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At least 145 records · Page 8Linked to original sources

Monogenetic origin of Ubehebe Crater maar volcano, Death Valley, California: Paleomagnetic and stratigraphic evidence

Paleomagnetic data for samples collected from outcrops of basaltic spatter at the Ubehebe Crater cluster, Death Valley National Park, California, record a single direction of remanent magnetization indicating that these materials were emplaced during a short duration, monogenetic eruption sequence ~ 2100 years ago. This conclusion is supported by geochemical data encompassing a narrow range of oxide variation, by detailed stratigraphic studies of conformable phreatomagmatic tephra deposits showing no evidence of erosion between layers, by draping of sharp rimmed craters by later tephra falls, and by oxidation of later tephra layers by the remaining heat of earlier spatter. This model is also supported through a reinterpretation and recalculation of the published age results (Sasnett et al., 2012) from an innovative and bold exposure-age study on very young materials. Their conclusion of multiple and protracted eruptions at Ubehebe Crater cluster is here modified through the understanding that some of their quartz-bearing clasts inherited from previous exposure on the fan surface (too old), and that other clasts were only exposed at the surface by wind and/or water erosion centuries after their eruption (too young). Ubehebe Crater cluster is a well preserved example of young monogenetic maar type volcanism protected within a National Park, and it represents neither a protracted eruption sequence as previously thought, nor a continuing volcanic hazard near its location.

California

Transport of suspended solids from a karstic to an alluvial aquifer: The role of the karst/alluvium interface

This study focuses on the coupled transport of dissolved constituents and particulates, from their infiltration on a karst plateau to their discharge from a karst spring and their arrival at a well in an alluvial plain. Particulate markers were identified and the transport of solids was characterised in situ in porous and karstic media, based on particle size analyses, SEM, and traces. Transport from the sinkhole to the spring appeared to be dominated by flow through karst: particulate transport was apparently conservative between the two sites, and there was little difference in the overall character of the particle size distribution of the particulates infiltrating the sinkhole and of those discharging from the spring. Qualitatively, the mineralogy of the infiltrating and discharging material was similar, although at the spring an autochthonous contribution from the aquifer was noted (chalk particles eroded from the parent rock by weathering). In contrast, transport between the spring and the well appears to be affected by the overlying alluvium: particles in the water from the well, showed evidence of considerable size-sorting. Additionally, SEM images of the well samples showed the presence of particles originating from the overlying alluvial system; these particles were not found in samples from the sinkhole or the spring. The differences between the particulates discharging from the spring and the well indicate that the water pumped from the alluvial plain is coming from the karst aquifer via the very transmissive, complex geologic interface between the underlying chalk formation and the gravel at the base of the overlying alluvial system. ?? 2002 Elsevier Science B.V. All rights reserved.

Journal of Hydrology

Simulating the water budget of a Prairie Potholes complex from LiDAR and hydrological models in North Dakota, USA

Hydrological processes of the wetland complex in the Prairie Pothole Region (PPR) are difficult to model, partly due to a lack of wetland morphology data. We used Light Detection And Ranging (LiDAR) data sets to derive wetland features; we then modelled rainfall, snowfall, snowmelt, runoff, evaporation, the “fill-and-spill” mechanism, shallow groundwater loss, and the effect of wet and dry conditions. For large wetlands with a volume greater than thousands of cubic metres (e.g. about 3000 m 3 ), the modelled water volume agreed fairly well with observations; however, it did not succeed for small wetlands (e.g. volume less than 450 m 3 ). Despite the failure for small wetlands, the modelled water area of the wetland complex coincided well with interpretation of aerial photographs, showing a linear regression with R 2 of around 0.80 and a mean average error of around 0.55 km 2 . The next step is to improve the water budget modelling for small wetlands.

North Dakota

Changes in concentration of certain constituents of treated waste water during movement through the Magothy Aquifer, Bay Park, New York

Approximately 7 million gallons (27 million litres) of tertiary-treated sewage (reclaimed water) was injected by well into the Magothy aquifer and was subsequently pumped out. As the reclaimed water moved through the aquifer, concentrations of certain dissolved constituents decreased as follows: Total nitrogen, 7 percent; methylene blue active substances, 49 percent; chemical oxygen demand, 50 percent; and phosphate, more than 93 percent.

New York

Enhanced microbial coalbed methane generation: A review of research, commercial activity, and remaining challenges

Coalbed methane (CBM) makes up a significant portion of the world’s natural gas resources. The discovery that approximately 20% of natural gas is microbial in origin has led to interest in microbially enhanced CBM (MECoM), which involves stimulating microorganisms to produce additional CBM from existing production wells. This paper reviews current laboratory and field research on understanding processes and reservoir conditions which are essential for microbial CBM generation, the progress of efforts to stimulate microbial methane generation in coal beds, and key remaining knowledge gaps. Research has been primarily focused on identifying microbial communities present in areas of CBM generation and attempting to determine their function, in-situ reservoir conditions that are most favorable for microbial CBM generation, and geochemical indicators of metabolic pathways of methanogenesis (i.e., acetoclastic or hydrogenotrophic methanogenesis). Meanwhile, researchers at universities, government agencies, and companies have focused on four primary MECoM strategies: 1) microbial stimulation (i.e., addition of nutrients to stimulate native microbes); 2) microbial augmentation (i.e., addition of microbes not native to or abundant in the reservoir of interest); 3) physically increasing microbial access to coal and distribution of amendments; and 4) chemically increasing the bioavailability of coal organics. Most companies interested in MECoM have pursued microbial stimulation: Luca Technologies, Inc., successfully completed a pilot scale field test of their stimulation strategy, while two others, Ciris Energy and Next Fuel, Inc., have undertaken smaller scale field tests. Several key knowledge gaps remain that need to be addressed before MECoM strategies can be implemented commercially. Little is known about the bacterial community responsible for coal biodegradation and how these microorganisms may be stimulated to enhance microbial methanogenesis. In addition, research is needed to understand what fraction of coal is available for biodegradation, and methods need to be developed to determine the extent of in-situ coal biodegradation by MECoM processes for monitoring changes to coal quality. Questions also remain about how well field-scale pilot tests will scale to commercial production, how often amendments will need to be added to maintain new methane generation, and how well MECoM strategies transfer between coal basins with different formation water geochemistries and coal ranks. Addressing these knowledge gaps will be key in determining the feasibility and commercial viability of MECoM technology.

International Journal of Coal Geology

Low prevalence of VHSV detected in round goby collected in offshore regions of Lake Ontario

Since the first reports of mortalities due to viral hemorrhagic septicemia virus (VHSV) type IVb in the Laurentian Great Lakes basin during 2005 (Lake St. Clair, USA and Bay of Quinte, Lake Ontario, Canada), many groups have conducted surveillance efforts for the virus, primarily in nearshore areas. The round goby ( Neogobius melanostomus ) has been identified as a key species to target for surveillance, because they have a very high probability of infection at a given site. Our objective in this study was to document and quantify VHSV in round gobies in offshore waters of Lake Ontario using molecular techniques. We collected 139 round gobies from depths ranging from 55 to 150 m using bottom trawls during the early spring of 2011 and detected VHSV in 4 individuals (1/26 fish at 95 m, 2/12 fish at 105 m, and 1/24 fish at 135 m). These results expand the known depth range of VHSV in the Great Lakes. They also have implications on the management of the spread of VHSV within infected bodies of water related to the mixing of populations of fish that would remain distinct in their breeding habitats, but then have the opportunity to mix in their overwintering habitats, as well as to increase overlap of predator and prey species in overwintering habitats.

Lake Ontario

Simulating and understanding sand wave variation: A case study of the Golden Gate sand waves

In this paper we present a detailed comparison between measured features of the Golden Gate sand wave field and the results of a nonlinear sand wave model. Because the Golden Gate sand waves exhibit large variation in their characteristics and in their environmental physics, this area gives us the opportunity to study sand wave variation between locations, within one well-measured, large area. The nonlinear model used in this paper is presently the only tool that provides information on the nonlinear evolution of large-amplitude sand waves. The model is used to increase our understanding of the coupling between the variability in environmental conditions and the sand wave characteristics. Results show that the model is able to describe the variation in the Golden Gate sand waves well when both the local oscillating tidal current and the residual current are taken into account. Current and water depth seem to be the most important factors influencing sand wave characteristics. The simulation results give further confidence in the underlying model hypothesis and assumptions. Copyright 2009 by the American Geophysical Union.

Journal of Geophysical Research F: Earth Surface

Modeling thermal dynamics of active layer soils and near-surface permafrost using a fully coupled water and heat transport model

Thawing and freezing processes are key components in permafrost dynamics, and these processes play an important role in regulating the hydrological and carbon cycles in the northern high latitudes. In the present study, we apply a well-developed soil thermal model that fully couples heat and water transport, to simulate the thawing and freezing processes at daily time steps across multiple sites that vary with vegetation cover, disturbance history, and climate. The model performance was evaluated by comparing modeled and measured soil temperatures at different depths. We use the model to explore the influence of climate, fire disturbance, and topography (north- and south-facing slopes) on soil thermal dynamics. Modeled soil temperatures agree well with measured values for both boreal forest and tundra ecosystems at the site level. Combustion of organic-soil horizons during wildfire alters the surface energy balance and increases the downward heat flux through the soil profile, resulting in the warming and thawing of near-surface permafrost. A projection of 21st century permafrost dynamics indicates that as the climate warms, active layer thickness will likely increase to more than 3 meters in the boreal forest site and deeper than one meter in the tundra site. Results from this coupled heat-water modeling approach represent faster thaw rates than previously simulated in other studies. We conclude that the discussed soil thermal model is able to well simulate the permafrost dynamics and could be used as a tool to analyze the influence of climate change and wildfire disturbance on permafrost thawing.

Journal of Geophysical Research D: Atmospheres

Origin of two clay-mineral facies of the Potomac Group (Cretaceous) in the Middle Atlantic States

Sedimentary clay that crops out in the coastal plains of New Jersey, Delaware, the part of Maryland north and east of Washington, B.C., and the northeast half of Washington, D.C., in the nonmarine Cretaceous Potomac Group is predominantly kaolinite and illite. In contrast, in part of southeastern Maryland, the southwest half of Washington, D.C., and most of eastern Virginia, Potomac Group clay is predominantly montmorillonite. Kaolinite and illite were probably derived by intense acid weathering of metamorphic and granitic rocks to the west during the Cretaceous and were deposited in a well-drained basin. Montmorillonite was most likely produced by deep weathering of a mainly granitic source. Poor drainage and alkaline surface- and ground-water conditions probably accompanied the production, transportation, deposition, and burial of the montmorillonite. Kaolinization of the montmorillonite is taking place now at the surface in northern Virginia.

Delaware, Maryland, New Jersey, Pennsylvania, Virg

Channel incision and patterns of cottonwood stress and mortality along the Mojave River, California

In 1995, mapping and classification of riparian vegetation along the Mojave River in southern California revealed an 8-km reach in which riparian cottonwoods ( Populus fremontii Wats.) were stressed or dying. We tested a set of predictions based on the inference that cottonwood decline was an indirect result of lowered water-table levels following flood-related channel incision. Comparisons of topographic cross-sections from 1963 and 1997, indicated a net change in channel elevation between −0·71 and −3·6 m within zones of cottonwood stress and mortality. Ages of young cottonwood and willow stems adjacent to the present channel and radial stem growth of surviving cottonwoods were consistent with the inference that channel incision, associated with sustained flooding in January and February of 1993, lowered channel elevations throughout the affected reach. Well records and soil redoximorphic features indicate that channel incision caused net water-table declines ⩾1·5 m on portions of the adjacent flood plain where cottonwood stand mortality ranged between 58 and 93%. In areas where water-table declines were estimated to be <1·0 m, stand mortality was 7–13%.

Journal of Arid Environments

Factors affecting pesticide occurrence and transport in a large Midwestern river basin

Several factors affect the occurrence and transport of pesticides in surface waters of the 29,400 km2 White River Basin in Indiana. A relationship was found between pesticide use and the average annual concentration of that pesticide in the White River, although this relationship varies for different classes of pesticides. About one percent of the mass applied of each of the commonly used agricultural herbicides was transported from the basin via the White River. Peak pesticide concentrations were typically highest in late spring or early summer and were associated with periods of runoff following application. Concentrations of diazinon were higher in an urban basin than in two agricultural basins, corresponding to the common use of this insecticide on lawns and gardens in urban areas. Concentrations of atrazine, a corn herbicide widely used in the White River Basin, were higher in an agricultural basin with permeable, well-drained soils, than in an agricultural basin with less permeable, more poorly drained soils. Although use of butylate and cyanazine was comparable in the White River Basin between 1992 and 1994, concentrations in the White River of butylate, which is incorporated into soil, were substantially less than for cyanazine, which is typically applied to the soil surface.

Indiana

Organic substances in produced and formation water from unconventional natural gas extraction in coal and shale

Organic substances in produced and formation water from coalbed methane (CBM) and gas shale plays from across the USA were examined in this study. Disposal of produced waters from gas extraction in coal and shale is an important environmental issue because of the large volumes of water involved and the variable quality of this water. Organic substances in produced water may be environmentally relevant as pollutants, but have been little studied. Results from five CBM plays and two gas shale plays (including the Marcellus Shale) show a myriad of organic chemicals present in the produced and formation water. Organic compound classes present in produced and formation water in CBM plays include: polycyclic aromatic hydrocarbons (PAHs), heterocyclic compounds, alkyl phenols, aromatic amines, alkyl aromatics (alkyl benzenes, alkyl biphenyls), long-chain fatty acids, and aliphatic hydrocarbons. Concentrations of individual compounds range from < 1 to 100 μg/L, but total PAHs (the dominant compound class for most CBM samples) range from 50 to 100 μg/L. Total dissolved organic carbon (TOC) in CBM produced water is generally in the 1–4 mg/L range. Excursions from this general pattern in produced waters from individual wells arise from contaminants introduced by production activities (oils, grease, adhesives, etc.). Organic substances in produced and formation water from gas shale unimpacted by production chemicals have a similar range of compound classes as CBM produced water, and TOC levels of about 8 mg/L. However, produced water from the Marcellus Shale using hydraulic fracturing has TOC levels as high as 5500 mg/L and a range of added organic chemicals including, solvents, biocides, scale inhibitors, and other organic chemicals at levels of 1000 s of μg/L for individual compounds. Levels of these hydraulic fracturing chemicals and TOC decrease rapidly over the first 20 days of water recovery and some level of residual organic contaminants remain up to 250 days after hydraulic fracturing. Although the environmental impacts of the organics in produced water are not well defined, results suggest that care should be exercised in the disposal and release of produced waters containing these organic substances into the environment because of the potential toxicity of many of these substances.

International Journal of Coal Geology

Progression of natural attenuation processes at a crude-oil spill site . I. Geochemical evolution of the plume

A 16-year study of a hydrocarbon plume shows that the extent of contaminant migration and compound-specific behavior have changed as redox reactions, most notably iron reduction, have progressed over time. Concentration changes at a small scale, determined from analysis of pore-water samples drained from aquifer cores, are compared with concentration changes at the plume scale, determined from analysis of water samples from an observation well network. The small-scale data show clearly that the hydrocarbon plume is growing slowly as sediment iron oxides are depleted. Contaminants, such as ortho -xylene that appeared not to be moving downgradient from the oil on the basis of observation well data, are migrating in thin layers as the aquifer evolves to methanogenic conditions. However, the plume-scale observation well data show that the downgradient extent of the Fe 2+ and BTEX plume did not change between 1992 and 1995. Instead, depletion of the unstable Fe (III) oxides near the subsurface crude-oil source has caused the maximum dissolved iron concentration zone within the plume to spread at a rate of approximately 3 m/year. The zone of maximum concentrations of benzene, toluene, ethylbenzene and xylene (BTEX) has also spread within the anoxic plume. In monitoring the remediation of hydrocarbon-contaminated ground water by natural attenuation, subtle concentration changes in observation well data from the anoxic zone may be diagnostic of depletion of the intrinsic electron-accepting capacity of the aquifer. Recognition of these subtle patterns may allow early prediction of growth of the hydrocarbon plume.

Journal of Contaminant Hydrology

Bayesian hierarchical modeling for probabilistic estimation of tsunami amplitude from far-field earthquake sources

Evaluation of tsunami disaster risk for a coastal region requires reliable estimation of tsunami hazard, for example, wave amplitude close to the shore. Observed tsunami data are scarce and have poor spatial coverage, and for this reason probabilistic tsunami hazard analysis (PTHA) traditionally relies on numerical simulation of “synthetic” tsunami generation and propagation toward the coast. Such an approach has been extensively studied in the past and it is widely recognized as an important disaster-risk mitigation tool. PTHA can not only provide less uncertain and spatially coherent hazard estimates in comparison with classical empirical data analysis which is restricted at the tide gauge stations, but also local inundation information. In this paper, we explore a purely statistical alternative to traditional PTHA for evaluation of tsunami amplitude hazard. Here, we use tide gauge measurements of tsunami amplitude along the western United States, specifically California and Oregon, and develop a spatial Bayesian hierarchical model (BHM) to assess tsunami hazard from far-field earthquake sources at various recurrence intervals. The configuration of our model incorporates latent Gaussian fields that utilize information on the distance between tide gauges as well as on the continental shelf width, that is, a covariate linked to potential dissipative effects on wave energy as the tsunami travels over shallow water. Through our BHM, we produce spatially continuous probabilistic maps of far-field tsunami hazard which can aid comprehensive tsunami disaster risk reduction and management.

California, Oregon, Washington

Phytoremediation of a petroleum-hydrocarbon contaminated shallow aquifer in Elizabeth City, North Carolina, USA

A former bulk fuel terminal in North Carolina is a groundwater phytoremediation demonstration site where 3,250 hybrid poplars, willows, and pine trees were planted from 2006 to 2008 over approximately 579,000 L of residual gasoline, diesel, and jet fuel. Since 2011, the groundwater altitude is lower in the area with trees than outside the planted area. Soil-gas analyses showed a 95 percent mass loss for total petroleum hydrocarbons (TPH) and a 99 percent mass loss for benzene, toluene, ethylbenzene, and xylenes (BTEX). BTEX and methyl tert-butyl ether concentrations have decreased in groundwater. Interpolations of free-phase, fuel product gauging data show reduced thicknesses across the site and pooling of fuel product where poplar biomass is greatest. Isolated clusters of tree mortalities have persisted in areas with high TPH and BTEX mass. Toxicity assays showed impaired water use for willows and poplars exposed to the site's fuel product, but Populus survival was higher than the willows or pines on-site, even in a noncontaminated control area. All four Populus clones survived well at the site.

North Carolina

Successional trends in Sonoran Desert abandoned agricultural fields in northern Mexico

Excessive ground-water use and saline intrusion to the aquifer led, in less than three decades, to an increase in abandoned agricultural fields at La Costa de Hermosillo, within the Sonoran Desert. Using a chronosequence from years since abandonment, patterns of field succession were developed. Contrary to most desert literature, species replacement was found, both in fields with and without saline intrusion. Seasonal photosynthetic capacity as well as water and nitrogen use efficiencies were different in dominant early and late successional plant species. These ecological findings provided a framework for a general explanation of species dominance and replacement within abandoned agricultural fields in the Sonoran Desert. ?? 2004 Elsevier Ltd. All rights reserved.

Journal of Arid Environments

Rapid fluid disruption: A source for self-potential anomalies on volcanoes

Self-potential (SP) anomalies observed above suspected magma reservoirs, dikes, etc., on various volcanoes (Kilauea, Hawaii; Mount Unzen, Japan; Piton de la Fournaise, Reunion Island, Miyake Jima, Japan) result from transient surface electric fields of tens of millivolts per kilometer and generally have a positive polarity. These SP anomalies are usually attributed to electrokinetic effects where properties controlling this process are poorly constrained. We propose an alternate explanation that contributions to electric fields of correct polarity should be expected from charge generation by fluid vaporization/disruption. As liquids are vaporized or removed as droplets by gas transport away from hot dike intrusions, both charge generation and local increase in electrical resistivity by removal of fluids should occur. We report laboratory observations of electric fields in hot rock samples generated by pulses of fluid (water) through the rock at atmospheric pressure. These indicate the relative amplitudes of rapid fluid disruption (RFD) potentials and electrokinetic potentials to be dramatically different and the signals are opposite in sign. Above vaporization temperatures, RFD effects of positive sign in the direction of gas flow dominate, whereas below these temperatures, effects of negative sign dominate. This suggests that the primary contribution to observed self-potential anomalies arises from gas-related charge transport processes at temperatures high enough to produce vigorous boiling and vapor transport. At lower temperatures, the primary contribution is from electrokinetic effects modulated perhaps by changing electrical resistivity and RFD effects from high-pressure but low-temperature CO2 and SO2 gas flow ripping water molecules from saturated crustal rocks. If charge generation is continuous, as could well occur above a newly emplaced dike, positive static potentials will be set up that could be sustained for many years, and the simplest method for identifying these hot, active regions would be to identify the SP anomalies they generate.

Hawai'i

Temperature dependence of unsaturated hydraulic conductivity of two soils

Packed columns of Oakley sand (mixed, mesic Typic Paleudalfs) and Hanford sandy loam (mixed, nonacid, thermic Typic Xerorthents) were used to develop isothermal steady-state fluxes. Soil matric potentials were measured and unsaturated hydraulic conductivities were calculated over a range of matric potentials at 2°, 25°, and 45° ± 0.5°C. In addition, water retention characteristics (to −100 kPa) were measured at these same temperatures for both soils. In this paper, the calculated results are compared to an equation that relates unsaturated conductivity to the intrinsic permeability, the relative permeability, and the viscosity of water. The equation considers viscosity to be the only parameter that changes with temperature. The results show a much greater temperature dependence in the unsaturated conductivity than would be predicted by this equation. The results indicate that the relative permeability may be a function of temperature. The temperature dependence of the soil water matric potential, surface tension, and diffuse double-layer thickness are discussed in terms of their possible interaction with the unsaturated conductivity values obtained. A case is presented for further study to isolate these temperature-sensitive parameters as well as additional parameters related to fluid flow path changes with temperature.

Soil Science Society of America Journal