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The design of the Model V transmission fluorimeter

The transmission fluorimeter for the measurement of the fluorescence of uranium in fluoride melts is described. The instrument incorporates several improved features which have not been published previously. Unlike the earliest models, the design of the new fluorimeter, with its close machining of parts, reduces the possibility of light leakage and also increases considerably the ease with which the various components of the instrument may be assembled and adjusted. The Model V fluorimeter is a very rugged instrument with a compact arrangement of parts. It possess great flexibility so that various phototubes, measuring devices, light sources, and filter combinations may be used interchangeably. Detailed shop drawings are given for the construction of the fluorimeter.

Trace Elements Investigations

Short routine direct method for the fluorimetric determination of uranium in phosphate rocks

A short routine direct fluorimetric procedure for the determination of up to 0.06 percent uranium in phosphate ricks is described. The procedure employs a simple acid leach for preparing the solution, and the uranium is determined directly on a 1.8-mg aliquot. The results obtained by using this simply procedure on several thousand samples are discussed. The quenching of the uranium fluorescence by foreign elements was found to be negligible, for all practical purposes, and results on western phosphates may be corrected by using an empirically determined quenching factor.

Trace Elements Investigations

Non-pegmatitic resources of beryllium in United States

During the period from 1948 to 1950 the U.S. Geological Survey conducted a program of field and laboratory research w determine the mode of occurrence of beryllium in non-pegmatitic rocks and mineral deposits as part of the Beryllium Program of the Division of Raw Materials of the U.S. Atomic Energy Commission. Approximately 23 man months were spent in the field collecting samples from 146 localities in 15 states; a total of 680 samples were collected and analyzed for beryllium. Additional samples collected by the Geological Survey. U.S. Bureau of Mines, various state Geological Surveys and other institutions. and private companies were analyzed for beryllium. In total, the beryllium content of 1,238 samples from about 600 localities in the United States is compiled in the final report which is being prepared for publication by the U.S. Geological Survey. The main topics discussed are: uses and properties of beryllium; methods of analysis and mineralogy of beryllium; occurrence of beryllium in igneous, sedimentary and metamorphic rocks, pyrometasomatic and related deposits, vein deposits, and hot spring deposits; the genesis of beryllium deposits; and a description of the deposits examined. This abstract and table 1 summarize the more pertinent economic data. Beryllium is more abundant than arsenic, gold, silver, and molybdenum in the lithosphere, but its chemical and physical properties prohibit its concentration in minerals which are common w large commercial vein and replacement deposits. There are 29 minerals in which beryllium is an essential constituent but of these only beryl, mined from granite pegmatites, is an ore of beryllium., Beryl also occurs disseminated in granites and high-temperature veins. The other 28 minerals occur as rare constituents in syenite and granite pegmatites, granites, and pyrometasomatic deposits. Beryllium, as a trace constituent, has been detected in 49 minerals but recovery of the beryllium requires metallurgical methods as yet unknown.

Trace Elements Investigations

Geology of the Quartz Creek Pegmatite District, Gunnison County Colorado

The Quartz Creek pegmatite district includes an area about 29 square miles in the vicinity of Quartz Creek in Gunnison County,. Colo. This area contains 1,803 pegmatites that are intruded into pre-Cambrian rocks. The rocks exposed in the district range in age from pre-Cambrian to Recent. The oldest pre-Cambrian rocks are chiefly quartzites interbedded with a few arkoses and conglomerates. These rocks are surrounded by more abundant hornblende gneiss and tonalite. A small body of biotite tonalite was intruded and two thin layers of dacitic pillow lava were extruded into this series. The hornblende gneiss and tonalite have the same composition and differ only in texture. The older material (hornblende gneiss) has a well-marked lineation, whereas the younger (tonalite) is equigranular. Subsequently, a large body of quartz monzonite was intruded along the northern boundary of the mapped area. Later, coarse-grained granite was intruded into the southern part of the area. Dikes of fine-grained granite cut the coarse-grained variety. The last period of intrusive activity in pre-Cambrian time is marked by a large number of pegmatites. The pre-Cambrian rocks were tilted and eroded, and the flatlying Jurassic Morrison formation was deposited on the irregular surface. This formation is conformably overlain by the Cretaceous Dakota sandstone. Faulting produced a vertical offset of 410 feet in the Mesozoic sediments along the only large fault in the area. At the end of Mesozoic time there was another period of erosion. Tertiary (?) tuff is exposed in small, scattered areas in the southern part of the district. It overlies both the Dakota sandstone and pre-Cambrian formations. Glacial till occurs along the edges of Quartz Creek and Wood Gulch. Quaternary alluvium fills the valley bottoms. Although the composition of the country rock has little effect on the shape of the pegmatites, the foliation imposed on this rock has a localizing effect and in part controls the ultimate shape of pegmatites. Zoned and related internal structures are not well developed in the pegmatites of this region. Many of the pegmatites are homogeneous and those that are zoned usually contain a large wall zone and small discontinuous cores. In addition to the more common homogeneous and zoned pegmatites, 7 percent of the pegmatites show a layered structure of textural and mineralogical units not repeated on the opposite side of the pegmatite. Other internal structural units include pegmatites which vary in composition along strike, multiple or “line-rock pegmatites” and fracture fillings. The mineralogy of the pegmatites is described in detail. Specific attention was given to most of the 27 observed minerals. A study of the index of refraction of 439 specimens of plagioclase showed that the variation from zone to zone and layer to layer is minor and that there is no systematic variation in respect to the entire district. No correlation could be found between the refractive index of plagioclase in the pegmatites and the type country rock, or the presence of various accessory minerals. Index of refraction determinations on 95 specimens of muscovite showed no constant variation from wall zone to core or from layer to layer. Curved muscovite has identical optical properties with the flat variety. The index of refraction was determined for 189 beryl specimens. The beryl in the pegmatites containing only a wall zone and a core showed no difference between zones, but in pegmatites that have intermediate zones, the indices of refraction of the beryl showed an inward increase in the alkali content from the contact. Beryl occurs with almost all of the pegmatite minerals and is not restricted in its mineral associations. Tourmaline, except the black variety, is associated with lepidolite. Dark green and blue tourmaline is found in the outer zones of pegmatites containing lepidolite, and the pink and light green varieties are found in direct contact with lepidolite. Lepidolite occurs in aggregates of fine grains, in flat plates, and in curved plates; the three varieties are optically identical. The lighter-colored varieties have higher indices of refraction and contain less lithia than the darker varieties. In addition, the occurrence of the following minerals is described in detail: perthite, quartz, martite, biotite, garnet, columbite-tantalite, monazite, microlite, topaz, gahnite, allanite, and an unidentified mineral. The lack of alteration in the wall rocks adjacent to the pegmatites is interpreted as indicating that the original pegmatite magma did not have an excess of materials such as B, OH-, and P that are needed to form alteration minerals. Because of their low concentration, the above materials were available only in the pegmatitic magma during its crystallization. Pegmatites that contain the rare minerals such as beryl, tourmaline, curved muscovite, biotite, magnetite, monazite, columbite-tantalite, cleavelandite, topaz, lepidolite, and microlite show a grouping in clusters within the district. Beryl-bearing pegmatites occur most abundantly in hornblende gneiss and are only rarely found in either granite or quartz monzonite. The types of minerals that form in a pegmatite appear to be determined by the character of the material segregated from the original magma and the period in which it segregated. The elements escape at one period and may be from only-a specific pocket in the magma. These liquids tend to form groups of pegmatites in which the later bodies contain a high proportion of volatiles. Inferred reserves of the district are estimated for beryl, scrap mica, both hand-cobbing and milling feldspar, lepidolite, columbite-tantalite, topaz, monazite, and microlite. No sheet mica was found. Reserves are small and transportation costs are high so substantial production of low-priced feldspar and scrap mica will depend on the adoption of economica milling techniques for recovering the large quantities of feldspar available. Beryl is irregularly distributed and its recovery as a byproduct will depend on the establishment of a stable market for feldspar and scrap mica. Lepidolite reserves are small low grade.

Colorado

Pegmatites of the Crystal Mountain district, Larimer County, Colorado

The Front Range of Colorado is composed chiefly of schists of the pre-Cambrian Idaho Springs formation which have been intruded by a variety of granitic batholiths. In the Crystal Mountain district the Mount Olympus granite, a satellite of the Longs Peak batholith, forms sills and essentially concordant multiple intrusions in quartz-mica schist that dips southward at moderate to steep angles. A great number of pegmatites accompanied and followed the intrusion of the sills, and formed concordant and discordant bodies in schist and granite. Over 1,300 pegmatites in the Hyatt area north of the Big Thompson River are mapped and individually described. There are 27 pegmatites in the area that are made up of a wall zone and a core, and one, the pegmatite at the Hyatt mine, is composed of five zones. The largest pegmatites in the area are discordant in schist and occupy zones that are interpreted to be tear faults and tension fractures produced by the successive intrusions of granite that formed multiple sills. The majority of pegmatites in the large multiple sills were emplaced along the foliation and fractures. The composition of 96 percent of the pegmatites is granitic, 3.5 percent are quartz-rich pegmatites, and a few are tourmaline-rich. The pegmatites were intruded over a period of time and probably were derived from a granitic magma at different stages during differentiation. Solutions escaping from many of the pegmatites tournalinized and silicified the wall rocks for a few inches to two feet, but chemical and spectrographic analyses fail to show the transport of any other constituents. Perthite, plagioclase, and quartz are the essential minerals of the pegmatites, and muscovite is a minor but widespread constituent. Tourmaline, garnet, beryl, and apatite are common accessory minerals, and lithiophillitite-triphylite, bismuthinite, uraninite, columbite-tantalite, and chrysoberyl are rare constituents. Beryl is found in 250 or 27 percent of the pegmatites and makes up 0.01 percent or more of 77 bodies. The beryl-bearing pegmatites are richest in two of the three large granite masses, and are somewhat less rich at a distance of more than a thousand feet from the margins of the intrusives, but contain the least beryl in the thousand-foot belt immediately surrounding the intrusives. The Hyatt pegmatite is by far the richest deposit of beryl in the area mapped. Most of the pegmatites mapped are "unzoned" or homogeneous pegmatites. All gradations are visible between bodies consisting of uniform texture and mineral distribution to zoned pegmatites. The interpretation is made that, for most pegmatites, the initial composition determines whether or not zones will form. Pegmatites containing many zones can form from a magma composed of the elements in perthite, plagioclase, quartz, and muscovite, depending on the proportions of the components crystallizing at any given time. The complexly zoned deposits depend for their formation on the presence of a number of the rarer elements, principally lithium. Replacement textures in zones result from the interaction of the rest-liquid with the earlier-formed solid crystals. No mappable pegmatite in the Crystal Mountain district formed from the replacement of pre-existing pegmatite by solutions escaping from the rest-liquid, or by solutions originating outside the pegmatite. Three beryl-bearing zoned pegmatites, the Hyatt, Big Boulder, and Buckhorn Mica deposits, were explored by core drilling. Each deposit is mapped and described in detail, and the mineral reserves evaluated. The exploration indicates a total of 2,000 tons of beryl, of which 480 tons is estimated to be recoverable by hand sorting. The mapping of the 3 3/4-square mile Hyatt area indicates beryl in sufficient abundance to infer beryl resources of an additional 1,150 tons. Small tonnages of scrap mica and perthite may be obtained from the Hyatt and Big Boulder prospects, and columbite-tantalite may occur in sufficient amounts at the Buckhorn Mica mine and Tantalum claim to produce several hundred pounds as a byproduct of beryl mining. Dumps at the various deposits contain 25 to 50 tons of beryl.

Colorado

Carnotite resources of the upper group area, San Miguel County, Colorado

The Upper group area, which consists of 10 Government claims and adjoining public land, is 2 miles southeast of Slick Rock, San Miguel County, Colo., in unsurveyed secs. 5 and 6, T. 43 N., R. 18 W., New Mexico principal meridian. The area is equidistant from mills at Monticello, Utah, and Naturita, Colo. Both mills are reached by about 45 miles of all-weather roads. About 2,700 tons of carnotite ore was produced from the area between 1921 and 1943 (tons used in this report are short tons). This ore had an estimated average grade of 0.25 percent U30g and 1.7 percent V205. The ore deposits are in the top sandstone stratum of the Salt Wash sandstone member of the Tipper Jurassic Morrison formation. The principal ore-bearing minerals, which mainly impregnate the sandstone, consist of uranium-bearing carnotite and a micaceous vanadium-bearing mineral called “roscoelite." The deposits are mostly in small podlike masses called "rolls." The size of the rolls ranges from less than 50 to more than 1,500 tons each. The long axes of the rolls have a dominant northeasterly to easterly trend. Exploration by the Geological Survey was done on behalf of the Atomic Energy Commission to test unexplored ground for new deposits of carnotite ore and to gain a better appraisal of the reserves in the area. From 1948 to 1950, 186 diamond-drill holes were completed for a total of 14,577 feet. The areas of favorable sandstone were found and defined by holes drilled 300 to 500 feet apart. Altered mudstone, carbonaceous material in the sandstone, and color of the sandstone were used to determine the favorability of the sandstone. Within areas containing favorable sandstone holes were drilled on 100- to 150-foot centers to find deposits. Where deposits were found more than 20 feet below the surface, they were roughly outlined by holes drilled on 50- to 75- foot centers. Deposits discovered within 20 feet of the surface were not outlined. Reserves in deposits found by the drilling are classed as indicated and inferred, whereas those reserves that are predicted solely on geologic evidence are classed as potential. Indicated reserves computed at the highest thickness and grade cut-offs (1 foot or more thick and 0.10 percent U3O8 or .10 percent V205) total 5,000 tons, averaging 0.19 percent U308 and 1.6 percent V205. Inferred reserves computed at the same cut-offs total 3,500 tons, averaging .22 percent U308 and 1.7 percent V205. Both the indicated and inferred reserves, as well as the pounds of contained U3O8and V205, are summarized in table 1. Potential reserves are predicted to total about 1,500 tons, averaging about 0.20 percent U3O8 and 1.6 percent V205. Most of the potential reserves are expected to be in small scattered deposits within 20 feet of the surface. No additional diamond drilling by the Geological Survey is planned in the Upper group area. Several specific localities, principally in the central part of the area, are recommended for further exploration by jackhammer and wagon drilling by lessees and operators.

Colorado

Carnotite resources of the Calamity group area, Mesa County, Colorado

The Calamity group area, which includes 28 unpatented Government claims and enclosed fractions of public domain, lies along the east rim of Calamity Mesa, Mesa County, Colo. From 1915 through 1944, about 10,000 tons of carnotite ore, averaging about 1.0 percent U 3 O 8 and 2.5 percent V 2 O 5 , was produced from mines in this group (tons in this report are short tons). Production from this area from August 1949 to January 1, 1951, totaled 8,100 tons of ore with an average grade of 0.36 percent U 3 O 8 and 1.66 percent V 2 O 5 , containing about 58,600 pounds of U 3 O 8 and 268,000 pounds of V 2 O 5.

Colorado

Carnotite resources of Club Mesa, Montrose County, Colorado

Club Mesa is 1 mile west of Uravan, Montrose County, Colo. About 200,000 short tons of carnotite ore containing an estimated 0.45 percent U 3 O 8 and 2.1 percent V 2 O 5 has been mined from the mesa. This production represents about one-fifth of the carnotite ore mined from the Colorado Plateau. All the principal deposits on the mesa are in the main ore-bearing sandstone which is in the top part of the Salt Wash sandstone member of the Jurassic Morrison formation. The deposits are in tabular masses of uneven thickness lying more or less parallel to the enclosing strata. The ore consists mainly of sandstone impregnated with carnotite and vanadiferous clay minerals. The sandstone near the deposits is generally over 30 feet in thickness, contains noticeable quantities of carbon, and vivid patches of limonite (?) stain. Also near ore deposits, the mudstone in contact with the sandstone is altered from red to gray or green through a thickness of 3 or 4 feet. Certain linear features of the ore bodies and of favorable parts of the main ore-bearing sandstone offer clues by their orientation to extensions of known ore bodies and of favorable ground. These features on Club Mesa trend mostly east to northeast. Between March 6, 1948, and January 22, 1952, the U.S. Geological Survey drilled 651 holes for a total of 167,495 feet. As a result of this drilling, 18 deposits were discovered and partly outlined. These range in size from 200 to 55,000 short tons of indicated ore reserves and are in layers 1 foot or more thick containing 0.10 percent or more U 3 O 8 or 1.0 percent or more V 2 O 5 . About 85 percent of this ore is in public land; the remainder is in claims owned by the United States Vanadium Co. Reserves in deposits known from drill holes or exposures are classed as indicated or inferred, and those in deposits that are predicted solely on geologic evidence are classed as potential. The tons of indicated and inferred reserves and the pounds of contained U 3 O 8 and V 2 O 5 are summarized in table 1. These reserves are subdivided also by thickness and grade cutoffs. At the higher grade cutoff, reserve figures express approximately the tonnage and grade of material that might actually be mined from these deposits under 1951 conditions. Indicated and inferred reserves of this type total 198,000 short tons, averaging 0.35 percent U 3 O 8 and 1.8 percent V 2 O 5, and contain 1,1,372,000 pounds of U 3 O 8 and 7,260,000 pounds of V 2 O 5. These reserves are based on Geological Survey drilling. Potential reserves are predicted to total about 40,000 short tons, averaging about 0.35 percent U 3 O 8 and 1.9 percent V 2 O 5 . No additional exploration on Club Mesa is planned by the Geological Survey, but exploration by private companies is recommended.

Colorado