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At least 145 records · Page 8Linked to original sources
USGS1969

Determination of gold in waters in the nanogram range by anion exchange and atomic absorption spectrophotometry

A method has been developed whereby nanogram amounts of gold in waters can be accurately determined. The development of the method involves determination of optimum conditions for the complete recovery of gold from water using an anion exchange resin column, quantitative elution of gold from the resin, and final measurement of gold by atomic absorption spectrophotometry following MIBK (methyl isobutyl ketone) extraction of gold from a nitric acid solution.

Economic Geology↗
USGS1971

Gold content of natural waters in Colorado

Neutron activation analysis of 67 samples of water draining from gold-barren and gold-enriched sedimentary, igneous, and metamorphic rocks of the Colorado Front Range reveals a relatively small range in total gold content (nondetectable to 150 nanograms per liter). "Solute" gold concentrations were generally higher than particulate gold concentrations and both were unrelated to rock or water types. The data suggest the occurrence of a spring flush out of "solute" gold in groundwater discharge during the snow-melt recharge period but indicate that direct hydrogeochemical prospecting for gold is unpromising.

Colorado↗
USGS1987

Selenium adsorption by goethite

The adsorption of Se by goethite was studied as a function of time (10 min–24 h), temperature (295.5 and 303.5 K), pH (4–11), particle concentration (3–300 mg/L), total Se concentration (0.02–5 × 10 −5 M ), oxidation state [Se(IV) and Se(VI)], and competing anion concentration [(anion)/(Se(IV) = 0.25 to 50 000] in order to assess the influence of these factors on Se mobility. The data indicate that (i) the surface sites of goethite are heterogeneous, (ii) the adsorption of selenite [Se(IV)] reaches equilibrium in 2 h and is completely reversible with respect to pH, (iii) the removal of selenite from solution increases with decreasing pH and increasing particle concentration, (iv) the adsorption edge for selenite shifts to lower pH values with increasing total selenite concentrations, (v) selenite adsorbs much more strongly than selenate [Se(VI)], and (vi) the influence of additional anions on selenite adsorption depends on the relative affinity of the anions for the surface and the relative concentrations of the anions. For a given anion concentration ratio, the competition sequence with selenite is phosphate > silicate ≥ citrate > molybdate > bicarbonate/carbonate > oxalate > fluoride > sulfate. Therefore, the conditions that favor the mobility of Se in the environment with respect to adsorption are alkaline pH, high Se concentrations, oxidizing conditions, and high concentrations of additional anions that strongly adsorb.

Soil Science Society of America Journal↗
USGS1997

Sedimentary carbonate-hosted giant Bayan Obo REE-Fe-Nb ore deposit of Inner Mongolia, China; a cornerstone example for giant polymetallic ore deposits of hydrothermal origin

Detailed, integrative field and laboratory studies of the textures, structures, chemical characteristics, and isotopically determined ages and signatures of mineralization of the Bayan Obo deposit provided evidence for the origin and characteristics favorable for its formation and parameters necessary for defining giant polymetallic deposits of hydrothermal origin. Bayan Obo is an epigenetic, metasomatic, hydrothermal rare earth element (REE)-Fe-Nb ore deposit that is hosted in the metasedimentary H8 dolostone marble of the Middle Proterozoic Bayan Obo Group. The metasedimentary sequence was deposited on the northern continental slope of the North China craton. The mine area is about 100 km south of the suture marking Caledonian subduction of the Mongolian oceanic plate from the north beneath the North China craton. The mineralogy of the deposit is very complex, consisting of more than 120 different minerals, some of which are epigenetic minerals introduced by hydrothermal solutions, and some of which are primary and secondary metamorphic minerals. The major REE minerals are monazite and bastnaesite, whereas magnetite and hematite are the dominant Fe-ore minerals, and columbite is the most abundant Nb mineral. Dolomite, alkali amphibole, fluorite, barite, aegirine augite, apatite, phlogopite, albite, and microcline are the most widespread gangue minerals. Three general types of ores occur at Bayan Obo: disseminated, banded, and massive ores. Broad zoning of these ore types occurs in the Main and East Orebodies. Disseminated ores are in the outermost zone, banded ores are in the intermediate zone, and massive ores are in the cores of the orebodies. On the basis of field relations, host rocks, textures, structures, and mineral assemblages, many varieties of these three types of ores have been recognized and mapped. Isotopic dating of monazite, bastnaesite, aeschynite, and metamorphic and metasomatic alkali amphiboles associated with the deposit provides constraints on the ages of mineralization and the history of the deposit. Textural relations, differences in chemical composition, and 232Th/208Pb internal isochron ages of monazite and bastnaesite samples indicate that many episodes of REE mineralization occurred at Bayan Obo, ranging from about 555 Ma to about 398 Ma. Initial 208Pb/204Pb ratios suggest different sources of REE's for different generations of REE minerals. Relative ages of Fe mineralization were deduced from textural relationships of Fe minerals with other, dated mineral phases in the deposit. Most Nb mineralization was in the area of the West Orebodies and resulted in disseminated ore. Aeschynite, an early stage of Nb mineralization (438+-25.1 Ma), occurs with huanghoite and alkali amphiboles in veins. The 40Ar/39Ar ages of amphiboles, as well as petrographic textures, were used to distinguish three periods of regional metamorphism in the Bayan Obo mine area: (1) Late Proterozoic, about 890 Ma, which recrystallized H8 carbonate to marble and crystallized lineated alkali amphiboles along foliation planes in the marble; (2) Caledonian, about 425-395 Ma, which resulted in metamorphic and metasomatic-metamorphic alkali amphiboles; and (3) Hercynian, about 300 Ma, based on biotite 40Ar/39Ar analyses from biotite schist and folded banded ores. The 40Ar/39Ar ages of metasomatic alkali amphiboles also place time constraints on the hydrothermal history of the ore deposit. Metasomatic amphiboles represent periods of intense hydrothermal activity, which began as early as 1.26 Ga; that date is based on the age of amphibole from a vein that crosscuts the H6 quartzite that underlies the H8 dolostone marble. Although much of the metasomatic amphibole formed during periods that overlapped the peak period of REE mineralization of banded ores, REE and alkali amphibole phases generally occur in different mineral assemblages or are of very different ages in the same assemblage and, therefore, may have been derived from

Bulletin↗
USGS1983

Recommended procedures and methodology of coal description

This document is the result of a workshop on coal description held for the Branch of Coal Resources of the U.S. Geological Survey in March 1982. It has been prepared to aid and encourage the field-oriented coal scientist to participate directly in petrographic coal-description activities. The objectives and past and current practices of coal description vary widely. These are briefly reviewed and illustrated with examples. Sampling approaches and techniques for collecting columnar samples of fresh coal are also discussed. The recommended procedures and methodology emphasize the fact that obtaining a good megascopic description of a coal bed is much better done in the laboratory with a binocular microscope and under good lighting conditions after the samples have been cut and quickly prepared. For better observation and cross-checking using a petrographic microscope for identification purposes, an in-place polishing procedure (requiring less than 2 min) is routinely used. Methods for using both the petrographic microscope and an automated image analysis system are also included for geologists who have access to such instruments. To describe the material characteristics of a coal bed in terms of microlithotypes or lithotypes, a new nomenclature of (V), (E), (1), (M). (S). (X 1 ). (X 2 ) and so on is used. The microscopic description of the modal composition of a megascopically observed lithologic type is expressed in terms of (VEIM); subscripts are used to denote the volume percentage of each constituent present. To describe a coal-bed profile, semiquantitative data (without microscopic study) and quantitative data (with microscopic study) are presented in ready-to-understand form. The average total composition of any thickness interval or of the entire coal bed can be plotted on a triangular diagram having V, E, and I+ M +S as the apices. The modal composition of any mixed lithologies such as (X 1 ), (X 2 ), and so on can also be plotted on such a triangular ternary diagram. Such diagrams can be used either for tracing compositional variations throughout a single coal-bed profile or for comparing variations between different coal beds.

Circular↗
USGS2001

Comparative water-quality assessment of the Hai He River basin in the People's Republic of China and three similar basins in the United States

Ground-water quality with respect to nitrate, major inorganic constituents, pesticides, stable isotopes, and tritium was assessed in the agricultural Tangshan region in the Hai He River basin of the People's Republic of China and compared with three similar regions in the United States: the Delmarva Peninsula of the States of Delaware, Maryland, and Virginia, and the San Joaquin and Sacramento Valleys of the State of California. These four regions are considered similar with respect to size, land use, or climate. Median nitrate concentrations were found to be similar in the four regions in most instances, and those median concentrations were below the American nitrate drinking water standard of 10 milligrams per liter, however, higher concentrations, and a greater range of concentration, were evident for the Tangshan region.

Delmarva Peninsula, Hai He River basin, Sacramento↗
USGS2017

Geology and undiscovered resource assessment of the potash-bearing Pripyat and Dnieper-Donets Basins, Belarus and Ukraine

Undiscovered potash resources in the Pripyat Basin, Belarus, and Dnieper-Donets Basin, Ukraine, were assessed as part of a global mineral resource assessment led by the U.S. Geological Survey (USGS). The Pripyat Basin (in Belarus) and the Dnieper-Donets Basin (in Ukraine and southern Belarus) host stratabound and halokinetic Upper Devonian (Frasnian and Famennian) and Permian (Cisuralian) potash-bearing salt. The evaporite basins formed in the Donbass-Pripyat Rift, a Neoproterozoic continental rift structure that was reactivated during the Late Devonian and was flooded by seawater. Though the rift was divided, in part by volcanic deposits, into the separate Pripyat and Dnieper-Donets Basins, both basins contain similar potash‑bearing evaporite sequences. An Early Permian (Cisuralian) sag basin formed over the rift structure and was also inundated by seawater resulting in another sequence of evaporite deposition. Halokinetic activity initiated by basement faulting during the Devonian continued at least into the Permian and influenced potash salt deposition and structural evolution of potash-bearing salt in both basins. Within these basins, four areas (permissive tracts) that permit the presence of undiscovered potash deposits were defined by using geological criteria. Three tracts are permissive for stratabound potash-bearing deposits and include Famennian (Upper Devonian) salt in the Pripyat Basin, and Famennian and Cisuralian (lower Permian) salt in the Dnieper-Donets Basin. In addition, a tract was delineated for halokinetic potash-bearing Famennian salt in the Dnieper-Donets Basin. The Pripyat Basin is the third largest source of potash in the world, producing 6.4 million metric tons of potassium chloride (KCl) (the equivalent of about 4.0 million metric tons of potassium oxide or K 2 O) in 2012. Potash production began in 1963 in the Starobin #1 mine, near the town of Starobin, Belarus, in the northwestern corner of the basin. Potash is currently produced from six potash mines in the Starobin area. Published reserves in the Pripyat Basin area are about 7.3 billion metric tons of potash ore (about 1.3 billion metric tons of K 2 O) mostly from potash-bearing salt horizons in the Starobin and Petrikov mine areas. The 15,160-square-kilometer area of the Pripyat Basin underlain by Famennian potash-bearing salt contains as many as 60 known potash-bearing salt horizons. Rough estimates of the total mineral endowment associated with stratabound Famennian salt horizons in the Pripyat Basin range from 80 to 200 billion metric tons of potash-bearing salt that could contain 15 to 30 billion metric tons of K 2 O. Parameters (including the number of economic potash horizons, grades, and depths) for these estimates are not published so the estimates are not easily confirmed. Historically, reserves have been estimated above a depth of 1,200 meters (m) (approximately the depths of conventional underground mining). Additional undiscovered K 2 O resources could be significantly greater in the remainder of the Fammenian salt depending on the extents and grades of the 60 identified potash horizons above the USGS assessment depth of 3,000 m in the remainder of the tract. Increasing ambient temperatures with increasing depths in the eastern parts of the Pripyat Basin may require a solution mining process which is aided by higher temperatures. No resource or reserve data have been published and little is known about stratabound Famennian and Frasnian salt in the Dnieper-Donets Basin. These Upper Devonian salt units dip to the southeast and extend to depths of 15–19 kilometers (km) or greater. The tract of stratabound Famennian salt that lies above a depth of 3 km, the depth above which potash is technically recoverable by solution mining, underlies an area of about 15,600 square kilometers (km 2 ). If Upper Devonian salt units in the Dnieper-Donets Basin contain potash-bearing strata similar to salt of the same age in the Pripyat Basin, then the stratabound Famennian tract in the Dnieper-Donets Basin could contain significant undiscovered potash resources. The Cisuralian evaporite sequence in the Dnieper-Donets Basin consists of 10 evaporite cycles with the upper 3 cycles containing potash-bearing salt (mainly as sylvite and carnallite) in several subbasins and polyhalite in the sulfate bearing parts of the identified tract. The area of the Cisuralian tract is 62,700 km 2 . Potash-bearing cycles are as much as 40 m thick. One subbasin is reported to contain 794 million metric tons of “raw or crude” potash-bearing salt which could contain 50 to 150 million metric tons of K 2 O, depending on the grade. Undiscovered potash resources in the remainder of this permissive tract may be significantly greater. Depths to the Permian salt range from less than 100 to about 1,500 m. Undiscovered resources of halokinetic potash-bearing salt in the Dnieper-Donets Basin were assessed quantitatively for this study by using the standard USGS three-part form of mineral resource assessment (Singer, 2007a; Singer and Menzie, 2010). Delineation of the permissive tract was based on distributions of mapped halokinetic salt structures. This tract contains at least 248 diapiric salt structures with a total area of 7,840 km 2 that occupies approximately 8 percent of the basin area. The vertical extent of these salt structures is hundreds of meters to several kilometers. This assessment estimated that a total mean of 11 undiscovered deposits contain an arithmetic mean estimate of about 840 million metric tons of K 2 O in the halokinetic salt structures of the Dnieper-Donets Basin for which the probabilistic estimate was made.

Dnieper-Donets Basin, Pripyat Basin↗
USGS2023

Geology and undiscovered resource assessment of the potash-bearing, Middle Devonian (Givetian), Prairie Evaporite, Elk Point Basin, Canada and United States

The U.S. Geological Survey (USGS) assessed undiscovered potash resources in the Elk Point Basin in Canada and the United States as part of a global mineral resource assessment. The Elk Point Basin is a large, Middle Devonian (Givetian) intracratonic evaporite basin covering approximately 1,200,000 square kilometers (km 2 ) and filled mainly with marine evaporite and minor clastic sedimentary rocks that contain stratabound potash-bearing salt. The potash-bearing salt is concentrated in four stratigraphic members (Patience Lake, Belle Plaine, White Bear, and Esterhazy) in the upper 100 meters (m) of the Prairie Evaporite and are separated by beds of halite (NaCl) that contain lesser—presently non-economic—amounts of sylvite (KCl) and carnallite (KMgCl 3 ·6H 2 O). The principal ore-bearing salt contains mainly sylvite. Four permissive tracts were defined that permit the presence of undiscovered stratabound potash (both sylvite- and carnallite-bearing salt) using geological criteria. Permissive tracts are defined by the spatial extent of each stratigraphic member that is at least 1 m thick, are less than 3 kilometers (km) from the surface, contain at least 4 percent equivalent potassium oxide (K 2 O), and contain the currently known resources. The permissive tracts include known potash deposits and potash occurrences as wells or mines not in production and show where undiscovered potash resources may be present. Well data are used to define the extent, thickness, average K 2 O equivalent grades, and volumes of each member. Data were supplied by the Saskatchewan Geological Survey or were obtained from published National Instrument (NI) 43-101 technical reports and other published reports, such as annual 10-K reports or news releases. The Elk Point Basin is the world’s largest source of potash, producing 23.0 million metric tons (Mt) of potassium chloride (KCl) (the equivalent of about 14.4 Mt of K 2 O) in 2018. In terms of global importance, the Elk Point Basin may contain 40 to greater than 50 percent of the world’s potash resources. Since 1962, potash companies have mined more than 1.5 trillion metric tons of ore containing 605 Mt of KCl (the equivalent of about 380 Mt of K 2 O). The total value of the ore produced through 2018 is on the order of $70 trillion (CAD). Potash is currently produced from eight conventional and three underground solution mines at depths ranging from 900 m to nearly 1,800 m. Estimates of the amount of potash in the Elk Point Basin vary considerably and the data and methods used in those estimations are not well documented. Known potash resources are approximately 99 billion metric tons (Bt) of ore containing 22 Bt of K 2 O equivalent. As a result of new mine openings and increased production capacity at existing mines, the total production capacity of mines in the Elk Point Basin has increased significantly (to about 32.8 Mt of KCl or 22.8 Mt of K 2 O equivalent per year). Additional production capacity of about 31 Mt of KCl (or 17 Mt of K 2 O equivalent) per year could be realized over the next decade if several current (as of 2019) exploration and development projects reach production status. Stratabound potash-bearing salt of the Prairie Evaporite presently underlies a total area of about 188,000 km 2 and has a total volume of about 2,690 cubic kilometers (km 3 ). Post-depositional solution processes considerably modified the mineralogy and presence of the potash-bearing salt. These changes had a profound effect on the volume and grade of potash resources that remained in the Prairie Evaporite and are a major consideration of exploration and mining operations as well as in this assessment of undiscovered potash resources. This USGS assessment includes the locations and possible amounts of undiscovered potash resources in the Prairie Evaporite. Volumes for each stratigraphic member were computed using member thicknesses and areal extent modified by actual, estimated geologic loss owing to salt dissolution and extraction ratios, as well as estimated distribution of carnallite and sylvite. Both sylvite- and carnallite-bearing salts were assessed for potash in this study. The assessment uses modern published grade and tonnage data. The amount of undiscovered potash is estimated by using Monte Carlo simulations to combine volume estimates of the potash-bearing members with probability distributions for average grade and bulk density. Mean potash grades (expressed as percentage of K 2 O equivalent) calculated using drill core analyses are 17.76 for the Patience Lake Member, 15.98 for the Belle Plaine Member, 10.66 for the White Bear Member, and 15.30 for the Esterhazy Member. Geologic losses reported as extraction ratios during mining may range from 27.5 to 41.6 percent and are dependent on mining method and local geologic conditions. The assessment determined that mean estimated undiscovered K 2 O equivalent resources for the Patience Lake, Belle Plaine, White Bear, and Esterhazy Members are 340, 220, 34, and 190 Bt, respectively, and estimated a total mean of 790 Bt for the entire Prairie Evaporite above a depth of 3 km. The total mineralized rock tonnage is estimated to be about 5,000 Bt. Most of the assessed potash is located within Saskatchewan with lesser amounts in Alberta and Manitoba as well as Montana and North Dakota within the United States. Although carnallite is mined for potash in Europe, it has historically been avoided in mining plans for potash-producing companies in Saskatchewan because of mining, processing, and grade considerations. Carnallite-rich salt is locally present in concentrations and volumes that could be a significant resource of magnesium chloride (MgCl 2 ) obtained as a byproduct of processing the carnallite for potash. Previously estimated reserves (not NI 43-101 compliant) of mineralized material from 1955 to 2019 are 695 Mt at 22.1 percent MgCl 2 . The total amount of K 2 O equivalent as carnallite was estimated during this USGS assessment to be about 120 Bt (or 180 Bt KCl). With uncertainties in defining the areal extent of carnallite in each of the potash-bearing members, the amount of MgCl 2 as carnallite in the Elk Point Basin could be approximately 180 Bt.

Elk Point basin↗
USGS2014

Potash: a global overview of evaporate-related potash resources, including spatial databases of deposits, occurrences, and permissive tracts

Potash is mined worldwide to provide potassium, an essential nutrient for food crops. Evaporite-hosted potash deposits are the largest source of salts that contain potassium in water-soluble form, including potassium chloride, potassium-magnesium chloride, potassium sulfate, and potassium nitrate. Thick sections of evaporitic salt that form laterally continuous strata in sedimentary evaporite basins are the most common host for stratabound and halokinetic potash-bearing salt deposits. Potash-bearing basins may host tens of millions to more than 100 billion metric tons of potassium oxide (K 2 O). Examples of these deposits include those in the Elk Point Basin in Canada, the Pripyat Basin in Belarus, the Solikamsk Basin in Russia, and the Zechstein Basin in Germany. This report describes a global, evaporite-related potash deposits and occurrences database and a potash tracts database. Chapter 1 summarizes potash resource history and use. Chapter 2 describes a global potash deposits and occurrences database, which contains more than 900 site records. Chapter 3 describes a potash tracts database, which contains 84 tracts with geology permissive for the presence of evaporite-hosted potash resources, including areas with active evaporite-related potash production, areas with known mineralization that has not been quantified or exploited, and areas with potential for undiscovered potash resources. Chapter 4 describes geographic information system (GIS) data files that include (1) potash deposits and occurrences data, (2) potash tract data, (3) reference databases for potash deposit and tract data, and (4) representative graphics of geologic features related to potash tracts and deposits. Summary descriptive models for stratabound potash-bearing salt and halokinetic potash-bearing salt are included in appendixes A and B, respectively. A glossary of salt- and potash-related terms is contained in appendix C and a list of database abbreviations is given in appendix D. Appendix E describes GIS data files, and appendix F is a guide to using the geodatabase.

Scientific Investigations Report↗
USGS2025

Computing discharge using the entropy-based probability concept

This report describes the techniques and methods for computing the mean-channel velocity and discharge using the entropy-based probability concept (probability concept). The method is an alternative to or augments standard streamgaging methods adopted by the U.S. Geological Survey (USGS). Although sensor technology for measuring the mean velocity and discharge has advanced, standard streamgaging and computational methods have remained relatively unchanged since the USGS established its first streamgage at the Rio Grande at Embudo, New Mexico in 1889. Standard streamgaging methods rely on integrating velocities and depths measured at multiple verticals at a channel cross section (standard cross section) to compute a discharge. The probability concept computes discharge at a single vertical (y-axis) using the ratio of the mean-channel velocity (mean velocity) and maximum velocity, the measured maximum velocity, and the area as a function of stage at the standard cross section. Proper siting and operation and maintenance are required. If siting is conducted appropriately, the probability concept parameters and the y-axis stationing will be similar for different streamflow conditions. The timing of operation and maintenance visits should be based on hydrologic and meteorologic occurrences and seasonality and should capture low, medium, high, and opportunistic streamflow conditions. Advantages of the probability concept are the capacity to (1) compute discharge time series immediately after streamgage siting, (2) compute discharge for complex streamflow conditions that cannot be quantified by stage-discharge methods, (3) augment time-series data where gaps exist, and (4) integrate with surface velocity sensors such as Doppler velocity radars and cameras, which are not subject to damage caused by ice, debris, and flood flows. Potential sources of bias in discharge derived from the probability concept include (1) rain, (2) wind, and (3) geomorphologic and hydraulic instabilities. Recommendations to address these biases are provided. This report guides users through the steps to parameterize the probability concept, process field data, and compute the mean velocity and discharge using the probability concept.

Techniques and Methods↗
USGS2017

Identification of Chelonid herpesvirus 5 (ChHV5) in endangered green turtles (Chelonia mydas) with fibropapillomatosis in Asia

Fibropapillomatosis (FP), a debilitating tumor disease of sea turtles, was first identified in green turtles [ Chelonia mydas (Linnaeus, 1758)] in Florida in 1938. In recent decades, FP has been observed globally and is an emerging panzootic disease in sea turtles. However, few reports of FP in Asia exist. Here, we provide the first evidence of Chelonid herpesvirus 5 (ChHV5) DNA associated with FP in endangered green turtles from Taiwan, through molecular characterization, phylogenetic analysis, and histopathological examination. In our study, ChHV5 was successfully detected by PCR in the FP tumor lesions of green turtles. The sequences were found to be consistent with those of tumor-inducing viruses shown to affect sea turtles in the other parts of the world. ChHV5 RNA from the FP tissues was further detected by RT-PCR, indicating active replication of the viruses inside FP tumors. In addition to the molecular evidence of ChHV5 in FP, epidermal intranuclear inclusions were identified in tumor lesions upon histopathological examination. This further suggests that ChHV5 should be in a transcriptionally active (i.e., non-latent) state in FP tumors of affected green turtles. The phylogenetic tree revealed that ChHV5 from the green turtles in Taiwan were closest to the ChHV5 from Hawaii, Puerto Rico, and Sao Tome. For conservation of endangered sea turtles, ChHV5 should be considered an emerging virus, which threatens sea turtles in marine waters in Asia.

Bulletin of Marine Science↗
USGS1983

PROBLEMS AND METHODOLOGY OF THE PETROLOGIC ANALYSIS OF COAL FACIES.

This condensed synthesis gives a broad outline of the methodology of coal facies analysis, procedures for constructing sedimentation and geochemical formation curves, and micro- and macrostratigraphic analysis. The hypothetical coal bed profile has a 3-fold cycle of material characteristics. Based on studies of other similar profiles of the same coal bed, and on field studies of the sedimentary rock types and their facies interpretation, one can assume that the 3-fold subdivision is of regional significance.

Conference Paper↗
USGS1983

SUBMICROSCOPIC ( less than 1 mu m) MINERAL CONTENTS OF VITRINITES IN SELECTED BITUMINOUS COAL BEDS.

An important aspect of the petrographic description of coal is the characterization of coal quality, including chemical attributes. For geologic investigations, data on the concentrations, distribution, and modes of occurrence of minor and trace elements provide a basis for reconstructing the probable geochemical environment of the swamp material that was converted into peat, and the geochemical conditions that prevailed during and subsequent to coalification. We have been using electron (EPMA) and proton (PIXE) microprobe analytical methods to obtain data on the chemical characteristics of specific coal constituents in their original associations within coal samples. The present study is aimed at evaluation of the nature of mineral occurrences and heterogeneous elemental concentrations within vitrinites. Vitrinites are usually the most abundant, and therefore most important, maceral group in bituminous coal. 8 refs.

Conference Paper↗
USGS1984

MICROCHARACTERIZATION OF ARSENIC- AND SELENIUM-BEARING PYRITE IN UPPER FREEPORT COAL, INDIANA COUNTY, PENNSYLVANIA.

Optical and scanning electron microscope as well as electron and proton microprobe techniques have been used in a detailed investigation of the modes of occurrence of arsenic and selenium in pyrite in Upper Freeport coal from the Homer City area, Indiana County, Pennsylvania. Polished blocks were prepared from columnar samples of the coal bed to represent particular zones continuously from top to bottom. Initial selection of zones to be studied was based on chemical analysis of bench-channel samples. Microprobe data indicate that the highest concentrations of arsenic (as great as 1. 5 wt. %) are apparently in solid solution in pyrite within a limited stratigraphic interval of the coal bed. Smaller amounts of arsenic and selenium (concentrations up to approximately 0. 1 and 0. 2 wt. % respectively) were detected at isolated points within pyrite grains in various strata of the coal bed.

Scanning Electron Microscopy↗
USGS1987

PROTON MICROPROBE ANALYSIS OF TRACE-ELEMENT VARIATIONS IN VITRINITES IN THE SAME AND DIFFERENT COAL BEDS.

The PIXE (proton-induced X-ray emission) microprobe can be used for nondestructive, in-situ analyses of areas as small as those analyzed by the electron microprobe, and has a sensitivity of detection as much as two orders of magnitude better than the electron microprobe. Preliminary studies demonstrated that PIXE provides a capability for quantitative determination of elemental concentrations in individual coal maceral grains with a detection limit of 1-10 ppm for most elements analyzed. Encouraged by the earlier results, we carried out the analyses reported below to examine trace element variations laterally (over a km range) as well as vertically (cm to m) in the I and J coal beds in the Upper Cretaceous Ferron Sandstone Member of the Mancos Shale in central Utah, and to compare the data with the data from two samples of eastern coals of Pennsylvanian age.

Scanning Micros↗