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At least 145 records · Page 8Linked to original sources

Hydrogeology, water quality, and saltwater intrusion in the Upper Floridan Aquifer in the offshore area near Hilton Head Island, South Carolina, and Tybee Island, Georgia, 1999-2002

To assess the hydrogeology, water quality, and the potential for saltwater intrusion in the offshore Upper Floridan aquifer, a scientific investigation was conducted near Tybee Island, Georgia, and Hilton Head Island, South Carolina. Four temporary wells were drilled at 7, 8, 10, and 15 miles to the northeast of Tybee Island, and one temporary well was drilled in Calibogue Sound west of Hilton Head Island. The Upper Floridan aquifer at the offshore and Calibogue sites includes the unconsolidated calcareous quartz sand, calcareous quartz sandstone, and sandy limestone of the Oligocene Lazaretto Creek and Tiger Leap Formations, and the limestone of the late Eocene Ocala Limestone and middle Avon Park Formation. At the 7-, 10-, and 15-mile sites, the upper confining unit between the Upper Floridan and surficial aquifers correlates to the Miocene Marks Head Formation. Paleochannel incisions have completely removed the upper confining unit at the Calibogue site and all but a 0.8-foot-thick interval of the confining unit at the 8-mile site, raising concern about the potential for saltwater intrusion through the paleochannel-fill sediments at these two sites. The paleochannel incisions at the Calibogue and 8-mile sites are filled with fine- and coarse-grained sediments, respectively. The hydrogeologic setting and the vertical hydraulic gradients at the 7- and 10-mile sites favored the absence of saltwater intrusion during predevelopment. After decades of onshore water use in Georgia and South Carolina, the 0-foot contour in the regional cone of depression of the Upper Floridan aquifer is estimated to have been at the general location of the 7- and 10-mile sites by the mid-1950s and at or past the 15-mile site by the 1980s. The upward vertical hydraulic gradient reversed, but the presence of more than 17 feet of upper confining unit impeded the downward movement of saltwater from the surficial aquifer to the Upper Floridan aquifer at the 7- and 10-mile sites. At the 10-mile site, the chloride concentration in the Upper Floridan borehole-water sample and the pore-water samples from the Oligocene and Eocene strata support the conclusion of no noticeable modern saltwater intrusion in the Upper Floridan aquifer. The chloride concentration of 370 milligrams per liter in the borehole-water sample at the 7-mile site from the Upper Floridan aquifer at 78 to 135 feet below North American Vertical Datum of 1988 is considerably higher than the chloride concentration of 25 milligrams per liter measured at the 10-mile site. The higher concentration probably is the result of downward leakage of saltwater through the confining unit at the 7-mile site or could reflect downward leakage of saltwater through an even thinner layer of the upper confining unit beneath the paleochannel to the northeast and lateral movement (encroachment) from the paleochannel to the 7-mile site. Carbon-14 concentrations at both sites, however, are low and indicate that most of the water is relict fresh ground water. The hydrogeology at the 15-mile site includes 17 feet of the upper confining unit. The chloride concentration in the Upper Floridan aquifer is 6,800 milligrams per liter. The setting for the Upper Floridan aquifer beneath the 15-mile site is interpreted as a transitional mixing zone between relict freshwater and relict saltwater. At the Calibogue site, 35 feet of fine-grained paleochannel-fill sediments overlies the Oligocene strata of the Upper Floridan aquifer. The vertical hydraulic conductivity of the paleochannel fill at this site is similar to the upper confining unit and effectively replaces the missing upper confining unit. Chloride concentrations and low carbon-14 and tritium concentrations in borehole water from the Upper Floridan aquifer, and low chloride concentrations in pore water from the upper confining unit indicate relict freshwater confined in the Upper Floridan aquifer at the Calibogue site. The coarse-grained paleochannel-f

Georgia, South Carolina

Summary of hydrologic testing in Tertiary limestone aquifer, Tenneco offshore exploratory well--Atlantic OCS, lease-block 427 (Jacksonville NH 17-5)

A summary of hydrologic testing in an offshore oil-test well (LB427) drilled for Tenneco, Inc., 55 miles east of Fernandina Beach, Florida, is presented. The interval tested (1,050 to 1,070 feet below sea level) is in a calcarenite that is equivalent to the Ocala Limestone (late Eocene) of onshore Florida and South Georgia. At this site the Ocala forms the highly productive Tertiary limestone aquifer system of the southeastern United States. Pressure-head measurements indicate an equivalent freshwater head of 24 to 29 feet above sea level. These pressure-head measurements and an earlier one made in the nearby JOIDES J- I hole are the only hydraulic head determinations to date in the offshore extensions of any of the aquifers underlying the Atlantic coastal plain. A drill-stem test recovered water samples containing about 7,000 milligrams per liter chloride. However, seawater used in the drilling process apparently contaminated the samples and the formation water is considered slightly fresher. The head and salinity data from the Tenneco well suggest that the sampled interval lies in the transition zone between fresh and seawater in the limestone aquifer. These data, when viewed with similar data from JOIDES J-I, show the transition zone to slope very slightly landward. The interface position is probably intermediate between a position compatible with present-day heads and a position compatible with predevelopment heads.

Water Supply Paper

Whole-body concentrations of elements in three fish species from offshore oil platforms and natural areas in the Southern California Bight, USA

There is concern that offshore oil platforms off Southern California may be contributing to environmental contaminants accumulated by marine fishes. To examine this possibility, 18 kelp bass (Paralabrax clathratus Girard, 1854), 80 kelp rockfish (Sebastes atrovirens Jordan and Gilbert, 1880), and 98 Pacific sanddab (Citharichthys sordidus Girard, 1854) were collected from five offshore oil platforms and 10 natural areas during 2005–2006 for whole-body analysis of 63 elements. Forty-two elements were excluded from statistical comparisons as they (1) consisted of major cations that were unlikely to accumulate to potentially toxic concentrations; (2) were not detected by the analytical procedures; or (3) were detected at concentrations too low to yield reliable quantitative measurements. The remaining 21 elements consisted of aluminum, arsenic, barium, cadmium, chromium, cobalt, copper, gallium, iron, lead, lithium, manganese, mercury, nickel, rubidium, selenium, strontium, tin, titanium, vanadium, and zinc. Statistical comparisons of these elements indicated that none consistently exhibited higher concentrations at oil platforms than at natural areas. However, the concentrations of copper, selenium, titanium, and vanadium in Pacific sanddab were unusual because small individuals exhibited either no differences between oil platforms and natural areas or significantly lower concentrations at oil platforms than at natural areas, whereas large individuals exhibited significantly higher concentrations at oil platforms than at natural areas.

California

Nature and distribution of potential heavy-mineral resources offshore of the Atlantic Coast of the United States.

The US is dependent on foreign imports of placer heavy minerals for a majority of its ilmenite and rutile, and virtually all of its monazite requirements. Although sand deposits in the SE US are important domestic sources of these heavy minerals (HM) and a number of other less well-known heavy-mineral species, global onshore reserves of placer minerals may fall short of demand in as few as 20 years. Insofar as they are important commodities for the future, offshore HM placers will become more important, but much research on them remains to be done. Results of recent offshore studies, based on surficial grab samples, indicate an average of about 2 weight percent HM in surficial Atlantic Continental Shelf (ACS) sediments, in strong contrast with previous estimates of an average of 0.16% HM. Although provocative, the information from these grab samples does not include the thickness of the HM deposits and thus their volume and tonnage cannot be estimated.-from Author

Marine Mining

Status and trends of the Lake Huron offshore demersal fish community, 1976-2012

The USGS Great Lakes Science Center has conducted trawl surveys to assess annual changes in the offshore demersal fish community of Lake Huron since 1973. Sample sites include five ports in U.S. waters with less frequent sampling near Goderich, Ontario. The 2012 fall bottom trawl survey was carried out between 20 October – 5 November 2012 and included all U.S. ports as well as Goderich, ON. The 2012 main basin prey fish biomass estimate for Lake Huron was 97 kilotonnes, higher than the estimate in 2011 (63.2 Kt), approximately one third of the maximum estimate in the time series, and nearly 6 times higher than the minimum estimate in 2009. The biomass estimates for adult alewife in 2012 were higher than 2011, but remained much lower than observed before the crash in 2004, and populations were dominated by small fish. Estimated biomass of rainbow smelt also increased and was the highest observed since 2005. Estimated adult bloater biomass in Lake Huron has been increasing in recent years, and the 2012 biomass estimate was the third highest ever observed in the survey. Biomass estimates for trout-perch and ninespine stickleback were higher than in 2011 but still remained low compared to historic estimates. The estimated biomass of deepwater and slimy sculpins increased over 2011, and slimy sculpin in particular seem to be increasing in abundance. The 2012 biomass estimate for round goby was similar to that in 2011 and was the highest observed in the survey. Substantial numbers of wild juvenile lake trout were captured again in 2012, suggesting that natural reproduction by lake trout continues to occur. The 2012 Lake Huron bottom trawl survey results suggest that several species of offshore demersal fish are beginning to increase in abundance.

Michigan

Distribution of regional pressure in the onshore and offshore Gulf of Mexico basin, USA

The U.S. Geological Survey (USGS) has created a comprehensive geopressure-gradient model of the regional pressure system spanning the onshore and offshore portions of the Gulf of Mexico, USA. The model was used to generate ten maps: five contour maps (Maps 1A - 5A) characterize the depth to the surface defined by the first occurrence of isopressure-gradients ranging from 0.60 psi/ft to 1.00 psi/ft, in 0.10-psi/ft increments, and five supporting maps (Maps 1B - 5B) display the spatial density of the data used to construct the isopressure-gradient maps. The boundary of the geopressure-gradient model represents the maximum extent of the calculated pressure-gradient data. The regional investigation, however, encompassed an area defined by the USGS Upper Jurassic-Cretaceous-Tertiary Composite Total Petroleum System Boundary, and the availability of offshore data. A description of the geopressure-gradient model, including related mathematical derivations, the data-quality control methodology, linear pressure interpolation calculations, and contouring algorithms is provided by Burke et al. (in press [a]; in press [b]); these references, as well as a summary of the geopressure-gradient model, are supplied in the online documentation .

Gulf of Mexico

Describing the distribution and productivity of biota along a nearshore to offshore gradient

The Lake Michigan Lakewide Action and Management Plan (LAMP) proposed adding nutrients (phosphorus) to its “pollutant of concern” list in 2002, given that excessive nutrients were causing impairments in nearshore waters. Since that time, scientists have highlighted the “shunting” of nutrients to the nearshore (Hecky et al. 2004), owing to the ability of invasive dreissenid mussels to capture some portion of allochthonous phosphorus that enters the lake through tributaries. These changes are believed to increase productivity in the nearshore, reflected in increased benthic and pelagic primary production and nuisance Cladophora (Auer et al. 2010). Whether increases in primary productivity lead to concomitant increases for secondary (by zooplankton) and tertiary (by fish) production remains largely untested. Hence, understanding the distribution and abundance of nutrients and biota (e.g., zooplankton, fish) across a nearshore to offshore gradient was identified as a Cooperative Science and Monitoring Initiative (CSMI) priority in 2015. Increased understanding of the Lake Michigan nearshore will also facilitate the development of a Nearshore Strategy by the LAMP, which is called for in the 2012 Great Lakes Water Quality Agreement. Working collaboratively with Environmental Protection Agency (EPA) and National Oceanic and Atmospheric Administration (NOAA), United States Geological Survey (USGS) described the distribution of nutrients and biota across nearshore to offshore transects in 2015 (see Appendix 1). At each transect, we sampled the food web at three sites with differing bottom depths: 18 m, 46 m, and 91-110 m. We purposefully chose transects near tributaries of varying total phosphorus (TP) input (see Figure 1, Dolan and Chapra 2012): three transects that were not associated with any large tributary where total phosphorus would be loaded (Waukegan IL, Frankfort MI, Sturgeon Bay WI), three transects adjacent to tributaries presumed to be relatively low loaders of TP (Pere Marquette MI, Root WI, Muskegon MI), and three transects adjacent to tributaries presumed to be relatively high loaders of TP (St. Joseph MI, Kalamazoo MI, Manitowoc WI). USGS estimated chlorophyll concentrations, zooplankton, Mysis , larval fish, and juvenile and adult fish seasonally (April/May, July, October/November) at eight of these transects (all but Muskegon).

Illinois, Michigan, Wisconsin

Synopsis of research programs that can provide baseline and monitoring information for offshore energy activities in the Pacific region: Seabird and marine mammal surveys in the Pacific region

We assembled and tabulated information about marine bird and mammal research and monitoring programs that could provide data needed to support environmental risk assessments. This included identifying ongoing or completed research programs that contain information on species and habitats sensitive to offshore energy activities and that could provide baseline and monitoring data to understand and mitigate potential impacts of offshore energy development in the Southern California Planning Area, Washington-Oregon Planning Area, and the Hawaiian OCS of the Bureau of Ocean Energy Management (BOEM). When available, we also included information regarding programs in Alaska, but the catalog for Alaska is not comprehensive. We included programs that assessed the distribution, abundance, or biology of marine birds (seabirds, waterbirds, or sea ducks) and marine mammals (cetaceans, pinnipeds, and sea otters), some of which are protected species under the Endangered Species Act (ESA of 1973) or the Marine Mammal Protection Act (MMPA of 1972). We canvassed data providers with spreadsheet or web-based survey forms. The marine bird survey returned information on research and monitoring efforts for 28 parameters across 46 species from 36 entities. The marine mammal survey returned information on research and monitoring efforts for 24 parameters across 22 marine mammal species from 22 entities. We tabulated the parameters by species to show which parameters are most commonly measured and where there might be information gaps. Both marine bird and marine mammal research and monitoring are widespread throughout the Pacific, with 535 entries for marine mammals and 1,911 entries for marine birds. Although we provide summaries of key aspects within research and monitoring programs, the associated database can be further queried in several ways. Versioning of this database format essentially creates a “living database” that can be updated in the future as new information becomes available.

California, Oregon, Washington

Synopsis of research programs that can provide baseline and monitoring information for offshore energy activities in the Pacific region: Seabird and marine mammal surveys in the Pacific region

We assembled and tabulated information about marine bird and mammal research and monitoring programs that could provide data needed to support environmental risk assessments. This included identifying ongoing or completed research programs that contain information on species and habitats sensitive to offshore energy activities and that could provide baseline and monitoring data to understand and mitigate potential impacts of offshore energy development in the Southern California Planning Area, Washington-Oregon Planning Area, and the Hawaiian OCS of the Bureau of Ocean Energy Management (BOEM). When available, we also included information regarding programs in Alaska, but the catalog for Alaska is not comprehensive. We included programs that assessed the distribution, abundance, or biology of marine birds (seabirds, waterbirds, or sea ducks) and marine mammals (cetaceans, pinnipeds, and sea otters), some of which are protected species under the Endangered Species Act (ESA of 1973) or the Marine Mammal Protection Act (MMPA of 1972). We canvassed data providers with spreadsheet or web-based survey forms. The marine bird survey returned information on research and monitoring efforts for 28 parameters across 46 species from 36 entities. The marine mammal survey returned information on research and monitoring efforts for 24 parameters across 22 marine mammal species from 22 entities. We tabulated the parameters by species to show which parameters are most commonly measured and where there might be information gaps. Both marine bird and marine mammal research and monitoring are widespread throughout the Pacific, with 535 entries for marine mammals and 1,911 entries for marine birds. Although we provide summaries of key aspects within research and monitoring programs, the associated database can be further queried in several ways. Versioning of this database format essentially creates a “living database” that can be updated in the future as new information becomes available.

Alaska, California, Hawaii, Oregon, Washington

The Palos Verdes Fault offshore southern California: late Pleistocene to present tectonic geomorphology, seascape evolution and slip rate estimate based on AUV and ROV surveys

The Palos Verdes Fault (PVF) is one of few active faults in Southern California that crosses the shoreline and can be studied using both terrestrial and subaqueous methodologies. To characterize the near-seafloor fault morphology, tectonic influences on continental slope sedimentary processes and late Pleistocene to present slip rate, a grid of high-resolution multibeam bathymetric data, and chirp subbottom profiles were acquired with an autonomous underwater vehicle (AUV) along the main trace of PVF in water depths between 250 and 600 m. Radiocarbon dates were obtained from vibracores collected using a remotely operated vehicle (ROV) and ship-based gravity cores. The PVF is expressed as a well-defined seafloor lineation marked by subtle along-strike bends. Right-stepping transtensional bends exert first-order control on sediment flow dynamics and the spatial distribution of Holocene depocenters; deformed strata within a small pull-apart basin record punctuated growth faulting associated with at least three Holocene surface ruptures. An upper (shallower) landslide scarp, a buried sedimentary mound, and a deeper scarp have been right-laterally offset across the PVF by 55 ± 5, 52 ± 4 , and 39 ± 8 m, respectively. The ages of the upper scarp and buried mound are approximately 31 ka; the age of the deeper scarp is bracketed to 17–24 ka. These three piercing points bracket the late Pleistocene to present slip rate to 1.3–2.8 mm/yr and provide a best estimate of 1.6–1.9 mm/yr. The deformation observed along the PVF is characteristic of strike-slip faulting and accounts for 20–30% of the total right-lateral slip budget accommodated offshore Southern California.

California

Observations of wave transformation over a fringing coral reef and the importance of low-frequency waves and offshore water levels to runup, overwash, and coastal flooding

Many low-lying tropical islands are susceptible to sea level rise and often subjected to overwash and flooding during large wave events. To quantify wave dynamics and wave-driven water levels on fringing coral reefs, a 5 month deployment of wave gauges and a current meter was conducted across two shore-normal transects on Roi-Namur Island in the Republic of the Marshall Islands. These observations captured two large wave events that had waves with maximum heights greater than 6 m with peak periods of 16 s over the fore reef. The larger event coincided with a peak spring tide, leading to energetic, highly skewed infragravity (0.04–0.004 Hz) and very low frequency (0.004–0.001 Hz) waves at the shoreline, which reached heights of 1.0 and 0.7 m, respectively. Water surface elevations, combined with wave runup, reached 3.7 m above the reef bed at the innermost reef flat adjacent to the toe of the beach, resulting in flooding of inland areas. This overwash occurred during a 3 h time window that coincided with high tide and maximum low-frequency reef flat wave heights. The relatively low-relief characteristics of this narrow reef flat may further drive shoreline amplification of low-frequency waves due to resonance modes. These results (1) demonstrate how the coupling of high offshore water levels with low-frequency reef flat wave energetics can lead to large impacts along fringing reef-lined shorelines, such as island overwash, and (2) lend support to the hypothesis that predicted higher sea levels will lead to more frequent occurrences of these extreme events, negatively impacting coastal resources and infrastructure.

Journal of Geophysical Research C: Oceans

Forage fish species prefer habitat within designated offshore wind energy areas on the US Northeast Shelf ecosystem

As the world develops sources of renewable energy, there is an intensifying interest in offshore wind energy production. The Northeast U.S. Continental Shelf (NES) ecosystem has favorable wind dynamics, with active development of wind energy. In this study, we present species distribution models that consider both occupancy and biomass responses for a broad spectrum of fish and macroinvertebrate taxa ( n = 177). Building upon prior analyses, habitat was differentiated into overall and core habitats based on statistical distributions of habitat scores. Overall habitat was used to show each species' regional distribution based on fishery-independent survey captures between 1976 and 2019, whereas core habitat represented where the focus of the species' abundance was located as a subset of overall habitat. Wind energy developments may modify the water column in ways that impact lower-trophic-level productivity; therefore, added attention was given to the response of forage species. Over 20% of species showed preferential use of putative and potential wind development areas, including a disproportionate number of forage taxa. Principal usage varied by season, with forage species like Atlantic Menhaden Brevoortia tyrannus and Atlantic Mackerel Scomber scombrus preferentially using the lease areas in spring and Round Herring Etrumeus teres and longfin inshore squid Doryteuthis pealeii using lease areas in autumn. For species with relatively low usage of the lease areas, there was a tendency for the usage related to overall habitat to be lower than usage for core habitat; in contrast, for species with high usage of the lease areas, that usage was higher for overall habitat than for core habitat. The area of habitat tended to have positive trends across species, with these positive trends being disproportionately higher among forage taxa. These results frame the importance of wind lease areas for species in the NES, particularly forage taxa that fulfill many important ecological functions.

Marine and Coastal Fisheries: Dynamics, Management

Gas hydrates from the continental slope, offshore Sakhalin Island, Okhotsk Sea

Ten gas-vent fields were discovered in the Okhotsk Sea on the northeast continental slope offshore from Sakhalin Island in water depths of 620-1040 m. At one vent field, estimated to be more than 250 m across, gas hydrates, containing mainly microbial methane (??13C = -64.3???), were recovered from subbottom depths of 0.3-1.2 m. The sediment, having lenses and bedded layers of gas hydrate, contained 30-40% hydrate per volume of wet sediment. Although gas hydrates were not recovered at other fields, geochemical and thermal measurements suggest that gas hydrates are present. ?? 1993 Springer-Verlag.

Geo-Marine Letters

Pockmark asymmetry and seafloor currents in the Santos Basin offshore Brazil

Pockmarks form by gas/fluid expulsion into the ocean and are preserved under conditions of negligible sedimentation. Ideally, they are circular at the seafloor and symmetrical in profile. Elliptical pockmarks are more enigmatic. They are associated with seafloor currents while asymmetry is connected to sedimentation patterns. This study examines these associations through morphological analysis of new multibeam data collected across the Santos continental slope offshore Brazil in 2011 (353–865 mbsl). Of 984 pockmarks, 78% are both elliptical and asymmetric. Geometric criteria divide the pockmarks into three depth ranges that correlate with a transition between two currents: the Brazil Current transfers Tropical Water and South Atlantic Central Water southwestwards while the Intermediate Western Boundary Current transfers Antarctic Intermediate Water northeastwards. It is suggested that the velocity of seafloor currents and their persistence dictate pockmark ellipticity, orientation and profile asymmetry. Fast currents (>20 cm/s) are capable of maintaining pockmark flank steepness close to the angle of repose. These morphological expressions present direct evidence for an edge effect of the South Atlantic Subtropical Gyre and, in general, provide a correlation between pockmark geometry and seafloor currents that can be applied at other locations worldwide.

Santos Basin

Velocity structure of a bottom simulating reflector offshore Peru: Results from full waveform inversion

Much of our knowledge of the worldwide distribution of submarine gas hydrates comes from seismic observations of Bottom Simulating Reflectors (BSRs). Full waveform inversion has proven to be a reliable technique for studying the fine structure of BSRs using the compressional wave velocity. We applied a non-linear full waveform inversion technique to a BSR at a location offshore Peru. We first determined the large-scale features of seismic velocity variations using a statistical inversion technique to maximise coherent energy along travel-time curves. These velocities were used for a starting velocity model for the full waveform inversion, which yielded a detailed velocity/depth model in the vicinity of the BSR. We found that the data are best fit by a model in which the BSR consists of a thin, low-velocity layer. The compressional wave velocity drops from 2.15 km/s down to an average of 1.70 km/s in an 18m thick interval, with a minimum velocity of 1.62 km/s in a 6 m interval. The resulting compressional wave velocity was used to estimate gas content in the sediments. Our results suggest that the low velocity layer is a 6-18 m thick zone containing a few percent of free gas in the pore space. The presence of the BSR coincides with a region of vertical uplift. Therefore, we suggest that gas at this BSR is formed by a dissociation of hydrates at the base of the hydrate stability zone due to uplift and subsequently a decrease in pressure.

Earth and Planetary Science Letters

Observations of gas hydrates in marine sediments, offshore northern California

Biogenic gas hydrates were recovered in shallow cores (< 6 m deep) from the Eel River basin in offshore northern California between 40°38′ and 40°56′N. The gas hydrates contained primarily methane ( δ 13 C = −57.6 to −69.1‰) and occurred as dispersed crystals, small (2–20 mm) nodules, and layered bands within the sediment. These hydrates, recovered in sediment at water depths between 510 and 642 m, coincide nearly, but not exactly, with areas showing bottom-simulating reflectors (BSRs) on seismic-reflection records. This study confirms indirect geophysical and geologic observations that gas hydrates are present north of the Mendocino Fracture Zone in sediment of the Eel River basin but probably are absent to the south in the Point Arena basin. This discovery extends the confirmed sites of gas hydrates in the eastern Pacific region beyond the Peruvian and Central American margins to the northern California margin.

Marine Geology

LITHOPROBE East onshore-offshore seismic refraction survey -constraints on interpretation of reflection data in the Newfoundland Appalachians

Combined onshore-offshore seismic refraction/ wide-angle reflection data have been acquired across Newfoundland, eastern Canada, to investigate the structural architecture of the northern Appalachians, particularly of distinct crustal zones recognized from earlier LITHOPROBE vertical incidence studies. A western crustal unit, correlated with the Grenville province of the Laurentian plate margin thins from 44 to 40 km and a portion of the lower crust becomes highly reflective with velocities of 7.2 km/s. In central Newfoundland, beneath the central mobile belt, the crust thins to 35 km or less and is marked by average continental velocities, not exceeding 7.0 km/s in the lower crust. Further east, in a crustal unit underlying the Avalon zone and associated with the Gondwanan plate margin, the crust is 40 km thick, and has velocities of 6.8 km/s in the lower crust. Explanations for the thin crust beneath the central mobile belt include (1) post-orogenic isostatic readjustment associated with a density in the mantle which is lower beneath this part of the orogen than beneath the margin, (2) mechanical thinning at the base of the crust during orogenic collapse perhaps caused by delamination, and (3) transformation by phase change of a gabbroic lower crust to eclogite which seismologically would be difficult to distinguish from mantle. Except for a single profile in western Newfoundland, velocities in the crust are of typical continental affinity with lower-crustal velocities less than 7.0 km/s. This indicates that there was no significant magmatic underplating under the Newfoundland Appalachians during Mesozoic rifting of the Atlantic Ocean as proposed elsewhere for the New England Appalachians. A mid-crustal velocity discontinuity observed in the Newfoundland region does not coincide with any consistent reflection pattern on vertical incidence profiles. However, we suggest that localized velocity heterogeneities at mid-crustal depths correspond to organized vertical incidence reflections.

Newfoundland Appalachians

Laboratory simulation of hydrothermal petroleum formation from sediment in Escanaba Trough, offshore from northern California

Petroleum associated with sulfide-rich sediment is present in Escanaba Trough at the southern end of the Gorda Ridge spreading axis offshore from northern California within the Exclusive Economic Zone (EEZ) of the U.S. This location and occurrence are important for evaluation of the mineral and energy resource potential of the seafloor under U.S. jurisdiction. In Escanaba Trough, petroleum is believed to be formed by hydrothermal processes acting on mainly terrigenous organic material in Quaternary, river-derived sediment. To attempt to simulate these processes in the laboratory, portions of a Pleistocene gray-green mud, obtained from ∼ 1.5 m below the seafloor at a water depth of ∼ 3250 m in Escanaba Trough, were heated in the presence of water in four hydrous-pyrolysis experiments conducted at temperatures ranging from 250 to 350°C and at a pressure of 350 bar for 1.0–4.5 days. Distributions of n -alkanes, isoprenoid hydrocarbons, triterpanes, and steranes in the heated samples were compared with those in a sample of hydrothermal petroleum from the same area. Mud samples heated for less than 4.5 days at less than 350°C show changes in some, but not all, molecular marker ratios of organic compounds that are consistent with those expected during hydrothermal petroleum formation. Our results suggest that the organic matter in this type of sediment serves as one possible source for some of the compounds found in the hydrothermal petroleum.

California