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USGS1996

Characterizing coal beds in western Kentucky with the Al-La-Sc coherent triad

Cyclic sedimentation and lateral facies changes make coal bed correlations inconclusive and difficult. This uncertainty can be further complicated if a coal basin has been structurally deformed. Coal macerals can be studied to indicate the nature and degree of coalification. Their use in coal bed correlation, however, is limited. Most of the trace elements and their ratios that have been studied show significant within-bed lateral and stratigraphic variations, and thus are not effective in correlating coal beds regionally. Geochemically coherent groups of elements, such as rare earth elements (REE) and platinum group elements (PGE), appear to be highly differentiated in coal-forming environments. Geochemical coherent elemental triads appear to be useful for coal bed identification or fingerprinting. The best triad which was demonstrated to be effective in coal bed characterization in western Kentucky, is that of Al, La and Sc. These three elements are highly correlated with one another and they can be determined accurately and simultaneously with instrumental neutron activation analysis (INAA). The elemental triad Al-La-Sc is used to identify and fingerprint three key coal beds in western Kentucky: the Springfield (western Kentucky No. 9), the Davis (western Kentucky No. 6), and the Mining City and Dawson Springs are both considered to be the No. 4 coal bed in western Kentucky). Four distinct groupings can be recognized by use of the Al-La-Sc triad. The Dawson Springs coals have the highest Al/(La + Sc) ratios, followed by the Springfield, the Davis and the Mining City. The Mining City coal bed generally has the highest La/Sc ratio. However, the Dawson Springs is not correlated with the Mining City using the triad analysis, even though they have reportedly similar stratigraphic positions in the western Kentucky coal basin. The Al-La-Sc triad appears to be effective in discriminating between the Springfield and the Davis coal beds throughout the entire Illinois Basin. Furthermore, the range of concentration variation of the AL-La-Sc triad suggests individual groupings of the No. 4 coal in western Kentucky. In addition to characterizing these coal beds, the Al-La-Sc triad may be used to confirm stratigraphic correlations.

International Journal of Coal Geology↗

USGS2014

Sequence stratigraphy of the Upper Cambrian (Furongian; Jiangshanian and Sunwaptan) Tunnel City Group, Upper Mississippi Valley: Transgressing assumptions of cratonic flooding

New data from detailed measured sections permit comprehensive analysis of the sequence framework of the Furongian (Upper Cambrian; Jiangshanian and Sunwaptan stages) Tunnel City Group (Lone Rock Formation and Mazomanie Formation) of Wisconsin and Minnesota. The sequence-stratigraphic architecture of the lower part of the Sunwaptan Stage at the base of the Tunnel City Group, at the contact between the Wonewoc Formation and Lone Rock Formation, records the first part of complex polyphase flooding (Sauk III) of the Laurentian craton, at a scale smaller than most events recorded by global sea-level curves. Flat-pebble conglomerate and glauconite document transgressive ravinement and development of a condensed section when creation of accommodation exceeded its consumption by sedimentation. Thinly-bedded, fossiliferous sandstone represents the most distal setting during earliest highstand. Subsequent deposition of sandstone characterized by hummocky or trough cross-stratification records progradational pulses of shallower, storm- and wave-dominated environments across the craton before final flooding of Sauk III commenced with carbonate deposition during the middle part of the Sunwaptan Stage. Comparison of early Sunwaptan flooding of the inner Laurentian craton to published interpretations from other parts of North America suggests that Sauk III was not a single, long-term accommodation event as previously proposed.

Minnesota;Wisconsin↗

USGS2015

In-reservoir behavior, dam passage, and downstream migration of juvenile Chinook salmon and juvenile steelhead from Detroit Reservoir and Dam to Portland, Oregon, February 2013-February 2014

In the second year of 2 years of study, the movements of juvenile spring Chinook salmon ( Oncorhynchus tshawytscha ) and juvenile summer steelhead ( Oncorhynchus mykiss ) through Detroit Reservoir, passing Detroit Dam, and migrating downstream to Portland, Oregon, were studied during a 1-year-long period beginning in February 2013. The primary purpose of the study was to provide empirical data to inform decisions about future alternatives for improving downstream passage of salmonids at Detroit Dam. A secondary purpose was to design and assess the performance of a system to detect juvenile salmonids implanted with acoustic transmitters migrating in the Willamette River. Inferences about fish migration were made from detections of juvenile fish of hatchery origin at least 95 millimeters in fork length surgically implanted with an acoustic transmitter and released during the spring (March–May) and fall (September–November) of 2013. Detection sites were placed throughout the reservoir, near the dam, and at two sites in the North Santiam River and at three sites in the Willamette River culminating at Portland, Oregon. We based most inferences on an analysis period up to the 90th percentile of tag life (68–78 days after release, depending on species and season), although a small number of fish passed after that period as late as April 8, 2014. Chinook salmon migrated from the tributaries of release to the reservoir in greater proportion than steelhead, particularly in the fall. The in-reservoir migration behaviors and dam passage of the two species were similar during the spring study, but during the fall study, few steelhead reached the reservoir and none passed the dam within the analysis period. Migrations in the reservoir were directed and non-random, except in the forebay. Depths of fish within 25 meters of the dam were deeper in the day than at night for Chinook salmon and similar in the day and night for steelhead; steelhead generally were at shallower depths than Chinook salmon. The primary factors affecting dam passage rates were seasonal dam operating conditions and diel period. Fish passage rates were much greater during the spring and summer than in the fall and winter, and the difference was attributed to the availability and use of the spillway near the top of the dam during the spring and summer. The flood-control purpose of the reservoir prevented spillway use during much of the fall and winter because of the low forebay elevation. Passage rates at night were greater than in the day during spring and summer (4.2 times) and during the fall and winter (14.9 times). Fish length, dam discharge, and forebay elevation also affected dam passage rates. Travel times from Detroit Dam passage to the downstream sites were shorter during the fall and winter than during the spring and summer, and were less than a median of 8.68 days to Portland. The estimated survival in the 11 kilometers (km) between Detroit Dam and the Minto Dam forebay was lower than in the remaining 241 km to the Portland site. Estimated survival per 100 km in the free-flowing reach from Minto Dam to Portland was 0.675–0.836, depending on species and season, and was similar to other free-flowing rivers in the Western United States. The high probability of fish in the reservoir reaching the dam, the chance for repeated presence near the dam, the fish depths, and the factors known to affect passage rates suggest that a properly designed surface passage route could be a viable downstream passage alternative for juvenile Chinook salmon and steelhead at Detroit Dam. As part of the evaluations conducted at Detroit Dam, we continued to refine and improve methods for monitoring fish movements in the Willamette River. The goal was to develop stable, cost-effective, long-term monitoring arrays suitable for detection of any Juvenile Salmon Acoustic Telemetry System (JSATS)-tagged fish in the Willamette River. These data then could be used to estimate timing, migration rates, and survival of JSATS-tagged fish from various studies in the Willamette River Basin. The challenge, however, is that acoustic telemetry generally performs poorly in shallow, turbulent water, like that found in the Willamette River. We successfully designed, deployed, and maintained a series of monitoring sites near the Oregon cities of Salem, Wilsonville, and Portland. In the spring, detection probabilities at these sites ranged from 0.900 to 1.000. In the fall, the detection probabilities decreased and ranged from 0.526 to 1.000. The lower detection probabilities, particularly at the Salem site (0.526), were owing to loss of data caused by abnormally high flows as well as the 2013 Federal government shutdown, which prevented us from servicing the equipment. The monitoring sites that we installed seem to be robust and enable the efficient use of acoustic-tagged fish for studies of migration or survival in the Willamette River and similar environments.

Oregon↗

USGS1966

Geologic effects of the March 1964 earthquake and associated seismic sea waves on Kodiak and nearby islands, Alaska

Kodiak Island and the nearby islands constitute a mountainous landmass with an aggregate area of 4,900 square miles that lies at the western border of the Gulf of Alaska and from 20 to 40 miles off the Alaskan mainland. Igneous and metamorphic rocks underlie most of the area except for a narrow belt of moderately to poorly indurated rocks bordering the Gulf of Alaska coast and local accumulations of unconsolidated alluvial and marine deposits along the streams and coast. The area is relatively undeveloped and is sparsely inhabited. About 4,800 of the 5,700 permanent residents in the area live in the city of Kodiak or at the Kodiak Naval Station. The great earthquake, which occurred on March 27, 1964, at 5:36 p.m. Alaska standard time (March 28,1964, 0336 Greenwich mean time), and had a Richter magnitude of 8.4-8.5, was the most severe earthquake felt on Kodiak Island and its nearby islands in modern times. Although the epicenter lies in Prince William Sound 250 miles northeast of Kodiak—the principal city of the area—the areal distribution of the thousands of aftershocks that followed it, the local tectonic deformation, and the estimated source area of the subsequent seismic sea wave, all suggest that the Kodiak group of islands lay immediately adjacent to, and northwest of, the focal region from which the elastic seismic energy was radiated. The duration of strong ground motion in the area was estimated at 2½ minutes. Locally, the tremors were preceded by sounds audible to the human ear and were reportedly accompanied in several places by visible ground waves. Intensity and felt duration of the shocks during the main earthquake and aftershock sequence varied markedly within the area and were strongly influenced by the local geologic environment. Estimated Mercalli intensities in most areas underlain by unconsolidated Quaternary deposits ranged from VIII to as high as IX. In contrast, intensities in areas of upper Tertiary rock ranged from VII to VIII, and in areas of relatively well indurated lower Tertiary and Mesozoic rocks, from VI to VII. Local subsidence of as much as 10 feet was widespread in noncohesive granular deposits through compaction, flow, and sliding that resulted from vibratory loading during the earthquake. This phenomenon, which was largely restricted to saturated beach and alluvial deposits or artificial fill, was locally accompanied by extensive cracking of the ground and attendant ejection of water and water-sediment mixtures. Numerous landslides, including a wide variety of rockfalls, rockslides, and flows along steep slopes, were triggered by the long-duration horizontal and vertical accelerations during the earthquake. The landslides are most numerous in a narrow belt along the southeast coast of Kodiak Island and the nearby offshore islands. Their abundance appears to be related to an area underlain predominantly by Tertiary rocks. Temporary and permanent changes of level occurred after the earthquake in some wells, lakes, and streams throughout the area; ice was cracked, and the salinity of a few wells increased. Permanent change of water level at some localities appears to be related to readjustments of fracture porosity by earthquake-induced movements of bedrock blocks. Increased salinity of wells in coastal areas resulted from encroachment of seawater into aquifiers after subsidence during the earthquake, and to flooding of watersheds by seismic sea waves. Vertical displacements, both downward and upward, occurred throughout the area as a result of crustal warping along a northeast-trending axis. Most of Kodiak and all of Afognak, Shuyak, and adjacent islands are within a regional zone of subsidence whose trough plunges gently northeastward and approximately coincides with the mountainous backbone of Kodiak Island. Subsidence in excess of 6 feet occurred throughout the northern part of the zone-a maximum subsidence of 6½ feet having occurred on Marmot and, eastern Afognak Islands. Southeast of the axis of tectonic tilting, uplift of at least 2lh feet occurred in a narrow zone that includes most of the southeasterly capes of Kodiak Island, the southeastern half of Sitkalidak Island, and Sitkinak Island. The uplift is inferred to extend offshore over much or all of the continental shelf adjacent to the Kodiak group of islands. Within the affected area, tectonic subsidence, which was locally augmented by surficial subsidence of unconsolidated. deposits, caused widespread inundation of shorelines and attendant damage to intertidal organisms, nearshore terrestrial vegetation, and salmon-spawning areas. The most devastating effect of the earthquake on Kodiak Island and nearby islands resulted from seismic sea waves that probably originated along a linear zone of differential uplift in the Gulf of Alaska. A train of at least seven seismic sea waves, having initial periods of 50–55 minutes, struck along all the southeast coast of the island group from 38 to 63 minutes after the earthquake. The southeast shores were repeatedly washed by destructive waves having runup heights along exposed coasts of perhaps as much as 40 feet above existing tide level, and of 8–20 feet along protected shores. Runup heights of the waves were much less on the northwest and southwest sides of the islands, and no wave damage was incurred there. Locally, high-velocity currents that accompanied the waves caused intense erosion and redistribution of unconsolidated natural and artificial shore deposits and of shallow sea-floor deposits. The Alaska earthquake was the greatest natural catastrophe to befall the Kodiak Island area in historic time. The combination of seismic shock and the earthquake-related tectonic deformation and seismic sea waves took 18 lives, destroyed property worth about $45 million, and resulted in estimated losses of income to the fishing industry of an additional $5 million. Most of the damage and all of the loss of life were directly attributable to the seismic sea waves that crippled the city of Kodiak, wiped out the village of Kaguyak, and destroyed most of the village of Old Harbor and parts of the villages of Afognak and Uzinki. Bridges and segments of the highways in the vicinity of the city of Kodiak were washed out, and parts of the Kodiak Naval Station were inundated and damaged. Especially serious to all the damaged communities was the loss of fishing boats, seafood processing plants, and other waterfront installations, which had been the mainstay of the economy. Additional heavy losses resulted from the combined regional tectonic and local surficial subsidence that occurred during the earthquake. Widespread shoreline flooding by high tides necessitated raising, protecting, or removing many installations otherwise undamaged by the earthquake or waves. Structural damage attributable to seismic shock during the earthquake was relatively light and was restricted to areas underlain by saturated unconsolidated deposits. The chief structural failure in the area as a result of shaking was the collapse of part of a cannery built on saturated beach deposits that were partially liquefied during the earthquake. Minor structural damage resulted from differential settlement and cracking of the ground on natural granular deposits and artificial fills. The overwhelming majority of structures are constructed on indurated bedrock; none of these sustained damage other than small losses resulting from shifting about and breakage of their contents.

Alaska↗

USGS2025

Hot stops, cool looks: Aesthetic solutions for thermal comfort at transit stops

Increased urban heat intensifies thermal discomfort, particularly in critical public spaces such as transit stops. This study investigated the predictors of transit users' thermal perceptions in Denver, Colorado—a semi-arid city. Sixty bus stops spanning a gradient of land cover compositions were selected for study. Micrometeorological data, including thermal comfort indices, were collected alongside survey responses from 77 users at 31 unique stops. Survey responses captured thermal sensation votes (TSV) and thermal comfort votes (TCV) as well as aesthetic preference votes (APV) of bus stop structure. Ordinal forest analysis revealed that for both TSV and TCV, aesthetic preferences and thermal comfort indices were the most influential predictors of transit user thermal perception. Multiple ordered logistic regression further demonstrated that, for TSV, higher APV was associated with lower odds of rating a thermal environment as hot (OR = 0.664, p < 0.002) while increased Physiological Equivalent Temperature (PET) raised these odds (OR = 1.101, p < 0.006). An interaction analysis demonstrated that APV significantly moderated the effect of PET on TCV (interaction OR = 1.040, p < 0.041), suggesting that aesthetic preferences are significantly correlated with an alleviation of thermal discomfort under high heat stress. Bivariate analyses further indicated that bus stops with greater tree canopy cover (OR = 1.032, p < 0.025) and higher visible vegetation view factors (OR = 10.350, p < 0.022) were more likely to be rated as aesthetically pleasing. These findings underscore the importance of aesthetic preferences in transit stop planning for urban heat resiliency.

Colorado↗

USGS2026

Compounding of 100-year coastal floods by rainfall in an urban environment

Coastal and pluvial flooding are both becoming more prevalent and severe due to climate change and urbanization in floodplains. The co-occurrence of these flood drivers is generally assumed to exacerbate the resulting flood impacts, a result referred to as compound flooding. However, few observational or modeling studies have investigated the circumstances under which this occurs. Here, we study the impacts of these combined flood drivers and evaluate the implicit hypothesis of official flood maps, which is that rainfall has a negligible impact on the flood depth and flooded area due to a 100 year coastal flood. A coastal system model, configured to capture coastal and pluvial flood drivers, is used. We evaluate the flooding for different urban landform types, including coastal landfill (human-made land), convergent areas (topographic depressions) and other urban terrain, within a model domain covering the Jamaica Bay watershed of New York City. A scenario-based strategy is adopted with a 100 year coastal flood as a control simulation, to which we add a set of realistic scenarios of rainfall data from historical tropical cyclones. We also apply a joint probability analysis framework with historical data to evaluate the probability of these compound coastal-pluvial scenarios. Results reveal cases where the pluvial driver compounds the coastal flood through expansion of the flood zone, with a 17% chance of rainfall increasing the flood area by 6%–38%, and a 5% chance of an increase of 61%–73%. It is rare that floods are significantly deepened but when deepening occurs, it is more common for the convergent zone than for the coastal landfill. These findings quantitatively assess the potential of the pluvial driver to exacerbate flooding, which may influence emergency management strategies such as evacuation plans, shelter arrangements, and related preparedness measures.

New York↗

USGS2000

Geochemical investigations by the U.S. Geological Survey on uranium mining, milling, and environmental restoration

Recent research by the U.S. Geological Survey has characterized contaminant sources and identified important geochemical processes that influence transport of radionuclides from uranium mining and milling wastes. 1) Selective extraction studies indicated that alkaline earth sulfates and hydrous ferric oxides are important hosts of 226 Ra in uranium mill tailings. The action of sulfate-reducing and ironreducing bacteria on these phases was shown to enhance release of radium, and this adverse result may temper decisions to dispose of uranium mill tailings in anaerobic environments. 2) Field studies have shown that although surface-applied sewage sludge/wood chip amendments aid in revegetating pyritic spoil, the nitrogen in sludge leachate can enhance pyrite oxidation, acidification of groundwater, and the consequent mobilization of metals and radionuclides. 3) In a U.S. Environmental Protection Agencyfunded study, three permeable reactive barriers consisting of phosphate-rich material, zero-valent iron, or amorphous ferric oxyhydroxide have been installed at an abandoned uranium upgrader facility near Fry Canyon, UT. Preliminary results indicate that each of the permeable reactive barriers is removing the majority of the uranium from the groundwater. 4) Studies on the geochemistry of rare earth elements as analogues for actinides such as uranium and thorium in acid mine drainage environments indicate high mobility under acid-weathering conditions but measurable attenuation associated with iron and aluminum colloid formation. Mass balances from field and laboratory studies are being used to quantify the amount of attenuation. 5) A field study in Colorado demonstrated the use of 234 U/ 238 U isotopic ratio measurements to evaluate contamination of shallow groundwater with uranium mill effluent.

Utah↗

USGS2022

National strategy for landslide loss reduction

Executive Summary Landslide hazards are present in all 50 States and most U.S. territories, and they affect lives, property, infrastructure, and the environment. Landslides are the downslope movement of earth materials under the force of gravity. They can occur without any obvious trigger. Widespread or severe landslide events are often driven by such hazards as hurricanes, earthquakes, volcanic eruptions, heavy rain events, flooding, and wildfires. Landslides can also cause their own cascading consequences, such as the spread of hazardous materials or the creation of devastating local tsunamis. This strategy document describes goals and strategic actions of a comprehensive strategy to meet key challenges to reducing the Nation’s risk from landslide hazards equitably and effectively. The document follows the direction of the National Landslide Preparedness Act (Public Law 116–323) by presenting a strategy for addressing landslide hazards, including risk reduction and response. The act directs the Department of the Interior to establish a program that will work with State, Tribal, and local governments as well as with academia, the private sector, community-based groups, and nonprofit organizations to identify landslide hazards and risk and improve communication, coordination, and emergency preparedness, with the objective of reducing landslide losses. As the only Federal program dedicated to landslide hazard science, the U.S. Geological Survey’s Landslide Hazards Program will lead and coordinate many of the efforts described in this strategy document. Landslide hazard risk reduction must be undertaken collectively and collaboratively across the Federal Government. This strategy document will provide a framework for the creation of an interagency management plan that describes the programs, projects, workforce, and budgets required to carry out the national strategy. The strategy outlined in this document presents a vision of how to equitably produce, communicate, and apply landslide data and science to support a broad range of land management, infrastructure, planning, and emergency response decisions. These decisions are made by a variety of actors, including private and nonprofit landholders; State, Tribal, territorial, city, and county planners; emergency managers; engineers; infrastructure managers; Federal agencies and their partners; and community leaders and individuals. Supporting those decisions and reducing the Nation’s vulnerability to landslides requires overcoming three main challenges: (1) gaps in basic information needed to describe and understand landslide occurrence and societal risk, (2) difficulty in accurately mapping and forecasting landslide hazards, and (3) communication and coordination among the many jurisdictions and sectors that have responsibility for and interest in reducing landslide losses. To address those challenges, this strategy document puts forward a series of strategic actions to achieve four goals: Assess: Decision makers have access to detailed, nationwide, and contextually relevant information on landslide hazard and risk. Coordinate: Landslide hazard mitigation, preparedness, response, and recovery efforts are coordinated across Federal, State, Tribal, territorial, and local levels. Plan: Communities and land managers are prepared and able to plan for landslide hazards. Respond: Landslide surveillance, warnings, and responses to events are effective, efficient, equitable, cooperative, and data-driven to protect lives, property, infrastructure, and the environment. These strategic actions focus on expanding the knowledge of societal risk posed by landslides as well as better understanding of where, when, and why they occur. They focus on applying that knowledge to support landslide risk reduction efforts and decisions, including the establishment of new advisory, coordination, and working groups focused on landslide hazard and risk. They take into account that supporting landslide loss reduction decisions also requires new guidance, tools, and training codeveloped with the entities, organizations, and individuals faced with making those decisions. Finally, they address actions needed to support and expand landslide warning information and improve the technical response to landslide emergencies.

Open-File Report↗

USGS1992

The stable isotope geochemistry of acid sulfate alteration

Acid sulfate wall-rock alteration, characterized by the assemblage alunite + kaolinite + quartz + or - pyrite, results from base leaching by fluids concentrated in H 2 SO 4 . Requisite amounts of H 2 SO 4 can be generated by different mechanisms in three principal geologic environments: (1) by atmospheric oxidation of sulfides in the supergene environment, (2) by atmospheric oxidation at the water table in the steam-heated environment of H 2 S released by deeper, boiling fluids, and (3) by the disproportionation of magmatic SO 2 to H 2 S and H 2 SO 4 during condensation of a magmatic vapor plume at intermediate depths in magmatic hydrothermal environments in silicic and andesitic volcanic terranes. In addition, coarse vein alunite may form in a magmatic steam environment from rapid release of an SO 2 -rich magmatic vapor phase at high temperature and low pressure or from the oxidation of a more reduced magmatic vapor by entrained atmospheric oxygen in the carapace of a volcanic edifice.Alunite [KAl 3 (SO 4 ) 2 (OH) 6 ] contains four stable isotope sites and complete analyses (delta D, delta 18 O (sub SO 4 ) , delta 18 O OH , and delta 34 S) are now possible. Except for delta 18 O OH in magmatic hydrothermal alunites, primary values are usually retained. In cooperation with many colleagues, over 500 measurements have been made on nearly 200 samples of alunite and associated minerals from 23 localities, and 55 additional analyses have been taken from the literature. This survey confirms that kinetic factors play an important role in the stable isotope systematics of alunite and acid sulfate alteration. To a very large extent they form the isotopic basis for distinguishing between environments of acid sulfate alteration, and they provide important insights into attendant processes. Stable isotope analyses of alunite, often in combination with those on associated sulfides and kaolinite, permit recognition of environments of formation and provide information on origins of components, processes (including rates), physical-chemical environments, and temperatures of formation.Supergene acid sulfate alteration may form over any sulfide zone when it is raised above the water table by tectonics or exposed by erosion. It may overprint earlier acid sulfate assemblages, particularly the magmatic hydrothermal assemblages which are pyrite rich such as at El Salvador, Chile; Rodalquilar, Spain; and Goldfield, Nevada. Supergene alunite normally has delta 34 S values virtually identical to precursor sulfides unless bacteriogenic reduction of aqueous sulfate takes place in standing pools of water. delta D values are close to that of local meteoric water unless extensive evaporation occurs. delta D and delta 18 O OH values of supergene alunites from a range of latitudes fall in a broad zone parallel to the meteoric water line much the way delta D and delta 18 O values of associated halloysite-kaolinite fall near the kaolinite line of Savin and Epstein (1970). delta 18 O (sub SO 4 ) values are kinetically controlled and will reflect the hydro-geochemistry of the environment. delta 18 O (sub SO 4 -OH) alues are grossly out of equilibrium and large negative values are definitive of a supergene origin.In steam-heated environments, such as those at the Tolfa district, Italy, and Marysvale, Utah, and numerous modern geothermal systems, acid sulfate alteration zones are characterized by pronounced vertical zoning. Such acid sulfate alteration may occur over adularia-sericite-type base and precious metal ore deposits such as the one at Buckskin, Nevada. Initial delta 18 O (sub SO 4 ) and delta 34 S values are kinetically controlled, but delta 18 O (sub SO 4 ) values usually reach equilibrium with fluids, and even delta 34 S values may reflect partial exchange with H 2 S where the residence time of aqueous sulfate is sufficient. Most alunites of steam-heated origin have delta 34 S values the same as those of precursor H 2 S (and as related sulfides, if present) and delta D values similar to that of local meteoric water. In the samples analyzed, most delta 18 O (sub SO 4 -OH) values give reasonable temperatures of 90 degrees to 160 degrees C, indicating that delta 18 O (sub SO 4 ) and delta 18 O OH values reflect a close approach to equilibrium with the fluid. The delta 18 O (sub SO 4 ) and delta 18 O OH values also reflect the degree of exchange of the meteoric fluids with wall rock. Coeval kaolinites typically have delta 18 O and delta D values to the left of the kaolinitc line.Magmatic hydrothermal, acid sulfate alteration zones in near-surface epithermal deposits such as Summitville, Colorado. Julcani, Peru, and Red Mountain and Lake City, Colorado, are characterized by vertical orientation and horizontal zoning, the presence of coeval pyrite, PO 4 analogues of alunite, zunyite, and later gold, pyrite and enargite, and often other Cu-As-Sb-S minerals. Acid sulfate alteration assemblages also occur as late stages in the porphyry-copper deposit at E1 Salvador, Chile. In the examples studied, magmatic hydrothermal alunites have delta D values close to those for magmatic water. delta 34 S values are 16 to 28 per mil larger than those for associated pyrite, reflecting equilibrium between aqueous H 2 S and SO 4 formed by the disproportionation of magmatically derived SO 2 . delta 18 O (sub SO 4 ) values are usually 8 to 18 per mil and vary systematically with delta 34 S values, reflecting variations in temperature and/or H 2 S/SO 4 fluid ratios. Further variation in delta 18 O (sub SO 4 ) values may result if SO 2 condenses in mixed magmatic meteoric water fluids. delta 18 O (sub SO (sub 4-) OH) values of magmatic hydrothermal alunites are generally unsuitable for temperature determinations because of retrograde exchange in the OH site, but delta 34 S (sub alunite-pyrite) values provide reliable temperature estimates.Magmatic steam environments appear to occur over a range of depths and are characterized by monomineralic veins of coarse alunite in variably alunitized and kaolinized wall rocks containing minor pyrite. Alunite formed in the magmatic steam environment can usually be recognized by delta 34 S near delta 34 S (sub Sigma S) values and delta D and delta 18 O (sub SO 4 ) values near magmatic values. Magmatic steam alunite differs from magmatic hydrothermal alunite by having delta 34 S close to delta 34 S (sub Sigma S) values of the system. delta 18 O (sub SO (sub 4-) OH) values of most magmatic steam alunite give temperatures ranging from 90 degrees to 210 degrees C but, for reasons which are not understood, some temperatures as well as calculated delta 18 O (sub H 2 O) values are too low for presumed precipitation from a magmatic vapor phase. Magmatic steam environments may occur over porphyry-type mineralization as at Red Mountain, Colorado, and Alunite Ridge, Utah, and over or adjacent to adularia-sericite-type deposits in volcanic domes as at Cactus, California.

Economic Geology↗

USGS2010

Interpolating a consumption variable for scaling and generalizing potential population pressure on urbanizing natural areas

Measures of population pressure, referring in general to the stress upon the environment by human consumption of resources, are imperative for environmental sustainability studies and management. Development based on resource consumption is the predominant factor of population pressure. This paper presents a spatial model of population pressure by linking consumption associated with regional urbanism and ecosystem services. Maps representing relative geographic degree and extent of natural resource consumption and degree and extent of impacts on surrounding areas are new, and this research represents the theoretical research toward this goal. With development, such maps offer a visualization tool for planners of various services, amenities for people, and conservation planning for ecologist. Urbanization is commonly generalized by census numbers or impervious surface area. The potential geographical extent of urbanism encompasses the environmental resources of the surrounding region that sustain cities. This extent is interpolated using kriging of a variable based on population wealth data from the U.S. Census Bureau. When overlayed with land-use/land-cover data, the results indicate that the greatest estimates of population pressure fall within mixed forest areas. Mixed forest areas result from the spread of cedar woods in previously disturbed areas where further disturbance is then suppressed. Low density areas, such as suburbanization and abandoned farmland are characteristic of mixed forest areas.

Missouri↗

USGS2007

U.S. Geological Survey Mineral Resources Program - Science Supporting Mineral Resource Stewardship

The United States is the world's largest user of mineral resources. We use them to build our homes and cities, fertilize our food crops, and create wealth that allows us to buy goods and services. Individuals rarely use nonfuel mineral resources in their natural state - we buy light bulbs, not the silica, soda ash, lime, coal, salt, tungsten, copper, nickel, molybdenum, iron, manganese, aluminum, and zinc used to convert electricity into light. The USGS Mineral Resources Program (MRP) is the sole Federal source of scientific information and unbiased research on nonfuel mineral potential, production, and consumption, as well as on the environmental effects of minerals. The MRP also provides baseline geochemical, geophysical, and mineral-deposit data used to understand environmental issues related to extraction and use of mineral resources. Understanding how minerals, water, plants, and organisms interact contributes to our understanding of the environment, which is essential for maintaining human and ecosystem health. To support creation of economic and national security policies in a global context, MRP collects and analyzes data on essential mineral commodities from around the world.

Fact Sheet↗

USGS2005

Volcano hazards

Not only do “Volcanoes assail the senses …” (Decker and Decker, 1997, p. vii), but they also assail the environment when they erupt, terrifying and fascinating humankind for countless millennia. Volcanic processes and products – beneficial and hazardous – have profoundly impacted and continue to impact society (Chester, 1993, Chapter 14, this volume). It is estimated that about 10% of the world's population live within proximity of active and potentially active volcanoes. With projected population growth, by the twenty-first century more than 500 million people could be at risk from volcano hazards (Peterson, 1986; Tilling and Lipman, 1993). Of these half billion people at risk, roughly equal to the estimated entire world population at the beginning of the seventeenth century, about 90% live in the circum-Pacific region. Also in the twenty-first century, with continued increasing urbanization there will be more than 100 cities with greater than 2 million population, and many of these will be located within 200 km of volcanically active subduction zones (McGuire, 1995a, Fig. 15.1). Over 1500 subaerial volcanoes have been active during the Holocene (i.e., the past 10,000 years), and more than a third of these have erupted one or more times during recorded history (Simkin and Siebert, 1994). Active or potentially active volcanoes occur in narrow belts that collectively comprise less than 1% of the Earth's total surface area, dotting the divergent and convergent boundaries between the tectonic plates and above well-documented intraplate “hot spots,” such as Hawaii and the Galapagos (Simkin et al. , 1994).

Book chapter↗

USGS2006

Development of land segmentation, stream-reach network, and watersheds in support of hydrological simulation program: Fortran (HSPF) modeling, Chesapeake Bay watershed, and adjacent parts of Maryland, Delaware, and Virginia

The U.S. Geological Survey, U.S. Environmental Protection Agency Chesapeake Bay Program Office, Interstate Commission on the Potomac River Basin, Maryland Department of the Environment, Virginia Department of Conservation and Recreation, Virginia Department of Environmental Quality, and the University of Maryland Center for Environmental Science are collaborating on the Chesapeake Bay Regional Watershed Model, using Hydrological Simulation Program - FORTRAN to simulate streamflow and concentrations and loads of nutrients and sediment to Chesapeake Bay. The model will be used to provide information for resource managers. In order to establish a framework for model simulation, digital spatial datasets were created defining the discretization of the model region (including the Chesapeake Bay watershed, as well as the adjacent parts of Maryland, Delaware, and Virginia outside the watershed) into land segments, a stream-reach network, and associated watersheds. Land segmentation was based on county boundaries represented by a 1:100,000-scale digital dataset. Fifty of the 254 counties and incorporated cities in the model region were divided on the basis of physiography and topography, producing a total of 309 land segments. The stream-reach network for the Chesapeake Bay watershed part of the model region was based on the U.S. Geological Survey Chesapeake Bay SPARROW (SPAtially Referenced Regressions On Watershed attributes) model stream-reach network. Because that network was created only for the Chesapeake Bay watershed, the rest of the model region uses a 1:500,000-scale stream-reach network. Streams with mean annual streamflow of less than 100 cubic feet per second were excluded based on attributes from the dataset. Additional changes were made to enhance the data and to allow for inclusion of stream reaches with monitoring data that were not part of the original network. Thirty-meter-resolution Digital Elevation Model data were used to delineate watersheds for each stream reach. State watershed boundaries replaced the Digital Elevation Model-derived watersheds where coincident. After a number of corrections, the watersheds were coded to indicate major and minor basin, mean annual streamflow, and each watershed's unique identifier as well as that of the downstream watershed. Land segments and watersheds were intersected to create land-watershed segments for the model.

Delaware, Maryland, Virginia↗

USGS2005

Hydrologic and water-quality conditions in the Kansas River, northeast Kansas, November 2001–August 2002, and simulation of ammonia assimilative capacity and bacteria transport during low flow

Large concentrations of ammonia and densities of bacteria have been detected in reaches of the Kansas River in northeast Kansas during low streamflow conditions, prompting the Kansas Department of Health and Environment (KDHE) to list these reaches as water-quality limited with respect to ammonia and fecal coliform bacteria. Sources for ammonia and bacteria in the watershed consist of wastewater-treatment facilities (WWTFs) and agricultural and urban runoff. The U.S. Geological Survey (USGS), in cooperation with KDHE, conducted an investigation of the Kansas River to characterize hydrologic and water-quality conditions and to simulate ammonia assimilative capacity and bacteria transport during low streamflow. This report characterizes the water-quality conditions, documents the calibration of a two-dimensional water-quality model, and presents results of hypothetical simulations of existing and future WWTFs discharging to the Kansas River during low streamflow. Water samples were collected during low streamflow conditions at 50 sampling sites along and near the Kansas River between Wamego and Kansas City, Kansas, during three synoptic surveys conducted between November 2001 and August 2002. The analytical results from these samples indicated that ammonia and other nutrient concentrations and fecal coliform bacteria densities increased in the Kansas River from Wamego to Kansas City. Point sources were the primary contributors of ammonia and fecal coliform bacteria during low-flow conditions. Generally, ammonia concentrations in the Kansas River were largest at sampling sites just downstream from WWTFs. Overall, ammonia concentrations in the Kansas River, tributaries, and WWTF effluent were larger in the winter than during the summer. None of the main-stem sample concentrations exceeded the State of Kansas pH- and temperature-dependent chronic aquatic-life criteria for ammonia during the sampling periods. Other nutrients, such as total nitrogen and total phosphorus, indicated a similar, but less variable, spatial pattern along the main stem of the Kansas River, with concentrations increasing slightly downstream from major WWTFs. The temporal variance defined by the results of synoptic survey III (July 22–August 8, 2002) indicated that ammonia concentrations in the Kansas River sometimes varied daily by as much as 155 percent at a single site. Samples analyzed for densities of fecal coliform bacteria illustrated a seasonal, spatial, and temporal pattern slightly different from that of nutrients. Overall, the bacteria densities measured during the summer were larger than the densities measured in the winter. The only fecal coliform bacteria density to exceed the former State water-quality, single-sample criteria of 2,000 col/100 mL (colonies per 100 milliliters of water) was measured at 4,000 col/100 mL during synoptic III (summer 2002) on the main stem of the Kansas River at Kansas City. Temporal variability measured during synoptic survey III indicated up to a 263-percent difference in bacteria density over a 12-day period. Instantaneous loads of ammonia and bacteria were computed to determine primary inputs to the Kansas River and ammonia and bacteria decay rates in the river. The Oakland WWTF in Topeka was the largest contributor of both ammonia and bacteria on the basis of samples collected during the three synoptic surveys, except for fecal coliform bacteria collected during synoptic survey III when the DeSoto WWTF was discharging the largest concentration of bacteria. The ammonia assimilative process was about twice as effective during the summer synoptic survey than it was during the winter survey. Decay of fecal coliform bacteria density was less evident and appeared to have little seasonal effect on the basis of data collected for this report. The summer low-streamflow water-quality conditions were suitable for nitrification, algae that consume ammonia, and consequently, decaying organic matter that consume oxygen. The consumption of dissolved oxygen due to nitrification and decaying algae contributed to three measurements of dissolved oxygen that were less than the State of Kansas aquatic-life-support use criteria of 5.0 milligrams per liter. CE–QUAL–W2, a two-dimensional, hydrodynamic and water-quality model, was used to simulate ammonia and bacteria transport in the Kansas River from Topeka to Kansas City. The model was calibrated and verified using data from the three synoptic surveys. The calibrated model successfully simulated the hydrodynamics, water temperature, dissolved oxygen, ammonia, and fecal coliform bacteria in the Kansas River. Simulated in-stream ammonia concentrations were compared to measured concentrations upstream to downstream along the Kansas River. The simulated in-stream ammonia concentrations mostly overestimated the measured values for both winter and summer, with a few exceptions. Comparisons between measured and simulated in-stream ammonia concentrations indicated ammonia assimilation was simulated more accurately in the summer than during the winter. Four hypothetical simulations of varied effluent discharges from existing WWTFs and addition of a proposed WWTF near DeSoto were simulated to better understand future water-quality conditions in the Kansas River. Results indicated that ammonia and dissolved-oxygen concentrations in the Kansas River will decrease from the conditions observed during synoptic surveys II (February 25 through March 1, 2002) and III (July 22 through August 8, 2002) except near the proposed WWTF where concentrations of ammonia would be near or exceed criteria for waterborne species. Effects of the proposed WWTF on dissolved oxygen would result in concentrations less than the State of Kansas aquatic-life-support use criteria of 5.0 milligrams per liter for 1 to 2 miles downstream from either of the proposed sites.

Kansas↗

USGS1998

Transmissivity and water quality of water-producing zones in the intermediate aquifer system, Sarasota County, Florida

The intermediate aquifer system is an important water source in Sarasota County, Florida, because the quality of water in it is usually better than that in the underlying Upper Floridan aquifer. The intermediate aquifer system consists of a group of up to three water-producing zones separated by less-permeable units that restrict the vertical movement of ground water between zones. The diverse lithology, that makes up the intermediate aquifer system, reflects the variety of depositional environments that occurred during the late Oligocene and Miocene epochs. Slight changes in the depositional environment resulted in aquifer heterogeneity, creating both localized connection between water-producing zones and abrupt culmination of water-producing zones that are not well documented. Aquifer heterogeneity results in vertical and areal variability in hydraulic and water-quality properties. The uppermost water-producing zone is designated producing zone 1 but is not extensively used because of its limited production capability and limited areal extent. The second water-producing zone is designated producing zone 2, and most of the domestic- and irrigation-supply wells in the area are open to this zone. Additionally, producing zone 2 is utilized for public supply in southern coastal areas of Sarasota County. Producing zone 3 is the lowermost and most productive water-producing zone in the intermediate aquifer system. Public-supply well fields serving the cities of Sarasota and Venice, as well as the Plantation and Mabry Carlton Reserve well fields, utilize producing zone 3. Heads within the intermediate aquifer system generally increase with aquifer depth. However, localized head-gradient reversals occur in the study area, coinciding with sites of intense ground-water withdrawals. Heads in producing zones 1, 2, and 3 range from 1 to 23, 0.2 to 34, and 7 to 42 feet above sea level, respectively. Generally, an upward head gradient exists between producing zones 3 and 2. However, an upward head gradient between producing zones 2 and 1 does not consistently occur throughout Sarasota County, probably the result of greater ground-water withdrawals from producing zone 2 than from producing zone 1. The transmissivity of the intermediate aquifer system is spatially variable. Specific-capacity data from selected wells penetrating producing zones 2 and 3, were used to estimate transmissivity. Estimated transmissivity values for producing zones 2 and 3 range from about 100 to 26,000 feet squared per day and from about 1,300 to 6,200 feet squared per day, respectively. Because the capacity of specific water-producing zones is highly variable from site to site, estimating the performance of a specific water-producing zone as a water resource is difficult. Water samples collected during the study were analyzed for major-ion concentrations. Generally, bicarbonate type water from rock interaction occurs in northern Sarasota County; enriched calcium-magnesium-sulfate type water from deeper aquifers occurs in central Sarasota County; and sodium-chloride type water from saltwater mixing occurs in southern Sarasota County. In some areas of northern Sarasota County, the major-ion concentrations in water are lower in producing zone 2 than in producing zone 1. Major-ion concentrations in water are higher in producing zone 3 throughout the study area. A major objective of the study was to evaluate hydraulic and water-quality data to determine distinctions that could be used to characterize a particular producing zone. However, data indicate that both hydraulic and water-quality properties are highly variable within and between zones, and are more related to the degree of connection between and areal extent of water-producing zones than to aquifer depth and distance from the coast.

Florida↗

USGS2002

Stable isotope composition of waters in the Great Basin, United States 1. Air-mass trajectories

Isentropic trajectories, calculated using the NOAA/Climate Monitoring and Diagnostics Laboratory's isentropic transport model, were used to determine air-parcel origins and the influence of air mass trajectories on the isotopic composition of precipitation events that occurred between October 1991 and September 1993 at Cedar City, Utah, and Winnemucca, Nevada. Examination of trajectories that trace the position of air parcels backward in time for 10 days indicated five distinct regions of water vapor origin: (1) Gulf of Alaska and North Pacific, (2) central Pacific, (3) tropical Pacific, (4) Gulf of Mexico, and (5) continental land mass. Deuterium (??D) and oxygen-18 (??18O) analyses were made of precipitation representing 99% of all Cedar City events. Similar analyses were made on precipitation representing 66% of the precipitation falling at Winnemucca during the same period. The average isotopic composition of precipitation derived from each water vapor source was determined. More than half of the precipitation that fell at both sites during the study period originated in the tropical Pacific and traveled northeast to the Great Basin; only a small proportion traversed the Sierra Nevada. The isotopic composition of precipitation is determined by air-mass origin and its track to the collection station, mechanism of droplet formation, reequilibration within clouds, and evaporation during its passage from cloud to ground. The Rayleigh distillation model can explain the changes in isotopic composition of precipitation as an air mass is cooled pseudo-adiabatically during uplift. However, the complicated processes that take place in the rapidly convecting environment of cumulonimbus and other clouds that are common in the Great Basin, especially in summer, require modification of this model because raindrops that form in the lower portion of those clouds undergo isotopic change as they are elevated to upper levels of the clouds from where they eventually drop to the ground.

Journal of Geophysical Research D: Atmospheres↗

USGS1979

Better utilization of ground water in the Piedmont and mountain region of the southeast

The development of water supplies for domestic consumption, and for those commercial and industrial uses requiring relatively pure water, has followed a pattern in the Piedmont and mountain areas of the southeast similar to that in most other humid areas. The first settlers utilized seepage springs on hillsides. Such springs occur along steep slopes where the water table intersects the land surface. As the population of the region grew, it became increasingly necessary to resort to shallow dug wells for domestic water supplies. Such wells also served as sources of water for the villages that developed, in time, around crossroad taverns. Seepage springs and dug wells are a satisfactory source of water in a virgin environment but are quickly polluted by careless waste-disposal practices. Thus disposal of domestic wastes in shallow pits resulted in epidemics of water-borne diseases as the villages grew into towns. This resulted in the third phase of water-supply development, which consisted of installing water lines and supplying water to homes from town-owned wells. In time, some of these wells became polluted and others failed to supply adequate water for the increasing needs of the larger urban areas. In the fourth phase these areas met their needs by drawing water from nearby streams. By the early years of this century it was possible to make this water palatable and relatively safe as a result of improvement in filtration methods. Streams, of course, have highly variable rates of flow and, as towns grew into small cities, the minimum flow of many streams was not adequate to meet the water-supply needs. This problem was solved in the fifth phase by building dams on the streams. We are still in this phase as we build larger and larger reservoirs to meet our growing water needs. Thus, through five phases of growth in the Piedmont and mountains we have advanced from the point where ground water was the sole source of supply to the point where it is the forgotten resource . For reasons to be explained below, a sixth phase can be foreseen in which ground water and surface water are recognized as parts of the hydrologic system with advantages in their conjunctive development and use.

Piedmont↗

USGS2005

Compilation of geologic, hydrologic, and ground-water flow modeling information for the Spokane Valley-Rathdrum Prairie aquifer, Spokane County, Washington, and Bonner and Kootenai Counties, Idaho

The U.S. Geological Survey, in cooperation with the Idaho Department of Water Resources and Washington Department of Ecology compiled and described geologic, hydrologic, and ground-water flow modeling information about the Spokane Valley-Rathdrum Prairie (SVRP) aquifer in northern Idaho and northeastern Washington. Descriptions of the hydrogeologic framework, water-budget components, ground- and surface-water interactions, computer flow models, and further data needs are provided. The SVRP aquifer, which covers about 370 square miles including the Rathdrum Prairie, Idaho and the Spokane valley and Hillyard Trough, Washington, was designated a Sole Source Aquifer by the U.S. Environmental Protection Agency in 1978. Continued growth, water management issues, and potential effects on water availability and water quality in the aquifer and in the Spokane and Little Spokane Rivers have illustrated the need to better understand and manage the region's water resources. The SVRP aquifer is composed of sand, gravel, cobbles, and boulders primarily deposited by a series of catastrophic glacial outburst floods from ancient Glacial Lake Missoula. The material deposited in this high-energy environment is coarser-grained than is typical for most basin-fill deposits, resulting in an unusually productive aquifer with well yields as high as 40,000 gallons per minute. In most places, the aquifer is bounded laterally by bedrock composed of granite, metasedimentary rocks, or basalt. The lower boundary of the aquifer is largely unknown except along the margins or in shallower parts of the aquifer where wells have penetrated its entire thickness and reached bedrock or silt and clay deposits. Based on surface geophysics, the thickness of the aquifer is about 500 ft near the Washington-Idaho state line, but more than 600 feet within the Rathdrum Prairie and more than 700 feet in the Hillyard trough based on drilling records. Depth to water in the aquifer is greatest in the northern Rathdrum Prairie (about 500 feet) and least near the city of Spokane along the Spokane River (less than about 50 feet). Ground-water flow is south from near the southern end of Lake Pend Oreille and Hoodoo Valley, through the Rathdrum Prairie, then west toward Spokane. In Spokane, the aquifer splits and water moves north through the Hillyard Trough as well as west through the Trinity Trough. From the Trinity Trough water flows north along the western arm of the aquifer. The aquifer's discharge area is along the Little Spokane River and near Long Lake, Washington. A compilation of estimates of water-budget components, including recharge (precipitation, irrigation, canal leakage, septic tank effluent, inflow from tributary basins, and flow from the Spokane River) and discharge (withdrawals from wells, flow to the Spokane and Little Spokane Rivers, evapotranspiration, and underflow to Long Lake) illustrates that these estimated values should be compared with caution due to several variables including the area and time period of interest as well as methods employed in making the estimates. Numerous studies have documented the dynamic ground-water and surface-water interaction between the SVRP aquifer and the Spokane and Little Spokane Rivers. Gains and losses vary throughout the year, as well as the locations of gains and losses. September 2004 streamflow measurements indicated that the upper reach of the Spokane River between Post Falls and downstream at Flora Road lost 321 cubic feet per second. A gain of 736 cubic feet per second was measured between the Flora Road site and downstream at Green Street Bridge. A loss of 124 cubic feet per second was measured for the reach between the Green Street Bridge and the Spokane River at Spokane gaging station. The river gained about 87 cubic feet per second between the Spokane River at Spokane gaging station and the TJ Meenach Bridge. Overall, the Spokane River gained about 284 cubic feet per second between the Post Falls,

Scientific Investigations Report↗