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Ecology of Greater Sage-Grouse in the Bi-State Planning Area Final Report, September 2007

Conservation efforts for greater sage-grouse (Centrocercus urophasianus), hereafter sage-grouse, are underway across the range of this species. Over 70 local working groups have been established and are implementing on-the-ground sage-grouse oriented conservation projects. Early on in this process, the California Department of Fish and Game (CDFG) recognized the need to join in these efforts and received funding from the U.S. Fish and Wildlife Service (USFWS) under the Candidate Species Conservation Program to help develop a species conservation plan for sage-grouse in the Mono County area. This conservation plan covers portions of Alpine, Mono, and Inyo counties in California and Douglas, Esmeralda, Lyon, and Mineral counties in Nevada. A concurrent effort underway through the Nevada Governor's Sage-grouse Conservation Team established Local Area Working Groups across Nevada and eastern California. The Mono County populations of sage-grouse were encompassed by the Bi-State Local Planning Area, which was comprised of six population management units (PMUs). The state agencies from California (CDFG) and Nevada (Nevada Department of Wildlife; NDOW) responsible for the management of sage-grouse agreed to utilize the process that had begun with the Nevada Governor's Team in order to develop local plans for conservation planning and implementation. Resources from the USFWS were applied to several objectives in support of the development of the Bi-State Local Area Sage-grouse Conservation Plan through a grant to the U.S. Geological Survey (USGS). Objectives included: (1) participate in the development of the Bi-State Conservation Plan, (2) compile and synthesize existing sage-grouse data, (3) document seasonal movements of sage-grouse, (4) identify habitats critical to sage-grouse, (5) determine survival rates and identify causal factors of mortality, (6) determine nest success and brood success of sage-grouse, and (7) identify sage-grouse lek sites. Progress reports completed in 2004 and 2005 addressed each of the specific objectives and this final report focuses on the biological information gathered in support of local conservation efforts. Participation in the development of the Bi-State Local Area Conservation Plan was accomplished on multiple scales. Beginning in the fall of 2002, USGS personnel began participating in meetings of local stakeholders involved in the development of a sage-grouse conservation plan for the Bi-State planning area. This included attendance at numerous local PMU group meetings and field trips as well as participating on the technical advisory committee (TAC) for the Bi-State group. Whenever appropriate, ongoing results and findings regarding sage-grouse ecology in the local area were incorporated into these working group meetings. In addition, the USGS partnered with CDFG to help reorganize one of the local PMU groups (South Mono) and edited that portion of the Bi-State plan. The USGS also worked closely with CDFG to draft a description of the state of knowledge for sage-grouse genetic information for inclusion in the Bi-State Conservation Plan. The first edition of the Bi-State Conservation Plan for Greater Sage-Grouse was completed in June 2004 (Bi-State Sage-grouse Conservation Team 2004). This report is organized primarily by PMU to facilitate the incorporation of these research findings into the individual PMU plans that compose the Bi-State plan. Information presented in this report was derived from over 7,000 radio-telemetry locations obtained on 145 individual sage-grouse during a three year period (2003-2005). In addition, we collected detailed vegetation measurements at over 590 habitat sampling plots within the study area including canopy cover, shrubs, forbs, and grasses diversity. Vegetation data collection focused on sage-grouse nests, and brood-use areas. Additionally we collected data at random sites to examine sage-grouse habitat relationships within the study area. The majori

Open-File Report

Methods for estimating magnitude and frequency of floods in Arizona, developed with unregulated and rural peak-flow data through water year 2010

Flooding is among the worst natural disasters responsible for loss of life and property in Arizona, underscoring the importance of accurate estimation of flood magnitude for proper structural design and floodplain mapping. Twenty-four years of additional peak-flow data have been recorded since the last comprehensive regional flood frequency analysis conducted in Arizona. Periodically, flood frequency estimates and regional regression equations must be revised to maintain the accurate estimation of flood frequency and magnitude. Annual peak-flow data collected through water year 2010 were compiled from 448 unregulated streamflow-gaging stations, hereafter referred to as streamgages, in Arizona having a minimum of 10 years of record. Flood frequency estimates were first computed with station (or at-site) skew using the Expected Moments Algorithm with a multiple Grubbs-Beck test to identify multiple potentially influential low flows to fit a Pearson Type III distribution. Next, a multiple step Bayesian least-squares-regression approach was used to determine a new statewide regional skew of −0.09. No basin characteristics analyzed were statistically significant in explaining the variation in skew and as a result, the constant model was chosen as the best regional skew model for the Arizona study area. The mean square error used in Bulletin 17B (B17B) of the Interagency Advisory Committee on Water Data is used to describe the precision of the regional skew. The constant model had a mean square error equal to 0.08, which corresponds to an effective record length of 85 years. This is a marked improvement over a previous Arizona regional skew analysis, with a reported mean square error of 0.31, for a corresponding effective record length of around 17 years. Thus the new regional model had almost five times the information content (as measured by effective record length) of that calculated in USGS Water Supply Paper 2433, published in 1997, or the value of 0.302 reported in the B17B generalized skew map. The flood frequency estimates were recalculated using a weighted skew of the station and regional skew. Station flood frequency estimates for each streamgage are presented for the 50-, 20-, 10-, 4-, 2-, 1-, 0.5-, and 0.2-percent annual exceedance probabilities. Geographical information systems were used to compute basin characteristic information for each streamgage for the purpose of developing regional equations to estimate flood statistics at ungaged basins. Five hydrologic flood regions in Arizona were defined in a multivariate regionalization process based on mean basin elevation, mean annual precipitation, and soil permeability. A regional generalized least-squares-regression analysis was used to develop five sets of equations from 344 nonredundant streamgages, corresponding to five regions, for estimating the 50-, 20-, 10-, 4-, 2-, 1-, 0.5-, and 0.2-percent annual exceedance probabilities at ungaged basins in Arizona. The regression equations developed for these five regions were based on one or more of the statistically significant explanatory variables: drainage area, mean basin elevation, and mean annual precipitation. Average standard errors of prediction for the regression regions for the five regions ranged from 27 to 122 percent and the pseudo-coefficients of determination (pseudo-R 2 ), a measure of the proportion of peak-flow variation that is explained by the basin characteristics, ranged from 68 to 98 percent. Regression equations for Central Highlands (region 4) had the lowest model error and the greatest pseudo-R 2 metrics. The equations for Colorado Plateau (region 2) regression equations generally had greater model error and lower pseudo-R 2 metrics. The improvement of regional regression equation model error and pseudo-R 2 metrics was related to higher numbers of streamgages, longer period of record, and even spatial coverage within a region. The regional regression equations were integrated into the U.S. Geological Survey’s StreamStats program. The StreamStats program is a national map-based web application that allows the public to easily access published flood frequency and basin characteristic statistics. The interactive web application allows a user to select a point within a watershed (gaged or ungaged) and retrieve flood-frequency estimates derived from the current regional regression equations and geographic information system data within the selected basin. StreamStats provides users with an efficient and accurate means for retrieving the most up to date flood frequency and basin characteristic data. StreamStats is intended to provide consistent statistics, minimize user error, and reduce the need for large datasets and costly geographic information system software.

Arizona

Runoff and water-quality characteristics of three Discovery Farms in North Dakota, 2008–16

Agricultural producers in North Dakota are aware of concerns about degrading water quality, and many of the producers are interested in implementing conservation practices to reduce the export of nutrients from their farms. Producers often implement conservation practices without knowledge of the water quality of the runoff from their farm or if conservation practices they may implement have any effect on water quality. In response to this lack of information, the U.S. Geological Survey, in cooperation with North Dakota State University Extension Service and in coordination with an advisory group consisting of State agencies, agricultural producers, and commodity groups, implemented a monitoring study as part of a Discovery Farms program in North Dakota in 2007. Three data-collection sites were established at each of three farms near Underwood, Embden, and Dazey, North Dakota. The purpose of this report is to describe runoff and water-quality characteristics using data collected at the three Discovery Farms during 2008–16. Runoff and water-quality data were used to help describe the implications of agricultural conservation practices on runoff and water-quality patterns. Runoff characteristics of monitoring sites at the three farms were determined by measuring flow volume and precipitation. Runoff at the Underwood farm monitoring sites generally was controlled by precipitation in the area, antecedent soil moisture conditions, and, after 2012, possibly by the diversion ditch constructed by the producer. Most of the annual runoff was in March and April each year during spring snowmelt. Runoff characteristics at the Embden farm are complex because of the mix of surface runoff and flow through two separate drainage tile systems. Annual flow volumes for the drainage tiles sites (sites E2 and E3) were several orders of magnitude greater than measured at the surface water site E1. Site E1 generally only had runoff briefly in March and April during spring snowmelt and during only a few large rain events throughout 2009–16. Flow was somewhat continuous at sites E2 and E3 throughout the year during years of increased precipitation, such as in 2010 and 2011. At Dazey farm, annual flow volumes at the most downstream site D3 for 2010–15 ranged from 88 acre-feet (2012) to 12,060 acre-feet (2010). The largest monthly runoff volumes at D1 (most upstream site; combination of data from site D1a [original site] and site D1b [relocated site]) and D3 were in March and April during spring snowmelt runoff and rain events. At Underwood farm, total ammonia and total phosphorus had the highest concentrations at the most upstream site (U1) and decreased sequentially at sites U2 and U3 downstream. Total ammonia and total phosphorus concentrations at the sites for Underwood farm also generally were higher than measured at sites for the Dazey and Embden farms. At Embden farm, nitrate plus nitrite concentrations were lowest at site E1 (surface-water site) and highest at sites E2 and E3 (drainage tile sites). Nitrate plus nitrite concentrations at sites E2 and E3 also were the highest among all the sites at all three farms. Median total nitrate plus nitrite concentrations for sites E1, E2, and E3 were 0.22, 13, and 10 milligrams per liter as nitrogen, respectively. Nutrient concentrations generally were greater at site D1 (most upstream site) compared to site D3 (most downstream site) at Dazey farm. Higher concentrations at site D1, which is farther upstream and closer to potential sources of nutrients, compared to lower concentrations at site D3, which is farther downstream and receives more runoff, indicates that dilution may be the reason concentrations decrease downstream. Annual loads for chloride at all three Underwood sites were the greatest in 2011 and the least in 2012, which coincided with years of the greatest and least annual flow volume, respectively. Total ammonia had a similar pattern at the three sites. Nitrate plus nitrite loads displayed a different pattern than chloride and total ammonia, indicating possible different sources. Chloride, total ammonia, total phosphorus, and suspended sediment were transported past site U1 mostly in March and the least from July through October. Monthly nitrate plus nitrite loads had a different pattern than the other constituents, indicating other possible sources such as fertilizer application in the surrounding cropland. Annual loads for Embden farm were considerably greater at sites E2 and E3 compared to site E1. Annual yields for all constituents also were substantially greater at sites E2 and E3 compared to site E1, mainly because of a combination of higher flow volumes and small contributing drainage areas at sites E2 and E3 compared to site E1. The greatest annual loads at Dazey farm site D3 for chloride, nitrate plus nitrite, and suspended sediment were in 2010 and 2011, and zero loads were estimated for 2012 because no flow was measured at the site. Mean monthly loads generally were greatest for most constituents in March and April at sites D1 and D3 except for suspended sediment that had the greatest monthly loads in May. To mitigate runoff and water-quality effects of their operations, the producers implemented various agricultural conservation practices before and during the Discovery Farms monitoring. Even though it was difficult to quantify the effects of the agricultural conservation practices implemented at the farms, the data collected from the Discovery Farms program provided a better understanding of some of the variables that affect runoff and water quality.

North Dakota

The National Climate Change and Wildlife Science Center annual report for 2013

In 2008, Congress created the National Climate Change and Wildlife Science Center (NCCWSC) within the U.S. Geological Survey (USGS). The center was formed to respond to the demands of natural resource managers for rigorous scientific information and effective tools for assessing and responding to climate change. Located at the USGS National Headquarters in Reston, Va., the NCCWSC has invested more than $93 million (through FY13) in cutting-edge climate change research and, in response to Secretarial Order No. 3289, established and is managing eight regional Department of Interior (DOI) Climate Science Centers (CSCs). In 2013: The DOI CSCs awarded nearly $7 million in funding to universities and other partners for climate and land-use change research. The scientific work of the NCCWSC-CSC enterprise moved toward projects that focus on ‘Science Infrastructure and Capacity Building’ and ‘Thematic Science’. A permanent director, David Helweg, Ph.D., was hired for the Pacific Islands CSC (PI CSC), completing the CSC leadership team. Staff scientists were hired at the Alaska (AK), Northeast (NE), and Southeast (SE) CSCs. Each of the eight CSCs completed the formation of regional Stakeholder Advisory Committees (SACs) and a national advisory committee (ACCCNRS) was created to oversee the NCCWSC-CSC enterprise. NCCWSC staff worked on creating a searchable public database on climate change vulnerability assessments. NCCWSC scientists authored articles in a special issue of the Ecological Society of America’s journal Frontiers in Ecology and the Environment, which was devoted to an assessment of climate change effects on biodiversity and ecosystems, and the consequences for people. Learn more about these achievements in The National Climate Change and Wildlife Science Center Annual Report for 2013 .

Circular

Occurrence of the gasoline additive MTBE in shallow ground water in urban and agricultural areas

Methyl tert -butyl ether (MTBE) is a volatile organic compound (VOC) derived from natural gas that is added to gasoline either seasonally or year round in many parts of the United States to increase the octane level and to reduce carbon monoxide and ozone levels in the air. In 1993, production of MTBE ranked second among all organic chemicals manufactured in the United States. Currently, the U.S. Environmental Protection Agency (EPA) tentatively classifies MTBE as a possible human carcinogen. Health complaints related to MTBE in the air were first reported in Fairbanks, Alaska in November 1992 when about 200 residents reported problems such as headaches, dizziness, eye irritation, burning of the nose and throat, disorientation, and nausea. Similar health complaints have been registered in Anchorage, Alaska; Missoula, Montana; Milwaukee, Wisconsin; and New Jersey. As part of the U.S. Geological Survey’s National Water-Quality Assessment (NAWQA) Program, concentrations of 60 VOCs were measured in samples from 211 shallow wells in 8 urban areas and 524 shallow wells in 20 agricultural areas. Chloroform and MTBE were the two most frequently detected VOCs. MTBE was detected in 27 percent of the urban wells and 1.3 percent of the agricultural wells. Concentrations ranged from less than the detection level of 0.2 μg/L (micrograms per liter) to as high as 23,000 μg/L. When detected, the median concentration of MTBE was 0.6 μg/L. MTBE was most frequently detected in shallow ground water in Denver, Colorado and urban areas in New England. In Denver, 79 percent of the samples from shallow urban wells had detectable concentrations of MTBE and in New England, 37 percent of the samples from urban wells had detectable concentrations. Only 3 percent of the wells sampled in urban areas had concentrations of MTBE that exceeded 20 μg/L, which is the estimated lower limit of the EPA draft drinking water health advisory level. Contaminant concentrations below the health advisory are not expected to cause any adverse effects over a lifetime of exposure. MTBE is on the EPA’s Drinking Water Priority List, which means it is a possible candidate for future regulation.

Fact Sheet

Estimating the magnitude of peak flows for streams in Kentucky for selected recurrence intervals

This report gives estimates of, and presents techniques for estimating, the magnitude of peak flows for streams in Kentucky for recurrence intervals of 2, 5, 10, 25, 50, 100, 200, and 500 years. A flowchart in this report guides the user to the appropriate estimates and (or) estimating techniques for a site on a specific stream. Estimates of peak flows are given for 222 U.S. Geological Survey streamflow-gaging stations in Kentucky. In the development of the peak-flow estimates at gaging stations, a new generalized skew coefficient was calculated for the State. This single statewide value of 0.011 (with a standard error of prediction of 0.520) is more appropriate for Kentucky than the national skew isoline map in Bulletin 17B of the Interagency Advisory Committee on Water Data. Regression equations are presented for estimating the peak flows on ungaged, unregulated streams in rural drainage basins. The equations were developed by use of generalized-least-squares regression procedures at 187 U.S. Geological Survey gaging stations in Kentucky and 51 stations in surrounding States. Kentucky was divided into seven flood regions. Total drainage area is used in the final regression equations as the sole explanatory variable, except in Regions 1 and 4 where main-channel slope also was used. The smallest average standard errors of prediction were in Region 3 (from -13.1 to +15.0 percent) and the largest average standard errors of prediction were in Region 5 (from -37.6 to +60.3 percent). One section of this report describes techniques for estimating peak flows for ungaged sites on gaged, unregulated streams in rural drainage basins. Another section references two previous U.S. Geological Survey reports for peak-flow estimates on ungaged, unregulated, urban streams. Estimating peak flows at ungaged sites on regulated streams is beyond the scope of this report, because peak flows on regulated streams are dependent upon variable human activities.

Kentucky

Health-Based Screening Levels and their Application to Water-Quality Data

To supplement existing Federal drinking-water standards and guidelines, thereby providing a basis for a more comprehensive evaluation of contaminant-occurrence data in a human-health context, USGS began a collaborative project in 1998 with USEPA, the New Jersey Department of Environmental Protection, and the Oregon Health & Science University to calculate non-enforceable health-based screening levels. Screening levels were calculated for contaminants that do not have Maximum Contaminant Level values using a consensus approach that entailed (1) standard USEPA Office of Water methodologies (equations) for establishing Lifetime Health Advisory (LHA) and Risk-Specific Dose (RSD) values for the protection of human health, and (2) existing USEPA human-health toxicity information.

Fact Sheet

Volcano Hazards Program

Diagram of common volcano hazards. The U.S. Geological Survey Volcano Hazards Program (VHP) monitors unrest and eruptions at U.S. volcanoes, assesses potential hazards, responds to volcanic crises, and conducts research on how volcanoes work. When conditions change at a monitored volcano, the VHP issues public advisories and warnings to alert emergency-management authorities and the public. See http://volcanoes.usgs.gov/ to learn more about volcanoes and find out what's happening now.

General Information Product

Progress toward establishing a national assessment of water availability and use

The Omnibus Public Land Management Act of 2009 (Public Law 111-11) was passed into law on March 30, 2009. Subtitle F, also known as the SECURE Water Act, calls for the establishment of a "national water availability and use assessment program" within the U.S. Geological Survey (USGS). A major driver for this recommendation was that national water availability and use have not been comprehensively assessed since 1978. This report fulfills a requirement to report to Congress on progress in implementing the national water availability and use assessment program, also referred to as the National Water Census. The SECURE Water Act authorized \$20 million for each of fiscal years (FY) 2009 through 2023 for assessment of national water availability and use. The first appropriation for this effort was \$4 million in FY 2011, followed by an appropriation of \$6 million in FY 2012. The National Water Census synthesizes and reports information at the regional and national scales, with an emphasis on compiling and reporting the information in a way that is useful to states and others responsible for water management and natural-resource issues. The USGS works with Federal and non-Federal agencies, universities, and other organizations to ensure that the information can be aggregated with other types of water-availability and socioeconomic information, such as data on food and energy production. To maximize the utility of the information, the USGS coordinates the design and development of the effort through the Federal Advisory Committee on Water Information. A National Water Census is a complex undertaking, particularly because there are major gaps in the information needed to conduct such an assessment. To maximize progress, the USGS engaged stakeholders in a discussion of priorities and leveraged existing studies and program activities to enhance efforts toward the development of a National Water Census.

Circular

Occurrence and distribution of volatile organic compounds in drinking water supplied by community water systems in the Northeast and Mid-Atlantic regions of the United States, 1993-98

Data on volatile organic compounds (VOCs) in drinking water supplied by community water systems (CWSs) are available for 12 Northeast and Mid-Atlantic States from 1993-98. The data are from 2,110 CWSs representing a 20 percent random selection of the total 10,749 active CWSs in the region. The data were collected for compliance monitoring under the Safe Drinking Water Act from both surface-and ground-water sources and largely represent samples of finished drinking water collected prior to distribution. Overall, 39 percent of the 2,110 randomly selected CWSs reported a detection of one or more VOCs at or above 1.0 μg/L (micrograms per liter). Although differences in analytical coverage complicate comparisons, in the 1,543 CWSs with THM data at or above 1.0 μg/L, 42 percent reported an occurrence of one or more THMs. The common detection of THMs in finished drinking water probably is related to their formation through the chlorination of drinking-water supplies. Comparatively, solvents, the next most frequently detected VOC group, were reported in 9.8 percent of 2,097 CWSs with solvent data at or above 1.0 μg/L, and gasoline components were detected in 9.0 percent of 2,098 CWSs with data at or above 1.0 μg/L. Individually, the THMs—chloroform, bromodichloromethane, chlorodibromomethane, and bromoform—were the most frequently detected VOCs ranging from 33 to 8 percent. The most frequently detected non-THM compound was methyl tert-butyl ether, which was identified in 8 percent of CWSs. Of the 2,110 randomly selected CWSs, 6 percent had at least one sample with one or more VOCs with a concentration above a Maximum Contaminant Level, Health Advisory, or Drinking-Water Advisory. VOCs were more frequently detected in drinking water from systems that are supplied by surface-water sources, or both surface-and ground-water sources, than in systems that are supplied exclusively by ground water, and from systems serving very large and large populations (serving <3,300 people) compared to systems serving medium and small populations (serving <3,300 people).

Fact Sheet

Assessment of Water-Quality Conditions in Fivemile Creek in the Vicinity of the Fivemile Creek Greenway, Jefferson County, Alabama, 2003-2005

The watershed of Fivemile Creek (FMC), a tributary to the Locust Fork of the Black Warrior River, is located north of Birmingham, Alabama. Areas that have been previously coal-mined border the creek, and portions of the upper watershed have been and are currently (2007) being used for industrial and urban uses. The U.S. Geological Survey (USGS), in cooperation with the City of Tarrant, the Freshwater Land Trust, and the Jefferson County Commission, conducted a water-quality assessment of 12 sites along FMC during 2003?2005. Water samples were analyzed for basic physical and chemical properties and concentrations of major ions, nutrients, fecal indicator bacteria, organic wastewater compounds, pesticides, trace elements, and semivolatile organic compounds. Streambed-sediment samples were analyzed for concentrations of trace elements and semivolatile organic compounds. Benthic invertebrate communities were evaluated for taxonomic composition and relation to water-quality conditions. Nutrient concentrations in the FMC watershed reflect the influences of natural and anthropogenic sources. Concentrations of total nitrogen in all samples and total Kjeldahl nitrogen in at least one sample each collected from FMC at Hewitt Park, FMC below Springdale Road, FMC at Lewisburg, FMC near Republic, FMC at Brookside, and FMC at Linn Crossing exceeded U.S. Environmental Protection Agency (USEPA) ecoregion nutrient criteria. Total phosphorus concentrations in about 58 percent of all samples were above the ecoregion nutrient criteria. Concentrations of chlorophyll a, an indicator of algal biomass, in the FMC watershed were below the appropriate USEPA ecoregion criteria. Fecal indicator bacteria concentrations occasionally exceeded criteria established by the Alabama Department of Environmental Management (ADEM) and the USEPA to protect human health and aquatic life. Median fecal-coliform concentrations equaled or exceeded USEPA criteria at four of the six sites with multiple samples. Maximum Escherichia coli (E. coli) concentrations usually occurred during high-flow conditions and exceeded the single-sample criterion for infrequently-used whole-body contact (576 colonies per 100 milliliters) at all but one site. Median E. coli concentrations for two of the seven sites with multiple samples exceeded USEPA criteria. Twenty-nine samples were collected from sites along FMC and analyzed by the USGS National Water Quality Laboratory for the presence of 57 organic wastewater compounds. Forty-six of the 57 organic wastewater compounds, representing all 11 general-use categories, were detected in samples from FMC. All detections of organic wastewater compounds were estimated below laboratory reporting limits except for several detections of the herbicide bromacil. Herbicides accounted for approximately 62 percent of the number of pesticide detections in the FMC study area. Two herbicides, atrazine and simazine, were detected most frequently, in 100 percent of the surface-water samples. Fipronil sulfide was the most commonly detected insecticide-derived compound, occurring in 52 percent of the surface-water samples. Concentrations of one insecticide, dieldrin, exceeded the USEPA?s health advisory level for drinking water in one sample at FMC at Hewitt Park and in one sample at FMC below Springdale Road. Concentrations of carbaryl in two samples and malathion in one sample exceeded aquatic-life criteria. Only a few trace element concentrations measured in FMC exceeded established standards or criteria. Some concentrations of aluminum and manganese were above secondary drinking-water standards. One cadmium concentration and three selenium concentrations measured at FMC at Lewisburg exceeded ADEM chronic aquatic-life criteria. Streambed-sediment samples were collected at seven sites along FMC, and analyzed for selected semivolatile organic compounds and trace elements. Forty-nine of 98 semivolatile organic compounds were detected in stre

Scientific Investigations Report

Occurrence and distribution of pesticide compounds in surface water of the Santa Ana basin, California, 1998-2001

A study of the occurrence and distribution of pesticide compounds in surface water of the highly urbanized Santa Ana Basin, California, was done as part of the U.S. Geological Survey's National Water-Quality Assessment Program (NAWQA). One-hundred and forty-eight samples were collected from 23 sites, and analyzed for pesticide compounds during the study period from November 1998 to September 2001. Sixty-six different pesticide compounds were detected at varying frequencies and concentrations, and one or more pesticides were detected in 92 percent of the samples. All pesticide concentrations were below maximum levels permitted in drinking water. However, two compounds-diazinon and diuron-exceeded nonenforceable drinking water health-advisory levels in at least one stream sample, and five compounds exceeded guidelines to protect aquatic life-carbaryl, chlorpyrifos, diazinon, lindane, and malathion. Twenty-two pesticide compounds were detected in at least 25 percent of the samples collected from any one fixed site. These are identified as 'major' pesticide compounds and are emphasized in this report. The degree to which pesticides were used in the basin, as well as their physical-chemical properties, are important explanatory factors in stream pesticide occurrence, and most pesticides probably enter streams with urban runoff. Stormflow substantially increases urban runoff, and storm effects on stream pesticide concentrations sometimes persist for several days or weeks after the storm. Water sources other than urban runoff also deliver pesticide compounds to surface water in the basin. For example, atrazine may enter streams in gaining reaches where ground water carries high loads as a result of historical use in the basin. Also, the data suggest that lindane, and perhaps bromacil, are present in treated wastewater, the predominant source of water to streams in the Santa Ana Basin.

Scientific Investigations Report

A preliminary assessment of the occurrence and possible sources of MTBE in ground water of the United States, 1993-94

The 1990 Clean Air Act Amendments require fuel oxygenates to be added to gasoline used in some metropolitan areas to reduce atmospheric concen- trations of carbon monoxide or ozone. Methyl tert-butyl ether (MTBE), is the most commonly used fuel oxygenate and is a relatively new gasoline additive. Nevertheless, out of 60 volatile organic chemicals analyzed, MTBE was the second most frequently detected chemical in samples of shallow ambient ground water from urban areas that were collected during 1993-94 as part of the U.S. Geological Survey's National Water-Quality Assessment program. Samples were collected from 5 drinking-water wells, 12 springs, and 193 monitoring wells in urban areas. No MTBE was detected in drinking-water wells. At a reporting level of 0.2 ug/L (micrograms per liter), MTBE was detected most frequently in shallow ground water from urban areas (27 percent of 210 wells and springs sampled in 8 areas) as compared to shallow ground water from agricultural areas (1.3 percent of 549 wells sampled in 21 areas) or deeper ground water from major aquifers (1 percent of 412 wells sampled in 9 areas). Only 3 percent of the shallow wells sampled in urban areas had concentrations of MTBE that exceed 20 ug/L, which is the estimated lower limit of the U.S. Environmental Protection Agency draft drinking-water health advisory. Because MTBE is persistent and mobile in ground water, it can move from shallow to deeper aquifers with time. In shallow urban ground water, MTBE generally was not found with benzene, toluene, ethylbenzene, or xylenes (BTEX) compounds which commonly are associated with gasoline spills. This disassociation causes uncertainty as to the source of MTBE. Possible sources of MTBE in ground water include point sources, such as leaking storage tanks, and nonpoint sources, such as recharge of precipitation and storm-water runoff.

Open-File Report

Developing and implementing the use of predictive models for estimating water quality at Great Lakes beaches

Predictive models have been used at beaches to improve the timeliness and accuracy of recreational water-quality assessments over the most common current approach to water-quality monitoring, which relies on culturing fecal-indicator bacteria such as Escherichia coli (E. coli.) . Beach-specific predictive models use environmental and water-quality variables that are easily and quickly measured as surrogates to estimate concentrations of fecal-indicator bacteria or to provide the probability that a State recreational water-quality standard will be exceeded. When predictive models are used for beach closure or advisory decisions, they are referred to as “nowcasts.” During the recreational seasons of 2010-12, the U.S. Geological Survey (USGS), in cooperation with 23 local and State agencies, worked to improve existing nowcasts at 4 beaches, validate predictive models at another 38 beaches, and collect data for predictive-model development at 7 beaches throughout the Great Lakes. This report summarizes efforts to collect data and develop predictive models by multiple agencies and to compile existing information on the beaches and beach-monitoring programs into one comprehensive report. Local agencies measured E. coli concentrations and variables expected to affect E. coli concentrations such as wave height, turbidity, water temperature, and numbers of birds at the time of sampling. In addition to these field measurements, equipment was installed by the USGS or local agencies at or near several beaches to collect water-quality and metrological measurements in near real time, including nearshore buoys, weather stations, and tributary staff gages and monitors. The USGS worked with local agencies to retrieve data from existing sources either manually or by use of tools designed specifically to compile and process data for predictive-model development. Predictive models were developed by use of linear regression and (or) partial least squares techniques for 42 beaches that had at least 2 years of data (2010-11 and sometimes earlier) and for 1 beach that had 1 year of data. For most models, software designed for model development by the U.S. Environmental Protection Agency (Virtual Beach) was used. The selected model for each beach was based on a combination of explanatory variables including, most commonly, turbidity, day of the year, change in lake level over 24 hours, wave height, wind direction and speed, and antecedent rainfall for various time periods. Forty-two predictive models were validated against data collected during an independent year (2012) and compared to the current method for assessing recreational water quality-using the previous day’s E. coli concentration (persistence model). Goals for good predictive-model performance were responses that were at least 5 percent greater than the persistence model and overall correct responses greater than or equal to 80 percent, sensitivities (percentage of exceedances of the bathing-water standard that were correctly predicted by the model) greater than or equal to 50 percent, and specificities (percentage of nonexceedances correctly predicted by the model) greater than or equal to 85 percent. Out of 42 predictive models, 24 models yielded over-all correct responses that were at least 5 percent greater than the use of the persistence model. Predictive-model responses met the performance goals more often than the persistence-model responses in terms of overall correctness (28 versus 17 models, respectively), sensitivity (17 versus 4 models), and specificity (34 versus 25 models). Gaining knowledge of each beach and the factors that affect E. coli concentrations is important for developing good predictive models. Collection of additional years of data with a wide range of environmental conditions may also help to improve future model performance. The USGS will continue to work with local agencies in 2013 and beyond to develop and validate predictive models at beaches and improve existing nowcasts, restructuring monitoring activities to accommodate future uncertainties in funding and resources.

Great Lakes

Trip report: pilot study of factors linking watershed function and coastal ecosystem health in American Samoa

Coral reef resources in the territory of American Samoa face significant problems from overfishing, non-point source pollution, global warming, and continuing population growth and development. The islands are still relatively isolated relative to other parts of the Pacific and have managed to avoid some of the more devastating invasive species that have reached other archipelagoes. As a result, there are opportunities for collaborative and integrative research and monitoring programs to help restore and maintain biodiversity and functioning natural ecosystem in the archipelago. We found that the “Ridge to Reef” paradigm already exists in American Samoa, with a high degree of interagency cooperation and efficient use of limited resources already taking place in the Territory. USGS may be able to make contributions as a partner organization in the Coral Reef Advisory Group (CRAG) through deployment of sediment monitoring instrumentation to supplement stream monitoring by the American Samoa Environmental Protection Agency, by providing high resolution vegetation and land-use maps of main islands, by providing additional support to the American Samoa Department of Marine and Wildlife Resources and the National Park Service for monitoring of invasive species, by working with members of CRAG to initiate sediment transport studies on Samoan reefs, and by developing new projects on the effects of bacterial contamination and pollutants on coral reef physiology and demography.

Open-File Report

Estimating the magnitude of peak flows for streams in Maine for selected recurrence intervals

This report gives estimates of, and presents techniques for estimating, the magnitude of peak flows for streams in Maine for recurrence intervals of 2, 5, 10, 25, 50, 100, and 500 years. A flowchart in this report guides the user to the appropriate estimates and (or) estimating techniques for a site on a specific stream. Section 1, 'Estimates of peak flows and maximum recorded flows at USGS streamflow-gaging stations,' contains peak-flow estimates and the maximum recorded flows at 98 U.S. Geological Survey (USGS) streamflow-gaging stations. In the development of the peak-flow estimates at gaging stations, a new generalized skew coefficient was calculated for Maine. This single statewide value of 0.029 (with a standard error of prediction of 0.297) is more accurate for Maine than the national skew isoline map in Bulletin 17B of the Interagency Advisory Committee on Water Data. Two techniques are presented to estimate the peak flows for ungaged, unregulated streams in rural drainage basins. These two techniques were developed using generalized least squares regression procedures at 70 USGS gaging stations in Maine and eastern New Hampshire. Section 2, 'Estimating peak flows for ungaged, unregulated streams in rural drainage basins,' uses the final explanatory variables of drainage area and basin wetlands. The average standard error of prediction for the 100-year peak flow regression equation in section 2 was 48.6 percent to -32.7 percent. Drainage area was the only explanatory variable used in section 3, 'Estimating peak flows for ungaged, unregulated streams in rural drainage basins - Simplified technique.' The average standard error of prediction for the 100-year peak flow regression equation in section 3 was 80.3 percent to -44.5 percent. Section 4 of the report describes techniques for estimating peak flows for ungaged sites on gaged, unregulated streams in rural drainage basins. Section 5, 'Estimating peak flows for ungaged, unregulated streams in urbanized drainage basins,' describes regression equations for use when a drainage basin is urbanized. These urban regression equations come from a previous USGS nationwide study. As stated in section 6, because peak flows on regulated streams are dependent on variable human actions, estimating peak flows at ungaged sites on regulated streams is beyond the scope of this report.

Maine

Spatial variability of harmful algal blooms in Milford Lake, Kansas, July and August 2015

Cyanobacterial harmful algal blooms (CyanoHABs) tend to be spatially variable vertically in the water column and horizontally across the lake surface because of in-lake and weather-driven processes and can vary by orders of magnitude in concentration across relatively short distances (meters or less). Extreme spatial variability in cyanobacteria and associated compounds poses unique challenges to collecting representative samples for scientific study and public-health protection. The objective of this study was to assess the spatial variability of cyanobacteria and microcystin in Milford Lake, Kansas, using data collected on July 27 and August 31, 2015. Spatially dense near-surface data were collected by the U.S. Geological Survey, nearshore data were collected by the Kansas Department of Health and Environment, and open-water data were collected by U.S. Army Corps of Engineers. CyanoHABs are known to be spatially variable, but that variability is rarely quantified. A better understanding of the spatial variability of cyanobacteria and microcystin will inform sampling and management strategies for Milford Lake and for other lakes with CyanoHAB issues throughout the Nation. The CyanoHABs in Milford Lake during July and August 2015 displayed the extreme spatial variability characteristic of cyanobacterial blooms. The phytoplankton community was almost exclusively cyanobacteria (greater than 90 percent) during July and August. Cyanobacteria (measured directly by cell counts and indirectly by regression-estimated chlorophyll) and microcystin (measured directly by enzyme-linked immunosorbent assay [ELISA] and indirectly by regression estimates) concentrations varied by orders of magnitude throughout the lake. During July and August 2015, cyanobacteria and microcystin concentrations decreased in the downlake (towards the outlet) direction. Nearshore and open-water surface grabs were collected and analyzed for microcystin as part of this study. Samples were collected in the uplake (Zone C), midlake (Zone B), and downlake (Zone A) parts of the lake. Overall, no consistent pattern was indicated as to which sample location (nearshore or open water) had the highest microcystin concentrations. In July, the maximum microcystin concentration observed in each zone was detected at a nearshore site, and in August, maximum microcystin concentrations in each zone were detected at an open-water site. The Kansas Department of Health and Environment uses two guidance levels (a watch and a warning level) to issue recreational public-health advisories for CyanoHABs in Kansas lakes. The levels are based on concentrations of microcystin and numbers of cyanobacteria. In July and August, discrete water-quality samples were predominantly indicative of warning status in Zone C, watch status in Zone B, and no advisories in Zone A. Regression-estimated microcystin concentrations, which provided more thorough coverage of Milford Lake ( n =683–720) than discrete samples ( n =21–24), generally indicated the same overall pattern. Regardless of the individual agencies sampling approach, the overall public-health advisory status of each zone in Milford Lake was similar according to the Kansas Department of Health and Environment guidance levels.

Kansas

Target and suspect per- and polyfluoroalkyl substances in fish from an AFFF-impacted waterway

A major source of toxic per - and polyfluoroalkyl substances (PFAS) is aqueous film-forming foams (AFFF) used in firefighting and training at airports and military installations, however, PFAS have many additional sources in consumer products and industrial processes. A field study was conducted on fish tissues from three reaches of the Columbia Slough, located near Portland International Airport, OR, that are affected by AFFF and other PFAS sources. Fishes including largescale sucker ( Catostomus macrocheilus ), goldfish ( Carassius auratus ), and largemouth bass ( Micropterus salmoides ) were collected in 2019 and 2020. Fish blood, liver, and fillet (muscle) were analyzed for target and suspect PFAS by liquid chromatography high resolution mass spectrometry (LC-HRMS). Data were analyzed for patterns by fish species, tissue type, and river reach. Thirty-three out of 50 target PFAS and additional suspect compounds were detected at least once during the study, at concentrations up to 856 ng/g. Seven carboxylic acids (PFOA, PFNA, PFDA, PFUdA, PFDoA, PFTrDA, PFTeDA), three sulfonates (PFHxS, PFOS, PFDS), three electrofluorination-based compounds (FBSA, FHxSA, FOSA), and two fluorotelomer-based compounds (8:2 FTS, 10:2 FTS) were the most frequently detected compounds in all tissue types. The C6 (PFHxS) to C10 (PFDS) homologs were detected with PFOS and FHxSA at concentrations 1–3 orders of magnitude greater than the other PFAS detected. This is the first report of Cl-PFOS, FPeSA, and FHpSA detected in fish tissue. In all fish samples, fillet concentrations of PFAS were the lowest, followed by liver, and blood concentrations of PFAS were the highest. Differences in PFAS concentrations were driven primarily by tissue types and to a lesser extent fish species, but weakly by river reach. The Oregon Health Authority modified an existing fish consumption advisory on the Columbia Slough to recommend no whole-body consumption of most fish to avoid elevated levels of PFOS in fish liver. Measured PFAS concentrations in fish tissues indicate the potential for adverse ecological effects.

Oregon