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At least 145 records · Page 8Linked to original sources
USGS2016

Trace elements in stormflow, ash, and burned soil following the 2009 station fire in southern California

Most research on the effects of wildfires on stream water quality has focused on suspended sediment and nutrients in streams and water bodies, and relatively little research has examined the effects of wildfires on trace elements. The purpose of this study was two-fold: 1) to determine the effect of the 2009 Station Fire in the Angeles National Forest northeast of Los Angeles, CA on trace element concentrations in streams, and 2) compare trace elements in post-fire stormflow water quality to criteria for aquatic life to determine if trace elements reached concentrations that can harm aquatic life. Pre-storm and stormflow water-quality samples were collected in streams located inside and outside of the burn area of the Station Fire. Ash and burned soil samples were collected from several locations within the perimeter of the Station Fire. Filtered concentrations of Fe, Mn, and Hg and total concentrations of most trace elements in storm samples were elevated as a result of the Station Fire. In contrast, filtered concentrations of Cu, Pb, Ni, and Se and total concentrations of Cu were elevated primarily due to storms and not the Station Fire. Total concentrations of Se and Zn were elevated as a result of both storms and the Station Fire. Suspended sediment in stormflows following the Station Fire was an important transport mechanism for trace elements. Cu, Pb, and Zn primarily originate from ash in the suspended sediment. Fe primarily originates from burned soil in the suspended sediment. As, Mn, and Ni originate from both ash and burned soil. Filtered concentrations of trace elements in stormwater samples affected by the Station Fire did not reach levels that were greater than criteria established for aquatic life. Total concentrations for Fe, Pb, Ni, and Zn were detected at concentrations above criteria established for aquatic life.

California↗
USGS1997

Soluble trace elements and total mercury in Arctic Alaskan snow

Ultraclean field and laboratory procedures were used to examine trace element concentrations in northern Alaskan snow. Sixteen soluble trace elements and total mercury were determined in snow core samples representing the annual snowfall deposited during the 1993-94 season at two sites in the Prudhoe Bay oil field and nine sites in the Arctic National Wildlife Refuge (Arctic NWR). Results indicate there were two distinct point sources for trace elements in the Prudhoe Bay oil field- a source associated with oil and gas production and a source associated with municipal solid-waste incineration. Soluble trace element concentrations measured in snow from the Arctic NWR resembled concentrations of trace elements measured elsewhere in the Arctic using clean sample-collection and processing techniques and were consistent with deposition resulting from widespread arctic atmospheric contamination. With the exception of elements associated with sea salts, there were no orographic or east-west trends observed in the Arctic NWR data, nor were there any detectable influences from the Prudhoe Bay oil field, probably because of the predominant easterly and northeasterly winds on the North Slope of Alaska. However, regression analysis on latitude suggested significant south-to-north increases in selected trace element concentrations, many of which appear unrelated to the sea salt contribution.

Alaska↗
USGS1968

Distribution of minor elements in ore and host rock, Illinois-Kentucky fluorite district and Upper Mississippi Valley zinc-lead district

This paper presents data on the distribution of minor elements in ore and gangue minerals and in adjacent host rock from the Illinois-Kentucky fluorite district and Upper Mississippi Valley zinc-lead district. Comparisons are made of the minor-element abundances between districts and within the paragenetic sequence in individual districts.The ore of the Illinois-Kentucky fluorite district is characterized by greater abundance of minor elements than in other Mississippi Valley deposits, by large fractionation of silver between galena and sphalerite, and by a low ratio of antimony to silver in galena. Silver and antimony are concentrated in the galena and show a marked zonal pattern within the district. Sphalerite is high in cadmium, gallium, and germanium.The Upper Mississippi Valley zinc-lead district differs markedly from the Illinois-Kentucky fluorite district in minor-element concentrations and distribution. The minor elements are much less abundant, and silver is slightly more concentrated in sphalerite than in galena.Several analyses of minor elements in ore minerals from the Southeast Missouri lead district are given for comparison.It is concluded that the minor elements were largely leached from the basement by convective circulation of heated oilfield brine.

Illinois, Kentucky↗
USGS2000

Trace elements and semi-volatile organic compounds in bed sediments from streams and impoundments at Fort Gordon, Georgia

In May 1998, the U.S. Geological Survey, in cooperation with the Environmental and Natural Resources Management Office of the U.S. Army Signal Center and Fort Gordon, investigated the presence and disbursal of trace elements and semi-volatile organic compounds in bed sediments from selected streams and impoundments at the Fort Gordon military installation near Augusta, Georgia. Concentrations of 18 trace elements and total organic carbon, and 66 semi-volatile compounds were determined from analysis of the fine-grained fraction of bed-sediment samples from 29 surface-water deposition locations. Analysis of the bed-sediment data indicates that commercial and industrial land-use areas generally are associated with the highest concentrations of trace elements and semi-volatile organic compounds, and the greatest occurrence and distribution of trace elements and semi-volatile organic compounds in bed sediments at Fort Gordon. Bed sediment collected at sites having drainage areas less than 1.0 square mile and greater than 45 percent commercial and industrial land uses, have the most occurrences and the highest concentrations of trace elements and semi-volatile organic compounds. Sampling sites having less than 2 percent commercial and industrial land uses had the lowest concentrations, regardless of drainage basin size. Relative rankings and evaluation of individual trace element and semi-volatile organic compound concentration data identified two sites that have substantially higher sediment-quality scores than the other sites. This suggests that these sites have the greatest potential risk for adverse effects on aquatic life. The effects of these elevated trace element and semi-volatile organic compound concentrations on aquatic life in these basins may merit further investigation.

Georgia↗
USGS2014

The presence and distribution of polycyclic aromatic hydrocarbons and inorganic elements in water and lakebed materials and the potential for bioconcentration in biota at established sampling sites on Lake Powell, Utah and Arizona

The National Park Service is responsible for monitoring the effects of visitor use on the quality of water, lakebed material (bottom sediments), and biota, in Lake Powell, Utah and Arizona. A sampling program was begun in 2010 to assess the presence, distribution, and concentrations of organic and inorganic compounds in the water column and bottom sediment. In response to an Environmental Impact Statement regarding personal watercraft and as a continuation from previous studies by the U.S. Geological Survey and the National Park Service, Glen Canyon National Recreation Area, water samples were collected and analyzed for polycyclic aromatic hydrocarbons (PAHs) using semipermeable membrane devices and inorganic elements using a fixed-bottle sampler deployed at established monitoring sites during 2010 and 2011. Lakebed material samples were also analyzed for polycyclic aromatic hydrocarbons and inorganic elements, some of which could be harmful to aquatic biota if present at concentrations above established aquatic life criteria. Of the 44 PAH compounds analyzed, 26 individual compounds were detected above the censoring limit in the water column by semipermeable membrane devices. The highest number of compounds detected were at Lone Rock Beach, Wahweap Marina, Rainbow Bridge National Monument, and Antelope Marina which are all located in the southern part of Lake Powell where visitation and boat use is high. Because PAHs can remain near their source, the potential for bioconcentration is highest near these sites. The PAH compound found in the highest concentration was phenol (5,902 nanograms per liter), which is included in the U.S. Environmental Protection Agency’s priority pollutants list. The dissolved inorganic chemistry of water samples measured at the sampling sites in Lake Powell defined three different patterns of elements: (1) concentrations were similar between sites in the upper part of the lake near Farley Canyon downstream to Halls Crossing Marina, a distance of about 36 lake miles, (2) concentrations varied depending on the element between Halls Crossing Marina downstream to the mouth of the Escalante River, a distance of about 33 lake miles, and (3) concentrations were similar between sites from below the mouth of the Escalante River to Glen Canyon Dam, a distance of about 68 lake miles. Analysis of lakebed bottom sediment material samples detected PAH compounds at all sampling sites except at Halls Crossing Marina, Stanton Creek, and Forgotten Canyon. Twenty-four of 44 PAHs analyzed in lakebed material were detected above the reporting limit. Perylene was the most prevalent compound detected above the reporting limit in lakebed material and was detected at three sampling sites. Concentrations of perylene ranged from an estimate of 24.0 to 47.9 micrograms per kilogram (μg/kg). Fluoranthene had the highest concentration of any PAH and was detected at the Wahweap Marina with a concentration of 565 μg/kg. The highest sum of concentrations for all compounds found in lakebed material samples at one site was at the Wahweap Marina, which had concentrations five times higher than the next highest site. The three major tributaries to Lake Powell—the Colorado, Escalante, and San Juan Rivers—all showed elevated concentrations of inorganic elements in their delta sediments for most elements relative to the majority of the sediment samples taken from the lake itself. However, there were four lake sites that had concentrations for most inorganic elements that equaled or exceeded those of the tributaries. Two of these sites were at the northeast part of the lake, nearest to the Colorado River as it enters Lake Powell (Farley Canyon and Blue Notch Canyon), one was at the Escalante River below 50-Mile Canyon, and other was at Antelope Marina.

Arizona;Utah↗
USGS1980

Distribution of trace elements in bottom sediment of the northern Bering Sea

2-dimensional contour and 3-dimensional value-surface maps of semi-quantitative emission spectographic analyses for over 50 elements in surface sediment from 180 sampling stations are presented. For purposes of discussion, certain of these elements have been grouped into the following categories: petroleum indicators, heavy metals, potentially toxic elements, chemically sensitive elements, major elements, minor elements, and a group of elements of economic interest.

Alaska↗
USGS1982

Uranium and other element geochemical covariation in a granitic host rock and in the derived sediment, Deep Creek Range, Juab County, Utah

Correlation and factor analysis of geochemical data from a Tertiary biotite quartz monzonite, the Ibapah stock, and from derived sediment shows on comparison a major shift in element covariation among uranium and 24 other elements. Samples used were collected for a 1978 study in the central part of the Deep Creek Range, Juab County, Utah. Computed correlations among elements in granitic igneous rock samples suggest a high degree of covariation among elements that compose the rock. Uranium, however, shows significant correlation with only 12 elements and almost zero correlation with thorium. Computed correlations among elements in the derived sediment suggest that major decreases have occurred in covariation of the elements in the derived sands. Uranium in the sands, however, shows 15 significant correlations compared to 12 in the igneous rock samples, and shows an extremely high correlation with thorium. Factor analysis shows three geochemical petrogenic factors and the regional Be-U mineralization factor in the igneous rocks, and two mechanical segregation and one chemical precipitation factors in the sediments.

Open-File Report↗
USGS2010

Review of Trace-Element Field-Blank Data Collected for the California Groundwater Ambient Monitoring and Assessment (GAMA) Program, May 2004-January 2008

Trace-element quality-control samples (for example, source-solution blanks, field blanks, and field replicates) were collected as part of a statewide investigation of groundwater quality in California, known as the Priority Basins Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basins Project is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB) to assess and monitor the quality of groundwater resources used for drinking-water supply and to improve public knowledge of groundwater quality in California. Trace-element field blanks were collected to evaluate potential bias in the corresponding environmental data. Bias in the environmental data could result from contamination in the field during sample collection, from the groundwater coming into contact with contaminants on equipment surfaces or from other sources, or from processing, shipping, or analyzing the samples. Bias affects the interpretation of environmental data, particularly if any constituents are present solely as a result of extrinsic contamination that would have otherwise been absent from the groundwater that was sampled. Field blanks were collected, analyzed, and reviewed to identify and quantify extrinsic contamination bias. Data derived from source-solution blanks and laboratory quality-control samples also were considered in evaluating potential contamination bias. Eighty-six field-blank samples collected from May 2004 to January 2008 were analyzed for the concentrations of 25 trace elements. Results from these field blanks were used to interpret the data for the 816 samples of untreated groundwater collected over the same period. Constituents analyzed were aluminum (Al), antimony (Sb), arsenic (As), barium (Ba), beryllium (Be), boron (B), cadmium (Cd), chromium (Cr), cobalt (Co), copper (Cu), iron (Fe), lead (Pb), lithium (Li), manganese (Mn), mercury (Hg), molybdenum (Mo), nickel (Ni), selenium (Se), silver (Ag), strontium (Sr), thallium (Tl), tungsten (W), uranium (U), vanadium (V), and zinc (Zn). The detection frequency and the 90th percentile concentration at greater than 90 percent confidence were determined from the field-blank data for each trace element, and these results were compared to each constituent's long-term method detection level (LT-MDL) to determine whether a study reporting level (SRL) was necessary to ensure that no more than 10 percent of the detections in groundwater samples could be attributed solely to contamination bias. Only two of the trace elements analyzed, Li and Se, had zero detections in the 86 field blanks. Ten other trace elements (Sb, As, Be, B, Cd, Co, Mo, Ag, Tl, and U) were detected in fewer than 5 percent of the field blanks. The field-blank results for these constituents did not necessitate establishing SRLs. Of the 13 constituents that were detected in more than 5 percent of the field blanks, six (Al, Ba, Cr, Mn, Hg, and V) had field-blank results that indicated a need for SRLs that were at or below the highest laboratory reporting levels (LRL) used during the sampling period; these SRLs were needed for concentrations between the LT-MDLs and LRLs. The other seven constituents with detection frequencies above 5 percent (Cu, Fe, Pb, Ni, Sr, W, and Zn) had field-blank results that necessitated SRLs greater than the highest LRLs used during the study period. SRLs for these seven constituents, each set at the 90th percentile of their concentrations in the field blanks, were at least an order of magnitude below the regulatory thresholds established for drinking water for health or aesthetic purposes; therefore, reporting values below the SRLs as less than or equal to (=) the measured value would not prevent the identification of values greater than the drinking-water thresholds. The SRLs and drinking-water thresholds, respectively, for these 7 trace elements are Cu (1.7 ?g/L and 1,300

Scientific Investigations Report↗
USGS2011

Rare earth elements: end use and recyclability

Rare earth elements are used in mature markets (such as catalysts, glassmaking, lighting, and metallurgy), which account for 59 percent of the total worldwide consumption of rare earth elements, and in newer, high-growth markets (such as battery alloys, ceramics, and permanent magnets), which account for 41 percent of the total worldwide consumption of rare earth elements. In mature market segments, lanthanum and cerium constitute about 80 percent of rare earth elements used, and in new market segments, dysprosium, neodymium, and praseodymium account for about 85 percent of rare earth elements used. Regardless of the end use, rare earth elements are not recycled in large quantities, but could be if recycling became mandated or very high prices of rare earth elements made recycling feasible.

Scientific Investigations Report↗
USGS2002

Trace elements and organic compounds in bed sediment from selected streams in southern Louisiana, 1998

Bed-sediment samples from 21 selected streams in southern Louisiana were collected and analyzed for the presence of trace elements and organic compounds during 1998 as part of the U.S. Geological Survey National Water-Quality Assessment Program. Concentrations of selected trace elements and organic compounds were compared on the basis of sediment-quality criteria, land use, and grain size; concentrations of selected trace elements also were compared with concentrations from previous studies. Concentrations of seven selected trace elements and 21 organic compounds were evaluated with sediment-quality criteria established by the Canadian Council of Ministers of the Environment. Concentrations of selected trace elements and organic compounds were highest at sites draining urban and agricultural areas and may result from cumulative effects of relatively high percentages of fine-grained material, iron, and organic material. Concentrations exceeding sediment-quality criteria for the protection of aquatic life occurred most frequently at Bayou Grosse Tete at Rosedale and Bayou Lafourche below weir at Thibodaux. Exceedance of Interim Sediment Quality Guidelines occurred most frequently for arsenic and chromium. Trace-element concentrations in fine-grained samples were compared with concentrations in bulk samples and were determined to be significantly different, and concentrations were generally higher in finegrained sediment. Shapiro-Wilk, paired t-test, and Wilcoxon rank sum statistical procedures, with an alpha of 0.05, were used to compare concentrations of 21 trace elements, total organic carbon, and total carbon in finegrained and bulk sediment samples for 19 sites. Significant differences were determined between fine-grained and bulk sediment samples for aluminum, barium, beryllium, chromium, copper, iron, lithium, nickel, phosphorus, selenium, titanium, and zinc concentrations. Of 133 paired concentrations, 69 percent were greater in fine-grained samples, and 23 percent were greater in bulk samples. Comparisons with data from previous studies indicate increases by more than 20 percent in concentrations of antimony at Bayou Lafourche below weir at Thibodaux, arsenic and chromium at Tickfaw River at Liverpool, lead at Bayou Lafourche below weir at Thibodaux, and zinc at Bayou Lafourche below weir at Thibodaux and Vermilion River at Perry. Historic comparisons also indicate decreases by more than 20 percent in concentrations of chromium at Bayou des Cannes near Eunice and mercury at Mermentau River at Mermentau.

Water-Resources Investigations Report↗
USGS1993

Element concentrations in growth rings of trees near an abandoned wood-preserving plant site at Jackson, Tennessee

Multielement analysis was performed on individual annual rings of trees growing at and near an abandoned wood-preserving plant site in Jackson, Tennessee, that operated from the early 1930's until 1981. Numerous organic compounds associated with the wood-preserving process have been detected in soils, ground water, and surface water within much of the site. Tree-ring investigations were conducted prior to investigations of ground water downgradient from the site to determine if trees preserved an areal and temporal record of contaminant movement into offsite areas. Increment cores were collected from trees on the abandoned plant site, in downgradient areas west and south of the site, and at two locations presumably unaffected by contamination from the site. Multielement analysis by proton-induced X-ray emission was performed on 5 to 15 individual growth rings from each of 34 trees that ranged in age from about 5 to 50 years. Concentrations of 16 elements were evaluated by analyzing average concentrations within the 1987, 1989, and 1990 rings of all trees; analyzing element-concentration trends along entire core radii; and analyzing element correlations between and among trees. Concentrations of some nutrients and trace metals were elevated in the outermost sapwood rings of some trees that grow south and southwest of the most contaminated part of the site; small trees on the main part of the site and larger trees to the west generally contained fewer rings with elevated concentrations, particularly of trace metals. Concentrations of several elements elevated in tree rings also were elevated in water samples collected from the reach of a stream that flows near the southwestern part of the site. Multielement analysis of each ring of a willow growing along the southern boundary of the site detected extremely large concentrations of chromium, nickel, and iron in rings that formed in 1986 and thereafter. Relative increases in the concentrations of these elements also were detected in a silver maple growing next to the willow, but not in another silver maple growing 150 meters farther to the west. An oak growing in the southwestern part of the study area contained large concentrations of calcium and several trace elements, and some trees south of the abandoned site contained large concentrations of phosphorus or potassium. Concentrations of trace metals and nutrients in some trees may be related to wood-preserving activities at the site and possibly to remedial efforts conducted during the early to mid 1980's.However, the possibility cannot be discounted that large concentrations of some elements are from sources other than the wood-preserving facility, or in part from flooding of the South Fork Forked Deer River.

Water-Resources Investigations Report↗
USGS1997

Water-quality assessment of the Rio Grande Valley, Colorado, New Mexico and Texas: Organic compounds and trace elements in bed sediment and fish tissue, 1992-93

The occurrence and distribution of contaminants in aquatic systems are major components of the National Water-Quality Assessment (NAWQA) Program. Bed-sediment samples were collected at 18 sites in the Rio Grande Valley study unit between September 1992 and March 1993 to characterize the geographic distribution of organic compounds, including chlorinated insecticides, polychlorinated biphenyls (PCB's), and other chlorinated hydrocarbons, and also trace elements. Two-millimeter-size- fraction sediment was analyzed for organic compounds and less than 63-micron-size-fraction sediment was analyzed for trace elements. Concentrations of p,p'-DDE were detected in 33 percent of the bed-sediment samples. With the exception of DDT-related compounds, no other organochlorine insecticides or polychlorinated biphenyls were detected in samples of bed sediment. Whole-body fish samples were collected at 11 of the bed- sediment sites and analyzed for organic compounds. Organic compounds were reported more frequently in samples of fish, and more types of organic compounds were found in whole-body fish samples than in bed-sediment samples. Concentrations of p,p'-DDE were detected in 91 percent of whole-body fish samples. Polychlorinated biphenyls, cis-chlordane, trans-chlordane, trans- nonachlor, and hexachlorobenzene were other organic compounds detected in whole-body samples of fish from at least one site. Because of the extent of mineralized areas in the Rio Grande Basin arsenic, cadmium, copper, lead, mercury, selenium, and zinc concentrations in bed-sediment samples could represent natural conditions at most sites. However, a combination of natural conditions and human activities appears to be associated with elevated trace-element concentrations in the bed-sediment sample from the site Rio Grande near Creede, Colorado, because this sample exceeded the background trace-element concentrations calculated for this study. Fish-liver samples were collected at 12 of the bed-sediment sites and analyzed for trace elements. Certain trace elements were detected at higher concentrations in fish-liver samples than in bed-sediment samples from the same site. Both bed-sediment and fish-tissue samples are necessary for a complete environmental assessment of the occurrence and distribution of trace elements.

Colorado, New Mexico, Texas↗
USGS2022

Geochemical studies of the Green River Formation in the Piceance Basin, Colorado: I. Major, minor, and trace elements

The Eocene Green River Formation contains the largest oil shale deposits in the world and is a welldocumented example of a lacustrine depositional system. In addition, mineral resources associated with oil shale in the Piceance Basin nahcolite [NaHCO3] and dawsonite [NaAl(CO3)(OH)2)] are of current and potential economic value, respectively. Detailed geochemical analysis across the basin can aid in the understanding of the depositional environment, sedimentary processes, and water-chemistry evolution in this system. Quantitative geochemical data for Green River oil shale from the Piceance Basin of Colorado were collected by inductively coupled plasma optical emission spectroscopy and mass spectrometry as part of this study. The basin margin is represented by samples from exposures at Douglas Pass (Garfield County) and the basin center area is characterized by core samples from two drilled wells: the Shell 23X-2 and John Savage 24-1 (Rio Blanco County). Major elements and groups of elements are used as proxies for clastic influx (Si, Al, K, Ti), carbonate deposition (Ca, Mg), salinity (Na), paleo-productivity (P), and redox state (Fe, S), respectively. Minor and trace elements reinforce observations based on major elements, including Rb, Zr, Nb for clastic influx and Mn, Sr for carbonate. Trace elements are used to characterize redox conditions (As, Mo, U, V, Co, Ni, Cu, Zn) and salinity (Rb/K, B/Ga). Chemical distinctions between the basin margin and the basin center, in terms of these components and total organic carbon concentrations, support the model of a permanently stratified lake through most of the depositional interval. A primary purpose of the study was to conduct more extensive sampling to confirm conclusions of a previous reconnaissance study. Geochemical data from this study indicates elevated Na around the basin margin occurring earlier than in the deeper basin. Early in the history of Lake Uinta, the salinity may have been elevated first in the shallower marginal waters, due to increased evaporation, which then led to elevated salinity in the basin center through transport of saline density currents. Other indicators of salinity (Rb/K, B/Ga) do not track Na content in intervals where clay minerals are absent due to diagenetic alteration under hypersaline conditions but may be used to indicate the salinities at which authigenic Na-bearing minerals begin to form. Most Na-rich samples show high proportions of clastic constituents (Si, Al, K, Ti) compared to conventional carbonate constituents (Ca, Mg). Redox-sensitive period IV transition metal elements (V, Co, Ni, Cu, Zn) show only local occurrence of significant enrichment relative to average shale abundances. Analysis of Fe/Al ratios for this dataset suggests that the depletion of these elements may be related to source rocks depleted in mafic constituents, with apparent redox-related enrichments subdued by this effect. The basin margin samples reflect generally oxic bottom waters, with some intervals deposited under more reducing, possibly dysoxic to anoxic conditions. The basin center results indicate more reducing conditions, with Mo and U enrichment factors suggesting operation of a particulate shuttle mechanism that scavenged Mo on Fe/Mn-oxyhydroxides that redissolved at depth, with Mo precipitating along with sulfides and/or organic matter at or near the sediment/water interface.

Colorado↗
USGS2006

Effect of mining and related activities on the sediment trace element geochemistry of Lake Coeur D'Alene, Idaho, USA. Part I: Surface sediments

During the summer of 1989 surface sediment samples were collected in Lake Coeur d'Alene, the Coeur d'Alene River and the St Joe River, Idaho, at a density of approximately one sample per square kilometre. Additional samples were collected from the banks of the South Fork of the Coeur d'Alene and the Coeur d'Alene Rivers in 1991. All the samples were collected to determine trace element concentrations, partitioning and distribution patterns, and to relate them to mining, mining related and discharge operations that have occurred in the Coeur d'Alene district since the 1880s, some of which are ongoing. Most of the surface sediments in Lake Coeur d'Alene north of Conkling Point and Carey Bay are substantially enriched in Ag, As, Cu, Cd, Hg, Pb, Sb and Zn relative to unaffected sediments in the southern portion of the lake near the St Joe River. All the trace element enriched sediments are extremely fine grained (mean grain sizes « 63 μm). Most of the enriched trace elements, based on both the chemical analyses of separated heavy and light mineral fractions and a two step sequential extraction procedure, are associated with an operationally defined Fe oxide phase; much smaller percentages are associated either with operationally defined organics/sulphides or refractory phases. The presence, concentration and distribution of the Fe oxides and heavy minerals indicates that a substantial portion of the enriched trace elements are probably coming from the Coeur d'Alene River, which is serving as a point source. Within the lake, this relatively simple point source pattern is complicated by a combination of (1) the formation of trace element rich authigenic Fe oxides that appear to have reprecipitated from material solubilized from anoxic bed sediments and (2) physical remobilization by currents and wind driven waves. The processes that have caused the trace element enrichment in the surface sediments of Lake Coeur d'Alene are likely to continue for the foreseeable future.

Idaho↗
USGS2011

Selected trace elements in the Sacramento River, California: Occurrence and distribution

The impact of trace elements from the Iron Mountain Superfund site on the Sacramento River and selected tributaries is examined. The concentration and distribution of many trace elements—including aluminum, arsenic, boron, barium, beryllium, bismuth, cadmium, cerium, cobalt, chromium, cesium, copper, dysprosium, erbium, europium, iron, gadolinium, holmium, potassium, lanthanum, lithium, lutetium, manganese, molybdenum, neodymium, nickel, lead, praseodymium, rubidium, rhenium, antimony, selenium, samarium, strontium, terbium, thallium, thulium, uranium, vanadium, tungsten, yttrium, ytterbium, zinc, and zirconium—were measured using a combination of inductively coupled plasma-mass spectrometry and inductively coupled plasma-atomic emission spectrometry. Samples were collected using ultraclean techniques at selected sites in tributaries and the Sacramento River from below Shasta Dam to Freeport, California, at six separate time periods from mid-1996 to mid-1997. Trace-element concentrations in dissolved (ultrafiltered [0.005-μm pore size]) and colloidal material, isolated at each site from large volume samples, are reported. For example, dissolved Zn ranged from 900 μg/L at Spring Creek (Iron Mountain acid mine drainage into Keswick Reservoir) to 0.65 μg/L at the Freeport site on the Sacramento River. Zn associated with colloidal material ranged from 4.3 μg/L (colloid-equivalent concentration) in Spring Creek to 21.8 μg/L at the Colusa site on the Sacramento River. Virtually all of the trace elements exist in Spring Creek in the dissolved form. On entering Keswick Reservoir, the metals are at least partially converted by precipitation or adsorption to the particulate phase. Despite this observation, few of the elements are removed by settling; instead the majority is transported, associated with colloids, downriver, at least to the Bend Bridge site, which is 67 km from Keswick Dam. Most trace elements are strongly associated with the colloid phase going downriver under both low- and high-flow conditions.

Archives of Environmental Contamination and Toxico↗
USGS2021

Chemical connectivity and multi-element composition of groundwater in depressional wetlands

Little is known about the element composition of groundwater along flow paths between wetlands. What is known is based on a few major elements, such as Na and Ca. We examined the spatial and temporal variation of elements in a depressional-wetland, groundwater-flow system in the Prairie Pothole Region of North Dakota, USA. Wetlands of the region are characterized by their occurrence in hydrologically connected complexes, where those at higher elevations in the groundwater flow system often recharge groundwater (recharge wetlands), while those at lower elevations receive groundwater (discharge wetlands). The aim of our study was to get a better understanding of factors affecting the distribution of more than 30 elements in groundwater along a flow path between recharge and discharge wetlands. We found that oxidation-reduction potential (ORP) decreased as electrical conductivity (EC) increased along the flow path. As EC increased, so did the concentrations of major ions, such as Na, Ca, and Mg. That was already well known. Less known, however, was that concentrations of Cs, Sn, U and Zr increased along the flow path as well. Not reported before was that concentrations of Sn increased strongly as ORP decreased. The concentrations of most elements in groundwater increased with lower relative elevation in the groundwater flow system, but notable exceptions were Ba and Zn, which both showed opposite patterns. Our results contribute to a better understanding of element cycling in groundwater between wetlands, which in turn is important for our understanding of resultant influences on associated biogeochemistry and ecosystem services.

North Dakota↗
USGS1982

The mobility of uranium and other elements during alteration of rhyolite ash to montmorillonite: A case study in the Troublesome Formation, Colorado, U.S.A.

An unusual occurrence of juxtaposed glassy and clay-altered ash was sampled to estimate the degree and type of element mobility during alteration of glass to montmorillonite. The results are particularly interesting in that major mobilization of uranium is indicated. Closely spaced samples of glassy and montmorillonitic ash were collected from the same 20-50 cm thick stratigraphic horizon in the Troublesome Formation (Miocene) of northwestern Colorado. Sharp contacts exist between glassy ash and underlying pink montmorillonite and indicate that water-saturated conditions were restricted to basal ash layers. Formation of montmorillonite instead of zeolites suggests that the water was not highly saline or alkaline. Isotopic and chemical analyses of glassy and clay-altered samples indicate the following: 1. (1) Montmorillonite has U concentrations which are only 10-15% of the concentrations in coexisting glass. Similarly depleted elements include Cs, Rb, Na and K. Much smaller depletions of these elements in some glassy samples serve as sensitive indicators of incipient alteration of glass to montmorillonite. 2. (2) Abundances of relatively insoluble elements such as Th, Ta, Hf and Al are slightly higher (5-50%) in clay-altered ash and serve as indicators of the maximum levels of enrichment in residual material. Greater enrichment of elements such as Ca, Mg, Sr, Sc, P, Cr and Co indicate structural incorporation, adsorption, or ion-exchange uptake by clay or secondary hydrous oxides of Fe and Mn. 3. (3) The rare-earth-element patterns and abundances in glass are sufficiently mimicked by detritus-free montmorillonite to document the compositional equivalency of the two. 4. (4) Radioactive equilibrium exists between 238U and its decay products 234U and 230Th. This documents minimal open-system mobility of U within the last ??? 0.3 Ma. ?? 1982.

Chemical Geology↗
USGS1984

The group separation of the rare-earth elements and yttrium from geologic materials by cation-exchange chromatography

Demand is increasing for the determination of the rare-earth elements (REE) and yttrium in geologic materials. Due to their low natural abundance in many materials and the interferences that occur in many methods of determination, a separation procedure utilizing gradient strong-acid cation-exchange chromatography is often used to preconcentrate and isolate these elements from the host-rock matrix. Two separate gradient strong-acid cation-exchange procedures were characterized and the major elements as well as those elements thought to provide the greatest interference for the determination of the REE in geologic materials were tested for separation from the REE. Simultaneous inductively coupled argon plasma-atomic emission spectroscopy (ICAP-AES) measurements were used to construct the chromatograms for the elution studies, allowing the elution patterns of all the elements of interest to be determined in a single fraction of eluent. As a rock matrix, U.S. Geological Survey standard reference BCR-1 basalt was digested using both an acid decomposition procedure and a lithium metaborate fusion. Hydrochloric and nitric acids were tested as eluents and chromatograms were plotted using the ICAP-AES data; and we observed substantial differences in the elution patterns of the REE and as well as in the solution patterns of Ba, Ca, Fe and Sr. The nitric acid elution required substantially less eluent to elute the REE and Y as a group when compared to the hydrochloric acid elution, and provided a clearer separation of the REE from interfering and matrix elements. ?? 1984.

Chemical Geology↗