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USGS2018

Spatial and temporal variability of pCO2, carbon fluxes and saturation state on the West Florida Shelf

The West Florida Shelf (WFS) is a source of uncertainty for the Gulf of Mexico carbon budget. Data from the synthesis of approximately 135,000 pCO2 values from over 96 cruises from the WFS show that the shelf waters fluctuate between being a weak source to a weak sink of carbon with the atmosphere. Overall, the shelf acts as a weak source of CO2 at 0.32 ± 1.5 mol m-2 yr-1. Subregions, however, reveal slightly different trends, where surface waters associated with 40 m – 200 m isobaths in the northern and southern WFS are generally weak sinks all year, except for summer when they act as sources of CO2. Conversely, nearshore waters (< 40 m) are a source of CO2 are a source all year round, particularly the southern shallow waters. The pCO2 of seawater has been increasing at a rate of approximately 5.26 µatm yr-1 as compared to atmospheric pCO2 which has increased at a rate of about 1.7 µatm yr-1 from 1996 to 2016. The pCO2 and CO2 flux on the shelf from 1996 - 2016 have increased about 49 µatm, and 1.08 mol m-2, respectively. The WFS is emitting 9.23 Tg C yr-1, with the southern nearshore region emitting the most at 9.01 Tg C yr-1 and the northern region acting as a sink of -1.96 Tg C yr-1.

West Florida shelf↗

USGS2014

Controls on methane released through ebullition in peatlands affected by permafrost degradation

Permafrost thaw in peat plateaus leads to the flooding of surface soils and the formation of collapse scar bogs, which have the potential to be large emitters of methane (CH 4 ) from surface peat as well as deeper, previously frozen, permafrost carbon (C). We used a network of bubble traps, permanently installed 20 cm and 60 cm beneath the moss surface, to examine controls on ebullition from three collapse bogs in interior Alaska. Overall, ebullition was dominated by episodic events that were associated with changes in atmospheric pressure, and ebullition was mainly a surface process regulated by both seasonal ice dynamics and plant phenology. The majority (>90%) of ebullition occurred in surface peat layers, with little bubble production in deeper peat. During periods of peak plant biomass, bubbles contained acetate-derived CH 4 dominated (>90%) by modern C fixed from the atmosphere following permafrost thaw. Post-senescence, the contribution of CH 4 derived from thawing permafrost C was more variable and accounted for up to 22% (on average 7%), in the most recently thawed site. Thus, the formation of thermokarst features resulting from permafrost thaw in peatlands stimulates ebullition and CH 4 release both by creating flooded surface conditions conducive to CH 4 production and bubbling as well as by exposing thawing permafrost C to mineralization.

Alaska↗

USGS2003

Sources of global warming of the upper ocean on decadal period scales

Recent studies find global climate variability in the upper ocean and lower atmosphere during the twentieth century dominated by quasi-biennial, interannual, quasi-decadal and interdecadal signals. The quasi-decadal signal in upper ocean temperature undergoes global warming/cooling of ???0.1??C, similar to that occuring with the interannual signal (i.e., El Nin??o-Southern Oscillation), both signals dominated by global warming/cooling in the tropics. From the National Centers for Environmental Prediction troposphere reanalysis and Scripps Institution of Oceanography upper ocean temperature reanalysis we examine the quasi-decadal global tropical diabetic heat storage (DHS) budget from 1975 to 2000. We find the anomalous DHS warming tendency of 0.3-0.9 W m-2 driven principally by a downward global tropical latent-plus-sensible heat flux anomaly into the ocean, overwhelming the tendency by weaker upward shortwave-minus-longwave heat flux anomaly to drive an anomalous DHS cooling tendency. During the peak quasi-decadal warming the estimated dissipation of DHS anomaly of 0.2-0.5 W m-2 into the deep ocean and a similar loss to the overlying atmosphere through air-sea heat flux anomaly are balanced by a decrease in the net poleward Ekman heat advection out of the tropics of 0.4-0.7 W m-2. This scenario is nearly the opposite of that accounting for global tropical warming during the El Nin??o. These diagnostics confirm that even though the global quasi-decadal signal is phase-locked to the 11-year signal in the Sun's surface radiative forcing of ???0.1 W m-2, the anomalous global tropical DHS tendency cannot be driven by it directly.

Journal of Geophysical Research C: Oceans↗

USGS1999

Ventifacts at the Pathfinder landing site

About half of the rocks at the Mars Pathfinder Ares Vallis landing site appear to be ventifacts, rocks abraded by windborne particles. Comparable resolution images taken by the Imager for Mars Pathfinder (IMP) camera and the Viking landers show that ventifacts are more abundant at the Pathfinder site. The ventifacts occur in several forms, including rocks with faceted edges, finger‐like projections, elongated pits, flutes, grooves, and possible rills. The trends of elongated pits, flutes, grooves, and rills cluster at ∼280–330° clockwise from north and generally dip 10–30° away from their trend direction. These orientations are indicative of southeast to northwest winds and differ from the trend of wind tails at the landing site, the direction of local wind streaks, and predictions of the Global Circulation Model, all of which indicate northeast to southwest winds. The disparity between these data sets strongly suggests that local circulation patterns have changed since the abrasion of the ventifacted rocks. The greater number of ventifacts at the Pathfinder site compared to either of the Viking sites is most easily explained as being due to a larger supply of abrading particles, composed of either sand‐sized grains or indurated dust aggregates, and higher surface roughness, which should increase the momentum of saltating grains. The Pathfinder ventifacts may have formed shortly after the deposition of outflow channel sediments nearly 2 Gry ago, when a large local supply of abrading particles should have been abundant and atmospheric conditions may have been more conducive to rock abrasion from saltating grains. Based on how ventifacts form on Earth, the several ventifact forms seen at the Pathfinder site and their presence on some rocks but not on others are probably due to local airflow conditions, original rock shape, exposure duration, rock movement, and to a lesser extent, rock lithology. The abundance of ventifacts at the Pathfinder site, together with other evidence of weathering, indicates that unaltered rock surfaces are rare on Mars.

Journal of Geophysical Research E: Planets↗

USGS2015

Source limitation of carbon gas emissions in high-elevation mountain streams and lakes

Inland waters are an important component of the global carbon cycle through transport, storage, and direct emissions of CO 2 and CH 4 to the atmosphere. Despite predictions of high physical gas exchange rates due to turbulent flows and ubiquitous supersaturation of CO 2 —and perhaps also CH 4 —patterns of gas emissions are essentially undocumented for high mountain ecosystems. Much like other headwater networks around the globe, we found that high-elevation streams in Rocky Mountain National Park, USA, were supersaturated with CO 2 during the growing season and were net sources to the atmosphere. CO 2 concentrations in lakes, on the other hand, tended to be less than atmospheric equilibrium during the open water season. CO 2 and CH 4 emissions from the aquatic conduit were relatively small compared to many parts of the globe. Irrespective of the physical template for high gas exchange (high k ), we found evidence of CO 2 source limitation to mountain streams during the growing season, which limits overall CO 2 emissions. Our results suggest a reduced importance of aquatic ecosystems for carbon cycling in high-elevation landscapes having limited soil development and high CO 2 consumption via mineral weathering.

Journal of Geophysical Research G: Biogeosciences↗

USGS2006

Physical properties of the Mars Exploration Rover landing sites as inferred from Mini-TES-derived thermal inertia

The Miniature Thermal Emission Spectrometer (Mini‐TES) on board the two Mars Exploration Rovers provides the first opportunity to observe thermal properties from the Martian surface, relate these properties to orbital data, and perform soil conductivity experiments under Martian conditions. The thermal inertias of soils, bedforms, and rock at each landing site were derived to quantify the physical properties of these features and understand geologic processes occurring at these localities. The thermal inertia for the Gusev plains rock target Bonneville Beacon (∼1200 J m −2 K −1 s −1/2 ) is consistent with a dense, basaltic rock, but the rocks at the Columbia Hills have a lower thermal inertia (∼620 J m −2 K −1 s −1/2 ), suggesting that they have a volcaniclasic origin. Bedforms on the floors of craters at both landing sites have thermal inertias of 200 J m −2 K −1 s −1/2 , consistent with a particle diameter of ∼160 μm. This diameter is comparable to the most easily moved grain size in the current atmosphere on Mars, suggesting that these bedforms may have formed under current atmospheric conditions. Along the Meridiani plains, the thermal inertia is lower than that derived from TES and Thermal Emission Imaging System (THEMIS) orbital data. This discrepancy is not well understood. Mini‐TES–derived thermal inertias at Gusev along a ∼2.5 km traverse follow trends in thermal inertia measured from orbit with TES and THEMIS. However, along the traverse, there are variability and mixing of particle sizes that are not resolved in the orbital thermal inertia data due to meter‐scale processes that are not identifiable at larger scales.

Journal of Geophysical Research E: Planets↗

USGS2003

High-resolution topomapping of candidate MER landing sites with Mars Orbiter Camera narrow-angle images

We analyzed narrow‐angle Mars Orbiter Camera (MOC‐NA) images to produce high‐resolution digital elevation models (DEMs) in order to provide topographic and slope information needed to assess the safety of candidate landing sites for the Mars Exploration Rovers (MER) and to assess the accuracy of our results by a variety of tests. The mapping techniques developed also support geoscientific studies and can be used with all present and planned Mars‐orbiting scanner cameras. Photogrammetric analysis of MOC stereopairs yields DEMs with 3‐pixel (typically 10 m) horizontal resolution, vertical precision consistent with ∼0.22 pixel matching errors (typically a few meters), and slope errors of 1–3°. These DEMs are controlled to the Mars Orbiter Laser Altimeter (MOLA) global data set and consistent with it at the limits of resolution. Photoclinometry yields DEMs with single‐pixel (typically ∼3 m) horizontal resolution and submeter vertical precision. Where the surface albedo is uniform, the dominant error is 10–20% relative uncertainty in the amplitude of topography and slopes after “calibrating” photoclinometry against a stereo DEM to account for the influence of atmospheric haze. We mapped portions of seven candidate MER sites and the Mars Pathfinder site. Safety of the final four sites (Elysium, Gusev, Isidis, and Meridiani) was assessed by mission engineers by simulating landings on our DEMs of “hazard units” mapped in the sites, with results weighted by the probability of landing on those units; summary slope statistics show that most hazard units are smooth, with only small areas of etched terrain in Gusev crater posing a slope hazard.

Journal of Geophysical Research E: Planets↗

USGS2010

Controls on mangrove forest‐atmosphere carbon dioxide exchanges in western Everglades National Park

We report on net ecosystem production (NEP) and key environmental controls on net ecosystem exchange (NEE) of carbon dioxide (CO 2 ) between a mangrove forest and the atmosphere in the coastal Florida Everglades. An eddy covariance system deployed above the canopy was used to determine NEE during January 2004 through August 2005. Maximum daytime NEE ranged from −20 to −25 μ mol (CO 2 ) m −2 s −1 between March and May. Respiration (R d ) was highly variable (2.81 ± 2.41 μ mol (CO 2 ) m −2 s −1 ), reaching peak values during the summer wet season. During the winter dry season, forest CO 2 assimilation increased with the proportion of diffuse solar irradiance in response to greater radiative transfer in the forest canopy. Surface water salinity and tidal activity were also important controls on NEE. Daily light use efficiency was reduced at high (>34 parts per thousand (ppt)) compared to low (<17 ppt) salinity by 46%. Tidal inundation lowered daytime R d by ∼0.9 μ mol (CO 2 ) m −2 s −1 and nighttime R d by ∼0.5 μ mol (CO 2 ) m −2 s −1 . The forest was a sink for atmospheric CO 2 , with an annual NEP of 1170 ± 127 g C m −2 during 2004. This unusually high NEP was attributed to year‐round productivity and low ecosystem respiration which reached a maximum of only 3 g C m −2 d −1 . Tidal export of dissolved inorganic carbon derived from belowground respiration likely lowered the estimates of mangrove forest respiration. These results suggest that carbon balance in mangrove coastal systems will change in response to variable salinity and inundation patterns, possibly resulting from secular sea level rise and climate change.

Florida↗

USGS2017

Terrestrial ecosystem model performance in simulating productivity and its vulnerability to climate change in the northern permafrost region

Realistic projection of future climate-carbon (C) cycle feedbacks requires better understanding and an improved representation of the C cycle in permafrost regions in the current generation of Earth system models. Here we evaluated 10 terrestrial ecosystem models for their estimates of net primary productivity (NPP) and responses to historical climate change in permafrost regions in the Northern Hemisphere. In comparison with the satellite estimate from the Moderate Resolution Imaging Spectroradiometer (MODIS; 246 ± 6 g C m −2 yr −1 ), most models produced higher NPP (309 ± 12 g C m −2 yr −1 ) over the permafrost region during 2000–2009. By comparing the simulated gross primary productivity (GPP) with a flux tower-based database, we found that although mean GPP among the models was only overestimated by 10% over 1982–2009, there was a twofold discrepancy among models (380 to 800 g C m −2 yr −1 ), which mainly resulted from differences in simulated maximum monthly GPP (GPP max ). Most models overestimated C use efficiency (CUE) as compared to observations at both regional and site levels. Further analysis shows that model variability of GPP and CUE are nonlinearly correlated to variability in specific leaf area and the maximum rate of carboxylation by the enzyme Rubisco at 25°C ( V c max_25 ), respectively. The models also varied in their sensitivities of NPP, GPP, and CUE to historical changes in climate and atmospheric CO 2 concentration. These results indicate that model predictive ability of the C cycle in permafrost regions can be improved by better representation of the processes controlling CUE and GPP max as well as their sensitivity to climate change.

Journal of Geophysical Research: Biogeosciences↗

USGS2008

Physical property changes in hydrate-bearing sediment due to depressurization and subsequent repressurization

Physical property measurements of sediment cores containing natural gas hydrate are typically performed on material exposed, at least briefly, to non-in situ conditions during recovery. To examine the effects of a brief excursion from the gas-hydrate stability field, as can occur when pressure cores are transferred to pressurized storage vessels, we measured physical properties on laboratory-formed sand packs containing methane hydrate and methane pore gas. After depressurizing samples to atmospheric pressure, we repressurized them into the methane-hydrate stability field and remeasured their physical properties. Thermal conductivity, shear strength, acoustic compressional and shear wave amplitudes, and speeds of the original and depressurized/repressurized samples are compared. X– ray computed tomography images track how the gas-hydrate distribution changes in the hydrate-cemented sands owing to the depressurizaton/repressurization process. Because depressurization-induced property changes can be substantial and are not easily predicted, particularly in water-saturated, hydrate-bearing sediment, maintaining pressure and temperature conditions throughout the core recovery and measurement process is critical for using laboratory measurements to estimate in situ properties.

Journal of Geophysical Research B: Solid Earth↗

USGS2012

An assessment of the accuracy of the geodetic measurements that define the southern California uplift

Examination of the charge that the geodetic measurements which define the southern California uplift are seriously flawed by height-dependent systematic errors indicates that this charge is unfounded. Our review of those factors designed to minimize the effects of rod error shows that systematic errors attributable to rod miscalibration are trivial and would tend to cancel during the particularly pertinent period 1955–1965. Comparisons between the results of measurements in which the correlation between topography and signal is generally poor reveal large aseismic tilts in a number of places within and around the margins of the uplift. Especially significant in this context are the results of preuplift and postuplift levelings over routes characterized by diverse length, topography, and atmospheric conditions that produce closely matching, temporally equivalent heights for a representative bench mark within the uplift. Statistical analyses of the short-wavelength components of uplift signal and elevation along a frequently repeated survey line indicate variable correlations between the two. However, the spatial and temporal patterns of these correlations are inconsistent with their attribution to height-dependent systematic errors. Statistically significant short-wavelength correlations along this survey line are reasonably explained in part as due to real movement associated with differentially subsiding bench marks, and there is a strong likelihood that this movement tends to dominate many of the correlations.

Journal of Geophysical Research Solid Earth↗

USGS2022

Ancient winds, waves, and atmosphere in Gale Crater, Mars, inferred from sedimentary structures and wave modeling

Wave modeling and analysis of sedimentary structures were used to evaluate whether four examples of symmetrical, reversing, or straight-crested bedforms in Gale crater sandstones are preserved wave ripples; deposition by waves would demonstrate that the lake was not covered by ice at that time. Wave modeling indicates that regardless of atmospheric density, winds that exceeded the threshold of aeolian sand transport could have generated waves capable of producing nearshore wave ripples in most grain sizes of sand. Reversing 3-m-wavelength bedforms in the Kimberley formation are interpreted not as wave ripples but rather as large aeolian ripples that formed in an atmosphere approximately as thin as at present. These exhumed bedforms define many of the ridges at outcrops that appear striated in satellite images. At Kimberley these bedforms demonstrably underlie and therefore predate subaqueous beds, suggesting that a thin atmosphere existed at least temporarily before subaqueous deposition ceased in the crater. The other three candidate wave ripples (Square Top, Hunda, and Voe) are consistent with modeled waves, but other origins cannot be excluded. The predominance of flat-laminated (non-rippled) beds in the lacustrine Murray formation suggests that some aspect of the lake was not conducive to formation or preservation of recognizable wave ripples. Water depths may generally have been too deep, lakebed sediment may have been too fine-grained, the lake may have been smaller than modeled, or the lake may have been covered by ice. Plain Language Summary Wave modeling and analysis of sedimentary structures were used to evaluate whether ancient lake deposits in Gale crater contain ripples formed by waves on the surface of the lake. Deposition by waves would show that the lake was not covered by ice at that time. Modeling shows that regardless of atmospheric density, winds capable of moving sand on land would generally have been strong enough to form waves that would produce ripples near shore. Large bedforms in the Kimberley formation are interpreted as ripples formed by the wind in an atmosphere similar to that of Mars today. These bedforms underlie and are older than other beds deposited in water, thereby showing that a thin atmosphere existed at least temporarily before deposition in water ceased in the crater. Three other candidate wave ripples are consistent with modeled waves, but other origins are possible. Thick sequences of sedimentary rock in Gale crater are flat-laminated rather than rippled, suggesting that some aspect of the lake was not favorable for their formation or preservation. Much of the lake may have been too deep or ice-covered, or the lake may have been smaller than modeled or had sediment too fine to form easily observed ripples.

Journal of Geophysical Research: Planets↗

USGS2016

Long period seismicity and very long period infrasound driven by shallow magmatic degassing at Mount Pagan, Mariana Islands

Long period (LP) seismicity and very long period infrasound (iVLP) were recorded during continuous degassing from Mount Pagan, Mariana Islands, in July 2013 to January 2014. The frequency content of the LP and iVLP events and delay times between the two arrivals were remarkably stable and indicate nearly co-located sources. Using phase-weighted stacking over similar events to dampen noise, we find that the LP source centroid is located 60 m below and 180 m west of the summit vent. The moment tensor reveals a volumetric source modeled as resonance of a subhorizontal sill intersecting a dike. We model the seismoacoustic wavefields with a coupled earth-air 3-D finite difference code. The ratios of pressure to velocity measured at the infrasound arrays are an order of magnitude larger than the synthetic ratios, so the iVLP is not the result of LP energy transmitting into the atmosphere at its epicenter. Based on crater shape and dimensions determined by structure from motion, we model the iVLP as acoustic resonance of an exponential horn. The source of the continuous plume from gas analysis is shallow magmatic degassing, which repeatedly pressurized the dike-sill portion of the conduit over the 7 months of observation. Periodic gas release caused the geologically controlled sill to partially collapse and resonate, while venting of gas at the surface triggered resonance in the crater. LP degassing only accounts for ~12% of total degassing, indicating that most degassing is relatively aseismic and that multiple active pathways exist beneath the vent.

Mount Pagan↗

USGS2018

Salt marsh loss affects tides and sediment budget in shallow bays

The current paradigm is that salt marshes and their important ecosystem services are threatened by global climate change; indeed, large marsh losses have been documented worldwide. Morphological changes associated with salt marsh erosion are expected to influence the hydrodynamics and sediment dynamics of coastal systems. Here the influence of salt marsh erosion on the tidal hydrodynamics and sediment storage capability of shallow bays is investigated. Hydrodynamics, sediment transport, and vegetation dynamics are simulated using the numerical framework Coupled Ocean‐Atmosphere‐Wave‐Sediment Transport in the Barnegat Bay‐Little Egg Harbor system, USA. We show that salt marsh erosion influences the propagation of tides into back‐barrier basins, reducing the periodic inundation and sediment delivery to marsh platforms. As salt marshes erode, the sediment trapping potential of marsh platforms decreases exponentially. In this test case, up to 50% of the sediment mass trapped by vegetation is lost once a quarter of the marsh area is eroded. Similarly, without salt marshes the sediment budget of the entire bay significantly declines. Therefore, a positive feedback might be triggered such that as the salt marsh retreats the sediment storage capacity of the system declines, which could in turn further exacerbate marsh degradation.

New Jersey↗

USGS2008

Distributed energy balance modeling of South Cascade Glacier, Washington and assessment of model uncertainty

We have developed a physically based, distributed surface energy balance model to simulate glacier mass balance under meteorological and climatological forcing. Here we apply the model to estimate summer ablation on South Cascade Glacier, Washington, for the 2004 and 2005 mass balance seasons. To arrive at optimal mass balance simulations, we investigate and quantify model uncertainty associated with selecting from a range of physical parameter values that are not commonly measured in glaciological mass balance field studies. We optimize the performance of the model by varying values for atmospheric transmissivity, the albedo of surrounding topography, precipitation-elevation lapse rate, surface roughness for turbulent exchange of momentum, and snow albedo aging coefficient. Of these the snow aging parameter and precipitation lapse rates have the greatest influence on the modeled ablation. We examined model sensitivity to varying parameters by performing an additional 103 realizations with parameters randomly chosen over a ??5% range centered about the optimum values. The best fit suite of model parameters yielded a net balance of -1.69??0.38 m water equivalent (WE) for the 2004 water year and -2.10??0.30 m WE up to 11 September 2005. The 2004 result is within 3% of the measured value. These simulations account for 91% and 93% of the variance in measured ablation for the respective years. Copyright 2008 by the American Geophysical Union.

Journal of Geophysical Research F: Earth Surface↗

USGS2014

Triggering and modulation of geyser eruptions in Yellowstone National Park by earthquakes, earth tides, and weather

We analyze intervals between eruptions (IBEs) data acquired between 2001 and 2011 at Daisy and Old Faithful geysers in Yellowstone National Park. We focus our statistical analysis on the response of these geysers to stress perturbations from within the solid earth (earthquakes and earth tides) and from weather (air pressure and temperature, precipitation, and wind). We conclude that (1) the IBEs of these geysers are insensitive to periodic stresses induced by solid earth tides and barometric pressure variations; (2) Daisy (pool geyser) IBEs lengthen by evaporation and heat loss in response to large wind storms and cold air; and (3) Old Faithful (cone geyser) IBEs are not modulated by air temperature and pressure variations, wind, and precipitation, suggesting that the subsurface water column is decoupled from the atmosphere. Dynamic stress changes of 0.1−0.2 MPa resulting from the 2002 M-7.9 Denali, Alaska, earthquake surface waves caused a statistically significant shortening of Daisy geyser's IBEs. Stresses induced by other large global earthquakes during the study period were at least an order of magnitude smaller. In contrast, dynamic stresses of >0.5 MPa from three large regional earthquakes in 1959, 1975, and 1983 caused lengthening of Old Faithful's IBEs. We infer that most subannual geyser IBE variability is dominated by internal processes and interaction with other geysers. The results of this study provide quantitative bounds on the sensitivity of hydrothermal systems to external stress perturbations and have implications for studying the triggering and modulation of volcanic eruptions by external forces.

Wyoming↗

USGS2001

TES premapping data: Slab ice and snow flurries in the Martian north polar night

In the 1970s, Mariner and Viking spacecraft observations of the north polar region of Mars revealed polar brightness temperatures that were significantly below the expected kinetic temperatures for CO 2 sublimation. For the past few decades, the scientific community has speculated as to the nature of these Martian polar cold spots. Thermal Emission Spectrometer (TES) thermal spectral data have shown these cold spots to result largely from fine‐grained CO 2 and have constrained most of these cold spots to the surface (or near‐surface). Cold spot formation is strongly dependent on topography, forming preferentially near craters and on polar slopes. TES data, combined with Mars Orbiter Laser Altimeter (MOLA) cloud data, suggest atmospheric condensates form a small fraction of the observed cold spots. TES observations of spectra close to a blackbody indicate that another major component of the polar cap is slab CO 2 ice; these spectrally bland regions commonly have a low albedo. The cause is uncertain but may result from most of the light being reflected toward the specular direction, from the slab ice being intrinsically dark, or from it being transparent. Regions of the cap where the difference between the brightness temperatures at 18 μm ( T 18 ) and 25 μm ( T 25 ) is less than 5° are taken to indicate deposits of slab ice. Slab ice is the dominant component of the polar cap at latitudes outside of the polar night.

Journal of Geophysical Research E: Planets↗

USGS2020

Timescales and processes of methane hydrate formation and breakdown, with application to geologic systems

Gas hydrate is an ice-like form of water and low molecular weight gas stable at temperatures of roughly -10ºC to 25ºC and pressures of ~3 to 30 MPa in geologic systems. Natural gas hydrates sequester an estimated one-sixth of Earth’s methane and are found primarily in deepwater marine sediments on continental margins, but also in permafrost areas and under continental ice sheets. When gas hydrate is removed from its stability field, its breakdown has implications for the global carbon cycle, ocean chemistry, marine geohazards, and interactions between the geosphere and the ocean-atmosphere system. Gas hydrate breakdown can also be artificially driven as a component of studies assessing the resource potential of these deposits. Furthermore, geologic processes and perturbations to the ocean-atmosphere system (e.g., warming temperatures) can cause not only dissociation, but also more widespread dissolution of hydrate or even formation of new hydrate in reservoirs. Linkages between gas hydrate and disparate aspects of Earth’s near-surface physical, chemical, and biological systems render an assessment of the rates and processes affecting the persistence of gas hydrate an appropriate Centennial Grand Challenge. This paper reviews the thermodynamic controls on methane hydrate stability and then describes the relative importance of kinetic, mass transfer, and heat transfer processes in the formation and breakdown (dissociation and dissolution) of gas hydrate. Results from numerical modeling, laboratory, and some fields studies are used to summarize the rates of hydrate formation and breakdown, followed by an extensive treatment of hydrate dynamics in marine and cryospheric gas hydrate systems.

Journal of Geophysical Research-Solid Earth↗