Search USGSSearch

SEARCH · Search USGS

Results for “Mine Water and the Environment”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 145 records · Page 8Linked to original sources

Potential for increased mercury accumulation in the estuary food web

Present concentrations of mercury in large portions of San Francisco Bay (Bay), the Sacramento-San Joaquin Delta (Delta), and the Sacramento and San Joaquin rivers are high enough to warrant concern for the health of humans and wildlife. Large scale tidal wetland restoration is currently under consideration as a means of increasing populations of fish species of concern. Tidal wetland restoration activities may lead to increased concentrations of mercury in the estuarine food web and exacerbate the existing mercury problem. This paper evaluates our present ability to predict the local and regional effects of restoration actions on mercury accumulation in aquatic food webs. A sport fish consumption advisory is in place for the Bay, and an advisory is under consideration for the Delta and lower Sacramento and San Joaquin rivers. Mercury concentrations in eggs of several water bird species from the Bay have exceeded the lowest observed effect level. A variety of mercury sources, largely related to historic mercury and gold mining, is present in the watershed and has created a spatially heterogeneous distribution of mercury in the Bay-Delta Estuary. Mercury exists in the environment in a variety of forms and has a complex biogeochemical cycle. The most hazardous form, methylmercury, is produced at a relatively high rate in wetlands and newly flooded aquatic habitats. It is likely that distinct spatial variation on multiple spatial scales exists in net methylmercury production in Bay-Delta tidal wetlands, including variation within each tidal wetland, among tidal wetlands in the same region, and among tidal wetlands in different regions. Understanding this spatial variation and its underlying causes will allow environmental managers to minimize the negative effects of mercury bioaccumulation as a result of restoration activities. Actions needed to reduce the uncertainty associated with this issue include a long term, multifaceted research effort, long term monitoring on local and regional scales, and careful evaluation of individual restoration projects with regard to potential increase of food web mercury.

California

Antimony recycling in the United States in 2000

The importance of recycling has become more obvious as concerns about the environment and import dependence have grown in recent years. When materials are recycled, fewer natural resources are consumed, and less waste products go to landfills or pollute the water and air. This study, one of a series of reports on metals recycling in 2000, discusses the flow of antimony from mining through its uses and disposal with emphasis on recycling. In 2000, the recycling efficiency for antimony was estimated to be 89 percent, and the recycling rate was about 20 percent.

Circular

Natural aggregates of the conterminous United States

Crushed stone and sand and gravel are the two main sources of natural aggregates. These materials are commonly used construction materials and frequently can be interchanged with one another. They are widely used throughout the United States, with every State except two producing crushed stone. Together they amount to about half the mining volume in the United States. Approximately 96 percent of sand and gravel and 77 percent of the crushed stone produced in the United States are used in the construction industry. Natural aggregates are widely distributed throughout the United States in a variety of geologic environments. Sand and gravel deposits commonly are the results of the weathering of bedrock and subsequent transportation and deposition of the material by water or ice (glaciers). As such, they commonly occur as river or stream deposits or in glaciated areas as glaciofluvial and other deposits. Crushed stone aggregates are derived from a wide variety of parent bedrock materials. Limestone and other carbonates account for approximately three quarters of the rocks used for crushed stone, with granite and other igneous rocks making up the bulk of the remainder. Limestone deposits are widespread throughout the Central and Eastern United States and are scattered in the West. Granites are widely distributed in the Eastern and Western United States, with few exposures in the Midwest. Igneous rocks (excluding granites) are largely concentrated in the Western United States and in a few isolated localities in the East. Even though natural aggregates are widely distributed throughout the United States, they are not universally available for consumptive use. Some areas are devoid of sand and gravel, and potential sources of crushed stone may be covered with sufficient unconsolidated material to make surface mining impractical. In some areas many aggregates do not meet the physical property requirements for certain uses, or they may contain mineral constituents that react adversely when used as concrete aggregate. In areas where suitable natural aggregate is not available or accessible, it may become necessary to improve the quality of existing aggregate, to import aggregate from outside the area, or to substitute artificial aggregate for natural aggregate. In most cases, all of these alternatives add substantially to the cost of the final product. Even though an area may be blessed with an abundance of aggregate suitable for the intended purpose, existing land uses, zoning, or regulations may preclude commercial exploitation of the aggregate. This report also discusses the aggregate industry in general terms, including exploration, mining, and processing, as well as aggregate production rates. Proper long-range planning based on an understanding of the aggregate industry can help assure adequate supplies of aggregate.

conterminous United States

Landscape geochemistry near mineralized areas of eastern Alaska: Chapter H in Recent U.S. Geological Survey studies in the Tintina Gold Province, Alaska, United States, and Yukon, Canada--results of a 5-year project

The Pogo lode gold deposit was discovered in eastern Alaska in the early 1990s and provided the opportunity to study elemental distribution and mobility in the natural environment prior to mine development. Studying mineralized systems prior to mining allows us to compare the natural biogeochemical signature in mineralized versus nonmineralized areas. The resultant data and interpretation also provide a baseline for evaluating what, if any, changes in elemental distribution result from development. This report investigates the chemistry of stream water, streambed sediment, and soil in the context of regional bedrock geology. The major-ion chemistry of the waters reflects a rock-dominated aqueous system, and the waters are classified as Ca 2+ and Mg 2+ - HCO 3 - to Ca 2+ and Mg 2+ - SO 4 -2 waters. Creeks draining the gneissic lithologies tend to be more sulfate dominated than those draining the intrusive units. Sulfate also dominated creeks draining mineralized areas; however, the underlying paragneiss unit could be contributing substantially to the sulfate concentration, and the sulfate concentration in these creeks may reflect a complex baltholith-paragneiss boundary rather than mineralization. Arsenic concentrations in bed sediments were elevated in mineralized areas relative to nonmineralized areas. Elevated concentrations of nickel, chromium, iron, manganese, and cobalt appear to reflect the presence of ultramafic rocks in the drainage. In general, aqueous metal concentrations were below the State of Alaska’s Aquatic Life Criteria and Drinking Water Standards, with the exception of arsenic in stream water, which ranged in concentration from less than 1 to 14 micrograms per liter (μg/L) and exceeded the drinking water standard at one site. The arsenic and antimony concentration in the A, B, and C soil horizons ranged from 3 to 410 milligrams per kilogram (mg/kg), 6.1 to 440 mg/kg, and 2 to 300 mg/kg, respectively, for arsenic and 0.4 to 24 mg/kg, 0.6 to 25 mg/kg, and 0.2 to 16 mg/kg, respectively, for antimony. The arsenic and antimony concentrations in stream waters correlate well with the concentrations in soils. However, significantly less arsenic and antimony was extracted from C horizon soils in water leaching experiments, indicating that the arsenic and antimony in the C horizon is present in a less available form than in the A or B horizons. Arsenic and antimony uptake by grayleaf willow (Salix glauca L.) appears minimal, with arsenic concentrations ranging from less than 0.01 to 0.14 mg/kg and antimony concentrations ranging from less than 0.003 to 0.23 mg/kg in willow leaves. In general, the highest concentrations of both arsenic and antimony in water and soils were found near mineralized areas. Elevated arsenic concentrations were also found in bed sediments from mineralized areas. In these sample matrices, the presence of arsenic and (or) antimony was a good indicator of contact with mineralized rock units.

Alaska;Yukon

Occurrence and transport of total mercury and methyl mercury in the Sacramento River Basin, California

Mercury poses a water-quality problem for California's Sacramento River, a large river with a mean annual discharge of over 650 m3/s. This river discharges into the San Francisco Bay, and numerous fish species of the bay and river contain mercury levels high enough to affect human health if consumed. Two possible sources of mercury are the mercury mines in the Coast Ranges and the gold mines in the Sierra Nevada. Mercury was once mined in the Coast Ranges, west of the Sacramento River, and used to process gold in the Sierra Nevada, east of the river. The mineralogy of the Coast Ranges mercury deposits is mainly cinnabar (HgS), but elemental mercury was used to process gold in the Sierra Nevada. Residual mercury from mineral processing in the Sierra Nevada is mainly in elemental form or in association with oxide particles or organic matter and is biologically available. Recent bed-sediment sampling, at sites below large reservoirs, showed elevated levels of total mercury (median concentration 0.28 ??g/g) in every large river (the Feather, Yuba, Bear, and American rivers) draining the Sierra Nevada gold region. Monthly sampling for mercury in unfiltered water shows relatively low concentrations during the nonrainy season in samples collected throughout the Sacramento River Basin, but significantly higher concentrations following storm-water runoff. Measured concentrations, following storm-water runoff, frequently exceeded the state of California standards for the protection of aquatic life. Results from the first year of a 2-year program of sampling for methyl mercury in unfiltered water showed similar median concentrations (0.1 ng/l) at all sampling locations, but with apparent high seasonal concentrations measured during autumn and winter. Methyl mercury concentrations were not significantly higher in rice field runoff water, even though rice production involves the creation of seasonal wetlands: higher rates of methylation are known to occur in stagnant wetland environments that have high dissolved carbon.Mercury poses a water-quality problem for California's Sacramento River, a large river with a mean annual discharge of over 650 m3/s. This river discharges into the San Francisco Bay, and numerous fish species of the bay and river contain mercury levels high enough to affect human health if consumed. Two possible sources of mercury are the mercury mines in the Coast Ranges and the gold mines in the Sierra Nevada. Mercury was once mined in the Coast Ranges, west of the Sacramento River, and used to process gold in the Sierra Nevada east of the river. The mineralogy of the Coast Ranges mercury deposits is mainly cinnabar (HgS), but elemental mercury was used to process gold in the Sierra Nevada. Residual mercury from mineral processing in the Sierra Nevada is mainly in elemental form or in association with oxide particles or organic matter and is biologically available. Recent bed-sediment sampling, at sites below large reservoirs, showed elevated levels of total mercury (median concentration 0.28 ??g/g) in every large river (the Feather, Yuba, Bear, and American rivers) draining the Sierra Nevada gold region. Monthly sampling for mercury in unfiltered water shows relatively low concentrations during the nonrainy season in samples collected throughout the Sacramento River Basin, but significantly higher concentrations following storm-water runoff. Measured concentrations, following storm-water runoff, frequently exceeded the state of California standards for the protection of aquatic life. Results from the first year of a 2-year program of sampling for methyl mercury in unfiltered water showed similar median concentrations (0.1 ng/l) at all sampling locations, but with apparent high seasonal concentrations measured during autumn and winter. Methyl mercury concentrations were not significantly higher in rice field runoff water, even though rice production involves the creation of seasonal wetlands: higher rates of methylation a

Journal of Geochemical Exploration

Aluminum mobility in mildly acidic mine drainage: Interactions between hydrobasaluminite, silica and trace metals from the nano to the meso-scale

Aluminum precipitates control the hydrochemistry and mineralogy of a broad variety of environments on Earth (e.g., acid mine drainage, AMD, coastal wetlands, boreal and alpine streams, tropical acid sulfate soils, laterites and bauxites, …). However, the geochemical and mineralogical processes controlling Al (and other associated metals and metalloids) transport and removal in those environments are not fully understood. The geochemical system of Paradise Portal (Colorado, USA) comprises sulfate-rich mildly acidic waters, the hydrochemistry of which is directly controlled by the massive precipitation of hydrobasaluminite Al 4 (SO 4 )(OH) 10 ·12-36H 2 O. Three connected but discernible aluminum precipitation stages were identified and described: 1) nanoparticle formation and size decrease along the creek, 2) hydrobasaluminite neoformation on the riverbed, and 3) precipitate accretion and accumulation on the riverbed leading to Al and Fe banded formations. The co-occurrence of Al and Si in the system was observed, recording significant amounts of Si accompanying the three different components of the system (i.e., nanoparticles and fresh and aged Al-precipitates). Also, abrupt and minor changes in the sedimentary record were described and proposed to be the response of the system to seasonal and interannual changes in AMD chemistry. Concerning the mobility of other metals and metalloids, P, Th, V, W, Ti and B showed a tendency to be preferentially incorporated into hydrobasaluminite, while others like Be, As, Se or Ba tend to remain dissolved in the water.

Chemical Geology

Dominance of 'Gallionella capsiferriformans' and heavy metal association with Gallionella -like stalks in metal-rich pH 6 mine water discharge

Heavy metal-contaminated, pH 6 mine water discharge created new streams and iron-rich terraces at a creek bank in a former uranium-mining area near Ronneburg, Germany. The transition from microoxic groundwater with ~5 m m Fe(II) to oxic surface water may provide a suitable habitat for microaerobic iron-oxidizing bacteria (FeOB). In this study, we investigated the potential contribution of these FeOB to iron oxidation and metal retention in this high-metal environment. We (i) identified and quantified FeOB in water and sediment at the outflow, terraces, and creek, (ii) studied the composition of biogenic iron oxides ( Gallionella -like twisted stalks) with scanning and transmission electron microscopy (SEM, TEM) as well as confocal laser scanning microscopy (CLSM), and (iii) examined the metal distribution in sediments. Using quantitative PCR, a very high abundance of FeOB was demonstrated at all sites over a 6-month study period. Gallionella spp. clearly dominated the communities, accounting for up to 88% of Bacteria , with a minor contribution of other FeOB such as Sideroxydans spp. and ‘ Ferrovum myxofaciens ’. Classical 16S rRNA gene cloning showed that 96% of the Gallionella -related sequences had ≥97% identity to the putatively metal-tolerant ‘ Gallionella capsiferriformans ES-2’, in addition to known stalk formers such as Gallionella ferruginea and Gallionellaceae strain R-1. Twisted stalks from glass slides incubated in water and sediment were composed of the Fe(III) oxyhydroxide ferrihydrite, as well as polysaccharides. SEM and scanning TEM-energy-dispersive X-ray spectroscopy revealed that stalk material contained Cu and Sn, demonstrating the association of heavy metals with biogenic iron oxides and the potential for metal retention by these stalks. Sequential extraction of sediments suggested that Cu (52–61% of total sediment Cu) and other heavy metals were primarily bound to the iron oxide fractions. These results show the importance of ‘ G. capsiferriformans ’ and biogenic iron oxides in slightly acidic but highly metal-contaminated freshwater environments.

Geobiology

Natural attenuation can lead to environmental resilience in mine environment

Four streams flowing in the Iglesiente and Arburese mine districts (SW Sardinia, Italy), exploited for zinc (Zn) and lead (Pb) extraction from sulphides and secondary non-sulphide mineralization (calamine ores), have been studied combining investigations from the macroscale (hydrologic tracer techniques) to the microscale (X-ray powder diffraction, scanning electron microscopy, X-ray absorption spectroscopy). In the investigated area, concerns arise from release of metals to water during weathering of ore minerals and mine-waste. Specifically, Zn is observed at extremely high concentrations (10s of mg/L or more) in waters in some of the investigated catchments. The results from synoptic sampling campaigns showed marked differences of Zn loads, from 6.3 kg/day (Rio San Giorgio) to 2000 kg/day (Rio Irvi). Moreover, natural attenuation of metals was found to occur i) through precipitation of Fe compounds (Fe oxy/hydroxides and “green rust”), ii) by means of the authigenic formation of metal sulphides promoted by microbial sulphate reduction, iii) by metal intake in roots and stems of plants ( Phragmites australis and Juncus acutus ) and by immobilization in the rhizosphere, and iv) by cyanobacterial biomineralization processes that lead to formation of Zn-rich phases (hydrozincite and amorphous Zn-silicate) The biologically mediated natural processes that lead to significant abatement and/or reduction of metal loads, are the response of environmental systems to perturbations caused from mine activities, and can be considered part of the resilience of the system itself. The aim of this study is to understand the effect of these processes on the evolution of the studied systems towards more stable and, likely, resilient conditions, e.g. by limiting metal mobility and favoring the improvement of the overall quality of water. The understanding of how ecosystems adapt and respond to contamination, and which chemical and physical factors control these natural biogeochemical barriers, can help to plan effective remediation actions.

Sardinia

Swatara Creek basin of southeastern Pennsylvania: An evaluation of its hydrologic system

Local concentrations of population in the Swatara Creek basin of Pennsylvania find it necessary to store, transport, and treat water because local supplies are either deficient or have been contaminated by disposal of wastes in upstream areas. Water in the basin is available for the deficient areas and for dilution of the coal-mine drainage in the northern parts and the sewage wastes in the southern parts. Swatara Creek drains 576 square miles just east of Harrisburg, Pa., and is the largest tributary to the Susquehanna River from the north side below Harrisburg. It rises in the southern Pocono Mountains and flows southwestward across the Lebanon Plateau. On an average day Swatara Creek discharges more than 630 million gallons into the Susquehanna River at Middletown, Pa. In a year this amounts to about 23 inches of water over the entire basin and is the residual from an average annual precipitation of 45.5 inches. During an average year the flow in Swatara Creek from the upper third of the basin above Harper Tavern is always greater than 1,300 mgd (million gallons per day) for at least 15 days and is always greater than 25 mgd for at least 350 days. The daily streamflow from the basin averages 1.1 mgd per sq mi, but yields from different areas range from 0.97 to 1.22 mgd per sq mi. These variations are caused chiefly by differences in precipitation and land cover. The area of lowest yield is in the valleys west of Tremont, and the highest yields are in the Upper and Lower Little Swatara Creek subbasins. At high and medium stages the chemical character of the water in the streams is suitable for public and private supplies. At lower stages, defending on the areas and the amounts of contamination by coal-mine drainage and sewage pollution, the natural flow may require some treatment. At low stages the chemical characteristics of the natural flow not affected by man is almost identical with that of the ground water in the area drained by the stream. In general, the total dissolved solids range from about 25 to 400 parts per million and the hardness is as much as about 300 parts per million. The ground-water increment to the base flow of Swatara Creek averages about 240 mgd, or about 8.8 inches annually, for the basin. Generally, ground-water supplies in amounts of less than 0.5 mgd can be developed south of Blue Mountain. Supplies of several million gallons per day have been developed for industrial use from the permeable limestones in the south-central part of the basin. More intensive investigation in other parts of the basin would indicate areas where supplies of more than 0.5 mgd could be developed from properly spaced wells. The chemical character of water from wells depends largely on the host rock. In highly soluble rocks water contains large amount of dissolved solids; in more resistant rocks concentrations are lower. The chemical character of unpolluted ground water generally reflects the composition of the more readily soluble minerals in the local geologic environment. Areas contaminated by septic- tank effluent may have above normal amounts of nitrate and detergent products. Except where polluted, most ground water is suitable for public and industrial uses without extensive treatment. Sites for storage of surface water exist in the part of the basin lying in the valley and ridge area. As much as 30 to 40 percent of the annual flow could be impounded for release as low-flow augmentation for dilution of mine drainage and other wastes in the basin. Low sediment yields of supplying drainage areas would ensure a long life expectancy of reservoirs at these sites. Overbank flooding of the main stem of the Swatara Creek and its tributaries has occurred many times in the past. However, it has not been a hazard because urban development has not encroached on the flood plain. An inundation map of the August 1933 flood provides a basis that urban planners may use to avoid future damage. As water in the Swatara Creek moves downstream to the Susquehanna River, the flow is influenced consecutively by a large annual rainfall on the northern valley and ridge area, the wastes of surface and subsurface coal-mining activities, and less annual rainfall on the part of the basin lying in the Lebanon Plateau area; the flow is supplemented and further influenced by many tributaries and by the industrial and domestic wastes that are carried by these secondary streams. The annual precipitation ranges from 52 inches at the east edge and 49 inches at the west edge of the mountainous part of the basin to about 41 inches at the southwestern part at Middletown. The rainfall generally is adequate during the growing season to mature the crops. The mean annual temperature at Lebanon is about 52°F, and the growing season is about 180 days. In this report the basin has been divided into eight hydrologic zones, leased on runoff, natural use of water, and chemical character of water. Four zones lie in the valley and ridge area, three lie in the Lebanon Plateau area, and one lies in the highland along the southeastern basin boundary. In each of the zones the hydrologic characteristics are virtually the same, but they may be completely different from those in adjacent zones. The boundaries of the zones generally coincide with boundaries between geologic formations, and the areas in each zone include rocks of similar influence on water. Streams in zone 4 at the northeast edge of the plateau have the highest average surface runoff from 1.2 to 1.1 mgd per sq mi whereas those in zone 2 at the northwest edge of the valley and ridge area have the lowest, about 1.0 mgd. Streams in zone 8, along the southeast edge of the basin, have the largest sustained low-flow yield, about 0.26 to 0.19 mgd per sq mi; those in zone 5 overlying the Martinsburg Shale east of Harrisburg have the smallest sustained low-flow yields, 0.03 to 0.01 mgd. Streams in the limestone area of zone 7 have the greatest range in low-flow yields in any one zone from 0.60 to 0 mgd per sq mi. Low-flow yields in zones 1 through 4 range from 0.13 to 0.03 mgd per sq mi. Surface flows from zones 1 and 2 are generally acidic and contain high concentrations of sulfate, iron, and total dissolved solids especially where contaminated with mine wastes. Surface flows from zones 3 and 4 are dilute, slightly alkaline, and suitable for public water supplies. Surface flows from zones 5, 6, and 7 are alkaline and contain moderate concentrations of dissolved solids with waters of highest hardness occurring in zone 7. Surface flows from zone 8 are dilute to moderately mineralized and are relatively high in silica concentration. Nitrate concentrations are high in surf Fee flows below sewage outfalls and in ground water contaminated by septic tank effluent and industrial wastes. Average annual sediment yields of 550 to 650 tons per square mile are characteristic of zones 1 and 2 where strip mining has destroyed the forest cover and coal culm is carried into the streams. From agricultural lands on the Martinsburg Shale in zones 5 and 6, annual sediment yields range from 300 to 350 tons per square mile; but from agricultural lands on the siliceous rocks in zone 8 and zones 3 and 4 in the valley and ridge area, the sediment yield ranges from 200 to 250 tons annually per square mile. Lowest annual sediment yields in the basin are in the forested areas of siliceous rocks in zones 2, 3, 4, and 5, and in the sinkhole topography of the limestones in zone 7 where the yield ranges from 30 to 35 tons and 50 to 60 tons per square mile, respectively. The amount of ground water that can be developed in the basin is dependent on the ability of the underlying rocks to yield water to wells. More than 300 gpm (gallons per minute) can be obtained from wells in alluvial materials in the valley bottoms and in some of the limestones where large solution channels and fractures are penetrated by the wells. From 50 to 300 gpm can be obtained from wells in loosely cemented sandstones and in fractured limestones. From 10 to 50 gpm can be developed from wells in the shales and harder sandstones. The most dense rocks will yield from 1 to 10 gpm from fractures and crevices. Most wells yield water from the upper 350 feet of the formation, for this part contains the most fractures or solution channels. Studies show that the velocity at which a contaminant will move downstream in the basin is related to the discharge of the stream at the time. At a stream discharge of about 400 mgd at Pine Grove, a contaminant in Swatara Creek would require about 40 hours to move from Pine Grove to Middletown. As a result of dispersion and dilution, the maximum concentration of the contaminant at Middletown would be less than 20 percent the concentration at Pine Grove under these conditions. An evaluation of the availability of water in the basin indicates that about I,239 mgd enters as precipitation, 630 mgd leaves as streamflow, 580 mgd is evaporated and transpired, and 56 mgd is diverted for use by man. Not all the diversions for man's use are lost to the basin, as about 27 mgd is returned as sewage for reuse. About one-fourth of the waste water is returned to the ground and the remainder to stream drainageways. Of that diverted by man, 11.6 mgd is used for public supply and 44.4 mgd for industrial and private supplies. Diversions of streamflow furnish 86 percent of the public supply and 27 percent of the industrial supply, and ground-water sources yield the remainder. Municipal and private sewage treatment plants are upgrading the waste water in many places, but no provisions are being made for treatment other than natural dilution and assimilation for the 15 mgd of coal-nine drainage in the northern part of the basin. Technology for economic treatment of mine water is not available at this time, although research in this field is being done. Urbanization eastward from Harrisburg and around Lebanon has increased the population density of the basin. Densities of 500 people per square mile and water use exceeding 2.0 mgd per sq mi can be expected in the future. By the year 2000 the population of the basin may increase 60 percent; and if the per capita rate of use increases 0.5 percent per year the domestic requirements for water will be about two times the present use, or 23 mgd. Similarly, if the present 1:4 ratio of domestic use to industrial use of water continues, at least 89 mgd will be needed for industry in the future. Although an increase to twice the present use of water can be foreseen, or 112 mgd, water for the dilution and assimilation of wastes from treatment systems are not included. Providing water for dilution of wastes from treatment plants has not been a problem, but in the future the amounts needed for this purpose will be greater as the population increases. As water becomes more valuable, treatment of sewage wastes to reduce the biochemical-oxygen-demand load by at least 80 to 90 percent will be necessary to conserve water for more productive uses. As much as 100 mgd may be needed for waste dilution in the basin by year 2000. The present trends in suburban and light industrial development will probably persist in the basin. Problems arising through changes in economic value of water, conflicts in use, and alternatives in development are typical of those confronting the manager of a water-resource system.

Pennsylvania

Applications of imaging spectroscopy data: A case study at Summitville, Colorado

From 1985 through 1992, the Summitville open-pit mine produced gold from lowgrade ore using cyanide heap-leach techniques, a method to extract gold whereby the ore pile is sprayed with water containing cyanide, which dissolves the minute gold grains. Environmental problems due to mining activity at Summitville include significant increases in acidic and metal-rich drainage from the site, leakage of cyanide-bearing solutions from the heap-leach pad into an underdrain system, and several surface leaks of cyanide-bearing solutions into the Wightman Fork of the Alamosa River. In general, drainage from the Summitville mine moves downslope into the Wightman Fork, a small tributary of the Alamosa River, which in turn flows east into the Terrace Reservoir before entering the agricultural lands of the San Luis Valley. The increase in the trace-metal burden of the Alamosa River watershed due to the mining activities at Summitville is of concern to farmers and fisherman, as well as Federal and State of Colorado agencies having responsibility for land stewardship. The environment of the Summitville area is a result of 1) its geologic evolution, that culminated in the formation of precious-metal mineral deposits; and 2) previous metal mining activity. Mining accentuates, accelerates, and pertubates natural geochemical processes. The development of underground workings, open pits, mill tailings, and spoil heaps and the extractive processing of ore enhances the likelihood of releasing chemicals and elements to the surrounding areas and at increased rates relative to unmined areas. Both mined and unmined mineralized areas can produce acid drainage from the formation and movement of highly acidic water rich in heavy metals. This acidic water forms principally through the chemical reaction of oxygenated surface water and shallow subsurface water with rocks that contain sulfide minerals, producing sulphuric acid. Heavy metals can be leached by the acid solution that comes in contact with mineralized rocks, a process that may be enhanced by bacterial action. The resulting fluids may be highly toxic and, when mixed with groundwater, surface water, and soil, may have harmful effects on humans, animals, and plants. Thus, understanding the geologic and hydrologic history of this area is a critical piece of the environmental puzzle in the Summitville area. The Summitville mine operators had ceased active mining and begun environmental remediation, including treatment of the heap-leach pile and installation of a water-treatment facility, when it declared bankruptcy in December 1992 and abandoned the mine site. The U.S. Environmental Protection Agency (EPA) immediately took over the Summitville site under EPA Superfund Emergency Response authority. Summitville has focused public attention on the environmental effects of modern mineral-resource development. Soon after the mine was abandoned, Federal, State, and local agencies, along with Alamosa River water users and private companies, began extensive studies at the mine site and surrounding areas. These studies included analysis of water, soil, livestock and vegetation. The role of the U.S. Geological Survey (USGS) was to provide geologic, hydrologic and agricultural information about the mine and surrounding area and to describe and evaluate the environmental condition of the Summitville mine and the downstream effects of the mine on the San Luis Valley (King 1995).

Colorado

Assessing mercury distribution using isotopic fractionation of mercury processes and sources adjacent and downstream of a legacy mine district in Tuscany, Italy

Mercury (Hg) concentrations and isotopic compositions in a range of sample types collected from the legacy Abbadia San Salvatore Mine (ASSM) area were used to evaluate the distribution of Hg in the region. The district generated more than 100,000 metric tons of Hg releasing extensive amounts of gaseous Hg emissions and producing large amounts of mine waste calcine from which Hg can be mobilized into the local and regional environments. Direct and indirect impact from cinnabar ore mining and processing resulted in elevated Hg concentrations in the calcine, soils, lake and stream sediments, and fish samples collected at and downstream of ASSM. The contribution of Hg from the different sources and processes resulted in a wide range of 202Hg and 199Hg isotopic compositions (-2.25 to 0.96‰, -0.12 to 0.72‰ respectively). Fish samples resulted in negative values for 202Hg (-0.53 to -1.21‰) and positive Hg (0.12 to 0.73‰). Primary cinnabar ore and present-day geothermal water and precipitate showed distinctly negative 202Hg (-0.96 to -2.25‰), whereas waste calcine were enriched in 202Hg (202Hg from about -1 to +1‰); soils and sediments show intermediate compositions, reflecting different extents of contributions from the various Hg sources and processes. These sources and processes of Hg include weathering cinnabar, gaseous Hg emissions from ore processing, and geothermal activity to a lesser extent. Hg speciation in concert with Hg isotope ratios can better ascertain source attribution and assist in identifying Hg pathways into the environment to distinguish the more bioavailable forms of Hg entering the ecosystem.

Tuscany

Preliminary report on Tertiary volcanism and uranium mineralization in the Thomas Range and northern Drum Mountains, Juab County, Utah

The Thomas Range and northern Drum Mountains have a history of volcanism, faulting, and mineralization that began about 42 m.y. ago. Volcanic activity and mineralization in the area can be divided into three stages according to the time-related occurrence of rock types, trace element associations, and chemical nature of mineralization. Volcanic activity switched abruptly from rhyodacite-quartz latite (42-39 m.y. ago) to rhyolite (38-32 m.y. ago) to alkali rhyolite stages (21 and 6-7 m.y. ago); these stages correspond to periods of chalcophile and siderophile metal mineralization, no mineralization, and lithophile metal mineralization, respectively. Angular unconformities record episodes of cauldron collapse and block faulting between the stages of volcanic activity and mineralization. The youngest angular unconformity formed between 21 and 7 m.y. ago during basin-and-range faulting. Early rhyodacite-quartz latite volcanism from composite volcanoes and fissures produced flows, breccias, and ash-flow tuff of the Drum Mountains Rhyodacite and Mt. Laird Tuff. Eruption of the Mt. Laird Tuff about 39 m.y. ago from an area north of Joy townsite was accompanied by collapse of the Thomas caldera. Part of the roof of the magma chamber did not collapse, or the magma was resurgent, as is indicated by porphyry dikes and plugs in the Drum Mountains. Chalcophile and siderophile metal mineralization, including copper, gold, and manganese, accompanied early volcanism. The middle stage of volcanic activity was characterized by explosive eruption of rhyolitic ash-flow tuffs and collapse of the Dugway Valley cauldron. Eruption of the Joy Tuff 38 m.y. ago was accompanied by subsidence of this cauldron and followed by collapse and sliding of Paleozoic rocks from the west wall of the cauldron. Landslides in The Dell were covered by the Dell Tuff, erupted 32 m.y. ago from an unknown source to the east. An ash-flow of the Needles Range Formation was erupted 30-31 m.y. ago, probably from a distant source outside the volcanic field. The rhyolitic stage of volcanism was barren of mineralization. The last stage of volcanism was contemporaneous with basin-and-range faulting and was characterized by explosive eruption of ash and pumice, forming stratified tuff, and by quiet eruption of alkali rhyolite as viscous flows and domes. The first episode of alkali rhyolite volcanism deposited the beryllium tuff and porphyritic rhyolite members of the Spor Mountain Formation 21 m.y. ago. After a period of block faulting, the stratified tuff and alkali rhyolite of the Topaz Mountain Rhyolite were erupted 6-7 m.y. ago along faults and fault intersections. Erosion of Spor Mountain may have provided abundant dolomite detritus to the beryllium tuff member. The alkali rhyolite of both formations is fluorine-rich, as is evident from abundant topaz, and contains anomalous amounts of lithophile metals. Alkali rhyolite volcanism was accompanied by lithophile metal mineralization which deposited fluorite, beryllium, and uranium. The structure of the area is dominated by the Thomas caldera, and the younger Dugway Valley cauldron, which is nested within the Thomas caldera; the Thomas caldera is surrounded by a rim of Paleozoic rocks at Spor Mountain and Paleozoic to Precambrian rocks in the Drum Mountains. The Joy fault and Dell fault system mark the ring fracture zone of the Thomas caldera. These structural features began to form about 39 m.y. ago during eruption of the Mt. Laird Tuff and cauldon subsidence. The Dugway Valley cauldron sank along a series of step-like normal faults southeast of Topaz Mountain in response to collapse of the magma chamber of the Joy Tuff. The caldera structure was modified by block faulting between 21 and 7 m.y. ago, the time of widespread extensional faulting in the basin-and-range province. Vents erupted alkali rhyolite 6-7 m.y. ago along basin-and-range faults. Uranium mineralization was associated with the stage of alkali rhyolite volcanism, extensional basin-and-range faulting, and lithophile metal mineralization; it occurred at least 11 m.y. after the end of the caldera cycle. Uranium, derived from alkali rhyolite magma, was concentrated in trace amounts by magmatic fluids and in potentially economic amounts by hydrothermal fluids and ground water. Hydrothermal fluids deposited uraniferous fluorite as pipes in carbonate rocks of Paleozoic age on Spor Mountain and uranium-bearing disseminated deposits of fluorite and beryllium in the beryllium tuff member of the Spor Mountain Formation. Uranium of hydrothermal origin is dispersed in fluorite and opal. Uranium in fluorite may be tetravalent(?) but that in opal is probably hexavalent; no primary minerals of tetravalent uranium are known to occur. Ground waters have concentrated significant ores of hexavalent uranium minerals in the beryllium tuff member of the Spor Mountain Formation at the Yellow Chief Mine, and are probably also responsible for widespread low concentrations (0.0X percent) of uranium that occur separately from beryllium ore in the beryllium tuff member. More deposits of the Yellow Chief type may occur in down-faulted sections of beryllium tuff beneath the Thomas Range. The ground water ores show no evidence of a reducing environment; instead, precipitation of hexavalent uranium minerals occurred by evaporation, decline in concentration of complexing ions such as carbonate, or some other mechanism. Reducing environments for hydrothermal deposits must be sought around rhyolite vents and in a hypothesized pluton of alkali rhyolite composition beneath Spor Mountain; for ground-water deposits, reducing environments may occur in basin fill such as that of the Dugway Valley cauldron.

Utah

Selenium in water, sediment, plants, invertebrates, and fish in the Blackfoot River drainage

Nine stream sites in the Blackfoot River watershed in southeastern Idaho were sampled in September 2000 for water, surficial sediment, aquatic plants, aquatic invertebrates, and fish. Selenium was measured in these aquatic ecosystem components, and a hazard assessment was performed on the data. Water quality characteristics such as pH, hardness, and specific conductance were relatively uniform among the nine sites examined. Selenium was elevated in water, sediment, aquatic plants, aquatic invertebrates, and fish from several sites suggesting deposition in sediments and food web cycling through plants and invertebrates. Selenium was elevated to concentrations of concern in water at eight sites (>5 ??g/L), sediment at three sites (>2 ??g/g), aquatic plants at four sites (>4 ??g/g), aquatic invertebrates at five sites (>3 ??g/g), and fish at seven sites (>4 ??g/g in whole body). The hazard assessment of selenium in the aquatic environment suggested low hazard at Sheep Creek, moderate hazard at Trail Creek, upper Slug Creek, lower Slug Creek, and lower Blackfoot River, and high hazard at Angus Creek, upper East Mill Creek, lower East Mill Creek, and Dry Valley Creek. The results of this study are consistent with results of a previous investigation and indicate that selenium concentrations from the phosphate mining area of southeastern Idaho were sufficiently elevated in several ecosystem components to cause adverse effects to aquatic resources in the Blackfoot River watershed. ?? 2004 Kluwer Academic Publishers.

Water, Air, & Soil Pollution

Urbanization and water management control stream water quality along a mountain to plains transition

Urbanization can have substantial effects on water quality due to altered hydrology and introduction of constituents to water bodies. In arid and semi-arid environments, streams are further stressed by dewatering as a result of diversions. We conducted a high-resolution synoptic survey of two streams in Colorado, USA that transition abruptly from granitic/metamorphic forested mountains to sedimentary urbanized plains and are both highly managed for water supply, yet differ in degree of urbanization. A synoptic mass balance approach developed for mine drainage applications was adapted to elucidate effects of urbanization, geology, and diversions on stream chemistry during baseflow conditions. Urbanization was a more important driver of stream concentrations than geology. The urban area was a strong source of bromide, calcium, chloride, and manganese, while lanthanum and dissolved organic carbon were primarily sourced from the mountains. A majority of streamflow was removed by diversions near the mountains/plains interface. Groundwater accounted for 31% of the subsequent flow increase to the urbanized stream, and delivered at least 33% of chloride loading. Constituents that were primarily urban-derived (bromide, calcium, chloride, and manganese) were 2–3 times higher in the urban region due to diversions; without diversions, stream water quality would have largely retained characteristics of forested streams through the urban reach. This study provides insights into processes that affect water quality in highly managed streams of the semi-arid western USA.

Colorado

Environmental processes that affect mineral deposits in the eastern United States

A thorough understanding of the environmental processes that affect mineral deposits and mine wastes has become increasingly important as the Nation wrestles with how to meet our current demand for metals without compromising the environment and how to mitigate the damage caused by the mining practices of previous generations. Regulatory requirements are dominated by empirical approaches to environmental problems associated with mining, but mitigation and reclamation can be enhanced greatly by a theoretical and conceptual understanding of the processes that affect the availability, transport, and fixation of metals and the generation of acidic waters. U.S. Geological Survey (USGS) research efforts in the Eastern United States are concentrating on environmental processes that affect a class of mineral deposits known as massive sulfide deposits. These occurrences were valued historically for their sulfur content and recently for their metals. This deposit type is a research priority because of its economic significance and high potential for adverse environmental impact due to its high sulfide content and the low acid-buffering capacity of host rocks. Numerous examples of these deposits are found in the East, including reclaimed mine sites, abandoned mines, active mines, and sites currently in the permitting process for future production. Published studies of mine drainage chemistry from the Iron Mountain massive sulfide deposit in California have documented extreme conditions of very low pH and high heavy-metal concentrations. These extreme conditions are attributed to the unique hydrologic and climatic settings of the deposit and probably are independent of the mineral deposit type. Areas currently under study include Bald Mountain, Maine, the Great Smoky Mountains National Park, the Vermont copper belt, Contrary Creek, Virginia, and Prince William Forest Park, Virginia (fig.1). Goals of the research are (1) to give land-use planners and the mining industry a better empirical framework from which to assess potential environmental impacts of mining, particularly under eastern climatic conditions, and (2) to provide a better theoretical and conceptual framework from which to design more effective and cost efficient mitigation and reclamation programs.

Information Handout

Evaluation of polymer-based dust palliatives in soil and stormwater runoff in an arid environment

Dust palliatives are used to reduce fugitive dust in areas susceptible to erosion by wind and rain. In 2015, the Bureau of Land Management (BLM) temporarily approved the use of polymer-based dust palliatives during the construction and operation of a solar energy facility and, in 2019, on a mining access road in Clark County, Nevada. The areas treated with palliative are habitat to the desert tortoise. The desert tortoise consumes water opportunistically from puddles, saturated soils, or by the collection of precipitation on their carapaces. Since little is known about the toxicity of polymeric substances to the desert tortoise, the BLM is concerned with the exposure of the desert tortoise to palliative in stormwater runoff. The BLM collaborated with the US Geological Survey (USGS) to evaluate the transport of butyl acrylate vinyl acetate (BA-VA), the copolymer ingredient in the dust palliatives applied in the study, away from areas of application. BA-VA concentrations were measured in soils treated with palliative up to 90 days post-treatment, after which the copolymer became undetectable (< 0.55 mg/g). BA-VA concentrations in all stormwater samples within and outside treated areas were consistently below detection (< 0.20 mg/mL). Although stormwater and treated soils eroded from the solar facility application area were found to have BA-VA concentrations below detection (< 0.55 mg/g), it is likely that some BA-VA (parent or degradation product) was transported with suspended material. It is also likely that the amount of BA-VA transported away from areas of application was a small fraction of that applied.

Nevada

Radionuclides in surface water and groundwater

Unique among all the contaminants that adversely affect surface- and groundwater quality, radioactive compounds pose a double threat from toxicity and ionizing radiation. The high energy potential of many of these materials makes them both useful and hazardous. The unique properties of radioactive materials make them invaluable for medical and energy applications. However, mining, production, use, and disposal of compounds and their byproducts provide potential pathways for their release into the environment, posing a risk to both humans and ecosystems. This chapter presents an overview of the sources and uses of radioactive compounds in the United States, biogeochemical processes that control mobility in the environment, examples of radionuclide contamination, and an overview of remediation strategies.

Book chapter

Radionuclides in surface and groundwater

Unique among all the contaminants that adversely affect surface and water quality, radioactive compounds pose a double threat from both toxicity and damaging radiation. The extreme energy potential of many of these materials makes them both useful and toxic. The unique properties of radioactive materials make them invaluable for medical, weapons, and energy applications. However, mining, production, use, and disposal of these compounds provide potential pathways for their release into the environment, posing a risk to both humans and wildlife. This chapter discusses the sources, uses, and regulation of radioactive compounds in the United States, biogeochemical processes that control mobility in the environment, examples of radionuclide contamination, and current work related to contaminated site remediation.

Book chapter