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Bathymetry and absorptivity of Titan's Ontario Lacus

Ontario Lacus is the largest and best characterized lake in Titan's south polar region. In June and July 2009, the Cassini RADAR acquired its first Synthetic Aperture Radar (SAR) images of the area. Together with closest approach altimetry acquired in December 2008, these observations provide a unique opportunity to study the lake's nearshore bathymetry and complex refractive properties. Average radar backscatter is observed to decrease exponentially with distance from the local shoreline. This behavior is consistent with attenuation through a deepening layer of liquid and, if local topography is known, can be used to derive absorptive dielectric properties. Accordingly, we estimate nearshore topography from a radar altimetry profile that intersects the shoreline on the East and West sides of the lake. We then analyze SAR backscatter in these regions to determine the imaginary component of the liquid's complex index of refraction (κ). The derived value, κ = (6.1 −1.3 +1.7 ) × 10 −4 , corresponds to a loss tangent of tan Δ = (9.2 −2.0 +2.5 ) × 10 −4 and is consistent with a composition dominated by liquid hydrocarbons. This value can be used to test compositional models once the microwave optical properties of candidate materials have been measured. In areas that do not intersect altimetry profiles, relative slopes can be calculated assuming the index of refraction is constant throughout the liquid. Accordingly, we construct a coarse bathymetry map for the nearshore region by measuring bathymetric slopes for eleven additional areas around the lake. These slopes vary by a factor of ∼5 and correlate well with observed shoreline morphologies.

Journal of Geophysical Research E: Planets

Thin-skinned deformation of sedimentary rocks in Valles Marineris, Mars

Deformation of sedimentary rocks is widespread within Valles Marineris, characterized by both plastic and brittle deformation identified in Candor, Melas, and Ius Chasmata. We identified four deformation styles using HiRISE and CTX images: kilometer-scale convolute folds, detached slabs, folded strata, and pull-apart structures. Convolute folds are detached rounded slabs of material with alternating dark- and light-toned strata and a fold wavelength of about 1 km. The detached slabs are isolated rounded blocks of material, but they exhibit only highly localized evidence of stratification. Folded strata are composed of continuously folded layers that are not detached. Pull-apart structures are composed of stratified rock that has broken off into small irregularly shaped pieces showing evidence of brittle deformation. Some areas exhibit multiple styles of deformation and grade from one type of deformation into another. The deformed rocks are observed over thousands of kilometers, are limited to discrete stratigraphic intervals, and occur over a wide range in elevations. All deformation styles appear to be of likely thin-skinned origin. CRISM reflectance spectra show that some of the deformed sediments contain a component of monohydrated and polyhydrated sulfates. Several mechanisms could be responsible for the deformation of sedimentary rocks in Valles Marineris, such as subaerial or subaqueous gravitational slumping or sliding and soft sediment deformation, where the latter could include impact-induced or seismically induced liquefaction. These mechanisms are evaluated based on their expected pattern, scale, and areal extent of deformation. Deformation produced from slow subaerial or subaqueous landsliding and liquefaction is consistent with the deformation observed in Valles Marineris.

Journal of Geophysical Research E: Planets

Properties and distribution of paired candidate stony meteorites at Meridiani Planum

The Mars Exploration Rover Opportunity investigated four rocks, informally dubbed Barberton, Santa Catarina, Santorini, and Kasos, that are possible stony meteorites. Their chemical and mineralogical composition is similar to the howardite, eucrite, and diogenite group but with additional metal, similar to mesosiderite silicate clasts. Because of their virtually identical composition and because they appear to represent a relatively rare group of meteorites, they are probably paired. The four rocks were investigated serendipitously several kilometers apart, suggesting that Opportunity is driving across a larger population of similar rock fragments, maybe a meteorite strewn field. Small amounts of ferric Fe are a result of weathering. We did not observe evidence for fusion crusts. Four iron meteorites were found across the same area. Although mesosiderites are stony irons, a genetic link to these irons is unlikely. The stony meteorites probably fell later than the irons. The current atmosphere is sufficiently dense to land such meteorites at shallow entry angles, and it would disperse fragments over several kilometers upon atmospheric breakup. Alternatively, dispersion by spallation from an impacting meteoroid may have occurred. Santa Catarina and a large accumulation of similar rocks were found at the rim of Victoria crater. It is possible that they are associated with the impactor that created Victoria crater, but our limited knowledge about their distribution cannot exclude mere coincidence.

Journal of Geophysical Research E: Planets

Mineralogy and chemistry of cobbles at Meridiani Planum, Mars, investigated by the Mars Exploration Rover Opportunity

Numerous loose rocks with dimensions of a few centimeters to tens of centimeters and with no obvious physical relationship to outcrop rocks have been observed along the traverse of the Mars Exploration Rover Opportunity. To date, about a dozen of these rocks have been analyzed with Opportunity's contact instruments, providing information about elemental chemistry (Alpha Particle X‐ray Spectrometer), iron mineralogy and oxidation states (Mössbauer Spectrometer) and texture (Microscopic Imager). These “cobbles” appear to be impact related, and three distinct groups can be identified on the basis of chemistry and mineralogy. The first group comprises bright fragments of the sulfate‐rich bedrock that are compositionally and texturally indistinguishable from outcrop rocks. All other cobbles are dark and are divided into two groups, referred to as the “Barberton group” and the “Arkansas group,” after the first specimen of each that was encountered by Opportunity. Barberton group cobbles are interpreted as meteorites with an overall chemistry and mineralogy consistent with a mesosiderite silicate clast composition. Arkansas group cobbles appear to be related to Meridiani outcrop and contain an additional basaltic component. They have brecciated textures, pointing to an impact‐related origin during which local bedrock and basaltic material were mixed.

Journal of Geophysical Research E: Planets

Spirit Mars Rover Mission: Overview and selected results from the northern Home Plate Winter Haven to the side of Scamander crater

This paper summarizes Spirit Rover operations in the Columbia Hills, Gusev crater, from sol 1410 (start of the third winter campaign) to sol 2169 (when extrication attempts from Troy stopped to winterize the vehicle) and provides an overview of key scientific results. The third winter campaign took advantage of parking on the northern slope of Home Plate to tilt the vehicle to track the sun and thus survive the winter season. With the onset of the spring season, Spirit began circumnavigating Home Plate on the way to volcanic constructs located to the south. Silica‐rich nodular rocks were discovered in the valley to the north of Home Plate. The inoperative right front wheel drive actuator made climbing soil‐covered slopes problematical and led to high slip conditions and extensive excavation of subsurface soils. This situation led to embedding of Spirit on the side of a shallow, 8 m wide crater in Troy, located in the valley to the west of Home Plate. Examination of the materials exposed during embedding showed that Spirit broke through a thin sulfate‐rich soil crust and became embedded in an underlying mix of sulfate and basaltic sands. The nature of the crust is consistent with dissolution and precipitation in the presence of soil water within a few centimeters of the surface. The observation that sulfate‐rich deposits in Troy and elsewhere in the Columbia Hills are just beneath the surface implies that these processes have operated on a continuing basis on Mars as landforms have been shaped by erosion and deposition.

Journal of Geophysical Research E: Planets

Regional and grain size influences on the geochemistry of soil at Gusev Crater

Congruous with earlier work, Martian soil along the Spirit Rover's traverse at Gusev crater can be divided into three broad groups by size: fines (<150 μ m), sand, and a mix of various grain sizes. The key chemical observation is greater homogeneity in fines relative to the other two, consistent with regional‐ and global‐scale sampling of chemical compositions by finer particle sizes. The mix class is generally more heterogeneous as are samples from the Columbia Hills within each class. Variation in the trace element Ni is consistent with a CI contribution not exceeding 3%, while that of Ti is compatible with Fe‐Ti oxide enrichment not exceeding 3%. Physical mixing models are poorly supported. Among many potential binary and three‐component mixing models, only two show some consistency with the soil data: typical fines with the opaline Si end‐member identified at Home Plate and typical fines with sulfates (bearing a variable mix of Ca, Fe, and Mg cations). We also infer that binary mixing transcends classes, contrasting strongly with terrestrial sediments, and that mixing trends are consistent with significant nonmixing contributions, perhaps including localized chemical alteration. The decoupling between chemistry and grain size classes also suggests that processes linking composition with grain size, such as heavy mineral sorting, may have been minimal or absent entirely. The primary exception to this is the correlation between Cl and Si, Cl‐S, and Al‐Si, which is strongest in the fines class.

Journal of Geophysical Research E: Planets

Visible and near-infrared multispectral analysis of geochemically measured rock fragments at the Opportunity landing site in Meridiani Planum

We have used visible and near‐infrared Panoramic Camera (Pancam) spectral data acquired by the Opportunity rover to analyze 15 rock fragments at the Meridiani Planum landing site. These spectral results were then compared to geochemistry measurements made by the in situ instruments Mössbauer (MB) and Alpha Particle X‐ray Spectrometer (APXS) to determine the feasibility of mineralogic characterization from Pancam data. Our results suggest that dust and alteration rinds coat many rock fragments, which limits our ability to adequately measure the mineralogy of some rocks from Pancam spectra relative to the different field of view and penetration depths of MB and APXS. Viewing and lighting geometry, along with sampling size, also complicate the spectral characterization of the rocks. Rock fragments with the same geochemistry of sulfate‐rich outcrops have similar spectra, although the sulfate‐rich composition cannot be ascertained based upon Pancam spectra alone. FeNi meteorites have spectral characteristics, particularly ferric oxide coatings, that generally differentiate them from other rocks at the landing site. Stony meteorites and impact fragments with unknown compositions have a diverse range of spectral properties and are not well constrained nor diagnostic in Pancam data. Bounce Rock, with its unique basalt composition, is easily differentiated in the Pancam data from all other rock types at Meridiani Planum. Our Pancam analyses of small pebbles adjacent to these 15 rock fragments suggests that other rock types may exist at the landing site but have not yet been geochemically measured.

Journal of Geophysical Research E: Planets

Evidence for mechanical and chemical alteration of iron-nickel meteorites on Mars: Process insights for Meridiani Planum

The weathering of meteorites found on Mars involves chemical and physical processes that can provide clues to climate conditions at the location of their discovery. Beginning on sol 1961, the Opportunity rover encountered three large iron meteorites within a few hundred meters of each other. In order of discovery, these rocks have been assigned the unofficial names Block Island, Shelter Island, and Mackinac Island. Each rock presents a unique but complimentary set of features that increase our understanding of weathering processes at Meridiani Planum. Significant morphologic characteristics interpretable as weathering features include (1) a large pit in Block Island, lined with delicate iron protrusions suggestive of inclusion removal by corrosive interaction; (2) differentially eroded kamacite and taenite lamellae in Block Island and Shelter Island, providing relative timing through crosscutting relationships with deposition of (3) an iron oxide-rich dark coating; (4) regmaglypted surfaces testifying to regions of minimal surface modification, with other regions in the same meteorites exhibiting (5) large-scale, cavernous weathering (in Shelter Island and Mackinac Island). We conclude that the current size of the rocks is approximate to their original postfall contours. Their morphology thus likely results from a combination of atmospheric interaction and postfall weathering effects. Among our specific findings is evidence supporting (1) at least one possible episode of aqueous acidic exposure for Block Island; (2) ripple migration over portions of the meteorites; (3) a minimum of two separate episodes of wind abrasion; alternating with (4) at least one episode of coating-forming chemical alteration, most likely at subzero temperatures.

Journal of Geophysical Research E: Planets

Transient and steady state creep response of ice I and magnesium sulfate hydrate eutectic aggregates

Using uniaxial compression creep experiments, we characterized the transient and steady state deformation behaviors of eutectic aggregates of system ice I and MgSO4 11H2O (MS11; meridianiite), which has significance because of its likely presence on moons of the outer solar system. Synthetic samples of eutectic liquid bulk composition, which produce eutectic colonies containing 0.35-0.50 volume fraction MS11, were tested as functions of colony size and lamellar spacing, temperature (230-250 K), and confining pressure (0.1 and 50 MPa) to strains ???0.2. Up to a differential stress of 6 MPa, the ice I-MS11 aggregates display an order of magnitude higher effective viscosity and higher stress sensitivity than do aggregates of pure polycrystalline ice at the same conditions. The creep data and associated microstructural observations demonstrate, however, that the aggregates are additionally more brittle than pure ice, approaching rate-independent plasticity that includes rupture of the hydrate phase at 6-8 MPa, depending on the scale of the microstructure. Microstructures of deformed samples reveal forms of semibrittle flow in which the hydrate phase fractures while the ice phase deforms plastically. Semibrittle flow in the icy shell of a planetary body would truncate the lithospheric strength envelope and thereby decrease the depth to the brittle-ductile transition by 55% and reduce the failure limit for compressional surface features from 10 to ???6 MPa. A constitutive equation that includes eutectic colony boundary sliding and intracolony flow is used to describe the steady state rheology of the eutectic aggregates. Copyright ?? 2011 by the American Geophysical Union.

Journal of Geophysical Research E: Planets

Columbus crater and other possible groundwater-fed paleolakes of Terra Sirenum, Mars

Columbus crater in the Terra Sirenum region of the Martian southern highlands contains light‐toned layered deposits with interbedded sulfate and phyllosilicate minerals, a rare occurrence on Mars. Here we investigate in detail the morphology, thermophysical properties, mineralogy, and stratigraphy of these deposits; explore their regional context; and interpret the crater's aqueous history. Hydrated mineral‐bearing deposits occupy a discrete ring around the walls of Columbus crater and are also exposed beneath younger materials, possibly lava flows, on its floor. Widespread minerals identified in the crater include gypsum, polyhydrated and monohydrated Mg/Fe‐sulfates, and kaolinite; localized deposits consistent with montmorillonite, Fe/Mg‐phyllosilicates, jarosite, alunite, and crystalline ferric oxide or hydroxide are also detected. Thermal emission spectra suggest abundances of these minerals in the tens of percent range. Other craters in northwest Terra Sirenum also contain layered deposits and Al/Fe/Mg‐phyllosilicates, but sulfates have so far been found only in Columbus and Cross craters. The region's intercrater plains contain scattered exposures of Al‐phyllosilicates and one isolated mound with opaline silica, in addition to more common Fe/Mg‐phyllosilicates with chlorides. A Late Noachian age is estimated for the aqueous deposits in Columbus, coinciding with a period of inferred groundwater upwelling and evaporation, which (according to model results reported here) could have formed evaporites in Columbus and other craters in Terra Sirenum. Hypotheses for the origin of these deposits include groundwater cementation of crater‐filling sediments and/or direct precipitation from subaerial springs or in a deep (∼900 m) paleolake. Especially under the deep lake scenario, which we prefer, chemical gradients in Columbus crater may have created a habitable environment at this location on early Mars.

Journal of Geophysical Research E: Planets

Thorium abundances of basalt ponds in South Pole-Aitken basin: Insights into the composition and evolution of the far side lunar mantle

Imbrian-aged basalt ponds, located on the floor of South Pole-Aitken (SPA) basin, are used to provide constraints on the composition and evolution of the far side lunar mantle. We use forward modeling of the Lunar Prospector Gamma Ray Spectrometer thorium data, to suggest that at least five different and distinct portions of the far side lunar mantle contain little or no thorium as of the Imbrian Period. We also use spatial correlations between local thorium enhancements and nonmare material on top of the basalt ponds to support previous assertions that lower crustal materials exposed in SPA basin have elevated thorium abundances, consistent with noritic to gabbronoritic lithologies. We suggest that the lower crust on the far side of the Moon experienced multiple intrusions of thorium-rich basaltic magmas, prior to the formation of SPA basin. The fact that many of the ponds on the lunar far side have elevated titanium abundances indicates that the far side of the Moon experienced extensive fractional crystallization that likely led to the formation of a KREEP-like component. However, because the Imbrian-aged basalts contain no signs of elevated thorium, we propose that the SPA impact event triggered the transport of a KREEP-like component from the lunar far side and concentrated it on the nearside of the Moon. Because of the correlation between basaltic ponds and basins within SPA, we suggest that Imbrian-aged basaltic volcanism on the far side of the Moon was driven by basin-induced decompressional melting.

Journal of Geophysical Research E: Planets

Compositional diversity and geologic insights of the Aristarchus crater from Moon Mineralogy Mapper data

The Moon Mineralogy Mapper (M3) acquired high spatial and spectral resolution data of the Aristarchus Plateau with 140 m/pixel in 85 spectral bands from 0.43 to 3.0 m. The data were collected as radiance and converted to reflectance using the observational constraints and a solar spectrum scaled to the Moon-Sun distance. Summary spectral parameters for the area of mafic silicate 1 and 2 m bands were calculated from the M3 data and used to map the distribution of key units that were then analyzed in detail with the spectral data. This analysis focuses on five key compositional units in the region. (1) The central peaks are shown to be strongly enriched in feldspar and are likely from the upper plagioclase-rich crust of the Moon. (2) The impact melt is compositionally diverse with clear signatures of feldspathic crust, olivine, and glass. (3) The crater walls and ejecta show a high degree of spatial heterogeneity and evidence for massive breccia blocks. (4) Olivine, strongly concentrated on the rim, wall, and exterior of the southeastern quadrant of the crater, is commonly associated the impact melt. (5) There are at least two types of glass deposits observed: pyroclastic glass and impact glass. Copyright 2011 by the American Geophysical Union.

Journal of Geophysical Research E: Planets

M3 spectral analysis of lunar swirls and the link between optical maturation and surface hydroxyl formation at magnetic anomalies

We examined the lunar swirls using data from the Moon Mineralogy Mapper (M 3 ). The improved spectral and spatial resolution of M 3 over previous spectral imaging data facilitates distinction of subtle spectral differences, and provides new information about the nature of these enigmatic features. We characterized spectral features of the swirls, interswirl regions (dark lanes), and surrounding terrain for each of three focus regions: Reiner Gamma, Gerasimovich, and Mare Ingenii. We used Principle Component Analysis to identify spectrally distinct surfaces at each focus region, and characterize the spectral features that distinguish them. We compared spectra from small, recent impact craters with the mature soils into which they penetrated to examine differences in maturation trends on- and off-swirl. Fresh, on-swirl crater spectra are higher albedo, exhibit a wider range in albedos and have well-preserved mafic absorption features compared with fresh off-swirl craters. Albedoand mafic absorptions are still evident in undisturbed, on-swirl surface soils, suggesting the maturation process is retarded. The spectral continuum is more concave compared with off-swirl spectra; a result of the limited spectral reddening being mostly constrained to wavelengths less than ∼1500 nm. Off-swirl spectra show very little reddening or change in continuum shape across the entire M 3 spectral range. Off-swirl spectra are dark, have attenuated absorption features, and the narrow range in off-swirl albedos suggests off-swirl regions mature rapidly. Spectral parameter maps depicting the relative OH surface abundance for each of our three swirl focus regions were created using the depth of the hydroxyl absorption feature at 2.82 μ m. For each of the studied regions, the 2.82 μ m absorption feature is significantly weaker on-swirl than off-swirl, indicating the swirls are depleted in OH relative to their surroundings. The spectral characteristics of the swirls and adjacent terrains from all three focus regions support the hypothesis that the magnetic anomalies deflect solar wind ions away from the swirls and onto off-swirl surfaces. Nanophase iron (npFe 0 ) is largely responsible for the spectral characteristics we attribute to space weathering and maturation, and is created by vaporization/deposition by micrometeorite impacts and sputtering/reduction by solar wind ions. On the swirls, the decreased proton flux slows the spectral effects of space weathering (relative to nonswirl regions) by limiting the npFe 0 production mechanism almost exclusively to micrometeoroid impact vaporization/deposition. Immediately adjacent to the swirls, maturation is accelerated by the increased flux of protons deflected from the swirls.

Journal of Geophysical Research E: Planets

Lunar mare deposits associated with the Orientale impact basin: New insights into mineralogy, history, mode of emplacement, and relation to Orientale Basin evolution from Moon Mineralogy Mapper (M3) data from Chandrayaan-1

Moon Mineralogy Mapper (M3) image and spectral reflectance data are combined to analyze mare basalt units in and adjacent to the Orientale multiring impact basin. Models are assessed for the relationships between basin formation and mare basalt emplacement. Mare basalt emplacement on the western nearside limb began prior to the Orientale event as evidenced by the presence of cryptomaria. The earliest post-Orientale-event mare basalt emplacement occurred in the center of the basin (Mare Orientale) and postdated the formation of the Orientale Basin by about 60-100 Ma. Over the next several hundred million years, basalt patches were emplaced first along the base of the Outer Rook ring (Lacus Veris) and then along the base of the Cordillera ring (Lacus Autumni), with some overlap in ages. The latest basalt patches are as young as some of the youngest basalt deposits on the lunar nearside. M3 data show several previously undetected mare patches on the southwestern margins of the basin interior. Regardless, the previously documented increase in mare abundance from the southwest toward the northeast is still prominent. We attribute this to crustal and lithospheric trends moving from the farside to the nearside, with correspondingly shallower density and thermal barriers to basaltic magma ascent and eruption toward the nearside. The wide range of model ages for Orientale mare deposits (3.70-1.66 Ga) mirrors the range of nearside mare ages, indicating that the small amount of mare fill in Orientale is not due to early cessation of mare emplacement but rather to limited volumes of extrusion for each phase during the entire period of nearside mare basalt volcanism. This suggests that nearside and farside source regions may be similar but that other factors, such as thermal and crustal thickness barriers to magma ascent and eruption, may be determining the abundance of surface deposits on the limbs and farside. The sequence, timing, and elevation of mare basalt deposits suggest that regional basin-related stresses exerted control on their distribution. Our analysis clearly shows that Orientale serves as an excellent example of the early stages of the filling of impact basins with mare basalt. Copyright ?? 2011 by the American Geophysical Union.

Journal of Geophysical Research E: Planets

Opportunity Mars Rover mission: Overview and selected results from Purgatory ripple to traverses to Endeavour crater

Opportunity has been traversing the Meridiani plains since 25 January 2004 (sol 1), acquiring numerous observations of the atmosphere, soils, and rocks. This paper provides an overview of key discoveries between sols 511 and 2300, complementing earlier papers covering results from the initial phases of the mission. Key new results include (1) atmospheric argon measurements that demonstrate the importance of atmospheric transport to and from the winter carbon dioxide polar ice caps; (2) observations showing that aeolian ripples covering the plains were generated by easterly winds during an epoch with enhanced Hadley cell circulation; (3) the discovery and characterization of cobbles and boulders that include iron and stony-iron meteorites and Martian impact ejecta; (4) measurements of wall rock strata within Erebus and Victoria craters that provide compelling evidence of formation by aeolian sand deposition, with local reworking within ephemeral lakes; (5) determination that the stratigraphy exposed in the walls of Victoria and Endurance craters show an enrichment of chlorine and depletion of magnesium and sulfur with increasing depth. This result implies that regional-scale aqueous alteration took place before formation of these craters. Most recently, Opportunity has been traversing toward the ancient Endeavour crater. Orbital data show that clay minerals are exposed on its rim. Hydrated sulfate minerals are exposed in plains rocks adjacent to the rim, unlike the surfaces of plains outcrops observed thus far by Opportunity. With continued mechanical health, Opportunity will reach terrains on and around Endeavour's rim that will be markedly different from anything examined to date.

Journal of Geophysical Research E: Planets

Optical maturity variation in lunar spectra as measured by Moon Mineralogy Mapper data

High spectral and spatial resolution data from the Moon Mineralogy Mapper (M3) instrument on Chandrayaan-1 are used to investigate in detail changes in the optical properties of lunar materials accompanying space weathering. Three spectral parameters were developed and used to quantify spectral effects commonly thought to be associated with increasing optical maturity: an increase in spectral slope ("reddening"), a decrease in albedo ("darkening"), and loss of spectral contrast (decrease in absorption band depth). Small regions of study were defined that sample the ejecta deposits of small fresh craters that contain relatively crystalline (immature) material that grade into local background (mature) soils. Selected craters are small enough that they can be assumed to be of constant composition and thus are useful for evaluating trends in optical maturity. Color composites were also used to identify the most immature material in a region and show that maturity trends can also be identified using regional soil trends. The high resolution M3 data are well suited to quantifying the spectral changes that accompany space weathering and are able to capture subtle spectral variations in maturity trends. However, the spectral changes that occur as a function of maturity were observed to be dependent on local composition. Given the complexity of space weathering processes, this was not unexpected but poses challenges for absolute measures of optical maturity across diverse lunar terrains. Copyright 2011 by the American Geophysical Union.

Journal of Geophysical Research E: Planets

Field Reconnaissance Geologic Mapping of the Columbia Hills, Mars: Results from MER Spirit and MRO HiRISE Observations

Chemical, mineralogic, and lithologic ground truth was acquired for the first time on Mars in terrain units mapped using orbital Mars Reconnaissance Orbiter's High Resolution Imaging Science Experiment (MRO HiRISE) image data. Examination of several dozen outcrops shows that Mars is geologically complex at meter length scales, the record of its geologic history is well exposed, stratigraphic units may be identified and correlated across significant areas on the ground, and outcrops and geologic relationships between materials may be analyzed with techniques commonly employed in terrestrial field geology. Despite their burial during the course of Martian geologic time by widespread epiclastic materials, mobile fines, and fall deposits, the selective exhumation of deep and well-preserved geologic units has exposed undisturbed outcrops, stratigraphic sections, and structural information much as they are preserved and exposed on Earth. A rich geologic record awaits skilled future field investigators on Mars. The correlation of ground observations and orbital images enables construction of a corresponding geologic reconnaissance map. Most of the outcrops visited are interpreted to be pyroclastic, impactite, and epiclastic deposits overlying an unexposed substrate, probably related to a modified Gusev crater central peak. Fluids have altered chemistry and mineralogy of these protoliths in degrees that vary substantially within the same map unit. Examination of the rocks exposed above and below the major unconformity between the plains lavas and the Columbia Hills directly confirms the general conclusion from remote sensing in previous studies over past years that the early history of Mars was a time of more intense deposition and modification of the surface. Although the availability of fluids and the chemical and mineral activity declined from this early period, significant later volcanism and fluid convection enabled additional, if localized, chemical activity.

Journal of Geophysical Research E: Planets

Characteristics, distribution, origin, and significance of opaline silica observed by the Spirit rover in Gusev crater, Mars

The presence of outcrops and soil (regolith) rich in opaline silica (∼65–92 wt % SiO 2 ) in association with volcanic materials adjacent to the “Home Plate” feature in Gusev crater is evidence for hydrothermal conditions. The Spirit rover has supplied a diverse set of observations that are used here to better understand the formation of silica and the activity, abundance, and fate of water in the first hydrothermal system to be explored in situ on Mars. We apply spectral, chemical, morphological, textural, and stratigraphic observations to assess whether the silica was produced by acid sulfate leaching of precursor rocks, by precipitation from silica‐rich solutions, or by some combination. The apparent lack of S enrichment and the relatively low oxidation state of the Home Plate silica‐rich materials appear inconsistent with the originally proposed Hawaiian analog for fumarolic acid sulfate leaching. The stratiform distribution of the silica‐rich outcrops and their porous and brecciated microtextures are consistent with sinter produced by silica precipitation. There is no evidence for crystalline quartz phases among the silica occurrences, an indication of the lack of diagenetic maturation following the production of the amorphous opaline phase.

Journal of Geophysical Research E: Planets