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At least 1,459 records · Page 81Linked to original sources
USGS2001

Benthic flux of dissolved nickel into the water column of south San Francisco Bay

Field and laboratory studies were conducted between April, 1998 and May, 1999 to provide the first direct measurements of the benthic flux of dissolved (0.2-micron filtered) nickel between the bottom sediment and water column at three sites in the southern component of San Francisco Bay (South Bay), California. Dissolved nickel and predominant ligands (represented by dissolved organic carbon, and sulfides) were the solutes of primary interest, although a variety of ancillary measurements were also performed to provide a framework for interpretation. Results described herein integrate information needs identified by the State Water Resources Control Board and local stakeholders with fundamental research associated with the U.S. Geological Survey Toxic Substances Hydrology Program. Dissolved-Ni concentrations in the bottom water over the three sampling dates ranged from 34 to 43 nanomoles per liter. Dissolved-macronutrient concentrations in the bottom water were consistently higher (frequently by orders of magnitude) than surface-water determinations reported for similar times and locations (Regional Monitoring Program, 2001). This is consistent with measured positive benthic fluxes for the macronutrients. Benthic-flux estimates for dissolved nickel from core-incubations, when areally averaged over the South Bay, were significant (that is, of equivalent or greater order of magnitude) relative to previously reported freshwater point and non-point sources. This observation is consistent with previous determinations for other metals, and with the potential remobilization of sediment-associated metals that have been ubiquitously distributed in the South Bay. Similar to dissolved-nickel results, benthic flux of macronutrients was also consistently significant relative to surface-water inputs. These results add to a growing body of knowledge that strongly suggests a need to consider contaminant transport across the sediment-water interface when establishing future management strategies for the watershed.

California↗
USGS2005

Gulf of Mexico integrated science - Tampa Bay study, the impact of groundwater and contaminants on Tampa Bay

Despite the recreational and economic value of coastal bays and estuaries, these ecosystems are often among our most 'troubled' natural environments. Urbanization, agriculture, mining, and shipping are just a few activities that can have a profound and lasting impact on the coastal zone. In order to maintain a healthy coastal ecosystem, it is crucial to develop reasonable management practices around expert scientific information. We still have much to learn about the quantity and quality of groundwater being discharged into Tampa Bay, Florida. We also need to improve our knowledge of a wide range of contaminants entering the bay and must be able to determine where they accumulate in seafloor sediments. Such buried contaminants can potentially be harmful to biota if they are released to the water column. U.S. Geological Survey (USGS) scientists and research partners from the University of South Florida (USF), the University of Florida (UF), and the Florida Marine Research Institute (FMRI) are mapping sources of groundwater, measuring groundwater flow into Tampa Bay, and assessing the impact of contaminants and sediments on bay water quality and ecosystem health.

Open-File Report↗
USGS2009

High-Resolution Seismic-Reflection and Marine Magnetic Data Along the Hosgri Fault Zone, Central California

The U.S. Geological Survey (USGS) collected high-resolution shallow seismic-reflection and marine magnetic data in June 2008 in the offshore areas between the towns of Cayucos and Pismo Beach, Calif., from the nearshore (~6-m depth) to just west of the Hosgri Fault Zone (~200-m depth). These data are in support of the California State Waters Mapping Program and the Cooperative Research and Development Agreement (CRADA) between the Pacific Gas & Electric Co. and the U.S. Geological Survey. Seismic-reflection and marine magnetic data were acquired aboard the R/V Parke Snavely, using a SIG 2Mille minisparker seismic source and a Geometrics G882 cesium-vapor marine magnetometer. More than 550 km of seismic and marine magnetic data was collected simultaneously along shore-perpendicular transects spaced 800 m apart, with an additional 220 km of marine magnetometer data collected across the Hosgri Fault Zone, resulting in spacing locally as smallas 400 m. This report includes maps of the seismic-survey sections, linked to Google Earth software, and digital data files showing images of each transect in SEG-Y, JPEG, and TIFF formats, as well as preliminary gridded marine-magnetic-anomaly and residual-magnetic-anomaly (shallow magnetic source) maps.

Open-File Report↗
USGS2023

Human factors used to estimate and forecast water supply and demand in the Upper Colorado River Basin

Water availability is a result of complex interactions between regional water supply and demand and underlying environmental, institutional, and economic determinants. For this study, water availability is defined as “access to a specific quantity and quality of water at a point in time and space, for a specific use, recognizing the social and economic value of water across uses and institutions that facilitate or hinder its equitable and efficient provisioning.” This report identifies the human factors that influence water supply and demand and summarizes (1) the extensive sets of data available to estimate these factors in the agricultural, municipal, and industrial water-use sectors and (2) factors of recreation and ecosystem services that influence water availability in the Upper Colorado River Basin. Lastly, future research needs are identified that can help prioritize collection and refinement of human factors of water use to improve water availability estimation and forecasting.

Arizona, Colorado, Nevada, New Mexico, Utah, Wyomi↗
USGS2024

Hydrologic study of green infrastructure in poorly drained urbanized soils at RecoveryPark, Detroit, Michigan, 2014–21

Uncontrolled stormwater runoff volume is a legacy stressor on sewer-system capacity that is further compromised by the effects of aging infrastructure. Green stormwater infrastructure (GSI) has been used in a variety of designs and configurations (for example, bioretention) with the goal of increasing evapotranspiration and infiltration in the local water cycle. In practice, GSIs have variable effectiveness in reducing runoff volume. An urban residential site near Detroit, Michigan, called RecoveryPark was monitored for 8 years before and after GSI construction to evaluate how effectively the GSI reduced volumes of stormwater flowing to Detroit’s Water Resource Recovery Facility through combined sewer systems. In addition to the GSI, the study site included an urban farm where salad crops were grown in hoop houses. The monitoring approach was to characterize the urban water cycle through high-frequency measurements of inflows and outflows. Datasets included meteorological data, soils and sediment characteristics, groundwater levels, flows within the combined sewer system, and soils and water chemistry with specific focus on the disposition of road salt. Although land cover within the RecoveryPark sewershed was high-density residential in the 1950s, the sewershed included only one residence within the 8.74-acre sewershed during this study. Measurements of annual precipitation at the site exceeded long-term annual averages by more than 10 inches during 3 of the 8 years of study. Potential evapotranspiration was often greater than the measured precipitation that averaged 28–34 inches per year. As compared to underlying clay-rich sediments, soils data indicated relatively permeable sediments near land surface with estimated hydraulic conductivity of 0.75 inches per hour; however, these values decreased with increasing depth. Groundwater-level data revealed increases in groundwater storage as indicated by increases in seasonal groundwater levels and development of a groundwater mound adjacent to the GSI. These increases in groundwater levels were directly adjacent to swales designed to infiltrate stormwater and only became evident after installing the GSI. Flows within the combined sewer system included rainwater, septic effluent, groundwater infiltration, leakage from water-supply lines, and release of water stored in abandoned foundations. Dry-weather flows (no rain fell within the prior 3 days) averaged 7–10 gallons per minute, which were much greater than flows estimated by septic outflow alone. A set of estimated water budgets were compiled, and results showed large discrepancies in unaccounted flows. To further examine these discrepancies, dye-tracing within the combined sewer system helped examine the sources of water by relating flow volumes to drainage area. For one of the monitoring sites within the combined sewer system along the southeast side of the study area, flows estimated by dye concentrations were more than 10 percent greater than those measured by standard methods. Through peak-flow-regression analysis, a minimum of 2.4 million gallons of water per year were infiltrated or lost to evapotranspiration because of GSI construction. After site modifications were made by excavating gravel drains to improve drainage characteristics, estimated stormwater volumes within the combined sewer system returned to near preconstruction levels. The GSI was effectively bypassed to address slow infiltration rates and standing water; the bypass all but eliminated the potential benefits of volume reduction. Late in the project, a water-quality study was added to examine the transport of road salt and associated chloride within the GSI and the combined sewer system. Continuous specific conductance was used as a surrogate for chloride concentrations to estimate that 2,790 pounds of dissolved chloride passed through the sewershed during the winter months of late 2020 through early 2021. These data were collected after GSI modification, therefore most, if not all, of the chloride was transported directly to Detroit’s Water Resource Recovery Facility via the combined sewer system. Mixing diagrams using chloride and bromide concentrations of road salt, potable water, rainwater, groundwater, and water from the combined sewer system confirmed that water within the combined sewer system is a mix of these sources. The poor condition of the combined sewer system pipes and resulting unaccounted inflows added to the challenge of accurately monitoring and identifying sources and sinks of water within the RecoveryPark sewershed. Our research results suggest that—along with clear and quantifiable objectives—the catchment and site conditions should be well-characterized before determining the GSI design. In addition, the work presented in this report provides implications and lessons learned for effectiveness and future studies of GSI in urban settings. These efforts can be improved through increased communication between stakeholders, use of high-quality soils in GSI that have suitable hydraulic characteristics, redundant data-collection networks for critical data streams, and focusing meteorological-data collection within the GSI to obtain relevant evapotranspiration data.

Michigan↗
USGS2024

Physics-based satellite-derived bathymetry (SDB) using Landsat OLI images

The estimation of depth in optically shallow waters using satellite imagery can be efficient and cost-effective. Active sensors measure the distance traveled by an emitted laser pulse propagating through the water with high precision and accuracy if the bottom peak intensity of the waveform is greater than the noise level. However, passive optical imaging of optically shallow water involves measuring the radiance after the sunlight undergoes downward attenuation on the way to the sea floor, and the reflected light is then attenuated while moving back upward to the water surface. The difficulty of satellite-derived bathymetry (SDB) arises from the fact that the measured radiance is a result of a complex association of physical elements, mainly the optical properties of the water, bottom reflectance, and depth. In this research, we attempt to apply physics-based algorithms to solve this complex problem as accurately as possible to overcome the limitation of having only a few known values from a multispectral sensor. Major analysis components are atmospheric correction, the estimation of water optical properties from optically deep water, and the optimization of bottom reflectance as well as the water depth. Specular reflection of the sky radiance from the water surface is modeled in addition to the typical atmospheric correction. The physical modeling of optically dominant components such as dissolved organic matter, phytoplankton, and suspended particulates allows the inversion of water attenuation coefficients from optically deep pixels. The atmospheric correction and water attenuation results are used in the ocean optical reflectance equation to solve for the bottom reflectance and water depth. At each stage of the solution, physics-based models and a physically valid, constrained Levenberg–Marquardt numerical optimization technique are used. The physics-based algorithm is applied to Landsat Operational Land Imager (OLI) imagery over the shallow coastal zone of Guam, Key West, and Puerto Rico. The SDB depths are compared to airborne lidar depths, and the root mean squared error (RMSE) is mostly less than 2 m over water as deep as 30 m. As the initial choice of bottom reflectance is critical, along with the bottom reflectance library, we describe a pure bottom unmixing method based on eigenvector analysis to estimate unknown site-specific bottom reflectance.

Remote Sensing↗
USGS2012

An Automated Cropland Classification Algorithm (ACCA) for Tajikistan by combining Landsat, MODIS, and secondary data

The overarching goal of this research was to develop and demonstrate an automated Cropland Classification Algorithm (ACCA) that will rapidly, routinely, and accurately classify agricultural cropland extent, areas, and characteristics (e.g., irrigated vs. rainfed) over large areas such as a country or a region through combination of multi-sensor remote sensing and secondary data. In this research, a rule-based ACCA was conceptualized, developed, and demonstrated for the country of Tajikistan using mega file data cubes (MFDCs) involving data from Landsat Global Land Survey (GLS), Landsat Enhanced Thematic Mapper Plus (ETM+) 30 m, Moderate Resolution Imaging Spectroradiometer (MODIS) 250 m time-series, a suite of secondary data (e.g., elevation, slope, precipitation, temperature), and in situ data. First, the process involved producing an accurate reference (or truth) cropland layer (TCL), consisting of cropland extent, areas, and irrigated vs. rainfed cropland areas, for the entire country of Tajikistan based on MFDC of year 2005 (MFDC2005). The methods involved in producing TCL included using ISOCLASS clustering, Tasseled Cap bi-spectral plots, spectro-temporal characteristics from MODIS 250 m monthly normalized difference vegetation index (NDVI) maximum value composites (MVC) time-series, and textural characteristics of higher resolution imagery. The TCL statistics accurately matched with the national statistics of Tajikistan for irrigated and rainfed croplands, where about 70% of croplands were irrigated and the rest rainfed. Second, a rule-based ACCA was developed to replicate the TCL accurately (∼80% producer’s and user’s accuracies or within 20% quantity disagreement involving about 10 million Landsat 30 m sized cropland pixels of Tajikistan). Development of ACCA was an iterative process involving series of rules that are coded, refined, tweaked, and re-coded till ACCA derived croplands (ACLs) match accurately with TCLs. Third, the ACCA derived cropland layers of Tajikistan were produced for year 2005 (ACL2005), same year as the year used for developing ACCA, using MFDC2005. Fourth, TCL for year 2010 (TCL2010), an independent year, was produced using MFDC2010 using the same methods and approaches as the one used to produce TCL2005. Fifth, the ACCA was applied on MFDC2010 to derive ACL2010. The ACLs were then compared with TCLs (ACL2005 vs. TCL2005 and ACL2010 vs. TCL2010). The resulting accuracies and errors from error matrices involving about 152 million Landsat (30 m) pixels of the country of Tajikistan (of which about 10 million Landsat size, 30 m, cropland pixels) showed an overall accuracy of 99.6% (k hat = 0.97) for ACL2005 vs. TCL2005. For the 3 classes (irrigated, rainfed, and others) mapped in ACL2005, the producer’s accuracy was >86.4% and users accuracy was >93.6%. For ACL2010 vs. TCL2010, the error matrix showed an overall accuracy on 96.2% (k hat = 0.96). For the 3 classes (irrigated, rainfed, and others) mapped in ACL2010, the producer’s and user’s accuracies for the irrigated areas were ≥82.9%. Any intermixing was overwhelmingly between irrigated and rainfed croplands, indicating that croplands (irrigated plus rainfed areas) as well as irrigated areas were mapped with high levels of accuracies (∼90% or higher) even for the independent year. The ACL2005 and ACL2010, each, were produced using ACCA algorithm in ∼30 min using a Dell Precision desktop T7400 computer for the entire country of Tajikistan once the MFDCs for the years were ready. The ACCA algorithm for Tajikistan is made available through US Geological Survey’s ScienceBase: http://www.sciencebase.gov/catalog/folder/4f79f1b7e4b0009bd827f548 or at: https://powellcenter.usgs.gov/globalcroplandwater/content/models-algorithms . The research contributes to the efforts of global food security through research on global croplands and their water use (e.g., https://powellcenter.usgs.gov/globalcroplandwater/ ). The above results clearly demonstrated the ability of a rule-based ACCA to rapidly and accurately produce cropland data layer year after year (hindcast, nowcast, forecast) for the country it was developed using MFDCs that consist of combining multiple sensor data and secondary data. It needs to be noted that the ACCA is applicable to the area (e.g., country, region) for which it is developed. In this case, ACCA is applicable for the Country of Tajikistan to hindcast, nowcast, and forecast agricultural cropland extent, areas, and irrigated vs. rainfed. The same fundamental concept of ACCA applies to other areas of the World where ACCA codes need to be modified to suite the area/region of interest. ACCA can also be expanded to compute other crop characteristics such as crop types, cropping intensities, and phenologies.

Remote Sensing↗
USGS2000

Environmental Contaminants and Terrestrial Vertebrates: Effects on Populations, Communities, and Ecosystems

The desire of resource managers, risk assessors, and the general public to better understand the consequences of environmental contamination has produced a strong and growing need for information on the effects of contaminants on populations and groups of species, and over moderate to large areas of land or water. However, the problems associated with research involving populations and groups of species or large and complex geographic areas, especially in terrestrial environments, are well known within the scientific community. With the previous thoughts in mind, an interactive symposium was held at the University of Maryland in October 1998. The purpose of the symposium was to review and critically evaluate our understanding of the effects of contaminants on terrestrial vertebrates at levels of organization above that of the individual. Invited background and technical presentations provided a common baseline of information for symposium participants. Discussion groups were then asked to critically evaluate the topics of two technical sessions. Several presentations of recent or ongoing research provided participants with examples of current approaches to assessments of the effects of contaminants on terrestrial vertebrates at the population or higher level of organization. The book consists of 10 chapters written by presenters at the symposium and three chapters conveying the reports of discussion group.

SETAC Special Publications Series.↗
USGS1988

The ecology of the soft-bottom benthos of San Francisco Bay: a community profile

This profile, part of a series of profiles concerning coastal habitats of the United States, is a detailed examination of the soft-bottom benthos of San Francisco Bay. A U.S. Fish and Wildlife Service and California Department of Fish and Game report (1979) entitled "Protection and Restoration of San Francisco Bay Fish and Wildlife Habitat" provides clear recognition of the importance of intertidal and subtidal soft-bottom habitats and their associated organisms to the bay's birds and fishes and to the overall functioning of the estuary. The purpose of this profile is to provide a description of the structure and functioning of the benthic community in San Francisco Bay (exclusive of its tidal marshes, which are discussed by M. Josselyn [1983] in another profile). The habitats covered in this volume include all nonvegetated soft-bottom intertidal and subtidal areas of the bay between the Golden Gate and the mouths of the Sacramento and San Joaquin Rivers to the northeast, and to the southern extremity of the bay. The profile provides a reference to the scientific information concerning the animals and plants of the bay's benthic communities, their importance to the bay ecosystem, and their value as a resource measured in human terms. Because there have been few process-oriented studies of the benthos of San Francisco Bay (e.g., field and laboratory rate-measurement experiments), the material presented herein is largely descriptive. Nonetheless, we have described the processes that interconnect the various physical, chemical, and biological components of the benthic environment, and the important couplings between this environment and the water column above, with reference to research results from other estuaries where necessary. We consider the role of the benthic community as a food source for fish, aquatic birds, and humans; as a consumer or degrader of organic materials including wastes; as a recycler of minerals and nutrients; and as an accumulator of pollutants.

California↗
USGS1997

Coordination and standardization of federal sedimentation activities

In August 1964, the Bureau of the Budget issued Circular A-67 to set forth guidelines for the coordination of water-data acquisition activities throughout the Federal government. The U.S. Department of the Interior was assigned the task of implementing Circular A-67, which in turn redelegated this responsibility to the U.S. Geological Survey (USGS). Delegation of the lead responsibility for water-data coordination to the USGS occurred because of its historical role as the primary agency for water-data acquisition in the United States. To provide overall leadership for implementing the provisions of Circular A-67, the USGS established the Office of Water Data Coordination in the Water Resources Division (WRD). In addition, regional and district offices of the WRD were delegated responsibility for coordinating water data within their geographic areas of responsibility. On December 10, 1991, the Office of Management and Budget issued OMB Number Memorandum M-92-01, which expands the USGS's coordination role to encompass all water information. This includes data critical to water resources in the following categories: - surface- and ground-water quality and quantity, - sediment, - constituent transport, - erosion, - water chemistry, and - precipitation information critical to water resources management. Memorandum M-92-01 covers primarily freshwater bodies and includes activities, such as "development and distribution of consensus standards, field-data collection and laboratory analytical methods, data processing and interpretation, data-base management, quality control and quality assurance, and water- resources appraisals, assessments, and investigations." Research activities are not included.

Conference Paper↗
USGS2009

Evaluating the spatial variation of total mercury in young-of-year yellow perch (Perca flavescens), surface water and upland soil for watershed-lake systems within the southern Boreal Shield

The primary objective of this research is to investigate relationships between mercury in upland soil, lake water and fish tissue and explore the cause for the observed spatial variation of THg in age one yellow perch ( Perca flavescens ) for ten lakes within the Superior National Forest. Spatial relationships between yellow perch THg tissue concentration and a total of 45 watershed and water chemistry parameters were evaluated for two separate years: 2005 and 2006. Results show agreement with other studies where watershed area, lake water pH, nutrient levels (specifically dissolved NO 3 − -N) and dissolved iron are important factors controlling and/or predicting fish THg level. Exceeding all was the strong dependence of yellow perch THg level on soil A-horizon THg and, in particular, soil O-horizon THg concentrations (Spearman ρ = 0.81). Soil B-horizon THg concentration was significantly correlated (Pearson r = 0.75) with lake water THg concentration. Lakes surrounded by a greater percentage of shrub wetlands (peatlands) had higher fish tissue THg levels, thus it is highly possible that these wetlands are main locations for mercury methylation. Stepwise regression was used to develop empirical models for the purpose of predicting the spatial variation in yellow perch THg over the studied region. The 2005 regression model demonstrates it is possible to obtain good prediction (up to 60% variance description) of resident yellow perch THg level using upland soil O-horizon THg as the only independent variable. The 2006 model shows even greater prediction ( r 2 = 0.73, with an overall 10 ng/g [tissue, wet weight] margin of error), using lake water dissolved iron and watershed area as the only model independent variables. The developed regression models in this study can help with interpreting THg concentrations in low trophic level fish species for untested lakes of the greater Superior National Forest and surrounding Boreal ecosystem.

Science of the Total Environment↗
USGS2023

Linking ecosystem processes to consumer growth rates: Gross primary productivity as a driver of freshwater fish somatic growth in a resource-limited river

Individual growth can exert strong controls on population dynamics and be constrained by resource acquisition rates. Difficulty in accurately quantifying resource availability over large spatial extents and at high temporal frequency often limits attempts to understand the extent that resources limit individual growth. Daily estimates of stream metabolism, including gross primary productivity (GPP), are increasingly available but have not, to our knowledge, been linked to fish growth. Here we examine how GPP, water temperature, high flow and turbidity are linked to spatiotemporal variation in growth of flannelmouth sucker (Catostomus latipinnis). We fit state space growth models to six years of mark-recapture data collected in four river reaches spanning 300 river kilometers. Consistent with past research in this system, we find that water temperature is the dominant driver of spatiotemporal variation in growth. However, we also find that GPP is strongly linked to fish growth. Fish growth is likely to be linked to stream metabolism in other systems where overall productivity, not the quality of primary producers, limits the food webs that support fish growth.

Arizona↗
USGS1997

Hydrogeologic and water-quality data used to evaluate the effects of focused recharge on ground-water quality near Princeton, Minnesota, 1991-95

This study was part of the Management Systems Evaluation Area (MSEA) Program, a multi-scale, inter-agency initiative to evaluate the effects of agricultural systems on water quality in the midwest corn belt. The research was part of the U.S. Geological Survey Toxics Substances Hydrology Program. The research area was located in the Anoka Sand Plain about 5 kilometers southwest of Princeton, Minnesota. This report presents temperature, precipitation, soil-moisture, water-quality, and other data collected during 1991-95 to evaluate the effects of focused recharge on ground-water quality at the Princeton MSEA.

Minnesota↗
USGS2020

Microbial source tracking (MST) in Chattahoochee River National Recreation Area: Seasonal and precipitation trends in MST marker concentrations, and associations with E. coli levels, pathogenic marker presence, and land use

Escherichia coli levels in recreational waters are often used to predict when fecal-associated pathogen levels are a human health risk. The reach of the Chattahoochee River that flows through the Chattahoochee River National Recreation Area (CRNRA), located in the Atlanta-metropolitan area, is a popular recreation area that frequently exceeds the U.S. Environmental Protection Agency beach action value (BAV) for E. coli . A BacteriALERT program has been implemented to provide real-time E. coli estimates in the reach and notify the public of potentially harmful levels of fecal-associated pathogens as indicated by surrogate models based on real-time turbidity measurements from continuous water quality monitoring stations. However, E. coli does not provide information about the sources of fecal contamination and its accuracy as a human health indicator is questionable when sources of contamination are non-human. The objectives of our study were to investigate, within the Park and surrounding watersheds, seasonal and precipitation-related patterns in microbial source tracking marker concentrations of possible sources (human, dog, and ruminant), assess correlations between source contamination levels and culturable E. coli levels, determine which sources best explained model-based E. coli estimates above the BAV and detection of esp2 (a marker for the esp gene associated with pathogenic strains of Enterococcus faecium and Enterococcus faecalis) , and investigate associations between source contamination levels and land use features. Three BacteriALERT sites on the Chattahoochee River were sampled six times per season in the winter and summer from December 2015 through September 2017, and 11 additional stream sites (synoptic sites) from the CRNRA watershed were sampled once per season. Samples were screened with microbial source tracking (MST) quantitative PCR (qPCR) markers for humans (HF183 Taqman), dogs (DogBact), and ruminants (Rum2Bac), the esp2 qPCR marker, and culturable E. coli. At the BacteriALERT sites, HF183 Taqman concentrations were higher under wet conditions DogBact concentrations were greater in the winter and under wet conditions, and Rum2Bac concentrations were comparatively low throughout the study with no difference across seasons or precipitation conditions. Concentrations of HF183 Taqman, DogBact, and Rum2Bac were positively correlated with culturable E. coli concentrations; however, DogBact had the largest R 2 value among the three markers, and the forward stepwise regression indicated it was the best predictor of culturable E. coli concentrations at the BacteriALERT sites. Recursive partitioning indicated that BAV exceedances of model-based E. coli estimates were best explained by DogBact concentrations ≥3 gene copies per mL (CN/mL). Detections of esp2 at BacteriALERT sites were best explained by DogBact concentrations ≥11 CN/mL, while detections of esp2 at synoptic sites were best explained by HF183 Taqman ≥29 CN/mL. At the synoptic sites, HF183 Taqman levels were associated with wastewater treatment plant density. However, this relationship was driven primarily by a single site, suggesting possible conveyance issues in that catchment. esp2 detections at synoptic sites were positively associated with development within a 2-km radius and negatively associated with development within the catchment, suggesting multiple sources of esp2 in the watershed. DogBact and Rum2Bac were not associated with the land use features included in our analyses. Implications for Park management include: 1) fecal contamination levels were highest during wet conditions and in the off season when fewer visitors are expected to be participating in water-based recreation, 2) dogs are likely contributors to fecal contamination in the CRNRA and may be sources of pathogenic bacteria indicating further investigation of the origins of this contamination may be warranted as would be research to understand the human health risks from exposure to dog fecal contamination, and 3) high levels of the human marker at one site in the CRNRA watershed suggests more extensive monitoring in that catchment may locate the origin of human fecal contamination detected during this study.

Georgia↗
USGS2020

Inventory and analysis of groundwater resources: Theodore Roosevelt National Park, North Dakota

Industrial and commercial developments in western North Dakota potentially could affect the sources of water that contribute to wells, spring flow, and seeps within Theodore Roosevelt National Park. Without basic water resources data, accurately predicting the effects of water withdrawals and water quality concerns related to industrial and commercial developments near the park would be challenging. Water resources in the park include surface water and groundwater. The Little Missouri River and its tributaries cross all three Theodore Roosevelt National Park units and are the primary surface-water features in the park. Groundwater resources include well discharges, springs, and seeps. The geology and hydrogeology of Theodore Roosevelt National Park are defined by the surrounding Williston Basin. Four aquifers are sources of groundwater to the park: unconsolidated aquifers including alluvial systems, the upper Fort Union aquifer, the lower Fort Union aquifer, and the Fox Hills-lower Hell Creek aquifer. Data used for wells, springs, seeps, and water quality in this report were compiled from the U.S. Geological Survey National Water Information System or from the North Dakota State Water Commission. An inventory of 16 wells was completed for sites within the boundaries of the park. In addition to well data, an inventory of 11 springs and seeps was completed. The groundwater-quality analysis had two objectives: (1) to characterize the groundwater chemistry in aquifers underlying the park and (2) to spatially map selected physical properties and chemical constituents of interest. Groundwater-quality data from the North Dakota State Water Commission were summarized, mapped, and used to characterize groundwater for each aquifer in the study area. Spatial concentration distribution maps were constructed for selected physical properties and chemical constituents using summary statistics and exceedances. Piper diagrams were used to classify and characterize groundwater for each aquifer. Future research to help fill data gaps in water resources information for Theodore Roosevelt National Park, including recommendations from previous studies, consists of the following: (1) evaluating the variability in discharge from springs and seeps in comparison to changes in precipitation or other recharge sources, (2) evaluating flow control measures for flowing artesian wells, (3) completing a water rights review, and (4) performing routine water-quality monitoring for wells and springs.

North Dakota↗
USGS2003

Environmental impacts of petroleum production--Initial results from the Osage-Skiatook Petroleum Environmental Research Sites, Osage County, Oklahoma

Exploration for and production of petroleum have caused major detrimental impacts to soils, surface and ground waters, and the local ecosystems in the United States. These impacts arise primarily from the improper disposal of large volumes of saline water produced with oil and gas, from accidental hydrocarbon and produced water releases, and from abandoned oil wells that were not correctly sealed. It is important to understand the long-term and short-term effects of produced water and hydrocarbon releases from these sites in order to develop risk-based remediation plans. Remediation is particularly needed in aging and depleted fields where land use is changing from petroleum production to residential, agricultural or recreational uses. About 20 scientists from the USGS and other governmental agencies and academia are involved in a multidisciplinary investigation to study the transport, fate, and natural attenuation of inorganic salts, trace metals, organic compounds and radionuclides present in produced water, and their impacts at the Osage-Skiatook Petroleum Environmental Research (OSPER) 'A' and 'B' sites, located on the Osage Reservation in Osage County, Oklahoma. Stakeholders in the project include the Osage Nation, which holds the mineral rights, the Bureau of Indian Affairs with trust responsibility, and the Army Corps of Engineers, which owns the surface rights at these sites and manages adjacent Skiatook Lake. The 4250-hectare Skiatook Lake provides drinking water to local Tulsa suburban communities and a rural water district, and offers recreational fishing and boating opportunities to tens of thousands of visitors each year. Approximately 1.5 and 1.0 hectare of land at the OSPER 'A' (depleted Lester lease) and 'B' (active Branstetter lease) sites, respectively, are affected by salt scarring, tree kills, soil salinization and brine and petroleum contamination due to the leakage of produced water and associated hydrocarbons from brine pits and accidental releases from active and inactive pipes and tank batteries. The leases are typical of many depleted and aging petroleum fields in Osage County, which ranks among the top oil and gas producing counties in Oklahoma with about 39,000 wells. Oil and gas production has occurred in Osage county for over one hundred years, but current production is mainly from stripper wells (averaging ~2.8 bbl/d oil and >30 bbl/d brine) that are shallow, mostly 300-700 m in depth, and produce from several sandstones of Pennsylvanian age. Results to date show that the produced water source is a Na-Ca-Cl brine (~150,000 mg/L total dissolved solids), with relatively high concentrations of Mg, Sr, and NH4, but low SO4 and H2S. With the exception of Fe and Mn, the concentrations of trace metals are low. Results also show that some and, eventually, the bulk, of inorganic salts and some dissolved organic species in the released brine from both sites will reach Skiatook Lake. Results at the 'A' site show that the salts have essentially been removed from the sandy soil which formed in a surficial layer of eolian sand, but degraded and weathered oil persists on the surface of old oil and brine pits, close to sites of old tanks, on old channels that carried oil from tanks to the oil pits and other impacted areas. Results also show a plume of high salinity water (5,000-30,600 mg/L TDS) is present at intermediate depths that extend from below the old oil and brine pits to Skiatook Lake. No liquid petroleum was found in the contaminated groundwater, but soluble petroleum byproducts, including organic acid anions and other volatile organic compounds (VOCs) are present. Results to date clearly show that significant amounts of salts from produced-water releases and petroleum hydrocarbons still remain in the soils and rocks of the impacted area after more than 60 years of natural attenuation.

Oklahoma↗
USGS2021

Demography of the Oregon spotted frog along a hydrologically modified river

Altered flow regimes can contribute to dissociation between life history strategies and environmental conditions, leading to reduced persistence reported for many wildlife populations inhabiting regulated rivers. The Oregon spotted frog ( Rana pretiosa ) is a threatened species occurring in floodplains, ponds, and wetlands in the Pacific Northwest with a core range in Oregon, USA. All life stages of R. pretiosa are reliant on aquatic habitats, and inundation patterns across the phenological timeline can have implications for population success. We conducted capture–mark–recapture (CMR) sampling of adult and subadult R. pretiosa at three sites along the Deschutes River downstream from two dams that regulate flows. We related the seasonal extent of inundated habitat at each site to monthly survival probabilities using a robust design CMR model. We also developed matrix projection models to simulate population dynamics into the future under current river flows. Monthly survival was strongly associated with the extent and variability of inundated habitat, suggesting some within-season fluctuations at higher water levels could be beneficial. Seasonal survival was lowest in the winter for all three sites, owing to limited water availability and the greater number of months within this season relative to other seasons. Population growth for the two river-connected sites was most strongly linked to adult survival, whereas population growth at the river-disconnected site was most strongly tied to survival in juvenile stages. This research identifies population effects of seasonally limited water and highlights conservation potential of enhancing survival of particularly influential life stages.

Oregon↗
USGS2008

Determination of human-health pharmaceuticals in filtered water by chemically modified styrene-divinylbenzene resin-based solid-phase extraction and high-performance liquid chromatography/Mass Spectrometry

In 1999, the Methods Research and Development Program of the U.S. Geological Survey National Water Quality Laboratory began the process of developing a method designed to identify and quantify human-health pharmaceuticals in four filtered water-sample types: reagent water, ground water, surface water minimally affected by human contributions, and surface water that contains a substantial fraction of treated wastewater. Compounds derived from human pharmaceutical and personal-care product use, which enter the environment through wastewater discharge, are a newly emerging area of concern; this method was intended to fulfill the need for a highly sensitive and highly selective means to identify and quantify 14 commonly used human pharmaceuticals in filtered-water samples. The concentrations of 12 pharmaceuticals are reported without qualification; the concentrations of two pharmaceuticals are reported as estimates because long-term reagent-spike sample recoveries fall below acceptance criteria for reporting concentrations without qualification. The method uses a chemically modified styrene-divinylbenzene resin-based solid-phase extraction (SPE) cartridge for analyte isolation and concentration. For analyte detection and quantitation, an instrumental method was developed that used a high-performance liquid chromatography/mass spectrometry (HPLC/MS) system to separate the pharmaceuticals of interest from each other and coextracted material. Immediately following separation, the pharmaceuticals are ionized by electrospray ionization operated in the positive mode, and the positive ions produced are detected, identified, and quantified using a quadrupole mass spectrometer. In this method, 1-liter water samples are first filtered, either in the field or in the laboratory, using a 0.7-micrometer (μm) nominal pore size glass-fiber filter to remove suspended solids. The filtered samples then are passed through cleaned and conditioned SPE cartridges at a rate of about 15 milliliters per minute. Excess water is eliminated from the cartridge sorbent bed by passing air through the cartridges, and the analytes retained on the SPE bed are eluted from the cartridge sequentially, first with methanol, followed by acidified methanol, and combined in collection tubes. This sample extract then is reduced from about 10 milliliters (mL) to about 0.1 mL (or 100 microliters) under a stream of purified nitrogen gas with the collection tubes in a heated (40°C) water bath. The reduced extracts then are fortified with an internal standard solution (when using internal standard quantitation), brought to a final volume of 1 mL with an aqueous ammonium formate buffer solution, and filtered through a 0.2-μm Teflon syringe filter as they are transferred into vials for instrumental analysis. Instrumental analysis by the HPLC/MS procedure permits determination of individual pharmaceutical concentrations from 0.005 to 1.0 microgram per liter, based on the lowest and the highest calibration standards routinely used. The reporting levels for this method are compound dependent, and have been experimentally determined based on the precision of quantitation of compounds from eight fortified organic-free water samples in single-operator experiments. The method detection limits and interim reporting levels for the compounds determined by this method were calculated from recoveries of the pharmaceuticals from reagent-water samples amended at 0.05 microgram per liter, and ranged between 0.0069 and 0.0142 microgram per liter, and 0.015 and 0.10 microgram per liter, respectively. Concentrations for 12 compounds are reported without qualification, and for two compounds are reported as qualified estimates. After initial development, the method was applied to more than 1,800 surface-, ground-, and wastewater samples from 2002 to 2005 and documented in a number of published studies. This research application of the method provided the opportunity to collect a large data set of ambient environmental concentrations and also permitted the collection of an extensive set of reagent blanks and spike quality-control (QC) samples. This multiple-year set of QC samples enabled further evaluation of method performance under multiple operator and multiple instrument conditions typical of routine laboratory operation. These results are an important part of the entire data set contained in this report because they document method performance over an extended time. Because sample matrix can substantially affect method performance, inclusion of environmental matrix-spike samples is required as a routine component of study plan quality control. Method performance has been measured by long-term tracking of observed recoveries from fortified organic-free water samples processed with environmental samples (laboratory reagent spikes), as well as by observed recoveries from multiple fortified environmental water samples. The fortified environmental samples included surface water, wastewater effluent-dominated surface water, and ground water, fortified at two environmentally relevant concentrations and corrected for ambient environmental concentrations. Because the responses of individual pharmaceuticals vary as a function of proton affinity, the ionization efficiency, and thus relative response, of each pharmaceutical, the quality-control surrogate compounds, and the quantitation internal standard can be suppressed or enhanced by the presence of the sample matrix. As a result, several quality-control sample types are required to properly interpret the ambient environmental concentrations of pharmaceuticals in aqueous samples. The quality-control sample types and results include laboratory reagent spikes and laboratory reagent blanks to provide insight into the performance of the method in the absence of a sample matrix, and matrix-spike recovery samples and replicate environmental samples, collected from representative sample matrix types within the aquatic system under study.

Techniques and Methods↗