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Alkylphenols, other endocrine-active chemicals, and fish responses in three streams in Minnesota — Study design and data, February-September 2007

This report presents the study design and environmental data for an integrated chemical and biological study of three streams (South Fork Crow River, Redwood River, and Grindstone River) that receive wastewater in Minnesota. The objective of the study was to identify distribution patterns of endocrine-active chemicals and other organic chemicals indicative of wastewater, and to identify fish responses in the same streams. Endocrine-active chemicals are a class of chemicals that interfere with the natural regulation of endocrine systems, and an understanding of their distribution in aquatic systems is important so that aquatic organism exposure can be evaluated. This study was a cooperative effort of the U.S. Geological Survey (USGS), the Minnesota Pollution Control Agency, and St. Cloud State University (St. Cloud, Minn.). The USGS collected and analyzed water and quality-assurance samples and measured streamflow during six sampling events in each of three streams. Water samples were collected upstream from and at two successive points downstream from wastewater-treatment plant (WWTP) effluent discharge and from treated effluent from February through September 2007. Bed-sediment samples were collected during one sampling period at each of the stream locations. Water and bed-sediment samples were analyzed for endocrine-active chemicals including alkylphenols, alkylphenol polyethoxylates, and nonylphenol ethoxycarboxlylates (NPECs). Water samples also were analyzed for major ions, nutrients, and organic carbon. In addition, as part of an intensive time-series investigation, the USGS staff collected daily water samples for 8 weeks from the Redwood River near Marshall, Minn., for analyses of total alkylphenols and atrazine. St. Cloud State University staff collected and analyzed fish to determine male fish responses at all water sampling sites and at an additional site near the discharge of wastewater-treatment plant effluent to these streams. Male fish responses included the presence and concentration of vitellogenin in plasma, gonadosomatic indices, and histological characterizations of liver and testes tissue. Hydrologic, chemical and biological characteristics were different among sites. The percentage of streamflow contributed by WWTP effluent (ranging from less than 1 to 79 percent) was greatest at the South Fork Crow River and least at the Grindstone River. WWTP effluent generally contributed the greatest percentage of streamflow during winter and late summer when streamflows were low. A wide variety of chemicals were detected. More chemicals were detected in WWTP effluent samples than in stream samples during most time periods. The most commonly detected chemicals in samples collected monthly and analyzed at the USGS National Research Program Laboratory were 2,6-di- tert -butyl-1,4-benzoquinone, 2,6-di- tert -butyl-4-methylphenol, 3- beta -coprostanol, 4-methylphenol, 4-nonylphenol (NP), 4- tert -octylphenol, bisphenol A, cholesterol, ethylenediaminetetraacetic acid, and triclosan. The chemicals 4-nonylphenolmonoethoxycarboxylate (NP1EC), 4-nonylphenoldiethoxycarboxylate (NP2EC), and 4-nonylphenoltriethoxycarboxylate (NP3EC) also were detected. Excluding nondetections, the sum of NP1EC through NP3EC concentrations ranged from 5.1 to 260 µg/L among all samples. NP was detected in upstream, effluent, and downstream samples in each stream during at least one time period. NP was detected in 49 percent of environmental samples. Excluding nondetections, concentrations of NP ranged from 100 to 880 nanograms per liter among all samples. NP was also detected in more than one-half of the bed-sediment samples. The most commonly detected wastewater indicator chemicals in samples analyzed by schedule 4433 at the USGS National Water Quality Laboratory were 3,4-dichlorophenyl isocyanate, acetyl-hexamethyl-tetrahydronaphthalene, benzophenone, cholesterol, hexahydrohexamethyl-cyclopenta-benzopyran, N,N-diethyl- meta -toluamide, and tri(dichloroisopropyl) phosphate. Male fish responses were the focus of the fish analyses, and 508 male fish were collected among all sampling sites. Vitellogenin was detected in 57 percent of the 415 male fish analyzed; concentrations ranged from an estimated value of 0.1 to 330 micrograms per milliliter (µg/mL) (average of 17.1 µg/mL). Intersex (the presence of oocytes in testes tissue) was observed in only one fathead minnow from an upstream site on the Grindstone River.

Minnesota

Geochemical and mineralogical data for soils of the conterminous United States

In 2007, the U.S. Geological Survey initiated a low-density (1 site per 1,600 square kilometers, 4,857 sites) geochemical and mineralogical survey of soils of the conterminous United States as part of the North American Soil Geochemical Landscapes Project. Sampling and analytical protocols were developed at a workshop in 2003, and pilot studies were conducted from 2004 to 2007 to test and refine these recommended protocols. The final sampling protocol for the national-scale survey included, at each site, a sample from a depth of 0 to 5 centimeters, a composite of the soil A horizon, and a deeper sample from the soil C horizon or, if the top of the C horizon was at a depth greater than 1 meter, from a depth of approximately 80–100 centimeters. The <2-millimeter fraction of each sample was analyzed for a suite of 45 major and trace elements by methods that yield the total or near-total elemental content. The major mineralogical components in the samples from the soil A and C horizons were determined by a quantitative X-ray diffraction method using Rietveld refinement. Sampling in the conterminous United States was completed in 2010, with chemical and mineralogical analyses completed in May 2013. The resulting dataset provides an estimate of the abundance and spatial distribution of chemical elements and minerals in soils of the conterminous United States and represents a baseline for soil geochemistry and mineralogy against which future changes may be recognized and quantified. This report (1) describes the sampling, sample preparation, and analytical methods used; (2) gives details of the quality control protocols used to monitor the quality of chemical and mineralogical analyses over approximately six years; and (3) makes available the soil geochemical and mineralogical data in downloadable tables.

Data Series

1990 National Water Quality Laboratory Services Catalog

PREFACE This catalog provides information about analytical services available from the National Water Quality Laboratory (NWQL) to support programs of the Water Resources Division of the U.S. Geological Survey. To assist personnel in the selection of analytical services, the catalog lists cost, sample volume, applicable concentration range, detection level, precision of analysis, and preservation techniques for samples to be submitted for analysis. Prices for services reflect operationa1 costs, the complexity of each analytical procedure, and the costs to ensure analytical quality control. The catalog consists of five parts. Part 1 is a glossary of terminology; Part 2 lists the bottles, containers, solutions, and other materials that are available through the NWQL; Part 3 describes the field processing of samples to be submitted for analysis; Part 4 describes analytical services that are available; and Part 5 contains indices of analytical methodology and Chemical Abstract Services (CAS) numbers. Nomenclature used in the catalog is consistent with WATSTORE and STORET. The user is provided with laboratory codes and schedules that consist of groupings of parameters which are measured together in the NWQL. In cases where more than one analytical range is offered for a single element or compound, different laboratory codes are given. Book 5 of the series 'Techniques of Water Resources Investigations of the U.S. Geological Survey' should be consulted for more information about the analytical procedures included in the tabulations. This catalog supersedes U.S. Geological Survey Open-File Report 86-232 '1986-87-88 National Water Quality Laboratory Services Catalog', October 1985.

Open-File Report

Contaminants of emerging concern in the lower Stillaguamish River Basin, Washington, 2008-11

A series of discrete water-quality samples were collected in the lower Stillaguamish River Basin near the city of Arlington, Washington, through a partnership with the Stillaguamish Tribe of Indians. These samples included surface waters of the Stillaguamish River, adjacent tributary streams, and paired inflow and outflow sampling at three wastewater treatment plants in the lower river basin. Chemical analysis of these samples focused on chemicals of emerging concern, including wastewater compounds, human-health pharmaceuticals, steroidal hormones, and halogenated organic compounds on solids and sediment. This report presents the methods used and data results from the chemical analysis of these samples

Washington

Salinity of the Delaware Estuary

The purpose of this investigation was to obtain data on and study the factors affecting the salinity of the Delaware River from Philadelphia, Pa., to the Appoquinimink River, Del. The general chemical quality of water in the estuary is described, including changes in salinity in the river cross section and profile, diurnal and seasonal changes, and the effects of rainfall, sea level, and winds on salinity. Relationships are established of the concentrations of chloride and dissolved solids to specific conductance. In addition to chloride profiles and isochlor plots, time series are plotted for salinity or some quantity representing salinity, fresh-water discharge, mean river level, and mean sea level. The two major variables which appear to have the greatest effect on the salinity of the estuary are the fresh-water flow of the river and sea level. The most favorable combination of these variables for salt-water encroachment occurs from August to early October and the least favorable combination occurs between December and May.

Water Supply Paper

Redwood National Park studies; data release number 2, Redwood Creek, Humboldt County, and Mill Creek, Del Norte County, California, April 11, 1974-September 30, 1975

An interdisciplinary study has been undertaken in Redwood National Park, Calif., to describe parts of the ecosystems and recent changes in the intensity of erosion and sedimentation, define processes that may alter the natural ecosystems, and assess the impact of recent road construction and timber harvest. This report is the second of a series that will present data collected in this study. Stream-discharge and water-quality data were collected at 53 sampling stations in the Redwood Creek and Mill Creek drainage basins. Measurements included the following variables: Stream stage and discharge; turbidity; sediment; onsite water-quality determinations of temperature, pH , total alkalinity, specific conductance, and dissolved-oxxygen concentration; chemical analyses of water samples for major dissolved solids, selected trace elements, nitrogen, phosphorus, and organic carbon; chemical analyses of bottom sediment for organic carbon and pesticides; bacteria; benthic invertebrates; fish; periphyton; phytoplankton; and seston. Additional data include changes in geometry at 10 stream-channel cross sections along Mill Creek and the distribution of erosional landforms in the Mill Creek drainage basin; quantity and chemical composition of rainwater; and the intragravel-streambed condition at selected stations in the Redwood Creek drainage basin. (Woodard-USGS)

Open-File Report

Assessment of elemental concentrations in streams of the New Lead Belt in southeastern Missouri, 2002-05

Concerns about possible effects of lead-mining activities on the water quality of federally protected streams located in southeastern Missouri prompted a suite of multidisciplinary studies to be conducted by the U.S. Geological Survey. As part of this investigation, a series of biological studies were initiated in 2001 for streams in the current mining region and the prospecting area. In this report, results are examined for trace elements and other selected chemical measurements in sediment, surface water, and sediment interstitial (pore) water sampled between 2002 and 2005 in association with these biological studies. Compared to reference sites, fine sediments collected downstream from mining areas were enriched in metals by factors as large as 75 for cadmium, 62 for cobalt, 171 for nickel, 95 for lead, and 150 for zinc. Greatest metal concentrations in sediments collected in 2002 were from sites downstream from mines on Strother Creek, Courtois Creek, and the West Fork Black River. Sediments from sites on Bee Fork, Logan Creek, and Sweetwater Creek also were noticeably enriched in lead. Sediments in Clearwater Lake, at least 75 kilometers downstream from mining activity, had metal concentrations that were 1.5 to 2.1 times greater than sediments in an area of the lake with no upstream mining activity. Longitudinal sampling along three streams in 2004 indicated that sediment metal concentrations decreased considerably a few kilometers downstream from mining activities; however, in Strother Creek some metals were still enriched by a factor of five or more as far as 13 kilometers downstream from the Buick tailings impoundment. Compared with 2002 samples, metals concentrations were dramatically lower in sediments collected in 2004 at an upper West Fork Black River site, presumably because beneficiation operations at the West Fork mill ceased in 2000. Concentrations of metals and sulfate in sediment interstitial (pore) waters generally tracked closely with metal concentrations in sediments. Metals, including cobalt, nickel, lead, and zinc, were elevated substantially in laboratory-produced pore waters of fine sediments collected near mining operations in 2002 and 2004. Passive diffusion samplers (peepers) buried 4 to 6 centimeters deep in riffle-run stream sediments during 2003 and 2005 had much lower pore-water metal concentrations than the laboratory-produced pore waters of fine sediments collected in 2002 and 2004, but each sampling method produced similar patterns among sites. The combined mean concentration of lead in peeper samples from selected sites located downstream from mining activities for six streams was about 10-fold greater than the mean of the reference sites. In most instances, metals concentrations in surface water and peeper water were not greatly different, indicating considerable exchange between the surface water and pore water at the depths and locations where peepers were situated. Passive sampling probes used to assess metal lability in pore waters of selected samples during 2004 sediment toxicity tests indicated that most of the filterable lead in the laboratory-prepared pore water was relatively non-labile, presumably because lead was complexed by organic matter, or was present as colloidal species. In contrast, large percentages of cobalt and nickel in pore water appeared to be labile. Passive integrative samplers deployed in surface water for up to 3 weeks at three sites in July 2005 confirmed the presence of elevated concentrations of labile metals downstream from mining operations on Strother Creek and, to a lesser extent, Bee Fork. These samplers also indicated a considerable increase in metal loadings occurred for a few days at the Strother Creek site, which coincided with moderate increases in stream discharges in the area.

Scientific Investigations Report

Patterns and scales of phytoplankton variability in estuarine: Coastal ecosystems

Phytoplankton variability is a primary driver of chemical and biological dynamics in the coastal zone because it directly affects water quality, biogeochemical cycling of reactive elements, and food supply to consumer organisms. Much has been learned about patterns of phytoplankton variability within individual ecosystems, but patterns have not been compared across the diversity of ecosystem types where marine waters are influenced by connectivity to land. We extracted patterns from chlorophyll- a series measured at 84 estuarine–coastal sites, using a model that decomposes time series into an annual effect, mean seasonal pattern, and residual “events.” Comparisons across sites revealed a large range of variability patterns, with some dominated by a recurrent seasonal pattern, others dominated by annual (i.e., year-to-year) variability as trends or regime shifts and others dominated by the residual component, which includes exceptional bloom events such as red tides. Why is the partitioning of phytoplankton variability at these three scales so diverse? We propose a hypothesis to guide next steps of comparative analysis: large year-to-year variability is a response to disturbance from human activities or shifts in the climate system; strong seasonal patterns develop where the governing processes are linked to the annual climate cycle; and large event-scale variability occurs at sites highly enriched with nutrients. Patterns of phytoplankton variability are therefore shaped by the site-specific relative importance of disturbance, annual climatology, and nutrient enrichment.

Estuaries and Coasts

Mapping of coal quality using stochastic simulation and isometric logratio transformation with an application to a Texas lignite

Coal is a chemically complex commodity that often contains most of the natural elements in the periodic table. Coal constituents are conventionally grouped into four components (proximate analysis): fixed carbon, ash, inherent moisture, and volatile matter. These four parts, customarily measured as weight losses and expressed as percentages, share all properties and statistical challenges of compositional data. Consequently, adequate modeling should be done in terms of a logratio transformation, a requirement that is commonly overlooked by modelers. The transformation of choice is the isometric logratio transformation because of its geometrical and statistical advantages. The modeling is done through a series of realizations prepared by applying sequential simulation for the purpose of displaying the parts in maps incorporating uncertainty. The approach makes realistic assumptions and the results honor the data and basic considerations, such as percentages between 0 and 100, all four parts adding to 100% at any location in the study area, and a style of spatial fluctuation in the realizations equal to that of the data. The realizations are used to prepare different results, including probability distributions across a deposit, E-type maps displaying average properties, and probability maps summarizing joint fluctuations of several parts. Application of these maps to a lignite bed clearly delineates the deposit boundary, reveals a channel cutting across, and shows that the most favorable coal quality is to the north and deteriorates toward the southeast.

International Journal of Coal Geology

Chemical composition of Texas surface waters, 1949

This report is the fifth the a series of publications by the Texas Board of Water Engineers giving chemical analyses of the surface waters in the State of Texas. The samples for which data are given were collected between October 1, 1948 and September 30, 1949. During the water year 25 daily sampling stations were maintained by the Geological Survey. Sampled were collected less frequently during the year at many other points. Quality of water records for previous years can be found in the following reports: "Chemical Composition of Texas Surface Waters, 1938-1945," by W. W. Hastings, and J. H. Rowley; "Chemical Composition of Texas Surface Waters, 1946," by W. W. Hastings and B. Irelan; "Chemical Composition of Texas Surface Waters, 1947," by B. Irelan and J. R. Avrett; "Chemical Composition of Texas Surface Waters, 1948," by B. Irelan, D. E. Weaver, and J. R. Avrett. These reports may be obtained from the Texas Board of Water Engineers and Geological Survey at Austin, Texas. Samples for chemical analysis were collected daily at or near points on streams where gaging stations are maintained for measurement of discharge. Most of the analyses were made of 10-day composites of daily samples collected for a year at each sampling point. Three composite samples were usually prepared each month by mixing together equal quantities of daily samples collected for the 1st to the 10th, from the 11th to the 20th, and during the remainder of the month. Monthly composites were made at a few stations where variation in daily conductance was small. For some streams that are subject to sudden large changes in chemical composition, composite samples were made for shorter periods on the basis of the concentration of dissolved solids as indicated by measurement of specific conductance of the daily samples. The mean discharge for the composite period is reported in second-feet. Specific conductance values are expressed as "micromhos, K x 10 at 25&deg; C." Silica, calcium, magnesium, sodium, potassium, bicarbonate, sulfate, chloride, and nitrate are reported in parts per million. The quantity of dissolved solids is given in tons per acre-foot, tons per day (if discharge records are available), and parts per million. The total and non-carbonate hardness are reported as parts per million calcium carbonate (CaCO 3 ). For those analyses where sodium and potassium are reported separately, "recent sodium" will include the equivalent quantity of sodium only. In analyses where sodium and potassium were calculated and reported as a combined value, the "percent sodium" will include the equivalent quantity of sodium and potassium. Weighted average analyses are given for most daily sampling stations. The weighted average analysis represent approximately the composition of water that would be found in a reservoir containing all the water passing a given station during the year after through mixing in the reservoir. Samples were analyzed according to method regularly used by the Geological Survey. These methods are essentially the same or are modifications of methods described in recognized authoritative publications for mineral analysis of water samples. These quality of water records have been collected as part of the cooperative investigations of the water resources of Texas conducted by the Geological Survey and the Texas Board of Water Engineers. Much of the work would have been impossible without the support of the following Federal State, and local agencies The United States Bureau of Reclamation, U. S. Corps of Engineers, Brazos River Conservation and Reclamation District, Lower Colorado River Authority, Red Bluff Water Power Control District, City of Amarillo, City of Abilene, and City of Forth Worth. The investigations were under the firection of Burdge Irelan, District Chemist, Austin, Texas. Analyses of water samples were made by Clara J. Carter, Lee J. Freeman, Homer D. Smith, Dorothy M. Suttle, DeForrest E. Weaver, and Clarence T. Welborn. Calculations of weighted averages were made by James R. Avrett, Burdge Irelan, Dorothy M. Suttle, and DeForrest E. Weaver.

Texas

Well yields and chemical quality of water from water-table aquifers in the greater Denver area, Front Range urban corridor, Colorado

Knowledge of the well yields and chemical quality of water from water-table aquifers is useful to State and local officials in making decisions on land use and in locating water supplies in the rapidly urbanizing greater Denver are. This report presents the results of a 2-year investigation to obtain this knowledge and to relate the results to urban planning in the greater Denver area. The report is one of a series of geologic and hydrologic reports prepared by the U.S. Geological Survey to demonstrate the usefulness of Earth-science information in urban planning.

Colorado

Evaluation of selected wells in Pennsylvania's observation-well program as of 1993

In 1993, the U.S. Geological Survey operated 62 observation wells in 60 of Pennsylvania's 67 counties in cooperation with the Pennsylvania Department of Environmental Resources. These wells attempt to monitor an aerial extent of 45,000 square miles and penetrate 39 geologic formations or water-bearing units of 14 physiographic provinces. Some wells were drilled specifically for the observation-well program, some were drilled for other U.S. Geological Survey projects, and some were drilled for other purposes and were no longer used. Approximately 3 percent of the network wells have less than 5 years of record, 5 percent have 5 to 15 years of record, and 92 percent have greater than 15 years of record. The older the observation well, the greater the possibility of water levels being affected by physical deterioration of the borehole. Therefore, it is necessary to periodically conduct a series of physical, chemical, and hydraulic tests to determine changes in the physical condition of the well and local land-use practices that may affect water-level response. Nineteen wells were selected for evaluation on the basis of past questionable water-level responses. These wells were evaluated for functionality by analyzing historical water-level fluctuations, geophysical logs, single-well aquifer tests, and water-quality analyses. These parameters indicated that well Je-23 (Jefferson County) is affected by coal-mine pumpage, well Bt-311 (Butler County) is periodically affected by strip mine activities, well Gr-118 (Greene County) and Mc-110 (McKean County exhibit unexplained fluctuations not desirable for an observation well, and 15 wells show no obvious problems or degradation that would affect their functionality to monitor natural water-level fluctuations.

Water-Resources Investigations Report

Water resources data, Pennsylvania, water year 2000, Volume 1. Delaware River Basin

The Water Resources Division of the U.S. Geological Survey, in cooperation with State, municipal, and Federal agencies, collects a large amount of data pertaining to the water resources of Pennsylvania each water year. These data, accumulated during many water years, constitute a valuable data base for developing an improved understanding of the water resources of the State. To make these data readily available to interested parties outside the Geological Survey, these data are published annually in this report series entitled "Water Resources Data - Pennsylvania, Volumes 1, 2, and 3." Volume 1 contains data for the Delaware River Basin; Volume 2, the Susquehanna and Potomac River Basins; and Volume 3, the Ohio River and St. Lawrence River Basins. This report, Volume 1, contains: (1) discharge records for 76 continuous-record streamflow-gaging stations, 7 partial-record stations, and 13 special study and miscellaneous streamflow sites; (2) elevation and contents records for 14 lakes and reservoirs; (3) water-quality records for 28 gaging stations and 14 ungaged streamsites; (4) water-quality records for 77 special-study stations; (5) water-level records for 53 network observation wells; and (6) water-quality analyses of ground water from 101 ground-water wells. Additional water data collected at various sites not involved in the systematic data-collection program may also be presented. Publications similar to this report are published annually by the Geological Survey for all States. For the purpose of archiving, these official reports have an identification number consisting of the two-letter State abbreviation, the last two digits of the water year, and the volume number. For example, this volume is identified as "U.S. Geological Survey Water-Data Report PA-00-1." These water data reports, beginning with the 1971 water year, are for sale as paper copy or microfiche by the National Technical Information Service, U.S. Department of Commerce, Springfield, VA 22161. The annual series of Water Data Reports for Pennsylvania began with the 1961 water-year report and contained only data relating to quantities of surface water. With the 1964 water year, a companion report (part 2) was introduced that contained only data relating to water quality. Beginningwith the 1975 water year the report was changed to its present format of three volumes (by river basin), with each volume containing data on quantities of surface water, quality of surface and ground water, and ground-water levels. Prior to the introduction of this series and for several years concurrent with it, water-resources data for Pennsylvania were published in U.S. Geological Survey Water-Supply Papers. Data on stream discharge and stage, and on lake or reservoir contents and stage, through September 1960, were published annually under the title "Surface-Water Supply of the United States," which was released in numbered parts as determined by natural drainage basins. For the 1961-70 water years, these data were published in two 5-year reports. Data prior to 1961 are included in two reports: "Compilation of Records of Surface Waters of the United States through 1950," and "Compilation of Records of Surface Waters of the United States, October 1950 to September 1960." Data for Pennsylvania are published in Parts 1, 3, and 4. Data on chemical quality, temperature, and suspended sediment for the 1941-70 water years were published annually under the title "Quality of Surface Waters of the United States," and ground-water levels for the 1935-74 water years were published under the title "Ground-Water Levels in the United States." The above mentioned Water-Supply Papers may be consulted in the libraries of the principal cities of the United States and may be purchased from the U.S. Geological Survey, Information Services, Box 25286, Denver, CO 80225. Information for ordering specific reports may be obtained from the Pennsylvania District Office at the address given on the back of the title page or by phoning the Scientific and Technical Products Section, at (717) 730-6940. Information on the availability of unpublished data or statistical analyses may be obtained from the District Information Specialist by telephone at (717) 730-6916 or by FAX at (717) 730-6997.

Water Data Report

Water resources data, Pennsylvania, water year 2000. Volume 2. Susquehanna and Potomac River Basins

Introduction The Water Resources Division of the U.S. Geological Survey, in cooperation with State, municipal, and Federal agencies, collects a large amount of data pertaining to the water resources of Pennsylvania each water year. These data, accumulated during many water years, constitute a valuable data base for developing an improved understanding of the water resources of the State. To make these data readily available to interested parties outside the Geological Survey, these data are published annually in this report series entitled "Water Resources Data - Pennsylvania, Volumes 1, 2, and 3." Volume 1 contains data for the Delaware River Basin; Volume 2, the Susquehanna and Potomac River Basins; and Volume 3, the Ohio and St. Lawrence River Basins. This report, Volume 2, contains: (1) discharge records for 83 continuous-record streamflow-gaging stations, 16 partial-record stations, and 24 special study and miscellaneous streamflow sites; (2) elevation and contents records for 12 lakes and reservoirs; (3) water-quality records for 11 streamflow gaging stations and 70 partial-record and project stations; and (4) water-level records for 30 ground-water network observation wells and water-quality analyses of ground water from 8 wells; and (5) water-quality analyses at 60 special study ground-water wells. Additional water data collected at various sites not involved in the systematic data-collection program may also be presented. Publications similar to this report are published annually by the Geological Survey for all States. For the purpose of archiving, these official reports have an identification number consisting of the two-letter State abbreviation, the last two digits of the water year, and the volume number. For example, this volume is identified as "U.S. Geological Survey Water-Data Report PA-00-2." These water-data reports, beginning with the 1971 water year, are for sale as paper copy or microfiche by the National Technical Information Service, U.S. Department of Commerce, Springfield, VA 22161. The annual series of Water Data Reports for Pennsylvania began with the 1961 water-year report and contained only data relating to quantities of surface water. With the 1964 water year, a companion report (part 2) was introduced that contained only data relating to water quality. Beginning with the 1975 water year the report was changed to three volumes (by river basin), with each volume containing data on quantities of surface water, quality of surface and ground water, and ground-water levels. Prior to the introduction of this series and for several years concurrent with it, water-resources data for Pennsylvania were published in U.S. Geological Survey Water-Supply Papers. Data on stream discharge and stage, and on lake or reservoir contents and stage, through September 1960, were published annually under the title "Surface-Water Supply of the United States," which was released in numbered parts as determined by natural drainage basins. For the 1961-70 water years, these data were published in two 5-year reports. Data prior to 1961 are included in two reports: "Compilation of Records of Surface Waters of the United States through 1950," and "Compilation of Records of Surface Waters of the United States, October 1950 to September 1960." Data for Pennsylvania are published in Parts 1, 3, and 4. Data on chemical quality, temperature, and suspended sediment for the 1941-70 water years were published annually under the title "Quality of Surface Waters of the United States," and ground-water levels for the 1935-74 water years were published annually under the title "Ground-Water Levels in the United States." The above mentioned Water-Supply Papers may be consulted in the libraries of the principal cities of the United States and may be purchased from the U.S. Geological Survey, Information Services, Box 25286, Denver, CO 80225. Information for ordering specific reports may be obtained from the Pennsylvania District Office at the address on the back of the title page or by phoning the Scientific and Technical Products Section at (717) 730-6940. Information on the availability of unpublished data or statistical analyses may be obtained from the District Information Specialist by telephone at (717) 730-6916 or by FAX at (717) 730-6997.

Water Data Report

Water resources data, Pennsylvania, water year 2000. Volume 3. Ohio and St. Lawrence River Basins

Introduction The Water Resources Division of the U.S. Geological Survey, in cooperation with State, municipal, and Federal agencies, collects a large amount of data pertaining to the water resources of Pennsylvania each water year. These data, accumulated during many water years, constitute a valuable data base for developing an improved understanding of the water resources of the State. To make these data readily available to interested parties outside the Geological Survey, these data are published annually in this report series entitled "Water Resources Data - Pennsylvania, Volumes 1, 2, and 3." Volume 1 contains data for the Delaware River Basin; Volume 2, the Susquehanna and Potomac River Basins; and Volume 3, the Ohio and St. Lawrence River Basins. This report, Volume 3, contains: (1) discharge records for 58 continuous-record streamflow-gaging stations, 5 partial-record stations, and 12 special study and miscellaneous streamflow sites; (2) elevation and contents records for 11 lakes and reservoirs; (3) water-quality records for 1 streamflow gaging station and 8 ungaged streamsites; and (4) water-level records for 15 ground-water network observation wells and. Additional water data collected at various sites not involved in the systematic data-collection program may also be presented. Publications similar to this report are published annually by the Geological Survey for all States. For the purpose of archiving, these official reports have an identification number consisting of the two-letter State abbreviation, the last two digits of the water year, and the volume number. For example, this volume is identified as "U.S. Geological Survey Water-Data Report PA-00-3." These water-data reports, beginning with the 1971 water year, are for sale as paper copy or microfiche by the National Technical Information Service, U.S. Department of Commerce, Springfield, VA 22161. The annual series of Water Data Reports for Pennsylvania began with the 1961 water-year report and contained only data relating to quantities of surface water. With the 1964 water year, a companion report (part 2) was introduced that contained only data relating to water quality. Beginning with the 1975 water year the report was changed to three volumes (by river basin), with each volume containing data on quantities of surface water, quality of surface and ground water, and ground-water levels. Prior to the introduction of this series and for several years concurrent with it, water-resources data for Pennsylvania were published in U.S. Geological Survey Water-Supply Papers. Data on stream discharge and stage, and on lake or reservoir contents and stage, through September 1960, were published annually under the title "Surface-Water Supply of the United States," which was released in numbered parts as determined by natural drainage basins. For the 1961-70 water years, these data were published in two 5-year reports. Data prior to 1961 are included in two reports: "Compilation of Records of Surface Waters of the United States through 1950," and "Compilation of Records of Surface Waters of the United States, October 1950 to September 1960." Data for Pennsylvania are published in Parts 1, 3, and 4. Data on chemical quality, temperature, and suspended sediment for the 1941-70 water years were published annually under the title "Quality of Surface Waters of the United States," and ground-water levels for the 1935-74 water years were published annually under the title "Ground-Water Levels in the United States." The above mentioned Water-Supply Papers may be consulted in the libraries of the principal cities of the United States and may be purchased from the U.S. Geological Survey, Information Services, Box 25286, Denver, CO 80225. Information for ordering specific reports may be obtained from the Pennsylvania District Office at the address on the back of the title page or by phoning the Scientific and Technical Products Section at (717) 730-6940. Information on the availability of unpublished data or statistical analyses may be obtained from the District Information Specialist by telephone at (717) 730-6916 or by FAX at (717) 730-6997.

Water Data Report

Water Resources Data, Pennsylvania, Water Year 2001, Volume 2. Susquehanna and Potomac River Basins

Introduction The Water Resources Division of the U.S. Geological Survey, in cooperation with State, municipal, and Federal agencies, collects a large amount of data pertaining to the water resources of Pennsylvania each water year. These data, accumulated during many water years, constitute a valuable data base for developing an improved understanding of the water resources of the State. To make these data readily available to interested parties outside the Geological Survey, these data are published annually in this report series entitled "Water Resources Data - Pennsylvania, Volumes 1, 2, and 3." Volume 1 contains data for the Delaware River Basin; Volume 2, the Susquehanna and Potomac River Basins; and Volume 3, the Ohio and St. Lawrence River Basins. This report, Volume 2, contains: (1) discharge records for 83 continuous-record streamflow-gaging stations, 15 partial-record stations, and 24 special study and miscellaneous streamflow sites; (2) elevation and contents records for 12 lakes and reservoirs; (3) water-quality records for 9 streamflow gaging stations and 73 partial-record and project stations; and (4) water-level records for 36 ground-water network observation wells and water-quality analyses of ground water from 8 wells; (5) water-quality analyses at 123 special study ground-water wells; and, (6) miscellaneous water-level measurements at 80 special study ground-water wells. Additional water data collected at various sites not involved in the systematic data-collection program may also be presented. Publications similar to this report are published annually by the Geological Survey for all States. For the purpose of archiving, these official reports have an identification number consisting of the two-letter State abbreviation, the last two digits of the water year, and the volume number. For example, this volume is identified as "U.S. Geological Survey Water-Data Report PA-01-2." These water-data reports, beginning with the 1971 water year, are for sale as paper copy or microfiche by the National Technical Information Service, U.S. Department of Commerce, Springfield, VA 22161. The annual series of Water Data Reports for Pennsylvania began with the 1961 water-year report and contained only data relating to quantities of surface water. With the 1964 water year, a companion report (part 2) was introduced that contained only data relating to water quality. Beginning with the 1975 water year the report was changed to three volumes (by river basin), with each volume containing data on quantities of surface water, quality of surface and ground water, and ground-water levels. Prior to the introduction of this series and for several years concurrent with it, water-resources data for Pennsylvania were published in U.S. Geological Survey Water-Supply Papers. Data on stream discharge and stage, and on lake or reservoir contents and stage, through September 1960, were published annually under the title "Surface-Water Supply of the United States," which was released in numbered parts as determined by natural drainage basins. For the 1961-70 water years, these data were published in two 5-year reports. Data prior to 1961 are included in two reports: "Compilation of Records of Surface Waters of the United States through 1950," and "Compilation of Records of Surface Waters of the United States, October 1950 to September 1960." Data for Pennsylvania are published in Parts 1, 3, and 4. Data on chemical quality, temperature, and suspended sediment for the 1941-70 water years were published annually under the title "Quality of Surface Waters of the United States," and ground-water levels for the 1935-74 water years were published annually under the title "Ground-Water Levels in the United States." The above mentioned Water-Supply Papers may be consulted in the libraries of the principal cities of the United States and may be purchased from the U.S. Geological Survey, Information Services, Box 25286, Denver, CO 80225. Information for ordering specific reports may be obtained from the Pennsylvania District Office at the address on the back of the title page or by phoning the Scientific and Technical Products Section at (717) 730-6940. Information on the availability of unpublished data or statistical analyses may be obtained from the District Information Specialist by telephone at (717) 730-6916 or by FAX at (717) 730-6997.

Water Data Report

Water-quality and lake-stage data for Wisconsin lakes, water year 1997

The U.S. Geological Survey (USGS), in cooperation with local and other agencies, collects data at selected lakes throughout Wisconsin. These data, accumulated over many years, provide a data base for developing an improved understanding of the water quality of lakes. To make these data available to interested parties outside the USGS, the data are published annually in this report series. The location of water-quality and lake-stage stations in Wisconsin for water year 1997 are shown in figure 1. A water year is the 12-month period from October 1 through September 30. It is designated by the calendar year in which it ends. Thus, the period October 1, 1996 through September 30, 1997 is called 'water year 1997'. The purpose of this report is to provide information about the physical and chemical characteristics of Wisconsin lakes. Data that have been collected at specific lakes, and information to aid in the interpretation of those data, are included in this report. Data collected include measurements of lake stage and in-lake water quality. Graphs of Secchi depths, surface total-phosphorus and chlorophyll-a concentrations versus time are usually included for lakes with two or more years of data. Graphs of vertical profiles of temperature, dissolved oxygen, pH, and specific conductance are included for sites where these parameters were measured. Descriptive information for each lake includes: location of the lake, area of the lake's watershed, period for which data are available, revisions to previously published records, and pertinent remarks. Additional data, such as streamflow and water quality in tributary and outlet streams of some of the lakes, are published in another volume: 'Water Resources Data-Wisconsin, 1997'.

Wisconsin

Benthos and plankton community data for selected rivers and harbors along the western Lake Michigan shoreline, 2014

Benthos (benthic invertebrates) and plankton (zooplankton and phytoplankton) communities were sampled in 2014 at 10 Wisconsin rivers and harbors, including 4 sites in Great Lakes Areas of Concern and 6 less degraded comparison sites with similar physical and chemical characteristics, including climate, latitude, geology, and land use. Previous U.S. Geological Survey sampling was completed in 2012, but because of ongoing sediment remediation at three of the Areas of Concern (AOCs) and unusually hot and dry conditions in many areas during 2012, additional sampling was added in 2014. Comparable sampling methods were used in 2012 and 2014. Benthos were collected by using Hester-Dendy artificial substrate samplers and composite Ponar grab samples of bottom sediment; zooplankton were collected by using tows from depth to the surface with a 63-micrometer mesh plankton net; phytoplankton were collected by using whole water samples composited from set depth intervals. This report describes the study areas and field sampling methods for 2014, and it presents data on taxonomic identification and abundance of benthos and plankton that can serve as a basis for evaluation of related Beneficial Use Impairments (BUIs) at the AOCs. Physical and chemical data were sampled concurrently (specific conductance, temperature, pH, dissolved oxygen, chlorophyll a , total and volatile suspended solids in water samples; particle size and volatile-on-ignition of sediment in benthic grab samples). The results of field quality assurance-quality control are also presented.

Wisconsin