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Role of ground ice dynamics and ecological feedbacks in recent ice wedge degradation and stabilization

Ground ice is abundant in the upper permafrost throughout the Arctic and fundamentally affects terrain responses to climate warming. Ice wedges, which form near the surface and are the dominant type of massive ice in the Arctic, are particularly vulnerable to warming. Yet processes controlling ice wedge degradation and stabilization are poorly understood. Here we quantified ice wedge volume and degradation rates, compared ground ice characteristics and thermal regimes across a sequence of five degradation and stabilization stages and evaluated biophysical feedbacks controlling permafrost stability near Prudhoe Bay, Alaska. Mean ice wedge volume in the top 3 m of permafrost was 21%. Imagery from 1949 to 2012 showed thermokarst extent (area of water-filled troughs) was relatively small from 1949 (0.9%) to 1988 (1.5%), abruptly increased by 2004 (6.3%) and increased slightly by 2012 (7.5%). Mean annual surface temperatures varied by 4.9°C among degradation and stabilization stages and by 9.9°C from polygon center to deep lake bottom. Mean thicknesses of the active layer, ice-poor transient layer, ice-rich intermediate layer, thermokarst cave ice, and wedge ice varied substantially among stages. In early stages, thaw settlement caused water to impound in thermokarst troughs, creating positive feedbacks that increased net radiation, soil heat flux, and soil temperatures. Plant growth and organic matter accumulation in the degraded troughs provided negative feedbacks that allowed ground ice to aggrade and heave the surface, thus reducing surface water depth and soil temperatures in later stages. The ground ice dynamics and ecological feedbacks greatly complicate efforts to assess permafrost responses to climate change.

Journal of Geophysical Research F: Earth Surface

Regional flow system and ground-water quality in western Ohio

Most relatively deep wells drilled in the carbonate aquifers in western Ohio tap a recognizable regional flow system encompassing all or parts of several major basins. The principal recharge area includes the higher, central part of the region, where much of the terrane is hummocky to hilly glacial moraine. The principal discharge areas are the valleys of the major streams and lowlands along Lake Erie. Ground water moving through this system undergoes a progressive change in chemical quality, from a calcium bicarbonate type in recharge areas to a calcium sulfate type in discharge areas. Changes in selected chemical constituents are orderly and, within the observed parameters, predictable.

Ohio

Hydrologic landscapes on the Delmarva Peninsula - Part 2: Estimates of base-flow nitrogen load to Chesapeake Bay

ABSTRACT: The relation between landscape characteristics and water chemistry on the Delmarva Peninsula can be determined through a principal-component analysis of basin characteristics. Two basin types were defined by factor scores: (1) well-drained basins, characterized by combinations of a low percentage of forest cover, a low percentage of poorly drained soil, and elevated channel slope; and (2) poorly drained basins, characterized by a combinations of an elevated percentage of forest cover, an elevated percentage of poorly drained soil, and low channel slopes. Results from base-flow sampling of 29 basins during spring 1991 indicate that water chemistry of the two basin types differ significantly. Concentrations of calcium, magnesium, potassium, alkalinity, chloride, and nitrate are elevated in well-drained basins, and specific conductance is elevated. Concentrations of aluminum, dissolved organic carbon, sodium, and silica are elevated in poorly drained basins whereas specific conductance is low. The chemical patterns found in well-drained basins can be attributed to the application of agricultural chemicals, and those in poorly drained basins can be attributed to ground-water flowpaths. These results indicate that basin types determined by a quantitative analysis of basin characteristics can be related statistically to differences in base-flow chemistry, and that the observed statistical differences can be related to major processes that affect water chemistry.

Journal of the American Water Resources Associatio

Parent brine of the castile evaporites (Upper Permian), Texas and New Mexico

The Upper Permian (lower Ochoan) Castile Formation is a major evaporite sequence (∼10,000 km 3 ) of calcite, anhydrite, and halite in west Texas and southeastern New Mexico. Traditionally the Castile brine has been considered to have been derived from seawater. This tradition has recently been challenged by two versions of the closed-basin drawdown model. They call for deposition from a mixed brine, in part marine and in large part nonmarine. They propose drawdown of as much as 500 m to form a major sink for ground water issuing from the surrounding Capitan reef complex. A large fraction of the solute in the brine body is inferred to have been recycled from older Permian evaporites on the surrounding shelf. Strontium-isotope analyses show no evidence that meteoric ground water was contributed to the Castile brine. From a stratigraphic, geographic, and lithologic array of 65 samples of anhydrite, gypsum, and calcite, 59 have an 87 Sr/ 86 Sr ratio of 0.706923 (Δsw of -225.0), a ratio that is the same as that of strontium in early Ochoan ocean water. If considerable (>15%) influx of meteoric water had occurred, enough continental strontium would have been introduced to have resulted in higher ratios. Low bromide values (20-40 ppm) in Castile halite, which have been used to argue for meteoric influx and for recycled salt, probably resulted from diagenesis. During shallow burial by halite, centimeter-size, bottom-grown crystals of gypsum were altered to nodular anhydrite. The rising water of dehydration caused the halite to recrystallize. During the recrystallization, some bromide was expelled. Despite the large volume of water that evaporated annually from its surface (∼52 km 3 /yr, assuming an evaporation rate of 2 m/yr), the Castile brine body never completely desiccated. The surrounding shelf was flat, hot, and generally dry. It probably could not have supplied a significant volume of meteoric spring water to the basin over tens of thousands of years. More likely, during the entire history of the evaporite sequence, influx was dominantly marine. Marine ground water flowed through the Capitan Formation into the evaporite basin along its southern and possibly western margin probably with a rate of flow that was usually fast enough to prevent major drawdown of the brine surface.

Journal of Sedimentary Research

Publications of the Geological Survey, 1983

This catalog is a list of (1) books and maps that were published during 1983, and (2) articles by Geological Survey personnel in non-Geological Survey journals and books that came to our attention in 1983; it supplements the permanent catalogs "Publications of the Geological Survey, 1879-1961" and "Publications of the Geological Survey, 1962-1970."

Publications of the US Geological Survey

Publications of the U.S. Geological Survey, 1984

This catalog is a list of (1) books and mapsl that were published during 1984, and (2) articles by Geological Survey personnel in non-Geological Survey journals and books that came to our attention in 1984; it supplements the permanent catalogs "Publications of the Geological Survey, 1879-1961" and "Publications of the Geological Survey, '1962-1970."

Publications of the US Geological Survey

Evaporite encrustations and sulphide oxidation products from the southern Antarctic peninsula.

White evaporite encrustations collected from 66 sites scattered over 30 000km2 of S.Antarctic Peninsula are dominantly gypsum and calcite, and subordinate aragonite and thenardite. Natrojarosite occurs as locally developed yellow surface stains on c30% of the white encrustations examined. Water, which forms by the melting of snow blown into cracks in highly fractured rocks by ground blizzards, dissolves soluble ions from minerals in these rocks as it percolates into them. The white encrustations appear to be deposited when this water later rises to the surface by capillary action and evaporates.-from Author Antarctica chemical weathering evaporites sulphide oxidation.

New Zealand Journal of Geology and Geophysics

Helping Students make the transition from novice learner of ground-water concepts to expert using the Plume Busters software

Environmental and earth science students are novice learners and lack the experience needed to rise to the level of expert. To address this problem we have developed the prototype Plume Busters?? software as a capstone educational experience, in which students take on the role of an environmental consultant. Following a pipeline spill, the environmental consultant is hired by the pipeline owner to locate the resulting plume created by spill and remediate the contaminated aquifer at minimum monetary and time cost. The contamination must be removed from the aquifer before it reaches the river and eventually a downstream public water supply. The software consists of an interactive Java application and accompanying HTML linked pages. The application simulates movement of a plume from a pipeline break throug h a shallow alluvial aquifer towards the river. The accompanying web pages establish the simulated contamination scenario and provide students with background material on ground-water flow and transport principles. To make the role-play more realistic, the student must consider cost and time when making decisions about siting observation wells and wells for the pump-and-treat remediation system.

Journal of Geoscience Education

Topography and flooding of coastal ecosystems on the Yukon-Kuskokwim Delta, Alaska: Implications for sea level rise

We measured surface elevations, stage of annual peak flooding, and sedimentation along 10 toposequences across coastal ecosystems on the Yukon-Kuskokwim (Y-K) Delta in western Alaska during 1994-1998 to assess some of the physical processes affecting ecosystem distribution. An ecotype was assigned to each of 566 points, and differences in elevations among 24 ecotypes were analyzed within individual toposequences and across the 40 x 40-km study area. Elevations of vegetated ecotypes along the longest toposequence rose only ~1 m over a distance of 7.5 km, and mean elevations of most ecotype across the study area were within 0.5 m of mean higher-high water (1.47 m). During 1994 to 1998, monitoring of annual peak stage using crest gauges revealed flooding from the highest fall storm surge reached 2.58 m (1.11 m above mean higher-high tide). In each year, only the highest surface was unaffected by flooding. Mean annual sedimentation rates for the various ecotypes were 8.0 ram/y on tidal flats, 1.4 to 3.8 mm/y on the active floodplain, 0.1-0.2 mm/y on the inactive floodplain, and 0 mm/ on the abandoned floodplain. If sea levels in the Bering Sea rise ~0.5 m by 2100, as predicted by some on a global basis, large portions of the coastal margin of the delta could be regularly inundated by water during high tides, and even the highest ecotypes could be affected by storm surges. Predicting the extent of future inundation is difficult, however, because of the changes in the ground-surface elevation through sedimentation, organic matter accumulation, and permafrost development.

Alaska

Water tracks enhance water flow above permafrost in upland Arctic Alaska hillslopes

Upland permafrost regions occupy approximately one third of the Arctic landscape. In upland regions, hydrologic fluxes are influenced by water tracks, curvilinear features on hillslopes that preferentially fill with and route water in response to snowmelt and rainfall when the soil above continuous permafrost thaws in the summer. As continued warming of the Arctic may alter hydrologic cycling leading to increased frequency of extreme hydrologic events like drought and flooding as well as modification of biogeochemical cycling, it is imperative to untangle the interplay between precipitation, runoff, and subsurface flow as water is routed from upland Arctic regions to the Arctic Ocean. This study quantifies how ground surface temperatures affect groundwater discharge from hillslopes with water tracks in the upland Arctic by employing a three-dimensional, physically based subsurface flow model with variable saturation and freeze and thaw capabilities that is calibrated to field measurements from the Upper Kuparuk River watershed on the North Slope of Alaska, USA. Model analysis indicates that higher ground surface temperatures along water track hillslopes promote increases in groundwater discharge where water tracks act as conduits for large recharge events and continue to discharge groundwater into the autumn after the adjacent hillslope has frozen. Simulating the conditions that distinguish water tracks from their hillslope watersheds changes subsurface water storage and ground thermal responses but does not alter the total magnitude of groundwater discharge outside of parameter uncertainty. These findings suggest that water tracks play a complex and critical role in hydrologic cycles of the upland Arctic.

Alaska

Environmental occurrence and shallow ground water detection of the antibiotic monensin from dairy farms

Pharmaceuticals used in animal feeding operations have been detected in various environmental settings. There is a growing concern about the impact on terrestrial and aquatic organisms and the development of antibiotic-resistant strains of microorganisms. Pharmaceutical use in milking cows is relatively limited compared with other livestock operations, except for the ionophore monensin, which is given to lactating cows as a feed. By weight, monensin can be the most significant antibiotic used in a dairy farm. This study investigates the potential of monensin to move from dairy operations into the surrounding ground water. Using two dairy farms in California as study sites, we twice collected samples along the environmental pathway-from flush lanes, lagoon waters, and shallow ground water beneath the dairies and beneath its associated manured fields. Monensin concentrations were determined using solid-phase extraction and liquid chromatography-tandem mass spectrometry with positive electrospray ionization. Monensin was detected in all of the flush lane and lagoon water samples. Theoretical maximum concentration estimated from the actual dosing rate and the theoretical excretion rate assuming no attenuation was one order of magnitude greater than observed concentrations, suggesting significant attenuation in the manure collection and storage system. Monensin was also detected, at levels ranging from 0.04 to 0.39 microg L(-1), in some of the ground water samples underneath the production area of the dairy but not from the adjacent manured fields. Concentrations in ground water immediately downgradient of the lagoons were one to two orders of magnitude lower than the concentrations detected in lagoons, suggesting attenuation in the subsurface. The data suggest the possibility of monensin transport into shallow (2-5 m) alluvial ground water from dairy management units, including manure storage lagoons and freestalls occupied by heifers, lactating cows, and dry cows.

Journal of Environmental Quality

Near-decadal changes in nitrate and pesticide concentrations in the South Platte River alluvial aquifer, 1993-2004

The lower South Platte River basin of Colorado and Nebraska is an area of intense agriculture supported by surface-water diversions from the river and ground-water pumping from a valley-fill alluvial aquifer. Two well networks consisting of 45 wells installed in the South Platte alluvial aquifer were sampled in the early 1990s and again in the early 2000s to examine near-decadal ground-water quality changes in irrigated agricultural areas. Ground-water age generally increases and dissolved-oxygen content decreases with distance along flow paths and with depdi below the water table, and denitrification is an important natural mitigation mechanism for nitrate in downgradient areas. Ground-water travel time from upland areas to the river ranges from 12 to 31 yr on the basis of apparent ground-water ages. Ground-water nitrate concentrations for agricultural land-use wells increased significantly for oxidized samples over the decade, and nitrogen isotope ratios for oxidized samples indicate synthetic fertilizer as the predominant nitrate source. Ground-water concentrations of atrazine, DEA, and prometon decreased significandy. The decrease in pesticide concentrations and a significant increase in the ratio of DEA to atrazine suggest decreases in pesticide concentrations are likely caused by local decreases in application rates and/or degradation processes and that atrazine degradation is promoted by oxidizing conditions. The difference between results for oxidizing and nitrate-reducing conditions indicates redox state is an important variable to consider when evaluating ground-water quality trends for redox-sensitive constituents such as nitrate and pesticides in the South Platte alluvial aquifer. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Journal of Environmental Quality

Delineation of tile-drain networks using thermal and multispectral imagery—Implications for water quantity and quality differences from paired edge-of-field sites

As part of the Great Lakes Restoration Initiative, paired edge-of-field sites were established in high priority subwatersheds to assess the effectiveness of agricultural management practices. One pairing was in Black Creek, a tributary to the Maumee River and Lake Erie. These fields were paired because of similarity in soils, topography, and agricultural management. Following two years of baseline data collection from these fields, consistent differences in water quantity and quality were observed for tile networks draining the fields, despite these fields being adjacent and managed together. Consequently, it was hypothesized that differences in subsurface water movement, specifically tile-drain density and connectivity, were the source of the observed differences. Our objective was to map the tile-drain network using remote sensing methodology in order to improve the understanding of nutrient and water transport as well as management on these fields. A combination of multispectral and thermal imagery, collected in spring of 2017, was incorporated to delineate the tile-drain network within each field. This imagery led to locating a cracked tile, which provided a direct path for overland flow to enter the tile-drain system and suggested that a tile-drain segment under the road connected the two fields. A ground-penetrating radar survey verified multiple tile locations, including the tile segment under the road. The distribution of these tiles helps explain the difference in water quantity and quality in the two fields.

Journal of Soil and Water Conservation

Recurrent geothermally induced debris avalanches on Boulder Glacier, Mount Baker, Washington

Avalanches of snow, firn and hydrothermally altered rock and mud have been released six times since 1958 from Sherman Peak, part of the crater rim south of the main summit of Mount Baker, Wash. The avalanches traveled nearly identical paths 2.0-2.6 km down Boulder Glacier on the east slope of the volcano. Debris from at least one past avalanche can be seen as a thin bed of acidic mud in the glacier terminus. Fumaroles. thermal springs, and areas of warm ground, some of which are subglacial, are concentrated in the crater and were mapped by aerial infrared thermography. The outgoing radiant flux per unit area from a cluster of infrared anomalies within 50-150 m of the avalanche source was estimated to be 319 W m -2 (7,620 μ cal cm -2 s -1 ) in November 1972, which is sufficient to account for observed ice perforations. In addition vapor emission, not apparent in thermography, was observed along the source margin after the avalanche of August 1973. The principal conditions that produce the avalanches are considered to be the large accumulation of snow and firn on top of hydrothermally altered clay-rich ground at Sherman Peak and the saturation near the ground-firn interface by melt water produced both by summer snow ablation and by geothermal emission. The periodic avalanches have a potential for impounding water in the crater in addition to ponded water already known to occur. Sudden release of impounded water could present a danger to the Boulder Creek valley below.

Washington

Estimating nitrogen loading to ground water and assessing vulnerability to nitrate contamination in a large karstic springs Basin, Florida

A nitrogen (N) mass-balance budget was developed to assess the sources of N affecting increasing ground-water nitrate concentrations in the 960-km 2 karstic Ichetucknee Springs basin. This budget included direct measurements of N species in rainfall, ground water, and spring waters, along with estimates of N loading from fertilizers, septic tanks, animal wastes, and the land application of treated municipal wastewater and residual solids. Based on a range of N leaching estimates, N loads to ground water ranged from 262,000 to 1.3 million kg/year; and were similar to N export from the basin in spring waters (266,000 kg/year) when 80-90% N losses were assumed. Fertilizers applied to cropland, lawns, and pine stands contributed about 51% of the estimated total annual N load to ground water in the basin. Other sources contributed the following percentages of total N load to ground water: animal wastes, 27%; septic tanks, 12%; atmospheric deposition, 8%; and the land application of treated wastewater and biosolids, 2%. Due to below normal rainfall (97.3 cm) during the 12-month rainfall collection period, N inputs from rainfall likely were about 30% lower than estimates for normal annual rainfall (136 cm). Low N-isotope values for six spring waters (??15N-NO3 = 3.3 to 6.3???) and elevated potassium concentrations in ground water and spring waters were consistent with the large N contribution from fertilizers. Given ground-water residence times on the order of decades for spring waters, possible sinks for excess N inputs to the basin include N storage in the unsaturated zone and parts of the aquifer with relatively sluggish ground-water movement and denitrification. A geographical-based model of spatial loading from fertilizers indicated that areas most vulnerable to nitrate contamination were located in closed depressions containing sinkholes and other dissolution features in the southern half of the basin. ?? 2009 American Water Resources Association.

Journal of the American Water Resources Associatio

Comparison of ground-water flow model particle-tracking results and isotopic data in the Mojave River ground-water basin, southern California, USA

Flow-path and time-of-travel results for the Mojave River ground-water basin, southern California, calculated using the ground-water flow model MODFLOW and particle-tracking model MODPATH were similar to flow path and time-of-travel interpretations derived from delta-deuterium and carbon-14 data. Model and isotopic data both show short flow paths and young ground-water ages throughout the floodplain aquifer along most the Mojave River. Longer flow paths and older ground-water ages as great as 10,000 years before present were measured and simulated in the floodplain aquifer near the Mojave Valley. Model and isotopic data also show movement of water between the floodplain and regional aquifer and subsequent discharge of water from the river to dry lakes in some areas. It was not possible to simulate the isotopic composition of ground-water in the regional aquifer away from the front of the San Gabriel and San Bernardino Mountains - because recharge in these areas does not occur under the present-day climatic conditions used for calibration of the model.

Journal of Hydrology

The value of geophysical methods in ground‐water studies

Two meanings are unfortunately given to the term geophysics. In the broad sense, based on the etymology of the term, geophysics means the physics of the Earth. This is its significance in the names “Geophysical Laboratory of the Carnegie Institution of Washington,” “International Union of Geodesy and Geophysics,” and “American Geophysical Union.” In this sense the sciences of geology and hydrology are largely geophysics, although in part they are geochemistry or biology. Geologists and hydraulic engineers who are elected to membership in the American Geophysical Union are, however, often surprised to find that they are regarded as “geophysicists.” I hope that when the Union establisnes a journal, its name will include the expression “Earth physics” or “Physics of the Earth,” in order that there will be no misunderstanding as to its scope.

Eos, Transactions, American Geophysical Union

In-situ alteration of minerals by acidic ground water resulting from mining activities: Preliminary evaluation of method

The chemical composition of the Cu-mining-related acidic ground water (pH ∼ 3.5 to near neutral) in Pinal Creek Basin, Arizona has been monitored since 1980. In-situ experiments are planned using alluvial sediments placed in the ground-water flow path to measure changes in mineral and chemical composition and changes in dissolution rates of subsurface alluvial sediments. The test results should help refine developed models of predicted chemical changes in ground-water composition and models of streamflow. For the preliminary test, sediment from the depth of the well screen of a newly drilled well was installed in three wells, the source well (pH 4.96) and two up-gradient wells (pHs 4.27 and 4.00). The sediment was placed in woven macrofilters, fastened in series to polyvinyl chloride (PVC) pipes, and hung at the screened level of each well. After interacting with the slowly moving ground water for 48 days, the test sediments were removed for analysis. There was no evidence that any of the materials used were biologically or chemically degraded or that the porosity of the filters was diminished by ferric hydroxide precipitation. These materials included 21-μm-pore (21PEMF) and 67-μm-pore polyester and the 174-μm-pore fluorocarbon Spectra/mesh macrofilters containing the in-situ sediment, the polypropylene (PP) macrofilter support structures, and the Nylon (NY) monofilament line used to attach the samples to the PVC pipe. Based on chemical and mineral composition and on particle-size distribution of the sediment before and after ground-water exposure, the 21PEMF macrofilter was chosen as the most suitable macrofilter for the long-term in-situ experiment. Tests also showed that the PP support structures and the NY monofilament line were sufficiently durable for this experiment.

Arizona