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Proposal and work plan to calibrate and verify a water-quality model to simulate effects of wastewater discharges to the Red River of the North at drought streamflow near Fargo, North Dakota, and Moorhead, Minnesota

This report presents a proposal for conducting a water-quality modeling study at drought streamflow, a detailed comprehensive plan for collecting the data, and an annual drought-formation monitoring plan. A 30.8 mile reach of the Red River of the North receives treated wastewater from plants at Fargo, North Dakota, and Moorhead, Minnesota, and streamflow from the Sheyenne River. The water-quality modeling study will evaluate the effects of continuous treated-wastewater discharges to the study reach at drought streamflow. The study will define hydraulic characteristics and reaeration and selected reaction coefficients and will calibrate and verity a model. The study includes collecting synoptic water-quality samples for various types of analyses at a number of sites in the study reach. Dye and gas samples will be collected for traveltime and reaeration measurements. Using the Lagrangian reference frame, synoptic water-quality samples will be collected for analysis of nutrients, chlorophyll a, alkalinity, and carbonaceous biochemical oxygen demand. Field measurements will be made of specific conductance, pH, air and water temperature, dissolved oxygen, and sediment oxygen demand. Two sets of water-quality data will be collected. One data set will be used to calibrate the model, and the other data set will be used to verity the model. The DAFLOW/BLTM models will be used to evaluate the effects of the treated wastewater on the water quality of the river. The model will simulate specific conductance, temperature, dissolved oxygen, carbonaceous biochemical oxygen demand, total nitrogen (organic, ammonia, nitrite, nitrate), total orthophosphorus, total phosphorus, and phytoplankton as chlorophyll a. The work plan identifies and discusses the work elements needed for accomplishing the data collection for the study. The work elements specify who will provide personnel, vehicles, instruments, and supplies needed during data collection. The work plan contains instructions for data collection; inventory lists of needed personnel, vehicles, instruments, and supplies; and examples of computations for determining quantities of tracer to be injected into the stream. The work plan also contains an annual drought-formation monitoring plan that includes a 9-month time line that specifies when essential planning actions must occur before actual project start up. Drought streamflows are rare. The annual drought-formation monitoring plan is presented to assist project planning by providing early warning that conditions are favorable to produce drought streamflow. The plan to monitor drought-forming conditions discusses the drought indices to be monitored. To establish a baseline, historic values for some of the drought indices for selected years were reviewed. An annual review of the drought indices is recommended.

Open-File Report↗

Summary of floods in the United States during 1967

This report describes the most outstanding floods in the United States during 1967. The two most destructive floods occurred in August in east-central Alaska and in September and October in southern Texas. In east-central Alaska, heavy rain on August 8-17 produced record-breaking floods near Fairbanks. Peak discharges on some streams in the area were from two to four times the 50-yea.r flood. Flood damage was estimated to have been $85 million, and six lives were lost. Torrential rains produced by Hurricane Beulah caused record-breaking floods on many streams in a 50,000-square-mile area in southern Texas and northeastern Mexico in September and October. As much as 25.5 inches of rain was measured at ESSA Weather Bureau stations in the period September 19-25. Major flooding occurred in the basins of the Guadalupe, San Antonio, Mission, Arkansas, and Nueces Rivers and in many small coastal basins in Texas ; on the Rio Grande and its floodways ; and in the Rio Alamo and Rio San Juan basins in Mexico. Peak discharges at several sites in Texas were more than three times the magnitude of a 50-year flood. Total damage in Texas due to wind, rain, stream flooding, sheet flow, ponding, and tidal flooding was $167 million. In addition to the two floods mentioned above, 27 others of lesser magnitude are considered important enough to be included in this annual flood summary.

Water Supply Paper↗

Estimation of upstream water use with Ohio’s StreamStats application

This report describes the analytical methods and results of a pilot study to enhance the Ohio StreamStats application by adding the ability to obtain water-use information for selected areas in the northeast quadrant of Ohio. Water-use estimates are determined in StreamStats through a simple multistep process. Water-use data used to develop the Ohio StreamStats water-use application were obtained from the Ohio Department of Natural Resources (ODNR) and 2010 countywide estimates of self-supplied domestic water use (hereafter referred to as “domestic water use”) compiled by the U.S. Geological Survey (USGS). With the exception of domestic water uses, monthly time series of reported water uses for 2005–2012 are used to calculate average monthly and average annual withdrawals. Domestic water use is estimated from the USGS 2010 countywide estimates, assuming that water use is distributed uniformly in space and time. Consumptive-use coefficients are used to estimate net withdrawals and facilitate computation of return flows. Temporary water-use registrations for hydraulic fracturing are tabulated separately from the other water uses. Water-use indices are computed by dividing average annual net withdrawals (with and without temporary registrations) by the mean October streamflow estimated with StreamStats. The water-use indices are intended to provide metrics of potential consumptive water use.

Scientific Investigations Report↗

Atmospheric wet deposition of trace elements to a suburban environment, Reston, Virginia, USA

Wet deposition from a suburban area in Reston, Virginia was collected during 1998 and analyzed to assess the anion and trace-element concentrations and depositions. Suburban Reston, approximately 26 km west of Washington, DC, is densely populated and heavily developed. Wet deposition was collected bi-weekly in an automated collector using trace-element clean sampling and analytical techniques. The annual volume-weighted concentrations of As, Cd, and Pb were similar to those previously reported for a remote site on Catoctin Mt., Maryland (70 km northwest), which indicated a regional signal for these elements. The concentrations and depositions of Cu and Zn at the suburban site were nearly double those at remote sites because of the influence of local vehicular traffic. The 1998 average annual wet deposition (μg m −2 yr −1 ) was calculated for Al (52,000), As (94), Cd (54), Cr (160), Cu (700), Fe (23,000), Mn (2000), Ni (240), Pb (440), V (430), and Zn (4100). The average annual wet deposition (meq m −2 yr −1 ) was calculated for H + (74), Cl − (8.5), NO 3 − (33), and SO 4 2− (70). Analysis of digested total trace-element concentrations in a subset of samples showed that the refractory elements in suburban precipitation comprised a larger portion of the total deposition of trace elements than in remote areas.

Virginia↗

Estimating monthly, annual, and low 7-day, 10-year streamflows for ungaged rivers in Maine

Regression equations to estimate monthly, annual, and low 7-day, 10-year (7Q10) streamflows were derived for rivers in Maine. The derived regression equations for estimating mean monthly, mean annual, median monthly, median annual, and low 7Q10 streamflows for ungaged rivers in Maine presented in this report supersede those derived in previous studies. Twenty-six U.S. Geological Survey streamflow-gaging stations on unregulated, rural rivers in Maine with 10 years or more of recorded streamflow were used to develop the regression equations. Ordinary least squares (OLS) regression techniques were used to select the explanatory variables (basin and climatic characteristics) that would appear in the final regression equations. OLS regression of all possible subsets was done with 62 explanatory variables for each of 27 response variables. Five explanatory variables were chosen for the final regression equations: drainage basin area, areal fraction of the drainage basin underlain by sand and gravel aquifers, distance from the coast to the drainage basin centroid, mean drainage basin annual precipitation, and mean drainage basin winter precipitation (the sum of mean monthly precipitation for December, January, and February). Generalized least-squares regression techniques were used to derive the final coefficients and measures of uncertainty for the regression equations. The forms of many of the derived regression equations indicate some physical, mechanistic processes. Drainage basin area is the most statistically important explanatory variable and appears in all derived regression equations. Monthly streamflows are related inversely to the distance from the coast to the drainage basin centroid during December, January, February, and March; that is, the closer a river basin is to the coast, the higher monthly streamflows are per unit drainage basin area during the winter. The relation reverses in May when higher streamflows are attributed to basins farther from the coast. These relations are consistent with colder, inland drainage basins storing more water in snowpack during the winter and releasing it in the spring. The monthly streamflows (and low 7Q10) during July, August, September, and October are related positively to areal fraction of the drainage basin underlain by sand and gravel aquifers. In general, sand and gravel aquifers underlying Maine river basins have excellent water-yielding characteristics and can provide water to streams during low-flow conditions in the summer and early fall.

Maine↗

High resolution study of petroleum source rock variation, Lower Cretaceous (Hauterivian and Barremian) of Mikkelsen Bay, North Slope, Alaska

Open File Report 01-480 was designed as a large format poster for the Annual Meeting of the American Association of Petroleum Geologists and the Society for Sedimentary Geology in Denver Colorado in June 2001. It is reproduced here in digital format to make widely available some unique images of mudstones. The images include description, interpretation, and Rock-Eval data that resulted from a high-resolution study of petroleum source rock variation of the Lower Cretaceous succession of the Mobil-Phillips Mikkelsen Bay State #1 well on the North Slope of Alaska. Our mudstone samples with Rock-Eval data plus color images are significant because they come from one of the few continuously cored and complete intervals of the Lower Cretaceous succession on the North Slope. This succession, which is rarely preserved in outcrop and very rarely cored in the subsurface, is considered to include important petroleum source rocks that have not previously been described nor explained Another reason these images are unique is that the lithofacies variability within mudstone dominated successions is relatively poorly known in comparison with that observed in coarser clastic and carbonate successions. They are also among the first published scans of thin sections of mudstone, and are of excellent quality because the sections are well made, cut perpendicular to bedding, and unusually thin, 20 microns. For each of 15 samples, we show a thin section scan (cm scale) and an optical photomicrograph (mm scale) that illustrates the variability present. Several backscattered SEM images are also shown. Rock-Eval data for the samples can be compared with the textures and mineralogy present by correlating sample numbers and core depth.

Open-File Report↗

Nutrient additions by waterfowl to lakes and reservoirs: predicting their effects on productivity and water quality

Lakes and reservoirs provide water for human needs and habitat for aquatic birds. Managers of such waters may ask whether nutrients added by waterfowl degrade water quality. For lakes and reservoirs where primary productivity is limited by phosphorus (P), we developed a procedure that integrates annual P loads from waterfowl and other external sources, applies a nutrient load-response model, and determines whether waterfowl that used the lake or reservoir degraded water quality. Annual P loading by waterfowl can be derived from a figure in this report, using the days per year that each kind spent on any lake or reservoir. In our example, over 6500 Canada geese ( Branta canadensis ) and 4200 ducks (mostly mallards, Anas platyrhynchos ) added 4462 kg of carbon (C), 280 kg of nitrogen (N), and 88 kg of P y -1 to Wintergreen Lake in southwestern Michigan, mostly during their migration. These amounts were 69% of all C, 27% of all N, and 70% of all P that entered the lake from external sources. Loads from all external sources totaled 840 mg P m -2 y -1 . Application of a nutrient load-response model to this concentration, the hydraulic load (0.25 m y -1 ), and the water residence time (9.7 y) of Wintergreen Lake yielded an average annual concentration of total P in the lake of 818 mg m -3 that classified the lake as hypertrophic. This trophic classification agreed with independent measures of primary productivity, chlorophyll- a , total P, total N, and Secchi disk transparency made in Wintergreen Lake. Our procedure showed that waterfowl caused low water quality in Wintergreen Lake.

Hydrobiologia↗

Method for Estimating Annual Atrazine Use for Counties in the Conterminous United States, 1992-2007

A method was developed to estimate annual atrazine use during 1992 to 2007 on sixteen crops and four agricultural land uses. For each year, atrazine use was estimated for all counties in the conterminous United States (except California) by combining (1) proprietary data from the Doane Marketing Research-Kynetec (DMRK) AgroTrak database on the mass of atrazine applied to agricultural crops, (2) county harvested crop acreage, by county, from the 1992, 1997, 2002, and 2007 Censuses of Agriculture, and (3) annual harvested crop acreage from National Agriculture Statistics Service (NASS) for non-Census years. DMRK estimates of pesticide use on individual crops were derived from surveys of major field crops and selected specialty crops in multicounty areas referred to as Crop Reporting Districts (CRD). The CRD-level atrazine-use estimates were disaggregated to obtain county-level application rates by dividing the mass (pounds) of pesticides applied to a crop by the acreage of that crop in the CRD to yield a rate per harvested acre. When atrazine-use estimates were not available for a CRD, crop, or year, an estimated rate was developed following a hierarchy of decision rules that checked first for the availability of a crop application rate from surveyed atrazine application rate(s) for adjacent CRDs for a specific year, and second, the rates from surveyed CRDs within for U.S. Department of Agriculture Farm Production Regions for a specific year or multiple years. The estimation method applied linear interpolation to estimate crop acreage for years when harvested acres for a crop and county were not reported in either the Census of Agriculture or the NASS database, but were reported by these data sources for other years for that crop and county. Data for atrazine use for the counties in California was obtained from farmers' reports of pesticide use collected and published by the California Department of Pesticide Regulation-Pesticide Use Reporting (DPR-PUR) because these data are more complete than DMRK survey data. National and state annual atrazine-use totals derived by this method were compared with other published pesticide-use estimates and were highly correlated. The method developed is designed to be applicable to other pesticides for which there are similar data; however, for some pesticides that are applied to specialty crops, fewer surveys are usually available to estimate application rates and there are a greater number of years with unreported crop acreage, potentially resulting in greater uncertainty in use

Scientific Investigations Report↗

North American Commission on Stratigraphic Nomenclature Report 12 – Revision of article 37, lithodemic units, of the North American Stratigraphic Code

At the 71st Annual Meeting of the North American Commission on Stratigraphic Nomenclature, 26 September, 2016, in Denver, Colorado, the Commission voted unanimously to accept the revision of Article 37 of the North American Stratigraphic Code (North American Commission on Stratigraphic Nomenclature, 2005), printed below. It replaces all older versions of this Article. An application for this revision (Easton et al. 2015) was published in Stratigraphy more than one year prior to the meeting; thus, the vote on this application for revision follows Article 21 of the Code.

Stratigraphy↗

Water Budgets for Coeur d'Alene Lake, Idaho, Water Years 2000-2005

The U.S. Geological Survey, in cooperation with the Idaho Department of Water Resources, calculated annual water budgets and a mean annual water budget for Coeur d'Alene Lake, Idaho, for water years 2000 through 2005. Mean annual inflow to Coeur d'Alene Lake, including precipitation, was about 167,110 million cubic feet. Mean annual outflow, including evaporation, but excluding wastewater effluent to the Spokane River, was about 167,850 million cubic feet. The amount of water lost from Coeur d'Alene Lake and the Spokane River to the Spokane Valley-Rathdrum Prairie aquifer was estimated at 7,250 million cubic feet. Mean annual precipitation into Coeur d'Alene Lake was 3,267 million cubic feet, which exceeded mean annual evaporation of 2,483 million cubic feet. Withdrawals directly from the lake and from wells within a 1,000 foot buffer of the lakeshore for domestic and municipal water uses were reported. However, only the estimate for the consumptive use part of the withdrawals, 265 million cubic feet, was considered in the budget. Mean annual change in lake storage resulted in a net loss of about 49 million cubic feet. The mean annual residual value was about -8,310 million cubic feet.

Scientific Investigations Report↗

Effects of Withdrawals on Ground-Water Levels in Southern Maryland and the Adjacent Eastern Shore, 1980-2005

Ground water is the primary source of water supply in most areas of Maryland?s Atlantic Coastal Plain, including Southern Maryland. The counties in this area are experiencing some of the most rapid growth and development in the State, resulting in an increased demand for ground-water production. The cooperative, basic water-data program of the U.S. Geological Survey and the Maryland Geological Survey has collected long-term observations of ground-water levels in Southern Maryland and parts of the Eastern Shore for many decades. Additional water-level observations were made by both agencies beginning in the 1970s, under the Power Plant Research Program of the Maryland Department of Natural Resources. These long-term water levels commonly show significant declines over several decades, which are attributed to ground-water withdrawals. Ground-water-level trends since 1980 in major Coastal Plain aquifers such as the Piney Point-Nanjemoy, Aquia, Magothy, upper Patapsco, lower Patapsco, and Patuxent were compared to water use and withdrawal data. Potentiometric surface maps show that most of the declines in ground-water levels can be directly related to effects from major pumping centers. There is also evidence that deep drawdowns in some pumped aquifers may be causing declines in adjacent, unpumped aquifers. Water-level hydrographs of many wells in Southern Maryland show linear declines in levels year after year, instead of the gradual leveling-off that would be expected as the aquifers equilibrate with pumping. A continual increase in the volumes of water being withdrawn from the aquifers is one explanation for why they are not reaching equilibrium. Although reported ground-water production in Southern Maryland has increased somewhat over the past several decades, the reported increases are often not large enough to account for the observed water-level declines. Numerical modeling simulations indicate that a steady, annual increase in the number of small wells could account for the observed aquifer behavior. Such wells, being pumped at rates below the minimum legal reporting threshold of 10,000 gallons per day, might be the source of the additional withdrawals. More detailed water-use data, especially from domestic wells, central-pivot irrigation wells, and other small users not currently reporting withdrawals to the State, may help to determine the cause of the aquifer declines.

Scientific Investigations Report↗

Evaluating CO2 and CH4 dynamics of Alaskan ecosystems during the Holocene Thermal Maximum

The Arctic has experienced much greater warming than the global average in recent decades due to polar amplification. Warming has induced ecological changes that have impacted climate carbon-cycle feedbacks, making it important to understand the climate and vegetation controls on carbon (C) dynamics. Here we used the Holocene Thermal Maximum (HTM, 11–9 ka BP, 1 ka BP = 1000 cal yr before present) in Alaska as a case study to examine how ecosystem Cdynamics responded to the past warming climate using an integrated approach of combining paleoecological reconstructions and ecosystem modeling. Our paleoecological synthesis showed expansion of deciduous broadleaf forest (dominated by Populus ) into tundra and the establishment of boreal evergreen needleleaf and mixed forest during the second half of the HTM under a warmer- and wetter-than-before climate, coincident with the occurrence of the highest net primary productivity, cumulative net ecosystem productivity, soil C accumulation and CH 4 emissions. These series of ecological and biogeochemical shifts mirrored the solar insolation and subsequent temperature and precipitation patterns during HTM, indicating the importance of climate controls on C dynamics. Our simulated regional estimate of CH 4 emission rates from Alaska during the HTM ranged from 3.5 to 6.4 Tg CH 4 yr −1 and highest annual NPP of 470 Tg C yr −1 , significantly higher than previously reported modern estimates. Our results show that the differences in static vegetation distribution maps used in simulations of different time slices have greater influence on modeled C dynamics than climatic fields within each time slice, highlighting the importance of incorporating vegetation community dynamics and their responses to climatic conditions in long-term biogeochemical modeling.

Alaska↗

Distribution and demography of coastal Cactus Wrens (Campylorhynchus brunneicapillus) in southern San Diego County, California — 2021 Data summary

We surveyed for coastal Cactus Wren ( Campylorhynchus brunneicapillus ) in 378 established plots in southern San Diego County in 2021, encompassing 3 genetic clusters (Otay, Lake Jennings, and Sweetwater/Encanto). Two surveys were completed at each plot between March 1 and July 31. Cactus Wrens were detected in 130 plots (34 percent of plots), remaining virtually the same as the percentage of plots occupied in 2020 (35 percent). There were 113 Cactus Wren territories detected across all survey plots in 2021, an increase from 109 in 2020. At least 86 percent of Cactus Wren territories were occupied by pairs, and 50 fledglings were observed in 2021. We observed 48 color-banded Cactus Wrens in 2021, 44 of which we could identify to individual. Adults of known age ranged from 2 to at least 7 years old. Adult Cactus Wrens moved, on average, 0.1 kilometers (maximum 0.5 kilometers) from their 2020 territories to their 2021 territories. No known-identity Cactus Wrens moved between genetic clusters from 2020 to 2021. Vegetation at Cactus Wren plots typically was dominated by coastal sage scrub shrubs, such as California sagebrush ( Artemisia californica ), California buckwheat ( Eriogonum fasciculatum ), lemonadeberry ( Rhus integrifolia ), and San Diego sunflower ( Bahiopsis laciniata ). Twenty-nine percent of plots contained blue elderberry ( Sambucus nigra ssp. caerulea ), and Cactus Wrens occupied proportionally more plots with elderberry than plots without elderberry. Very little dead or unhealthy cactus was observed within all survey plots, and the plots that were occupied by Cactus Wrens were likely to contain more healthy cactus than plots that were not occupied by Cactus Wrens. Thirteen percent of plots had 5 percent or less of the cactus crowded or overtopped by vines and shrubs. Although in 2020, Cactus Wrens occupied proportionally more plots with 5 percent or less of cactus crowded or overtopped by vines and shrubs, this pattern was not found in 2021. Non-native annual cover was 5 percent or less at 29 percent of plots and, unlike in 2020, Cactus Wrens appeared to occupy proportionally more plots with less non-native annual cover than plots with more than 5-percent annual cover.

California↗

Changes to Idaho's statewide surface-water quality monitoring program since 1995

In 1990, the U.S. Geological Survey (USGS), in cooperation with the Idaho Division of Environmental Quality (formerly Idaho Department of Health and Welfare, Division of Environmental Quality), implemented a statewide water- quality monitoring program in response to Idaho’s antidegradation policy as required by the Clean Water Act (CWA). The objective was to provide water-quality managers with a coordinated state- wide program to detect trends in surface-water quality. The program design included chemical analyses of water samples collected at 56 sites on the Bear, Clearwater, Kootenai, Pend Oreille, Salmon, Snake, and Spokane Rivers and their tributaries (fig. 1). Samples were collected every year (1990 through 1995) at 5 sites (annual sites), every other year at 19 sites (biennial sites), and every third year at 32 sites (triennial sites). Each year, 25 of the 56 sites were sampled. During water years 1990–95 (October 1, 1989, to September 30, 1995), samples were collected bimonthly. Onsite analyses consisted of discharge, specific conductance, pH, temperature, dissolved oxygen, bacteria (fecal coliform and fecal streptococci), and alkalinity. Laboratory analyses consisted of major ions, nutrients, trace elements, turbidity, and suspended sediment. Analytical results from the five annual sites sampled during water years 1990–93 are presented in a report by O’Dell and Berenbrock (1994).

Idaho↗

The 3D Elevation Program—Supporting New Mexico’s Economy

Introduction Federal, State, Tribal, and local entities managing lands in New Mexico have concerns about wildfire risk, wildlife habitat, and flood risk. Land managers in urban areas along the Rio Grande corridor and in the State’s rural northwest and southeast also have concerns about existing and developing roads, buildings, and other infrastructure. Federal, State, Tribal, and local organizations actively manage and monitor New Mexico’s water resources. Critical applications that meet the State’s management needs depend on light detection and ranging (lidar) data that provide a highly detailed three-dimensional (3D) model of the Earth’s surface and aboveground features. The 3D Elevation Program (3DEP) is managed by the U.S. Geological Survey in partnership with Federal, State, Tribal, U.S. territorial, and local agencies to acquire consistent lidar coverage at quality level 2 or better to meet the many needs of the Nation and New Mexico. The status of available and in-progress 3DEP baseline lidar data in New Mexico is shown. 3DEP baseline lidar data include quality level 2 or better, 1-meter or better digital elevation models, and lidar point clouds, and must meet the Lidar Base Specification version 1.2 or newer requirements. The National Enhanced Elevation Assessment identified user requirements and conservatively estimated that availability of lidar data would result in at least $9.32 million in new benefits annually to the State.

New Mexico↗

Storage requirements for Georgia streams

The suitability of a stream as a source of water supply or for waste disposal may be severely limited by low flow during certain periods. A water user may be forced to provide storage facilities to supplement the natural flow if the low flow is insufficient for his needs. This report provides data for evaluating the feasibility of augmenting low streamflow by means of storage facilities. It contains tabular data on storage requirements for draft rates that are as much as 60 percent of the mean annual flow at 99 continuous-record gaging stations, and draft-storage diagrams for estimating storage requirements at many additional sites. Through analyses of streamflow data, the State was divided into four regions. Draft-storage diagrams for each region provide a means of estimating storage requirements for sites on streams where data are scant, provided the drainage area, mean annual flow, and the 7-day, 10-year low flow are known or can be estimated. These data are tabulated for the 99 gaging stations used in the analyses and for 102 partial-record sites where only base-flow measurements have been made. The draft-storage diagrams are useful not only for estimating in-channel storage required for low-flow augmentation, but also can be used for estimating the volume of off-channel storage required to retain wastewater during low-flow periods for later release. In addition, these relationships can be helpful in estimating the volume of wastewater to be disposed of by spraying on land, provided that the water disposed of in this manner is only that for which streamflow dilution water is not currently available. Mean annual flow can be determined for any stream within the State by using the runoff map in this report. Low-flow indices can be estimated by several methods, including correlation of base-flow measurements with concurrent flow at nearby continuous-record gaging stations where low-flow indices have been determined.

Georgia↗

Snowpack chemistry at selected sites in northwestern Colorado during spring 1995

Samples of the alpine and subalpine snowpack were collected in and near the headwater basins of the Yampa River in northwestern Colorado during maximum annual accumulation of snowpack in spring 1995. Sampling protocol at seven selected sites at more than 2,500 meters above sea level divided the snowpack into two distinct strata to enable separate chemical analyses of upper and lower layers of the annual snow cover. These two layers correspond to the early snow season beginning in September until December 12, 1994, and the remainder of the season from January 1 until the sampling date in spring 1995. At one site these two strata were resampled at closely spaced intervals defining substrata to observe variance within the two strata dividing the snow season. Analytical results of snowpack chemistry are presented in support of investigations of seasonal effects on ion concentrations in the snowpack. Chemical concentrations of major anions and cations, dissolved organic carbon, and alkalinity; measured pH; calculated charge balance between anions and cations; the stable-sulfur isotope ratio (34S/32S); and summary statistics of chemical concentrations are tabulated. Sampling sites are plotted on a map of the area. Spatial distributions of the concentrations of the hydrogen, nitrate, and sulfate ions and stable- sulfur isotope ratios also are mapped. Several unusual, late-season, snowfall events occurred during April and May of 1995 after the snowpack was sampled at most of the seven sites in the study area. Consequently, a considerable fraction of the total annual snowpack was not sampled. At one site, the full snowpack was sampled again in June, after the late-spring storms, for comparison to the chemistry of the snowpack sampled earlier in April. Precipitation chemistry from a National Atmospheric Deposition Program (NADP) collector located near the site is presented for comparison of the chemistry of the late-season snow to that of the typical annual snowpack season.

Open-File Report↗