Search USGSSearch

SEARCH · Search USGS

Results for “Journal of Chemical Physics”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

134 records · Page 8Linked to original sources

Importance of storm events in controlling ecosystem structure and function in a Florida Gulf Coast estuary

From 8/95 to 2/01, we investigated the ecological effects of intra- and inter-annual variability in freshwater flow through Taylor Creek in southeastern Everglades National Park. Continuous monitoring and intensive sampling studies overlapped with an array of pulsed weather events that impacted physical, chemical, and biological attributes of this region. We quantified the effects of three events representing a range of characteristics (duration, amount of precipitation, storm intensity, wind direction) on the hydraulic connectivity, nutrient and sediment dynamics, and vegetation structure of the SE Everglades estuarine ecotone. These events included a strong winter storm in November 1996, Tropical Storm Harvey in September 1999, and Hurricane Irene in October 1999. Continuous hydrologic and daily water sample data were used to examine the effects of these events on the physical forcing and quality of water in Taylor Creek. A high resolution, flow-through sampling and mapping approach was used to characterize water quality in the adjacent bay. To understand the effects of these events on vegetation communities, we measured mangrove litter production and estimated seagrass cover in the bay at monthly intervals. We also quantified sediment deposition associated with Hurricane Irene's flood surge along the Buttonwood Ridge. These three events resulted in dramatic changes in surface water movement and chemistry in Taylor Creek and adjacent regions of Florida Bay as well as increased mangrove litterfall and flood surge scouring of seagrass beds. Up to 5 cm of bay-derived mud was deposited along the ridge adjacent to the creek in this single pulsed event. These short-term events can account for a substantial proportion of the annual flux of freshwater and materials between the mangrove zone and Florida Bay. Our findings shed light on the capacity of these storm events, especially when in succession, to have far reaching and long lasting effects on coastal ecosystems such as the estuarine ecotone of the SE Everglades.

Journal of Coastal Research

The compositionally zoned eruption of 1912 in the Valley of Ten Thousand Smokes, Katmai National Park, Alaska

On June 6–8, 1912, ∼ 15 km 3 of magma erupted from the Novarupta caldera at the head of the Valley of Ten Thousand Smokes (VTTS), producing ∼ 20 km 3 of air-fall tephra and 11–15 km 3 of ash-flow tuff within ∼ 60 hours. Three discrete periods of ash-fall at Kodiak correlate, respectively, with Plinian tephra layers designated A, CD, and FG by Curtis (1968) in the VTTS. The ash-flow sequence overlapped with but outlasted pumice fall A, terminating within 20 hours of the initial outbreak and prior to pumice fall C. Layers E and H consist mostly of vitric dust that settled during lulls, and Layer B is the feather edge of the ash flow. The fall units filled and obscured the caldera, but arcuate and radial fissures outline a 6-km 2 depression. The Novarupta lava dome and its ejecta ring were emplaced later within the depression. At Mt. Katmai, 10 km east of the 1912 vent, a 600-m-deep caldera of similar area also collapsed at about this time, probably owing to hydraulic connection with the venting magma system; but all known ejecta are thought to have erupted at Novarupta. Mingling of three distinctive magmas during the eruption produced an abundance of banded pumice, and mechanical mixing of chilled ejecta resulted in deposits with a wide range of bulk composition. Pumice in the initial fall unit (A) is 100% rhyolite, but fall units atop the ash flow are > 98% dacite; black andesitic scoria is common only in the ash flows and in near-vent air-fall tephra. Pumice counts show the first half of the ash-flow deposit to be 91–98% rhyolite, but progressive increases of dacite and andesite eventually reduced the rhyolitic component to < 2%. The later, rhyolite-poor flows were hotter, less mobile, and widely produced partially welded tuff and vapor-indurated sillar. The main ash flow was too deflated and sluggish 16 km from the vent to surmount a 25-m-high moraine in its path but was diverted around it and continued 5 km down-valley, engulfing and charring trees but not toppling all of them. Thin ash-flow veneers feather 30–40 m up the enclosing valley walls but only where a constriction in the central VTTS locally raised the flow level. In the upper VTTS, the “high sand mark” is not a veneer but a marginal bench formed in thick tuff by differential compaction. Flooding from adjacent glaciers led to phreatic explosions that ejected blocks of tuff more welded than any yet exposed. A cluster of phreatic craters dammed a lake atop the tuff, the breaching of which caused a flood that scoured the ash-flow surface in the central VTTS, transported 50-cm blocks of welded tuff > 20 km to the lowermost VTTS, and deposited 1–8 m of debris there. Rhyolitic ejecta contain only 1–2% phenocrysts but andesite and dacite have 30–45%. Quartz is present and augite absent only in the rhyolite, but all ejecta contain plagioclase, orthopyroxene, titanomagnetite, ilmenite, apatite, and pyrrhotite; rare olivine occurs in the andesite. The zoning ranges of phenocrysts in the rhyolitic and intermediate ejecta do not overlap. New chemical data show the bulk SiO 2 range to be: rhyolite 77 ± 0.6, dacite 66-64.5, and andesite 61.5–58.5%. The dacitic and andesitic ejecta contrast in color and density, and it is not certain whether they form a compositional continuum. Analyses reported by Fenner within the 66–76% SiO 2 range were of banded pumice and lava and of bulk tephra that mechanically fractionated and mixed during flight. Despite the gap of 10% SiO 2 , Fe-Ti-oxide temperatures show a continuous range from rhyolite (805–850°C) through dacite (855–955°C) to andesite (955–990°C). Thermal continuity and isotopic and trace-element data suggest that all were derived from a single magmatic system, whether or not they were physically contiguous before eruption. If the rhyolitic liquid separated from dacitic magma, extraction was so efficient that no dacitic phenocrysts were retained and no bulk compositions in the range 66–76% SiO 2 were created; if it were a partial melt of roof rocks atop an intermediate magma body, then such rocks had no O- or Sr-isotopic contrast with the andesite-dacite magma and clearly did not include the Jurassic arkosic or granitic basement. The presence of Holocene domes of pre-1912 glassy dacite adjacent to the 1912 vent suggest that the 7 km 3 (or more) of high-silica rhyolitic magma (a composition rare in the Aleutian arc) was generated in less than a few thousand years. The 1912 vent is semi-encircled by several andesitic stratocones and is as close to Mageik, Trident, and Griggs volcanoes as it is to Mt. Katmai. The erupted magma probably occupied only shallow levels of an extensive system of injection and storage under a cluster of several stratovolcanoes. Although Quaternary basalt is not known to have erupted here, the intrusion of basaltic magma probably sustains the greater-VTTS magmatic system.

Alaska

A comparison of Sr-Nd-Pb isotopes in young and old continental lithospheric mantle: Patagonia and eastern China

It is commonly accepted that beneath the continental crust lies a keel of lithospheric mantle, which extends 50–200 kilometres downward to a transition zone into the asthenosphere. The chemical and physical properties of this reservoir are best known through studies of the basalts and xenoliths that provide samples of the subcrustal mantle. Although sharing many characteristics with oceanic island basalts, some continental basalts become increasingly distinct isotopically as crustal age increases, strongly supporting a permanent association between crust and mantle. Consequently, the distinctive trace element and isotope composition of the lithospheric mantle is able to give important clues to its origin and evolution. The mantle under newly‐created crust is typified by a radiogenic isotope variability that emphasizes the materials from which the continental lithosphere is assembled. Old lithospheric mantle, on the other hand, exhibits more evolved isotopic patterns that attest to the existence of long‐lived, chemically complex systems. A comparison of the Pb, Sr and Nd isotopes in alkalic to sub‐alkalic basalt derived from Phanerozoic (Patagonia) and Middle Archaean to Early Proterozoic (eastern China) subcrustal mantle is useful for identifying ‘end‐member’ components of the lithosphere. One component, having an isotopic composition close to PREMA, either continues to evolve virtually unchanged after incorporation into the lithosphere or is, itself, a relatively new addition even to old lithosphere. Another component, beginning with the isotopic composition of BSE, undergoes significant reduction in U/Pb and Sm/Nd (but not Rb/Sr) upon incorporation into the lithosphere and, with time, shows an increasingly retarded evolution of 206 Pb/ 204 Pb and negative ε Nd‐values approaching the isotopic composition of EMI. Five models are discussed that relate the isotopic composition of the continental lithospheric mantle to that of other parts of the terrestrial system, which may be involved in its origin and evolution. The potential locations of the contributing components and the mechanisms and timing of their assembly into lithosphere are considered. Current knowledge, however, does not allow us to distinguish unequivocally among the various scenarios for the creation and evolution of this reservoir.

Australian Journal of Earth Sciences

Chemical hydrogeology in natural and contaminated environments

Chemical hydrogeology, including organic and inorganic aspects, has contributed to an increased understanding of groundwater flow systems, geologic processes, and stressed environments. Most of the basic principles of inorganic-chemical hydrogeology were first established by investigations of organic-free, regional-scale systems for which simplifying assumptions could be made. The problems of groundwater contamination are causing a shift of emphasis to microscale systems that are dominated by organic-chemical reactions and that are providing an impetus for the study of naturally occurring and manmade organic material. Along with the decrease in scale, physical and chemical heterogeneity become major controls. Current investigations and those selected from the literature demonstrate that heterogeneity increases in importance as the study site decreases from regional-scale to macroscale to microscale. Increased understanding of regional-scale flow systems is demonstrated by selection of investigations of carbonate and volcanic aquifers to show how applications of present-day concepts and techniques can identify controlling chemical reactions and determine their rates; identify groundwater flow paths and determine flow velocity; and determine aquifer characteristics. The role of chemical hydrogeology in understanding geologic processes of macroscale systems is exemplified by selection of investigations in coastal aquifers. Phenomena associated with the mixing zone generated by encroaching sea water include an increase in heterogeneity of permeability, diagenesis of minerals, and formation of geomorphic features, such as caves, lagoons, and bays. Ore deposits of manganese and uranium, along with a simulation model of ore-forming fluids, demonstrate the influence of heterogeneity and of organic compounds on geochemical reactions associated with genesis of mineral deposits. In microscale environments, importance of heterogeneity and consequences of organic reactions in determining the distribution and concentrations cf. constituents are provided by several studies, including infiltration of sewage effluent and migration of creosote in coastal plain aquifers. These studies show that heterogeneity and the dominance of organically controlled reactions greatly increase the complexity of investigations.Current investigations and those selected from the literature demonstrate that heterogeneity increases in importance as the study site decreases from regional-scale to macroscale to microscale. Increased understanding of regional-scale flow systems is demonstrated by selection of investigations of carbonate and volcanic aquifers to show how application of present-day concepts and techniques can identify controlling chemical reactions and determine their rates; identify groundwater flow paths and determine flow velocity; and determine aquifer characteristics. The role of chemical hydrogeology in understanding geologic processes of macroscale systems is exemplified by selection of investigations in coastal aquifers. Ore deposits of manganese and uranium, along with a simulation model of ore-forming fluids, demonstrate the influence of heterogeneity and of organic compounds on geochemical reactions associated with genesis of mineral deposits. In microscale environments, importance of heterogeneity is illustrated by studies of infiltration of sewage effluent and migration of creosote in coastal plain aquifers.

Journal of Hydrology

Factors of ecologic succession in oligotrophic fish communities of the Laurentian Great Lakes

Oligotrophic fish communities of the Great Lakes have undergone successive disruptions since the mid-1800s. Major contributing factors have been intensive selective fisheries, extreme modification of the drainage, invasion of marine species, and progressive physical&ndash;chemical changes of the lake environments. Lake Ontario was the first to be affected as its basin was settled and industrialized earliest, and it was the first to be connected by canals to the mid-Atlantic where the alewife ( Alosa pseudoharengus ) and sea lamprey ( Petromyzon marinus ) which ultimately became established in the Great Lakes were abundant. Oligotrophic fish communities were successively disrupted in Lakes Erie, Huron, Michigan, and Superior as the affects of population growth, industrialization, and marine invaders spread upward in the Laurentian drainage.The degree and sequence of response of families offish and species within families differed for each factor, but the sequence of change among families and species has been the same in response to each factor as it affected various lakes at different times. The ultimate result of the disruption of fish communities has been a reduction of productivity of oligotrophic species that ranges from extreme in Lake Ontario to moderate in Lake Superior, and which has reached a state of instability and rapid change in the upper three Great Lakes by the rnid-1900s similar to the situation in Lake Ontario in the mid-1800s. Since oligotrophic species (primarily salmonines, coregonines, and deepwater cottids) are the only kinds of fish that fully occupied the entire volume of the deepwater Great Lakes (Ontario, Huron, Michigan, and Superior), the fish biomass of these lakes has been reduced as various species declined or disappeared. In Lake Erie, which is shallow, and in the shallow bays of the deep lakes, oligotrophic species were replaced by mesotrophic species, primarily percids, which have successively increased and declined. All oligotrophic species are greatly reduced or extinct in lakes Ontario and Erie, and are in various stages of decline in lakes Huron, Michigan, and Superior, from greatest to least, respectively. The percids appear to be near the end of their sequence of succession in lakes Erie, Ontario, and Huron (primarily Saginaw Bay) where only the yellow perch ( Perca flavescens ) remains abundant. The yellow perch appears to be on the brink of decline in Lake Erie, which has been more severely influenced by water quality change than the other lakes.

Journal of the Fisheries Research Board of Canada

Facies development in the Lower Freeport coal bed, west-central Pennsylvania, U.S.A.

The Lower Freeport coal bed in west-central Pennsylvania is interpreted to have formed within a lacustrine-mire environment. Conditions of peat formation, caused by the changing chemical and physical environments, produced five coal facies and two mineral-rich parting facies within the coal bed. The coal bed facies are compositionally unique, having developed under varying conditions, and are manifested by megascopic, petrographic, palynologic and quality characteristics. The initial environment of the Lower Freeport peat resulted in a coal facies that is relatively high in ash yield and contains large amounts of lycopod miospores and moderate abundances of cryptotelinite, crypto-gelocollinite, inertinite and tree fern miospores. This initial Lower Freeport peat is interpreted to have been a topogenous body that was low lying, relatively nutrient rich (mesotrophic to eutrophic), and susceptible to ground water and to sediment influx from surface water. The next facies to form was a ubiquitous, clay-rich durain parting which is attributed to a general rise in the water table accompanied by widespread flooding. Following formation of the parting, peat accumulation resumed within an environment that inhibited clastic input. Development of doming in this facies restricted deposition of the upper shale parting to the margins of the mire and allowed low-ash peat to form in the interior of the mire. Because this environment was conducive to preservation of cellular tissue, this coal facies also contains large amounts of crypto-telinite. This facies development is interpreted to have been a transitional phase from topogenous, planar peat formation to slightly domed, oligotrophic (nutrient-poor) peat formation. As domed peat formation continued, fluctuations in the water table enabled oxidation of the peat surface and produced high inertinite concentrations toward the top of the coal bed. Tree ferns became an increasingly important peat contributor in the e upper facies, based on the palynoflora. This floral change is interpreted to have resulted from the peat surface becoming less wet or better drained, a condition that inhibited proliferation of lycopod trees. Accumulation of the peat continued until rising water levels formed a freshwater lake within which clays and silts were deposited. The development of the Lower Freeport peat from a planar mire through transitional phases toward domed peat formation may be an example of the type of peat formation of other upper Middle and Upper Pennsylvanian coal beds.

International Journal of Coal Geology

Lake sturgeon response to a spawning reef constructed in the Detroit river

Prior to the First World War, the bi-national Detroit River provided vast areas of functional fish spawning and nursery habitat. However, ongoing conflicting human uses of these waters for activities such as waste disposal, water withdrawals, shoreline development, shipping, recreation, and fishing have altered many of the chemical, physical, and biological processes of the Detroit River. Of particular interest and concern to resource managers and stakeholders is the significant loss and impairment of fish spawning and nursery habitat that led to the decline in abundance of most fish species using this ecosystem. Lake sturgeon ( Acipenser fulvescens ) populations for example, were nearly extirpated by the middle of the 20th century, leaving only a small fraction of their former population. Fisheries managers recognized that the loss of suitable fish spawning habitat is a limiting factor in lake sturgeon population rehabilitation in the Detroit River. In efforts to remediate this beneficial water use impairment, a reef consisting of a mixture of natural rock and limestone was constructed at the upstream end of Fighting Island in 2008. This paper focuses on the response by lake sturgeon to the different replicates of suitable natural materials used to construct the fish spawning habitat at Fighting Island in the Detroit River. Pre-construction fisheries assessment during 2006–2008 showed that along with the presence of adult lake sturgeon, spawning conditions were favorable. However, no eggs were found in assessments conducted prior to reef construction. The 3300 m 2 Fighting Island reef was placed at the upstream end of the island in October of 2008. The construction design included 12 spawning beds of three replicates each consisting of either round rock, small or large (shot-rock) diameter limestone or a mixture thereof. An observed response by spawning lake sturgeon occurred the following year when spawning-ready adults (ripe), viable eggs, and larvae were collected during May and June 2009. Additional eggs and spawning-ready adults were found in 2010 (no larval sampling occurred in 2010) as well as collection of three age-0 juvenile lake sturgeon in bottom trawls fished downstream of the reef during July 2010. Spawning lake sturgeon showed no repeatable preference for any of the four particular substrate types but showed a high degree of preference for the island side of the channel, where faster water current velocities occurred. In 2009, overall lake sturgeon egg densities across all replicates averaged 102 m -2 and seven larvae were found in night drift-net samples. In 2010, average lake sturgeon egg density was 12 m -2 and three age-0 lake sturgeon averaging 120 mm TL were collected in bottom trawls in deepwater (∼8 m depth) downstream from the constructed reef. These results demonstrated successful reproduction by lake sturgeon on a man-made reef and suggested that additions and improvements to fish spawning habitat could enhance reproduction and early life history survival of lake sturgeon in the Detroit River.

Michigan;Ontario

Economics and coal resource appraisal: strippable coal in the Illinois Basin ( USA)

Coal-resource appraisals generally describe the location and general characteristics of coal beds. Estimates are made of the average overburden depth (depth of the coal bed below the surface), bed thickness, and perhaps certain chemical properties of the coal [1]. Although such resource compilations represent an important initial step, neither they nor current estimates provide sufficient information to determine the costs of alternative options for National energy policy. Because coal is expected to provide an increasing part of future overall U.S. energy supply, it is crucial for long term planning that coalresource appraisals convey sufficient information regarding the degree of economic resource scarcity (escalation of unit costs for mining remaining deposits as the best deposits in an area are mined out) expected as coal consumption increases. However, assumptions embodied in most large-scale models of coal supply [13; 20] imply that the coal reserves that exist can be commercially produced as needed. As demonstrated by the embargo of 1973-1974 and more recent difficulties in obtaining crude oil, even a slight temporary commodity shortfall will result in significant economic losses when the commodity supplies a large proportion of the total energy used by an economy. For the United States, crude oil resource estimates did not give warning of a decline in domestic petroleum product. In this paper we argue that coal-resource estimates, as they are now made, will not give warning of future supply difficulties. A method for incorporating an economic dimension into appraisals of strippable coal resources is presented and is applied to a major U.S. coal-producing region, the Illinois part of the Illinois basin. Illinois accounts for nearly 70% of the demonstrated strippable coal reserve base of the Illinois basin [12]. In particular, a long-run incremental cost function (that is unit costs vs. cumulative reserves extracted) is estimated for strippable coal in Illinois. The estimated cost function exhibits an initial range over which costs increase at a constant rate-followed by a range where costs increase very rapidly and the function becomes quite inelastic. This long-run incremental cost function is significant for two reasons. Comparison of the demonstrated reserve base for strippable coal (14.8 billion tons) with cumulative production (since 1920 of 1.1 billion tons) might suggest that future depletion will not be significant when, in fact, the cost function presented here indicates otherwise. Because the only states having more reserves of strippable coal than Illinois are Montana and Wyoming [18], these results have implications for national coal-resource appraisal. Secondly, most models used to study the effects of alternative public policies in coal markets are static in nature [15; 16] and cannot consider the effects of increasing costs. Furthermore, models which are multi-period in nature [11; 13] appear to have little empirical basis for their assumptions regarding the escalation of production costs resulting from depletion. The plan of the paper is as follows. First a description of the analytical approach for constructing the long-run incremental cost-reserve function is discussed. Following this, the descriptions of the Illinois basin and the basic physical data are presented. In the concluding section, the main results are presented and their implications are explored

Southern Economic Journal