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USGS2012

Toxicity of carbon nanotubes to freshwater aquatic invertebrates

Carbon nanotubes (CNTs) are hydrophobic in nature and thus tend to accumulate in sediments if released into aquatic environments. As part of our overall effort to examine the toxicity of carbon-based nanomaterials to sediment-dwelling invertebrates, we have evaluated the toxicity of different types of CNTs in 14-d water-only exposures to an amphipod ( Hyalella azteca ), a midge ( Chironomus dilutus ), an oligochaete ( Lumbriculus variegatus ), and a mussel ( Villosa iris ) in advance of conducting whole-sediment toxicity tests with CNTs. The results of these toxicity tests conducted with CNTs added to water showed that 1.00g/L (dry wt) of commercial sources of CNTs significantly reduced the survival or growth of the invertebrates. Toxicity was influenced by the type and source of the CNTs, by whether the materials were precleaned by acid, by whether sonication was used to disperse the materials, and by species of the test organisms. Light and electron microscope imaging of the surviving test organisms showed the presence of CNTs in the gut as well as on the outer surface of the test organisms, although no evidence was observed to show penetration of CNTs through cell membranes. The present study demonstrated that both the metals solubilized from CNTs such as nickel and the "metal-free" CNTs contributed to the toxicity.

Environmental Toxicology and Chemistry↗

USGS2018

Assessment of chronic low‐dose elemental and radiological exposures of biota at the Kanab North uranium mine site in the Grand Canyon watershed

High‐grade U ore deposits are in various stages of exploitation across the Grand Canyon watershed, yet the effects of U mining on ecological and cultural resources are largely unknown. We characterized the concentrations of Al, As, Bi, Cd, Co, Cu, Fe, Pb, Hg, Mo, Ni, Se, Ag, Tl, Th, U, and Zn, gross alpha and beta activities, and U and Th radioisotopes in soil, vegetation ( Hesperostipa comata , Artemisia tridentata, Tamarix chinensis ), and rodents ( Peromyscus maniculatus , P. boylii ) to waste material at the Kanab North mine, a mine with decades‐long surficial contamination, and compared the concentrations ( P < 0.01) to those at a premining site (Canyon Mine). Rodent tissues were also analyzed for radium‐226 and microscopic lesions. Radioactivities and some elemental concentrations (e.g., Co, Pb, U) were greater in the Kanab North mine biological samples than in Canyon Mine biota, indicating a mining‐related elemental signature. Mean rodent Ra‐226 (111 Bq/kg dry weight [dry wt]) was 3 times greater than expected, indicating radioactive disequilibrium. Multiple soil sample U concentrations exceeded a screening benchmark, growth inhibition thresholds for sensitive plants, and an EC 20 for a soil arthropod. Lesions associated with metals exposure were also observed more frequently in rodents at Kanab North than those at Canyon Mine but could not be definitively attributed to U mining. Our results indicate that Kanab North biota have taken up U mining‐related elements owing to chronic exposure to surficial contamination. However, no literature‐based effects thresholds for small rodents were exceeded, and only a few soil and vegetation thresholds for sensitive species were exceeded; therefore, adverse effects to biota from U mining‐related elements at Kanab North are unlikely despite chronic exposure.

Integrated Environmental Assessment and Management↗

USGS2001

Evaluation of USEPA method 1622 for detection of Cryptosporidium oocysts in stream waters

To improve surveillance for Cryptosporidium oocysts in water, the US Environmental Protection Agency developed method 1622, which consists of filtration, concentration, immunomagnetic separation, fluorescent antibody and 4, 6-diamidino-2-phenylindole (DAPI) counter-staining, and microscopic evaluation. Two filters were compared for analysis of 11 stream water samples collected throughout the United States. Replicate 10-L stream water samples (unspiked and spiked with 100–250 oocysts) were tested to evaluate matrix effects. Oocyst recoveries from the stream water samples averaged 22% (standard deviation [SD] = ±17%) with a membrane disk and 12% (SD = ±6%) with a capsule filter. Oocyst recoveries from reagent water precision and recovery samples averaged 39% (SD = ±13%) with a membrane disk and 47% (SD = ±19%) with a capsule filter. These results demonstrate that Cryptosporidium oocysts can be recovered from stream waters using method 1622, but recoveries are lower than those from reagent-grade water. This research also evaluated concentrations of indicator bacteria in the stream water samples. Because few samples were oocyst-positive, relationships between detections of oocysts and concentrations of indicator organisms could not be determined.

Journal - American Water Works Association↗

USGS2013

Photometric properties of Mars soils analogs

We have measured the bidirectional reflectance of analogs of dry, wet, and frozen Martian soils over a wide range of phase angles in the visible spectral range. All samples were produced from two geologic samples: the standard JSC Mars-1 soil simulant and Hawaiian basaltic sand. In a first step, experiments were conducted with the dry samples to investigate the effects of surface texture. Comparisons with results independently obtained by different teams with similar samples showed a satisfying reproducibility of the photometric measurements as well as a noticeable influence of surface textures resulting from different sample preparation procedures. In a second step, water was introduced to produce wet and frozen samples and their photometry investigated. Optical microscope images of the samples provided information about their microtexture. Liquid water, even in relatively low amount, resulted in the disappearance of the backscattering peak and the appearance of a forward-scattering peak whose intensity increases with the amount of water. Specular reflections only appeared when water was present in an amount large enough to allow water to form a film at the surface of the sample. Icy samples showed a wide variability of photometric properties depending on the physical properties of the water ice. We discuss the implications of these measurements in terms of the expected photometric behavior of the Martian surface, from equatorial to circum-polar regions. In particular, we propose some simple photometric criteria to improve the identification of wet and/or icy soils from multiple observations under different geometries.

Journal of Geophysical Research E: Planets↗

USGS2025

Challenges and opportunities in mitigating sarcoptic mange in wild South American camelids

Vicuñas ( Vicugna vicugna ) and guanacos ( Lama guanicoe ) are the two species of wild South American camelids whose distributions range from Peru to northern Argentina and southern Peru to southern Argentina, respectively. Listed as critically endangered in the 1960s due to poaching, vicuña numbers had been gradually recovering; however, new concerns about population stability have arisen with recent observations of sarcoptic mange outbreaks in this species. Sarcoptic mange is an infectious skin disease caused by the microscopic burrowing mite, Sarcoptes scabiei , which infects nearly 150 mammalian species globally, including guanaco and vicuña. Wild camelid populations across Argentina, Bolivia, Chile, and Peru have been affected by sarcoptic mange, with the most severe outbreaks resulting in localized extirpation. Population declines have conservation and economic implications, as many local communities harvest vicuña and guanaco fiber for profit. We review the current literature on sarcoptic mange in wild camelids from Argentina, Bolivia, Chile, and Peru to establish a current state of knowledge on spatial prevalence, management, and therapeutics, and identify existing knowledge gaps. Critical next steps include 1) implementation of effective management strategies that limit the transmission of sarcoptic mange, 2) standardization of data collected during community capture (i.e., chaccu) events, 3) assessing the potential role of community captures in mite transmission, and 4) evaluation of treatment options and best practices for implementation. Further, there is a need for capacity building to improve disease diagnostics and surveillance in wild camelids. A multisectoral collaboration between governmental authorities, communities, academic institutions, and national and international organizations focusing on wild South American camelid conservation could contribute to building actions aimed at preventing future outbreaks and mitigating the current burden of sarcoptic mange disease.

Journal of Wildlife Management↗

USGS2017

Spatial and temporal dynamics of suspended particle characteristics and composition in Navigation Pool 19 of the Upper Mississippi River

Suspended particles are an essential component of large rivers influencing channel geomorphology, biogeochemical cycling of nutrients, and food web resources. The Upper Mississippi River is a large floodplain river that exhibits pronounced spatiotemporal variation in environmental conditions and biota, providing an ideal environment for investigating dynamics of suspended particles in large river ecosystems. Here we investigated two questions: (i) How do suspended particle characteristics (e.g. size and morphology) vary temporally and spatially? and (ii) What environmental variables have the strongest association with particle characteristics? Water sampling was conducted in June, August, and September of 2013 and 2014 in Navigation Pool 19 of the Upper Mississippi River. A FlowCAM® (Flow Cytometer and Microscope) particle imaging system was used to enumerate and measure particles 53–300 μm in diameter for size and shape characteristics (e.g. volume, elongation, and symmetry). Suspended particle characteristics varied considerably over space and time and were strongly associated with discharge and concentrations of nitrate + nitrite (NO 3 − ) and soluble reactive phosphorus. Particle characteristics in backwaters were distinct from those in other habitats for most of the study period, likely due to reduced hydrologic connectivity and higher biotic production in backwaters. During low discharge, phytoplankton and zooplankton made up relatively greater proportions of the observed particles. Concurrently during low discharge, concentrations of chlorophyll, volatile suspended solids, and total phosphorus were higher. Our results suggest that there are complex interactions among space, time, discharge, and other environmental variables (e.g. water nutrients), which drive suspended particle dynamics in large rivers.

Mississippi River↗

USGS1994

Galileo Photometry of Asteroid 951 Gaspra

Galileo images of Gaspra make it possible for the first time to determine a main-belt asteroid's photometric properties accurately by providing surface-resolved coverage over a wide range of incidence and emission angles and by extending the phase angle coverage to phases not observable from Earth. We combine Earth-based telescopic photometry over phase angles 2° ≤ α ≤ 25° with Galileo whole-disk and disk-resolved data at 33° ≤ α ≤ 51° to derive average global photometric properties in terms of Hapke's photometric model. The microscopic texture and particle phase-function behavior of Gaspra's surface are remarkably like those of other airless rocky bodies such as the Moon. The macroscopic surface roughness parameter, θ̄ = 29°, is slightly larger than that reported for typical lunar materials. The particle single scattering albedo, ώ 0 = 0.36 ± 0.07, is significantly larger than for lunar materials, and the opposition surge amplitude, B 0 = 1.63 ± 0.07, is correspondingly smaller. We determine a visual geometric albedo p v = 0.22 ± 0.06 for Gaspra, in close agreement with p v = 0.22 ± 0.03 estimated from Earth-based observations. Gaspra's phase integral is 0.47, and the bolometric Bond albedo is estimated to be 0.12 ± 0.03. An albedo map derived by correcting Galileo images with our average global photometric function reveals subdued albedo contrasts of ±10% or less over Gaspra's northern hemisphere. Several independent classification algorithms confirm the subtle spectral heterogeneity reported earlier (S. Mottola, M. DiMartino, M. Gonano-Beurer, H. Hoffman, and G. Neukum, 1993, Asteroids, Comets, Meteors, pp. 421-424; M. J. S. Belton et al ., 1992, Science 257, 1647-1652). Whole-disk colors (0.41 ≤ λ ≤ 0.99 μm) vary systematically with longitude by about ±5%, but color differences as large as 30% occur locally. Colors vary continuously between end-member materials whose areal distribution correlates with regional topography. Infrared: violet (0.99:0.41-μm) color ratios on Gaspra are strongly correlated with local elevation, being largest at lower elevations and smaller at higher elevations. No correlation was detected between elevation and the green:violet (0.56:0.41-μm) color ratio. Bright materials with a strong 1-μm absorption occur primarily in association with craters along ridges, while darker materials with 30% weaker 1-μm signatures occur downslope. The variations of color and albedo cannot be easily explained by grain-size effects alone or by differences in photometric geometry. The trends observed are consistent with those revealed by laboratory studies of the effects of comminution, glass formation, and segregation of metal from silicate components in chondritic meteorites and also in some silicate mixtures. The relative importance of these various processes on Gaspra remains to be determined.

Icarus↗

USGS2020

Introduction to life cycles, taxonomy, distribution and basic research techniques

Avian haemosporidian parasites are a closely related group of apicomplexan parasites with important similarities in their life cycles, development, physiology, and reproduction. Current phylogenies based on mitochondrial and nuclear genes reflect more traditional attempts to classify these organisms based on life history characteristics and morphology, but limited sampling from poorly characterized taxa such as the Garniidae from tropical and subtropical regions continues to limit our understanding of their phylogeny and evolution. Recent advances in molecular diagnostics and the ability to barcode these parasites using mitochondrial cytochrome b sequences have revolutionized the field, but traditional methodology based on microscopy of Giemsa-stained blood smears remains essential for diagnostics and understanding life history characteristics and biodiversity of these organisms. The relative strengths and weaknesses of current methods in wildlife haemosporidian research are discussed. We call for a combination of microscopic, PCR-based, and serological diagnostic methodologies for better estimates of true distribution and other aspects of biology of haemosporidians, particularly in studies on virulence, prevalence, and biodiversity.

Book chapter↗

USGS2022

Biofilms in the Critical Zone: Distribution and mediation of processes

Microbial biofilms occur in all levels of the Critical Zone (CZ); they are on and in the vegetation, throughout the soil-saprolite zone, and along fractures in deep subsurface. Here we discuss biofilms in each level of the CZ with a focus in the soil-saprolite continuum. We show how scanning electron microscope (SEM) images provide an appropriate scale to explore microbe mineral interactions in the CZ and can be used without extensive sample preparation. Through SEM imaging, we show that biofilms weather primary minerals, that macropores and fractures are hotspots of biofilm development, that biologic precipitation of short-range-order minerals (SROs) occurs in biofilms, and that biofilms are important in the process of organic matter stabilization.

Book chapter↗

USGS2021

Vitrinite reflectance analysis

Vitrinite is a maceral group (a set of organic matter types with similar properties and appearance) derived from the remains of woody material from vascular plants and is composed of the thermally evolved products of lignin and cellulose. Vitrinite is the dominant component of humic coal and is found as a minor component dispersed into sedimentary rocks, especially mudrocks, the primary source rocks for petroleum. Vitrinite reflectance analysis is the microscopical determination of the reflectance of incident light from vitrinite as calibrated to standards of known reflectance. The reflectance of vitrinite increases systematically with increasing thermal maturation during burial and heating of sedimentary rocks, and this property allows vitrinite reflectance analysis to be used as a common geothermometer for source rocks in petroliferous basins. Vitrinite reflectance analysis also is used as a method to determine coal rank.

Book chapter↗

USGS1976

Equilibrium-disequilibrium relations in the Monte Rosa Granite, Western Alps: Petrological, Rb-Sr and stable isotope data

Nine samples from the Monte Rosa Granite have been investigated by microscopic, X-ray, wet chemical, electron microprobe, stable isotope and Rb-Sr and K-Ar methods. Two mineral assemblages have been distinguished by optical methods and dated as Permian and mid-Tertiary by means of Rb-Sr age determinations. The Permian assemblage comprises quartz, orthoclase, oligoclase, biotite, and muscovite whereas the Alpine assemblage comprises quartz, microcline, albite+epidote or oligoclase, biotite, and phengite. Disequilibrium between the Permian and Alpine mineral assemblages is documented by the following facts: (i) Two texturally distinguishable generations of white K-mica are 2 M muscovite (Si=3.1–3.2) and 2 M or 3 T phengite (Si=3.3–3.4). Five muscovites show Permian Rb-Sr ages and oxygen isotope fractionations indicating temperatures between 520 and 560 ° C; however, K-Ar ages are mixed or rejuvenated. Phengite always shows mid-Tertiary Rb-Sr ages, (ii) Two biotite generations can be recognized, although textural evidence is often ambiguous. Three out of four texturally old biotites show mid-Tertiary Rb-Sr cooling ages while the oxygen isotopic fractionations point to Permian, mixed or Alpine temperatures, (iii) Comparison of radiogenic and stable isotope relations indicates that the radiogenic isotopes in the interlayer positions of the micas were mobilized during Alpine time without recrystallization, that is, without breaking Al-O or Si-O bonds. High Ti contents in young muscovites and biotites also indicate that the octahedral (and tetrahedral) sites remained undisturbed during rejuvenation. (iv) “Isotopic reversals” in the order of O 18 enrichment between K-feldspar and albite exist. Arguments for equilibrium during Permian time are meagre because of Alpine overprinting effects. Texturally old muscovites show high temperatures and Permian Rb-Sr ages in concordancy with Rb-Sr whole rock ages. For the tectonically least affected samples, excellent concordance between quartz-muscovite and quartz-biotite “Permian temperatures” implies oxygen isotope equilibrium in Permian time which was undisturbed during Alpine metamorphism. Arguments for equilibrium during the mid-Tertiary metamorphism are as follows: (i) Mid-Tertiary Rb-Sr mineral isochrons of up to six minerals exist, (ii) Oxygen isotope temperatures of coexisting Alpine phengites and biotites are concordant. The major factor for the adjustment of the Permian assemblages to Alpine conditions was the degree of Alpine tectonic overprinting rather than the maximum temperatures reached during the mid-Tertiary Alpine metamorphism. The lack of exchange with externally introduced fluid phases in the samples least affected by tectonism indicates that the Monte Rosa Granite “stewed in its own juices”. This seems to be the major cause for the persistence of Permian ages and corresponding temperatures.

Contributions to Mineralogy and Petrology↗

USGS1975

The orthoenstatite to clinoenstatite transformation by shearing and reversion by annealing: Mechanism and potential applications

Clinoenstatite (CE) was produced by deforming single-crystal specimens of ortho-enstatite (OE) in several different sorta of experiments. Examination with light and trans-mission electron microscopes shows that the transformation is coherent and involves a macroscopic shear on (100) [001] through an angle of 12.8±1.3 °, in good agreement with the theoretically expected value of 13.3 °, and that the transformation is accomplished by glide on (100) of partial dislocations with b = 0.83[001]. Structural analysis provides further insight into the transformation mechanism. Reversion occurs in specimens annealed under a variety of conditions, and thin lamellae of CE in unconstrained, low-strain specimens recover their original shape during transformation back to OE. Our experiments and thermodynamic estimates both suggest that the equilibrium transition temperature is raised roughly 300 ° C per kilobar of shear stress on (100) [001]. This provides the basis of a method by which it may be possible to determine the magnitude as well as the orientation of the principal stresses that produce CE in nature during deformation of enstatite-bearing rocks.

Contributions to Mineralogy and Petrology↗

USGS1993

Paper plant effluent revisited-southern Lake Champlain, Vermont and New York

We used geologic and geochemical techniques to document the change with time of the distribution and concentration of contaminated bottom sediments in southern Lake Champlain near an International Paper Company plant. Our work, initiated in 1972, was expanded on behalf of Vermont citizens in a class-action suit against the International Paper Company. To update our 1972-1973 results, we collected nine cores in 1988 upstream and downstream from the paper plant effluent diffuser. Water content, volatile solids, organic carbon, and three ratios, Al/Si, Cl/Si, and S/Si, in addition to megascopic and microscopic observations, were evaluated to identify and trace the distribution of effluent and to measure the thickness of sediment affected by or containing components of effluent. Analyses were carried out on samples from the cores as well as from effluent collected directly from the plant's waste treatment facility. In 1973, two years after the plant opened, we cored near the diffuser; sediment contaminated with effluent was 4.5 cm thick. In 1988, in the same area, sediment contaminated with effluent was 17 cm thick. In 15 years, water content increased from 72 to 85 percent, volatile solids from 7 to 20 percent, and organic carbon from 2 to 12 percent. Cl/Si and S/Si were high only near the diffuser and were zero elsewhere. In the area of the diffuser, contaminated sediment appears to be accumulating at a rate of about 1 cm/yr. At a control location 22 km upstream (south) from the plant, the top, poorly consoli-dated layer was only 1 cm or less thick both in 1973 and in 1988. The class-action suit was settled in favor of the plaintiffs for $5 million. ?? 1993 Springer-Verlag.

New York, Vermont↗

USGS1994

Direct observation of frictional contacts: New insights for state-dependent properties

Rocks and many other materials display a rather complicated, but characteristic, dependence of friction on sliding history. These effects are well-described by empirical rate- and state-dependent constitutive formulations which have been utilized for analysis of fault slip and earthquake processes. We present a procedure for direct quantitative microscopic observation of frictional contacts during slip. The observations reveal that frictional state dependence represents an increase of contact area with contact age. Transient changes of sliding resistance correlate with changes in contact area and arise from shifts of contact population age. Displacement-dependent replacement of contact populations is shown to cause the diagnostic evolution of friction over a characteristic sliding distance that occurs whenever slip begins or sliding conditions change. ?? 1994 Birkha??user Verlag.

Pure and Applied Geophysics PAGEOPH↗

USGS1977

Fluid inclusion geothermometry

Fluid inclusions trapped within crystals either during growth or at a later time provide many clues to the histories of rocks and ores. Estimates of fluid-inclusion homogenization temperature and density can be obtained using a petrographic microscope with thin sections, and they can be refined using heating and freezing stages. Fluid inclusion studies, used in conjunction with paragenetic studies, can provide direct data on the time and space variations of parameters such as temperature, pressure, density, and composition of fluids in geologic environments. Changes in these parameters directly affect the fugacity, composition, and pH of fluids, thus directly influencing localization of ore metals. ?? 1977 Ferdinand Enke Verlag Stuttgart.

Geologische Rundschau↗

USGS1990

The quantitative determination of FeS 2 phases in coal by means of 57 Fe Mössbauer spectroscopy

A knowledge of the concentration of pyrite and marcasite in coals can provide important insight into the genesis of coal deposits. Determinations of the relative amounts of pyrite and marcasite by traditional methods of coal analysis are, however, beset with many difficulties. Using 57 Fe Mössbauer spectroscopy and a mild chemical treatment with hydrofluoric acid, a technique has been devised for the quantitative determination of the relative concentrations of pyrite and marcasite in samples of whole coals or their low-temperature ashes. The sample preparation procedure is comparable to less accurate methods. Good qualitative agreement has been obtained between ore microscopic and Mössbauer spectroscopic techniques for a series of extensively investigated whole coal samples.

Hyperfine Interactions↗

USGS1980

Measurement of irrigated acreage in Western Kansas from LANDSAT images

In the past four decades, irrigated acreage in western Kansas has increased rapidly. Optimum utilization of vital groundwater supplies requires implementation of long-term water-management programs. One important variable in such programs is up-to-date information on acreage under irrigation. Conventional ground survey methods of estimating irrigated acreage are too slow to be of maximum use in water-management programs. Visual interpretation of LANDSAT images permits more rapid measurement of irrigated acreage, but procedures are tedious and still relatively slow. For example, using a LANDSAT false-color composite image in areas of western Kansas with few landmarks, it is impossible to keep track of fields by examination under low-power microscope. Irrigated fields are more easily delineated on a photographically enlarged false-color composite and are traced on an overlay for measurement. Interpretation and measurement required 6 weeks for a four-county (3140 mi2, 8133 km2) test area. Video image-analysis equipment permits rapid measurement of irrigated acreage. Spectral response of irrigated summer crops in western Kansas on MSS band 5 (visible red, 0.6-0.7 ??m) images is low in contrast to high response from harvested and fallow fields and from common soil types. Therefore, irrigated acreage in western Kansas can be uniquely discriminated by video image analysis. The area of irrigated crops in a given area of view is measured directly. Sources of error are small in western Kansas. After preliminary preparation of the images, the time required to measure irrigated acreage was 1 h per county (average area, 876 ml2 or 2269 km2). ?? 1980 Springer-Verlag New York Inc.

Environmental Geology↗

USGS2015

Extreme variation of sulfur isotopic compositions in pyrite from the Qiuling sediment-hosted gold deposit, West Qinling orogen, central China: An in situ SIMS study with implications for the source of sulfur

High spatial resolution textural (scanning electron microscope (SEM)), chemical (electron microprobe (EMP)) and laser ablation-inductively coupled plasma-mass spec- trometry (LA-ICP-MS)), and sulfur isotopic (secondary ion mass spectrometry (SIMS)) analyses of pyrite from the Qiuling sediment-hosted gold deposit (232±4 Ma) in the West Qinling orogen, central China were conducted to distinguish pyrite types and gain insights into the source and evolution of sulfur in hydrothermal fluids. The results reveal an enormous variation (−27.1 to +69.6‰) in sulfur isotopic composition of pyrite deposited during three paragenetic stages. Pre-ore framboidal pyrite, which is characterized by low concentra- tions of As, Au, Cu, Co, and Ni, has negative δ34S values of −27.1 to −7.6‰ that are interpreted in terms of bacterial re- duction of marine sulfate during sedimentation and diagenesis of the Paleozoic carbonate and clastic sequences, the predom- inant lithologies in the deposit area, and the most important hosts of many sediment-hosted gold deposits throughout the West Qinling orogen. The ore-stage hydrothermal pyrite con- tains high concentrations of Au, As, Cu, Sb, Tl, and Bi and hasa relatively narrow range of positive δ34S values ranging from +8.1 to +15.2‰. The sulfur isotope data are comparable to those of ore pyrite from many Triassic orogenic gold deposits and Paleozoic sedimentary exhalative (SEDEX) Pb-Zn de- posits in the West Qinling orogen, both being hosted mainly in the Devonian sequence. This similarity indicates that sulfur, responsible for the auriferous pyrite at Qiuling, was largely derived from the metamorphic devolatization of Paleozoic marine sedimentary rocks. Post-ore-stage pyrite, which is sig- nificantly enriched in Co and Ni but depleted in Au and As, has unusually high δ34S values ranging from +37.4 to +69.6 ‰, that are interpreted to result from thermochemical reduc- tion of evaporite sulfates in underlying Cambrian sedimentary rocks with very high δ34S values. The variations in Au content and sulfur isotopic compositions across a single ore-stage py- rite grain may reflect displacement of indigenous groundwater with low δ34S values by auriferous metamorphic fluids with high δ34S values. The very low-grade metamorphism of the host rocks and the metamorphic derivation of sulfur for the ore pyrite indicate that the Qiuling sediment-hosted gold deposit is an epizonal manifestation of an orogenic gold system in the West Qinling orogen.

Mineralium Deposita↗