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Hydrology of the Floridan Aquifer in Northwest Volusia County, Florida

Northwest Volusia County, in east-central Florida, is a 262-square-mile area including the southern part of the Crescent City Ridge and the northern tip of the DeLand Ridge. The hydrogeologic units in the area include the Floridan aquifer, which is made up of parts of the Lake City Limestone, the Avon Park Limestone, and the Ocala Limestone, all of Eocene age; the confining bed, which is composed of clays of Miocene or Pliocene age; and the surficial aquifer, which is made up of Pleistocene and Holocene sands. Ornamental fern growing is a $12 million per year industry in northwest Volusia County. Fern culture requires a large amount of good-quality water for irrigation, and more significantly, a large water withdrawal rate for freeze protection during winter months. The source of most water used is the Floridan aquifer. The large irrigation withdrawals, especially in winter months when spray irrigation is used for freeze protection of ferns, introduce problems such as the potential for saltwater intrusion, the temporary loss of water in domestic wells caused by large potentiometric drawdown, and increased sinkhole activity. The water budget of the surficial layer consists of 55 inches per year rainfall, 39 inches per year evapotranspiration, 13 inches per year runoff, and a net downward leakage of 3 inches per year. Average ground-water irrigational withdrawal is 8.1 million gallons per day, while the peak withdrawal rate is 300 million gallons per day during freeze-protection pumpage. The average irrigation well depth exceeds 300 feet. Transmissivities of the Floridan aquifer range from 4,500 to 160,000 feet squared per day. Highest transmissivities are in the DeLeon Springs area and the lowest are in the east Pierson area. Storage coefficients range from 0.0003 to 0.0013. The water budget of the Floridan aquifer under present conditions of withdrawal consists of 108 cubic feet per second recharge, 2 cubic feet per second horizontal ground-water inflow, 34 cubic feet per second direct discharge, 40 cubic feet per second upward leakage, 22 cubic feet per second horizontal outflow, and 14 cubic feet per second pumpage. The Floridan aquifer contains good-quality water in most of the study area, but also contains brackish water underneath the stressed zones and in the upper zones along the western and southern limits of the area. The altitude of the fresh- saltwater interface varies in the area from 1,500 to 300 feet below sea level. Areal drawdowns in the fern-growing areas of Pierson are 5 feet during growth irrigation periods and 20 to 30 feet during freeze-protection withdrawals. The drawdown in the Pierson area at the end of one intense period of pumpage exceeded 30 feet over a 4.4-square-mile area. A significant amount of the withdrawn water was replaced by leakage during the pumping period. Drawdowns in some pumping wells in northeast Pierson exceed 90 feet during freeze-protection withdrawals. No long-term residual drawdown has occurred. The predominant effect of pumpage on the water budget of the Floridan aquifer has been an increase in recharge. Sinkhole activity has been increased by the temporary increase in load on the aquifer's skeletal structure during intense lowering of the potentiometric surface. There is no evidence of saltwater intrusion, but a monitoring network for future early detection is suggested.

Open-File Report

Chemical quality of surface waters, and sedimentation in the Grand River drainage basin, North and South Dakota

An investigation of the chemical quality of surface waters and of the sedimentation in the Grand River drainage basin by the U.S. Geological Survey began in 1946. The chemical quality of the water was studied to obtain information on the nature and amounts of dissolved solids in the streams and on the suitability of the water for domestic, industrial, and irrigation uses. Sedimentation was studied to determine the quantity of sediment that is transported by the streams, the particle sizes of the sediment, and the probable specific weight of the sediment when deposited in a reservoir. The basin is underlain by consolidated sedimentary rocks of Cretaceous and Tertiary age; along the Grand River and its tributaries thefe rocks are mantled by alluvium of Quaternary age. The Hell Creek and Fort Union Formations underlie about 4,700 of the 5,680 square miles of drainage area. The climate of the basin is semiarid and is characterized by tot summers and cold winters. Mean annual runoff is about 53 acre-feet per square mile of drainage area and is equal to about 7 percent of the mean annual precipitation. The highest streamflows on the Grand River and major- tributaries are caused by melting of snow in March and April. Streamflow is extremely variable from year to year. Most of the surface waters in the basin are of the sodium sulfate or sodium bicarbonate type. High percent sodium is typical of almost all the surface water's. The streamflow-quality patterns of the Grand River and its two forks are very similar; dissolved-solids concentration, which usually c'oes not exceed 3,000 ppm, is maximum during low-flow periods. The water in Shadehill Reservoir became stratified during the flood inflow of 1952; about 75 percent of the flood water, which was of good qutlity, passed through the reservoir. The quality of the water became almost uniform throughout the reservoir the latter part of July 1952. After the specific conductance became relatively stable in 1956, it fluctuated from abrut 1,300 to 1,600 micromhos per centimeter and was between 1,400 and 1,500 rnicromhos per centimeter most of the time. During the representative period July 1937 to June 1950 the quantity of dissolved solids passing the station near Wakpala was estimated to have been about 140,000 tons per year. Yields computed for different parts of the basin ranged from about 22 to 32 tons per square mile. Except for sulfate, concentrations of chemical constituents usually do not exceed the maximum concentrations recommended for domestic supplies. The rather high dissolved solids and hardness of most of the surface waters prevent the use of these waters for most industrial purposes unless the quality is improved by treatment. Classified for irrigation use according to its specific conductance and sodiumadsorption-ratio, the water stored in Shadehill Reservoir has a high salinity hazard and a medium sodium hazard. The water can be used safely forsustained irrigation on soils of the proposed irrigation unit if adequate teaching is practiced and if gypsum or some other calcium compound is added to the water or land during the high sodium cycle.

North Dakota, South Dakota

Ground-water reconnaissance in Round Valley, Custer County, Idaho

Round Valley in central Idaho contains alluvial deposits of Pleistocene and Recent age which yield adequate supplies of ground water for stock and domestic wells. The alluvial deposits are underlain by Challis Volcanics of Oligocene or Early Miocene age and a few wells obtain domestic and stock water from the basalt, iatite, andesite, and rhyolite which are the principal rocks in the Challis. Very crude estimates indicate that the average annual recharge to the alluvium and Challis Volcanics from precipitation and irrigation is 50,000 acre-feet. Geologic and well data suggest that sufficient ground water might be obtained for irrigation supplies at some places.

Idaho

Ground-water conditions in Pecos County, Texas, 1987

A comparison of 1987 water levels with historical (1940-49) water levels in the Edwards-Trinity (Plateau) aquifer indicated that water levels declined more than 50 feet in three locations in the Leon-Belding irrigation area, in an area north of Fort Stockton, and in a well east of Bakersfield. Maximum measured declines were 54 and 82 feet in the Leon-Belding irrigation area. The maximum measured rise was 55 feet in one well in east-central Pecos County. The chemical quality of water in the Edwards-Trinity aquifer of Pecos County varied greatly during 1987. Most wells in the eastern, southern, and southwestern parts of the county had water with a specific conductance of 1,000 μ S/cm (microsiemens per centimeter at 25 °C) or less. Three areas that had anomalously large specific conductances in ground water in north-central Pecos County are associated with water issuing from Santa Rosa, Diamond Y, and Comanche Springs. Specific conductance in water from wells and springs ranged from 311 μ S/cm in south-central Pecos County to 9,600 μ S/cm in the north. Dissolved sulfate concentrations ranged from 17 to 2,300 mg/L (milligrams per liter), and dissolved chloride concentrations ranged from 12 to 1,400 mg/L. Dissolved-solids concentrations ranged from 251 to 5,580 mg/L. Total nitrite plus nitrate concentrations (considered to be all nitrate for this report) ranged from less than 0.1 to 8.9 mg/L. Chemical water types range from calcium bicarbonate to calcium sulfate to sodium chloride. Historical (1940-49) and 1987 dissolved-solids concentrations were compared to identify potential changes in water quality. In some local areas, dissolved-solids concentrations decreased as much as 1,630 mg/L. The increase in dissolved-solids concentrations in water from wells and springs ranged from 5 to 4,894 mg/L. Maximum increases in dissolved-solids concentrations were 3,290 mg/L in water from Comanche Springs and 4,894 mg/L in water from Santa Rosa Springs. The increases may represent a mixing of Edwards-Trinity water with moderately saline water from underlying rocks of Permian age, or an accumulation of salts from surface-water sources. Comanche Springs, dry since 1961, began flowing again in October 1986, following several weeks of record or near-record precipitation in Fort Stockton and the Trans-Pecos region. Accelerated recharge from the increased precipitation, combined with a cessation of irrigation pumpage in August 1986, probably were responsible. The springs ceased flowing in May 1987, following the start of irrigation pumpage in February 1987. Correlation between flow from Comanche Springs and water levels in Fort Stockton city well no. 2 in the Leon-Belding irrigation area indicates that the springs are unlikely to flow when the depth to water in this well exceeds about 232 feet.

Texas

Shallow ground-water quality beneath cropland in the Red River of the North Basin, Minnesota and North Dakota, 1993-95

During 1993-95, the agriculture on two sandy, surficial aquifers in the Red River of the North Basin affected the quality of shallow ground water in each aquifer differently. The Sheyenne Delta aquifer, in the western part of the basin, had land-use, hydrogeological, and rainfall characteristics that allowed few agricultural chemicals to reach or remain in the shallow ground water. The Otter Tail outwash aquifer, in the eastern part of the basin, had characteristics that caused significant amounts of nutrients and pesticides to reach and remain in the shallow ground water. Shallow ground water from both aquifers is dominated by calcium, magnesium, and bicarbonate ions. During the respective sampling periods, water from the Sheyenne Delta aquifer was mostly anoxic and water from the Otter Tail outwash aquifer had a median dissolved oxygen concentration of 3.6 mg/L (milligrams per liter). The median nitrate concentration was 0.03 mg/L as nitrogen (mg/L-N) in shallow ground water from the Sheyenne Delta aquifer and 6.1 mg/L-N in that from the Otter Tail outwash aquifer. Of 18 herbicides and 4 insecticides commonly used in the aquifer areas and for which analyses were done, 5 herbicides and 1 herbicide metabolite were detected in the shallow ground water from the Sheyenne Delta aquifer and 8 herbicides and 2 metabolites were detected in that from the Otter Tail outwash aquifer. The total herbicide concentration median was less than the detection limit in shallow ground water from the Sheyenne Delta aquifer and 0.023 μ g/L (micorgrams per liter) in that from the Otter Tail outwash aquifer. Triazine herbicides were the most commonly detected herbicides and were detected at the highest concentrations in the shallow ground water from both study areas. One sample from the Sheyenne Delta aquifer contained a high concentration of picloram. Agricultural chemicals in both aquifers were stratified vertically and their concentration correlated inversely with ground-water age. The highest concentrations of these chemicals and the youngest ground-water ages were at the water table. Concentrations decreased and age increased with water-table depth. Nitrate concentration varied seasonally over one-half an order of magnitude, though concentrations only repeated seasonally in some shallow ground water. Land-use factors that increased nitrate and herbicide concentrations were greater tilled area, chemical application, irrigation, and cropland contiguity. Hydrogeological factors that increased these concentrations were a deeper watertable (higher oxygen concentration and less organic carbon), larger grain-size and degree of sorting of aquifer material (shorter time in the soil zone and aquifer), and fewer sulfur-containing minerals (lignite and pyrite) composing the aquifer. High rainfall, just before sampling of the Sheyenne Delta aquifer, contributed to the relatively low nitrate and pesticide concentrations in the shallow ground water of this aquifer by raising the water table higher into the soil zone, increasing ponded water (increasing biodegradation), preventing some chemical application (flooded fields), and leaching and then displacing nitrate-rich water downward, beneath new recharge. The shallow ground-water quality measured beneath cropland in these land-use study areas covers a large range. The land-use, hydrogeological, and rainfall factors controlling this quality also control shallow ground-water quality in other surficial aquifers in the Red River of the North Basin. Although not used for drinking water, 43% of the shallow ground water from the Otter Tail outwash aquifer was above the U.S. Environmental Protection Agency's nitrate maximum contaminant level of 10 mg/L-N, reducing its potential uses. These high nitrate concentrations do not threaten the Otter Tail outwash aquifer's surface-water bodies with eutrophication however, because significant denitrification occurs beneath riparian wetlands before ground water discharges to surface waters.

Minnesota, North Dakota, South Dakota

Vertical gradients in water chemistry in the central High Plains aquifer, southwestern Kansas and Oklahoma panhandle, 1999

The central High Plains aquifer is the primary source of water for domestic, industrial, and irrigation uses in parts of Colorado, Kansas, New Mexico, Oklahoma, and Texas. Water-level declines of more than 100 feet in some areas of the aquifer have increased the demand for water deeper in the aquifer. The maximum saturated thickness of the aquifer ranged from 500 to 600 feet in 1999. As the demand for deeper water increases, it becomes increasingly important for resource managers to understand how the quality of water in the aquifer changes with depth. In 1998?99, 18 monitoring wells at nine sites in southwestern Kansas and the Oklahoma Panhandle were completed at various depths in the central High Plains aquifer, and one monitoring well was completed in sediments of Permian age underlying the aquifer. Water samples were collected once from each well in 1999 to measure vertical gradients in water chemistry in the aquifer. Tritium concentrations measured in ground water indicate that water samples collected in the upper 30 feet of the aquifer were generally recharged within the last 50 years, whereas all of the water samples collected at depths more than 30 feet below the water table were recharged more than 50 years ago. Dissolved oxygen was present throughout the aquifer, with concentrations ranging from 1.7 to 8.4 mg/L. Water in the central High Plains aquifer was predominantly a calcium-bicarbonate type that exhibited little variability in concentrations of dissolved solids with depth (290 to 642 mg/L). Exceptions occurred in some areas where there had been upward movement of mineralized water from underlying sediments of Permian age and areas where there had been downward movement of mineralized Arkansas River water to the aquifer. Calcium-sulfate and sodium-chloride waters dominated and concentrations of dissolved solids were elevated (862 to 4,030 mg/L) near the base of the aquifer in the areas of upward leakage. Dissolution of gypsum or anhydrite and halite in sediments of Permian age by ground water was the likely source of calcium, sulfate, sodium, and chloride in those waters. Calcium-sodium-sulfate waters dominated, and concentrations of dissolved solids were as large as 4,916 mg/L near the water table in the area of downward leakage. Dissolution of minerals in sedimentary deposits of marine origin in upstream areas of the Arkansas River drainage were the likely sources of calcium, sodium, and sulfate in those waters. Nitrate was detected throughout the aquifer and the background concentration was estimated to be 2.45 mg/L as N. The largest nitrate concentrations (8.28, 22, and 54.4 mg/L as N) occurred in recently recharged water collected adjacent to irrigated fields. Three pesticides (atrazine, metolachlor, simazine) and five pesticide degradation products (alachlor ethanesulfonic acid, alachlor oxanilic acid, deethylatrazine, metolachlor ethanesulfonic acid, metolachlor oxanilic acid) were detected in recently recharged water from six water-table wells. Five of the six wells were adjacent to irrigated fields. These data indicate that concentrations of nitrate and pesticides increased over time in some areas of the aquifer as a result of agricultural activities. Results from this study indicate that vertical gradients in water chemistry existed in the central High Plains aquifer. The chemical gradients resulted from chemical inputs to the aquifer from underlying sediments of Permian age, from the Arkansas River, and from agricultural activities. In areas where those chemical inputs occurred, water quality in the aquifer was impaired and may not have been suitable for some intended uses.

Water-Resources Investigations Report

The fate and transport of nitrate in shallow groundwater in northwestern Mississippi, USA

Agricultural contamination of groundwater in northwestern Mississippi, USA, has not been studied extensively, and subsurface fluxes of agricultural chemicals have been presumed minimal. To determine the factors controlling transport of nitrate-N into the Mississippi River Valley alluvial aquifer, a study was conducted from 2006 to 2008 to estimate fluxes of water and solutes for a site in the Bogue Phalia basin (1,250 km 2 ). Water-quality data were collected from a shallow water-table well, a vertical profile of temporary sampling points, and a nearby irrigation well. Nitrate was detected within 4.4 m of the water table but was absent in deeper waters with evidence of reducing conditions and denitrification. Recharge estimates from 6.2 to 10.9 cm/year were quantified using water-table fluctuations, a Cl – tracer method, and atmospheric age-tracers. A mathematical advection-reaction model predicted similar recharge to the aquifer, and also predicted that 15% of applied nitrogen is leached into the saturated zone. With current denitrification and application rates, the nitrate-N front is expected to remain in shallow groundwater, less than 6–9 m deep. Increasing application rates resulting from intensifying agricultural demands may advance the nitrate-N front to 16–23 m, within the zone of groundwater pumping.

Mississippi

Groundwater quality of southeastern Wyoming

Groundwater is an important resource for domestic, municipal, stock, and irrigation uses in southeastern Wyoming. Thirty-seven percent of water used in the tri-County area, which includes Laramie, Platte, and Goshen Counties, is from groundwater. Most groundwater use in the tri-County area is withdrawn from three primary aquifer groups: Quaternary-age unconsolidated-deposit aquifers, Tertiary-age units of the High Plains aquifer system, and Upper Cretaceous bedrock aquifers (Lance Formation and Fox Hills Sandstone). Authors include selected physical properties and chemicals found in water samples, describe sources and importance, and report maximum levels established by the U.S. Environmental Protection Agency. They also show concentration ranges for selected physical properties and chemicals in samples collected from the three primary aquifer groups in the tri-County area.

Wyoming

Groundwater quality in the Western San Joaquin Valley study unit, 2010: California GAMA Priority Basin Project

Water quality in groundwater resources used for public drinking-water supply in the Western San Joaquin Valley (WSJV) was investigated by the USGS in cooperation with the California State Water Resources Control Board (SWRCB) as part of its Groundwater Ambient Monitoring and Assessment (GAMA) Program Priority Basin Project. The WSJV includes two study areas: the Delta–Mendota and Westside subbasins of the San Joaquin Valley groundwater basin. Study objectives for the WSJV study unit included two assessment types: (1) a status assessment yielding quantitative estimates of the current (2010) status of groundwater quality in the groundwater resources used for public drinking water, and (2) an evaluation of natural and anthropogenic factors that could be affecting the groundwater quality. The assessments characterized the quality of untreated groundwater, not the quality of treated drinking water delivered to consumers by water distributors. The status assessment was based on data collected from 43 wells sampled by the U.S. Geological Survey for the GAMA Priority Basin Project (USGS-GAMA) in 2010 and data compiled in the SWRCB Division of Drinking Water (SWRCB-DDW) database for 74 additional public-supply wells sampled for regulatory compliance purposes between 2007 and 2010. To provide context, concentrations of constituents measured in groundwater were compared to U.S. Environmental Protection Agency (EPA) and SWRCB-DDW regulatory and non-regulatory benchmarks for drinking-water quality. The status assessment used a spatially weighted, grid-based method to estimate the proportion of the groundwater resources used for public drinking water that has concentrations for particular constituents or class of constituents approaching or above benchmark concentrations. This method provides statistically unbiased results at the study-area scale within the WSJV study unit, and permits comparison of the two study areas to other areas assessed by the GAMA Priority Basin Project statewide. Groundwater resources used for public drinking water in the WSJV study unit are among the most saline and most affected by high concentrations of inorganic constituents of all groundwater resources used for public drinking water that have been assessed by the GAMA Priority Basin Project statewide. Among the 82 GAMA Priority Basin Project study areas statewide, the Delta–Mendota study area ranked above the 90th percentile for aquifer-scale proportions of groundwater resources having concentrations of total dissolved solids (TDS), sulfate, chloride, manganese, boron, chromium(VI), selenium, and strontium above benchmarks, and the Westside study area ranked above the 90th percentile for TDS, sulfate, manganese, and boron. In the WSJV study unit as a whole, one or more inorganic constituents with regulatory or non-regulatory, health-based benchmarks were present at concentrations above benchmarks in about 53 percent of the groundwater resources used for public drinking water, and one or more organic constituents with regulatory health-based benchmarks were detected at concentrations above benchmarks in about 3 percent of the resource. Individual constituents present at concentrations greater than health-based benchmarks in greater than 2 percent of groundwater resources used for public drinking water included: boron (51 percent, SWRCB-DDW notification level), chromium(VI) (25 percent, SWRCB-DDW maximum contaminant level (MCL)), arsenic (10 percent, EPA MCL), strontium (5.1 percent, EPA Lifetime health advisory level (HAL)), nitrate (3.9 percent, EPA MCL), molybdenum (3.8 percent, EPA HAL), selenium (2.6 percent, EPA MCL), and benzene (2.6 percent, SWRCB-DDW MCL). In addition, 50 percent of the resource had TDS concentrations greater than non-regulatory, aesthetic-based SWRCB-DDW upper secondary maximum contaminant level (SMCL), and 44 percent had manganese concentrations greater than the SWRCB-DDW SMCL. Natural and anthropogenic factors that could affect the groundwater quality were evaluated by using results from statistical testing of associations between constituent concentrations and values of potential explanatory factors, inferences from geochemical and age-dating tracer results, and by considering the water-quality results in the context of the hydrogeologic setting of the WSJV study unit. Natural factors, particularly the lithologies of the source areas for groundwater recharge and of the aquifers, were the dominant factors affecting groundwater quality in most of the WSJV study unit. However, where groundwater resources used for public supply included groundwater recharged in the modern era, mobilization of constituents by recharge of water used for irrigation also affected groundwater quality. Public-supply wells in the Westside study area had a median depth of 305 m and primarily tapped groundwater recharged hundreds to thousands of years ago, whereas public-supply wells in the Delta–Mendota study area had a median depth of 85 m and primarily tapped either groundwater recharged within the last 60 years or groundwater consisting of mixtures of this modern recharge and older recharge. Public-supply wells in the WSJV study unit are screened in the Tulare Formation and zones above and below the Corcoran Clay Member are used. The Tulare Formation primarily consists of alluvial sediments derived from the Coast Ranges to the west, except along the valley trough at the eastern margin of the WSJV study unit where the Tulare Formation consists of fluvial sands derived from the Sierra Nevada to the east. Groundwater from wells screened in the Sierra Nevada sands had manganese-reducing or manganese- and iron-reducing oxidation-reduction (redox) conditions. These redox conditions commonly were associated with elevated arsenic or molybdenum concentrations, and the dominance of arsenic(III) in the dissolved arsenic supports reductive dissolution of iron and manganese oxyhydroxides as the mechanism. In addition, groundwater from many wells screened in Sierra Nevada sands contained low concentrations of nitrite or ammonium, indicating reduction of nitrate by denitrification or dissimilatory processes, respectively. Geology of the Coast Ranges westward of the study unit strongly affects groundwater quality in the WSJV. Elevated concentrations of TDS, sulfate, boron, selenium and strontium in groundwater were primarily associated with aquifer sediments and recharge derived from areas of the Coast Ranges dominated by Cretaceous-to-Miocene age, organic-rich, reduced marine shales, known as the source of selenium in WSJV soils, surface water, and groundwater. Low sulfur-isotopic values (δ34S) of dissolved sulfate indicate that the sulfate was largely derived from oxidation of biogenic pyrite from the shales, and correlations with trace element concentrations, geologic setting, and groundwater geochemical modeling indicated that distributions of sulfate, strontium, and selenium in groundwater were controlled by dissolution of secondary sulfate minerals in soils and sediments. Elevated concentrations of chromium(VI) were primarily associated with aquifer sediments and recharge derived from areas of the Coast Ranges dominated by the Franciscan Complex and ultramafic rocks. The Franciscan Complex also has boron-rich, sodium-chloride dominated hydrothermal fluids that contribute to elevated concentrations of boron and TDS. Groundwater from wells screened in Coast Ranges alluvium was primarily oxic and relatively alkaline (median pH value of 7.55) in the Delta–Mendota study area, and primarily nitrate-reducing or suboxic and alkaline (median pH value of 8.4) in the Westside study area. Many groundwater samples from those wells have elevated concentrations of arsenic(V), molybdenum, selenium, or chromium(VI), consistent with desorption of metal oxyanions from mineral surfaces under those geochemical conditions. High concentrations of benzene were associated with deep wells located in the vicinity of petroleum deposits at the southern end of the Westside study area. Groundwater from these wells had premodern age and anoxic geochemical conditions, and the ratios among concentrations of hydrocarbon constituents were different from ratios found in fuels and combustion products, which is consistent with a geogenic source for the benzene rather than contamination from anthropogenic sources. Water stable-isotope compositions, groundwater recharge temperatures, and groundwater ages were used to infer four types of groundwater: (1) groundwater derived from natural recharge of water from major rivers draining the Sierra Nevada; (2) groundwater primarily derived from natural recharge of water from Coast Ranges runoff; (3) groundwater derived from recharge of pumped groundwater applied to the land surface for irrigation; and (4) groundwater derived from recharge during a period of much cooler paleoclimate. Water previously used for irrigation was found both above and below the Corcoran Clay, supporting earlier inferences that this clay member is no longer a robust confining unit. Recharge of water used for irrigation has direct and indirect effects on groundwater quality. Elevated nitrate concentrations and detections of herbicides and fumigants in the Delta–Mendota study area generally were associated with greater agricultural land use near the well and with water recharged during the last 60 years. However, the extent of the groundwater resource affected by agricultural sources of nitrate was limited by groundwater redox conditions sufficient to reduce nitrate. The detection frequency of perchlorate in Delta–Mendota groundwater was greater than expected for natural conditions. Perchlorate, nitrate, selenium, and strontium concentrations were correlated with one another and were greater in groundwater inferred to be recharge of previously pumped groundwater used for irrigation. The source of the perchlorate, selenium, and strontium appears to be salts deposited in the soils and sediments of the arid WSJV that are dissolved and flushed into groundwater by the increased amount of recharge caused by irrigation. In the Delta–Mendota study area, the groundwater with elevated concentrations of selenium was found deeper in the aquifer system than it was reported by a previous study 25 years earlier, suggesting that this transient front of groundwater with elevated concentrations of constituents derived from dissolution of soil salts by irrigation recharge is moving down through the aquifer system and is now reaching the depth zone used for public drinking water supply.

California

Ground-water resources of Waupaca County, Wisconsin

Waupaca County is in east-central Wisconsin. No serious ground-water problems existed in 1960 except in a few localities where crystalline rock is near land surface or is covered by nearly impermeable till. The use of ground water for irrigation has not appreciably affected ground-water levels. The county is covered by Pleistocene till, glaciolacustrine (lake), glaciofluvial (stream), and eolian (wind) deposits. In the northern three-quarters of the county these deposits overlie Precambrian crystalline rocks; in the remainder, they overlie sandstone of Cambrian age and, to a minor extent, dolomite of the Prairie du Chien Group of Ordovician age. The deposits of Pleistocene age, particularly outwash, are the principal sources of ground water except in those areas where the saturated thickness is slight or the permeability low. The sandstone of Cambrian age is an important aquifer in the southeastern part of the county. The crystalline rocks of Precambrian age yield little water except from fractures, joints, and weathered zones, and they are a source of water only in areas where better aquifers are absent. Ground water in Waupaca County occurs under both water-table and artesian conditions. The source of this ground water is precipitation that falls on the county and percolates downward to the zone of saturation. Regional movement of ground water is to the Wolf River. In most of the county the direction of movement is eastward or southeastward, except in the southeastern corner of the county, where the movement is westward. Water-level fluctuations reflect the variations of ground-water storage or artesian pressure in response to variations in recharge and discharge. Declining water levels from 1956 to 1959 reflect a period of below-normal precipitation, and rising water levels in late 1959 and 1960 reflect above-normal precipitation. Average precipitation, runoff, and evapotranspiration in 1959 are estimated to be 1,000, 400, and 600 mgd (million gallons per day) respectively. Pumpage in the county was estimated to be about 4 mgd in 1959, and about half of this amount was used for public supplies. A pumping test of a well in outwash deposits near Waupaca indicated that at that point the coefficient of transmissibility is about 100,000 gpd (gallons per day) per ft, the permeability is about 1,000 gpd per sq ft, the coefficient of storage is about 0.2, and the specific capacity is 41 gpm (gallons per minute) per ft of drawdown. These hydraulic characteristics are probably in the same order of magnitude as the characteristics of outwash deposits in the county in general. The water from wells in Waupaca County, although hard and generally containing iron, is good for most purposes.

Wisconsin

Quality of groundwater in the Denver Basin aquifer system, Colorado, 2003-5

Groundwater resources from alluvial and bedrock aquifers of the Denver Basin are critical for municipal, domestic, and agricultural uses in Colorado along the eastern front of the Rocky Mountains. Rapid and widespread urban development, primarily along the western boundary of the Denver Basin, has approximately doubled the population since about 1970, and much of the population depends on groundwater for water supply. As part of the National Water-Quality Assessment Program, the U.S. Geological Survey conducted groundwater-quality studies during 2003–5 in the Denver Basin aquifer system to characterize water quality of shallow groundwater at the water table and of the bedrock aquifers, which are important drinking-water resources. For the Denver Basin, water-quality constituents of concern for human health or because they might otherwise limit use of water include total dissolved solids, fluoride, sulfate, nitrate, iron, manganese, selenium, radon, uranium, arsenic, pesticides, and volatile organic compounds. For the water-table studies, two monitoring-well networks were installed and sampled beneath agricultural (31 wells) and urban (29 wells) land uses at or just below the water table in either alluvial material or near-surface bedrock. For the bedrock-aquifer studies, domestic- and municipal-supply wells completed in the bedrock aquifers were sampled. The bedrock aquifers, stratigraphically from youngest (shallowest) to oldest (deepest), are the Dawson, Denver, Arapahoe, and Laramie-Fox Hills aquifers. The extensive dataset collected from wells completed in the bedrock aquifers (79 samples) provides the opportunity to evaluate factors and processes affecting water quality and to establish a baseline that can be used to characterize future changes in groundwater quality. Groundwater samples were analyzed for inorganic, organic, isotopic, and age-dating constituents and tracers. This report discusses spatial and statistical distributions of chemical constituents and evaluates natural and human-related processes that affect water quality. Findings are synthesized to assess the vulnerability of the Denver Basin aquifer system to groundwater contamination. The chemistry of groundwater samples collected from the water-table wells was generally different from that of samples collected from the bedrock-aquifer wells. Samples from the water-table wells tended to have higher concentrations of total dissolved solids and most major ions. Concentrations of several constituents with potential human-health concerns, including nitrate, selenium, uranium, and arsenic, decreased with depth and were highest in samples from the water-table wells. Exceedances of drinking-water standards and water-quality benchmarks were more frequently associated with shallow groundwater samples; concentrations of total dissolved solids and sulfate exceeded water-quality benchmarks for about half or more of samples from the water-table wells. The sediments and rocks of the Denver Basin are natural sources of the trace elements selenium, uranium, and arsenic, which affect their concentrations in groundwater. Detections of organic contaminants, which are typically indicative of human sources of contamination to groundwater, were more frequent in samples from the water-table wells. Pesticide compounds and volatile organic compounds were detected in 33 and 62 percent, respectively, of water-table well samples. Detected organic contaminant concentrations were much less than the associated drinking-water standards. Samples collected from the bedrock aquifers had lower concentrations of total dissolved solids than did samples collected from the water-table wells, although within the bedrock-aquifer samples, concentrations increased from the Dawson to Denver to Arapahoe to Laramie-Fox Hills aquifers. Concentrations of total dissolved solids and many constituents varied spatially and with depth in the bedrock aquifers, likely as a result of ion-exchange and oxidation-reduction reactions, which are important processes affecting water quality. Major-ion chemistry generally evolved from a calcium-bicarbonate to calcium-sulfate composition, with some sodium-bicarbonate and sodium-sulfate facies in the deeper bedrock aquifers, likely resulting from longer residence times and more extensive water-rock interaction. Oxidation-reduction conditions generally evolved from oxic at the water table to anoxic with increasing depth in the bedrock aquifers. Most samples from the bedrock aquifers were anoxic. Exceedances of drinking-water standards and water-quality benchmarks for the bedrock aquifers occurred in 1 percent or less of samples for nitrate, selenium, or arsenic; there were no exceedances for uranium. Exceedances for total dissolved solids, sulfate, manganese, and iron were generally between about 10 and 20 percent for the bedrock-aquifer samples. Radon concentrations, which were only measured in samples collected from two of the bedrock aquifers, exceeded the lower proposed drinking-water standard for more than 90 percent of samples but exceeded the higher alternative standard for less than 5 percent of samples. Pesticide compounds and volatile organic compounds were detected in 3 and 22 percent, respectively, of bedrock-aquifer samples, all at concentrations that were that were much less than drinking-water standards. Water-quality data were synthesized to evaluate factors that affect spatial and depth variability in water quality and to assess aquifer vulnerability to contaminants from geologic materials and those of human origin. The quality of shallow groundwater in the alluvial aquifer and shallow bedrock aquifer system has been adversely affected by development of agricultural and urban areas. Land use has altered the pattern and composition of recharge. Increased recharge from irrigation water has mobilized dissolved constituents and increased concentrations in the shallow groundwater. Concentrations of most constituents associated with poor or degraded water quality in shallow groundwater decreased with depth; many of these constituents are not geochemically conservative and are affected by geochemical reactions such as oxidation-reduction reactions. Groundwater age tracers provide additional insight into aquifer vulnerability and help determine if young groundwater of potentially poor quality has migrated to deeper parts of the bedrock aquifers used for drinking-water supply. Age-tracer results were used to group samples into categories of young, mixed, and old groundwater. Groundwater ages transitioned from mostly young in the water-table wells to mostly mixed in the shallowest bedrock aquifer, the Dawson aquifer, to mostly old in the deeper bedrock aquifers. Although the bedrock aquifers are mostly old groundwater of good water quality, several lines of evidence indicate that young, contaminant-bearing recharge has reached shallow to moderate depths in some areas of the bedrock aquifers. The Dawson aquifer is the most vulnerable of the bedrock aquifers to contamination, but results indicate that the older (deeper) bedrock aquifers are also vulnerable to groundwater contamination and that mixing with young recharge has occurred in some areas. Heavy pumping has caused water-level declines in the bedrock aquifers in some parts of the Denver Basin, which has the potential to enhance the transport of contaminants from overlying units. Results of this study are consistent with the existing conceptual understanding of aquifer processes and groundwater issues in the Denver Basin and add new insight into the vulnerability of the bedrock aquifers to groundwater contamination.

Colorado

Hydrology of Sanpete Valley, Sanpete and Juab Counties, Utah, and simulation of ground-water flow in the valley-fill aquifer

The surface-and ground-water hydrology of Sanpete Valley and the San Pitch River drainage basin, Sanpete and Juab Counties, Utah, was studied to define the current conditions of the hydrologic system, to detect causes for downstream changes in water quality in the San Pitch River and in areas of high concentration of dissolved solids in ground water, and to determine the possible effects of present changes in irrigation methods and possible future increased ground-water withdrawals from the valley-fill aquifer. Measurements of water levels in wells show responses to climatic variation. The dissolved-solids concentration of water from the San Pitch River increases downstream. Principal areas of ground water with high concentrations of dissolved solids occur downgradient from outcrops of rocks of Jurassic and Tertiary age. One local-scale ground-water flow system discharges small volumes of water with high concentrations of dissolved solids to the San Pitch River southwest of Ephraim. Although ground water occurs in both valley-fill and consolidated-rock aquifers in the study area, more hydrologic information is available for the valley-fill aquifer. The valley-fill aquifer consists primarily of fine-grained silt and clay in the center of the valley and coarser deposits along the margin of the valley. Surface- water inflow to the valley is estimated to be about 152,000 acre-feet per year. Recharge to the valley-fill aquifer is estimated to be between 74,000 and 103,000 acre-feet per year. A three-dimensional, ground-water flow model was developed to better define present ground-water conditions and to determine possible effects of future changes in ground-water withdrawals from the valley-fill aquifer. Computer simulation results indicate the possibility of recharge to the valleyfill aquifer as subsurface inflow from consolidated-rock aquifers. Simulation of water-level changes during the late 1980's indicate that some of the declines could have been caused by conversion from flood irrigation to sprinkler irrigation. Predictive simulations using three times the average pumping rates indicate possible water-level declines of as much as 70 feet.

Utah

Water resources of the Warm Springs Indian Reservation, Oregon

Water-resources data for the 1,000-square-mile Warm Springs Indian Reservation in north-central Oregon were obtained and evaluated. The area is bounded on the west by the crest of the Cascade Range and on the south and east by the Metolius and Deschutes Rivers. The mountainous western part is underlain by young volcanic rocks, and the plateaus and valleys of the eastern part are underlain by basalt, tuff, sand, and gravel of Tertiary and Quaternary ages. There are numerous springs, some developed for stock use, and about 50 domestic and community wells; yields are small, ranging from less than 1 to as much as 25 gallons per minute. Chemical quality of most ground water is suitable for stock or human consumption and for irrigation. Average flows of the Warm Springs River, Metolius River, and Deschutes River are 440, 1,400, and 4,040 cubic feet per second (cfs), respectively. Shitike Creek, which has an average flow of 108 cfs had a peak of 4,000 cfs in January 1974. Most streams have fewer than 100 milligrams per liter (mg/liter) of dissolved solids. Chemical and biological quality of the mountain lakes is also good; of 10 lakes studied, all had fewer than 50 mg/liter of dissolved solids and none had measurable fecal coliform bacteria. (Woodard-USGS)

Water-Resources Investigations Report

Geology and ground-water resources of the upper Lodgepole Creek drainage basin, Wyoming, with a section on chemical quality of the water

The principal sources of ground-water supply in the upper Lodgepole Creek drainage basin-the part of the basin west of the Wyoming-Nebraska State line-are the Brule formation of Oligocene age, the Arikaree formation of Miocene age, the Ogallala formation of Pliocene age, and the unconsolidated deposits of Quaternary age. The Brule formation is a moderately hard siltstone that generally is not a good aquifer. However, where it is fractured or where the upper part consists of pebbles of reworked siltstone, it will yield large quantities of water to wells. Many wells in the Pine Bluffs lowland, at the east end of the area, derive water from the Brule. The Arikaree formation, which consists of loosely to moderately cemented fine sand, will yield small quantities of water to wells but is not thick enough or permeable enough to supply sufficient water for irrigation. Only a few wells derive water from it. The Ogallala formation consists of lenticular beds of clay, silt, sand, and gravel which, in part, are cemented with calcium carbonate. Only the lower part of the formation is saturated. Nearly all the wells in the upland part of the area tap the Ogallala, but they supply water in amounts sufficient for domestic and stock use only. Two of the wells have a moderately large discharge, and other wells of comparable discharge probably could be drilled in those parts of the upland where the saturated part of the Ogallala is fairly thick. Most of the unconsolidated deposits of Quaternary age are very permeable and, where a sufficient thickness is saturated, will yield large quantities of water to wells. These deposits are a significant source of water supply in the southeastern part of the area. The Chadron formation of Oligocene age, which underlies the Brule formation, is a medium- to coarse-grained sandstone where it crops out in the Islay lowland. No wells tap the Chadron, but it probably would yield small quantities of water to wells. It lies at a relatively shallow depth beneath most of the Islay lowland, near the west end of the area, and at a depth of about 800 feet beneath the Pine Bluffs lowland. In the latter area it probably is finer grained and may not be permeable enough to yield water to wells. All the ground water in the area is derived from precipitation. It is estimated that about 5 percent of the precipitation infiltrates directly to the zone of saturation. The remainder either is evaporated immediately; is retained by the soil, later to be evaporated or transpired; or is discharged by overland flow to the surface drainage courses. Most of the water that reaches the surface drainage courses eventually sinks to the zone of saturation or is evaporated. The slope of the water table and the movement of ground water are generally eastward. The depth to water ranges from less than 10 feet in parts of the valley to about 300 feet in the upland areas. In much of the Pine Bluffs lowland, the depth to water is less than 50 feet. Ground water not pumped from wells within the area is discharged by evapotranspiration where the water table is close to the land surface, by outflow into streams, or by underflow eastward beneath the State line. The chemical quality of ground water from the principal sources is remarkably uniform, and the range in concentration of dissolved constituents is narrow. In general, the water is of the calcium bicarbonate type, is hard (hardness as CaC03 is as high as 246 ppm), and contains less than about 400 parts per million of dissolved solids, which is a moderate mineralization. Silica constitutes a large proportion of the dissolved solids. The water is suitable for irrigation and, except for iron in water from some wells that tap the Ogallala formation, meets the drinking water standards of the U.S. Public Health Service for chemical constituents. Because the water is siliceous, alkaline, and hard, it is unsuitable for many industrial uses unless treated.

Water Supply Paper

Hydrogeology and groundwater quality of Highlands County, Florida

Groundwater is the main source of water supply in Highlands County, Florida. As the demand for water in the county increases, additional information about local groundwater resources is needed to manage and develop the water supply effectively. To address the need for additional data, a study was conducted to evaluate the hydrogeology and groundwater quality of Highlands County. Total groundwater use in Highlands County has increased steadily since 1965. Total groundwater withdrawals increased from about 37 million gallons per day in 1965 to about 107 million gallons per day in 2005. Much of this increase in water use is related to agricultural activities, especially citrus cultivation, which increased more than 300 percent from 1965 to 2005. Highlands County is underlain by three principal hydrogeologic units. The uppermost water-bearing unit is the surficial aquifer, which is underlain by the intermediate aquifer system/intermediate confining unit. The lowermost hydrogeologic unit is the Floridan aquifer system, which consists of the Upper Floridan aquifer, as many as three middle confining units, and the Lower Floridan aquifer. The surficial aquifer consists primarily of fine-to-medium grained quartz sand with varying amounts of clay and silt. The aquifer system is unconfined and underlies the entire county. The thickness of the surficial aquifer is highly variable, ranging from less than 50 to more than 300 feet. Groundwater in the surficial aquifer is recharged primarily by precipitation, but also by septic tanks, irrigation from wells, seepage from lakes and streams, and the lateral groundwater inflow from adjacent areas. The intermediate aquifer system/intermediate confining unit acts as a confining layer (except where breached by sinkholes) that restricts the vertical movement of water between the surficial aquifer and the underlying Upper Floridan aquifer. The sediments have varying degrees of permeability and consist of permeable limestone, dolostone, or sand, or relatively impermeable layers of clay, clayey sand, or clayey carbonates. The thickness of the intermediate aquifer system/ intermediate confining unit ranges from about 200 feet in northwestern Highlands County to more than 600 feet in the southwestern part. Although the intermediate aquifer system is present in the county, it is unclear where the aquifer system grades into a confining unit in the eastern part of the county. Up to two water-bearing units are present in the intermediate aquifer system within the county. The lateral continuity and water-bearing potential of the various aquifers within the intermediate aquifer system are highly variable. The Floridan aquifer system is composed of a thick sequence of limestone and dolostone of Upper Paleocene to Oligocene age. The top of the aquifer system ranges from less than 200 feet below NGVD 29 in extreme northwestern Highlands County to more than 600 feet below NGVD 29 in the southwestern part. The principal source of groundwater supply in the county is the Upper Floridan aquifer. As of 2005, about 89 percent of the groundwater withdrawn from the county was obtained from this aquifer, mostly for agricultural irrigation and public supply. Over most of Highlands County, the Upper Floridan aquifer generally contains freshwater, and the Lower Floridan aquifer contains more mineralized water. The potentiometric surface of the Upper Floridan aquifer is constantly fluctuating, mainly in response to seasonal variations in rainfall and groundwater withdrawals. The potentiometric surface of the Upper Floridan aquifer in May 2007, which represents the hydrologic conditions near the end of the dry season when water levels generally are near their lowest, ranged from about 79 feet above NGVD 29 in northwestern Highlands County to about 40 feet above NGVD 29 in the southeastern part of the county. The potentiometric surface of the Upper Floridan aquifer in September 2007 was about 3 to 10 feet high

Scientific Investigations Report

Water-table contours, directions of ground-water movement, and measurements of inflow to American Falls Reservoir, southeastern Idaho, April 1984

In 1978 the U.S. Geological Survey began a 5-year study of the High Plains regional aquifer system to provide hydrologic information for evaluating the effects of long-term development of the aquifer and to develop a capability for predicting aquifer response to alternative changes in ground-water management. By use of a digital model, this report presents a quantitative description of the High Plains aquifer in Oklahoma. The High Plains aquifer consists predominantly of the Tertiary Ogallala Formation and overlying Quaternary alluvium and terrace deposits which are hydraulically connected to the High Plains aquifer. Much of the aquifer is underlain by formations of Permian through Cretaceous age, which generally have very small hydraulic conductivities. In some areas parts of underlying Triassic, Jurassic, or Cretaceous rocks are hydraulically connected with the aquifer. The High Plains aquifer is a water-table aquifer in which water moves generally to the east-southeast. Before the beginning of extensive irrigation of the 1960's, the aquifer was essentially in dynamic equilibrium with recharge from precipitation balanced by natural discharge from the aquifer. Ground-water discharge appeared in streams leaving the area or was returned to the atmosphere through evapotranspiration. Accurate records of irrigation pumpage are not available from the High Plains. In order to estimate irrigation pumpage, published records of crop distribution were used and a consumptive use was assigned to each principal irrigated crop. This method gave an estimated irrigation demand. Pumpage was taken as a percentage of the total irrigation demand. Irrigation has decreased ground-water discharge from the High Plains aquifer. Ground-water discharge was estimated as approximately 118 cubic feet per second in 1980. A finite-difference digital model was used to simulate flow in the High Plains aquifer. The recharge was adjusted so that 1980 ground-water discharge was 118 cubic feet per second, the estimated ground-water discharge for 1980. Recharge in the eastern half of the modeled area was 0.45 inch per year; one-half this value was used in the western half of the modeled area. Hydraulic conductivity was divided into three zones: 19.3 feet per day in the eastern zone; 16.2 feet per day in the central zone; and 8.28 feet per day in the western zone. A specific yield of 14.7 percent was used in the model. Using all these parameters, the model was calibrated so that the mean difference between predevelopment modeled and measured head was -0.044 foot. Following the calibration procedure, the model was used to predict the volumes of water in storage and distribution of saturated thickness in 1993 and 2020 using the 1980 pumping rates. The calculated quantity of water in storage in the aquifer in 1941 (predevelopment) was approximately 135.2 million acre-feet; in 1980, approximately 121.9 million acre-feet; in 1993 approximately 112.7 million acre-feet; and in 2020, approximately 96.2 million acre-feet. The High Plains aquifer in Oklahoma will continue to be an important source of water past the year 2000. As withdrawals continue from the aquifer at the present rate, the water table will continue to decline and when the water table drops below the streambed in any part of the area, ground-water discharge to streams will cease in that area. Based on the calculated volumes of water in storage, the volume of water remaining in storage as compared to the predevelopment volume is as follows: 90 percent in 1980, 83 percent in 1993, and 71 percent in 2020.

Idaho

Ecosystem-specific growth responses to climate pattern by a temperate freshwater fish

Somatic growth patterns among animal populations are maintained through complex processes that vary among ecosystems. Changes in growth patterns may be concomitant with changes in climate; however, understanding how growth will manifest among ecosystems is limited. Information embedded within fish hard-parts (i.e., otoliths, spines, vertebrae) can account for variation in growth patterns resulting from changing climate conditions. Channel catfish Ictalurus punctatus is a freshwater fish species widely distributed across North America with limited information regarding climate influences on growth and differences in climate-growth relations among ecological systems. We assessed growth (total length) response to changing climate conditions for channel catfish among three waterbody types—pit lakes, irrigation and power-generation reservoirs, and flood-control reservoirs in Nebraska, USA. We used linear mixed-effect models and an information theoretic approach to assess the relative strengths among competing hypotheses. The most supported linear mixed-effect model of channel catfish growth was a function of fish age and an interaction between waterbody type and growing-degree-day (GDD). A positive trend existed in GDD from 1990 through 2008 whereby the predicted increase in GDD among waterbody types ranged from 182 GDD to 189 GDD. The predicted change in channel catfish growth resulting from increased GDD ranged from 1% to 39% among waterbody types. Channel catfish population rate functions, thus, may not respond similarly to climate conditions across ecosystem types. Changes in climate variables may contribute to system-specific responses in population dynamics for channel catfish as well as other similar freshwater species. The establishment of relations between climate and growth variables for a freshwater generalist with a plastic diet and broad temperature tolerance serves as an indication of the breadth of responses possible for freshwater fishes under global changes in climate conditions.

Nebraska

Recharge, movement, and discharge in the Edwards Limestone Reservoir, Texas

The Edwards limestone of Lower Cretaceous age is the principal water‐bearing formation in a belt 5 to 25 miles wide that extends from Austin southwest to San Antonio and thence west through Uvalde and Del Rio to Comstock, a distance of about 250 miles (see Fig. 1). Throughout this belt it supplies water to wells for stock, industrial, irrigation, and municipal use and to a series of fault‐springs, some of which are among the largest in the United States. These springs have played an important part in the economic and cultural development of Texas. In 1718 the Spaniards stationed a department of light infantry near the springs at San Antonio and soon after established missions and constructed elaborate systems of canals for irrigating considerable areas. After the winning of Texas' independence large numbers of settlers moved into the area. This influx was greatly accelerated following the admission of Texas to the Federal Union and towns were soon established near all of the major springs. However, it was not until about 1880 that the rapid development of the Edwards limestone aquifer by wells was begun.

Texas