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At least 145 records · Page 8Linked to original sources

Results of a Survey of Residential Home Heating Fuel and Stove Type and Use in the Shiprock Area of the Navajo Nation

For many Navajo people, coal provides an affordable and convenient means of home heating. However, coal combustion results in the formation and mobilization of materials that are known risk factors for respiratory and other diseases. The level of respiratory morbidity among the Navajo people is higher than can be explained by usual epidemiological risk factors. The Shiprock area of the Navajo Nation is somewhat unique in that atmospheric thermal inversions trap air pollution low to the ground, especially in winter. There are two large mine mouth coal-fired power plants located in the vicinity, with a third plant in the planning stages. Both of the existing power plants are exempt from regulation under the U.S. Environmental Protection Agency 1990 Amendments to the Clean Air Act due to their age. The purpose of this survey was to assess the fuel and stove type and use, and document other household characteristics that might be related to the exposure of potentially toxic coal combustion products. A total of 137 surveys was conducted in English and Navajo to ascertain and document fuel usage and the type, size and conditions of heating stoves used in both traditional and modern homes. Results have been presented to the community at the Shiprock Chapter in the Navajo language. To increase public awareness, ways to properly use and store coal and to improve stove function and ventilation were also shared.

Open-File Report↗

Utilizing multiple hydrogeologic and anthropogenic indicators to understand zones of groundwater contribution to water-supply wells near Kirtland Air Force Base Bulk Fuels Facility in southeast Albuquerque, New Mexico

In 1999, a jet-fuels release was discovered at the Bulk Fuels Facility on Kirtland Air Force Base, Albuquerque, New Mexico. Contaminants had reached the water table and migrated north-northeast toward water-supply wells. Monitoring wells were installed downgradient from the facility to determine the primary zones of groundwater production for water-supply wells and assess contaminant presence. The monitoring wells are screened within the Santa Fe Group aquifer system, which includes clay units, at depths as great as 445 meters below land surface, and were categorized as water table, shallow, middle, deep, and aquifer-test pumping wells. Water-supply wells are screened across multiple water-bearing units within the aquifer system. All wells were sampled for major ions, trace elements, nutrients, stable isotopes, dissolved gases, tritium, carbon isotopes, and chlorofluorocarbons. The deeper and water-supply wells have evidence of longer groundwater residence times, as much as thousands of years, and water from the shallower wells shows evidence of anthropogenic nutrient inputs. Aquifer recharge is derived from either the mountain front or seepage from the Rio Grande. Dissolved-gas data indicate that the middle, deep, and aquifer-test pumping, and water-supply wells have cooler recharge temperatures than the shallower wells. Inferred groundwater age varies by method but indicates that the deeper, aquifer-test pumping, and water-supply wells have older water, as much as 15,000 years before present. Results indicate that the water-supply wells draw primarily from the middle and deeper portions of the aquifer system below the clay units and have not been affected by the contaminant plume, although some data indicate a potential for modern water entering some of the deeper and water-supply wells.

New Mexico↗

Completion summary for boreholes USGS 148, 148A, and 149 at the Materials and Fuels Complex, Idaho National Laboratory, Idaho

In 2019, the U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Energy, drilled and constructed boreholes USGS 148A and USGS 149 for stratigraphic framework analyses and long-term groundwater monitoring of the eastern Snake River Plain aquifer at the Idaho National Laboratory (INL) in southeastern Idaho. Initially, boreholes USGS 148A and USGS 149 were continuously cored to allow the USGS and INL subcontractor to collect select geophysical and seismic data and evaluate properties of recovered core material. The USGS geophysical data and descriptions of core material are described in this report; however, data collected by the INL contractor, including seismic data, are not included as part of the report. The unsaturated zone at both borehole locations is relatively thick, depth to water was measured at approximately 663.6 feet (ft) below land surface (BLS) in USGS 148A, and at approximately 654.1 ft BLS at USGS 149. On completion of coring and data collection, both boreholes (USGS 148A and USGS 149) were repurposed as monitoring wells. Well USGS 148A was constructed to a depth of 759 ft BLS and instrumented with a dedicated submersible pump and measurement line; well USGS 149 was constructed to a depth of 974 ft BLS and instrumented with a multilevel monitoring system (Westbay TM ). Geophysical data, collected by the USGS, were used to characterize the subsurface geology and aquifer conditions. Natural gamma log measurements were used to assess sediment-layer thickness and location. Neutron and gamma-gamma source logs were used to confirm fractured and vesicular basalt identified for aquifer testing and multilevel monitoring well zone testing. Acoustic televiewer logs, collected for well USGS 149, were used to identify fractures and assess groundwater movement when compared with neutron measurements. Furthermore, gyroscopic deviation measurements were used to measure horizontal and vertical displacement for the constructed boreholes USGS 148A and USGS 149. A single-well aquifer test was done in well USGS 148A during November 6–7, 2019, to provide estimates of transmissivity and hydraulic conductivity. Estimates for transmissivity and hydraulic conductivity were 6.34×10 3 feet squared per day and 3.17 feet per day, respectively. The aquifer test was run overnight (21.3 hours) and measured drawdown was relatively small (0.09 ft) at sustained pumping rates ranging from 15.7 to 16.1 gallons per minute. The transmissivity estimates for well USGS 148A were slightly lower than those determined from previous aquifer tests for wells near the Materials and Fuels Complex, but well within range of other aquifer tests done at the INL. Water-quality samples, collected from well USGS 148A and from four zones in well USGS 149, were analyzed for cations, anions, metals, nutrients, volatile organic compounds, stable isotopes, and radionuclides. Water samples for most of the inorganic constituents showed similar chemistry in USGS 148A and all four zones in USGS 149. Water samples for stable isotopes of oxygen and hydrogen indicated some possible influence of irrigation on the water quality. Nitrate plus nitrite concentrations indicated influence from anthropogenic sources. The volatile organic compound and radiochemical data indicated that wastewater disposal practices at the Materials and Fuels Complex or from drilling had no detectable influence on these wells.

Idaho↗

Geological setting of U.S. fossil fuels.

The USA has a special position in terms of fossil fuel development. Not only is it one of the most important nations in terms of resources of oil, gas and coal, but it has also been by far the dominant producer and consumer. In this thorough review of the regional geological environments in which fossil fuels formed in the USA, the authors point to a variety of models of resource occurrence of global interest.-Authors

Episodes↗

Geochemical controls of vanadium accumulation in fossil fuels

High vanadium contents in petroleum and other fossil fuels have been attributed to organic-matter type, organisms, volcanic emanations, diffusion of sea water, and epigenetic enrichment. However, these factors are inadequate to account for the high abundance of vanadium in some fossil fuels and the paucity in others. By examining vanadium deposits in sedimentary rocks with sparse organic matter, constraints are placed on processes controlling vanadium accumulation in organic-rich sediments. Vanadium, as vanadate (V(V)), entered some depositional basins in oxidizing waters from dry, subaerial environments. Upon contact with organic matter in anoxic waters, V(V) is reduced to vanadyl (V(IV)), which can be removed from the water column by adsorption. H2S reduces V(IV) to V(III), which hydrolyzes and precipitates. The lack of V(III) in petroleum suggests that reduction of V(IV) to V(III) is inhibited by organic complexes. In the absence of strong complexing agents, V(III) forms and is incorporated in clay minerals.

Conference Paper↗

Geochemical controls on vanadium accumulation in fossil fuels

High vanadium contents in petroleum and other fossil fuels have been attributed to organic-matter type, organisms, volcanic emanations, diffusion of sea water, and epigenetic enrichment. However, these factors are inadequate to account for the high abundance of vanadium in some fossil fuels and the paucity in others. By examining vanadium deposits in sedimentary rocks with sparse organic matter, constraints are placed on processes controlling vanadium accumulation in organic-rich sediments. Vanadium, as vanadate (V(V)), entered some depositional basins in oxidizing waters from dry, subaerial environments. Upon contact with organic matter in anoxic waters, V(V) is reduced to vanadyl (V(IV)), which can be removed from the water column by adsorption. H2S reduces V(IV) to V(III), which hydrolyzes and precipitates. The lack of V(III) in petroleum suggests that reduction of V(IV) to V(III) is inhibited by organic complexes. In the absence of strong complexing agents, V(III) forms and is incorporated in clay minerals.

Conference Paper↗

Decreased survival of rainbow trout exposed to no. 2 fuel oil caused by sublethal preexposure

Rainbow trout ( Oncorhynchus mykiss ) were exposed for 21 d to sublethal levels of No. 2 fuel oil (2FO). The four exposure concentrations ranged from 12 to 100 mg/L 2FO dispersed in water and resulted in 0 to 12% mortality. Following this exposure period (preexposure) the ability of preexposed trout to survive exposure to acutely lethal levels of 2FO was observed. Preexposure to either 50 or 100 mg/L 2FO consistently resulted in decreased survival and a lower LC50 for a given observation period. Unfortunately, because the LC50 determinations were not obtained independently, they could not be used to test statistically the effects of preexposure on survival. Therefore, two proportional hazard modeling techniques were applied to the data to test for effects due to preexposure. Both modeling techniques indicated that preexposure results in decreased survival of rainbow trout exposed to acutely toxic levels of 2FO. Thus, in contrast to preexposure to metals, which results in acclimation, preexposure to 2FO results in decreased survival.

Environmental Toxicology and Chemistry↗

No. 2 fuel oil decreases embryonic survival of great black-backed gulls

The great black-backed gull (Larus marinus ) is widespread in the northern hemisphere, breeding south to Britain and Ireland on the European side of the Atlantic and to Long Island in the United States where populations have increased markedly during the last 50 years (DRURY 1979). With growing exploitation of oil resources, seabird populations are being increasingly threatened by accidental oiling of individuals and the subsequent contamination of their eggs and young. It is generally agreed that gulls and terns, which spend much of their time airborne, are less vulnerable to oil pollution than alcids and seaducks (BOURNE 1968, VERMEER AND ANWEILER 1975). Nevertheless, oiled great black-backed gulls were sighted after the Argo Merchant spill off Nantucket Island in December 1976, demonstrating that this species of gull can be affected by surface oil (GROSE AND MATTSON 1977). In this paper we wish to report results of two concurrent studies in which eggs of the great black-backed gull were externally contaminated with No. 2 fuel oil.

Bulletin of Environmental Contamination and Toxico↗

Detritus fuels ecosystem metabolism but not metazoan food webs in San Francisco estuary's freshwater delta

Detritus from terrestrial ecosystems is the major source of organic matter in many streams, rivers, and estuaries, yet the role of detritus in supporting pelagic food webs is debated. We examined the importance of detritus to secondary productivity in the Sacramento and San Joaquin River Delta (California, United States), a large complex of tidal freshwater habitats. The Delta ecosystem has low primary productivity but large detrital inputs, so we hypothesized that de tritus is the primary energy source fueling production in pelagic food webs. We assessed the sources, quantity, composition, and bioavailability of organic matter among a diversity of habitats (e.g., marsh sloughs, floodplains, tidal lakes, and deep river channels) over two years to test this hypothesis. Our results support the emerging principle that detritus dominates riverine and estuarine organic matter supply and supports the majority of ecosystem metabolism. Yet in contrast to prevailing ideas, we found that detritus was weakly coupled to the Delta's pelagic food web. Results from independent approaches showed that phytoplankton production was the dominant source of organic matter for the Delta's pelagic food web, even though primary production accounts for a small fraction of the Delta's organic matter supply. If these results are general, they suggest that the value of organic matter to higher trophic levels, including species targeted by programs of ecosystem restoration, is a function of phytoplankton production.

Estuaries↗

Food web fuel differs across habitats and seasons of a tidal freshwater estuary

Estuarine food webs are fueled by multiple different primary producers. However, identifying the relative importance of each producer to consumers is difficult, particularly for fishes that utilize multiple food sources due to both their mobility and their generally high trophic levels. Previous studies have documented broad spatial differences in the importance of primary producers to fishes within the Upper San Francisco Estuary, California, including separation between pelagic and littoral food webs. In this study, we evaluated the importance of primary producers to adult fishes in three closely spaced subregions that represented disparate habitat types (a tidal wetland channel, a turbid backwater channel, and a deep open-water channel), each a potential outcome of local restoration projects. Using stable isotope analysis coupled with a Bayesian mixing model, we identified significant differences in primary-producer contribution to fishes and invertebrates across habitats and seasons, especially in the relative contribution of submersed aquatic vegetation and phytoplankton. Most fishes utilized multiple primary producers and showed little segregation between pelagic and littoral food webs among habitats. Availability of primary producers differs seasonally and across multiple spatial scales, helping to buffer environmental variability and thus enhancing food web resilience. Ecosystem restoration may improve with emphasis on restoring a wide variety of primary producers to support consumers.

California↗

Understanding market sensitivity: Estimation of supply and demand elasticities for non-fuel minerals

In today’s rapidly changing economic landscape, understanding market responsiveness to price changes and the factors influencing commodity prices has become increasingly relevant. Price elasticities serve as indicators of how variations in market conditions affect supply and demand, providing insights into the sensitivity of commodity markets to price fluctuations. This paper presents a comprehensive analysis of price elasticities of supply and demand for 74 non-fuel mineral commodities including precious metals, base metals, minor metals, and industrial minerals that are utilized across various industries. We employ various econometric techniques, including fixed effects models for panel data and two-stage dynamic ordinary least squares (2S-DOLS) alongside autoregressive distributed lag (ARDL) models for time series analysis, to derive robust estimates of price elasticities. Our findings reveal variability in elasticities among different commodities and indicate that all studied mineral commodities exhibit price inelastic supply and demand in the short run, which we define as one year for the purposes of our analysis, given that the data is all annual. This research provides original estimates of price responsiveness for a wide range of commodities that have not been previously addressed in the literature, thereby enhancing the understanding of market dynamics in the mineral sector. Given that price elasticities can be influenced by factors such as market structure, technological advancements, mining costs, and industry-specific demand drivers, we use variables that serve as proxies for these factors.

Mineral Economics↗

Accumulation of fossil fuels and metallic minerals in active and ancient rift lakes

A study of active and ancient rift systems around the world suggests that accumulations of fossil fuels and metallic minerals are related to the interactions of processes that form rift valleys with those that take place in and around rift lakes. The deposition of the precursors of petroleum, gas, oil shale, coal, phosphate, barite, Cu-Pb-Zn sulfides, and uranium begins with erosion of uplifted areas, and the consequent input of abundant nutrients and solute loads into swamps and tectonic lakes. Hot springs and volcanism add other nutrients and solutes. The resulting high biological productivity creates oxidized/reduced interfaces, and anoxic and H 2 S-rich bottom waters which preserves metal-bearing organic tissues and horizons. In the depositional phases, the fine-grained lake deposits are in contact with coarse-grained beach, delta, river, talus, and alluvial fan deposits. Earthquake-induced turbidites also are common coarse-grained deposits of rift lakes. Postdepositional processes in rifts include high heat flow and a resulting concentration of the organic and metallic components that were dispersed throughout the lakebeds. Postdepositional faulting brings organic- and metal-rich sourcebeds in contact with coarse-grained host and reservoir rocks. A suite of potentially economic deposits is therefore a characteristic of rift valleys.

Tectonophysics↗

Effects of external applications of No. 2 fuel oil on common eider eggs

Because eggs of marine birds may be exposed to oil adhering to the feathers of adult birds, a study was undertaken to determine the effects of oil contamination. Two hundred common eider eggs were divided into four experimental sets of 50 each. Two sets were treated with No. 2 fuel oil in amounts of 5 microliters to 20 microliters; a third with 20 microliters of propylene glycol, a neutral blocking agent. The fourth set served as a control. Hatching success was 96 percent for the eggs treated with 20 microliters propylene glycol, 96 percent for the controls and 92 percent for the eggs treated with 5 microliters oil hatched. Only 69 percent of the eggs treated with 20 microliters of oil survived - a significant reduction in hatchability (P 0.05). Mean Hatching weights for all sets were statistically equal. Thus, oil pollution may significantly increase embryonic mortality in marine birds.

Book chapter↗

Temporal variations in parameters reflecting terminal-electron-accepting processes in an aquifer contaminated with waste fuel and chlorinated solvents

A fundamental issue in aquifer biogeochemistry is the means by which solute transport, geochemical processes, and microbiological activity combine to produce spatial and temporal variations in redox zonation. In this paper, we describe the temporal variability of TEAP conditions in shallow groundwater contaminated with both waste fuel and chlorinated solvents. TEAP parameters (including methane, dissolved iron, and dissolved hydrogen) were measured to characterize the contaminant plume over a 3-year period. We observed that concentrations of TEAP parameters changed on different time scales and appear to be related, in part, to recharge events. Changes in all TEAP parameters were observed on short time scales (months), and over a longer 3-year period. The results indicate that (1) interpretations of TEAP conditions in aquifers contaminated with a variety of organic chemicals, such as those with petroleum hydrocarbons and chlorinated solvents, must consider additional hydrogen-consuming reactions (e.g., dehalogenation); (2) interpretations must consider the roles of both in situ (at the sampling point) biogeochemical and solute transport processes; and (3) determinations of microbial communities are often necessary to confirm the interpretations made from geochemical and hydrogeological measurements on these processes.

Michigan↗

Ancient low–molecular-weight organic acids in permafrost fuel rapid carbon dioxide production upon thaw

Northern permafrost soils store a vast reservoir of carbon, nearly twice that of the present atmosphere. Current and projected climate warming threatens widespread thaw of these frozen, organic carbon (OC)-rich soils. Upon thaw, mobilized permafrost OC in dissolved and particulate forms can enter streams and rivers, which are important processors of OC and conduits for carbon dioxide (CO 2 ) to the atmosphere. Here, we demonstrate that ancient dissolved organic carbon (DOC) leached from 35,800 y B.P. permafrost soils is rapidly mineralized to CO 2 . During 200-h experiments in a novel high–temporal-resolution bioreactor, DOC concentration decreased by an average of 53%, fueling a more than sevenfold increase in dissolved inorganic carbon (DIC) concentration. Eighty-seven percent of the DOC loss to microbial uptake was derived from the low–molecular-weight (LMW) organic acids acetate and butyrate. To our knowledge, our study is the first to directly quantify high CO 2 production rates from permafrost-derived LMW DOC mineralization. The observed DOC loss rates are among the highest reported for permafrost carbon and demonstrate the potential importance of LMW DOC in driving the rapid metabolism of Pleistocene-age permafrost carbon upon thaw and the outgassing of CO 2 to the atmosphere by soils and nearby inland waters.

PNAS↗

Influence of environmental factors on denitrification in sediment contaminated with JP-4 jet fuel

In 1975, the loss of approximately 83,000 gallons of JP-4 grade jet fuel resulted in contamination of the shallow aquifer near North Charleston, South Carolina. To identify those factors likely to influence microbial activity under denitrifying conditions, we examined the fate of amended NO 3 , the effect of pH, NO 3 , and PO 4 on denitrification, and the variability of denitrification in sediments collected at the site. Denitrification (N 2 O-N production) accounted for 98% of the depletion of NO 3 -N under anaerobic conditions. Both carbon mineralization and denitrification rates increased asymptotically with increasing NO 3 to a maximum at approximately 1 mM NO 3 . Addition of up to 1 mM PO 4 did not significantly increase N 2 O and CO 2 production. Denitrification rates were at least 38% lower at p H = 4 than observed at p H = 7. Comparison of samples with differing degrees of hydrocarbon contamination indicated that at least a tenfold variation in sediment denitrification occurs at the North Charleston site.

Groundwater↗

Fuel treatment impacts on estimated wildfire carbon loss from forests in Montana, Oregon, California, and Arizona

Using forests to sequester carbon in response to anthropogenically induced climate change is being considered across the globe. A recent U.S. executive order mandated that all federal agencies account for sequestration and emissions of greenhouse gases, highlighting the importance of understanding how forest carbon stocks are influenced by wildfire. This paper reports the effects of the most common forest fuel reduction treatments on carbon pools composed of live and dead biomass as well as potential wildfire emissions from six different sites in four western U.S. states. Additionally, we predict the median forest product life spans and uses of materials removed during mechanical treatments. Carbon loss from modeled wildfire-induced tree mortality was lowest in the mechanical plus prescribed fire treatments, followed by the prescribed fire-only treatments. Wildfire emissions varied from 10&ndash;80 Mg/ha and were lowest in the prescribed fire and mechanical followed by prescribed fire treatments at most sites. Mean biomass removals per site ranged from approximately 30&ndash;60 dry Mg/ha; the median lives of products in first use varied considerably (from <10 to >50 years). Our research suggests most of the benefits of increased fire resistance can be achieved with relatively small reductions in current carbon stocks. Retaining or growing larger trees also reduced the vulnerability of carbon loss from wildfire. In addition, modeled vulnerabilities to carbon losses and median forest product life spans varied considerably across our study sites, which could be used to help prioritize treatment implementation.

California, Oregon, Montana, Arizona↗

The devil is in the details: Variation in public acceptance of fuels treatments across western fire-prone communities

Implementation of broad landscape management goals to confront the wildfire crisis occurs at the project level and is subject to public scrutiny. Although the research literature demonstrates broad public acceptability of fuels treatments, a closer examination of the studies reveals notable variation in acceptance. Survey data from thirteen western U.S. communities using the same measures of acceptability are presented. Results highlight high acceptance with notable variation in treatment type and study location. Results indicate that the devil is in the details.

Western Economics Forum↗