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Habitat suitability index model improvements

Habitat suitability index (HSI) models were developed for the 2023 Coastal Master Plan to evaluate the potential effects of coastal restoration and protection projects on habitat for key coastal fish, shellfish, and wildlife species. These species included: eastern oyster, brown shrimp, white shrimp, blue crab, crayfish, gulf menhaden, spotted seatrout, largemouth bass, American alligator, gadwall, mottled duck, brown pelican, seaside sparrow, and bald eagle. Most of these species were included in the 2017 Coastal Master Plan analyses, and the HSI models from that effort were refined and improved following the recommendations described in the technical memorandum: 2023 Coastal Master Plan Habitat Suitability Index Model Improvement Recommendations (Sable et al., 2019). In addition to model improvements, HSI models were created for seaside sparrow and bald eagle, both of which are new species for the master plan analyses. For the HSI models that are primarily literature-based, literature reviews were conducted for recent studies that could be used to improve the suitability index (SI) relationships that compose the models. As a result of this review, modifications were made to the salinity-related SIs of the oyster model including: expanding the time period used for salinity effects to spawning; adjusting the range of suitable annual average salinity to be more representative of Louisiana populations; and making oyster’s minimum salinity tolerance temperature dependent. In addition, a new SI was incorporated in the oyster HSI model that accounts for the effects of sediment deposition on oysters. The crayfish HSI model was improved by adjusting the time periods used for the SIs that describe the hydrology required for the crayfish life cycle, and the soil characteristics SI that was part of the 2017 crayfish model was removed because soil conditions do not appear to be limiting for crayfish burrow construction in coastal Louisiana. The other literature-based HSI models from the 2017 Coastal Master Plan, i.e., American alligator, gadwall, mottled duck, and brown pelican, were unchanged, with the exception of a small adjustment made to the suitability of forested wetlands for gadwall. Lastly, a literature-based HSI model was created for seaside sparrow that consists of SIs related to vegetated habitat type, marsh vegetation coverage, and marsh elevation. Statistical-based HSI models were developed for brown shrimp (both small and large juvenile stages), white shrimp (small and large juvenile stages), blue crab (juvenile stage), gulf menhaden (juvenile and adult stages), spotted seatrout (juvenile and adult stages), largemouth bass, and bald eagle. The bald eagle HSI model was developed from a bald eagle nest probability of occurrence model that related nest occurrence from survey data with land cover type. The resulting model showed that combinations of forested wetlands, flotant marsh, and open water habitats were most suitable for nesting bald eagles. The 2023 fish, shrimp, and blue crab HSI models were developed using new approaches for the formulation of the water quality and structural habitat SIs that compose the models. For the 2017 models, the water quality SI was derived using only generalized linear mixed models (GLMMs) to estimate the relationship between salinity, water temperature, and species’ catch. For the 2023 models, however, multiple GLMMs and generalized additive models (GAMMs) were created for each species or life stage. These alternative models were compared and a single model that performed well statistically and was ecologically reasonable was selected for the species’ water quality SI. The structural habitat SI was developed using a meta-analysis of published literature to estimate the relative importance of various estuarine habitats to the fish and shellfish species. The results of this analysis were then used to modify the 2017 structural habitat SI relationship to account for the added habitat value of submerged aquatic vegetation and oyster reefs, which are also important habitats for juvenile fish and shellfish. Similar to the 2017 fish, shrimp, and blue crab models, the water quality and structural habitat SIs were then combined to create the 2023 HSI models. The 2023 Coastal Master Plan HSI models were integrated with the Integrated Compartment Model (and are referred to as ICM-HSIs) and tested using environmental output from the 2017 Coastal Master Plan Future Without Action scenario. The tests showed that, in general, the models produced reasonable representations of species’ habitat distribution. Furthermore, the improvements made to the oyster, crayfish, fish, shrimp, and blue crab HSI models generally yielded more realistic results compared to the 2017 HSI models.

Report↗

Pesticides in groundwater in the Anacostia River and Rock Creek watersheds in Washington, D.C., 2005 and 2008

The U.S. Geological Survey (USGS), in cooperation with the District Department of the Environment, conducted a groundwater-quality investigation to (a) determine the presence, concentrations, and distribution of selected pesticides in groundwater, and (b) assess the presence of pesticides in groundwater in relation to selected landscape, hydrogeologic, and groundwater-quality characteristics in the shallow groundwater underlying the Anacostia River and Rock Creek watersheds in Washington, D.C. With one exception, well depths were 100 feet or less below land surface. The USGS obtained or compiled ancillary data and information on land use (2001), subsurface sediments, and groundwater samples from 17 wells in the lower Anacostia River watershed from September through December 2005, and from 14 wells in the lower Anacostia River and lower Rock Creek watersheds from August through September 2008. Twenty-seven pesticide compounds, reflecting at least 19 different types of pesticides, were detected in the groundwater samples obtained in 2005 and 2008. No fungicides were detected. In relation to the pesticides detected, degradate compounds were as or more likely to be detected than applied (parent) compounds. The detected pesticides chiefly reflected herbicides commonly used in urban settings for non-specific weed control or insecticides used for nonspecific haustellate insects (insects with specialized mouthparts for sucking liquid) or termite-specific control. Detected pesticides included a combination of pesticides currently (2008) in use, banned or under highly restricted use, and some that had replaced the banned or restricted-use pesticides. The presence of banned and restricted-use pesticides illustrates their continued persistence and resistance to complete degradation in the environment. The presence of the replacement pesticides indicates the susceptibility of the surficial aquifer to contamination irrespective of the changes in the pesticides used. A preliminary review of the data collected in 2005 and 2008 indicated that differences in the surficial geology, land use (as a surrogate for pesticide use), and above-average precipitation for most of 2004 through 2008, as well as differences in the number and performance of USGS laboratory methods used, could have led to more pesticides detected in groundwater samples collected in 2008 than in groundwater samples collected in 2005. Thus, although data from both years of collection were used for interpretive analysis, emphasis was placed on the analysis of the data obtained in 2008. The presence of pesticides in shallow groundwater (less than approximately 100 ft (feet), or 30 m (meters), below land surface) indicated at least the upper surficial aquifer in Washington, D.C. was susceptible to contamination. One or more herbicides or insecticides were detected in groundwater samples collected from 50 percent of the shallow wells sampled in 2005, and from 62 percent of the shallow wells sampled in 2008. Differences among types of pesticides in shallow groundwater were apparent. The most frequently detected class of herbicides was the s-triazine compounds—atrazine, simazine, or prometon, or the atrazine-degradate compounds—2-chloro-4-ethylamino-6-amino-s-triazine (desethylatrazine or CIAT) and 2-chloro-4-isopropylamino-6-amino-s-triazine (hydroxyatrazine or OIET). The next most frequently detected classes of herbicides were the chloroacetanilides, including metolachlor and acetochlor, and the ureic herbicides, including diuron (and degradate, 3,4-dichloroaniline), fluometuron, metsulfuron methyl, sulfameturon, bromacil, and tebuthiuron. Insecticides also were detected, but less frequently than herbicides, with one or more insecticides present in groundwater samples from 38 percent of shallow wells sampled in 2008. Detected insecticides included parent or degradate compounds commonly used for either nonspecific or haustellate (sucking) insects, including chlorpyrifos and dichlorodiphenyldichloroethane (p,p’-DDD; a degradate of dichlorodiphenyltrichloroethane, DDT), and for termite control, including dieldrin, chlordane, heptachlor epoxide, (a degradate of heptachlor), fipronil, and the sulfone and sulfide degradates of fipronil. The concentrations of individual pesticides in shallow groundwater in both years were low. Maximum concentrations were no greater than a few tenths of a microgram per liter (μg/L); typical concentrations often were less than 0.1 μg/L. Multiple pesticides, however, commonly were present in groundwater. For example, in 2008, approximately 88 percent (7 of 8) of the wells that yielded a sample with at least one detectable pesticide contained five or more pesticides. The highest number of detections occurred in a groundwater sample from well WE Ca 32, which is located in a highly developed urban area; this sample contained 15 different pesticide residues. In relation to human and aquatic health, no pesticide concentration in either 2005 or 2008 exceeded Federal drinking-water standards. Groundwater samples from a few sites, however, contained levels of chiefly banned or restricted-use pesticides that exceeded other human-health and (or) aquatic-health guidelines. For example, concentrations of dieldrin in 2008 groundwater samples from three wells—WE Ca 32 (0.028 μg/L), WE Ba 11 (0.016 μg/L), and WW Ac 8 (0.014 μg/L)—fell within the range of concern for 2004 Federally approved non-regulatory USGS Health-Based Assessment benchmarks (0.002 to 0.2 μg/L), and exceeded earlier (1999) Federal criteria for drinking water (0.000052 μg/L). Other individual compounds whose concentrations exceeded 1999 Federal guidelines for samples from one or more of these three sites, or another site, included p,p’-DDD, dichlorodiphenyldichloroethylene (p,p’-DDE; another degradate of DDT), chlordane, and heptachlor epoxide. Pesticide concentrations in groundwater also were compared to three aquatic-health guidelines for freshwater (United States, Great Lakes, or Canada). One or more of these guidelines were exceeded in groundwater samples obtained in 2005 or 2008 for one or more of the compounds chlordane, dieldrin, heptachlor epoxide, p,p’-DDE, p,p’-DDD, and chlorpyrifos. The spatial distribution of pesticides in the shallow groundwater appeared to be related, in part, to land use, a surrogate for pesticide use. Although most of the wells sampled in this study are in parklands or other relatively open and accessible space, multiple pesticides most often were detected in 2008 groundwater samples collected from wells where a considerable percentage (in excess of 60 percent) of the land within a 500-m radius is developed space (residential, commercial, or other urban infrastructure). Insecticides were detected in wells surrounded by at least 50 percent, and most commonly by more than 80 percent, development. Well WE Ca 32, the site associated with the highest number of pesticide residues in groundwater (8 herbicides and 7 insecticides), is in a small residential park, where 99 percent of the surrounding land is well-maintained residential and commercial development. The vertical distribution of detected pesticides in shallow groundwater appeared to be related, in part, to depth below land surface, surficial-bedrock type, and differences in the chemistry of shallow groundwater. Pesticides were detected at relatively shallow depths in wells that may not have fully penetrated the shallow aquifer. For wells in which at least one pesticide was detected, the median depth below land surface to the top of the well screen was 5.8 m, and the maximum depth was 8.5 m. Among the types of surficial materials in which wells were completed—alluvium, terrace deposits, or Potomac Formation sub- or outcrops in the Coastal Plain Province, and saprolite or fractured bedrock (Laurel and Sykesville Formations) underlying saprolite in the Piedmont Province—no pesticides were detected in groundwater associated with wells completed in the alluvium or fractured bedrock. Detections occurred in some but not all wells completed in the other surficial materials. Overall, the pattern in occurrence appeared related to the local permeability of these sediments and groundwater chemistry. Groundwater with multiple pesticide detections tended to occur in permeable sediments (absent any appreciable overlying clay, silt, or clay-silt layers), in conjunction with other common urban contaminants (elevated chloride in excess of tens to hundreds of milligrams per liter (mg/L), and oxic, rather than reduced, groundwater as evidenced by elevated (in excess of 5 mg/L) concentrations of nitrate). The results of this investigation were compared to results from two other similar and recent studies on pesticide occurrence in the shallow aquifer. These included a study in the nearby Maryland and Delaware Coastal Plain Physiographic Province and one in the Maryland and Virginia Piedmont Physiographic Province. Results from these studies were similar to the current study in relation to (a) the types, frequencies, concentrations, and mixtures of pesticides detected; (b) compounds that exceeded human-and aquatic-health criteria; and (c) the occurrence and distribution of pesticides within the surficial aquifer in relation to depths, sediment types, and groundwater chemistries.

Washington D.C.↗

Evidence of mineral alteration in a salt marsh subterranean estuary: Implications for carbon and trace element cycling

Subterranean estuaries (STE) in salt marshes are biogeochemically active zones where interactions between terrestrial groundwater and seawater drive complex cycling of carbon and trace elements, influenced by mineral dissolution. These systems, characterized by fine-grained organic-rich peat overlying permeable coastal aquifers, play a crucial role as a blue carbon sink, yet their geochemical dynamics remain poorly understood. We investigated dissolved trace elements, carbon, silica, and radium isotopes in a salt marsh STE (Sage Lot Pond, Waquoit Bay, MA) over seasonal and annual cycles. Our results reveal that groundwater and estuarine water circulation through marsh peat and aquifer sediments leads to enrichments of dissolved organic and inorganic carbon (DOC and DIC), Si, Ba, and Mn, with variable source/sink behavior of Fe and net removal of U. Submarine groundwater discharge dominated Ba fluxes, whereas pore water drainage from marsh peat acted as the main sink for U and source of Si. Fe cycling was variable, with terrestrial Fe largely removed as groundwater passed through the STE, consistent with Fe-sulfide and amorphous phase formation. Radium isotope ratios identified two distinct subsurface flow pathways, influenced by metal-oxide cycling and organic matter breakdown. Si production was decoupled from DIC, suggesting Si originates from mineral alteration, whereas DIC results from both mineral weathering and microbial respiration. Silicate mineral alteration, coupled with marsh pore water drainage, accounts for up to 16% of annual DIC exports (66 g C m −2 y −1 ), highlighting the importance of STEs in coastal carbon and trace element cycling, especially as marshes face environmental change.

Massachusetts↗

Regional crustal structure and tectonics of the Pacific Coastal States: California, Oregon, and Washington

The Pacific Coastal States form a complex geologic environment in which the crust and lithosphere have been continuously reworked. We divide the region tectonically into the southern transform regime of the San Andreas fault and the northern subduction regime, and summarize the geophysical framework with contour maps of crustal thickness, lithospheric and seismicity cross sections, and results from site-specific geophysical studies. The uniformity of crustal thickness (30 ± 2 km) in southern California is remarkable, and appears to be primarily the result of crustal extension in the Mojave Desert and ductile shear of the lower crust along the plate transform boundary. Southern California seismicity defines a broad zone of deformation that extends from the Borderland to the Mojave Desert (about 300 km). The geophysical framework of central and northern California records magmatism and accretion associated with the Mesozoic and Cenozoic subduction, late Cenozoic transform faulting, and in the Basin and Range to the east, extension. The crust thickens from about 20 km at the coast to as much as 55 km in the Sierra Nevada, and thins to about 30 km in the Basin and Range. Cross sections of the crust show that seismic velocities and densities vary significantly over short distances perpendicular to the coast, reflecting processes that include the accretion of oceanic sediments and igneous crust, and significant lateral motion of crustal blocks. Maximum hypocentral depths in central California become deeper as the crust thickens to the west, but seismicity is low beneath the Great Valley and Sierra Nevada, which together appear to form a relatively undeforming block. The lower crust of the Pacific Coastal States has a high average seismic velocity (6.7 km/sec or greater), which probably is the product of tectonic underplating of oceanic crust and/or magmatic underplating by a basaltic melt.

California, Oregon, Washington↗

Modeling future scenarios of light attenuation and potential seagrass success in a eutrophic estuary

Estuarine eutrophication has led to numerous ecological changes, including loss of seagrass beds. One potential cause of these losses is a reduction in light availability due to increased attenuation by phytoplankton. Future sea level rise will also tend to reduce light penetration and modify seagrass habitat. In the present study, we integrate a spectral irradiance model into a biogeochemical model coupled to the Regional Ocean Model System (ROMS). It is linked to a bio-optical seagrass model to assess potential seagrass habitat in a eutrophic estuary under future nitrate loading and sea-level rise scenarios. The model was applied to West Falmouth Harbor, a shallow estuary located on Cape Cod (Massachusetts) where nitrate from groundwater has led to eutrophication and seagrass loss in landward portions of the estuary. Measurements of chlorophyll, turbidity, light attenuation, and seagrass coverage were used to assess the model accuracy. Mean chlorophyll based on uncalibrated in-situ fluorometry varied from 28 μg L −1 at the landward-most site to 6.5 μg L −1 at the seaward site, while light attenuation ranged from 0.86 to 0.45 m -1 . The model reproduced the spatial variability in chlorophyll and light attenuation with RMS errors of 3.72 μg L −1 and 0.07 m -1 respectively. Scenarios of future nitrate reduction and sea-level rise suggest an improvement in light climate in the landward basin with a 75% reduction in nitrate loading. This coupled model may be useful to assess habitat availability changes due to eutrophication and sediment resuspension and fully considers spatial variability on the tidal timescale.

Massachusetts↗

Stress in mangrove forests: early detection and preemptive rehabilitation are essential for future successful worldwide mangrove forest management

Mangrove forest rehabilitation should begin much sooner than at the point of catastrophic loss. We describe the need for “mangrove forest heart attack prevention”, and how that might be accomplished in a general sense by embedding plot and remote sensing monitoring within coastal management plans. The major cause of mangrove stress at many sites globally is often linked to reduced tidal flows and exchanges. Blocked water flows can reduce flushing not only from the seaward side, but also result in higher salinity and reduced sediments when flows are blocked landward. Long-term degradation of function leads to acute mortality prompted by acute events, but created by a systematic propensity for long-term neglect of mangroves. Often, mangroves are lost within a few years; however, vulnerability is re-set decades earlier when seemingly innocuous hydrological modifications are made (e.g., road construction, blocked tidal channels), but which remain undetected without reasonable large-scale monitoring.

Marine Pollution Bulletin↗

Fish growth rates and lake sulphate explain variation in mercury levels in ninespine stickleback (Pungitius pungitius) on the Arctic Coastal Plain of Alaska

Mercury concentrations in freshwater food webs are governed by complex biogeochemical and ecological interactions that spatially vary and are often mediated by climate. The Arctic Coastal Plain of Alaska (ACP) is a heterogeneous, lake-rich landscape where variability in mercury accumulation is poorly understood. Earlier research indicated that the level of catchment influence on lakes varied spatially on the ACP, and affected mercury accumulation in lake sediments. This work sought to determine drivers of spatial variation in mercury accumulation in lake food webs on the ACP. Three lakes that were a priori identified as “high catchment influence” (Reindeer Camp region) and three lakes that were a priori identified as “low catchment influence” (Atqasuk region) were sampled, and variability in water chemistry, food web ecology, and mercury accumulation was investigated. Among-lake differences in ninespine stickleback ( Pungitius pungitius ) length-adjusted methylmercury concentrations were significantly explained by sulphate concentration in lake water, a tracer of catchment runoff input. This effect was mediated by fish growth, which had no pattern between regions. Together, lake water sulphate concentration and fish age-at-size (proxy for growth) accounted for nearly all of the among-lake variability in length-adjusted methylmercury concentrations in stickleback (R 2 adj = 0.94, p < 0.01). The percentage of total mercury as methylmercury (a proxy for net Hg methylation) was higher in sediments of more autochthonous, “low catchment influence” lakes ( p < 0.05), and in the periphyton of more allochthonous, “high catchment influence” lakes (p < 0.05). The results indicate that dominant sources of primary production (littoral macrophyte/biofilm vs. pelagic phytoplankton) and food web structure (detrital vs. grazing) are regulated by catchment characteristics on the ACP, and that this ultimately influences the amount of methylmercury in the aquatic food web. These results have important implications for predicting future mercury concentrations in fish in lakes where fish growth rates and catchment inputs may change in response to a changing climate.

Alaska↗

Late Quaternary pollen record from southwest Seward Peninsula, western Alaska, and the vegetation history of central Beringia

Pollen analysis of samples from a coastal exposure near Teller, southwestern Seward Peninsula, Alaska, provides a record of vegetation and climate spanning the Last Glacial Maximum (LGM) through the Holocene. The site is near the center of the former Bering Land Bridge (BLB). The oldest pollen-bearing sediment unit is a loess deposit of LGM age, with pollen assemblages that closely resemble LGM assemblages from other key sites in central Beringia spanning 16° of latitude. These fossil assemblages represent vegetation composed primarily of grasses, sedges, Artemisia , willows, and forbs and are interpreted to represent steppe–tundra, associated with dry climates and summer temperatures cooler than at present. LGM mosses did not accumulate insulating layers of peat; the summer active soil layer was deeper than at present. Permafrost with ice wedges and loess deposition were widespread. A regional transition from steppe–tundra vegetation to a dwarf shrub–sedge–moss mesic-to-wetland vegetation began in central Beringia with the onset of Bølling–Allerød (B-A) warming at 14,700 cal yr BP. Warming events of the B-A and early Holocene resulted in widespread development of thermokarst terrain on the BLB and on ice-rich terrain in Western Alaska. Mesic climates and vegetation developed on the BLB during the marine transgression and because of B-A and early Holocene warming. Early Holocene warming allowed some boreal forest species such as alders to begin colonizing Western Alaska from the interior.

Alaska↗

Remote sensing of suspended sediment discharge into the western Gulf of Maine during the April 1987 100-year flood

The suspended sediment discharge during this event was identified using NOAA-9 and NOAA-10 Advanced Very High Resolution Radiometer (AVHRR) data from March 29 to April 14. The sediment plumes showed a westward movement upon reaching the Gulf of Maine. 105 metric tons of fine-grained sediments were carried onto the continental shelf in the largest plume, that from the Kennebec-Androscoggin river system. -from Authors

Journal of Coastal Research↗

Detrital zircon U-Pb reconnaissance of the Franciscan subduction complex in northwestern California

In northwestern California, the Franciscan subduction complex has been subdivided into seven major tectonostratigraphic units. We report U-Pb ages of &asymp;2400 detrital zircon grains from 26 sandstone samples from 5 of these units. Here, we tabulate each unit's interpreted predominant sediment source areas and depositional age range, ordered from the oldest to the youngest unit. (1) Yolla Bolly terrane: nearby Sierra Nevada batholith (SNB); ca. 118 to 98 Ma. Rare fossils had indicated that this unit was mostly 151-137 Ma, but it is mostly much younger. (2) Central Belt: SND; ca. 103 too 53 Ma (but poorly constrained), again mostly younger than previously thought. (3) Yager terrane: distant Idaho batholith (IB); ca. 52 to 50 Ma. Much of the Yager's detritus was shed during major core complex extension and erosion in Idaho that started 53 Ma. An eocene Princeton River-Princeton submarine canyon system transported this detritus to the Great Valley forearc basin and thence to the Franciscan trench. (4) Coastal terrane: mostly IB, &plusmn;SNB, &plusmn;nearby Cascade arc, &plusmn;Nevada Cenozoic ignimbrite belt; 52 to <32 Ma. (5) King Range terrane: dominated by IB and SNB zircons; parts 16-14 Ma based on microfossils. Overall, some Franciscan units are younger than previously thought, making them more compatible with models for the growth of subduction complexes by positive accretion. From ca. 118 to 70 Ma, Franciscan sediments were sourced mainly from the nearby Sierra Nevada region and were isolated from southwestern US and Mexican sources. From 53 to 49 Ma, the Franciscan was sourced from both Idaho and the Sierra Nevada. By 37-32 Ma, input from Idaho had ceased. The influx from Idaho probably reflects major tectonism in Idaho, Oregon, and Washington, plus development of a through-going Princeton River to California, rather than radical changes in the subduction system at the Franciscan trench itself.

California↗

Climatic-eustatic control of Holocene nearshore parasequence development, southeastern Texas coast

Sediment cores, seismic profiles, radiocarbon dates, and faunal assemblages were used to interpret the depositional setting and geological evolution of the southeastern Texas coast during the last glacio-eustatic cycle. Discrete lithofacies and biofacies zones in the ebb-dominated Sabine Lake estuary and adjacent chenier plain record alternating periods of rapid marine flooding and gradual shoaling related to linked climatic/eustatic fluctuations. Monospecific zones of the mollusks Rangia cuneata and Crassostrea virginica, respectively, indicate high fresh water outflow followed by invasion of marine water, whereas intervening organic-rich zones record bayhead delta deposition. High-frequency parasequence stacking patterns within the valley fill and across the adjacent interfluve reflect an initial rapid rise in sea level about 9 ka that flooded abandoned alluvial terraces and caused onlap of Holocene marsh in the incised valley. The rapid rise was followed by slowly rising and oscillating sea level that filled the deepest portions of the incised valleys with fluvially dominated estuarine deposits, and then a maximum highstand (+1 m msl) about 5 ka that flooded the former subaerial coastal plain between the incised valleys and constructed the highest beach ridges. Between 3.5 and 1.5 ka, sea level oscillated and gradually fell, causing a forced regression and rapid progradation of both the chenier plain and accretionary barrier islands. The only significant sands in the valley fill are (1) falling-stage and lowstand-fluvial sediments between the basal sequence boundary and transgressive surface unconformity, and (2) highstand beach-ridge sediments of the chenier plain.

Texas↗

Organic-carbon sequestration in soil/sediment of the Mississippi River deltaic plain — Data; landscape distribution, storage, and inventory; accumulation rates; and recent loss, including a post-Katrina preliminary analysis

Soil/sediment of the Mississippi River deltaic plain (MRDP) in southeastern Louisiana is rich in organic carbon (OC). The MRDP contains about 2 percent of all OC in the surface meter of soil/sediment in the Mississippi River Basin (MRB). Environments within the MRDP differ in soil/sediment organic carbon (SOC) accumulation rate, storage, and inventory. The focus of this study was twofold: (1) develop a database for OC and bulk density for MRDP soil/sediment; and (2) estimate SOC storage, inventory, and accumulation rates for the dominant environments (brackish, intermediate, and fresh marsh; natural levee; distributary; backswamp; and swamp) in the MRDP. Comparative studies were conducted to determine which field and laboratory methods result in the most accurate and reproducible bulk-density values for each marsh environment. Sampling methods included push-core, vibracore, peat borer, and Hargis1 sampler. Bulk-density data for cores taken by the "short push-core method" proved to be more internally consistent than data for samples collected by other methods. Laboratory methods to estimate OC concentration and inorganic-constituent concentration included mass spectrometry, coulometry, and loss-on-ignition. For the sampled MRDP environments, these methods were comparable. SOC storage was calculated for each core with adequate OC and bulk-density data. SOC inventory was calculated using core-specific data from this study and available published and unpublished pedon data linked to SSURGO2 map units. Sample age was estimated using isotopic cesium ( 37 Cs), lead ( 210 Pb), and carbon ( 14 C), elemental Pb, palynomorphs, other stratigraphic markers, and written history. SOC accumulation rates were estimated for each core with adequate age data. Cesium-137 profiles for marsh soil/sediment are the least ambiguous. Levee and distributary 137 Cs profiles show the effects of intermittent allochthonous input and/or sediment resuspension. Cesium-137 and 210 Pb data gave the most consistent and interpretable information for age estimations of soil/sediment deposited during the 1900s. For several cores, isotopic 14 C and 137 Cs data allowed the 1963-64 nuclear weapons testing (NWT) peak-activity datum to be placed within a few-centimeter depth interval. In some cores, a too old 14 C age (when compared to 137 Cs and microstratigraphic-marker data) is the probable result of old carbon bound to clay minerals incorporated into the organic soil/sediment. Elemental Pb coupled with Pb source-function data allowed age estimation for soil/sediment that accumulated during the late 1920s through the 1980s. Exotic pollen (for example, Vigna unguiculata and Alternanthera philoxeroides ) and other microstratigraphic indicators (for example, carbon spherules) allowed age estimations for marsh soil/sediment deposited during the settlement of New Orleans (1717-20) through the early 1900s. For this study, MRDP distributary and swamp environments were each represented by only one core, backswamp environment by two cores, all other environments by three or more cores. MRDP core data for the surface meter soil/sediment indicate that (1) coastal marshes, abandoned distributaries, and swamps have regional SOC-storage values >16 kg m -2 ; (2) swamps and abandoned distributaries have the highest SOC storage values (swamp, 44.8 kg m -2 ; abandoned distributary, 50.9 kg m -2 ); (3) fresh-to-brackish marsh environments have the second highest site-specific SOC-storage values; and (4) site-specific marsh SOC storage values decrease as the salinity of the environment increases (fresh-marsh, 36.2 kg m -2 ; intermediate marsh, 26.2 kg m -2 ; brackish marsh, 21.5 kg m -2 ). This inverse relation between salinity and SOC storage is opposite the regional systematic increase in SOC storage with increasing salinity that is evident when SOC storage is mapped by linking pedon data to SSURGO map units (fresh marsh, 47 kg m -2 ; intermediate marsh, 67 kg m -2 ; brackish marsh, 75 kg m -2 ; and salt marsh, 80 kg m -2 ). MRDP core data for this study also indicate that levees and backswamp have regional SOC-storage values <16 kg m -2 . Group-mean SOC storage for cores from these environments are natural levee (17.0 kg m -2 ) and backswamp (14.1 kg m -2 ). An estimate for the SOC inventory in the surface meter of soil/sediment in the MRDP can be made using the SSURGO mapped portion of the coastal-marsh vegetative-type map (13,236 km 2 , land-only area) published by the Louisiana Department of Wildlife and Fisheries and U.S. Geological Survey (1997). This area has a SOC inventory (surface meter) of 677 Tg (slightly more than 2 percent of the 30,289 Tg SOC inventory for the MRB). The MRDP (6,180 km2, land-only area) has an estimated SOC inventory of 397 Tg. Most of the MRDP is located within the SSURGO mapped coastal marshlands. The entire MRDP, including water, has an area of about 10,800 km 2 . Using the ratio of total MRDP area to SSURGO mapped MRDP area as an adjustment, the MRDP SOC inventory is estimated at 694 Tg. This larger estimate of 694 Tg for the SOC inventory is probably more realistic, because it is reasonable to assume that the marsh sediments overlain by shallow water have comparable SOC storage to that of the adjacent land areas. MRDP core data for this study indicate that there is some variability in long-term SOC mass-accumulation rates for centuries and millennia and that this variability may indicate important geologic changes or changes in land use. However, the consistency of the range in rates of SOC accumulation through time suggests a remarkable degree of marsh sustainability throughout the Holocene, including the recent period of significant marsh modification/channelization for human use. One example of marsh sustainability is its present ability to function as a SOC sink even with Louisiana's large-scale coastal land loss during the last several decades. With coastal-marsh restoration efforts, this sink potential will increase. Looking to the future, a total of 1,101 g m -2 yr -1 SOC is projected to be lost from all of coastal Louisiana (U.S. Army Corps of Engineers, Louisiana Coastal Area (LCA) subprovinces 1-4; not just the MRDP) through coastal erosion from year 2000 to 2050. This translates to a projected SOC-loss rate of about 0.20 percent per year. The recent Hurricanes Katrina and Rita, which devastated the Louisiana coast during late August and late September 2005, transformed about 259 km 2 (100 mi 2 ) of marsh to open water (U.S. Geological Survey, 2005). To the extent that some or all of this land loss is permanent, this result equates to a SOC loss of about 15 Tg. This estimate is based on the year-2000 15,153-km 2 land area for the LCA study area that includes LCA subprovince 4. Using the year-2000 land area, the LCA study area had an estimated SOC inventory of 858 Tg. The estimated 15 Tg SOC loss attributable to Hurricanes Katrina and Rita is 1.7 percent of the year-2000 LCA inventory and 2.3 percent of the year-2000 MRDP inventory. If this SOC loss is included in the projection for the year 2050, then the MRDP would either remain a source with a net SOC loss of 3 Tg or become a weak sink with a net SOC gain of 4 Tg. These estimates are lower bounds for potential SOC flux because they are only for the surface meter of landmass.

Louisiana↗

Advances and limitations of individual-based models to analyze and predict dynamics of mangrove forests: A review

Mangrove ecosystems are considered vulnerable to climate change as coastal development limits the ecosystem services and adaptations important to their survival. Although they appear rather simple in terms of species diversity, their ecology is complex due to interacting geophysical forces of tides, surface runoff, river and groundwater discharge, waves, and constituents of sediment, nutrients and saltwater. These interactions limit developing a comprehensive framework for science-based sustainable management practices. A suite of models have been developed independently by various academic and government institutions worldwide to understand the dynamics of mangrove ecosystems and to provide ecological forecasting capabilities under different management scenarios and natural disturbance regimes. The models have progressed from statistical tables representing growth and yield to more sophisticated models describing various system components and processes. Among these models are three individual-based models (IBMs) (FORMAN, KIWI, and MANGRO). A comparison of models’ designs reveal differences in the details of process description, particularly, regarding neighbor competition among trees. Each model has thus its specific range of applications. Whereas FORMAN and KIWI are most suitable to address mangrove forest dynamics of stands, MANGRO focuses on landscape dynamics on larger spatial scale. A comparison of the models and a comparison of the models with empirical knowledge further reveal the general needs for further field and validation studies to advance our ecological understanding and management of mangrove wetlands.

Aquatic Botany↗

Paleoenvironmental analyses of an organic deposit from an erosional landscape remnant, Arctic Coastal Plain of Alaska

The dominant landscape process on the Arctic Coastal Plain of northern Alaska is the formation and drainage of thaw lakes. Lakes and drained thaw-lake basins account for approximately 75% of the modern surface expression of the Barrow Peninsula. The thaw-lake cycle usually obliterates lacustrine or peat sediments from previous cycles, which could otherwise be used for paleoecological reconstruction of long-term landscape and vegetation changes. Several possible erosional remnants of a former topographic surface that predates the formation of the thaw lakes have been tentatively identified. These remnants are characterized by a higher elevation, a thick organic layer with very high ground ice content in the upper permafrost and a plant community somewhat atypical of the region. Ten soil cores were collected from one site, and one core was intensively sampled for soil organic carbon content, pollen analysis and 14 C dating. The lowest level of the organic sediments represents the earliest phase of plant growth and dates to ca. 9000 cal BP. Palynological evidence indicates the presence of mesic shrub tundra (including sedge, birch, willow and heath vegetation), and microfossil indicators point to wetter eutrophic conditions during this period. Carbon accumulation was rapid due to high net primary productivity in a relatively nutrient-rich environment. These results are interpreted as the local response to ameliorating climate during the early Holocene. The middle Holocene portion of the record contains an unconformity, indicating that between 8200 and 4200 cal BP sediments were eroded from the site, presumably in response to wind activity during a drier period centered around 4500 cal BP. The modern vegetation community of the erosional remnant was established after 4200 cal BP and peat growth resumed. During the late Holocene, carbon accumulation rates (CARs) were greatly reduced in response to the combined effects of declining productivity associated with climatic cooling, and increased nutrient stress as paludification and permafrost aggradation sequestered mineral nutrients.

Alaska↗

A ground penetrating radar investigation of a glacial-marine ice- contact delta, Pineo Ridge, eastern coastal Maine

In eastern coastal Maine, many flat-topped landforms, often identified as glacial-marine deltas, are cultivated for blueberry production. These agriculturally valuable features are not exploited for aggregate resources, severely limiting stratigraphic exposure. Coring is often forbidden; where permissible, coarse-grained surficial sediments make coring and sediment retrieval difficult. Ground penetrating radar (GPR) has become an invaluable tool in an ongoing study of the otherwise inaccessible subsurface morphology in this region and provides a means of detailing the large-scale sedimentary structures comprising these features. GPR studies allow us to reassess previous depositional interpretations and to develop alternative developmental models. The work presented here focuses on Pineo Ridge, a large, flat-topped ice-marginal glacial-marine delta complex with a strong linear trend and two distinct landform zones, informally termed East Pineo and West Pineo. Previous workers have described each zone separately due to local morphological variation. Our GPR work further substantiates this geomorphic differentiation. East Pineo developed as a series of deltaic lobes prograding southward from an ice-contact margin during the local marine highstand. GPR data do not suggest postdepositional modification by ice-margin re-advance. We suggest that West Pineo has a more complex, two-stage depositional history. The southern section of the feature consists of southward-prograding deltaic lobes deposited during retreat of the Laurentide ice margin, with later erosional modification during marine regression. The northern section of West Pineo formed as a series of northward-prograd- ing deltaic lobes as sediment-laden meltwater may have been diverted by the existing deposits of the southern section of West Pineo. ?? 2007 The Geological Society of America. All rights reserved.

Special Paper of the Geological Society of America↗

Neotectonics of the offshore Oak Ridge fault near Ventura, southern California

The Oak Ridge fault is a large-offset, south-dipping reverse fault that forms the south boundary of the Ventura Basin in southern California. Previous research indicates that the Oak Ridge fault south of the town of Ventura has been inactive since 200-400 ka ago and that the fault tip is buried by ??? 1 km of Quaternary sediment. However, very high-resolution and medium-resolution seismic reflection data presented here show a south-dipping fault, on strike with the Oak Ridge fault, that is truncated at 80 m depth by an unconformity that is probably at the base of late Pleistocene and Holocene sediment. Furthermore, if vertically aligned features in seismic reflection data are eroded remnants of fault scarps, then a subsidiary fault within the Oak Ridge system deforms the shallowest imaged sediment layers. We propose that this subsidiary fault has mainly left-slip offset. These observations of Holocene slip on the Oak Ridge fault system suggest that revision of the earthquake hazard for the densely populated Santa Clara River valley and the Oxnard coastal plain may be needed.

Bulletin of the Seismological Society of America↗

Quantitative controls on location and architecture of carbonate depositional sequences: upper miocene, cabo de gata region, se Spain

Sequence stratigraphy, pinning-point relative sea-level curves, and magnetostratigraphy provide the quantitative data necessary to understand how rates of sea-level change and different substrate paleoslopes are dominant controls on accumulation rate, carbonate depositional sequence location, and internal architecture. Five third-order (1-10 my) and fourth-order (0.1-1.0 my) upper Miocene carbonate depositional sequences (DS1A, DS1B, DS2, DS3, TCC) formed with superimposed higher-frequency sea-level cycles in an archipelago setting in SE Spain. Overall, our study indicates when areas of high substrate slope (>15 degrees ) are in shallow water, independent of climate, the location and internal architecture of carbonate deposits are not directly linked to sea-level position but, instead, are controlled by location of gently sloping substrates and processes of bypass. In contrast, if carbonate sediments are generated where substrates of low slope (<15 degrees in our area) are in shallow water, then architecture and location of deposits may be more directly controlled by the relative position of sea level. For these systems, the rates of relative sea-level change are important for determining which systems tracts develop. DS1A-DS1B, cooler-water ramps, result from sediment bypass across steep paleoslopes to toes of slopes. Accumulation rates decreased from >15.6 cm/ky to approximately 2 cm/ky and overall relative sea level rose at rates of 17-21.4 cm/ky. Higher frequency sea-level rates were about 111 to more than 260 cm/ky, producing onlapping, fining- (deepening-) upward cycles. Decreasing accumulation rates resulted from decreasing surface area for shallow-water sediment production, drowning of shallow-water substrates, and complex sediment dispersal related to the archipelago setting. Typical systems tract and parasequence development should not be expected in "bypass ramp" settings; facies of onlapping strata do not track base level and are likely to be significantly different compared to onlapping strata associated with coastal onlap. Basal and upper DS2 reef megabreccias (indicating the transition from cool to warmer climatic conditions) were eroded from steep upslope positions and redeposited downslope onto areas of gentle substrate during rapid sea-level falls (>22.7 cm/ky) of short duration. Such rapid sea-level falls and presence of steep slopes are not conducive to formation of forced regressive systems tracts composed of down-stepping reef clinoforms. The DS3 reefal platform formed where shallow water coincided with gently sloping substrates created by earlier deposition. Slow progradation (0.39-1.45 km/my) is best explained by the lack of an extensive bank top, progressively falling sea level, and low productivity resulting from siliciclastic debris and excess nutrients shed from nearby volcanic islands. Although DS3 strata were deposited during a third-order relative sea-level cycle, a typical transgressive systems tract is not recognizable, indicating that the initial relative rise in sea level was too rapid (>>19 cm/ky). Downstepping reefs, forming a forced regressive systems tract, were deposited during the relative sea-level fall at the end of DS3, indicating that relatively slow rates of fall (10 cm/ky or less) over favorable paleoslope conditions are conducive to generation of forced regressive systems tracts consisting of downstepping reef clinoforms. The TCC sequence consists of four shallow-water sedimentary cycles that were deposited during a 400 ky to 100 ky time span. Such shallow-water cycles, typical of many platforms, form only where shallow water intersects gently sloping substrates. The relative thicknesses of cycles (<2 m to 15 m thick), magnitudes of relative sea-level fluctuations associated with each cycle (25-30 m), high rates of relative sea-level fluctuations (minimum of 25-120 cm/ky), and the widespread distribution of similar TCC cycles in the Mediterranean and elsewhere are supportive of a glacio-eustatic influence. With rates of sea-level change so high, typical systems tracts do not form.

Journal of Sedimentary Research↗

Ocean acidification buffering effects of seagrass in Tampa Bay

The Intergovernmental Panel on Climate Change has identified ocean acidification as a critical threat to marine and estuarine species in ocean and coastal ecosystems around the world. However, seagrasses are projected to benefit from elevated atmospheric pCO2, are capable of increasing seawater pH and carbonate mineral saturation states through photosynthesis, and may help buffer against the chemical impacts of ocean acidification. Additionally, dissolution of carbonate sediments may also provide a mechanism for buffering seawater pH. Long-term water quality monitoring data from the Environmental Protection Commission of Hillsborough County indicates that seawater pH has risen since the 1980‘s as seagrass beds have continued to recover since that time. We examined the role of seagrass beds in maintaining and elevating pH and carbonate mineral saturation state in northern and southern Tampa Bay where the percent of carbonate sediments is low (<3%) and high (>40%), respectively. Basic water quality and carbonate system parameters (including pH, total alkalinity, dissolved inorganic carbon, partial pressure of CO2, and carbonate mineral saturation state) were measured over diurnal time periods along transects (50-100 m) including dense and sparse Thalassia testudinum. seagrass beds, deep edge seagrass, and adjacent bare sand bottom. Seagrass density and productivity, sediment composition and hydrodynamic parameters were also measured, concurrently. Results indicate that seagrass beds locally elevate pH by up to 0.5 pH unit and double carbonate mineral saturation states relative to bare sand habitats. Thus, seagrass beds in Tampa Bay may provide refuge for marine organisms from the impacts of ocean acidification.

Florida↗