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At least 145 records · Page 8Linked to original sources

Specific-lon electrode determinations of sulfide preconcentrated from San Francisco Bay waters

Measurements of low-level dissolved-sulfide concentrations in estuarine water from San Francisco Bay have been made using the sulfide-specific electrode after preservation, separation, and preconcentration of the sulfide species. The separation and preconcentration were acheived by coprecipitation of ZnS with Zn(OH)2 followed by collection and dissolution of the precipitate, giving concentration factors up to 160-fold Preconcentration provided sulfide solutions that were adequately measurable within the practical working range of the specific-ion electrode The sulfide detection limit with the preconcentration step is 0 02 ??g/l Spike recoveries in the range of 81 to 10 1% have been achieved for laboratory-prepared samples having S2- concentrations as low as 0 6 ??g/l and 84 to 100% for an estuarine sample spiked in the field with 2 ??g/l (S(-II) Positive correlations have been found between dissolved S(-II) concentrations and concentrations of dissolved Cd, Cu, and Ni, negative correlations have been found between bisulfide (HS-) activity and activities of Cd2+, Cu2+, and Ag+ species ?? 1984 Springer-Verlag New York Inc.

Environmental Geology and Water Sciences

Dendrogeomorphic evidence of debris flow frequency and magnitude at Mount Shasta, California

Debris-flow deposits and woody vegetation adjacent to and growing within the channels of Whitney, Bolam, Mud, Ash, and Panthe creeks provide a 300-year record of debris-flow frequency at Mount Shasta Dendrochronologic (tree-ring) dating methods for the debris flows proved consistent with available documented records of debris flows Nine debris flows not reported in the historic record were documented and dated dendrochronologically. The oldest tree-ring date for a mudflow was about 1670 Combined geomorphic and botanical evidence shows that debris flows are a common occurrence at Mount Shasta Debris flows traveling at least 2 km have occurred at the rate of about 8 3 per century Smaller debris flows occur substantially more frequently and usually do not proceed as far downslope as larger debris flows. Cyclic scouring and filling by debris flows, in and adjacent to the stream channels, is suggested by dendrogeomorphic evidence and appears to be related to their magnitude and frequency Debris flows, small and large, may be the major surficial geomorphic agent in the vicinity of mount Shasta, sculpturing the channels and developing large alluvial fans ?? 1984 Springer-Verlag New York Inc.

California

Wavelike movement of bedload sediment, East Fork River, Wyoming

Bedload is moved down the East Fork River in distinct wavelike pulses that have the form of composite dune fields The moving material consists mostly of coarse sand and fine gravel The wavelengths of the pulses are about 500-600 m, a distance that is predetermined by the pattern of stoage of bed sediment in the river during low water As the river discharge increases, the bed sediment is scoured from the storage areas, and it is moved onto and across the interventing riffles As the river discharge decreases, the bed sediment is scoured off the riffles and moved into the next storage area downstream Each successive pulse of water discharge sets into motion a wave of bedload that continues to move unitil it reaches the next storage area ?? 1985 Springer-Verlag New York Inc.

Environmental Geology and Water Sciences

Mobility of organic solvents in water-saturated soil materials

This investigation presents an analysis of the mobility of 37 organic solvents in saturated soil-water systems, focusing on adsorption phenomena at the solid-liquid interface This analysis was made, in part, by applying predictive expressions that estimate the potential magnitude of adsorption by soil materials Of the 37 solvents considered, 19 were classified as either "very highly mobile" or "highly mobile" and, thus, would have little tendency to be retained by soils to a significant extent, 12 were considered to have medium mobility and 6 low mobility None of these solvents were in the immobile class The limited information available indicates that these predictive expressions yield satisfactory first approximations of the magnitude of adsorption of these solvents by soil materials ?? 1985 Springer-Verlag New York Inc.

Environmental Geology and Water Sciences

Persisting effects of armored military maneuvers on some soils of the Mojave Desert

Soil compaction and substrate modification produced during large-scale armored military maneuvers in the early 1940s were examined in 1981 at seven sites in California's eastern Mojave Desert Recording penetrometer measurements show that tracks left by a single pass of an M3 "medium" tank have average soil resistance values that are 50% greater than those of the surrounding untracked soil in the upper 20 cm At one site, measurements made along short segments of track that have been visually eliminated by erosion and deposition processes show a 73% increase in penetrometer resistance over adjacent, undisturbed soils Dirt roadways at three former base camp locations could not be penetrated below 5-10 cm because of extreme compaction Soil bulk density was not as sensitive an indicator of soil compaction as was penetrometer resistance Density values in the upper 10 cm of soil are not significantly different between tank tracks and undisturbed soils at most sites, and roadways at two base camps show an average increase in bulk density of only 12% over adjacent soils. Trench excavations across tank tracks show that physical modifications of the substrate can extend vertically beneath a track to a depth of 25 cm and outward from a track's edge to 50 cm These soil disturbances are probably major factors that encourage accelerated soil erosion throughout the manuever area and also retard or prevent the return of vegetation to pre-disturbance conditions ?? 1985 Springer-Verlag New York Inc.

Environmental Geology and Water Sciences

Origin and influence of coal mine drainage on streams of the United States

Degradation of water quality related to oxidation of iron disulfide minerals associated with coal is a naturally occurring process that has been observed since the late seventeenth century, many years before commencement of commercial coal mining in the United States. Disturbing coal strata during mining operations accelerates this natural deterioration of water quality by exposing greater surface areas of reactive minerals to the weathering effects of the atmosphere, hydrosphere, and biosphere. Degraded water quality in the temperate eastern half of the United States is readily detected because of the low mineralization of natural water. Maps are presented showing areas in the eastern United States where concentrations of chemical constituents in water affected by coal mining (pH, dissolved sulfate, total iron, total manganese) exceed background values and indicate effects of coal mining. Areas in the East most affected by mine drainage are in western Pennsylvania, southern Ohio, western Maryland, West Virginia, southern Illinois, western Kentucky, northern Missouri, and southern Iowa. Effects of coal mining on water quality in the more arid western half of the United States are more difficult to detect because of the high degree of mineralization of natural water. Normal background concentrations of constituents are not useful in evaluating effects of coal mine drainage on streams in the more arid West. Three approaches to reduce the effects of coal mining on water quality are: (1) exclusion of oxygenated water from reactive minerals, (2) neutralization of the acid produced, (3) retardation of acid-producing bacteria population in spoil material, by application of detergents that do not produce byproducts requiring disposal. These approaches can be used to help prevent further degradation of water quality in streams by future mining. ?? 1988 Springer-Verlag New York Inc.

Environmental Geology and Water Sciences

Changes in groundwater quality in a conduit-flow-dominated karst aquifer, following BMP implementation

Water quality in the Pleasant Grove Spring karst groundwater basin, Logan County, Kentucky, was monitored to determine the effectiveness of best management practices (BMPs) in protecting karst aquifers. Ninety-two percent of the 4,069-ha (10,054-acre) watershed is used for agriculture. Water-quality monitoring began in October 1992 and ended in November 1998. By the fall of 1995 approximately 72% of the watershed was enrolled in BMPs sponsored by the US Department of Agriculture Water Quality Incentive Program (WQIP). Pre-BMP nitrate-nitrogen concentration averaged 4.65 mg/1. The median total suspended solids concentration was 127 mg/1. The median triazine concentration measured by immunosorbent assay was 1.44 ??tg/l. Median bacteria counts were 418 colonies per 100 ml (col/100 ml) for fecal coliform and 540 col/100 ml for fecal streptococci. Post-BMP, the average nitrate-nitrogen concentration was 4.74 mg/1. The median total suspended solids concentration was 47.8 mg/1. The median triazine concentration for the post-BMP period was 1.48 ??g/1. The median fecal coliform count increased to 432 col/100 ml after BMP implementation, but the median fecal streptococci count decreased to 441 col/100 ml. The pre- and post-BMP water quality was statistically evaluated by comparing the annual mass flux, annual descriptive statistics, and population of analyses for the two periods. Nitrate-nitrogen concentration was unchanged. Increases in atrazine-equivalent flux and triazine geometric averages were not statistically significant. Total suspended solids concentration decreased slightly, whereas orthophosphate concentration increased slightly. Fecal streptococci counts were reduced. The BMPs were only partially successful because the types available and the rules for participation resulted in less effective BMPs being chosen. Future BMP programs in karst areas should emphasize buffer strips around sinkholes, excluding livestock from streams and karst windows, and withdrawing land from production.

Environmental Geology

Coastal geoindicators of environmental change in the humid tropics

The primary geoindicators appropriate for monitoring environmental changes in the humid tropics are transitory surface water levels, shoreline position, wetlands distribution, coral reefs, landforms, and sediment sequence and composition. Lateral zonations and temporal successions of vegetation also can be used as geoindicators of riverine and shoreline changes. All of these coastal geoindicators are sensitive to regional tectonic processes and anthropogenic alterations and they typically reflect significant changes in coastal conditions such as fluvial processes, coastal energy, water quality, relative sea level, and sediment supply. Where humid tropical coasts coincide with active tectonic margins, indicators of seismic activity are critical to understanding Coastal changes associated with co-seismic subsidence or uplift, tsunamis, and liquefaction of coastal sediments. Coastal landforms and sedimentary deposits that record late Quaternary environmental changes include perched fluvial and marine terraces, delta-plain morphologies, crevassesplay deposits, peats and other paleosols, beach ridges, mud capes, and mud volcanoes. Although these features and deposits typically reflect environmental changes spanning more than 100 years, they are relevant to modern processes, management of coastal lands and resources, and prediction of future conditions. In some regions of the humid tropics, large coastal areas are unaffected by hurricanes or typhoons. Nevertheless, these tropical coasts are vulnerable to other non-storm processes, such as El Nin??o events, tsunamis, and monsoons that increase water levels, and cause widespread flooding and beach erosion. The environmental and political significance of coastal geoindicators increases when they are integrated and applied to issues of human safety and health such as hazards mapping, risk assessment, and dispersion of contaminated sediments. However, to be relevant, those socio-environmental applications demand accurate predictions of future trends and rates of change.

Environmental Geology

Microbial cycling of mercury in contaminated pelagic and wetland sediments of San Pablo Bay, California

San Pablo Bay is an estuary, within northern San Francisco Bay, containing elevated sediment mercury (Hg) levels because of historic loading of hydraulic mining debris during the California gold-rush of the late 1800s. A preliminary investigation of benthic microbial Hg cycling was conducted in surface sediment (0–4 cm) collected from one salt-marsh and three open-water sites. A deeper profile (0–26 cm) was evaluated at one of the open-water locations. Radiolabeled model Hg-compounds were used to measure rates of both methylmercury (MeHg) production and degradation by bacteria. While all sites and depths had similar total-Hg concentrations (0.3–0.6 ppm), and geochemical signatures of mining debris (as εNd, range: –3.08 to –4.37), in-situ MeHg was highest in the marsh (5.4±3.5 ppb) and ≤0.7 ppb in all open-water sites. Microbial MeHg production (potential rate) in 0–4 surface sediments was also highest in the marsh (3.1 ng g –1 wet sediment day –1 ) and below detection (<0.06 ng g –1 wet sediment day –1 ) in open-water locations. The marsh exhibited a methylation/demethylation (M/D) ratio more than 25× that of all open-water locations. Only below the surface 0–4-cm horizon was significant MeHg production potential evident in the open-water sediment profile (0.2–1.1 ng g –1 wet sediment day –1 ). In-situ Hg methylation rates, calculated from radiotracer rate constants, and in-situ inorganic Hg(II) concentrations compared well with potential rates. However, similarly calculated in-situ rates of MeHg degradation were much lower than potential rates. These preliminary data indicate that wetlands surrounding San Pablo Bay represent important zones of MeHg production, more so than similarly Hg-contaminated adjacent open-water areas. This has significant implications for this and other Hg-impacted systems, where wetland expansion is currently planned.

California

Mercury from mineral deposits and potential environmental impact

Mercury deposits are globally distributed in 26 mercury mineral belts. Three types of mercury deposits occur in these belts: silica-carbonate, hot-spring, and Almaden. Mercury is also produced as a by-product from several types of gold-silver and massive sulfide deposits, which account for 5% of the world's production. Other types of mineral deposits can be enriched in mercury and mercury phases present are dependent on deposit type. During processing of mercury ores, secondary mercury phases form and accumulate in mine wastes. These phases are more soluble than cinnabar, the primary ore mineral, and cause mercury deposits to impact the environment more so than other types of ore deposits enriched in mercury. Release and transport of mercury from mine wastes occur primarily as mercury-enriched particles and colloids. Production from mercury deposits has decreased because of environmental concerns, but by-product production from other mercury-enriched mineral deposits remains important.

Environmental Geology

Mercury in soil near a long-term air emission source in southeastern Idaho

At the Idaho National Engineering and Environmental Laboratory in southeastern Idaho, a 500 °C fluidized bed calciner was intermittently operated for 37 years, with measured Hg emission rates of 9–11 g/h. Surface soil was sampled at 57 locations around the facility to determine the spatial distribution of Hg fallout and surface Hg variability, and to predict the total residual Hg mass in the soil from historical emissions. Measured soil concentrations were slightly higher ( p <0.05) within 5 km of the source but were overall very low (15–20 ng/g) compared to background Hg levels published for similar soils in the USA (50–70 ng/g). Concentrations decreased 4%/cm with depth and were found to be twice as high under shrubs and in depressions. Mass balance calculations accounted for only 2.5–20% of the estimated total Hg emitted over the 37-year calciner operating history. These results suggest that much of the Hg deposited from calciner operations may have been reduced in the soil and re-emitted as Hg(0) to the global atmospheric pool.

Idaho

Mercury accumulation in snow on the Idaho National Engineering and Environmental Laboratory and surrounding region, southeast Idaho, USA

Snow was sampled and analyzed for total mercury (THg) on the Idaho National Engineering and Environmental Laboratory (INEEL) and surrounding region prior to the start-up of a large (9-11 g/h) gaseous mercury emission source. The objective was to determine the effects of the source on local and regional atmospheric deposition of mercury. Snow samples collected from 48 points on a polar grid near the source had THg concentrations that ranged from 4.71 to 27.26 ng/L; snow collected from regional background sites had THg concentrations that ranged from 0.89 to 16.61 ng/L. Grid samples had higher concentrations than the regional background sites, which was unexpected because the source was not operating yet. Emission of Hg from soils is a possible source of Hg in snow on the INEEL. Evidence from Hg profiles in snow and from unfiltered/filtered split samples supports this hypothesis. Ongoing work on the INEEL is investigating Hg fluxes from soils and snow.

Idaho

Characterization of anthropogenic and natural sources of acid rock drainage at the Cinnamon Gulch abandoned mine land inventory site, Summit County, Colorado

Colorado's Cinnamon Gulch releases acid rock drainage (ARD) from anthropogenic and natural sources. In 2001, the total discharge from Cinnamon Gulch was measured at 1.02 cfs (29 L/s) at base flow and 4.3 cfs (122 L/s) at high flow (spring runoff). At base flow, natural sources account for 98% of the discharge from the watershed, and about 96% of the chemical loading. At high flow, natural sources contribute 96% of discharge and 92 to 95% of chemical loading. The pH is acidic throughout the Cinnamon Gulch watershed, ranging from 2.9 to 5.4. At baseflow, nearly all of the trace metals analyzed in the 18 samples exceeded state hardness-dependent water quality standards for aquatic life. Maximum dissolved concentrations of selected constituents included 16 mg/ L aluminum, 15 mg/L manganese, 40 mg/L iron, 2 mg/L copper, 560 ??g/L lead, 8.4 mg/L zinc, and 300 mg/L sulfate. Average dissolved concentrations of selected metals at baseflow were 5.5 mg/L aluminum, 5.5 mg/L manganese, 14 ??g/L cadmium, 260 ??g/L copper, 82 ??g/L lead, and 2.8 mg/L zinc.

Environmental Geology

Weathering of sulfidic shale and copper mine waste: Secondary minerals and metal cycling in Great Smoky Mountains National Park, Tennessee, and North Carolina, USA

Metal cycling via physical and chemical weathering of discrete sources (copper mines) and regional (non-point) sources (sulfide-rich shale) is evaluated by examining the mineralogy and chemistry of weathering products in Great Smoky Mountains National Park, Tennessee, and North Carolina, USA. The elements in copper mine waste, secondary minerals, stream sediments, and waters that are most likely to have negative impacts on aquatic ecosystems are aluminum, copper, zinc, and arsenic because these elements locally exceed toxicity guidelines for surface waters or for stream sediments. Acid-mine drainage has not developed in streams draining inactive copper mines. Acid-rock drainage and chemical weathering processes that accompany debris flows or human disturbances of sulfidic rocks are comparable to processes that develop acid-mine drainage elsewhere. Despite the high rainfall in the mountain range, sheltered areas and intermittent dry spells provide local venues for development of secondary weathering products that can impact aquatic ecosystems.

Environmental Geology

Seasonality of diel cycles of dissolved trace-metal concentrations in a Rocky Mountain stream

Substantial diel (24-h) cycles in dissolved (0.1-μm filtration) metal concentrations were observed during summer low flow, winter low flow, and snowmelt runoff in Prickly Pear Creek, Montana. During seven diel sampling episodes lasting 34–61.5 h, dissolved Mn and Zn concentrations increased from afternoon minimum values to maximum values shortly after sunrise. Dissolved As concentrations exhibited the inverse timing. The magnitude of diel concentration increases varied in the range 17–152% for Mn and 70–500% for Zn. Diel increases of As concentrations (17–55%) were less variable. The timing of minimum and maximum values of diel streamflow cycles was inconsistent among sampling episodes and had little relation to the timing of metal concentration cycles, suggesting that geochemical rather than hydrological processes are the primary control of diel metal cycles. Diel cycles of dissolved metal concentrations should be assumed to occur at any time of year in any stream with dissolved metals and neutral to alkaline pH.

Environmental Geology

Karst database development in Minnesota: Design and data assembly

The Karst Feature Database (KFD) of Minnesota is a relational GIS-based Database Management System (DBMS). Previous karst feature datasets used inconsistent attributes to describe karst features in different areas of Minnesota. Existing metadata were modified and standardized to represent a comprehensive metadata for all the karst features in Minnesota. Microsoft Access 2000 and ArcView 3.2 were used to develop this working database. Existing county and sub-county karst feature datasets have been assembled into the KFD, which is capable of visualizing and analyzing the entire data set. By November 17 2002, 11,682 karst features were stored in the KFD of Minnesota. Data tables are stored in a Microsoft Access 2000 DBMS and linked to corresponding ArcView applications. The current KFD of Minnesota has been moved from a Windows NT server to a Windows 2000 Citrix server accessible to researchers and planners through networked interfaces. ?? Springer-Verlag 2005.

Environmental Geology

Geochemical and C, O, Sr, and U-series isotopic evidence for the meteoric origin of calcrete at Solitario Wash, Crater Flat, Nevada, USA

Calcite-rich soils (calcrete) in alluvium and colluvium at Solitario Wash, Crater Flat, Nevada, USA, contain pedogenic calcite and opaline silica similar to soils present elsewhere in the semi-arid southwestern United States. Nevertheless, a ground-water discharge origin for the Solitario Wash soil deposits was proposed in a series of publications proposing elevation-dependent variations of carbon and oxygen isotopes in calcrete samples. Discharge of ground water in the past would raise the possibility of future flooding in the unsaturated zone at Yucca Mountain, Nevada, site of a proposed high-level nuclear waste repository. New geochemical and carbon, oxygen, strontium, and uranium-series isotopic data disprove the presence of systematic elevation-isotopic composition relations, which are the main justification given for a proposed ground-water discharge origin of the calcrete deposits at Solitario Wash. Values of ??13C (-4.1 to -7.8 per mil [???]), ??18O (23.8-17.2???), 87Sr/ 86Sr (0.71270-0.71146), and initial 234U/238U activity ratios of about 1.6 in the new calcrete samples are within ranges previously observed in pedogenic carbonate deposits at Yucca Mountain and are incompatible with a ground-water origin for the calcrete. Variations in carbon and oxygen isotopes in Solitario Wash calcrete likely are caused by pedogenic deposition from meteoric water under varying Quaternary climatic conditions over hundreds of thousands of years. ?? Springer-Verlag 2005.

Environmental Geology

Subsidence hazards due to evaporite dissolution in the United States

Evaporites, including gypsum (or anhydrite) and salt, are the most soluble of common rocks; they are dissolved readily to form the same type of karst features that typically are found in limestones and dolomites, and their dissolution can locally result in major subsidence structures. The four basic requirements for evaporite dissolution to occur are: (1) a deposit of gypsum or salt; (2) water, unsaturated with CaSO 4 or NaCl; (3) an outlet for escape of dissolving water; and (4) energy to cause water to flow through the system. Evaporites are present in 32 of the 48 contiguous states of the United States, and they underlie about 35&ndash;40% of the land area. Karst is known at least locally (and sometimes quite extensively) in almost all areas underlain by evaporites, and some of these karst features involve significant subsidence. The most widespread and pronounced examples of both gypsum and salt karst and subsidence are in the Permian basin of the southwestern United States, but many other areas also are significant. Human activities have caused some evaporite&ndash;subsidence development, primarily in salt deposits. Boreholes may enable (either intentionally or inadvertently) unsaturated water to flow through or against salt deposits, thus allowing development of small to large dissolution cavities. If the dissolution cavity is large enough and shallow enough, successive roof failures above the cavity can cause land subsidence or catastrophic collapse.

Environmental Geology