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At least 145 records · Page 8Linked to original sources

Trends in snowpack chemistry and comparison to National Atmospheric Deposition Program results for the Rocky Mountains, US, 1993-2004

Seasonal snowpack chemistry data from the Rocky Mountain region of the US was examined to identify long-term trends in concentration and chemical deposition in snow and in snow-water equivalent. For the period 1993-2004, comparisons of trends were made between 54 Rocky Mountain Snowpack sites and 16 National Atmospheric Deposition Program wetfall sites located nearby in the region. The region was divided into three subregions: Northern, Central, and Southern. A non-parametric correlation method known as the Regional Kendall Test was used. This technique collectively computed the slope, direction, and probability of trend for several sites at once in each of the Northern, Central, and Southern Rockies subregions. Seasonal Kendall tests were used to evaluate trends at individual sites. Significant trends occurred during the period in wetfall and snowpack concentrations and deposition, and in precipitation. For the comparison, trends in concentrations of ammonium, nitrate, and sulfate for the two networks were in fair agreement. In several cases, increases in ammonium and nitrate concentrations, and decreases in sulfate concentrations for both wetfall and snowpack were consistent in the three subregions. However, deposition patterns between wetfall and snowpack more often were opposite, particularly for ammonium and nitrate. Decreases in ammonium and nitrate deposition in wetfall in the central and southern rockies subregions mostly were moderately significant (p<0.11) in constrast to highly significant increases in snowpack (p<0.02). These opposite trends likely are explained by different rates of declining precipitation during the recent drought (1999-2004) and increasing concentration. Furthermore, dry deposition was an important factor in total deposition of nitrogen in the region. Sulfate deposition decreased with moderate to high significance in all three subregions in both wetfall and snowpack. Precipitation trends consistently were downward and significant for wetfall, snowpack, and snow-telemetry data for the central and southern rockies subregions (p<0.03), while no trends were noted for the Northern Rockies subregion.

Atmospheric Environment↗

Differences between near-surface equivalent temperature and temperature trends for the Eastern United States. Equivalent temperature as an alternative measure of heat content

There is currently much attention being given to the observed increase in near-surface air temperatures during the last century. The proper investigation of heating trends, however, requires that we include surface heat content to monitor this aspect of the climate system. Changes in heat content of the Earth's climate are not fully described by temperature alone. Moist enthalpy or, alternatively, equivalent temperature, is more sensitive to surface vegetation properties than is air temperature and therefore more accurately depicts surface heating trends. The microclimates evident at many surface observation sites highlight the influence of land surface characteristics on local surface heating trends. Temperature and equivalent temperature trend differences from 1982-1997 are examined for surface sites in the Eastern U.S. Overall trend differences at the surface indicate equivalent temperature trends are relatively warmer than temperature trends in the Eastern U.S. Seasonally, equivalent temperature trends are relatively warmer than temperature trends in winter and are relatively cooler in the fall. These patterns, however, vary widely from site to site, so local microclimate is very important. ?? 2006 Elsevier B.V. All rights reserved.

Global and Planetary Change↗

Trends in concentrations of nitrate and total dissolved solids in public supply wells of the Bunker Hill, Lytle, Rialto, and Colton groundwater subbasins, San Bernardino County, California: Influence of legacy land use

Concentrations and temporal changes in concentrations of nitrate and total dissolved solids (TDS) in groundwater of the Bunker Hill, Lytle, Rialto, and Colton groundwater subbasins of the Upper Santa Ana Valley Groundwater Basin were evaluated to identify trends and factors that may be affecting trends. One hundred, thirty-one public-supply wells were selected for analysis based on the availability of data spanning at least 11 years between the late 1980s and the 2000s. Forty-one of the 131 wells (31%) had a significant (p < 0.10) increase in nitrate and 14 wells (11%) had a significant decrease in nitrate. For TDS, 46 wells (35%) had a significant increase and 8 wells (6%) had a significant decrease. Slopes for the observed significant trends ranged from − 0.44 to 0.91 mg/L/yr for nitrate (as N) and − 8 to 13 mg/L/yr for TDS. Increasing nitrate trends were associated with greater well depth, higher percentage of agricultural land use, and being closer to the distal end of the flow system. Decreasing nitrate trends were associated with the occurrence of volatile organic compounds (VOCs); VOC occurrence decreases with increasing depth. The relations of nitrate trends to depth, lateral position, and VOCs imply that increasing nitrate concentrations are associated with nitrate loading from historical agricultural land use and that more recent urban land use is generally associated with lower nitrate concentrations and greater VOC occurrence. Increasing TDS trends were associated with relatively greater current nitrate concentrations and relatively greater amounts of urban land. Decreasing TDS trends were associated with relatively greater amounts of natural land use. Trends in TDS concentrations were not related to depth, lateral position, or VOC occurrence, reflecting more complex factors affecting TDS than nitrate in the study area.

California↗

Climate extremes as drivers of surface-water-quality trends in the United States

Surface-water quality can change in response to climate perturbations, such as changes in the frequency of heavy precipitation or droughts, through direct effects, such as dilution and concentration, and through physical processes, such as bank scour. Water quality might also change through indirect mechanisms, such as changing water demand or changes in runoff interaction with organic matter on the landscape. Many studies predict future changes in water-quality related to climate changes; however, fewer studies specifically document changes in water quality related to changes in climate, and they are usually limited in geographic scope. Recently, the U.S. Geological Survey's National Water-Quality Program reported nearly 12,000 trends in concentration and load for numerous water-quality constituents, including nutrients, sediment, major ions, and carbon. The results provide an unprecedented opportunity to examine sites across the conterminous United States for changes in water quality related to climate changes. We used published water-quality trends, modeled using the method of Weighted Regressions on Time, Season and Discharge, and calculated trends in climate extremes indices, using a modified Mann-Kendall trend method. The water-quality and the climate extremes trends were combined to identify areas in the conterminous United States where changes in climate extremes may have changed water quality. We investigated the water-quality trends in these areas to determine whether the trends related to changes in climate. We found that it was important to go beyond spatial correlation and examine trends on a watershed scale to investigate key drivers of trends. We found successful management practices in Iowa to reduce chloride concentrations, despite increases in icing days. For sediment, it appeared that management practices were having a larger effect than climate changes. For nutrients, complex forces affecting water quality make it difficult to unequivocally attribute water-quality change to climate change.

Science of the Total Environment↗

Analysis options for estimating status and trends in long-term monitoring

This chapter describes methods for estimating long-term trends in ecological parameters. Other chapters in this volume discuss more advanced methods for analyzing monitoring data, but these methods may be relatively inaccessible to some readers. Therefore, this chapter provides an introduction to trend analysis for managers and biologists while also discussing general issues relevant to trend assessment in any long-term monitoring program. For simplicity, we focus on temporal trends in population size across years. We refer to the survey results for each year as the “annual means” (e.g. mean per transect, per plot, per time period). The methods apply with little or no modification, however, to formal estimates of population size, other temporal units (e.g. a month), to spatial or other dimensions such as elevation or a north–south gradient, and to other quantities such as chemical or geological parameters. The chapter primarily discusses methods for estimating population-wide parameters rather than studying variation in trend within the population, which can be examined using methods presented in other chapters (e.g. Chapters 7, 12, 20). We begin by reviewing key concepts related to trend analysis. We then describe how to evaluate potential bias in trend estimates. An overview of the statistical models used to quantify trends is then presented. We conclude by showing ways to estimate trends using simple methods that can be implemented with spreadsheets.

Book chapter↗

Detection of water quality trends at high, median, and low flow in a Catskill Mountain stream, New York, through a new statistical method

The effects of changes in acid deposition rates resulting from the Clean Air Act Amendments of 1990 should first appear in stream waters during rainstorms and snowmelt, when the surface of the watershed is most hydrologically connected to the stream. Early detection of improved stream water quality is possible if trends at high flow could be separately determined. Trends in concentrations of sulfate (SO 4 2− ), nitrate (NO 3 − ), calcium plus magnesium (Ca 2+ +Mg 2+ ), and acid‐neutralizing capacity (ANC) in Biscuit Brook, Catskill Mountains, New York, were assessed through segmented regression analysis (SRA). The method uses annual concentration‐to‐discharge relations to predict concentrations for specific discharges, then compares those annual values to determine trends at specific discharge levels. Median‐flow trends using SRA were comparable to those predicted by the seasonal Kendall tau test and a multiple regression residual analysis. All of these methods show that stream water SO 4 2− concentrations have decreased significantly since 1983; Ca 2+ +Mg 2+ concentrations have decreased at a steady but slower rate than SO 4 2− ; and ANC shows no trend. The new SRA method, however, reveals trends that differ at specified flow levels. ANC has increased, and NO 3 − concentrations have decreased at high flows, but neither has changed as significantly at low flows. The general downward trend in SO 4 2− flattened at median flow and reversed at high flow between 1997 and 2002. The reversal of the high‐flow SO 4 2− trend is consistent with increases in SO 4 2− concentrations in both precipitation and soil solutions at Biscuit Brook. Separate calculation of high‐flow trends provides resource managers with an early detection system for assessing changes in water quality resulting from changes in acidic deposition.

Water Resources Research↗

Long-term monotonic trends in water budget components in the contiguous United States: Insights from two hydrologic models

Characterizing changes to water availability for domestic, industrial, agricultural, and other uses is essential to support water management. To better quantify these changes, the U.S. Geological Survey and National Science Foundation National Center for Atmospheric Research produced two hydrologic models simulating water budget components from 1980 to 2021 over the contiguous United States (CONUS). Both hydrologic models were driven by a common atmospheric forcing dataset and aggregated to common spatial and temporal scales, which enables a novel evaluation of congruency between the models. We present annual and seasonal trends in six water budget components (precipitation, evapotranspiration, streamflow, groundwater recharge, soil saturation, and snow water equivalent) based on the Mann–Kendall test for monotonic trend and Theil-Sen slope estimate for the water year 1983–2021 period for ~86,000 catchments in CONUS. Additional components and metrics from our analysis pipeline are available in an associated published dataset, which contains more than 46 million trend results. The water budget trends showed broad agreement with prior observational and modeling studies that indicate increasing trends in the northeast and decreasing trends in southwestern CONUS. We found the seasonal variability in water budget trends was greatest in the southern, central, and northwest CONUS. These findings support integrated trend assessments when coupled with trends in water quality and use.

Contiguous United States↗

Spatial variability in seasonal snowpack trends across the Rio Grande headwaters (1984 - 2017)

This study evaluated the spatial variability of trends in simulated snowpack properties across the Rio Grande headwaters of Colorado using the SnowModel snow evolution modeling system. SnowModel simulations were performed using a grid resolution of 100 m and 3-hourly time step over a 34-yr period (1984–2017). Atmospheric forcing was provided by phase 2 of the North American Land Data Assimilation System, and the simulations accounted for temporal changes in forest canopy from bark beetle and wildfire disturbances. Annual summary values of simulated snowpack properties [snow metrics; e.g., peak snow water equivalent (SWE), snowmelt rate and timing, and snow sublimation] were used to compute trends across the domain. Trends in simulated snow metrics varied depending on elevation, aspect, and land cover. Statistically significant trends did not occur evenly within the basin, and some areas were more sensitive than others. In addition, there were distinct trend differences between the different snow metrics. Upward trends in mean winter air temperature were 0.3°C decade −1 , and downward trends in winter precipitation were −52 mm decade −1 . Middle elevation zones, coincident with the greatest volumetric snow water storage, exhibited the greatest sensitivity to changes in peak SWE and snowmelt rate. Across the Rio Grande headwaters, snowmelt rates decreased by 20% decade −1 , peak SWE decreased by 14% decade −1 , and total snowmelt quantity decreased by 13% decade −1 . These snow trends are in general agreement with widespread snow declines that have been reported for this region. This study further quantifies these snow declines and provides trend information for additional snow variables across a greater spatial coverage at finer spatial resolution.

Colorado↗

Salinity trends in surface waters of the Upper Colorado River Basin, Colorado

Dissolved-solids data collected in the Upper Colorado River Basin upstream from Cameo, Colorado, and in the Gunnison River Basin were analyzed for trends in flow-adjusted dissolved-solids concentrations and loads for water years 1970 to 1993, 1980 to 1993, and 1986 to 1993. Trend results for flow-adjusted periodic dissolved-solids concentrations for the Colorado River Basin upstream from Cameo, CO, generally were downward or no trend was indicated. Trends in flow-adjusted monthly and annual dissolved-solids loads primarily were downward or absent. These trend results partly agree with the downward trends reported by a previous investigation for the Colorado River near Cameo site. In the Gunnison River Basin, trends in flow-adjusted dissolved-solids concentrations and loads were not detected for more than one-half of the site/analysis-period combinations. Of the trends that were present, most indicated decreases in concentrations and loads rather than increases. In both the Colorado River Basin upstream from Cameo, CO, and the Gunnison River Basin, trends in flow-adjusted dissolved-solids concentrations and flow-adjusted monthly and annual dissolved-solids loads may be affected by a variety of factors. These include channel evolution and hydrologic variation, water quality and flow rate of groundwater discharges and springs, sample size and period of record of dissolved-solids data, and changes in land use in the basin.

Journal of Environmental Quality↗

Water-quality trends using sediment cores from White Rock Lake, Dallas, Texas

The U.S. Geological Survey National Water-Quality Assessment (NAWQA) Program has three objectives, one of which is "to define trends (or lack of trends) in water quality" (Leahy and others, 1990). Water-quality trends are of interest for at least three reasons: First, trends can improve our understanding of the influence of human activities on water-quality conditions; second, trends can indicate the effectiveness of environmental regulations; and third, trends can provide a warning of additional degradation of water quality in the future. A common approach for determining water-quality trends in streams is to apply statistical tests to historical data; however, historical water-quality data have several limitations. These include lack of data, inconsistent sampling and analytical methods, numerous measurements below detection levels, and questionable accuracy. If historical data are lacking or are inappropriate for statistical trend testing, water-quality records can be partly reconstructed using sediment cores from receiving water bodies such as reservoirs. The purpose of this fact sheet is to summarize the principal findings documented in a report on water-quality trends in White Rock Creek Basin using dated sediment cores from White Rock Lake (Van Metre and Callender, in press). The study used dated sediment cores to reconstruct water-quality conditions. More specifically, the changes in water quality associated with the watershed&rsquo;s change from agricultural to urban land use and with the implementation of environmental regulations were identified.

Texas↗

Streamflow characteristics and trends in New Jersey, water years 1897-2003

Streamflow statistics were computed for 111 continuous-record streamflow-gaging stations with 20 or more years of continuous record and for 500 low-flow partial-record stations, including 66 gaging stations with less than 20 years of continuous record. Daily mean streamflow data from water year 1897 through water year 2001 were used for the computations at the gaging stations. (The water year is the 12-month period, October 1 through September 30, designated by the calendar year in which it ends). The characteristics presented for the long-term continuous-record stations are daily streamflow, harmonic mean flow, flow frequency, daily flow durations, trend analysis, and streamflow variability. Low-flow statistics for gaging stations with less than 20 years of record and for partial-record stations were estimated by correlating base-flow measurements with daily mean flows at long-term (more than 20 years) continuous-record stations. Instantaneous streamflow measurements through water year 2003 were used to estimate low-flow statistics at the partial-record stations. The characteristics presented for partial-record stations are mean annual flow; harmonic mean flow; and annual and winter low-flow frequency. The annual 1-, 7-, and 30-day low- and high-flow data sets were tested for trends. The results of trend tests for high flows indicate relations between upward trends for high flows and stream regulation, and high flows and development in the basin. The relation between development and low-flow trends does not appear to be as strong as for development and high-flow trends. Monthly, seasonal, and annual precipitation data for selected long-term meteorological stations also were tested for trends to analyze the effects of climate. A significant upward trend in precipitation in northern New Jersey, Climate Division 1 was identified. For Climate Division 2, no general increase in average precipitation was observed. Trend test results indicate that high flows at undeveloped, unregulated sites have not been affected by the increase in average precipitation. The ratio of instantaneous peak flow to 3-day mean flow, ratios of flow duration, ratios of high-flow/low-flow frequency, and coefficient of variation were used to define streamflow variability. Streamflow variability was significantly greater among the group of gaging stations located outside the Coastal Plain than among the group of gaging stations located in the Coastal Plain.

Scientific Investigations Report↗

Nutrient Trends in Streams and Rivers of the United States, 1993-2003

Trends in streamflow and concentrations and loads of total phosphorus, total nitrogen, and nitrate were determined for the period from 1993 to 2003 in selected streams and ricers of the United States. Flow-adjusted trends in concentration (the trends that would have occurred in the absence of natural chances in streamflow), non-flow-adjusted trends in concentration (the trends resulting from both natural and human factors), and trends in load (trends in the nutrient mass transported downstream) were determined, and the results were examined spatially to determine whether a consistent pattern of trends occurred across groups of sites at multiple locations. Relations between the trends and changes in nutrient sources and streamflow are examined. See document for complete abstract.

Scientific Investigations Report↗

Analysis of Water-Quality Trends for Selected Streams in the Water Chemistry Monitoring Program, Michigan, 1998-2005

In 1998, the Michigan Department of Environmental Quality and the U.S. Geological Survey began a long-term monitoring program to evaluate the water quality of most watersheds in Michigan. Major goals of this Water-Chemistry Monitoring Program were to identify streams exceeding or not meeting State or Federal water-quality standards and to assess if constituent concentrations reflecting water quality in these streams were increasing or decreasing over time. As part of this program, water-quality data collected from 1998 to 2005 were analyzed to identify potential trends. Sixteen water-quality constituents were analyzed at 31 sites across Michigan, 28 of which had sufficient data to analyze for trends. Trend analysis on the various water-quality data was done using the uncensored Seasonal Kendall test within the computer program ESTREND. The most prevalent trend detected throughout the state was for chloride. Chloride trends were detected at 8 of the 28 sites; trends at 7 sites were increasing and the trend at 1 site was decreasing. Although no trends were detected for various nitrogen species or phosphorus, these constituents were detected at levels greater than the U.S. Environmental Protection Agency recommendations for nutrients in water. The results of the trend analysis will help to establish a baseline to evaluate future changes in water quality in Michigan streams.

Scientific Investigations Report↗

Trends in Water Quality in the Southeastern United States, 1973-2005

As part of the U.S. Geological Survey National Water-Quality Assessment Program, water-quality data for 334 streams in eight States of the Southeastern United States were assessed for trends from 1973 to 2005. Forty-four U.S. Geological Survey sites were examined for trends in pH, specific conductance, and dissolved oxygen, and in concentrations of dissolved solids, suspended sediment, chloride, sodium, sulfate, silica, potassium, dissolved organic carbon, total nitrogen, total ammonia, total ammonia plus organic nitrogen, dissolved nitrite plus nitrate, and total phosphorus. An additional 290 sites from the U.S. Environmental Protection Agency Storage and Retrieval database were tested for trends in total nitrogen and phosphorus concentrations for the 1975-2004 and 1993-2004 periods. The seasonal Kendall test or Tobit regression was used to detect trends. Concentrations of dissolved constituents have increased in the Southeast during the last 30 years. Specific conductance increased at 62 percent and decreased at 3 percent of the sites, and pH increased at 31 percent and decreased at 11 percent of the sites. Decreasing trends in total nitrogen were detected at 49 percent of the sites, and increasing trends were detected at 10 percent of the sites. Ammonia concentrations decreased at 27 percent of the sites and increased at 6 percent of the sites. Nitrite plus nitrate concentrations increased at 29 percent of the sites and decreased at 10 percent of the sites. These results indicate that the changes in stream nitrogen concentrations generally coincided with improved municipal wastewater-treatment methods. Long-term decreasing trends in total phosphorus were detected at 56 percent of the sites, and increasing trends were detected at 8 percent of the sites. Concentrations of phosphorus have decreased over the last 35 years, which coincided with phosphate-detergent bans and improvements in wastewater treatment that were implemented beginning in 1972. Multiple regression analysis indicated a relation between changes in atmospheric inputs and agricultural practices, and changes in water quality. A long-term water-quality and landscape trends-assessment network for the Southeast is needed to assess changes in water quality over time in response to variations in population, agricultural, wastewater, and landscape variables.

Scientific Investigations Report↗

Surface-Water Quality Conditions and Long-Term Trends at Selected Sites within the Ambient Water-Quality Monitoring Network in Missouri, Water Years 1993-2008

The U.S. Geological Survey, in cooperation with the Missouri Department of Natural Resources, collects data pertaining to the surface-water resources of Missouri. These data are collected as part of the Missouri Ambient Water-Quality Monitoring Network and constitute a valuable source of reliable, impartial, and timely information for developing an improved understanding of water resources in the State. Six sites from the Ambient Water-Quality Monitoring Network, with data available from the 1993 through 2008 water years, were chosen to compare water-quality conditions and long-term trends of dissolved oxygen, selected physical properties, total suspended solids, dissolved nitrate plus nitrite as nitrogen, total phosphorous, fecal indicator bacteria, and selected trace elements. The six sites used in the study were classified in groups corresponding to the physiography, main land use, and drainage basin size, and represent most stream types in Missouri. Long-term trends in this study were analyzed using flow-adjusted and non-flow adjusted models. Highly censored datasets (greater than 5 percent but less than 50 percent censored values) were not flow-adjusted. Trends that were detected can possibly be related to changes in agriculture or urban development within the drainage basins. Trends in nutrients were the most prevalent. Upward flow-adjusted trends in dissolved nitrate plus nitrite (as nitrogen) concentrations were identified at the Elk River site, and in total phosphorus concentrations at the South Fabius and Grand River sites. A downward flow-adjusted trend was identified in total phosphorus concentrations from Wilson Creek, the only urban site in the study. The downward trend in phosphorus possibly was related to a phosphorus reduction system that began operation in 2001 at a wastewater treatment plant upstream from the sampling site. Total suspended solids concentrations indicated an upward non-flow adjusted trend at the two northern sites (South Fabius and Grand Rivers). The increase in total suspended solids concentrations could be because of soil erosion from land cultivated for row crops. Most trace element data examined in the study were highly censored and could not be used for flow-adjusted trend analyses. Water-quality conditions were assessed to explore relations between data from sites and to the State water-quality standards where applicable for selected constituents. Streamflow varied at each site because of drainage area, land use, and groundwater inputs. Dissolved oxygen and water temperature were similar at all sites except the urban site located on Wilson Creek. Specific conductance was similar between the most northern (South Fabius and Grand River sites) and the most southern sites (Current and Elk River sites). Total suspended solids concentrations were near the method reporting level at all sites, except the northern sites. Streams in northern Missouri are more turbid than streams in southern Missouri and are affected by large volumes of sediment deposition because of soil erosion from land cultivated for row crops. Geometric means of Escherichia coli were calculated from the recreational seasons within the study period. Only the Grand River site exceeded the whole-body-contact standard for frequently used waters. The South Fabius and Grand River sites and the Wilson Creek site had statistically larger densities of both fecal indicator bacteria types than the remaining sites.

Scientific Investigations Report↗

Comparison of load estimation techniques and trend analysis for nitrogen, phosphorus, and suspended sediment in the Eucha-Spavinaw Basin, northwestern Arkansas and northeastern Oklahoma, 2002-10

The City of Tulsa, Oklahoma, uses water from Lake Eucha and Spavinaw Lake in the Eucha-Spavinaw basin of northwestern Arkansas and northeastern Oklahoma for public water supply. Increases in algal biomass, which cause taste and odor problems in drinking water produced from the lakes, may be attributable to increases in nitrogen and phosphorus concentrations in the lakes and in streams discharging to the lakes. To evaluate transport of nitrogen, phosphorus, and suspended sediment in this basin, loads and temporal trends were evaluated for five streamflow-gaging stations in the Spavinaw and Beaty Creek basins. Two approaches were used to develop regression equations for estimation of loads and yields of nitrogen, phosphorus, and sediment. The first approach used regression equations referred to as daily mean load (DM L ) regressions, developed from water-quality samples and daily mean streamflow data collected from 2002 through 2010 at five streamflow-gaging stations in the basin. This approach was updated to compare loading results with those used in previous investigations. The second approach used regression equations, referred to as instantaneous continuous (INST C ) regressions, developed from continuous measurements of physical water-quality constituents (specific conductance, temperature, and turbidity, and streamflow data) obtained from 2004 through 2010 to estimate loads of nitrogen, phosphorus, and sediment at two of the streamflow-gaging stations, Spavinaw Creek near Colcord, Okla., and Beaty Creek near Jay, Okla. Daily, annual, and mean annual loads estimated from these two regression methods were compared for the period 2005&ndash;10. Based on estimates obtained using DM L regressions, mean annual loads of 1,640,000 pounds of nitrogen, 99,900 pounds of phosphorus, and 116,000,000 pounds of sediment were transported into Lake Eucha from the Spavinaw and Beaty Creek basins. Estimated annual loads of nitrogen and phosphorus delivered to Lake Eucha from the Spavinaw and Beaty Creek basins during 2002&ndash;10 were 2.5 to 7.8 percent less, respectively, than the loads of those constituents discharged to Lake Eucha from 2002&ndash;09, indicating that nitrogen and phosphorus loads in 2010 were less than loads typical for the period 2002&ndash;09. Daily, annual, and mean annual load estimates varied substantially, depending on streamflow conditions and the independent variables used to develop regressions. Daily and annual loads estimated from INST C regressions that included turbidity, streamflow, temperature, specific conductance, and seasonality fit better with the field data than loads estimated from DM L regressions that included streamflow, seasonality, and time. Loads estimated from the INST C regression generally were greater than those estimated from the DM L regression. Relative percent differences in the mean annual total nitrogen load estimated by the INST C and DM L regressions were within 2 percent for Spavinaw Creek near Colcord, and Beaty Creek near Jay, Okla. The relative percent difference between the two types of regressions for estimates of mean annual total phosphorus loads at the two streamflow-gaging stations was 27.7 for Spavinaw Creek near Colcord, Okla., and only -2.6 percent for Beaty Creek near Jay, Okla. The relative percent difference between mean annual suspended-sediment loads at the streamflow-gaging stations was -38.6 percent for Spavinaw Creek near Colcord, Okla., and -122.7 percent for Beaty Creek near Jay, Okla. The DM L regression may have substantially underestimated phosphorus load at the Spavinaw Creek near Colcord, Okla., streamflow-gaging station in wet years and overestimated sediment load at both streamflow-gaging stations in wet years. Temporal trends in flow-adjusted nitrate-nitrogen, nitrogen, phosphorus, and suspended-sediment concentrations were analyzed for the five streamflow-gaging stations for the period 2001&ndash;10. No significant trends were observed for nitrate plus nitrite-nitrogen or total nitrogen concentrations at any streamflow-gaging station. There were significant upward trends in phosphorus concentrations in water samples collected during base-flow conditions at the Spavinaw Creek near Maysville, Okla., streamflow-gaging station and during runoff conditions for the Beaty Creek near Jay, Okla., streamflow-gaging station (3.5 to 4.2 percent per year). There were significant downward trends in phosphorus concentrations in base-flow and runoff samples collected at the Spavinaw Creek near Cherokee City, Sycamore, and Colcord, Okla., streamflow-gaging stations (-4.9 to -12.9 percent per year). There were significant downward trends in suspended-sediment concentration at the Spavinaw Creek near Maysville, and Sycamore, Okla., and the Beaty Creek near Jay, Okla., streamflow-gaging stations (-1.5 to -1.8 percent per year). No significant trends were detected in suspended-sediment concentration for the Spavinaw Creek near Cherokee City, and Colcord, Okla., streamflow-gaging stations. Possible causes for downward trends in phosphorus concentrations include decreases in phosphorus discharges from a wastewater-treatment plant upstream from the Spavinaw Creek near Cherokee City, Okla., streamflow-gaging station, and implementation of best management practices in the basin. Downward trends in sediment concentrations may be related to effects of best management practices in the basin.

Arkansas, Oklahoma↗

Trends in annual, seasonal, and monthly streamflow characteristics at 227 streamgages in the Missouri River watershed, water years 1960-2011

The Missouri River and its tributaries are an important resource that serve multiple uses including agriculture, energy, recreation, and municipal water supply. Understanding historical streamflow characteristics provides relevant guidance to adaptive management of these water resources. Streamflow records in the Missouri River watershed were examined for trends in time series of annual, seasonal, and monthly streamflow. A total of 227 streamgages having continuous observational records for water years 1960–2011 were examined. Kendall’s tau nonparametric test was used to determine statistical significance of trends in annual, seasonal, and monthly streamflow. A trend was considered statistically significant for a probability value less than or equal to 0.10 that the Kendall’s tau value equals zero. Significant trends in annual streamflow were indicated for 101 out of a total of 227 streamgages. The Missouri River watershed was divided into six watershed regions and trends within regions were examined. The western and the southern parts of the Missouri River watershed had downward trends in annual streamflow (56 streamgages), whereas the eastern part of the watershed had upward trends in streamflow (45 streamgages). Seasonal and monthly streamflow trends reflected prevailing annual streamflow trends within each watershed region.

Missouri River Watershed↗

Temporal trends in water-quality constituent concentrations and annual loads of chemical constituents in Michigan watersheds, 1998–2013

In 1998, the Michigan Department of Environmental Quality and the U.S. Geological Survey began the Water Chemistry Monitoring Program for select streams in the State of Michigan. Objectives of this program were to provide assistance with (1) statewide water-quality assessments, (2) the National Pollutant Discharge Elimination System permitting process, and (3) water-resource management decisions. As part of this program, water-quality data collected from 1998 to 2013 were analyzed to identify potential trends for select constituents that were sampled. Sixteen water-quality constituents were analyzed at 32 stations throughout Michigan. Trend analysis on the various water-quality data was done using either the uncensored Seasonal Kendall test or through Tobit regression. In total, 79 trends were detected in the constituents analyzed for 32 river stations sampled for the study period—53 downward trends and 26 upward trends were detected. The most prevalent trend detected throughout the State was for ammonia, with 11 downward trends and 1 upward trend estimated. In addition to trends, constituent loads were estimated for 31 stations from 2002 to 2013 for stations that were sampled 12 times per year. Loads were computed using the Autobeale load computation program, which used the Beale ratio estimator approach to estimate an annual load. Constituent loads were the largest in large watershed streams with the highest annual flows such as the Saginaw and Grand Rivers. Likewise, constituent loads were the smallest in smaller tributaries that were sampled as part of this program such as the Boardman and Thunder Bay Rivers.

Michigan↗