourage synthesis and integrated interpretations among scientists with different expertise who are working on a contamination issue, and Promote exchange of ideas among scientists working on different projects and issues within the Toxics Program. The Proceedings is published in three volumes. Volume 1 contains papers that report on results of research on contamination from hard-rock mining. Results include research on contamination from hard rock mining in arid southwest alluvial basins, research on hard rock mining in mountainous terrain, and progress from the USGS Abandoned Mine Lands Initiative. This Initiative is designed to develop a watershed-based approach to characterize and remediate contamination from abandoned mine lands and transfer technologies to Federal land management agencies and stakeholders. Volume 2 contains papers on contamination of hydrologic systems and related ecosystems. The papers discuss research on the response of estuarine ecosystems to contamination from human activities. They include research on San Francisco Bay; mercury contamination of aquatic ecosystems; and investigation of the occurrence, distribution, and fate of agricultural chemicals in the Mississippi River Basin. This volume also contains results on development and reconnaissance testing of new methods to detect emerging contaminants in environmental samples. Volume 3 contains papers on subsurface contamination from point sources. The papers discuss research on: hydrocarbons and fuel oxygenates at gasoline release sites; ground-water contamination by crude oil; complex contaminant mixtures from treated wastewater discharges; waste disposal and subsurface transport of contaminants in arid environments; ground water and surface water affected by municipal landfill leachate; natural attenuation of chlorinated solvents; and characterizing flow and transport in fractured rock aquifers. In all, the more than 175 papers contained in this proceedings reflect the contributions of more than 350 scientists who are co-authors. These scientists are from across the USGS, as well as from universities, other Federal and State agencies, and industry.

Water-Resources Investigations Report↗

U.S. Geological Survey Toxic Substances Hydrology Program: Proceedings of the technical meeting, Charleston, South Carolina, March 8-12, 1999: Volume 3 (Part C)

This report contains papers presented at the seventh Technical Meeting of the U.S. Geological Survey (USGS), Toxic Substances Hydrology (Toxics) Program. The meeting was held March 8-12, 1999, in Charleston, South Carolina. Toxics Program Technical Meetings are held periodically to provide a forum for presentation and discussion of results of recent research activities. The objectives of these meetings are to: Present recent research results to essential stakeholders, Encourage synthesis and integrated interpretations among scientists with different expertise who are working on a contamination issue, and Promote exchange of ideas among scientists working on different projects and issues within the Toxics Program. The Proceedings is published in three volumes. Volume 1 contains papers that report on results of research on contamination from hard-rock mining. Results include research on contamination from hard rock mining in arid southwest alluvial basins, research on hard rock mining in mountainous terrain, and progress from the USGS Abandoned Mine Lands Initiative. This Initiative is designed to develop a watershed-based approach to characterize and remediate contamination from abandoned mine lands and transfer technologies to Federal land management agencies and stakeholders. Volume 2 contains papers on contamination of hydrologic systems and related ecosystems. The papers discuss research on the response of estuarine ecosystems to contamination from human activities. They include research on San Francisco Bay; mercury contamination of aquatic ecosystems; and investigation of the occurrence, distribution, and fate of agricultural chemicals in the Mississippi River Basin. This volume also contains results on development and reconnaissance testing of new methods to detect emerging contaminants in environmental samples. Volume 3 contains papers on subsurface contamination from point sources. The papers discuss research on: hydrocarbons and fuel oxygenates at gasoline release sites; ground-water contamination by crude oil; complex contaminant mixtures from treated wastewater discharges; waste disposal and subsurface transport of contaminants in arid environments; ground water and surface water affected by municipal landfill leachate; natural attenuation of chlorinated solvents; and characterizing flow and transport in fractured rock aquifers. In all, the more than 175 papers contained in this proceedings reflect the contributions of more than 350 scientists who are co-authors. These scientists are from across the USGS, as well as from universities, other Federal and State agencies, and industry.

Water-Resources Investigations Report↗

Water-quality assessment of southern Florida: An overview of available information on surface- and ground-water quality and ecology

This report summarizes water-quality conditions, issues of concern, and management efforts underway in southern Florida. The report is designed to provide a conceptual framework for the Southern Florida National Water Quality Assessment (NAWQA) study that began in 1994. The report makes reference to the most important water-quality literature pertaining to southern Florida, to water-quality studies that are underway or planned, and to topics which are of high priority in the study unit. These topics include: the availability and suit ability of water for competing demands; nutrient enrichment of the Everglades; transport, degradation, and effects of pesticides; and the sources and cycling of mercury in the ecosystem. The report also includes a retrospective analysis and conceptual presentation of nutrient loading, which is a high priority for the national NAWQA Program and for regional water-quality managers. Nutrient contributions from point and nonpoint sources are estimated for nine basins in the study area and are discussed in relation to land use. Fertilizer is the dominant source of phosphorus in eight basins and the dominant source of nitrogen in at least five basins. Atmospheric sources of nitrogen contribute more than 20 percent of the total nitrogen input to all basins and are the dominant source of nitrogen input to Lake Okeechobee and the Everglades. Nutrient loads are also estimated in selected canal and river outflows in southern Florida to provide a spatial overview of the magnitude of nutrient loading to coastal waters. Annual phosphorus loads from the Peace River are the highest in the study unit; annual phosphorus loads from the Caloosahatchee River and the major Palm Beach canals are also high, compared to other parts of southern Florida. Estimated annual loads of phosphorus from parts of the Big Cypress Basin and the S-12 water-control structures of the Tamiami Canal are low compared with estimated phosphorus loads in outflows in the northern part of the study unit. Annual nitrogen loads in southern Florida were highest in outflows from the Caloosahatchee River Basin and the major Palm Beach canals. Nitrogen loads in outflows from parts of the Big Cypress subbasin were lower than those estimated to the north.

Florida↗

Review of Phosphorus Control Measures in the United States and Their Effects on Water Quality

Historical information on phosphorus loadings to the environment and the effect on water quality are summarized in this report, which was produced as part of the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) Program. Phosphorus is a water-quality constituent of concern because it is often the limiting nutrient responsible for accelerated eutrophication in water bodies. Phosphorus inputs to the environment have increased since 1950 as the use of phosphate fertilizer, manure, and phosphate laundry detergent increased; however, the manufacture of phosphate detergent for household laundry was ended voluntarily in about 1994 after many States had established phosphate detergent bans. Total phosphorus concentrations in raw wastewater effluent contained about 3 milligrams per liter of total phosphorus during the 1940's, increased to about 11 milligrams per liter at the height of phosphate detergent use (1970), and have currently declined to about 5 milligrams per liter. However, in some cases, tertiary wastewater treatment still is needed to effectively improve water quality of streams. Downward trends in phosphorus concentrations since 1970 have been identified in many streams, but median total phosphorus concentrations still exceed the recommended limit of 0.1 milligram per liter across much of the Nation. Data from the NAWQA Program are representative of a variety of phosphorus-control measures, and, therefore, may be used to evaluate the effects of various control strategies. Current areas of concern include: evaluation of the effects of increased manure loadings of phosphorus on soil phosphorus and, subsequently, on ground water and subsurface runoff; determination of point-source and nonpoint-source components of phosphorus loads by geographic modeling and hydrologic separation techniques; and development of methods or indices to evaluate nutrient impairment in streams and rivers to serve as a basis for developing phosphorus criteria or standards.

Water-Resources Investigations Report↗

Hydrogeology of a hazardous-waste disposal site near Brentwood, Williamson County, Tennessee

Approximately 44,000 gal of industrial solvent wastes were disposed in pits on a farm near Brentwood, Tennessee, in 1978, and contaminants were reported in the soil and shallow groundwater on the site in 1985. In order for the State to evaluate possible remedial-action alternatives, an 18-month study was conducted to define the hydrogeologic setting of the site and surrounding area. The area is underlain by four hydrogeologic units: (1) an upper aquifer consisting of saturated regolith, Bigby-Cannon Limestone, and weathered Hermitage Formation; (2) the Hermitage confining unit; (3) a lower aquifer consisting of the Carters Limestone; and (4) the Lebanon confining unit. Wells generally are low yielding less than 1 gal/min), although locally the aquifers may yield as much as 80 gal/minute. This lower aquifer is anisotropic, and transmissivity of this aquifer is greatest in a northwest-southeast direction. Recharge to the groundwater system is primarily from precipitation, and estimates of average annual recharge rates range from 6 to 15 inches/year. Discharge from the groundwater system is primarily to the Little Harpeth River and its tributaries. Groundwater flow at the disposal site is mainly to a small topographic depression that drains the site. Geochemical data indicate four distinct water types. These types represent (1) shallow, rapidly circulating groundwater; (2) deeper (> than 100 ft), rapidly circulating groundwater; (3) shallow, slow moving groundwater; and (4) deeper, slow moving groundwater. Results of the numerical model indicate that most flow is in the upper aquifer.

Tennessee↗

Computer programs for describing the recession of ground-water discharge and for estimating mean ground-water recharge and discharge from streamflow records-update

The computer programs included in this report can be used to develop a mathematical expression for recession of ground-water discharge and estimate mean ground-water recharge and discharge. The programs are intended for analysis of the daily streamflow record of a basin where one can reasonably assume that all, or nearly all, ground water discharges to the stream except for that which is lost to riparian evapotranspiration, and where regulation and diversion of flow can be considered to be negligible. The program RECESS determines the master reces-sion curve of streamflow recession during times when all flow can be considered to be ground-water discharge and when the profile of the ground-water-head distribution is nearly stable. The method uses a repetitive interactive procedure for selecting several periods of continuous recession, and it allows for nonlinearity in the relation between time and the logarithm of flow. The program RORA uses the recession-curve displacement method to estimate the recharge for each peak in the streamflow record. The method is based on the change in the total potential ground-water discharge that is caused by an event. Program RORA is applied to a long period of record to obtain an estimate of the mean rate of ground-water recharge. The program PART uses streamflow partitioning to estimate a daily record of base flow under the streamflow record. The method designates base flow to be equal to streamflow on days that fit a requirement of antecedent recession, linearly interpolates base flow for other days, and is applied to a long period of record to obtain an estimate of the mean rate of ground-water discharge. The results of programs RORA and PART correlate well with each other and compare reasonably with results of the corresponding manual method.

Water-Resources Investigations Report↗

Planning report for the Edwards-Trinity Regional Aquifer-System analysis in central Texas, southeast Oklahoma, and southwest Arkansas

The Edwards-Trinity regional aquifer system supplies more than 0.78 million acre-feet per year (700 million gallons per day) of water for central Texas and small adjacent parts of southeast Oklahoma and southwest Arkansas. The system consists of three major aquifers and at least three minor aquifers in predominantly Cretaceous rocks, which together have an areal extent of about 80,000 square miles. The major aquifers are the Edwards-Trinity (Plateau) in west-central Texas, the Edwards (Balcones Fault Zone) in south-central Texas, and the Trinity in north-central Texas, southeast Oklahoma, and southwest Arkansas. Current (1986) and future concerns about the aquifer system involve the ever-increasing demand for water, most of which is associated with rapid population increase. Decreases in or elimination of spring discharges and encroachment of water from downdip salinewater zones into updip freshwater zones are of primary concern in the area underlain by ttie Edwards (Balcones Fault Zone) aquifer. Water-level declines of several hundred feet in the Trinity aquifer are a serious concern in some metropolitan areas. The Edwards-Trinity regional aquifer-system analysis project, begun in October 1985 and scheduled to be completed by October 1991, is one of a series of similar projects being conducted nationwide. The project is intended to define the hydrogeologic framework, and to describe the geochemistry and groundwater flow of the aquifer system in order to provide a better understanding of the system's long-term water-yielding potential. A multidisciplinary approach will be used in which computer-based digital simulation of flow in the system will be the principal method of hydrogeologic investigation.

Arkansas, Oklahoma, Texas↗