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Likely ferromagnetic minerals identified by the Perseverance rover and implications for future paleomagnetic analyses of returned Martian samples

Although Mars today does not have a core dynamo, magnetizations in the Martian crust and in meteorites suggest a magnetic field was present prior to 3.7 billion years (Ga) ago. However, the lack of ancient, oriented Martian bedrock samples available on Earth has prevented accurate estimates of the dynamo's intensity, lifetime, and direction. Constraining the nature and lifetime of the dynamo are vital to understanding the evolution of the Martian interior and the potential habitability of the planet. The Perseverance rover, which is exploring Jezero crater, is providing an unprecedented opportunity to address this gap by acquiring absolutely oriented bedrock samples with estimated ages from ∼2.3 to >4.1 Ga. As a first step in establishing whether these samples could contain records of Martian paleomagnetism, it is important to determine their ferromagnetic mineralogy, the grain sizes of the phases, and the forms of any natural remanent magnetization. Here, we synthesize data from various Perseverance instruments to achieve those goals and discuss the implications for future laboratory paleomagnetic analyses. Using the rover's instrument payload, we find that cored samples likely contain iron oxides enriched in Cr and Ti. The relative proportions of Fe, Ti, and Cr indicate that the phases may be titanomagnetite or Fe-Ti-Cr spinels that are ferromagnetic at room temperature, but we cannot rule out the presence of non-ferromagnetic ulvöspinel, ilmenite, and chromite due to signal mixing. Importantly, the inferred abundance of iron oxides in the samples suggests that even <1 mm-sized samples will be easily measurable by present-day magnetometers.

Journal of Geophysical Research: Planets

Television observations from Surveyor 3

A total of 6315 pictures were taken by the television camera on Surveyor 3 after the lunar landing. These pictures have provided much new information about the location of the landing site on the moon, the detailed topographic and geologic characteristics of the lunar surface, and the appearance of the earth as seen from the moon, both during eclipse of the sun and during partial direct illumination by the sun. Surveyor 3 landed in a subdued crater slightly more than 200 meters in diameter, which has a low rounded rim and is about 15 meters deep. The spacecraft is situated on the east wall of the crater, about half way between the center of the crater and the rim crest. The spacecraft is inclined 14.7° ± 1.0° toward the west. The selenographic coordinates of the landing site are 2.94°S latitude, 23.34°W longitude, relative to selenodetic control adopted by the Aeronautical Chart and Information Center. Small morphologic elements of the landing site include small craters, linear ridges and troughs, and fragmental debris. The craters and fragmental debris resemble those observed at the Surveyor 1 landing site, both in distribution of shape and in distribution of size. Most of the craters in Surveyor 1 and 3 pictures are inferred to be of impact origin. Their size-frequency distribution corresponds to the distribution that would be produced by repetitive bombardment by meteoroids, a bombardment sufficiently prolonged that the crater population has reached a steady state or has come to equilibrium. Some of the craters observed at the Surveyor 3 landing site are inferred to be of secondary impact origin, and some probably have been formed either by subsidence or by drainage of fragmental debris into cracks or fissures in the subsurface. Fragmental debris at the landing site is inferred to have been derived primarily by the same process of repetitive bombardment that produced the majority of craters. The inferred volumetric size-frequency distribution of fragments, derived from the observed size distribution of fragments on the surface, is similar to the distribution that would be produced by repetitive bombardment of coherent rocks by meteoroids with a mass-frequency distribution like that found from observed meteors and recovered meteorites on earth. Two prominent strewn fields of blocky debris were observed around two craters, 13 and 15 meters across, at the Surveyor 3 site. The 13-meter crater has a sharp raised rim, and the 15-meter crater has a more subdued rounded rim. The blocks associated with the subdued crater have twice as high a mean roundness as the blocks associated with the raised-rim crater, and they are much more deeply buried. The size-frequency distribution function for the fragments in each of the strewn fields of blocks resembles the size-frequency distribution for fragments ejected by impacts in strong rock, such as Meteor Crater, Arizona. Most of the fragments at the surface of the Surveyor 3 landing site are evidently part of a layer of fragmental material of low cohesion that is at least 1 meter thick along the upper parts of the wall of the crater in which Surveyor 3 landed and may be much thicker near the center of the crater. The evidence from the Surveyor 3 pictures suggests that this layer of debris, or regolith, is subject to downslope creep or mass movement. Creep is probably caused by seismic shaking, due mainly to near and far impact events and perhaps due partly to internal lunar seismicity. Disturbances of the lunar surface produced by Surveyor 3, like those produced by Surveyor 1, exposed material at depths of a few centimeters or less that was darker than the material at the surface. The albedo of the fine-grained fragmental debris is probably 20 to 30% lower at depths of only a fraction of a millimeter than it is at the optically observed surface. All coarse fragments protruding above the general level of the surface have a higher albedo than the fine-grained matrix of the surface. These general photometric relationships can be explained if it is assumed that the surfaces of the particles in the shallow lunar subsurface tend to become coated with a dark substance; the term proposed for this hypothetical substance is ‘lunar varnish’ On the protruding surface of blocks and coarse fragments the lunar varnish is scrubbed off by the processes that cause rounding. The exposed surfaces of fine particles on the lunar surface are similarly affected, but, because they are mixed relatively rapidly with particles just beneath the surface, the process is incomplete and the fine-grained material exposed at the lunar surface, therefore, has a lower albedo than blocks and other large fragments. Coating of particles by lunar varnish evidently takes place just beneath the surface. The estimated normal luminance factor (normal albedo) of an undisturbed part of the lunar surface next to footpad 2 of the Surveyor 3 spacecraft is 8.5%. An area of the lunar surface disturbed by the surface sampler has an estimated normal luminance factor of 6.6%, and fine-grained material placed on footpad 2 by the surface sampler has an estimated normal luminance factor of 7.6%. The errors in all these estimates may be as high as 25% because of uncertainties of correction required for light scattered from the camera mirror. Preliminary search for color differences, by color reconstitution methods, revealed no determinable differences in color among various coarse blocks, the fine-grained matrix of the surface, or fine-grained material disturbed by the surface sampler. Surveyor 3 pictures of the eclipse of the sun by the earth revealed a bright region in the refraction halo surrounding the earth, which was correlated with the position of the sun, and a series of bright beads that occurred over regions of the earth largely clear of clouds. Clouds tend to occult the refracted rays of the sun, most of which pass through the lower part of the atmosphere at the limb; the beads occurred in the depressions in the optical silhouette of the earth. Preliminary reduction of the color of the refracted light showed that the brightest region, near the position of the sun, exhibited a correlated color temperature close to 4800°K. The color temperature tended to be lower for light that followed paths of greater atmospheric absorption. Preliminary analysis of Surveyor 3 pictures of the partly illuminated earth revealed colors similar to the colors recorded from orbit by the Mercury and Gemini astronauts.

Journal of Geophysical Research

Strangways Crater, Northern Territory, Australia: Siderophile element enrichment and lithophile element fractionation

The Strangways Crater, Northern Territory, Australia (15°12′S, 133°35′ E ), has a central core, about 10 km in diameter, of shocked granitic gneiss and amphibolite, and some remnants of a melt rock sheet, surrounded by outer rings of quartzite and siltstone to a diameter of 20–25 km. Seven samples of melt rock (six granitic melts, one shale melt clast) and four samples of country rock (granitic gneiss, amphibolite, shale, quartzite) were analyzed by neutron-activation analysis: for Sc, Cr, Fe, Co, Zn, Rb, Zr, Sb, Cs, Ba, rare earth elements, Hf, Ta, Th, and U, the samples were analyzed instrumentally; and for Ni, Se, Pd, Ag, Cd, Re, Os, Ir, and Au, they were analyzed radiochemically. Siderophile elements are significantly enriched in the granitic melt rocks relative to country rocks; for example, the Ir enrichments range from 0.6 to 2.8 ppb. The low Ir/Ni ratio (∼0.16 relative to C1 chondrites) excludes a chondritic impacting body, and Cr enrichment argues against impact by an iron meteorite. The Strangways Crater may have been formed by the impact of an olivine-rich achondrite and melt rocks appear to contain about 3 wt.% of projectile material. The composition of the granitic melt rocks cannot be reproduced by any simple mixture of analyzed country rock types and chemical fractionation by selective shock melting appears to have taken place.

Journal of Geophysical Research Solid Earth

Goat paddock cryptoexplosion crater, Western Australia

Goat Paddock, a crater slightly over 5 km in diameter (18??20??? S, 126??40???E), lies at the north edge of the King Leopold Range/Mueller Range junction in the Kimberley district, Western Australia (Fig. 1). It was noted as a geological anomaly in 1964 during regional mapping by the Bureau of Mineral Resources, Geology and Geophysics and the Geological Survey of Western Australia. The possibility of its being a meteorite impact crater has been discussed1, although this suggestion was subsequently ignored2. Two holes were drilled by a mining corporation in 1972 to test whether kimberlite underlay the structure. Here we report the findings of five days of reconnaissance in August 1979 which established that Goat Paddock is a cryptoexplosion crater containing shocked rocks and an unusually well exposed set of structural features. ?? 1980 Nature Publishing Group.

Nature

Possible solar noble-gas component in Hawaiian basalts

The noble-gas elemental and isotopic composition in the Earth is significantly different from that of the present atmosphere, and provides an important clue to the origin and history of the Earth and its atmosphere. Possible candidates for the noble-gas composition of the primordial Earth include a solar-like component, a planetary-like component (as observed in primitive meteorites) and a component similar in composition to the present atmosphere. In an attempt to identify the contributions of such components, we have measured isotope ratios of helium and neon in fresh basaltic glasses dredged from Loihi seamount and the East Rift Zone of Kilauea 1–3 . We find a systematic enrichment in 20 Ne and 21 Ne relative to 22 Ne, compared with atmospheric neon. The helium and neon isotope signatures observed in our samples can be explained by mixing of solar, present atmospheric, radiogenic and nucleogenic components. These data suggest that the noble-gas isotopic composition of the mantle source of the Hawaiian plume is different from that of the present atmosphere, and that it includes a significant solar-like component. We infer that this component was acquired during the formation of the Earth.

Hawaii

Bulk density of asteroid 243 Ida from the orbit of its satellite Dactyl

During its reconnaissance of the asteroid 243 Ida, the Galileo spacecraft returned images of a second object, 1993(243)1 Dactyl 1 — the first confirmed satellite of an asteroid. Sufficient data were obtained on the motion of Dactyl to determine its orbit as a function of Ida's mass. Here we apply statistical and dynamical arguments to constrain the range of possible orbits, and hence the mass of Ida. Combined with the volume of Ida 2 , this yields a bulk density of 2.6 ± 0.5 g cm −3 . Allowing for the uncertainty in the porosity of Ida, this density range is consistent with a bulk chon-dritic composition, and argues against some (but not all) classes of meteoritic igneous rock types that have been suggested as compositionally representative of S-type asteroids like Ida.

Nature

An integrated view of the chemistry and mineralogy of martian soils

The mineralogical and elemental compositions of the martian soil are indicators of chemical and physical weathering processes. Using data from the Mars Exploration Rovers, we show that bright dust deposits on opposite sides of the planet are part of a global unit and not dominated by the composition of local rocks. Dark soil deposits at both sites have similar basaltic mineralogies, and could reflect either a global component or the general similarity in the compositions of the rocks from which they were derived. Increased levels of bromine are consistent with mobilization of soluble salts by thin films of liquid water, but the presence of olivine in analysed soil samples indicates that the extent of aqueous alteration of soils has been limited. Nickel abundances are enhanced at the immediate surface and indicate that the upper few millimetres of soil could contain up to one per cent meteoritic material.

Nature

Geomorphological evidence for ground ice on dwarf planet Ceres

Five decades of observations of Ceres suggest that the dwarf planet has a composition similar to carbonaceous meteorites and may have an ice-rich outer shell protected by a silicate layer. NASA’s Dawn spacecraft has detected ubiquitous clays, carbonates and other products of aqueous alteration across the surface of Ceres, but surprisingly it has directly observed water ice in only a few areas. Here we use Dawn Framing Camera observations to analyse lobate morphologies on Ceres’ surface and we infer the presence of ice in the upper few kilometres of Ceres. We identify three distinct lobate morphologies that we interpret as surface flows: thick tongue-shaped, furrowed flows on steep slopes; thin, spatulate flows on shallow slopes; and cuspate sheeted flows that appear fluidized. The shapes and aspect ratios of these flows are different from those of dry landslides—including those on ice-poor Vesta—but are morphologically similar to ice-rich flows on other bodies, indicating the involvement of ice. Based on the geomorphology and poleward increase in prevalence of these flows, we suggest that the shallow subsurface of Ceres is comprised of mixtures of silicates and ice, and that ice is most abundant near the poles.

Nature Geoscience

Evidence of cosmic impact at Abu Hureyra, Syria at the Younger Dryas Onset (~12.8 ka): High-temperature melting at >2200 °C

At Abu Hureyra (AH), Syria, the 12,800-year-old Younger Dryas boundary layer (YDB) contains peak abundances in meltglass, nanodiamonds, microspherules, and charcoal. AH meltglass comprises 1.6 wt.% of bulk sediment, and crossed polarizers indicate that the meltglass is isotropic. High YDB concentrations of iridium, platinum, nickel, and cobalt suggest mixing of melted local sediment with small quantities of meteoritic material. Approximately 40% of AH glass display carbon-infused, siliceous plant imprints that laboratory experiments show formed at a minimum of 1200°–1300 °C; however, reflectance-inferred temperatures for the encapsulated carbon were lower by up to 1000 °C. Alternately, melted grains of quartz, chromferide, and magnetite in AH glass suggest exposure to minimum temperatures of 1720 °C ranging to >2200 °C. This argues against formation of AH meltglass in thatched hut fires at 1100°–1200 °C, and low values of remanent magnetism indicate the meltglass was not created by lightning. Low meltglass water content (0.02–0.05% H 2 O) is consistent with a formation process similar to that of tektites and inconsistent with volcanism and anthropogenesis. The wide range of evidence supports the hypothesis that a cosmic event occurred at Abu Hureyra ~12,800 years ago, coeval with impacts that deposited high-temperature meltglass, melted microspherules, and/or platinum at other YDB sites on four continents.

Abu Hureyra

Very high-temperature impact melt products as evidence for cosmic airbursts and impacts 12,900 years ago

It has been proposed that fragments of an asteroid or comet impacted Earth, deposited silica-and iron-rich microspherules and other proxies across several continents, and triggered the Younger Dryas cooling episode 12,900 years ago. Although many independent groups have confirmed the impact evidence, the hypothesis remains controversial because some groups have failed to do so. We examined sediment sequences from 18 dated Younger Dryas boundary (YDB) sites across three continents (North America, Europe, and Asia), spanning 12,000 km around nearly one-third of the planet. All sites display abundant microspherules in the YDB with none or few above and below. In addition, three sites (Abu Hureyra, Syria; Melrose, Pennsylvania; and Blackville, South Carolina) display vesicular, high-temperature, siliceous scoria-like objects, or SLOs, that match the spherules geochemically. We compared YDB objects with melt products from a known cosmic impact (Meteor Crater, Arizona) and from the 1945 Trinity nuclear airburst in Socorro, New Mexico, and found that all of these high-energy events produced material that is geochemically and morphologically comparable, including: (i) high-temperature, rapidly quenched microspherules and SLOs; (ii) corundum, mullite, and suessite (Fe 3,/sup>Si), a rare meteoritic mineral that forms under high temperatures; (iii) melted SiO 2 glass, or lechatelierite, with flow textures (or schlieren) that form at > 2,200 °C; and (iv) particles with features indicative of high-energy interparticle collisions. These results are inconsistent with anthropogenic, volcanic, authigenic, and cosmic materials, yet consistent with cosmic ejecta, supporting the hypothesis of extraterrestrial airbursts/impacts 12,900 years ago. The wide geographic distribution of SLOs is consistent with multiple impactors.

Proceedings of the National Academy of Sciences of

Pb-isotopic systematics of lunar highland rocks (>3.9 Ga): Constraints on early lunar evolution

The present lead (Pb)-isotopic database of over 200 analyses from nearly 90 samples of non-mare basalt, lunar highland rocks (>3.9 Ga) delineate at least three isotopically distinct signatures that in some combination can be interpreted to characterize the systematics of the entire database. Two are fairly new sets of lunar data and are typical of Pb data from other solar-system objects, describing nearly linear arrays slightly above the “geochron” values, with 207 Pb/ 206 Pb values <0.9. In aggregate, those data allow a relatively new interpretation of the Pb-isotopic evolution of the Moon, helping to identify and characterize a planetary evolutionary stage not preserved by Earth rocks. From the Pb-isotopic compositions, a source 238 U/ 204 Pb (μ) value can be calculated; differences in μ values from one Pb signature to another can have important implications on the age and evolution of Moon-forming events. In particular, the U/Pb ratio is one method of measuring the fractionation between refractory and volatile elements, an important indicator when considering large-scale planetary differentiation stages. The oldest Pb signature is represented solely by ferroan anorthosite 60025, presumably a piece of the early plagioclase-rich lunar crust produced from a magma ocean, and is characterized by source μ values between 35 and 100 at ~4.43 Ga. Another prominent and uniquely lunar Pb signature, identified more than 20 years ago, is representative of many ferroan anorthosites and most high-Mg suite rocks (particularly 15415, 62237, 76535, and 78235), and is characterized by extremely high 207 Pb/ 206 Pb values (∼1.45) that require extremely high source μ values (>500). Although the age and origin of this exotic Pb is not well constrained, it is interpreted to be related to the entrapment of incompatible-element-rich (U, Th) melts within the lunar upper mantle and crust between 4.36 and 4.46 Ga (urKREEP residuum?). The latest discovered Pb signature is found only in lunar meteorites and is characterized by relatively low source μ values between 10 and 50 at 3.9 Ga. The fact that most lunar crustal rocks (>3.9 Ga) exhibit high 207 Pb/ 206 Pb values requires that they were derived from, mixed with, or contaminated by Pb produced from early-formed, high-μ sources. The ubiquity of these U-Pb characteristics in the sample collection is probably an artifact of Apollo and Luna sampling sites, all located on the near side of the Moon, which was deeply excavated during the basin-forming event(s). However, the newest Pb-isotopic data support the idea that the Moon originally had a μ value of ~8 to 35, slightly elevated from Earth values, and that progressive U-Pb fractionations occurred within the Moon during later stages of differentiation between 4.36 and 4.46 Ga.

International Geology Review

Compositional and structural mapping of Northwest Africa 15507 angrite

Angrite meteorites represent interesting sampling of planetary crustal environments. Quench-textured angrites with strong crystal zoning originated from the shallow surface region, with evidence of reducing conditions during solidification. Plutonic angrites have more coarse-grained igneous and metamorphic textures with comparatively less zoning and are interpreted as having equilibrated at greater depth. Plutonic angrites contain the minerals magnetite Fe 3 O 4 comprised of Fe 2+ and Fe 3+ , and rhönite, where Fe 3+ is required by inspection of mineral stoichiometry. NWA 15507 is a plutonic angrite with a microgabbroic texture (mean grainsize ∼1.4 mm) composed of zoned Al-Ti-augite, Ca-bearing olivine, anorthite, with accessory kirschsteinite, rhönite, hercynite, low-Ni kamacite, merrillite, Ti-free magnetite and troilite [ 1 ]. Rhönite analyzed by electron-probe microanalysis (EPMA) has the formula Ca 2.04 (Mg 0.32 Fe 2+ 4.25 Fe 3+ 0.47 Ti 0.33 Al 0.61 )(Si 3.74 Al 2.26 )O 20 , where Fe 3+ was estimated by stoichiometric analysis. During preliminary cathodoluminescence (CL) analysis, complex subgrain and oscillatory zoning was observed in the anorthite. In this study we use a combined approach of electron probe microanalysis (EPMA), cathodoluminescence (CL), electron-backscatter diffraction (EBSD), and laser ablation inductively-coupled plasma mass spectrometry (LA-ICP-MS) to further investigate the anorthite and distribution of Fe 3+ in NWA 15507.

Microscopy and Microanalysis

Hyperspectral cathodoluminescence and quantitative EPMA mapping of angrite northwest Africa 15507

Angrite meteorites represent alkali depleted planetary crust of basaltic composition, and have both plutonic and volcanic lithologies. NWA 15507 is a microgabbroic specimen (mean grainsize ~1.4 mm) composed predominantly of zoned Al-Ti-augite, Ca-bearing olivine and anorthite together with accessory kirschsteinite, rhönite, hercynite, low-Ni kamacite, merrillite, magnetite and troilite. Upon initial investigation, the anorthite was found to exhibit a cathodoluminescence (CL) response which revealed a complex history of crystallization. Hyperspectral cathodoluminescence, quantitative electron probe microanalysis mapping, laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), and electron back scattered diffraction (EBSD) were used to determine the CL emitter to better unravel the crystallization history of NWA 15507.

Conference Paper

Mineralogy at Meridiani Planum from the Mini-TES experiment on the opportunity rover

The Miniature Thermal Emission Spectrometer (Mini-TES) on Opportunity investigated the mineral abundances and compositions of outcrops, rocks, and soils at Meridiani Planum. Coarse crystalline hematite and olivine-rich basaltic sands were observed as predicted from orbital TES spectroscopy. Outcrops of aqueous origin are composed of 15 to 35% by volume magnesium and calcium sulfates [a high-silica component modeled as a combination of glass, feldspar, and sheet silicates (???20 to 30%)], and hematite; only minor jarosite is identified in Mini-TES spectra. Mini-TES spectra show only a hematite signature in the millimeter-sized spherules. Basaltic materials have more plagioclase than pyroxene, contain olivine, and are similar in inferred mineral composition to basalt mapped from orbit. Bounce rock is dominated by clinopyroxene and is close in inferred mineral composition to the basaltic martian meteorites. Bright wind streak material matches global dust. Waterlain rocks covered by unaltered basaltic sands suggest a change from an aqueous environment to one dominated by physical weathering.

Science

The formation conditions of chondrules and chondrites

Chondrules, which are roughly millimeter-sized silicate-rich spherules, dominate the most primitive meteorites, the chondrites. They formed as molten droplets and, judging from their abundances in chondrites, are the products of one of the most energetic processes that operated in the early inner solar system. The conditions and mechanism of chondrule formation remain poorly understood. Here we show that the abundance of the volatile element sodium remained relatively constant during chondrule formation. Prevention of the evaporation of sodium requires that chondrules formed in regions with much higher solid densities than predicted by known nebular concentration mechanisms. These regions would probably have been self-gravitating. Our model explains many other chemical characteristics of chondrules and also implies that chondrule and planetesimal formation were linked.

Science

Exploration of Victoria crater by the mars rover opportunity

The Mars rover Opportunity has explored Victoria crater, a ???750-meter eroded impact crater formed in sulfate-rich sedimentary rocks. Impact-related stratigraphy is preserved in the crater walls, and meteoritic debris is present near the crater rim. The size of hematite-rich concretions decreases up-section, documenting variation in the intensity of groundwater processes. Layering in the crater walls preserves evidence of ancient wind-blown dunes. Compositional variations with depth mimic those ???6 kilometers to the north and demonstrate that water-induced alteration at Meridiani Planum was regional in scope.

Science

Elemental mapping by Dawn reveals exogenic H in Vesta's regolith

Using Dawn’s Gamma Ray and Neutron Detector, we tested models of Vesta’s evolution based on studies of howardite, eucrite, and diogenite (HED) meteorites. Global Fe/O and Fe/Si ratios are consistent with HED compositions. Neutron measurements confirm that a thick, diogenitic lower crust is exposed in the Rheasilvia basin, which is consistent with global magmatic differentiation. Vesta’s regolith contains substantial amounts of hydrogen. The highest hydrogen concentrations coincide with older, low-albedo regions near the equator, where water ice is unstable. The young, Rheasilvia basin contains the lowest concentrations. These observations are consistent with gradual accumulation of hydrogen by infall of carbonaceous chondrites—observed as clasts in some howardites—and subsequent removal or burial of this material by large impacts.

Science