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Thermogenic hydrocarbons in unconsolidated sediment of Eel river basin, offshore northern California

Thermally produced hydrocarbons were recovered from unconsolidated sediment ponded within a bathymetric depression on the surface of a shale diapir in the offshore Eel River Basin of northern California. Evidence that the hydrocarbons are thermogenic consists of the following: (1) very high concentrations of hydrocarbon gases, particularly ethane through butanes (C 2 -C 4 ); (2) methane having a carbon isotopic composition (relative to the PDB standard) of −43 and −44 per mil; (3) presence of gasoline-range (C 5+ ) hydrocarbons; and (4) presence of a complex mixture of heavy hydrocarbons (C 15+ ) with n-alkanes having a petroleumlike distribution. This mixture of gaseous and liquid hydrocarbons likely originated deep within the basin and migrated to the surface through fractures and faults developed during the emplacement of the diapir. The presence of thermogenic hydrocarbons in unconsolidated surface sediment indicates that conditions for petroleum generation have existed within this offshore basin.

California

Water resources inventory of Connecticut Part 8: Quinnipiac River basin

The Quinnipiac River basin area in southcentral Connecticut covers 363 square miles, and includes all drainage basins that enter Long Island Sound from the Branford to the Wepawaug Rivers. Its population in 1970 was estimated at 535,000. Precipitation averages 47 inches per year and provides an abundant supply of water. Twenty-one inches returns to the atmosphere as evapotranspiration; the remainder flows directly to streams or percolates to the water table and discharges to Long Island Sound. Small amounts of water are exported from the basin by the New Britain Water Department, and small amounts are imported to the basin by the New Haven Water Company. The amount of water that can be developed at a given place depends upon precipitation, variability of streamflow, hydraulic properties and areal extent of the aquifers, and hydraulic connection between the aquifers and major streams. The quality of the water is determined by the physical environment and the effects of man. Stratified drift is the only aquifer capable of large sustained yields of water to individual wells. Yields of 64 screened wells tapping stratified drift range from 17 to 2,000 gpm (gallons per minute); their median yield is 500 gpm. Till is widespread and generally provides only small amounts of water. Wells in till normally yield only a few hundred gallons of water daily and commonly are inadequate during dry periods. Till is generally used only as an emergency or secondary source of water. Bedrock aquifers underlie the entire report area and include sedimentary, igneous, and metamorphic rock types. These aquifers supply small but reliable quantities of water to wells throughout the basin and are the chief source for many nonurban homes and farms. About 90 percent of the wells tapping bedrock yield at least 2 pgm, and much larger yields are occasionally reported. Maximum well yields of 305 gpm for sedimentary, 75 gpm for igneous, and 200 gpm for metamorphic bedrock have been reported. Water potentially available from stratified drift was estimated on the basis of hydraulic characteristics of the aquifers and evaluation of natural and induced recharge. Long-term yields estimated for 14 favorable areas of stratified drift range from 0.8 to 16.1 mgd (million gallons per day), but detailed verification studies are needed before development. The natural quality of water in the report area is good. The water is generally low in dissolved solid and is soft to moderately hard. Surface water is less mineralized than ground water, especially during high flow when it is primarily surface runoff. A median dissolved-solids concentration of 117 mg/l (milligrams per liter) and a median hardness of 58 mg/l was determined for water samples collected at 20 sites on 16 streams during high flow. A median dissolved-solids concentration of 146 mg/l and a median hardness of 82 mg/l was determined for samples collected at the same sites during low flow. In contrast water from 130 wells had a median dissolved-solids concentration of 188 mg/l and a median hardness of 110 mg/l. Iron and manganese occur in objectionable concentrations in parts of the report area, particularly in water from streams draining swamps and in water from aquifers rich in iron- and manganese-bearing minerals. Concentrations of iron in excess of 0.3 mg/l were found in 40 percent of the high-streamflow samples, 59 percent of the low-streamflow samples and 20 percent of the ground-water samples. Human activities have modified the quality of water in much of the basin. Wide and erratic fluctuations in concentration of dissolved solids in streams, high bacterial content of the Quinnipiac River, and locally high nitrate and chloride concentrations in ground water are evidence of man's influence. Streams, wetlands, and some aquifers along the southern boundary of the basin contain salty water. Overpumping has caused extensive saltwater intrusion in aquifers in the southern and eastern parts of New Haven. The total amount of fresh water used in the area during 1970 is estimated at 35,710 million gallons, or 183 gallons per day per capita. Public water-supply systems met the domestic requirements of about 90 percent of the population; all the systems supplied water that met the drinking water standards of the Connecticut Department of Health.

Connecticut

The Pre-Messinian Total Petroleum System of the Provence Basin, Western Mediterranean Sea

The Provence Basin is in that portion of the western Mediterranean Sea that is deeper than 2 kilometers. The basin lies essentially beyond the outer continental shelf, between the countries of France, Italy, and Algeria, the Balearic Islands, and the islands of Sardinia and Corsica. It encompasses nearly 300,000 square kilometers and includes the Rhone River submarine fan on the continental slope of southern France. It is province 4068 in the World Energy study. A single, hypothetical, total petroleum system (TPS), the Pre-Messinian TPS (406801), was described for the Provence Basin. The designation hypothetical is used because there is no hydrocarbon production from the basin. The Provence Basin is a deep-water Tertiary rift basin in which the geothermal gradients vary regionally. The Red Sea Basin shares a similar geologic and thermal history with the rifted western Mediterranean Sea and was used as an analog to better understand the genesis of the Provence Basin and as a guide to estimating possible undiscovered amounts of hydrocarbons. For this assessment the basin was given a potential, at the mean, for undiscovered resources of 51 trillion cubic feet (1.4 trillion cubic meters) gas, 0.42 billion barrels oil, and 2.23 million barrels natural gas liquids.

Bulletin

SHRIMP U-Pb dating of recurrent Cryogenian and Late Cambrian-Early Ordovician alkalic magmatism in central Idaho: Implications for Rodinian rift tectonics

Composite alkalic plutonic suites and tuffaceous diamictite, although discontinuously exposed across central Idaho in roof pendants and inliers within the Idaho batholith and Challis volcanic-plutonic complex, define the >200-km-long northwest-aligned Big Creek-Beaverhead belt. Sensitive highresolution ion microprobe (SHRIMP) U-Pb zircon dates on these igneous rocks provide direct evidence for the orientation and location of the Neoproterozoic-Paleozoic western Laurentian rift margin in the northern U.S. Cordillera. Dating delimits two discrete magmatic pulses at ca. 665-650 Ma and 500-485 Ma at the western and eastern ends, respectively, of this belt. Together with the nearby 685 Ma volcanic rocks of the Edwardsburg Formation, there is a 200 Ma history of recurrent extensional magmatic pulses along the belt. A similar history of recurrent uplift is reflected in the stratigraphic record of the associated miogeoclinal and cratonal platform basins, suggesting that the Big Creek-Beaverhead belt originated as a border fault during continental rift events. The magmatic belt is paired with the recurrently emergent Lemhi Arch and narrow miogeoclinal facies belts and it lies inboard of a northwest-striking narrow zone of thinned continental crust. These features define a northeast-extending upper-plate extensional system between southeast Washington and southeast Idaho that formed a segment of the Neoproterozoic-Paleozoic miogeocline. This segment was flanked on the north by the St. Mary-Moyie transform zone (south of a narrow southern Canadian upper-plate margin) and on the south by the Snake River transfer zone (north of a broad Great Basin lower-plate margin). These are the central segments of a zigzagshaped Cordilleran rift system of alternating northwest-striking extensional zones offset by northeast-striking transfers and transforms. The data substantiate polyphase rift and continental separation events that included (1) pre-and syn-Windermere rifting, (2) Windermere margin subsidence, (3) late Ediacaran-Cambrain rifting, and (4) welldeveloped late Ediacaran-Devonian passive margin subsidence and deposition. Timing and geometries support synchronous but opposing divergence along Cordilleran and Atlantic rifts with a junction in Southern California-Sonora. ?? 2010 Geological Society of America.

Geological Society of America Bulletin

Paleomagnetism and tectonic rotation of the lower Miocene Peach Springs Tuff: Colorado Plateau, Arizona, to Barstow, California

We have determined remanent magnetization directions of the lower Miocene Peach Springs Tuff at 41 localities in western Arizona and southeastern California. An unusual northeast and shallow magnetization direction confirms the proposed geologic correlation of isolated outcrops of the tuff from the Colorado Plateau to Barstow, California, a distance of 350 km. The Peach Springs Tuff was apparently emplaced as a single cooling unit about 18 or 19 Ma and is now exposed in 4 tectonic provinces west of the Plateau, including the Transition Zone, Basin and Range, Colorado River extensional corridor, and central Mojave Desert strike-slip zone. As such, the tuff is an ideal stratigraphic and structural marker for paleomagnetic assessment of regional variations in tectonic rotations about vertical axes. From 4 sites on the stable Colorado Plateau, we have determined a reference direction of remanent magnetization (I = 36.4°, D = 33.0°, α 95 = 3.4°) that we interpret as a representation of the ambient magnetic field at the time of eruption. A steeper direction of magnetization (I = 54.8°, D = 22.5°, α 95 = 2.3°) was observed at Kingman where the tuff is more than 100 m thick, and similar directions were determined at 7 other thick exposures of the Peach Springs Tuff. The steeper component is presumably a later-stage magnetization acquired after prolonged cooling of the ignimbrite. When compared to the Plateau reference direction, tilt-corrected directions from 3 of 6 sites in the central Mojave strike-slip zone show localized rotations up to 13° in the vicinity of strike-slip faults. The other three sites show no significant rotations with respect to the Colorado Plateau. Both clockwise and counterclockwise rotations were measured, and no systematic regional pattern is evident. Our results do not support kinematic models which require consistent rotation of large regions to accommodate the cumulative displacement of major post-middle Miocene strike-slip faults in the central Mojave Desert. Most of our sites in the Transition Zone and Basin and Range province have had no significant rotation, although small counterclockwise rotation in the McCullough and New York Mountains may be related to sinistral shear along en echelon faults southwest of the Lake Mead shear zone. The larger rotations occur in the Colorado River extensional corridor, where 8 of 14 sites show rotations ranging from 37° clockwise to 51° counterclockwise. These rotations occur in allochthonous tilt blocks which have been transported northeastward above the Chemehuevi-Whipple Mountains detachment fault. Upper-plate blocks within 1 km of the exposed detachment unexpectedly show no significant rotation. From this relation, we infer that rotations are accommodated along numerous low-angle faults at higher structural levels above the detachment surface.

Arizona, California

Hydrologic effects of climate change in the Delaware River basin

The Thornthwaite water balance and combinations of temperature and precipitation changes representing climate change were used to estimate changes in seasonal soil-moisture and runoff in the Delaware River basin. Winter warming may cause a greater proportion of precipitation in the northern part of the basin to fall as rain, which may increase winter runoff and decrease spring and summer runoff. Estimates of total annual runoff indicate that a 5 percent increase in precipitation would be needed to counteract runoff decreases resulting from a warming of 2??C; a 15 percent increase for a warming of 4??C. A warming of 2?? to 4??C, without precipitation increases, may cause a 9 to 25 percent decrease in runoff. The general circulation model derived changes in annual runoff ranged from -39 to +9 percent. Results generally agree with those obtained in studies elsewhere. The changes in runoff agree in direction but differ in magnitude. Additional aspects of the subject are discussed.

Water Resources Bulletin

Origin and structural implications of upper Miocene rhyolites in Kingston Canyon, Piute County, Utah

Kingston Canyon is one of the deepest antecedent canyons in the High Plateaus subprovince of the Colorado Plateaus. Here the East Fork of the Sevier River flows westward transversely across the gently east tilted Sevier Plateau, which is developed on a basin-range fault block uplifted more than 1,500 m along the Sevier fault zone on the west. Upper Tertiary rhyolites, uncommon in southwestern Utah, occur both on the northern rim and in the bottom of Kingston Canyon. Those on the northern rim consist of lava flows and volcanic domes of the rhyolite of Forshea Mountain, dated by K-Ar methods at 7.6 m.y. old. Those in the bottom of Kingston Canyon, the rhyolite of Phonolite Hill, are especially well exposed and provide spectacular examples of a pyroclastic cone whose base is about at river level and a steep-sided volcanic dome emplaced into and through these deposits. The pyroclastic deposits, formerly 500 or more metres thick, consist of airfall, mudflow, and ash-flow(?) material of rhyolite and foreign lithic fragments, especially olivine basalt. The dome consists of flow-banded, mostly devitrified rhyolite as much as 500 m thick; it has been dated by K-Ar methods at 5.4 m.y. In addition to the rhyolites, a dome and lava-flow complex, the rhyodacite of Dry Lake, occurs near the northern rim and is considered to postdate the rhyolite of Forshea Mountain and predate the rhyolite of Phonolite Hill. The rhyolite of Forshea Mountain was deposited near basin-range faults, before the uplift of the Sevier Plateau and before the cutting of Kingston Canyon. Before uplift, a river flowed across the site of the present Sevier Plateau toward the east-southeast and perhaps also across the Awapa and Aquarius Plateaus to the east. The rhyodacite of Dry Lake was deposited during uplift and perhaps before canyon cutting. During uplift, the river maintained itself and cut Kingston Canyon. The rhyolite of Phonolite Hill was deposited in this canyon, blocking the river flow, which probably formed new outlets to the east. The Awapa and Aquarius Plateaus later were uplifted along faults, disrupting the eastern part of the river segment. The topography then took on its present appearance, and drainage was re-established through Kingston Canyon. There has been little deepening since the reopening of Kingston Canyon.

Utah

Effect of the northward-migrating Mendocino triple junction on the Eel River forearc basin, California: Stratigraphic development

The Eel River forearc basin, northern California, lies at the southern end of the Cascadia subduction zone and at the leading edge of the migrating Mendocino triple junction. Stratigraphic relationships within the Eel River forearc basin suggest that the current outer-arc high formed between ca. 3 and 2 Ma when the margin switched from a nonaccretionary to an accretionary phase and then uplifted to attain critical taper. Between ca. 2 and 1 Ma, an influx of sedimentation from the ancestral Klamath and Eel River systems increased the width of the northern California margin and caused continued uplift followed by widespread erosion of the western margin of the basin at ca. 1 Ma. In the northeastern part of the forearc basin, localized erosion of the shelf occurred at ca. 500 ka. The arrival of the northward-migrating Mendocino triple junction at ca. 500 ka is documented by uplift, northward tilting, erosion of the margin as much as 20 km north of Cape Mendocino, and reduced deposition within the forearc basin as much as 80 km north of the current position of the triple junction. Terrestrial sediments delivered to the continental margin and eroded sediments near the triple junction largely bypassed the southern part of the basin and were likely deposited in northern areas of the basin or flowed down the Eel Canyon to be deposited within the Gorda Fan.

California

The Glaciation of the Yellowstone Valley North of the Park

The local glaciers of Quaternary times, of which evidences abound throughout the highest portions of the Rocky mountain cordillera, attained an unusually extensive development in that broad elevated region known as the Yellowstone Park. It was indeed the center of a considerable ice sheet whose glaciers spread out and down the valleys leading from this mountain region in all directions. In the northern part of the park two streams of ice found an outlet for their united flow northward down the valley of the Yellowstone, and they have left impressive memorials of the power and size of this stream that at once attract the attention of the observant traveler on the way to the famous geyser basins of the park. The number and size of the erratic bowlders scattered so abundantly over the valley floor and perched high up on the mountain slopes, can not fail to impress the beholder, while the second canyon of the Yellowstone, known as Yankee Jim canyon, through which the river has cut its way to the broad mountain encircled lower valley, is a grand and perfect piece of ice sculpture that affords striking proof of the power and magnitude of the glacier which once filled the valley. While studying and mapping the geology of a portion of the country north of the Yellowstone Park, under the direction of Mr. Arnold Hague, and for the United States Geological Survey, I found a long desired opportunity to study the glaciation of this interesting region.

Bulletin

Forestry practices and aquatic biodiversity: Fish

In the Pacific Northwest, fish communities are found in a diverse array of aquatic habitats ranging from the large coastal rivers of the temperate rainforests, to the fragmented and sometimes ephemeral streams of the xeric interior basins, and high-elevation streams and lakes in the mountainous areas (Rieman et al. 2003). Only high-elevation lakes and streams isolated above barriers to fish passage remained historically devoid of fish because they were never invaded following Pleistocene glaciation (Smith 1981). Despite this widespread distribution and once great population abundances, taxonomic diversity of fishes in these forested systems is naturally lower than in aquatic habitats in the eastern U.S. (Reeves, Bisson, and Dambacher 1998). Interactions among factors that influence species richness in aquatic systems (e.g., basin size, long-term stability of habitat, and barriers to colonization; Smith 1981) continue to influence the occurrence and persistence of fishes in these systems today. Consequently, the larger low-elevation rivers and estuaries support the greatest variety of fish species. In the high-elevation tributary streams, fish communities are less complex because these aquatic systems were less climatically and geologically stable, and fish populations were smaller and more prone to local extirpation. Furthermore, barriers to fish passage inhibited dispersal and colonization (Smith 1981). Streams in forested landscapes generally support salmon and trout, Oncorhynchus spp., whitefish Prosopium spp., sculpins Cottus spp., suckers Catostomus spp., and minnows (Cyprinidae), but in some of the colder streams, chars (e.g., Salvelinus confluentus and Salvelinus malma ) and lampreys (Petromyzontidae)may also occur (Rieman et al. 2003). Although biodiversity defined in terms of fish species richness is low in the Pacific Northwest, intraspecific variability is high, and polytypic fish species are common in the diverse aquatic habitats of the region. For example, the salmonids in the coastal rivers and streams, and the larger interconnected streams, rivers, and lakes of the interior exhibit a variety of ecotypes and migratory life histories (Healey 1986; Trotter 1989; Larson and McIntire 1993; Northcote 1997). This life-history variation appears to be associated with adaptation to spatial and temporal variation in environment (e.g., Schaffer and Elson 1975; Carl and Healey 1984; Beacham and Murray 1987), and there is some evidence of the genetic heritability of life-history traits (Carl and Healey 1984; Gharrett and Smoker 1993; Hankin, Nicholas, and Downey 1993). Persistence of any level of biological organization (e.g., life-history type, population, metapopulation, subspecies, species, community) is related to the interaction of environmental and biological components, and intraspecific diversity is a means of spreading risk ( sensu den Boer 1968) of extirpation in dynamic environments (Gresswell 1999). Unfortunately, despite the broad distribution and extensive intraspecific diversity, persistence of native fishes is uncertain in the Pacific Northwest. Many populations of anadromous salmonids, once synonymous with vigorous biological communities throughout the region, are threatened with extinction (Nehlsen, Williams, and Lichatowich 1991; Frissell 1993; Thurow, Lee, and Rieman 1997). Furthermore, over half of the native taxa in the Columbia River Basin are either listed under the Endangered Species Act, are being considered for listing, or are deemed sensitive by the management agencies (Lee et al. 1997; Thurow, Lee, and Rieman 1997). Potamodromous species like bull trout Salvelinus confluentus are estimated to occur as strong populations in less than 5% of their potential range (Rieman, Lee, and Thurow 1997). Although not currently listed under the endangered species list, the coastal cutthroat trout Oncorhynchus clarki is managed as a sensitive species in Oregon and California (Hall, Bisson, and Gresswell 1997). Native non-game fishes have rarely been monitored, but populations of species such as large-scale suckers ( Catostomus macrocheilus ), squawfish ( Ptychocheilus umpquae ), and Pacific lamprey ( Lampetra tridentata ) also are declining in some drainages (Oregon Department of Fish and Wildlife, unpublished data).

Pacific Northwest

Drainage reversals in Mono Basin during the late pliocene and Pleistocene

Mono Basin, on the eastern flank of the central Sierra Nevada, is the highest of the large hydrographically closed basins in the Basin and Range province. We use geomorphic features, shoreline deposits, and basalt-filled paleochannels to reconstruct an early to middle Pleistocene record of shorelines and changing spillways of Lake Russell in Mono Basin. During this period of time, Lake Russell repeatedly attained altitudes between 2205 and 2280 m-levels far above the present surface of Mono Lake (~1950 m) and above its last overflow level (2188 m). The spill point of Lake Russell shifted through time owing to late Tertiary and Quaternary faulting and volcanism. During the early Pleistocene, the lake periodically discharged through the Mount Hicks spillway on the northeastern rim of Mono Basin and flowed northward into the Walker Lake drainage basin via the East Walker River. Paleochannels recording such discharge were incised prior to 1.6 Ma, possibly between 1.6 and 1.3 Ma, and again after 1.3 Ma (ages of basaltic flows that plugged the paleochannels). Faulting in the Adobe Hills on the southeastern margin of the basin eventually lowered the rim in this area to below the altitude of the Mount Hicks spillway. Twice after 0.76 Ma, and possibly as late as after 0.1 Ma, Lake Russell discharged southward through the Adobe Hills spillway into the Owens-Death Valley system of lakes. This study supports a pre-Pleistocene aquatic connection through Mono Basin between the hydrologically distinct Lahontan and Owens-Death Valley systems, as long postulated by biologists, and also confirms a probable link during the Pleistocene for species adapted to travel upstream in fast-flowing water.

Geological Society of America Bulletin

River channel change with time : An example

Monumented channel cross sections were resurveyed over a period of 20 yrs (1953 to 1972) to determine the amount and kind of change of channel area and position on a 3.7-sq-mi basin, Watts Branch near Rockville, Maryland. For the first 12 yrs, the channel progressively but slowly became smaller as urbanization of the basin gradually proceeded. After 1966, a threshold of change apparently was passed and, probably as a result of an increased rate of land alteration upstream, large amounts of sediment were deposited within the channel and overbank. The number of floods exceeding channel capacity increased dramatically from an average of two to more than ten per year. Simultaneously, the channel area began to increase. Despite the trend toward increasing cross-sectional area, the net result after 20 yrs was a channel smaller by 20 percent than it had been originally. Urbanization did not alter the rate of channel migration.

Maryland

Sensitivity of northern Sierra Nevada streamflow to climate change

The sensitivity of streamflow to climate change was investigated in the American, Carson, and Truckee River Basins, California and Nevada. Nine gaging stations were used to represent streamflow in the basins. Annual models were developed by regressing 1961-1991 streamflow data on temperature and precipitation. Climate-change scenarios were used as inputs to the models to determine streamflow sensitivities. Climate-change scenarios were generated from historical time series by modifying mean temperatures by a range of +4??C to -4??C and total precipitation by a range of +25 percent to -25 percent. Results show that streamflow on the warmer, lower west side of the Sierra Nevada generally is more sensitive to temperature and percipitation changes than is streamflow on the colder, higher east side. A 2??C rise in temperature and a 25-percent decrease in precipitation results in streamflow decreases of 56 percent on the American River and 25 percent on the Carson River. A 2??C decline in temperature and a 25-percent increase in precipitation results in streamflow increases of 102 percent on the American River and 22 percent on the Carson River.

Water Resources Bulletin

Covariation of climate and long-term erosion rates acrossa steep rainfall gradient on the Hawaiian island of Kaua'i

Erosion of volcanic ocean islands creates dramatic landscapes, modulates Earth’s carbon cycle, and delivers sediment to coasts and reefs. Because many volcanic islands have large climate gradients and minimal variations in lithology and tectonic history, they are excellent natural laboratories for studying climatic effects on the evolution of topography. Despite concerns that modern sediment fluxes to island coasts may exceed long-term fluxes, little is known about how erosion rates and processes vary across island interiors, how erosion rates are influenced by the strong climate gradients on many islands, and how modern island erosion rates compare to long-term rates. Here, we present new measurements of erosion rates over 5 yr to 5 m.y. timescales on the Hawaiian island of Kaua‘i, across which mean annual precipitation ranges from 0.5 to 9.5 m/yr. Eroded rock volumes from basins across Kaua‘i indicate that million-year-scale erosion rates are correlated with modern mean annual precipitation and range from 8 to 335 t km –2 yr –1 . In Kaua‘i’s Hanalei River basin, 3 He concentrations in detrital olivines imply millennial-scale erosion rates of >126 to >390 t km –2 yr –1 from olivine-bearing hillslopes, while fluvial suspended sediment fluxes measured from 2004 to 2009 plus estimates of chemical and bed-load fluxes imply basin-averaged erosion rates of 545 ± 128 t km –2 yr –1 . Mapping of landslide scars in satellite imagery of the Hanalei basin from 2004 and 2010 implies landslide-driven erosion rates of 30–47 t km –2 yr –1 . These measurements imply that modern erosion rates in the Hanalei basin are no more than 2.3 ± 0.6 times faster than millennial-scale erosion rates, and, to the extent that modern precipitation patterns resemble long-term patterns, they are consistent with a link between precipitation rates and long-term erosion rates.

Hawai'i

Factors affecting herbicide yields in the Chesapeake Bay watershed, June 1994

Median concentrations and instantaneous yields of alachlor, metolachlor, atrazine, cyanazine, and simazine were generally highest at sites in the Lower Susquehanna River Basin and in agricultural subbasins. Instantaneous herbicide yields are related to land use, hydrogeologic setting, streamflow yield, and agricultural row cropping practices. The significance of these relations may be affected by the interdependence of the factors. The percentage of basin area planted in corn is the most influential factor in the prediction of herbicide yield. Instantaneous yields of all five herbicides measured in June 1994 related poorly to averaged 199094 herbicide use. Annually averaged herbicide-use data are too general to use as a predictor for short-term herbicide yields. An evaluation of factors affecting herbicide yields could be refined with more-current land use and land cover information and a more accurate estimate of the percentage of basin area planted in corn. Factors related to herbicide yields can be used to predict herbicide yields in other basins within the Chesapeake Bay watershed and to develop an estimate of herbicide loads to Chesapeake Bay.Median concentrations and instantaneous yields of alachlor, metolachlor, atrazine, cyanazine, and simazine were generally highest at sites in the Lower Susquehanna River Basin and in agricultural subbasins. Instantaneous herbicide yields are related to land use, hydrogeologic setting, streamflow yield, and agricultural row cropping practices. The significance of these relations may be affected by the interdependence of the factors. The percentage of basin area planted in corn is the most influential factor in the prediction of herbicide yield. Instantaneous yields of all five herbicides measured in June 1994 related poorly to averaged 1990-94 herbicide use. Annually averaged herbicide-use data are too general to use as a predictor for short-term herbicide yields. An evaluation of factors affecting herbicide yields could be refined with more-current land use and land cover information and a more accurate estimate of the percentage of basin area planted in corn. Factors related to herbicide yields can be used to predict herbicide yields in other basins within the Chesapeake Bay watershed and to develop an estimate of herbicide loads to Chesapeake Bay.

Water Resources Bulletin

Long-term intermittent connection between the western Snake River Plain and Columbia basin: A two-phased incision history of Hells Canyon

For more than a century, researchers have debated the route of the Snake River across the northern Cordillera and U.S. Pacific Northwest, including the associated incision history of Hells Canyon. Here, we use detrital zircon U-Pb provenance analysis of Miocene strata upstream and downstream of Hells Canyon to constrain the evolution in fluvial pathways over time. Downstream of Hells Canyon, we show that the ca. 10−6 Ma Clarkston Heights gravel was dominantly sourced from the nearby Salmon and Clearwater rivers but also with substantial input from drainages that now flow into the western Snake River Plain. These same western Snake River Plain drainages were contributing to time-equivalent Lake Idaho strata, upstream of Hells Canyon, indicating a Hells Canyon fluvial connection between the western Snake River Plain and Columbia basin before 6 Ma. Results from Lake Idaho strata suggest a two-phased lacustrine history in the western Snake River Plain: Before ca. 6.0 Ma, lake strata were derived from local tributaries, suggesting that the western Snake River Plain was isolated from the modern upper Snake River system. Between ca. 4.3 Ma and 2.2 Ma, the source area expanded to include eastern tributaries in conjunction with migration of high-standing topography of the Yellowstone hotspot. Our results challenge the long-held hypothesis of “capture” of the Snake River through Hells Canyon. Instead, we infer that Hells Canyon was a long-established route for outflow of lakes occupying the western Snake River Plain, possibly intermittently, during a ca. 10−2 Ma phase of slow regional incision, followed by rapid incision in Hells Canyon starting ca. 2 Ma in conjunction with erosion of the topographic barrier impounding Lake Idaho.

Idaho, Oregon

Water resources inventory of Connecticut Part 5: lower Housatonic River basin

The 557 square miles of the lower Housatonic River basin in western Connecticut include the basins of two major tributaries, the Pomperaug and Naugatuck Rivers. Nearly all water is derived from precipitation, which averaged 47 inches per year during 1931-60, In this period an additional 570 billion gallons of water per year entered the basin in the main stem of the Housatonic River at Lake Lillinonah, and some water was imported by water-supply systems from outside the basin. Almost half the precipitation--21.6 inches--was lost from the basin by evapotranspiration. Except for small amounts exported, the remainder discharged as runoff and underflow into Long Island Sound. Variations in streamflow at 6 long-term continuous-record gaging stations are summarized in standardized graphs and tables that can be used to estimate streamflow characteristics at other sites. For example, mean flow and two low-flow characteristics, the 7-day annual minimum flow for 2-year and 10-year recurrence intervals, have been determined for many partial-record stations throughout the basin. Of the 37 principal lakes, ponds, and reservoirs in the basin, 6 have usable storage of more than 1 billion gallons. The “maximum safe draft rate” (described in: “Storage of Water in Lakes and Reservoirs”) of the largest of these, Thomaston Reservoir near Thomaston, is 75.6 million gallons per day for the 10-year and 20-year recurrence intervals of annual lowest mean flow. Floods have occurred during every month, at one time or another. The two greatest floods on the Naugatuck River in historical time occurred 2 months apart in 1955. The larger, in August, had a peak of 106,000 cfs (cubic feet per second) at Beacon Falls. Since then, the likelihood of major floods has been considerably reduced by a program of flood control in the basin. Water can be obtained from three aquifers under-lying the basin-stratified drift, till, and bedrock. Stratified drift covers about 16 percent of the basin, mostly in valleys and lowlands, and its saturated part generally ranges in thickness from 10 feet in small valleys to 200 feet in the Housatonic River valley. Its transmissivity ranges from 0 to 47,000 ft 2 /day (feet shared per day). Till, deposited directly by glacial ice, forms a widespread but discontinuous mantle over bedrock in most upland areas and extends beneath stratified drift in lowlands; it ranges in thickness from 0 to 200 feet. The median value of 31 published determinations of hydraulic conductivity of till in southern New England is 0.67 ft/day and ranges from 0.013 to 29 ft/day. Crystalline bedrock underlies most of the basin and is composed principally of granite, gneiss, and schist. Sedimentary volcanic bedrock underlies only the Pomperaug River basin. Regardless of rock type, water is obtained mostly from fractures. Streambed deposits are significant features of the hydrogeologic system because they affect the amount of water from streams and lakes that can be induced to infiltrate aquifers. Based on field tests, characteristic values of vertical hydraulic conductivity of streambed deposits are 0.40 ft/day for fine-grained deposits and 14 ft/day for gravelly deposits. Ground-water supplies generally range in yield from several millions of gallons per day from large well fields to 1 gpm (gallons per minute) from single wells. Large supplies, with yields of 100 gpm or more from individual wells, are most commonly obtained from stratified drift. Yields to be expected from screened wells tapping this aquifer can be calculated by use of a series of graphs in conjunction with estimates of transmissivity and aquifer thickness. The yields of 14 principal ground-water reservoirs are estimated from aquifer characteristics and also from the amount of water that can be obtained from aquifer storage, from interception or runoff, and from infiltration of streamflow at low-flow conditions, using a hypothetical well-field arrangement for each reservoir. It is assumed that induced infiltration is restricted to an amount equal to the 7-day annual minimum stream-flow for a 2-year recurrence interval. Yields range from 1.4 to 15 mgd (million gallons per day) during periods of no recharge, and from 2.0 to 17 mgd during recharge periods. Small to moderate water supplies can be obtained from any of the aquifers under suitable conditions. For example, data from 294 wells in the basin indicate that yields of a few gallons per minute can be obtained from bedrock at most sites. The likelihood of obtaining an adequate domestic supply is slightly greater in granite than in schist and also is greater where the overburden is stratified drift rather than till. Chemical analyses of precipitation samples collected monthly from five stations in the basin during a 9-month period in 1966 show that rainfall is acidic and that sulfate is the dominant anion, probably because of industrial fumes and smoke within and near the basin. Where unaffected by man’s activities, water in the basin is generally low in dissolved-solids concentration, is of the calcium magnesium bicarbonate type, and is soft to moderately hard. In general, streamflow is less mineralized than ground water, particularly when it consists largely of direct runoff. However, streamflow becomes more highly mineralized during low-flow conditions, when most of it consists of more highly mineralized water discharged from aquifers. The median value of dissolved-solids concentration of water at 22 stream sites was 51 mg/1 (milligrams per liter) during high flow, and 68 mg/1 during low flow within the study period. Iron and manganese occur naturally in objectionable concentrations in parts of the basin, particularly in streams draining swamps and in water from bedrock containing iron and manganese-bearing minerals. Man’s activities have degraded the quality of water in streams in much of the basin, except in the Pomperaug subbasin. In the Naugatuck River basin, the degradation in quality is shown by wide and erratic changes in dissolved-solids concentration, excessive amounts of certain trace elements, a low dissolved oxygen content, and abnormally high temperatures. Ground water is degraded principally by induced infiltration of stream water containing chemical wastes, by wastes stored on the ground and by effluents from septic tanks. Below its confluence with the Naugatuck River, much of the Housatonic River and adjoining marshes, wetlands, and aquifers contain salt water. Measurements of specific conductance during low-flow conditions in 1969 indicate that the dissolved-solids concentration of water in the estuary ranged from 210 mg/1 near Twomile Island to 20,000 mg/1 near Long Island Sound. The quantity and quality of water in the basin are satisfactory for a wide variety of uses, and, with suitable treatment, the water may be used for most purposes. In 1967, the total amount of water used in the basin was about 194 billion gallons. About 90 percent of this was used for industrial purposes, and 95 percent of the industrial water was obtained from surface-water sources. In the same year, 17 municipal and private water-supply systems supplied water of satisfactory quality to about three-fourths of the population.

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Water resources inventory of Connecticut Part 10: Lower Connecticut River basin

The lower Connecticut River basin study area in south-central Connecticut includes 639 square miles and is drained principally by the Connecticut River and by seven smaller streams that flow directly to Long Island Sound between the West River on the west and the Connecticut River on the east. The population in 1979 was estimated to be 210,380. Much of the industrial development and population centers are in the Mattabesset River basin in the northwestern part, and the largest water use is also in the Mattabesset River basin. Precipitation averages 47 inches per year and provides an abundant supply of water. About 20 inches returns to the atmosphere as evapotranspiration, and the remainder either flows directly to streams or percolates to the water table, eventually discharging to Long Island Sound. Small quantities of water are exported from the basin by the New Haven and Meridan Water Departments, and small quantities are imported by the New Britain Water Department and Metropolitan Direct Commission. Precipitation during 1931-60 resulted in an average annual runoff of 302 billion gallons. In inflow from the Connecticut River is added to the average annual runoff, the 4,370 billion gallon s per year is potentially available for water ue. The domestic, institutional, commercial, and industrial (other than cooling water) water use for 1970 was 7 billion gallons, which is only 3 percent of the total water used, whereas 97 percent of the total is cooling water for power plants. Approximately 60 percent of the 7 billion gallons is treated before being discharged back to the streams. The total amount of fresh water used during 1970 was estimated to be 256,000 million gallons (Mgal), of which 247,000 Mgal was used for cooling water at stream electric-generating plants. The quantity for domestic, commercial, industrial, and agricultural used was 9,000 Mgal, which was approximately 120 gallons a day per person. Public water systems providing 70 percent of these requirement and all the systems supplying water met the drinking water standards of the Connecticut General Assembly (1975). Till is widespread and generally provides only small amounts of water. Wells in till normally yield only a few hundred gallons of water daily and may be inadequate during dry periods. The thickness of of till ranges from 0 to 15 feet; a median thickness of 26 feet is estimated from information provided in drillers' logs of 467 wells penetrating underlying bedrock. The till is generally used only as an emergency or secondary source of water. Bedrock aquifers underlie the entire area and include sedimentary and crystalline (igneous and metamorphic) rock types. These aquifers supply small and usually reliable quantities of water to wells and are the chief source of water for many rural homes and farms., About 90 percent of the wells tapping bedrock yield at least 2 gal/min. The median yields from wells tapping aquifers in sedimentary, igneous, and metamorphic rocks are 11, 8, and 6.5 gal/min, respectively. The quantity of water potentially available from stratified drift was estimated on the basis of hydraulic characteristics of the aquifers, mathematical modeling of the aquifer system, and evaluation of natural and induced recharge. Long-term yields estimated or ten areas underlain by significant thickness of stratified drift range from 0.4 to 4.4 million gallons per day (Mgal/d). A change in well spacing or numbering could increase the long-term yields, but detailed modeling verification studies are needed to confirm optimal well locations. The chemical and physical (turbidity, color, taste, and sediment load) quality of water is good. The water if generally low in dissolved solids and is classified as soft to hard. Surface water is less mineralized than ground water, especially during high flow, when it is primarily derived from surface runoff rather than groundwater runoff. A median dissolved-solids concentration of 42 milligrams per liter (mg/L) and median hardness of 18 mg/L were determined from water samples collected from 26 streams during the high-flow period. During the low-flow period, median dissolved-solids concentration of 61 mg/L and median hardness of 27 mg/L were determined from sample from the same streams. The quality of water in stratified-drift and crystalline-rock aquifers is generally better than that in the sedimentary-rock aquifers. Water from 32 wells tapping stratified drift had median dissolved-solids concentrations of 116 mg/L; and 33 wells tapping stratified drift and 42 tapping crystalline rock had median hardness of 73 mg/L and 68 mg/L, respectively. Water from 32 wells tapping sedimentary rock had median dissolved concentrations of 231 and 156 mg/L, respectively. Sedimentary rock generally yields the hardest water. Iron and manganese occur objectionable concentrations in places, particularly in water from streams draining swamps and in water from aquifers either rich in iron and manganese-nearing minerals or where the reducing environment for solution of these minerals is favorable. Concentrations of iron in excess of 0.3 mg/L were found in 35 percent of the high streamflow samples, and in 45 percent of the ground-water samples. Most of the high iron and manganese concentration in streams and aquifers are found east of the Connecticut River. Human activities and tidal influence along the coast have modified the quality of water in much f the study area. The greatest influence from human activities has been in the northwestern part, in the Mattabesset River basin. There, the quality of water has been affected by domestic and animal wastes, which cause high dissolved-solids concentrations, high nitrate and phosphate loads and high bacterial counts. In the entire area, high nitrate in groundwater occur only locally, and its presence in an individual water supply is chiefly a function of its proximity to sources of contamination, of well construction, and of thickness of overburden. Thirty public-supply wells did have water that had high sodium concentrations or objectionable iron and manganese concentrations, but these are not considered health hazards in the concentrations found in the water samples. Streams, wetlands, and some aquifers along the sough boundary of the basin contain salty water because of tidal movement or extensive ground-water withdrawals. High sediment concentrations also occur as a result of tidal influence in this area.

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