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At least 1,441 records · Page 80Linked to original sources

Occurrence and temporal variability of methyl tert -butyl ether (MTBE) and other volatile organic compounds in select sources of drinking water : results of the focused survey

The large-scale use of the gasoline oxygenate methyl tert -butyl ether (MTBE), and its high solubility, low soil adsorption, and low biodegradability, has resulted in its detection in ground water and surface water in many places throughout the United States. Studies by numerous researchers, as well as many State and local environmental agencies, have discovered high levels of MTBE in soils and ground water at leaking underground gasoline-storage-tank sites and frequent occurrence of low to intermediate levels of MTBE in reservoirs used for both public water supply and recreational boating. In response to these findings, the American Water Works Association Research Foundation sponsored an investigation of MTBE and other volatile organic compounds (VOCs) in the Nation's sources of drinking water. The goal of the investigation was to provide additional information on the frequency of occurrence, concentration, and temporal variability of MTBE and other VOCs in source water used by community water systems (CWSs). The investigation was completed in two stages: (1) reviews of available literature and (2) the collection of new data. Two surveys were associated with the collection of new data. The first, termed the Random Survey, employed a statistically stratified design for sampling source water from 954 randomly selected CWSs. The second, which is the focus of this report, is termed the Focused Survey, which included samples collected from 134 CWS source waters, including ground water, reservoirs, lakes, rivers, and streams, that were suspected or known to contain MTBE. The general intent of the Focused Survey was to compare results with the Random Survey and provide an improved understanding of the occurrence, concentration, temporal variability, and anthropogenic factors associated with frequently detected VOCs. Each sample collected was analyzed for 66 VOCs, including MTBE and three other ether gasoline oxygenates (hereafter termed gasoline oxygenates). As part of the Focused Survey, 451 source-water samples and 744 field quality-control (QC) samples were collected from 78 ground-water, 39 reservoir and (or) lake, and 17 river and (or) stream source waters at fixed intervals for a period of 1 year. Using a common assessment level of 0.2 μg/L (micrograms per liter) (2.0 μg/L for methyl ethyl ketone), 37 of the 66 VOCs analyzed were detected in both surveys. However, VOCs, especially MTBE and other gasoline oxygenates, were detected more frequently in the Focused Survey than in the Random Survey. MTBE was detected in 55.5 percent of the CWSs sampled in the Focused Survey and in 8.7 percent of those sampled in the Random Survey. Little difference in occurrence, however, was observed for trihalomethanes (THMs), which were detected in 16.4 and 14.8 percent of Focused Survey and Random Survey CWSs, respectively. This may indicate a pervasive occurrence of THMs in several source-water types, regardless of CWS size or geographic location. Using data at or above the method detection limit to assess temporal variability and anthropogenic factors associated with frequent detection of select VOCs, concentrations in the Focused Survey in ground-water, reservoir, and river source waters were typically less than 1 μg/L. Also, at a 95-percent confidence interval, no statistically significant differences were observed in comparing concentrations in the first and second ground-water sample. A weak seasonal pattern was observed in samples collected from reservoirs and lakes where gasoline oxygenates and other gasoline compounds were detected more frequently during spring and summer, presumedly a result of increased use of motorized watercraft during these seasons. In contrast, seasonal patterns were not observed in samples collected from rivers and streams. The lack of seasonal differences in river and stream source waters sampled may indicate a common and continuous source of contamination. The most frequently detected VOC (MTBE) and the two most frequently occurring subgroups of VOCs (gasoline oxygenates and THMs) detected in CWS source waters were further characterized to evaluate some anthropogenic factors that may better explain their frequent occurrence. Gasoline oxygenates were detected in 73.9 percent of all CWSs sampled. The concentration of gasoline oxygenates was slightly correlated with watercraft use on reservoirs inside MTBE high-use areas (r2=0.3783) but not outside of these areas (r2=0.0242). In general, the concentration of gasoline oxygenates increased as watercraft use increased. THMs were detected in 47.8 percent of the CWSs supplied by surface water. The frequent occurrence of THMs in reservoir source waters was determined to be an artifact of disinfection and the recycling of chlorinated water to these reservoirs. All CWSs with frequent occurrence of THMs served by a reservoir indicated that chlorine was added to waters for various reasons and that the chlorinated water was then released back to, or upstream of, the reservoir or lake that was sampled.

Water-Resources Investigations Report↗

Flood characteristics of urban watersheds in the United States

A nationwide study of flood magnitude and frequency in urban areas was made for the purpose of reviewing available literature, compiling an urban flood data base, and developing methods of estimating urban floodflow characteristics in ungaged areas. The literature review contains synopses of 128 recent publications related to urban floodflow. A data base of 269 gaged basins in 56 cities and 31 States, including Hawaii, contains a wide variety of topographic and climatic characteristics, land-use variables, indices of urbanization, and flood-frequency estimates. Three sets of regression equations were developed to estimate flood discharges for ungaged sites for recurrence intervals of 2, 5, 10, 25, 50, 100, and 500 years. Two sets of regression equations are based on seven independent parameters and the third is based on three independent parameters. The only difference in the two sets of seven-parameter equations is the use of basin lag time in one and lake and reservoir storage in the other. Of primary importance in these equations is an independent estimate of the equivalent rural discharge for the ungaged basin. The equations adjust the equivalent rural discharge to an urban condition. The primary adjustment factor, or index of urbanization, is the basin development factor, a measure of the extent of development of the drainage system in the basin. This measure includes evaluations of storm drains (sewers), channel improvements, and curb-and-gutter streets. The basin development factor is statistically very significant and offers a simple and effective way of accounting for drainage development and runoff response in urban areas. Percentage of impervious area is also included in the seven-parameter equations as an additional measure of urbanization and apparently accounts for increased runoff volumes. This factor is not highly significant for large floods, which supports the generally held concept that imperviousness is not a dominant factor when soils become more saturated during large storms. Other parameters in the seven-parameter equations include drainage area size, channel slope, rainfall intensity, lake and reservoir storage, and basin lag time. These factors are all statistically significant and provide logical indices of basin conditions. The three-parameter equations include only the three most significant parameters: rural discharge, basin-development factor, and drainage area size. All three sets of regression equations provide unbiased estimates of urban flood frequency. The seven-parameter regression equations without basin lag time have average standard errors of regression varying from ? 37 percent for the 5-year flood to ? 44 percent for the 100-year flood and ? 49 percent for the 500-year flood. The other two sets of regression equations have similar accuracy. Several tests for bias, sensitivity, and hydrologic consistency are included which support the conclusion that the equations are useful throughout the United States. All estimating equations were developed from data collected on drainage basins where temporary in-channel storage, due to highway embankments, was not significant. Consequently, estimates made with these equations do not account for the reducing effect of this temporary detention storage.

Water Supply Paper↗

Tidal Wetlands and Estuaries

1. The top 1 m of tidal wetland soils and estuarine sediments of North America contains 1,886 ± 1046 teragrams of carbon (Tg C). [High confidence, Very likely] 2. Soil carbon accumulation rate (i.e., sediment burial) in North American tidal wetlands is currently 9 ± 5 Tg C per year and estuarine carbon burial is 5 ± 3 Tg C per year. [High confidence, Likely] 3. The lateral flux of carbon from tidal wetlands to estuaries is 16 ± 10 Tg C per year for North America. [Low confidence, Likely] 4. In North America, tidal wetlands remove 27 ± 13 Tg C per year from the atmosphere, estuaries outgas 10 ± 10 Tg C per year to the atmosphere, and the net uptake by the combined wetland-estuary system is 17 ± 16 Tg C per year. [Low confidence, Likely] 5. Research and modeling needs are greatest for understanding responses to accelerated sea level rise, mapping tidal wetland and estuarine extent and quantification of CO2 and CH4 exchange with the atmosphere, especially in large, under-sampled, and rapidly changing regions. [High confidence, Likely] Note: Confidence levels are provided as appropriate for quantitative, but not qualitative, Key Findings and statements.

Book chapter↗

Can differences in phosphorus uptake kinetics explain the distribution of cattail and sawgrass in the Florida Everglades?

Background Cattail ( Typha domingensis ) has been spreading in phosphorus (P) enriched areas of the oligotrophic Florida Everglades at the expense of sawgrass ( Cladium mariscus spp. jamaicense ). Abundant evidence in the literature explains how the opportunistic features of Typha might lead to a complete dominance in P-enriched areas. Less clear is how Typha can grow and acquire P at extremely low P levels, which prevail in the unimpacted areas of the Everglades. Results Apparent P uptake kinetics were measured for intact plants of Cladium and Typha acclimated to low and high P at two levels of oxygen in hydroponic culture. The saturated rate of P uptake was higher in Typha than in Cladium and higher in low-P acclimated plants than in high-P acclimated plants. The affinity for P uptake was two-fold higher in Typha than in Cladium , and two- to three-fold higher for low-P acclimated plants compared to high-P acclimated plants. As Cladium had a greater proportion of its biomass allocated to roots, the overall uptake capacity of the two species at high P did not differ. At low P availability, Typha increased biomass allocation to roots more than Cladium . Both species also adjusted their P uptake kinetics, but Typha more so than Cladium . The adjustment of the P uptake system and increased biomass allocation to roots resulted in a five-fold higher uptake per plant for Cladium and a ten-fold higher uptake for Typha . Conclusions Both Cladium and Typha adjust P uptake kinetics in relation to plant demand when P availability is high. When P concentrations are low, however, Typha adjusts P uptake kinetics and also increases allocation to roots more so than Cladium , thereby improving both efficiency and capacity of P uptake. Cladium has less need to adjust P uptake kinetics because it is already efficient at acquiring P from peat soils (e.g., through secretion of phosphatases, symbiosis with arbuscular mycorrhizal fungi, nutrient conservation growth traits). Thus, although Cladium and Typha have qualitatively similar strategies to improve P-uptake efficiency and capacity under low P-conditions, Typha shows a quantitatively greater response, possibly due to a lesser expression of these mechanisms than Cladium . This difference between the two species helps to explain why an opportunistic species such as Typha is able to grow side by side with Cladium in the P-deficient Everglades.

Florida↗

Spatial and temporal deformation along the northern San Jacinto fault, southern California: Implications for slip rates

The San Timoteo badlands is an area of uplift and erosional dissection that has formed as a result of late Quaternary uplift along a restraining bend in the San Jacinto fault, of the San Andreas fault system in southern California. This bend currently is located in a region where late Quaternary deposits and associated surfaces have formed in lower San Timoteo Canyon. We have used morphometric analysis of these surfaces, in conjunction with computer modeling of deformational patterns along the San Jacinto fault, to reconstruct spatial and temporal variations in uplift along the bend. Morphometric techniques used include envelope/subenvelope mapping, a gradient-length index along channels, and denudation values. Age control is determined using a combination of thermoluminescence (TL) and near infrared optical simulation luminescence dating (IROSL) and correlation of soil-development indices. These approaches are combined with an elastic half-space model used to determine the deformation associated with the fault bend. The region of modeled uplift has a similar distribution as that determined by morphometric techniques. Luminescence dates and soil-correlation age estimates generally agree. Based on soil development, surfaces within the study area were stabilized at approximately 300-700 ka for Q3, 43-67 ka for Q2, and 27.5-67 ka for Q1. Luminescence ages (both TL and IROSL) for the formation of the younger two surfaces are 58 to 94 ka for Q2 and 37 to 62 ka for Q1 (ages reported to 1?? uncertainty). Periods of uplift were determined for the surfaces in the study area, resulting in approximate uplift rates of 0.34 to 0.84 m/ka for the past 100 ka and 0.13 to 1.00 m/ka for the past 66 ka. Comparison of these rates of uplift to those generated by the model support a higher rate of lateral slip along the San Jacinto fault than commonly assumed (greater than 20 mm/yr, as compared to 8-12 mm/yr commonly cited). This higher slip rate supports the proposal that a greater amount of slip has transferred from the San Andreas fault to the San Jacinto fault than generally held. The San Jacinto fault may have accommodated a significant portion of the plate boundary slip during the past 100 ka.

California↗

Evaluation of measurement scale using imbibition experiments in volcanic tuffs

A major issue in the site characterization at Yucca Mountain, Nevada, a potential site for a high-level nuclear waste repository, is the relevance of laboratory-scale measurements on cores to field-scale processes, particularly water flow. Calculation of Philip`s sorptivity parameter using imbibition of water into rock was selected as a simple test to describe hydrologic parameters at both laboratory and field scales and to study effects of sample size and spatial variability. Laboratory-scale imbibition experiments were conducted on two sizes of core from two boreholes drilled in layered nonwelded tuff and fractured welded tuff. Laboratory experiments were compared with field experiments in the boreholes using neutron logs and a field-scale Mariotte system. Measured sorptivity for both sizes of core were virtually identical and both could predict field-scale sorptivity if enough samples were used to account for spatial heterogeneity. Core data was less useful in predicting the neutron log data due to the nature of the neutron probe measurement and difficulties in accounting for effects of the unique system geometry. Mean neutron log values could not predict the field results from the welded borehole due to fractures transmitting but not retaining water, and could not predict laboratory results because of scale and sampling volume differences. The mean neutron log data could, however, approximate the large-scale field results in the nonwelded borehole.

Nevada↗

Simulation of streamflow and estimation of ground-water recharge in the Upper Cibolo Creek Watershed, south-central Texas, 1992-2004

A watershed model (Hydrological Simulation Program?FORTRAN) was developed, calibrated, and tested by the U.S. Geological Survey, in cooperation with the U.S. Army Corps of Engineers, San Antonio River Authority, San Antonio Water System, and Guadalupe-Blanco River Authority, to simulate streamflow and estimate ground-water recharge in the upper Cibolo Creek watershed in south-central Texas. Rainfall, evapotranspiration, and streamflow data were collected during 1992?2004 for model calibrations and simulations. Estimates of average ground-water recharge during 1992?2004 from simulation were 79,800 acre-feet (5.47 inches) per year or about 15 percent of rainfall. Most of the recharge (about 74 percent) occurred as infiltration of streamflow in Cibolo Creek. The remaining recharge occurred as diffuse infiltration of rainfall through the soil and rock layers and karst features. Most recharge (about 77 percent) occurred in the Trinity aquifer outcrop. The remaining 23 percent occurred in the downstream part of the watershed that includes the Edwards aquifer recharge zone (outcrop). Streamflow and recharge in the study area are greatly influenced by large storms. Storms during June 1997, October 1998, and July 2002 accounted for about 11 percent of study-area rainfall, 61 percent of streamflow, and 16 percent of the total ground-water recharge during 1992?2004. Annual streamflow and recharge also were highly variable. During 1999, a dry year with about 16 inches of rain and no measurable runoff at the watershed outlet, recharge in the watershed amounted to only 0.99 inch compared with 13.43 inches during 1992, a relatively wet year with about 54 inches of rainfall. Simulation of flood-control/recharge-enhancement structures showed that certain structures might reduce flood peaks and increase recharge. Simulation of individual structures on tributaries showed relatively little effect. Larger structures on the main stem of Cibolo Creek were more effective than structures on tributaries, both in terms of flood-peak reduction and recharge enhancement. One simulated scenario that incorporated two main-stem structures resulted in a 37-percent reduction of peak flow at the watershed outlet and increases in stream-channel recharge of 6.6 percent in the Trinity aquifer outcrop and 12.6 percent in the Edwards aquifer (recharge zone) outcrop.

Texas↗

Crims Island-Restoration and monitoring of juvenile salmon rearing habitat in the Columbia River Estuary, Oregon, 2004-10

Under the 2004 Biological Opinion for operation of the Federal Columbia River Power System released by the National Marine Fisheries Service, the U.S. Army Corps of Engineers (USACE), the Bonneville Power Administration (BPA), and the Bureau of Reclamation (Reclamation) were directed to restore more than 4,047 hectares (10,000 acres) of tidal marsh in the Columbia River estuary by 2010. Restoration of Crims Island near Longview, Washington, restored 38.1 hectares of marsh and swamp in the tidal freshwater portion of the lower Columbia River. The goal of the restoration was to improve habitat for juveniles of Endangered Species Act (ESA)-listed salmon stocks and ESA-listed Columbian white-tailed deer. The U.S. Geological Survey (USGS) monitored and evaluated the fisheries and aquatic resources at Crims Island in 2004 prior to restoration (pre-restoration), which began in August 2004, and then post-restoration from 2006 to 2009. This report summarizes pre- and post-restoration monitoring data used by the USGS to evaluate project success. We evaluated project success by examining the interaction between juvenile salmon and a suite of broader ecological measures including sediments, plants, and invertebrates and their response to large-scale habitat alteration. The restoration action at Crims Island from August 2004 to September 2005 was to excavate a 0.6-meter layer of soil and dig channels in the interior of the island to remove reed canary grass and increase habitat area and tidal exchange. The excavation created 34.4 hectares of tidal emergent marsh where none previously existed and 3.7 hectares of intertidal and subtidal channels. Cattle that had grazed the island for more than 50 years were relocated. Soil excavated from the site was deposited in upland areas next to the tidal marsh to establish an upland forest. Excavation deepened and widened an existing T-shaped channel to increase tidal flow to the interior of the island. The western arm of the existing 'T-channel' was extended westward and connected to Bradbury Slough to create a second outlet to the main river. New intertidal channels were constructed from the existing 'T-channel' and tidal mudflats became inundated at high tide to increase rearing habitat for juvenile salmonids. The restoration action resulted in a 95-percent increase in available juvenile salmon rearing habitat. We collected juvenile salmon and other fishes at Crims Island and a nearby reference site using beach seines and fyke nets annually from March through August during all years. Benthic invertebrates were collected with sediment corers and drift invertebrates were collected with neuston nets. Juvenile salmon stomach contents were sampled using lavage. Vegetation and sediments characteristics were surveyed and we conducted a topographic/bathymetric survey using a RTK (real time kinematic) GPS (global positioning system). The fish assemblage at Crims Island, composed primarily of threespine stickleback (Gasterosteus aculeatus), non-native banded killifish (Fundulus diaphanus), peamouth chub (Mylocheilus caurinus), subyearling Chinook salmon (Oncorhynchus tshawytscha) (hereinafter referred to as subyearlings), and small numbers of juvenile chum salmon (Oncorhynchus keta), did not differ appreciably pre- and post-restoration. Subyearlings were the primary salmonid collected and were seasonally abundant from April through May during all years. The abundance of juvenile salmon declined seasonally as water temperature exceeded 20 degrees C in the Reference site by mid-June; however, subyearlings persisted at the Mainstem site and in subtidal channels of the Restoration site through the summer in water temperatures exceeding 22 degrees C. Residence times of subyearlings in Crims Island backwaters generally were short consisting of one or two tidal cycles. Median residence time was longer in the Restoration site than in the Reference site pre- and post-restoration. Small (mean = 55.7 millimeters) subyea

Scientific Investigations Report↗

Environmental variation, vegetation distribution, carbon dynamics and water/energy exchange at high latitudes

The responses of high latitude ecosystems to global change involve complex interactions among environmental variables, vegetation distribution, carbon dynamics, and water and energy exchange. These responses may have important consequences for the earth system. In this study, we evaluated how vegetation distribution, carbon stocks and turnover, and water and energy exchange are related to environmental variation spanned by the network of the IGBP high latitude transects. While the most notable feature of the high latitude transects is that they generally span temperature gradients from southern to northern latitudes, there are substantial differences in temperature among the transects. Also, along each transect temperature co-varies with precipitation and photosynthetically active radiation, which are also variable among the transects. Both climate and disturbance interact to influence latitudinal patterns of vegetation and soil carbon storage among the transects, and vegetation distribution appears to interact with climate to determine exchanges of heat and moisture in high latitudes. Despite limitations imposed by the data we assembled, the analyses in this study have taken an important step toward clarifying the complexity of interactions among environmental variables, vegetation distribution, carbon stocks and turnover, and water and energy exchange in high latitude regions. This study reveals the need to conduct coordinated global change studies in high latitudes to further elucidate how interactions among climate, disturbance, and vegetation distribution influence carbon dynamics and water and energy exchange in high latitudes.

Journal of Vegetation Science↗

Catchment-scale variation in the nitrate concentrations of groundwater seeps in the Catskill Mountains, New York, U.S.A.

Forested headwater streams in the Catskill Mountains of New York show significant among-catchment variability in mean annual nitrate (NO3-) concentrations. Large contributions from deep groundwater with high NO3- concentrations have been invoked to explain high NO3- concentrations in stream water during the growing season. To determine whether variable contributions of groundwater could explain among-catchment differences in streamwater, we measured NO3- concentrations in 58 groundwater seeps distributed across six catchments known to have different annual average streamwater concentrations. Seeps were identified based on release from bedrock fractures and bedding planes and had consistently lower temperatures than adjacent streamwaters. Nitrate concentrations in seeps ranged from near detection limits (0.005 mg NO3--N/L) to 0.75 mg NO3--N/L. Within individual catchments, groundwater residence time does not seem to strongly affect NO3- concentrations because in three out of four catchments there were non-significant correlations between seep silica (SiO2) concentrations, a proxy for residence time, and seep NO3- concentrations. Across catchments, there was a significant but weak negative relationship between NO3- and SiO2 concentrations. The large range in NO3- concentrations of seeps across catchments suggests: 1) the principal process generating among-catchment differences in streamwater NO3- concentrations must influence water before it enters the groundwater flow system and 2) this process must act at large spatial scales because among-catchment variability is much greater than intra-catchment variability. Differences in the quantity of groundwater contribution to stream baseflow are not sufficient to account for differences in streamwater NO3- concentrations among catchments in the Catskill Mountains.

Water, Air, & Soil Pollution↗

Influence of vertical and lateral heat transfer on permafrost thaw, peatland landscape transition, and groundwater flow

Recent climate change has reduced the spatial extent and thickness of permafrost in many discontinuous permafrost regions. Rapid permafrost thaw is producing distinct landscape changes in the Taiga Plains of the Northwest Territories, Canada. As permafrost bodies underlying forested peat plateaus shrink, the landscape slowly transitions into unforested wetlands. The expansion of wetlands has enhanced the hydrologic connectivity of many watersheds via new surface and near-surface flow paths, and increased streamflow has been observed. Furthermore, the decrease in forested peat plateaus results in a net loss of boreal forest and associated ecosystems. This study investigates fundamental processes that contribute to permafrost thaw by comparing observed and simulated thaw development and landscape transition of a peat plateau-wetland complex in the Northwest Territories, Canada from 1970 to 2012. Measured climate data are first used to drive surface energy balance simulations for the wetland and peat plateau. Near-surface soil temperatures simulated in the surface energy balance model are then applied as the upper boundary condition to a three-dimensional model of subsurface water flow and coupled energy transport with freeze-thaw. Simulation results demonstrate that lateral heat transfer, which is not considered in many permafrost models, can influence permafrost thaw rates. Furthermore, the simulations indicate that landscape evolution arising from permafrost thaw acts as a positive feedback mechanism that increases the energy absorbed at the land surface and produces additional permafrost thaw. The modeling results also demonstrate that flow rates in local groundwater flow systems may be enhanced by the degradation of isolated permafrost bodies.

Northwest Territories↗

Yucaipa valley integrated hydrological model

Introduction The hydrologic system in the Yucaipa Valley watershed (YVW) was simulated using the coupled Groundwater and Surface-water FLOW model (GSFLOW; Markstrom and others, 2008). This study uses version 2.0 of GSFLOW, which is a combination of the Precipitation-Runoff Modeling System (PRMS; Markstrom and others, 2015), and the Newton-Raphson formulation of the Modular Groundwater-Flow Model (MODFLOW-NWT; hereafter referred to as MODFLOW; Harbaugh, 2005; Niswonger and others, 2011). GSFLOW partitions the hydrologic system into three regions (fig. B1) that are linked by the exchange of unsaturated and saturated groundwater and surface water. The properties and processes within each region influence the flow of both groundwater and surface water into, out of, and within each region. The PRMS component of GSFLOW simulates Region 1, and the MODFLOW component simulates Regions 2 and 3. In the YVW, GSFLOW was applied as the simulation code and is referred to herein as the Yucaipa Integrated Hydrologic Model (YIHM; Alzraiee and others, 2022). In the YIHM, Region 1 includes the plant canopy, snowpack, and the soil zone; Region 2 includes the stream network; and Region 3 includes the subsurface beneath Regions 1 and 2 and consists of both the saturated and unsaturated zones. Soil-moisture conditions and head relations control the flow of both groundwater and surface water between regions. The maximum lateral extents of Regions 1 and 3 were defined using the surface-water drainage divides described in the “Description of Study Area” section of chapter A of this report. The boundaries for Region 2 are the lowest elevation of the streambeds, the stream channel widths, and the horizontal extent of the stream channels in the YVW. Flow across the unsaturated part of Region 3 is assumed to be vertical and does not cross the lateral boundary. To simulate hydrologic processes occurring within the YVW using GSFLOW, a model domain was defined to match the surface watershed such that the domain includes each surficial hydrologic unit coinciding (at least partially) with the Yucaipa groundwater subbasin (hereafter referred to as “Yucaipa subbasin”) as defined in California Bulletin 118 (California Department of Water Resources, 2016). The resulting simulated domain (fig. B2) includes the Yucaipa subbasin and intersects partially with parts of the San Bernardino and San Timoteo groundwater subbasins (fig. B2). The area of the active model domain in YIHM is about 121 square miles (mi2). The developed YIHM can be used to improve understanding of the hydrologic processes in YVW and to simulate future management scenarios with different climatic and anthropogenic changes.

Scientific Investigations Report↗

Effects of climate change on freshwater ecosystems of the south-eastern United States and the Gulf Coast of Mexico

The south-eastern United States and Gulf Coast of Mexico is physiographically diverse, although dominated by a broad coastal plain. Much of the region has a humid, warm temperate climate with little seasonality in precipitation but strong seasonality in runoff owing to high rates of summer evapotranspiration. The climate of southern Florida and eastern Mexico is subtropical with a distinct summer wet season and winter dry season. Regional climate models suggest that climate change resulting from a doubling of the pre-industrial levels of atmospheric CO2 may increase annual air temperatures by 3-4??C. Changes in precipitation are highly uncertain, but the most probable scenario shows higher levels over all but the northern, interior portions of the region, with increases primarily occurring in summer and occurring as more intense or clustered storms. Despite the increases in precipitation, runoff is likely to decline over much of the region owing to increases in evapotranspiration exceeding increases in precipitation. Only in Florida and the Gulf Coast areas of the US and Mexico are precipitation increases likely to exceed evapotranspiration increases, producing an increase in runoff. However, increases in storm intensity and clustering are likely to result in more extreme hydrographs, with larger peaks in flow but lower baseflows and longer periods of drought. The ecological effects of climate change on freshwaters of the region include: (1) a general increase in rates of primary production, organic matter decomposition and nutrient cycling as a result of higher temperatures and longer growing seasons: (2) reduction in habitat for cool water species, particularly fish and macroinvertebrates in Appalachian streams; (3) reduction in water quality and in suitable habitat in summer owing to lower baseflows and intensification of the temperature-dissolved oxygen squeeze in many rivers and reservoirs; (4) reduction in organic matter storage and loss of organisms during more intense flushing events in some streams and wetlands; (5) shorter periods of inundation of riparian wetlands and greater drying of wetland soils, particularly in northern and inland areas; (6) expansion of subtropical species northwards, including several non-native nuisance species currently confined to southern Florida; (7) expansion of wetlands in Florida and coastal Mexico, but increase in eutrophication of Florida lakes as a result of greater runoff from urban and agricultural areas; and (8) changes in the flushing rate of estuaries that would alter their salinity regimes, stratification and water quality as well as influence productivity in the Gulf of Mexico. Many of the expected climate change effects will exacerbate current anthropogenic stresses on the region's freshwater systems, including increasing demands for water, increasing waste heat loadings and land use changes that alter the quantity and quality of runoff to streams and reservoirs. Research is needed especially in several critical areas: long-term monitoring of key hydrological, chemical and biological properties (particularly water balances in small, forested catchments and temperature-sensitive species); experimental studies of the effects of warming on organisms and ecosystem processes under realistic conditions (e.g. in situ heating experiments); studies of the effects of natural hydrological variation on biological communities; and assessment of the effects of water management activities on organisms and ecosystem processes, including development and testing of management and restoration strategies designed to counteract changes in climate.

Hydrological Processes↗

Seasonal cycles of dissolved constituents in streamwater in two forested catchments in the mid-Atlantic region of the eastern U.S.A.

Streamwater discharge and chemistry of two small catchments on Catoctin Mountain in north-central Maryland have been monitored since 1982. Repetitive seasonal cycles in stream-water chemistry have been observed each year, along with seasonal cycles in the volume of stream discharge and in groundwater levels. The hypothesis that the observed streamwater chemical cycles are related to seasonal changes in the hydrological flow paths that contribute to streamflow is examined using a combination of data on groundwater levels, shallow and deep groundwater chemistry, streamwater discharge, streamwater chemistry, soil-water chemistry, and estimates of water residence times. The concentrations of constituents derived from rock weathering, particularly bicarbonate and silica, increase in streamwater during the summer when the water table is below the regolith-bedrock interface and stream discharge consists primarily of deep groundwater from the fractured-bedrock aquifer. Conversely, the concentrations in streamwater of atmospherically derived components, particularly sulfate, increase in winter when the water table is above the regolith-bedrock interface and stream discharge consists primarily of shallow groundwater from the regolith. Tritium and chlorofluorocarbon (CFC) measurements suggest that the groundwater in these systems is young, with a residence time of less than several years. The results of this study have implications for the design of large-scale water-quality monitoring programs.

Maryland↗

Infiltration through layered-soil trench covers: Response to an extended period of rainfall

Four experimental waste disposal trench covers were constructed to test the effectiveness of layered-soil cover designs in reducing infiltration. Three covers each consisted of a layer of gravel between an overlying wick layer of compacted fine-grained material (either silt or loam) and a compacted loam base; the fourth consisted of compactd silt over a loam base. Capillary pressures were monitored at various depths within each cover during October through December, 1985, a period of high rainfall following a dry summer. Moisture movement in response to the rainfall was rapid within the upper layers of all four test covers, but was retained within the upper layers of the three wick-system trenches, despite variations in the design thickness and composition of the wick layers. In the wick systems, moisture did not enter the gravel until a threshold level of pressure approaching saturation was established in the wick layer. Once this level was reached, moisture moved into and through the gravel. This experiment demonstrates the functionality of field-scale wick systems.

Journal of Contaminant Hydrology↗

A global dataset of terrestrial biological nitrogen fixation

Biological nitrogen fixation (BNF) is the main natural source of new nitrogen inputs in terrestrial ecosystems, supporting terrestrial productivity, carbon uptake, and other Earth system processes. We assembled a comprehensive global dataset of field measurements of BNF in all major N-fixing niches across natural terrestrial biomes derived from the analysis of 376 BNF studies. The dataset comprises 32 variables, including site location, biome type, N-fixing niche, sampling year, quantification method, BNF rate (kg N ha −1 y −1 ), the percentage of nitrogen derived from the atmosphere (%N dfa ), N fixer or N-fixing substrate abundance, BNF rate per unit of N fixer abundance, and species identity. Overall, the dataset combines 1,207 BNF rates for trees, shrubs, herbs, soil, leaf litter, woody litter, dead wood, mosses, lichens, and biocrusts, 152 herb %N dfa values, 1,005 measurements of N fixer or N-fixing substrate abundance, and 762 BNF rates per unit of N fixer abundance for a total of 424 species across 66 countries. This dataset facilitates synthesis, meta-analysis, upscaling, and model benchmarking of BNF fluxes at multiple spatial scales.

Scientific Data↗

Historic changes to floodplain systems in the Driftless Area

Floodplain systems in the Driftless Area have experienced widespread historical transformations in hydrologic and sediment characteristics as well as rates of hydrogeomorphic processes. These changes exceed natural variability experienced during the Holocene and are driven by nearly two centuries of major land-cover alterations coupled with shifting precipitation patterns. On the pre–Euro-American landscape, tributaries to the Upper Mississippi River had clear, constant base flow and low sedimentation rates due to a protective cover of prairie, oak savanna, and woodland. The Upper Mississippi River was sandy and braided, with geomorphologically diverse backwaters, side channels, and vegetated islands. Soil erosion and gullying caused by agriculture-related land clearance have had the largest historical effects on Upper Mississippi River tributary stream morphology and floodplain sedimentation. Floodplain sedimentation rates for tributaries and the Upper Mississippi River were 0.2 and 0.9 mm/yr, respectively, before Euro-American settlement, compared to 2–20 and 5–20 mm/yr after Euro-American settlement, respectively. The soil conservation movement had its birthplace in the Driftless Area in the 1920s because of the region’s widespread landscape degradation. As soil erosion decreased and gullies were stabilized in the middle to late twentieth century, land management efforts turned toward the lingering problem of fine-grained, phosphorus-rich sediment stored in tributary floodplains and channels. This trend has been complicated by a climatic shift in the late twentieth century toward increased annual precipitation, increased flood variability, and more floods in late fall and winter months, when bare fields are vulnerable to runoff. Floods are major contributors to channel erosion and deposition, and variability in magnitudes and frequency will likely continue in the early twenty-first century. Restoration efforts in tributaries have included reducing bank erosion, reconnecting floodplains, and adding trout habitat features. Lock and dam structures have altered sediment transport and erosion processes within the Upper Mississippi River, and restoration efforts there have focused on creation and rehabilitation of islands and protection of remnant off-channel backwater habitats.

Illinois, Wisconsin↗

Global methane budget 2000-2020

Understanding and quantifying the global methane (CH 4 ) budget is important for assessing realistic pathways to mitigate climate change. CH 4 is the second most important human-influenced greenhouse gas in terms of climate forcing after carbon dioxide (CO 2 ), and both emissions and atmospheric concentrations of CH 4 have continued to increase since 2007 after a temporary pause. The relative importance of CH 4 emissions compared to those of CO 2 for temperature change is related to its shorter atmospheric lifetime, stronger radiative effect, and acceleration in atmospheric growth rate over the past decade, the causes of which are still debated. Two major challenges in quantifying the factors responsible for the observed atmospheric growth rate arise from diverse, geographically overlapping CH 4 sources and from the uncertain magnitude and temporal change in the destruction of CH 4 by short-lived and highly variable hydroxyl radicals (OH). To address these challenges, we have established a consortium of multidisciplinary scientists under the umbrella of the Global Carbon Project to improve, synthesise, and update the global CH 4 budget regularly and to stimulate new research on the methane cycle. Following Saunois et al. (2016, 2020), we present here the third version of the living review paper dedicated to the decadal CH 4 budget, integrating results of top-down CH 4 emission estimates (based on in situ and Greenhouse Gases Observing SATellite (GOSAT) atmospheric observations and an ensemble of atmospheric inverse-model results) and bottom-up estimates (based on process-based models for estimating land surface emissions and atmospheric chemistry, inventories of anthropogenic emissions, and data-driven extrapolations). We present a budget for the most recent 2010–2019 calendar decade (the latest period for which full data sets are available), for the previous decade of 2000–2009 and for the year 2020. The revision of the bottom-up budget in this 2025 edition benefits from important progress in estimating inland freshwater emissions, with better counting of emissions from lakes and ponds, reservoirs, and streams and rivers. This budget also reduces double counting across freshwater and wetland emissions and, for the first time, includes an estimate of the potential double counting that may exist (average of 23 Tg CH 4 yr −1 ). Bottom-up approaches show that the combined wetland and inland freshwater emissions average 248 [159–369] Tg CH 4 yr −1 for the 2010–2019 decade. Natural fluxes are perturbed by human activities through climate, eutrophication, and land use. In this budget, we also estimate, for the first time, this anthropogenic component contributing to wetland and inland freshwater emissions. Newly available gridded products also allowed us to derive an almost complete latitudinal and regional budget based on bottom-up approaches. For the 2010–2019 decade, global CH 4 emissions are estimated by atmospheric inversions (top-down) to be 575 Tg CH 4 yr −1 (range 553–586, corresponding to the minimum and maximum estimates of the model ensemble). Of this amount, 369 Tg CH 4 yr −1 or ∼ 65 % is attributed to direct anthropogenic sources in the fossil, agriculture, and waste and anthropogenic biomass burning (range 350–391 Tg CH 4 yr −1 or 63 %–68 %). For the 2000–2009 period, the atmospheric inversions give a slightly lower total emission than for 2010–2019, by 32 Tg CH 4 yr −1 (range 9–40). The 2020 emission rate is the highest of the period and reaches 608 Tg CH 4 yr −1 (range 581–627), which is 12 % higher than the average emissions in the 2000s. Since 2012, global direct anthropogenic CH 4 emission trends have been tracking scenarios that assume no or minimal climate mitigation policies proposed by the Intergovernmental Panel on Climate Change (shared socio-economic pathways SSP5 and SSP3). Bottom-up methods suggest 16 % (94 Tg CH 4 yr −1 ) larger global emissions (669 Tg CH 4 yr −1 , range 512–849) than top-down inversion methods for the 2010–2019 period. The discrepancy between the bottom-up and the top-down budgets has been greatly reduced compared to the previous differences (167 and 156 Tg CH 4 yr −1 in Saunois et al. (2016, 2020) respectively), and for the first time uncertainties in bottom-up and top-down budgets overlap. Although differences have been reduced between inversions and bottom-up, the most important source of uncertainty in the global CH 4 budget is still attributable to natural emissions, especially those from wetlands and inland freshwaters. The tropospheric loss of methane, as the main contributor to methane lifetime, has been estimated at 563 [510–663] Tg CH 4 yr −1 based on chemistry–climate models. These values are slightly larger than for 2000–2009 due to the impact of the rise in atmospheric methane and remaining large uncertainty ( ∼ 25 %). The total sink of CH 4 is estimated at 633 [507–796] Tg CH 4 yr −1 by the bottom-up approaches and at 554 [550–567] Tg CH 4 yr −1 by top-down approaches. However, most of the top-down models use the same OH distribution, which introduces less uncertainty to the global budget than is likely justified. For 2010–2019, agriculture and waste contributed an estimated 228 [213–242] Tg CH 4 yr −1 in the top-down budget and 211 [195–231] Tg CH 4 yr −1 in the bottom-up budget. Fossil fuel emissions contributed 115 [100–124] Tg CH 4 yr −1 in the top-down budget and 120 [117–125] Tg CH 4 yr −1 in the bottom-up budget. Biomass and biofuel burning contributed 27 [26–27] Tg CH 4 yr −1 in the top-down budget and 28 [21–39] Tg CH 4 yr −1 in the bottom-up budget. We identify five major priorities for improving the CH 4 budget: (i) producing a global, high-resolution map of water-saturated soils and inundated areas emitting CH 4 based on a robust classification of different types of emitting ecosystems; (ii) further development of process-based models for inland-water emissions; (iii) intensification of CH 4 observations at local (e.g. FLUXNET-CH 4 measurements, urban-scale monitoring, satellite imagery with pointing capabilities) to regional scales (surface networks and global remote sensing measurements from satellites) to constrain both bottom-up models and atmospheric inversions; (iv) improvements of transport models and the representation of photochemical sinks in top-down inversions; and (v) integration of 3D variational inversion systems using isotopic and/or co-emitted species such as ethane as well as information in the bottom-up inventories on anthropogenic super-emitters detected by remote sensing (mainly oil and gas sector but also coal, agriculture, and landfills) to improve source partitioning.

Earth System Science Data↗