Geologic map of the Clarion River Roadless Area, Elk County, Pennsylvania
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The Shenango and Stoneboro 15-minute quadrangles are in northwestern Pennsylvania and are about 60 miles north of Pitts burgh. These two quadrangles comprise the following 7%-minute quadrangles: Greenville West, Greenville East, Sharpsville, Fredonia, Hadley, New Lebanon, Jackson Center, and Sandy Lake. The area covered by the two quadrangles includes the northern two thirds of Mercer County and a small amount of adjoining southern Crawford County.
The U.S. Geological Survey, in cooperation with the U.S. Department of Agriculture and Pennsylvania Department of Environmental Protection, investigated the effects of agricultural best-management practices on water quality in the Conestoga River headwaters watershed. This report describes environmental factors and the surface-water and ground-water quality of one 47.5-acre field site, Field-Site 2, from October 1984 through September 1986, prior to implementation of nutrient management. The site is partially terraced agricultural cropland underlain by carbonate rock. Twenty-seven acres are terraced, pipe-drained, and are under no-till cultivation. The remaining acreage is under minimum-till cultivation. Corn is the primary crop. The average annual rate of fertilization at the site was 480 pounds per acre of nitrogen and 110 pounds per acre of phosphorus. An unconfined limestone and dolomitic aquifer underlies the site, Depth to bedrock ranges from 5 to 30 feet below land surface. Estimated specific yields range from 0.05 to 0.10, specific capacities of wells range from less than 1 to about 20 gallons per minute per foot of drawdown, and estimates of transmissivities range from 10 to 10,000 square feet per day. Average ground-water recharge was estimated to be about 23 inches per year. The specific capacity and transmissivity data indicate that two aquifer regimes are present at the site. Wells drilled into dolomites in the eastern part of the site have larger specific capacities (averaging 20 gallons per minute per foot of drawdown) relative to specific capacities (averaging less than 1 gallon per minute per foot of drawdown) of wells drilled into limestones in the western part of the site. Median concentrations of soil-soluble nitrate and soluble phosphorus in the top 4 feet of silt- or silty-clay-loam soil ranged from 177 to 329 and 8.5 to 35 pounds per acre, respectively. Measured runoff from the pipe-drained terraces ranged from 10 to 48,000 cubic feet and was 1.7 and 0.8 percent, respectively, of the 1985 and 1986 annual precipitation. An estimated 90,700 cubic feet of surface runoff carried 87 pounds to total nitrogen and 37 pounds of total phosphorus, or less that 0.65 percent of the amount of either nutrient applied during the study period. Rainfall on the snow-covered, frozen ground produced more that half of the runoff and nitrogen and phosphorus loads measured in pipe-drained runoff. Graphical and regression analyses of surface runoff suggest that (1) mean-storm concentrations of total nitrogen species and total phosphorus decreased with increasing time between a runoff event and the last previous nutrient application, and (2) mean total-phosphorus concentrations approached a baseline value (estimated at 2 to 5 milligrams per liter for total-phosphorus concentrations) after several months without nutrient applications. Dissolved nitrate concentrations in ground water in wells unaffected by an on-site ammonia spill ranged from 7.4 to 100 milligrams per liter. Average annual additions and removals of nitrogen were estimated. Nitrogen was added to the site by applications of manure and commercial fertilizer nitrogen, as well as by precipitation and ground water entering across the western site boundary. These sources of nitrogen accounted for 95, 3, 1, and 1 percent, respectively, of estimated additions. Nitrogen was removed from the site in harvested crops, by ground-water discharge, by volatilization, and in surface runoff, which accounted for 42, 28, 29, and less than 1 percent, respectively, of estimated removals.
The U.S. Geological Survey, in cooperation with the Susquehanna River Basin Commission and the Pennsylvania Department of Environmental Resources, investigated the effects of agricultural best-management practices on surface-water quality as part of the U.S. Environmental Protection Agency's Chesapeake Bay Program. This report characterizes a 0.63-square- mile agricultural watershed underlain by shale, mudstone, and red arkosic sandstone in the Lower Susquehanna River Basin. The water quality of the Brush Run Creek site was studied from October 1985 through September 1991, prior to and during the implementation of nutrient management designed to reduce sediment and nutrient discharges into Conewago Creek, a tributary to the Chesapeake Bay. The original study area was 0.38 square mile and included an area immediately upstream from a manure lagoon. The study area was increased to 0.63 square mile in the fall of 1987 after an extensive tile-drain network was discovered upstream and downstream from the established streamflow gage, and the farm owner made plans to spray irrigate manure to the downstream fields. Land use for about 64 percent of the 0.63 square mile watershed is cropland, 14 percent is pasture, 7 percent is forest, and the remaining 15 percent is yards, buildings, water, or gardens. About 73 percent of the cropland was used to produce corn during the study. The average annual animal population consisted of 57,000 chickens, 1,530 hogs, and 15 sheep during the study. About 59,340 pounds of nitrogen and 13,710 pounds of phosphorus were applied as manure and commercial fertilizer to fields within the subbasin during the 3-year period prior to implementation of nutrient management. During nutrient management, about 14 percent less nitrogen and 57 percent less phosphorus were applied as commercial and manure fertilizer. Precipitation totaled 209 inches, or 13 percent less than the long-term normal, during the 6-year study. Concentrations of total ammonia in precipitation were as high as 2.7 mg/L (milligrams per liter); in dry deposition the concentrations were as high as 5.4 mg/L, probably because of the ammonia that had volatilized from the manure-storage lagoon. Nitrate nitrogen in the upper 4 feet of the soil ranged from 17 to 452 pounds per acre and soluble phosphorus content ranged from 0.29 to 65 pounds per acre. The maximum concentration of total nitrogen was 2,400 mg/L on September 10, 1986, in discharge from the tile drain near the streamflow gage. Median concentrations of total nitrogen and dissolved nitrite plus nitrate in base flow at the water-quality gage were 14 mg/L and 4.4 mg/L, respectively; prior to nutrient management and during nutrient management, median concentrations were 14 mg/L and 6.2 mg/L, respectively. Significant reductions in total phosphorus and suspended-sediment concentrations occurred at the water-quality gage. The maximum concentrations of total phosphorus (160 mg/L) and suspended sediment (3,530 mg/L) were measured at a tile line above the water-quality gage. Concentrations of total nitrogen, dissolved ammonia, and total phosphorus in base flow increased during dry periods when discharges from the tile drain were not diluted. During nutrient management, only base-flow loads of suspended sediment increased. Total streamflow was about 121.8 inches. About 81 percent was storm runoff. Loads of total nitrogen, total phosphorus in stormflow, and suspended sediment increased 14, 44, and 41 percent during nutrient management, respectively. A load of about 787,780 pounds of sediment, 22,418 pounds of nitrogen, and 5,479 pounds of phosphorus was measured during 214 sampled stormflow days that represented 84 percent of the stormflow. About 812,924 pounds of sediment, 38,421 pounds of nitrogen, and 6,377 pounds of phosphorus were discharged during the 6-year study.
This report presents environmental and quality-control data from analyses of 15 pharmaceutical and 31 antibiotic compounds in water samples from streams and wells in south-central Pennsylvania. The analyses are part of a study by the U.S. Geological Survey (USGS) in cooperation with the Pennsylvania Department of Environmental Protection (PADEP) to define concentrations of selected emerging contaminants in streams and well water in Pennsylvania. Sampling was conducted at 11 stream sites and at 6 wells in 9 counties of south-central Pennsylvania. Five of the streams received municipal wastewater and 6 of the streams received runoff from agricultural areas dominated by animal-feeding operations. For all 11 streams, samples were collected at locations upstream and downstream of the municipal effluents or animal-feeding operations. All six wells were in agricultural settings. A total of 120 environmental samples and 21 quality-control samples were analyzed for the study. Samples were collected at each site in March/April, May, July, and September 2006 to obtain information on changes in concentration that could be related to seasonal use of compounds. For streams, 13 pharmaceuticals and 11 antibiotics were detected at least 1 time. Detections included analytical results that were estimated or above the minimum reporting limits. Seventy-eight percent of all detections were analyzed in samples collected downstream from municipal-wastewater effluents. For streams receiving wastewater effluents, the pharmaceuticals caffeine and para-xanthine (a degradation product of caffeine) had the greatest concentrations, 4.75 μg/L (micrograms per liter) and 0.853 μg/L, respectively. Other pharmaceuticals and their respective maximum concentrations were carbamazepine (0.516 μg/L) and ibuprofen (0.277 μg/L). For streams receiving wastewater effluents, the antibiotic azithromycin had the greatest concentration (1.65 μg/L), followed by sulfamethoxazole (1.34 μg/L), ofloxacin (0.329 μg/L), and trimethoprim (0.256 μg/L). For streams receiving runoff from animal-feeding operations, the only pharmaceuticals detected were acetaminophen, caffeine, cotinine, diphenhydramine, and carbamazepine. The maximum concentration for pharmaceuticals was 0.053 μg/L. Three streams receiving runoff from animal-feeding operations had detections of one or more antibiotic compound--oxytetracycline, sulfadimethoxine, sulfamethoxazole, and tylosin. The maximum concentration for antibiotics was 0.157 μg/L. The average number of compounds (pharmaceuticals and antibiotics) detected in sites downstream from animal-feeding operations was three. The average number of compounds detected downstream from municipal-wastewater effluents was 13. For wells used to supply livestock, four compounds were detected--two pharmaceuticals (cotinine and diphenhydramine) and two antibiotics (tylosin and sulfamethoxazole). There were five detections in all the well samples. The maximum concentration detected in well water was for cotinine, estimated to be 0.024 μg/L. Seasonal occurrence of pharmaceutical and antibiotic compounds in stream water varied by compound and site type. At four stream sites, the same compounds were detected in all four seasonal samples. At other sites, pharmaceutical or antibiotic compounds were detected only one time in seasonal samples. Winter samples collected in streams receiving municipalwastewater effluent had the greatest number of compounds detected (21). Research analytical methods were used to determine concentrations for pharmaceuticals and antibiotics. To assist in evaluating the quality of the analyses, detailed information is presented on laboratory methodology and results from qualitycontrol samples. Quality-control data include results for nine blanks, nine duplicate environmental sample pairs, and three laboratory-spiked environmental samples as well as the recoveries of compounds in laboratory surrogates and laboratory reagent spikes.
In 1993, the U.S. Geological Survey operated 62 observation wells in 60 of Pennsylvania's 67 counties in cooperation with the Pennsylvania Department of Environmental Resources. These wells attempt to monitor an aerial extent of 45,000 square miles and penetrate 39 geologic formations or water-bearing units of 14 physiographic provinces. Some wells were drilled specifically for the observation-well program, some were drilled for other U.S. Geological Survey projects, and some were drilled for other purposes and were no longer used. Approximately 3 percent of the network wells have less than 5 years of record, 5 percent have 5 to 15 years of record, and 92 percent have greater than 15 years of record. The older the observation well, the greater the possibility of water levels being affected by physical deterioration of the borehole. Therefore, it is necessary to periodically conduct a series of physical, chemical, and hydraulic tests to determine changes in the physical condition of the well and local land-use practices that may affect water-level response. Nineteen wells were selected for evaluation on the basis of past questionable water-level responses. These wells were evaluated for functionality by analyzing historical water-level fluctuations, geophysical logs, single-well aquifer tests, and water-quality analyses. These parameters indicated that well Je-23 (Jefferson County) is affected by coal-mine pumpage, well Bt-311 (Butler County) is periodically affected by strip mine activities, well Gr-118 (Greene County) and Mc-110 (McKean County exhibit unexplained fluctuations not desirable for an observation well, and 15 wells show no obvious problems or degradation that would affect their functionality to monitor natural water-level fluctuations.
This report presents lithologic, hydrologic, and chemical data collected during a study of the ground-water resources of Warren County, Pa. The study was conducted during 1983-90 by the U.S. Geological Survey, in cooperation with the Pennsylvania Department of Conservation and Natural Resources, Bureau of Topographic and Geologic Survey, and the Warren County Commissioners. The data include information on aquifers, water levels, and yields for about 600 wells, and records for 57 springs. Descriptions of aquifer lithology and chemical analyses of water samples collected at well and spring sites are provided. Chemical analyses include major cations, anions, nutrients, and selected trace elements. Also included are data on concentrations of volatile organic compounds, dissolved methane, ethane, propane, and total organic carbon. The report presents a summary of the source and significance of selected chemical constituents in ground water, a listing of Federal drinking water standards, and information on selected methods of removing or reducing concentrations of undesirable chemical constituents from water. Daily ground- water levels for five observation wells are tabulated. Maps of Warren County show the location of townships, boroughs, and 7-1/2-minute quadrangles. Data-collection sites are shown on 18 figures. A glossary is provided for readers unfamiliar with ground-water terminology.
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The rocks seen in this segment of the field trip range in age from Middle Ordovician to Middle Devonian and constitute a deep basin-continental-shallow shelf succession. Within this succession, three lithotectonic units, or sequences of rock that were deformed semi-independently of each other, have somewhat different structural characteristics. Both the Alleghenian and Taconic orogenies have left their imprint on the rocks. Wind and water gaps are structurally controlled, thus placing doubt upon the hypothesis of regional superposition. Wisconsinan deposits and erosion effects are common. We will examine these geologic features as well as some of the economic deposits in the area. Figure 1 is an index map of the field-trip area, showing the trip route and quadrangle coverage. Figure 2 is a generalized geologic map,
Total coliform and Escherichia coli ( E. coli ) bacteria were analyzed in ground water sampled from 78 private household-supply wells as part of a study by the U.S. Geological Survey in cooperation with the Pennsylvania Department of Environmental Protection to evaluate the relation between well construction characteristics and the occurrence of bacteria in ground water. Sampling was done in eight counties in south-central and southeastern Pennsylvania from September 2000 to March 2001. All samples were collected from wells in close proximity to agricultural land-use areas. Total coliform bacteria were found in water from 62 percent (48 of 78) of the wells, and bacteria were just as likely to be found in sanitary wells (grouted/loose-fitting well cap or grouted/sanitary sealed well cap) as in nonsanitary wells (nongrouted/ loose-fitting well cap). The areas underlain by carbonate bedrock had the highest percentages of total coliform detected (about 75 percent). Nearly half of the samples collected in the areas underlain by noncarbonate bedrock also were found to have total coliform present. E. coli bacteria were found in water from 10 percent of the wells. Seventeen percent of the samples that were positive for total coliform also were positive for E. coli . The presence of E. coli bacteria was more likely in water from nonsanitary wells. Additionally, the presence of E. coli bacteria was more likely in ground water from wells underlain by carbonate bedrock. A further breakdown of the data into four groups on the basis of sanitary construction and bedrock type indicated the presence of E. coli was more likely in water from nonsanitary wells in areas underlain by carbonate bedrock. Statistical analysis of other well-construction characteristics that might relate to occurrence of bacteria showed that the presence of total coliform bacteria was related to the depth to water-bearing zone in both sanitary and nonsanitary wells in areas underlain by carbonate bedrock. Relations also are present between the presence of total coliform bacteria and casing length in nonsanitary wells in areas underlain by noncarbonate bedrock. Bacteria were found in wells both with and without insects observed on the underside of the well cap. Because of the small number of wells sampled that had sanitary sealed caps, it is uncertain whether installation of sanitary sealed well caps would reduce the incidence of bacteria in ground water from wells or if the presence of bacteria is because of a combination of well-construction characteristics or aquifer-wide contamination of limited or broad areal extent.