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USGS2015

Weathering and transport of chromium and nickel from serpentinite in the Coast Range ophiolite to the Sacramento Valley, California, USA

A soil geochemical study in northern California was done to investigate the role that weathering and transport play in the regional distribution and mobility of geogenic Cr and Ni, which are both potentially toxic and carcinogenic. These elements are enriched in ultramafic rocks (primarily serpentinite) and the soils derived from them (1700–10,000 mg Cr per kg soil and 1300–3900 mg Ni per kg soil) in the Coast Range ophiolite. Chromium and Ni have been transported eastward from the Coast Range into the western Sacramento Valley and as a result, valley soil is enriched in Cr (80–1420 mg kg −1 ) and Ni (65–224 mg kg −1 ) compared to median values of U.S. soils of 50 and 15 mg kg −1 , respectively. Nickel in ultramafic source rocks and soils is present in serpentine minerals (lizardite, antigorite, and chrysotile) and is more easily weathered compared to Cr, which primarily resides in highly refractory chromite ([Mg,Fe 2+ ][Cr 3+ ,Al,Fe 3+ ] 2 O 4 ). Although the majority of Cr and Ni in soils are in refractory chromite and serpentine minerals, the etching and dissolution of these minerals, presence of Cr- and Ni-enriched clay minerals and development of nanocrystalline Fe (hydr)oxides is evidence that a significant fractions of these elements have been transferred to potentially more labile phases.

California↗

USGS2004

A combined basalt and peridotite perspective on 14 million years of melt generation at the Atlantis Bank segment of the Southwest Indian Ridge: Evidence for temporal changes in mantle dynamics?

Little is known about temporal variations in melt generation and extraction at midocean ridges largely due to the paucity of sampling along flow lines. Here we present new whole-rock major and trace element data, and mineral and glass major element data, for 71 basaltic samples (lavas and dykes) and 23 peridotites from the same ridge segment (the Atlantis Bank segment of the Southwest Indian Ridge). These samples span an age range of almost 14 My and, in combination with the large amount of published data from this area, allow temporal variations in melting processes to be investigated. Basalts show systematic changes in incompatible trace element ratios with the older samples (from ???8-14 Ma) having more depleted incompatible trace element ratios than the younger ones. There is, however, no corresponding change in peridotite compositions. Peridotites come from the top of the melting column, where the extent of melting is highest, suggesting that the maximum degree of melting did not change over this interval of time. New and published Nd isotopic ratios of basalts, dykes and gabbros from this segment suggest that the average source composition has been approximately constant over this time interval. These data are most readily explained by a model in which the average source composition and temperature have not changed over the last 14 My, but the dynamics of mantle flow (active-to-passive) or melt extraction (less-to-more efficient extraction from the 'wings' of the melting column) has changed significantly. This hypothesised change in mantle dynamics occurs at roughly the same time as a change from a period of detachment faulting to 'normal' crustal accretion. We speculate that active mantle flow may impart sufficient shear stress on the base of the lithosphere to rotate the regional stress field and promote the formation of low angle normal faults. ?? 2004 Elsevier B.V. All rights reserved.

Chemical Geology↗

USGS2011

Trace and minor element variations and sulfur isotopes in crystalline and colloform ZnS: Incorporation mechanisms and implications for their genesis

Various models have been proposed to explain the formation mechanism of colloform sphalerite, but the origin is still under debate. In order to decipher influences on trace element incorporation and sulfur isotope composition, crystalline and colloform sphalerite from the carbonate-hosted Mississippi-Valley Type (MVT) deposit near Wiesloch, SW Germany, were investigated and compared to sphalerite samples from 52 hydrothermal vein-type deposits in the Schwarzwald ore district, SW Germany to study the influence of different host rocks, formation mechanisms and fluid origin on trace element incorporation. Trace and minor element incorporation in sphalerite shows some correlation to their host rock and/or origin of fluid, gangue, paragenetic minerals and precipitation mechanisms (e.g., diagenetic processes, fluid cooling or fluid mixing). Furthermore, crystalline sphalerite is generally enriched in elements like Cd, Cu, Sb and Ag compared to colloform sphalerite that mainly incorporates elements like As, Pb and Tl. In addition, sulfur isotopes are characterized by positive values for crystalline and strongly negative values for colloform sphalerite. The combination of trace element contents, typical minerals associated with colloform sphalerite from Wiesloch, sulfur isotopes and thermodynamic considerations helped to evaluate the involvement of sulfate-reducing bacteria in water-filled karst cavities. Sulfate-reducing bacteria cause a sulfide-rich environment that leads in case of a metal-rich fluid supply to a sudden oversaturation of the fluid with respect to galena, sphalerite and pyrite. This, however, exactly coincides with the observed crystallization sequence of samples involving colloform sphalerite from the Wiesloch MVT deposit.

Wiesloch↗

USGS2011

Seasonal dripwater Mg/Ca and Sr/Ca variations driven by cave ventilation: Implications for and modeling of speleothem paleoclimate records

A 4-year study in a central Texas cave quantifies multiple mechanisms that control dripwater composition and how these mechanisms vary at different drip sites. We monitored cave-air compositions, in situ calcite growth, dripwater composition and drip rate every 4–6 weeks. Three groups of drip sites are delineated (Groups 1–3) based on geochemical variations in dripwater composition. Quantitative modeling of mineral-solution reactions within the host carbonate rock and cave environments is used to identify mechanisms that can account for variations in dripwater compositions. The covariation of Mg/Ca (and Sr/Ca) and Sr isotopes is key in delineating whether Mg/Ca and Sr/Ca variations are dictated by water–rock interaction (i.e., calcite or dolomite recrystallization) or prior calcite precipitation (PCP). Group 1 dripwater compositions reflects a narrow range of the extent of water–rock interaction followed by varying amounts of prior calcite precipitation (PCP). Group 2 dripwater compositions are controlled by varying amounts of water–rock interaction with little to no PCP influence. Group 3 dripwater compositions are dictated by variable extents of both water–rock interaction and PCP. Group 1 drip sites show seasonal variations in dripwater Mg/Ca and Sr/Ca, whereas the other drip sites do not. In contrast to the findings of most previous dripwater Mg/Ca–Sr/Ca studies, these seasonal variations (at Group 1 drip sites) are independent of changes in water flux (i.e., rainfall and/or drip rate), and instead significantly correlate with changes in cave-air CO 2 concentrations. These results are consistent with lower cave-air CO 2 , related to cool season ventilation of the cave atmosphere, enhancing calcite precipitation and leading to dripwater geochemical evolution via PCP. Group 1 dripwater Mg/Ca and Sr/Ca seasonality and evidence for PCP as a mechanism that can account for that seasonality, have two implications for many other regions where seasonal ventilation of caves is likely: (1) speleothem trace-element records may provide seasonal signals, and (2) such records may be biased toward recording climate conditions during the season when calcite is depositing. Additionally, we use our results to construct a forward model that illustrates the types of speleothem Mg/Ca and Sr/Ca variations that would result from varying controls on dripwater compositions. The model provides a basis for interpreting paleo-dripwater controls from high frequency Mg/Ca and Sr/Ca variations for speleothems from caves at which long term monitoring studies are not feasible.

Geochimica et Cosmochimica Acta↗

USGS1991

Petrology of lower crustal and upper mantle xenoliths from the Cima Volcanic Field, California

Basaltic rocks of the Cima volcanic field in the southern Basin and Range province contain abundant gabbro, pyroxenite, and peridotite xenoliths. Composite xenoliths containing two or more rock types show that upper-mantle spinel peridotite was enriched by multiple dike intrusions in at least three episodes; the mantle was further enriched by intergranular and shear-zone melt infiltration in at least two episodes. The oldest dikes, now metamorphosed, are Cr-diopside websterite. Dikes of intermediate age are most abundant at Cima and consist of igneous-textured websterite and two-pyroxene gabbro and microgabbro of tholeiitic or calcalkalic parentage. The youngest dikes are igneous-textured clinopyroxenite, gabbro, and olivine microgabbro of alkalic parentage. The dikes in peridotite are interpreted as parts of a system of conduits through which tholeiitic (or calcalkalic) and alkalic magmas fed lower-crustal intrusions, which are represented by abundant xenoliths of the same igneous rock types as observed in the dikes. Mineral assemblages of dikes in peridotite indicate that an enriched uppermost mantle zone no thicker than 15 km could have been sampled. Because of their high densities, the gabbros and pyroxenites can occupy the zone immediately above the present Moho (modeled on seismic data as 10-13 km thick, with V p 6.8 km/s) only if their seismic velocities are reduced by the joints, partial melts, and fluid inclusions that occur in them. Alternatively, these xenoliths may have been derived entirely from beneath the Moho, in which case the Moho is not the local crust-mantle boundary.

Journal of Petrology↗

USGS1949

Hawaiian petrographic province

The lavas of the Hawaiian Islands range from mafic picrite-basalts and melilite-nepheline basalts to salic trachytes. Olivine basalt, by far the most abundant type, is regarded as representing the parent magma of the Hawaiian province. Closely associated with the olivine basalts are basalts, and picrite-basalts with many large phenocrysts of olivine. Further differentiation results in eruption of andesine andesite, oligoclase andesite, picritebasalt with abundant large augite phenocrysts, and more rarely trachyte. Following a long period of quiescence there have been erupted on some islands nepheline basanite, nepheline basalt, melilite-nepheline basalt, “linosaite,” and a third type of picrite-basalt. The mineral and chemical composition of the various rock types, and their distribution on the individual islands, are described. Starting with olivine basalt as the parent magma means of deriving the other rock types are considered. It is concluded that crystal differentiation has been the principal process, although assimilation of limestone may also have been important. The parts played by gaseous transfer and selective remelting are difficult to evaluate, though both probably operated to some extent. Comparison of the types of igneous rocks in the Hawaiian province with those recorded from other Pacific islands shows that the rocks throughout the true Pacific Basin are, for the most part, closely similar, and suggests essential uniformity of parent magma and petrogenic processes throughout the Pacific Basin.

Hawaii↗

USGS1992

Impact origin of the Avak Structure, Arctic Alaska, and genesis of the Barrow gas fields

Geophysical and subsurface geologic data suggest that the Avak structure, which underlies the Arctic Coastal Plain 12 km southeast of Barrow, Alaska, is a hypervelocity meteorite or comet impact structure. The structure is a roughly circular area of uplifted, chaotically deformed Upper Triassic to Lower Cretaceous sedimentary rocks 8 km in diameter that is bounded by a ring of anastomosing, inwardly dipping, listric normal faults 12 km in diameter. A zone of gently outward-dipping sedimentary country rocks forms a discontinuous ring of "rim anticlines" within the peripheral ring of normal faults. Beyond these anticlines, the sedimentary rocks are almost flat-lying. Basement consists of strongly deformed Ordovician and Silurian argillite. Density and acoustic impedance con rasts between the argillite and the overlying strata produce gravity and seismic-reflection signatures that define a ring of anticlines around the disturbed zone and a structural high surrounded by an annular structural low at its center. In the adjacent Barrow gas fields, the tops of the informally named Neocomian "pebble shale" unit and the gas-producing Lower Jurassic Barrow sand (local usage) lie at average subsea depths of 488 m and 670 m, respectively. In the Avak 1 well, drilled on the central high, the pebble shale and the Barrow sand lie near the surface, documenting more than 500 m of relative uplift at the high. The cores in this well have steep dips (30-90 degrees), mixed breccia with Franklinian argillite clasts 10 and 90 m above basement, quartz grains with shock mosaicism and multiple sets of shock lamellae, oriented concussion fractures in sand-size quartz grains, and shatter cones resembling those found in the peripheral zones of well-documented impact structures. In addition, above-background levels o fractured quartz grains in Barrow sand were found as far as 19 km beyond the rim of the Avak structure. Data concerning the age of the Avak structure are not definitive. If submarine landslide deposits in the upper part of the Aptian and Albian Torok Formation, in the subsurface 200 km to the east, were triggered by the Avak event, then the Avak meteorite struck a submerged marine shelf about 100 + or - 5 Ma. However, the impact features found at Avak (shatter cones, concussion fractures, shock lamellae and shock mosaicism in quartz grains, and widespread cataclasis) characterize the distal zones of meteorite impact structures. Fused rocks, plastic deformation, and shock-metamorphic minerals found in more proximal zones of impact structures are apparently missing. These observations, and the lack of Avak ejecta in cuttings and cores from the Torok Formation and Nanushuk Group (Albian to middle Cenomanian) in surrounding test wells, indicate that the impact event postdated these beds. In this case, the Avak meteorite struck a Late Cretaceous or Tertiary marine shelf or coastal plain between the Cenomanian (ca. 95 Ma), and deposition of the basal beds of the overlying late Pliocene and Quaternary Gubik Formation (ca. 3 Ma).

Alaska↗

USGS1983

The mobility and distribution of heavy metals during the formation of first cycle red beds

Holocene-Pliocene sequence sampled in northern Baja California. Geochemical data supported by petrographic, X-ray, and SEM observations of mineralogical transformations, fission-track radiography, and uranium decay series measurements. Results indicate that metal content of the studied samples is inherited from constituent detrital minerals and that reddening of whole-rock samples does not promote major open-system migration of heavy metals. The amount of secondary iron oxides and the fraction of whole-rock metals associated with the oxides increase during red-bed development. Results suggest that developed red beds which are well flushed by suitable pore fluids may be sources of significant quantities of heavy metals.

Economic Geology↗

USGS2015

Geochemistry and occurrence of selenium: An overview

Selenium (Se) is both beneficial and toxic to animals, plants, and humans. Consequently, it is imperative to know its concentration in the environment and to understand the processes controlling its distribution. Determinations of Se concentrations in a variety of materials indicate that Se is widely distributed throughout the environment. The processes responsible for its distribution include volcanic activity, the burning of fossil fuels, the weathering of rocks and soils, groundwater transport, precipitation of minerals, adsorption, chemical or bacterial reduction and oxidation, and metabolic uptake and release by plants and animals. The importance of a particular process in controlling the distribution of Se is intimately linked to the speciation of Se, which is controlled by the pH and redox conditions of the environment. Selenium can exist as selenide (Se 2− ), elemental Se (Se 0 ), selenite (SeO 2− 3 ), and selenate (SeO 2− 4 ). Each oxidation state exhibits different chemical behavior. Selenide and elemental Se occur in acidic, reducing, and organic-rich environments. Metal selenides, Se-sulfides, and elemental Se are insoluble, and therefore biologically unavailable. For the pH and redox conditions of most soil and aquatic environments, SeO 2− 3 and SeO 2− 4 ; should be the dominant forms of Se. Selenite is immobilized by adsorption onto particles, particularly Fe oxyhydroxides. Selenate is highly mobile and biologically available because of the solubility of its salts and its weak adsorption by particles. Microbial action can change the speciation of Se through oxidation or reduction, or through the formation of organic Se compounds.

Book chapter↗

USGS1967

Metalliferous lode deposits of Alaska

An important factor in any rebirth of metal mining in Alaska will be a thorough appraisal of the metalliferous lodes already known in the State. Any such appraisal probably will depend, at least in part, on an inventory of these 1 deposits and a knowledge of their geology. This report summarizes from repoAs of Federal and State agencies published before August 31, 1965, the geology of Alaska's metal-bearing lodes, including their structural or stratigraphic control, host rock, mode of origin, kinds of .Q minerals, grade, past production, and extent of exploration. In addition, the lists of mineral occurrences that accompany the 35 mineral-deposit location maps constitute an inventory of the State's known lodes. A total of 692 localities where m&alliferous deposits have been found are shown on the maps. The localities include 1,739 mines, prospects, and reported occurrences, of which 821 are described individually or otherwise cited in the text.

Alaska↗

USGS2005

Chapter K: Progress in the Evaluation of Alkali-Aggregate Reaction in Concrete Construction in the Pacific Northwest, United States and Canada

The supply of aggregates suitable for use in construction and maintenance of infrastructure in western North America is a continuing concern to the engineering and resources-management community. Steady population growth throughout the region has fueled demand for high-quality aggregates, in the face of rapid depletion of existing aggregate resources and slow and difficult permitting of new sources of traditional aggregate types. In addition to these challenges, the requirement for aggregates to meet various engineering standards continues to increase. In addition to their physical-mechanical properties, other performance characteristics of construction aggregates specifically depend on their mineralogy and texture. These properties can result in deleterious chemical reactions when aggregate is used in concrete mixes. When this chemical reaction-termed 'alkali-aggregate reaction' (AAR)-occurs, it can pose a major problem for concrete structures, reducing their service life and requiring expensive repair or even replacement of the concrete. AAR is thus to be avoided in order to promote the longevity of concrete structures and to ensure that public moneys invested in infrastructure are well spent. Because the AAR phenomenon is directly related to the mineral composition, texture, and petrogenesis of the rock particles that make up aggregates, an understanding of the relation between the geology and the performance of aggregates in concrete is important. In the Pacific Northwest, some aggregates have a moderate to high AAR potential, but many others have no or only a low AAR potential. Overall, AAR is not as widespread or serious a problem in the Pacific Northwest as in other regions of North America. The identification of reactive aggregates in the Pacific Northwest and the accurate prediction of their behavior in concrete continue to present challenges for the assessment and management of geologic resources to the owners and operators of pits and quarries and to the users of the concrete aggregates mined from these deposits. This situation is complicated by the length of time typically required for AAR to become noticeable in concrete construction in the Pacific Northwest, commonly on such a scale that other deterioration mechanisms may have masked the effects of AAR. Distinguishing between the effects of AAR and those related to other problems in concrete is important for understanding the nature and severity of AAR throughout the Pacific Northwest. Furthermore, developing an understanding of the extent of the problem will assist efforts to maximize the intelligent and stewardly use of aggregate resources in the Pacific Northwest. This chapter illustrates the current 'state of the art' of AAR studies in the Pacific Northwest, a region with a common geologic heritage as well as many distinct geologic elements. The optimal use of aggregates in the construction of concrete structures that will achieve their design life is possible through an understanding of the engineering and geologic properties of these aggregates and of their geologic setting.

Bulletin↗

USGS2000

U.S. Geological Survey Quality-Assurance Project for Sediment Analysis

Introduction Sediment is derived primarily from natural weathering of rock and is an assemblage of individual mineral grains that are then deposited by some physical agent, such as water, wind, ice, or gravity (Fetter, 1988). The U.S. Geological Survey (USGS) samples sediments and collects data on the amount of sediment in selected waterways. The most pressing sediment-related problems are associated with environmental questions, such as the transport and fate of attached pollutants, effects of sediment on aquatic biota and their habitats, and effects on sediment transport from land-use changes. Current (2000) sediment issues require that sediment studies address multiple objectives in water-resources management (Koltun and others, 1997). To support sediment research, the USGS operates laboratories for the analysis of the physical characteristics of sediment. Sediment laboratories producing data for the USGS have two principal functions: (1) the determination of suspended-sediment concentration in samples and (2) the determination of sand/fine separations. The reliability of these determinations and the usefulness of the data are dependent on the accuracy and reliability of the laboratory analyses (Guy, 1969).

Fact Sheet↗

USGS1975

Tungsten anomalies in the Uyaijah ring structure, Kushaymiyah igneous complex, Kingdom of Saudi Arabia - Section A, Geology and geochemistry of the Uyaijah ring structure; Section B, Regional geophysics

Anomalous amounts of tungsten, molybdenum, and bismuth are present in the Uyaijah ring structure of the Kushaymiyah igneous complex in the eastern part of the Precambrian shield of the Kingdom of Saudi Arabia. The complex includes four major rock units, the Murdama Group, porphyritic granodiorite, quartz monzonite, alkaline granite, and areas enriched in silica. Structural and compositional relationships among some of the rock units are defined in part by aeromagnetic and gamma-ray spectrometric geophysical data. Geochemical data from -10 +30 mesh surficial debris were primarily related to the composition of the major rock units, whereas data from heavy-mineral concentrates were used to establish the location of tungsten-molybdenum-bismuth anomalies. Two areas of about 40 sq km each are occupied by tungsten-molybdenum-bismuth anomalies interpreted to be related to the alkaline granite. One of these is a contact metasomatic anomaly; the other is related to leakage from an inferred underlying cupola of the alkaline granite. These two anomalous areas are recommended for further investigation

Open-File Report↗

USGS1996

Hydrogeologic framework of the Edwards-Trinity aquifer system, west-central Texas

The Edwards-Trinity aquifer system underlies about 42,000 square miles of west-central Texas, where mostly gently dipping Lower Cretaceous strata comprise three regional aquifers and two regional confining units. The aquifers are the Edwards Aquifer of the Balcones fault zone, the Trinity Aquifer of the Balcones fault zone and Hill County, and the Edwards-Trinity Aquifer of the Edwards Plateau and Trans-Pecos. The Navarro-Del Rio confining unit confines the downdip part of the Edwards Aquifer, and the Hammett confining unit confines the updip, basal part of the Trinity Aquifer and a small southeastern fringe of the Edwards-Trinity Aquifer. Transmissivity averages less than 10,000 feet squared per day throughout more than 90 percent of the study area as the result of widespread cementation and secondary mineral growth. However, in fractured and leached rocks in the Balcones fault zone, transmissivity averages about 750,000 feet squared per day in the Edwards aquifer, which occupies less than 10 percent of the area.

Texas↗

USGS1996

Ground-water resources and water-supply alternatives in the Wawona area of Yosemite National Park, California

Planning efforts to implement the 1980 General Management Plan, which recommends relocating park administrative facilities and employee housing from Yosemite Valley in Yosemite National Park, California, have focused on the availability of water at potential relocation sites within the park. Ground-water resources and water-supply alternatives in the Wawona area, one of several potential relocation sites, were evaluated between June 1991 and October 1993. Ground water flowing from Biledo Spring near the headwaters of Rainier Creek, about 5 miles southeast of Wawona, is probably the most reliable source of good quality ground water for Wawona. A dilute calcium bicarbonate ground water flows from the spring at about 250 gallons per minute. No Giardia was detected in a water sample collected from Biledo Spring in July 1992. The concentration of dissolved 222 radon at Biledo Spring was 420 picoCuries per liter, exceeding the primary drinking-water standard of 300 picoCuries per liter proposed by the U.S. Environmental Protection Agency. This concentration, however, was considerably lower than the concentrations of dissolved 222 radon measured in ground water at Wawona. The median value for 15 wells sampled at Wawona was 4,500 picoCuries per liter. Water-quality samples from 45 wells indicate that ground water in the South Fork Merced River valley at Wawona is segregated vertically. Shallow wells produce a dilute calcium sodium bicarbonate water that results from chemical dissolution of minerals as water flows through fractured granitic rock from hillside recharge areas toward the valley floor. Tritium concentrations indicate that ground water in the shallow wells originated as precipitation after the 1960's when testing of atmospheric nuclear devices stopped. Ground water from the deep flowing wells in the valley floor is older sodium calcium chloride water. This older water probably originated either as precipitation during a climatically cooler period or as precipitation from altitudes between 1,400 and 3,700 feet higher than precipitation that recharged the local shallow ground-water-flow system. Chloride and associated cations in the deepground-water-flow system may result from upward leakage of saline ground water or from leaching of saline fluid inclusions in the granitic rocks. Water-level and pressure-gage measurements for 38 wells in the South Fork Merced River valley also indicate that the ground water in the valley is segregated vertically. Hydraulic head in deep fractures is as much as 160 feet above the valley floor. Vertical hydraulic gradients between the shallow and deep systems are as high as 4.5 feet per foot in one of two test holes drilled for this study. Measurements of in situ stress in the two test holes indicate that the vertical segregation of ground water may be related to pressures in the earth that squeeze horizontal fractures closed at depth. Fractures within a few hundred feet of land surface are poorly connected to fractures deeper beneath the valley. About 100 privately owned wells currently are in use at Wawona; but, the ground-water-flow system may not be an adequate source of good quality ground water for relocated park facilities. Yields from existing wells are low (median 4-5 gallons per minute) and traditional methods for locating high-yielding wells in fractured rocks have not been successful in this area. Concentrations of dissolved 222 radon (median 4,500 picoCuries per liter) are high, and the development of deep ground water could cause deeper saline water to migrate upward into producing wells. The South Fork Merced River, the primary source of water supply for Wawona, does not meet current demands during late summer and autumn. Data collected between 1958 and 1968 indicate that 25 percent of the time discharge of the South Fork River at Wawona during the dry season (August through October) was less than 2 cubic feet per second-the discharge rate at which the National Park Service is restricted from withdrawing water from the river. the river, however, could be relied on for additional water supply if facilities were constructed to divert and store water during periods of high flow for use later in the year.

California↗

USGS2006

State summaries: Idaho

According to the United States Geological Survey (USGS), Idaho's preliminary nonfuel mineral production value jumped to $893 million in 2005. Principal minerals by value included molybdenum concentrates, phosphate rock, sand and gravel, silver and portland cement. The state ranked second in phosphate and garnet production, third in silver and pumice, fourth in molybdenum concentrate production, and 21st overall. Majority of mining increases for the year were spurred by demand for metals by China's growing economy.

Mining Engineering↗

USGS1984

EVALUATION OF LOW-SUN ILLUMINATED LANDSAT-4 THEMATIC MAPPER DATA FOR MAPPING HYDROTHERMALLY ALTERED ROCKS IN SOUTHERN NEVADA.

Landsat-4 Thematic Mapper (TM) data of southern Nevada collected under conditions of low-angle solar illumination were digitally processed to identify hydroxyl-bearing minerals commonly associated with hydrothermal alteration in volcanic terrains. Digital masking procedures were used to exclude shadow areas and vegetation and thus to produce a CRC image suitable for testing the new TM bands as a means to map hydrothermally altered rocks. Field examination of a masked CRC image revealed that several different types of altered rocks displayed hues associated with spectral characteristics common to hydroxyl-bearing minerals. Several types of unaltered rocks also displayed similar hues.

Conference Paper↗

USGS2014

Sulfur and oxygen isotopic study of Paleozoic sediment-hosted Zn-Pb(-Ag-Au-Ba-F) deposits and associated hydrothermal alteration zones in the Nome Complex, Seward Peninsula, Alaska

Results of sulfur and oxygen isotope studies of sedimentary exhalative (SEDEX) Zn-Pb(-Ag-Au-Ba-F) deposits hosted in metamorphosed Paleozoic clastic and carbonate rocks of the Nome Complex, Seward Peninsula, Alaska, are consistent with data for similar deposits worldwide. Stable isotopic studies of the Nome Complex are challenging because the rocks have undergone Mesozoic blueschist- and greenschist-facies metamorphism and deformation at temperatures estimated from 390–490 °C. Studies of sulfur and oxygen isotopes in other areas suggest that, in the absence of chemical and mineralogical evidence for metasomatism, the principal effect of metamorphism is re-equilibration between individual minerals at the temperature of metamorphism, which commonly leads to a narrowing of the overall range of isotope values for a suite of rocks, but generally does not significantly modify the average whole rock value for that suite. Sulfur isotope studies of the stratabound and locally stratiform sulfide lenses at the Aurora Creek-Christophosen deposit, which is of possible Late Devonian-early Carboniferous age, show a large range of δ34Ssulfide values from -9.7 to 39.4‰, suggesting multiple sulfur sources and possibly complex processes of sulfide formation that may include bacterial sulfate reduction, thermochemical sulfate reduction, and Rayleigh distillation. Low δ34S values probably represent bacterial sulfide minerals remobilized from the host metasedimentary rocks either during the original seafloor mineralization or are related to a Cretaceous mineralizing event that produced Au-vein and base-metal replacement deposits; the latter process is supported by Pb isotope data. The Wheeler North deposit is similar to Aurora Creek-Christophosen but does not have negative δ34S values. It also probably formed in an euxinic sub-basin. The stratabound Nelson deposit, and the deformed veins at the Galena and Quarry deposits, may be older than the Aurora Creek-Christophosen and Wheeler North deposits. The Nelson deposit has a lower and narrower range of δ34S values (1.9 to 10.4‰), averaging about 8‰. The Galena and Quarry veins display δ34S values that are similar to those of the stratabound Nelson deposit. Barite samples from the Aurora Creek-Christophosen, Wheeler North, and Quarry deposits have 34S-enriched δ34S values between 25 and 30‰ that are consistent with derivation of the sulfur from coeval (Paleozoic) seawater sulfate. Given their δ34S values, it is likely that the Aurora Creek-Christophosen and Wheeler North deposits formed in closed sub-basins with euxinic conditions that led to extreme Rayleigh distillation to produce the very large range and very high δ34S values. The Nelson deposit probably formed within an anoxic but not euxinic sub-basin. At Nelson, sulfide was likely derived by a subsurface thermochemical sulfate reduction (TSR) reaction, similar to reactions that are inferred to have produced the sulfides in the Galena and Quarry deposits, which are interpreted as feeder veins for the stratabound deposits. Calculations of oxygen isotope temperatures are based on the assumption that evolved seawater with δ18O of 3‰ was the mineralizing and altering fluid related to the formation of the sulfide deposits. Temperatures of aluminous alteration and sulfide mineralization were between 109 and 209 °C, determined on the basis of oxygen isotope fractionations between the mineralizing fluid and proportionate amounts of quartz and muscovite in the rocks. These temperature estimates agree well with known temperatures of SEDEX mineralization worldwide. Sulfur isotope values also are generally consistent with the known ranges in SEDEX deposits worldwide (δ34S ≈ -5 to 25‰).

GSA Special Papers↗