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Chapter A5. Section 6.1.F. Wastewater, Pharmaceutical, and Antibiotic Compounds

The USGS differentiates between samples collected for analysis of wastewater compounds and those collected for analysis of pharmaceutical and antibiotic compounds, based on the analytical schedule for the laboratory method. Currently, only the wastewater laboratory method for field-filtered samples (SH1433) is an approved, routine (production) method. (The unfiltered wastewater method LC 8033 also is available but requires a proposal for custom analysis.) At this time, analysis of samples for pharmaceutical and antibiotic compounds is confined to research studies and is available only on a custom basis.

Techniques of Water-Resources Investigations↗

Acid rain publications by the U.S. Fish and Wildlife Service, 1979-1989

Pollution of aquatic and terrestrial ecosystems has been a concern to society since the burning of fossil fuels began in the industrial revolution. In the past decade or so, this concern has been heightened by evidence that chemical transformation in the atmosphere of combustion by-products and subsequent long-range transport can cause environmental damage in remote areas. The extent of this damage and the rates of ecological recovery were largely unknown. "Acid rain" became the environmental issue of the 1980's. To address the increasing concerns of the public, in 1980 the Federal government initiated a 10-year interagency research program to develop information that could be used by the President and the Congress in making decisions for emission controls. The U.S. Fish and Wildlife Service has been an active participant in acid precipitation research. The Service provided support to a number of scientific conferences and forums, including the Action Seminar on Acid Precipitation held in Toronto, Canada, in 1979, an international symposium on Acidic Precipitation and Fishery Impacts in Northeastern North America in 1981, and a symposium on Acidic Precipitation and Atmospheric Deposition: A Western Perspective in 1982. These meetings as well as the growing involvement with the government's National Acidic Precipitation Assessment Program placed the Service in the lead in research on the biological effects of acidic deposition. Research projects have encompassed water chemistry, aquatic invertebrates, amphibians, fish, and waterfowl. Water quality surveys have been conducted to help determine the extent of acid precipitation effects in the northeast, Middle Atlantic, and Rocky Mountain regions. In addition to lake and stream studies, research in wetland and some terrestrial habitats has also been conducted. Specific projects have addressed important sport species such as brook trout (Salvelinus fontinalis), Atlantic salmon (Salmo salar), and striped bass (Morone saxatilis). Trace metal accumulation in fish has been investigated and a symposium sponsored on related work. U.S> Fish and Wildlife Service scientists serve as advisors and participants in research being conducted by industry, nonprofit groups, State and other Federal agencies. Researcher have worked closely with colleagues in Canada, England, Norway, Scotland, the Soviet Union, and Sweden to gain additional understanding of the problem. In 1982, the Service implemented a mitigation research program to provide resource managers with information to help them protect sensitive ecosystems, and rehabilitation methods for resources already affected by acidification. An international workshop was convened to outline the research needs. Several conferences were organized to develop appropriate field and laboratory procedures. Scientists with the mitigation research program are evaluating the ecological effects of liming (addition of base material) surface waters and surrounding watershed to provide buffering against acidic inputs. Through long-term cooperative project with States and other organizations, investigations are studying possible abatement methods for regions most affected by acidic deposition. To date, more than 200 reports the describe these studies have been published. These products include conference proceedings, journal articles, and in-house scientific publications. An education poster describing the effects of acid rain on aquatic ecosystems was developed and distributed to individuals, conservations and State organizations, and the public education system. This annotated bibliography lists current publications by Service authors, cooperators, or contractors on acid rain and related quality. Entire are arranged alphabetically by author surname. For further information about the research program, contact the U.S. Fish and Wildlife Service, Acid Precipitation Section, National Fishery Research Center -- Leetown, Box 700, Kearneysville, WV 25430.

Biological Report↗

Glacier recession since the Little Ice Age: Implications for water storage in a Rocky Mountain landscape

Glacial ice is a significant influence on local climate, hydrology, vegetation, and wildlife. We mapped a complete set of glacier areas from the Little Ice Age (LIA) using very high-resolution satellite imagery (30-cm) within Glacier National Park, a region that encompasses over 400,000 hectares. We measured glacier change across the park using LIA glacier area as a baseline and used this to estimate change in glacier area and volume over time. An estimated 146 glaciers existed within the current boundaries of Glacier National Park during the LIA. By 2005, only 51 (35%) persisted. Nearly 90% of LIA glaciers had lost 50% of their area by 2005. This decrease in glacier area equates to an estimated loss of ice volume of 1.52 km3, or 1.37 km3 of water storage, roughly equivalent to 40% of Lake McDonald, the largest lake in the park. Understanding rates of deglaciation and implications for water storage and use can assist local resource managers and downstream communities in planning for change.

Montana↗

Results of the second phase of the drought-disaster test-drilling program near Morristown, N.J.

The continued drought in northeastern New Jersey through the summer of 1966 with its attendant water-supply problems resulted in an extension of the drought-disaster test-drilling program originally requested by the Office of Emergency Planning on August 30, 1965. Authorization to continue test drilling was fiven by the Office of Emergency Planning on September 26, 1966, with the stipulation that all field work be complete by January 31, 1977. Contractural costs were paid by the Office of Emergency Planning, whereas personnel costs were shared by the U.S. Geological Survey and the New Jersey Department of Conservation and Economic Development, Division of Water Policy and Supply. The work undertaken in 1965 by the Geological Survey was "...to preform the necessary drilling and testing of wells to identify the extent and nature of a reserve ground-water source in the vicinity of the Passaic River near the northern New Jersey metropolitan area." Results of this first phase were made available in the fall of 1966 in Water Resources Circular 16 of the New Jersey Department of Conservation and Economic Development. Three of the five areas tested (figure 1)--two in Parsippany-Troy Hills Township (areas 2 and 4) and one in East Hanover Township (area 1), Morris County--proved capable of providing an aggregate sustained yield of 7.5 million gallons daily (mgd) from wells constructed in sand and gravel deposits. Because significant supplies of ground water for emergency use were located in the first phase of the exploratory test-drilling program, it was though desirable to extend the originally planned studies so as to obtain maximum practicable information on emergency supplies. During this second phase of the investigation, drilling was conducted in 16 sites in Chatham, Madison, and Florham Park Boroughs and in Hanover and East Hanover Townships, Morris County. (See figure 2.) The drilling in Hanover and East Hanover Townships, and part of the drilling done in Florham Park was to explore the availability of large undeveloped ground-water supplies. Drilling in Chatham, Madison, and Florham Park Boroughs was done primarily to determine the extent and continuity of buried valley-fill aquifers, so that a full evaluation of the effects of pumpage from other areas on these already heavily pumped areas could be made. In addition, it was anticipated that the drilling could help in defining the feasibility of artificial recharge of the heavily pumped areas and in the determination of the prospective method of recharge and points of emplacement. Arrangements for easements with landowners, preparation of specifications for well drilling and seismic work, and supervision of well drilling and seismic contracts were all performed by the New Jersey District, Water Resources Division of the Geological Survey. Prior to the test drilling, seismic exploration under contract with Alpine Geophysical Associates of Norwood, N. J. was conducted at five locations in the Chatham-Madison-Florham Park area and at one place in Parsippany-Troy Hills Township. The seismic work was done to determine the most favorable location for a test well at several potential test-well sites and to help in the interpretation of subsurface geology between test sites. Contracts for the drilling of the test holes were awarded during November and drilling commences on November 30. Kaye Well drilling, Inc. of Jackson, N. J. was the recipient of a contract for eight of the test holes, and a second contract was awarded to Rinbrand Well Drilling Co., Inc. of Glen Rock, N. J.--also for eight test holes. Acknowledgment is due to the many public officials of Chatham, Madison, Florham Park, Morristown, and East Hanover Township as well as officials of the Braidburn Corporation and Esso Research and Engineering Co., who cooperated by making their lands available for exploration.

New Jersey↗

Biota connect aquatic habitats throughout freshwater ecosystem mosaics

Freshwater ecosystems are linked at various spatial and temporal scales by movements of biota adapted to life in water. We review the literature on movements of aquatic organisms that connect different types of freshwater habitats, focusing on linkages from streams and wetlands to downstream waters. Here, streams, wetlands, rivers, lakes, ponds, and other freshwater habitats are viewed as dynamic freshwater ecosystem mosaics (FEMs) that collectively provide the resources needed to sustain aquatic life. Based on existing evidence, it is clear that biotic linkages throughout FEMs have important consequences for biological integrity and biodiversity. All aquatic organisms move within and among FEM components, but differ in the mode, frequency, distance, and timing of their movements. These movements allow biota to recolonize habitats, avoid inbreeding, escape stressors, locate mates, and acquire resources. Cumulatively, these individual movements connect populations within and among FEMs and contribute to local and regional diversity, resilience to disturbance, and persistence of aquatic species in the face of environmental change. Thus, the biological connections established by movement of biota among streams, wetlands, and downstream waters are critical to the ecological integrity of these systems. Future research will help advance our understanding of the movements that link FEMs and their cumulative effects on downstream waters.

Journal of the American Water Resources Associatio↗

Comparison of groundwater flow in Southern California coastal aquifers

Development of the coastal aquifer systems of Southern California has resulted in overdraft, changes in streamflow, seawater intrusion, land subsidence, increased vertical flow between aquifers, and a redirection of regional flow toward pumping centers. These water-management challenges can be more effectively addressed by incorporating new understanding of the geologic, hydrologic, and geochemical setting of these aquifers. Groundwater and surface-water flow are controlled, in part, by the geologic setting. The physiographic province and related tectonic fabric control the relation between the direction of geomorphic features and the flow of water. Geologic structures such as faults and folding also control the direction of flow and connectivity of groundwater flow. The layering of sediments and their structural association can also influence pathways of groundwater flow and seawater intrusion. Submarine canyons control the shortest potential flow paths that can result in seawater intrusion. The location and extent of offshore outcrops can also affect the flow of groundwater and the potential for seawater intrusion and land subsidence in coastal aquifer systems. As coastal aquifer systems are developed, the source and movement of ground-water and surface-water resources change. In particular, groundwater flow is affected by the relative contributions of different types of inflows and outflows, such as pump-age from multi-aquifer wells within basal or upper coarse-grained units, streamflow infiltration, and artificial recharge. These natural and anthropogenic inflows and outflows represent the supply and demand components of the water budgets of ground-water within coastal watersheds. They are all significantly controlled by climate variability related to major climate cycles, such as the El Niño–Southern Oscillation and the Pacific Decadal Oscillation. The combination of natural forcings and anthropogenic stresses redirects the flow of groundwater and either mitigates or exacerbates the potential adverse effects of resource development, such as declining water levels, sea-water intrusion, land subsidence, and mixing of different waters. Streamflow also has been affected by development of coastal aquifer systems and related conjunctive use. Saline water is the largest water-quality problem in Southern California coastal aquifer systems. Seawater intrusion is a significant source of saline water, but saline water is also known to come from other sources and processes. Seawater intrusion is typically restricted to the coarse-grained units at the base of fining-upward sequences of terrestrial deposits, and at the top of coarsening upward sequences of marine deposits. This results in layered and narrow intrusion fronts. Maintaining the sustainability of Southern California coastal aquifers requires joint management of surface water and groundwater (conjunctive use). This requires new data collection and analyses (including research drilling, modern geohydrologic investigations, and development of detailed computer groundwater models that simulate the supply and demand components separately), implementation of new facilities (including spreading and injection facilities for artificial recharge), and establishment of new institutions and policies that help to sustain the water resources and better manage regional development.

California↗

Precipitation regime change in Western North America: The role of atmospheric rivers

Daily precipitation in California has been projected to become less frequent even as precipitation extremes intensify, leading to uncertainty in the overall response to climate warming. Precipitation extremes are historically associated with Atmospheric Rivers (ARs). Sixteen global climate models are evaluated for realism in modeled historical AR behavior and contribution of the resulting daily precipitation to annual total precipitation over Western North America. The five most realistic models display consistent changes in future AR behavior, constraining the spread of the full ensemble. They, moreover, project increasing year-to-year variability of total annual precipitation, particularly over California, where change in total annual precipitation is not projected with confidence. Focusing on three representative river basins along the West Coast, we show that, while the decrease in precipitation frequency is mostly due to non-AR events, the increase in heavy and extreme precipitation is almost entirely due to ARs. This research demonstrates that examining meteorological causes of precipitation regime change can lead to better and more nuanced understanding of climate projections. It highlights the critical role of future changes in ARs to Western water resources, especially over California.

California↗

Concepts and evolution of urban hydrology.

Urbanization and climate change are exacerbating the flood risk and ecosystem degradation in urban catchments, with traditional stormwater management systems often overwhelmed. In this Review, we discuss changes in urban hydrology and approaches to stormwater management. Roughly 90% of rainfall on impervious surfaces and drainage infrastructure becomes run-off, enhancing rainfall export away from cities and leading to local water scarcity and downstream flooding and pollution. Projected increases in urban populations (68% in cities by 2050) and rainfall intensity (~12% in the 10-year and 50-year recurrence interval intensity, under 1.5 °C warming) will exacerbate these issues. Transforming stormwater systems is thus urgently needed, to mitigate flood risk and also to address community desires for environmental protection and enhanced water security. Opportunities include rain gardens and other nature-based stormwater control measures (which restore natural flows and offer other ecosystem services), smart sensor monitoring networks and real-time management (which sustain natural flow regimes, mitigate flood risk and protect ecosystem services) and stormwater harvesting (to avoid local water scarcity). Community acceptance of stormwater harvesting is as high as 96% and stormwater is a substantial resource, with volumes often exceeding demand in some parts of the world. Delivering additional transformations globally requires research into strategies to incentivize engagement and investment, and policies to guide governance of decentralized networks.

Nature Reviews Earth & Environment↗

U.S. Geological Survey Community for Data Integration-NWIS Web Services Snapshot Tool for ArcGIS

U.S. Geological Survey (USGS) data resources are so vast that many scientists are unaware of data holdings that may be directly relevant to their research. Data are also difficult to access and large corporate databases, such as the National Water Information System (NWIS) that houses hydrologic data for the Nation, are challenging to use without considerable expertise and investment of time. The USGS Community for Data Integration (CDI) was established in 2009 to address data and information management issues affecting the proficiency of earth science research. A CDI workshop convened in 2009 identified common data integration needs of USGS scientists and targeted high value opportunities that might address these needs by leveraging existing projects in USGS science centers, in-kind contributions, and supplemental funding. To implement this strategy, CDI sponsored a software development project in 2010 to facilitate access and use of NWIS data with ArcGIS, a widely used Geographic Information System. The resulting software product, the NWIS Web Services Snapshot Tool for ArcGIS, is presented here.

Fact Sheet↗

Vital signs monitoring plan for the Klamath Network: Phase I report

This report chronicles the Phase 1 stage of the vital signs monitoring program for the Klamath Network. It consists of two chapters and eleven appendixes. The purposes of Chapter One are to 1) describe the network administrative structure and approach to planning; 2) introduce the Klamath Network parks, their resources, and environmental settings; 3) explain the need for monitoring changes in resources and supporting environments; 4) identify key information gaps that limit understanding of how to best achieve these monitoring goals. The purpose of Chapter Two is to develop the descriptive information provided in Chapter One into a conceptual basis for vital signs monitoring and to present the Network’s initial suite of conceptual models. The Report Appendices provide in-depth information on a variety of topics researched in preparation of the report, including: detailed natural resource profiles for each park, supporting policies and guidelines, regional fire regimes, vegetation types of the parks, exotic species threats, interagency monitoring programs, air issues, water quality (Phase 1 Report), Network vital signs (Scoping Summary Report), rare species, and rare habitats of the parks.

Report↗

U.S. Geological Survey (USGS) Water-Use Data and Research (WUDR) program overview and status as of October 22, 2020

The USGS Water-Use Data and Research Program (WUDR) is an appropriated program that began in Federal fiscal year 2015 and is authorized under the SECURE Water Act (Sec. 9508 (c)). WUDR provides financial assistance through cooperative agreements to State water resource agencies. The WUDR Program has two main goals: To improve the availability, quality, compatibility, and delivery of water-use data that are collected and/or estimated by States to support national water-use assessments; and To integrate the water-use data into USGS databases in electronic or machine-readable formats.

Newsletter↗

USGS Science: Addressing Our Nation's Challenges

With 6.6 billion people already living on Earth, and that number increasing every day, human influence on our planet is ever more apparent. Changes to the natural world combined with increasing human demands threaten our health and safety, our national security, our economy, and our quality of life. As a planet and a Nation, we face unprecedented challenges: loss of critical and unique ecosystems, the effects of climate change, increasing demand for limited energy and mineral resources, increasing vulnerability to natural hazards, the effects of emerging diseases on wildlife and human health, and growing needs for clean water. The time to respond to these challenges is now, but policymakers and decisionmakers face difficult choices. With competing priorities to balance, and potentially serious - perhaps irreversible - consequences at stake, our leaders need reliable scientific information to guide their decisions. As the Nation's earth and natural science agency, the USGS monitors and conducts scientific research on natural hazards and resources and how these elements and human activities influence our environment. Because the challenges we face are complex, the science needed to better understand and deal with these challenges must reflect the complex interplay among natural and human systems. With world-class expertise in biology, geology, geography, hydrology, geospatial information, and remote sensing, the USGS is uniquely capable of conducting the comprehensive scientific research needed to better understand the interdependent interactions of Earth's systems. Every day, the USGS helps decisionmakers to minimize loss of life and property, manage our natural resources, and protect and enhance our quality of life. This brochure provides examples of the challenges we face and how USGS science helps decisionmakers to address these challenges.

General Information Product↗

Interim report on the scientific investigations in the Animas River watershed, Colorado to facilitate remediation decisions by the U.S. Bureau of Land Management and the U.S. Forest Service, March 29, 2000 meeting, Denver, Colo.

INTRODUCTION The joint U.S. Department of the Interior and U.S. Department of Agriculture Abandoned Mine Lands Initiative (AMLI) was developed as a collaborative effort between the Federal land management agencies (FLMA, that is the U.S. Bureau of Land Management and the U.S. Forest Service) and the U.S. Geological Survey (USGS) in 1996. The stated goal of the AML Initiative was to develop a strategy for gathering and communicating the scientific information needed to develop effective and cost-efficient remediation of abandoned mines within the framework of a watershed. Four primary objectives of the AMLI are to: 1. Provide the scientific information needed (in the short-term) by the FLMAs to make decisions related to the design and implementation of cleanup actions, 2. Develop a multi-disciplined, multi-division approach that integrates geologic, hydrologic, geochemical and ecological information into a knowledge base for sound decision making, 3. Transfer technologies developed within the scientific programs of the USGS to the field and demonstrate their suitability to solve real, practical problems, and 4. Establish working relationships among involved members of land management and regulatory agencies within the framework of a watershed approach to the cleanup of abandoned mines. Long-term process-based research, including development of analytical tools, is recognized as being critical to the long-term success in remediating watersheds impacted by historical mining activities (AML 5-year plan, http://amli.usgs.gov/amli). In a meeting of Federal agencies (U.S. Bureau of Land Management [BLM], U.S. Bureau of Reclamation [BOR], U.S. National Park Service [NPS], U.S. Forest Service [USFS], the U.S. Environmental Protection Agency [EPA], the U.S. Fish and Wildlife Service [F&WS]), and State agencies (Colorado Division of Public Health and Environment, Colorado Division of Mines and Geology), several watersheds were examined within the state whose water quality was presumed to be impacted by historical mining activities. The Animas River watershed (fig. 1) was selected by the State and Federal agencies as one of two watersheds in the U.S. to be studied in detail by the USGS in the AML Initiative. Beginning in October 1997, each of the four Divisions of the USGS (Water Resources, Geologic, Biological Resources, and National Mapping) initiated a collaborative integrated science study of the watershed. Funds were provided from USGS base funding to each of the four Divisions in response to the priorities set by Congressional action and within the flexibility provided by the budgetary framework funding individual research programs. The AML Initiative provides for a five-year focused scientific effort in the two watersheds with final synthesis of the scientific results from each to be published in 2001. Publications are released on the AML web site on a regular basis (http://amli.usgs.gov/amli). On March 29, 2000, the USGS hosted a meeting for the BLM and USFS to discuss remediation options that were under consideration for the summer of 2000. The purpose of this report is to provide an overview of the scientific rational provided by the USGS to meet objective one above, and to summarize our preliminary interpretations of our data. Additional information from sites on private lands have been collected by the State of Colorado, EPA, and the ARSG. Unfortunately, these data have not been fully supplied to the USGS so our conclusions are based only upon our data. These interpretations provide science-based constraints on possible remediation options to be considered by the FLMA, the State, and local property owners in the Animas River watershed. The report is presented in outline format to facilitate discussion of remediation options at the March 29, 2000 meeting. Not all historical mining sites within the watershed are on public lands. This should not be construed to be a final report of the USGS

Denver↗

Synthesis of thirty years of surface water quality and aquatic biota data in Shenandoah National Park: Collaboration between the US Geological Survey and the National Park Service

The eastern United States has been the recipient of acidic atmospheric deposition (hereinafter, “acid rain”) for many decades. Deleterious effects of acid rain on natural resources have been well documented for surface water (e.g., Likens et al. 1996; Stoddard et al. 2001), soils (Bailey et al. 2005), forest health (Long et al. 2009), and habitat suitability for stream biota (Baker et al. 1993). Shenandoah National Park (SNP) is located in northern and central Virginia and consists of a long, narrow strip of land straddling the Blue Ridge Mountains (Figure 1). The park’s elevated topography and location downwind of the Ohio River valley, where many acidic emissions to the atmosphere are generated (NSTC 2005), have made it a target for acid rain. Characterizing the link between air quality and water quality as related to acid rain, contaminants, soil conditions, and forest health is a high priority for research and monitoring in SNP. The US Geological Survey (USGS) and SNP have had a long history of collaboration on documenting acid rain effects on the park’s natural resources, starting in 1985 and continuing to the present (Lynch and Dise 1985; Rice et al. 2001, 2004, 2005, 2007; Deviney et al. 2006, 2012; Jastram et al. 2013).

Virginia↗

How quickly do oil and gas wells “Water Out”? Quantifying and contrasting water production trends

Water production from petroleum (oil and natural gas) wells is a topic of increasing environmental and economic importance, yet quantification efforts have been limited to date, and patterns between and within petroleum plays are largely unscrutinized. Additionally, classification of reservoirs as “unconventional” (also known as “continuous”) carries scientific and regulatory importance, but in some cases the distinction from "conventional" wells is unclear. Using water, oil, and gas production data, we calculated a set of quantitative metrics that elucidate trends in the water-to-petroleum ratio over the life of each producing well. The percent growth of the water-to-petroleum ratio quantifies the degree to which a well “waters out” over time; values calculated for 153,900 wells in 18 oil and gas plays show generally much higher values for conventional wells than for continuous/unconventional wells. Analysis of the percent growth along with the slope and median metrics reveals greater variation between conventional plays and between continuous (unconventional) plays than previously recognized. Further, an example from the Bakken Formation in the Williston Basin, USA, illustrates that, within a single play, the metrics provide insight into spatial variation of water production trends, as influenced by geology and reservoir characteristics. By quantifying the variability of water production trends within individual plays and between plays, including differences between conventional and continuous (unconventional) plays, these results provide a more nuanced view of water production from oil and gas wells than has previously been possible and they illustrate the degree to which water management considerations vary spatially and temporally.

Natural Resources Research↗

Black carbon dominated dust in recent radiative forcing on Rocky Mountain snowpacks

The vast majority of surface water resources in the semi-arid western United States start as winter snowpack. Solar radiation is a primary driver of snowmelt, making snowpack water resources especially sensitive to even small increases in concentrations of light absorbing particles such as mineral dust and combustion-related black carbon (BC). Here we show, using fresh snow measurements and snowpack modeling at 51 widely distributed sites in the Rocky Mountain region, that BC dominated impurity-driven radiative forcing in 2018. BC contributed three times more radiative forcing on average than dust, and up to 17 times more at individual locations. Evaluation of 2015 to 2018 archived samples from most of the same sites yielded similar results. These findings, together with long-term observations of atmospheric concentrations and atmospheric model studies, indicate that BC rather than dust has dominated radiative forcing by light absorbing impurities on snow for decades, indicating that mitigation strategies to reduce radiative forcing on headwater snow-water resources would need to focus on reducing winter and spring BC emissions.

Colorado, Idaho, Montana, New Mexico, Utah, Wyomin↗

Stream-water chemistry, nutrients, and pesticides in Town Brook, a headwater stream of the Cannonsville Reservoir Watershed, Delaware County, New York, 1999

Stream-water chemistry was monitored from January 1 through December 31, 1999, in the Town Brook watershed (TBW) in Delaware County, N.Y. to provide a basis for future evaluation of the effectiveness of Best Management Practices (BMPs) in decreasing agricultural nutrient and pesticide leaching to receiving waters. Total runoff from the watershed during 1999 was 664 millimeters (mm). Annual nutrient export (in kilograms per hectare) values were: ammonia (NH 3 ), 0.25; nitrate (NO 3 - ), 4.3; total nitrogen (TN), 10.6; orthophosphate (OP), 0.26; total dissolved phosphorus (TDP), 0.30; and total phosphorus (TP), 1.2 during 1999. Streamwater samples were collected during baseflow, elevated baseflow, and stormflow conditions. Stormflow, which produced the greatest flowweighted mean nutrient concentrations, represented only 41 percent of the annual runoff but accounted from 49 to 68 percent of the annual nutrient export. The highest seasonal flow-weighted mean concentrations were measured during the summer; the highest concentrations occurred during a large storm on July 4, 1999 with a recurrence interval greater than 100 years. The greatest seasonal export of dissolved nutrients (NH 3 , NO 3 - , OP, and TDP) occurred during the winter, whereas the greatest export of TN and TP was during the summer. Most of the TN and TP export during the summer occurred during the July 4 storm. That storm, together with a second large storm on September 16, 1999, accounted for the following percentages of annual export: ammonia, 17 percent; NO 3 - , 21 percent; TN, 45 percent; OP, 21 percent; TDP, 21 percent; and TP, 56 percent. Although these results provide information on the quantity and timing of nutrient export, they do not indicate the nutrient source nor the transport mechanisms by which nutrients are delivered to the stream. Baseflow and stormflow samples were collected for pesticide analyses at the Town Brook watershed outlet from January through July 1999. Eight pesticides and pesticide metabolites (degradation products) were detected in the samples. Four compounds (metolachlor, atrazine, metolachlor ESA, and metolachlor OA) were detected in concentrations greater than 1 micrograms per liter (μg/L) in one or more samples. Two of these compounds.the herbicide metabolites metalochlor ESA and metalochlor OA.were detected in concentrations higher than those of the parent compound metolachlor. Only one sample, collected during the July 4 storm, exceeded New York State surface-water-quality standards for any pesticide (simazine); its concentration of 0.53 μg/L was 0.03 μg/L higher than the New York State standard (0.50 μg/L). No concentrations exceeded Federal water-quality standards. Pesticide and metabolite concentrations were as much as 25 times greater during stormflow than during baseflow. Stormflow pesticide concentrations were indicative of a spring 'flushing', in which stream pesticide concentrations are elevated from concentrations typical during the rest of the year during the first few storms after pesticide application. Pesticides and pesticide metabolites were detected in all stormflow samples. These results illustrate the need to include baseflow and stormflow in pesticide sampling routines. The results of this study emphasize the need for (1) baseflow and stormflow sampling to capture the range of nutrient and pesticide concentrations from agricultural watersheds, and (2) research to define the mechanisms of nutrient and pesticide export in agriculutral watersheds.

New York↗

Development of regional curves of bankfull-channel geometry and discharge for streams in the non-urban, Piedmont Physiographic Province, Pennsylvania and Maryland

Stream-restoration projects utilizing natural stream designs frequently are based on the bankfull-channel characteristics of stream reaches that can accommodate streamflow and sediment transport without excessive erosion or deposition and lie within a watershed that has similar runoff characteristics. The bankfull channel at an ungaged impaired site or reference reach is identified by use of field indicators and is confirmed with tools such as regional curves. Channel dimensions were surveyed at 14 streamflow-measurement stations operated by the U.S. Geological Survey (USGS) in the Gettysburg-Newark Lowland Section, Piedmont Lowland Section, and the Piedmont Upland Section of the Piedmont Physiographic Province in Pennsylvania and Maryland. From the surveyed channel dimensions, regional curves were developed from regression analyses of the relations between drainage area and the cross-sectional area, mean depth, width, and streamflow of the bankfull channel at these sites. Bankfull cross-sectional area and bankfull discharge have the strongest relation to drainage area as evidenced by R 2 values of 0.94 and 0.93, respectively. The relation between bankfull crosssectional area and drainage area has a p-value of less than 0.001; no p-value is presented for the relation between bankfull discharge and drainage area because of a non-normal residual distribution. The relation between bankfull width and drainage area has an R 2 value of 0.80 and a p-value of less than 0.001 indicating a moderate linear relation between all stations. The relation between bankfull mean depth and drainage area, with an R 2 value of 0.72 and a p-value of less than 0.001, also indicates a moderate linear relation between all stations. The concept of regional curves can be a valuable tool to support efforts in stream restoration. Practitioners of stream restoration need to recognize it as such and realize the limitations. The small number of USGS streamflow-measurement stations available for analysis is a major limiting factor in the strength of the results of this investigation, as is the inherent problem of directly associating streamflow-measurement station data to geomorphic analysis of a stream reach. Subjective selection criteria may have unnecessarily eliminated streamflow-measurement stations that could have been included in the regional curves and (or) added those that may belong within a different region. A bankfull discharge with a recurrence interval within the 1- to 2-year range commonly is used as a criterion for the confirmation of the bankfull stage at each streamflow-measurement station. Many researchers accept this range for recurrence interval of the bankfull discharge; however, literature provides contradictory evidence.

Maryland, Pennsylvania↗