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Heat as a tool for studying the movement of ground water near streams

Stream temperature has long been recognized as an important water quality parameter. Temperature plays a key role in the health of a stream’s aquatic life, both in the water column and in the benthic habitat of streambed sediments. Many fish are sensitive to temperature. For example, anadromous salmon require specific temperature ranges to successfully develop, migrate, and spawn [see Halupka and others, 2000]. Metabolic rates, oxygen requirements and availability, predation patterns, and susceptibility of organisms to contaminants are but a few of the many environmental responses regulated by temperature. Hydrologists traditionally treated streams and ground water as distinct, independent resources to be utilized and managed separately. With increasing demands on water supplies, however, hydrologists realized that streams and ground water are parts of a single, interconnected resource [see Winter and others, 1998]. Attempts to distinguish these resources for analytical or regulatory purposes are fraught with difficulty because each domain can supply (or drain) the other, with attendant possibilities for contamination exchange. Sustained depletion of one resource usually results in depletion of the other, propagating adverse effects within the watershed. An understanding of the interconnections between surface water and ground water is therefore essential. This understanding is still incomplete, but receiving growing attention from the research community. Exchanges between streams and shallow ground-water systems play a key role in controlling temperatures not only in streams, but also in their underlying sediments. As a result, analyses of subsurface temperature patterns provide information about surface-water/ground-water interactions. Chemical tracers are commonly used for tracing flow between streams and ground water. Introduction of chemical tracers in near-stream environments is, however, limited by real and perceived issues regarding introduced contamination and practical constraints. As an alternative, naturally occurring variations in temperature can be used to track (or trace) the heat carried by flowing water. The hydraulic transport of heat enables its use as a tracer. Differences between temperatures in the stream and surrounding sediments are now being analyzed to trace the movement of ground water to and from streams. As shown in the subsequent chapters of this circular, tracing the transport of heat leads to a better understanding of the magnitudes and mechanisms of stream/ground-water exchanges, and helps quantify the resulting effects on stream and streambed temperatures. Chapter 1 describes the general principals and procedures by which the natural transport of heat can be utilized to infer the movement of subsurface water near streams. This information sets the foundation for understanding the advanced applications in chapters 2 through 8. Each of these chapters provides a case study, using heat tracing as a tool, of interactions between surface water and ground water for a different location in the western United States. Technical details of the use of heat as an environmental tracer appear in appendices.

Circular↗

Some aspects of U.S. Geological Survey activities related to the effects of contaminants on water resources

The U.S. Geological Survey 's water resources programs are supported by direct annual appropriations from Congress, the Federal-State Cooperative Program (50:50 matching of funds), and by funds provided by other Federal agencies. For fiscal year 1987, total obligations exceeded $250 million for activities in every State, Puerto Rico, and several territories in cooperation with nearly 1,000 local, State, regional, and other Federal agencies. The quality of the ground and surface waters has been of concern to the Geological Survey from the time it was established. During the past few years, water resources contamination has received highest priority consideration and a variety of investigations and research are ongoing to obtain an improved understanding of the Nation 's water quality and the factors affecting it. This report presents information on program priorities and discusses the coordinated activities focusing on the effects of contaminants on water resources. The report also describes a number of investigations and research activities in progress during fiscal years of 1986 and 1987, and provides guidance on how to obtain additional details. (Author 's abstract)

Open-File Report↗

Hydrology and geochemistry of aquifer and stream contamination related to acidic water in Pinal Creek basin near Globe, Arizona

Hydrologic and geochemical research has identified and characterized the physical and chemical processes that control the evolution and movement of metal contaminants in ground water beneath Miami Wash and lower Pinal Creek. The dissolution of calcite in the alluvial aquifer has slowed and neutralized part of the acidic plume, and the sorption of some metals such as nickel and copper to other solids in the subsurface has lowered concentrations of these metals in the ground water.

Arizona↗

Shifting species interactions in terrestrial dryland ecosystems under altered water availability and climate change

Species interactions play key roles in linking the responses of populations, communities, and ecosystems to environmental change. For instance, species interactions are an important determinant of the complexity of changes in trophic biomass with variation in resources. Water resources are a major driver of terrestrial ecology and climate change is expected to greatly alter the distribution of this critical resource. While previous studies have documented strong effects of global environmental change on species interactions in general, responses can vary from region to region. Dryland ecosystems occupy more than one-third of the Earth's land mass, are greatly affected by changes in water availability, and are predicted to be hotspots of climate change. Thus, it is imperative to understand the effects of environmental change on these globally significant ecosystems. Here, we review studies of the responses of population-level plant-plant, plant-herbivore, and predator-prey interactions to changes in water availability in dryland environments in order to develop new hypotheses and predictions to guide future research. To help explain patterns of interaction outcomes, we developed a conceptual model that views interaction outcomes as shifting between (1) competition and facilitation (plant-plant), (2) herbivory, neutralism, or mutualism (plant-herbivore), or (3) neutralism and predation (predator-prey), as water availability crosses physiological, behavioural, or population-density thresholds. We link our conceptual model to hypothetical scenarios of current and future water availability to make testable predictions about the influence of changes in water availability on species interactions. We also examine potential implications of our conceptual model for the relative importance of top-down effects and the linearity of patterns of change in trophic biomass with changes in water availability. Finally, we highlight key research needs and some possible broader impacts of our findings. Overall, we hope to stimulate and guide future research that links changes in water availability to patterns of species interactions and the dynamics of populations and communities in dryland ecosystems.

Biological Reviews↗

Response to comment on “Persistence of pharmaceutical compounds and other organic wastewater contaminants in a conventional drinking-water-treatment plant”

The U.S. Geological Survey (USGS) and the Centers for Disease Control thank Dr. Till for her comments concerning our research ( Till, 2005 ) and welcome the opportunity to respond. The primary objective of our study was to evaluate the potential for organic wastewater-related contaminants (OWCs), including pharmaceuticals, to survive a conventional drinking-water-treatment process and persist in potable-water supplies ( Stackelberg et al., 2004 ). Our study was supported by two USGS laboratories: the National Water Quality Laboratory (NWQL), which provided the HPLC/ESI-MS and CLLE GC/MS data and the Ocala Water Quality and Research Laboratory (OWQRL), which provided the LC/MS data ( Stackelberg et al., 2004 ). Although discussed as distinct techniques by Dr. Till and indicated by differing acronyms to distinguish the laboratories producing the data, as described in our paper, the two LC/MS methods are very similar; they consist of a solid-phase extraction method with analysis of the extract produced using high-performance liquid chromatography coupled to an electrospray ionization mass spectrometer operated in the positive mode. The NWQL and OWQRL report ‘trace’ and ‘ultratrace’ determinations of analytes that provide significant benefit for describing the presence and fate of low-level contaminants. For mass spectral methods, an analyte is qualitatively identified by its retention time on the chromatographic column as well as the presence of two or more confirming ions with area ratios that match that of the reference standard compounds. Because of a recognized increased risk of false positives, these qualitative identification criteria are used in conjunction with abundant quality-control samples (detailed below) to confirm detection prior to making an estimate of the concentration. These qualitative identification criteria must be met before a compound is considered present (or detected) in a sample ( Oblinger Childress et al., 1999 ). When a compound has been qualitatively identified in an environmental sample (whether above or below its reporting level [RL]), it is assessed in context with associated field and laboratory blanks, field and laboratory replicates, and other data, such as appropriate laboratory reagent spikes. An environmental concentration is calculated only after determining that field and laboratory procedures did not contaminate the samples. The concentrations are then calculated from 5- to 8-point calibration curves using internal standard quantitation. Our lowest calibration standard is intentionally much lower than the RL, typically 10 times lower. The most abundant molecular or fragment ion is used for quantitation, and, for the two LC/MS methods, at least one, and where possible two, qualifier ions are used for confirmation. For the GC/MS method, with its greater degree of fragmentation, one quantitation and two qualifier ions are used. When any of the abovementioned qualitative identification criteria are not met, the analyte is considered not present and is reported as “less than” the RL.

Science of the Total Environment↗

Evaluating the suitability of large-scale datasets to estimate nitrogen loads and yields across different spatial scales

Decision makers are often confronted with inadequate information to predict nutrient loads and yields in freshwater ecosystems at large spatial scales. We evaluate the potential of using data mapped at large spatial scales (regional to global) and often coarse resolution to predict nitrogen yields at varying smaller scales (e.g., at the catchment and stream reach level). We applied the SPAtially Referenced Regression On Watershed attributes (SPARROW) model in three regions: the Upper Midwest part of the United States, New Zealand, and the Grande River Basin in southeastern Brazil. For each region, we compared predictions of nitrogen delivery between models developed using novel large-scale datasets and those developed using local-scale datasets. Large-scale models tended to underperform the local-scale models in poorly monitored areas. Despite this, large-scale models are well suited to generate hypotheses about relative effects of different nutrient source categories (point and urban, agricultural, native vegetation) and to identify knowledge gaps across spatial scales when data are scarce. Regardless of the spatial resolution of the predictors used in the models, a representative network of water quality monitoring stations is key to improve the performance of large-scale models used to estimate loads and yields. We discuss avenues of research to understand how this large-scale modelling approach can improve decision making for managing catchments at local scales, particularly in data poor regions.

Water Research↗

A Compilation of Provisional Karst Geospatial Data for the Interior Low Plateaus Physiographic Region, Central United States

Geospatial data needed to visualize and evaluate the hydrogeologic framework and distribution of karst features in the Interior Low Plateaus physiographic region of the central United States were compiled during 2004-2007 as part of the Ground-Water Resources Program Karst Hydrology Initiative (KHI) project. Because of the potential usefulness to environmental and water-resources regulators, private consultants, academic researchers, and others, the geospatial data files created during the KHI project are being made available to the public as a provisional regional karst dataset. To enhance accessibility and visualization, the geospatial data files have been compiled as ESRI ArcReader data folders and user interactive Published Map Files (.pmf files), all of which are catalogued by the boundaries of surface watersheds using U.S. Geological Survey (USGS) eight-digit hydrologic unit codes (HUC-8s). Specific karst features included in the dataset include mapped sinkhole locations, sinking (or disappearing) streams, internally drained catchments, karst springs inventoried in the USGS National Water Information System (NWIS) database, relic stream valleys, and karst flow paths obtained from results of previously reported water-tracer tests.

Data Series↗

Knowledge and understanding of dissolved solids in the Rio Grande–San Acacia, New Mexico, to Fort Quitman, Texas, and plan for future studies and monitoring

Availability of water in the Rio Grande Basin has long been a primary concern for water-resource managers. The transport and delivery of water in the basin have been engineered by using reservoirs, irrigation canals and drains, and transmountain-water diversions to meet the agricultural, residential, and industrial demand. In contrast, despite the widespread recognition of critical water-quality problems, there have been minimal management efforts to improve water quality in the Rio Grande. Of greatest concern is salinization (concentration of dissolved solids approaching 1,000 mg/L), a water-quality problem that has been recognized and researched for more than 100 years because of the potential to limit both agricultural and municipal use. To address the issue of salinization, water-resource managers need to have a clear conceptual understanding of the sources of salinity and the factors that control storage and transport, identify critical knowledge gaps in this conceptual understanding, and develop a research plan to address these gaps and develop a salinity management program. In 2009, the U.S. Geological Survey (USGS) in cooperation with the U.S. Army Corps of Engineers (USACE), New Mexico Interstate Stream Commission (NMISC), and New Mexico Environment Department (NMED) initiated a project to summarize the current state of knowledge regarding the transport of dissolved solids in the Rio Grande between San Acacia, New Mexico, and Fort Quitman, Texas. The primary objective is to provide hydrologic information pertaining to the spatial and temporal variability present in the concentrations and loads of dissolved solids in the Rio Grande, the source-specific budget for the mass of dissolved solids transported along the Rio Grande, and the locations at which dissolved solids enter the Rio Grande. Dissolved-solids concentration data provide a good indicator of the general quality of surface water and provide information on the factors governing salinization within the Rio Grande study area. The pattern in dissolved-solids concentrations along the Rio Grande is one of increasing concentration with increasing distance downstream from Elephant Butte and Caballo Reservoirs. The concentration of dissolved solids in the Rio Grande doubles (approximately 500 to 1,000 mg/L) from below Elephant Butte Reservoir to El Paso and increases by more than a factor of 5 (approximately 500 to 3,200 mg/L) from below Elephant Butte Reservoir to Fort Quitman. Marked increases in the concentration of dissolved solids commonly coincide with contributions from agricultural drains, wastewater-treatment plants, regional groundwater, and upward-flowing saline groundwater. The greatest factor, from the surface-water system, in controlling dissolved solids in the Rio Grande is the amount of water that is being transported or stored. Annual variation in streamflow is influenced primarily by climate (precipitation and evaporation) and management of Elephant Butte and Caballo Reservoirs (water storage and release cycles). Seasonal variation in streamflow within the Rio Grande study area is generally categorized generally as irrigation (March–September) and nonirrigation (October–February) seasons; with streamflow in the Rio Grande is highest during the irrigation season and lowest during the nonirrigation season. Dissolved-solids loads during the irrigation season decrease between Leasburg and Fort Quitman primarily because of irrigation diversions and losses to the underlying alluvial aquifer. Conversely, dissolved-solids loads during the nonirrigation season increase between Caballo Dam and Fort Quitman primarily because of the inflow of dissolved solids from agricultural drains, wastewater-treatment plants, and groundwater with elevated concentrations of dissolved solids. Many studies have mass-balance budgets that account for the mass of dissolved solids transported along the Rio Grande. Results from mass-balance budgets developed for dissolved solids indicated that (1) the inflow of saline groundwater, inflow of regional groundwater, and chemical reactions between mineral phases are the primary sources controlling dissolved solids in the Rio Grande, and (2) groundwater pumping and mineral precipitation are causing a net storage of dissolved solids in the Leasburg to El Paso and El Paso to Fort Quitman reaches of the Rio Grande. Looking forward, multiple water-resource managers from State and local agencies in New Mexico and Texas and Federal agencies formed the Rio Grande Salinity Management Coalition with the goal to reduce the amount of dissolved solids that are transported and stored in the Rio Grande study area. The recommendations for additional monitoring to assist the coalition are as follows: -Monitoring: Couple water-quality and streamflow monitoring in the Rio Grande and agricultural drains; perform groundwater-seepage investigations in the Rio Grande and major agricultural drains; nonitor groundwater water-quality conditions in the Mesilla and Hueco Basins. -Focused Hydrogeology Studies at Inflow Sources: Map dissolved-solids concentrations in the Rio Grande and underlying alluvial aquifer; perform hydrogeologic characterization of subsurface areas containing unusually high concentrations of dissolved solids. -Modeling of Dissolved Solids: Develop models to simulate the transport and storage of dissolved solids in both surface-water and groundwater systems.

New Mexico;Texas↗

Cold blood in warming waters: Effects of air temperature, precipitation, and groundwater on Gulf Sturgeon thermal habitats in a changing climate

Objective In a changing climate, the effects of air temperature, precipitation, and groundwater on water temperature and thermal habitat suitability for Gulf Sturgeon Acipenser desotoi , listed as threatened under the U.S. Endangered Species Act, are not well understood. Hence, we incorporated these factors into thermal habitat models to forecast how Gulf Sturgeon may be affected by wide‐ranging climate change scenarios in 2024–2074. Methods Using data from the Choctawhatchee River, Florida, we developed precipitation‐ and groundwater‐corrected air–water temperature models, compared their accuracy with that of conventional air–water temperature models used in fisheries management, and projected future Gulf Sturgeon thermal habitat suitability for normal physiological functioning and fieldwork (i.e., population sampling and telemetry surgeries) in summer (May–August) under 16 climate change scenarios. Result Precipitation‐ and groundwater‐corrected models were more accurate than conventional air–water temperature models (mean improvement in adjusted R 2 = +0.45; range = +0.09 to +0.75). Water temperature was projected to warm at widely variable rates across climate change scenarios encompassing different air temperature, precipitation, and groundwater regimes. Importantly, Gulf Sturgeon summer aggregation areas were cooler and influenced more by precipitation and groundwater and less by air temperature than were non‐aggregation areas. If precipitation and groundwater—as drivers of cooling—become warm in a changing climate, summer aggregation areas were projected to exhibit thermal habitat degradation equivalent to or greater than that of non‐aggregation areas. Conclusion Our results add hydrological context to the premise that aggregation areas provide cool water and energetic savings for Gulf Sturgeon during summer, underscoring the importance of protecting these habitats through groundwater conservation, water quality monitoring, and riparian/watershed habitat management. Our findings indicate that identifying thermally appropriate times for fieldwork activities will be increasingly important and time‐restricted as climate change intensifies. However, our research provides managers with a portfolio of water temperature models and an accurate, cost‐effective, management‐relevant approach to forecasting thermal habitat conditions for Gulf Sturgeon and other species in a changing climate.

Alabama, Florida↗

Reevaluation of background iodine-129 concentrations in water from the Snake River Plain aquifer, Idaho, 2003

Background concentrations of iodine-129 (129I, half-life = 15.7 million years) resulting from natural production in the earth?s atmosphere, in situ production in the earth by spontaneous fission of uranium-238(238U), and fallout from nuclear weapons tests conducted in the 1950s and 1960s were reevaluated on the basis of 52 analyses of ground- and surface-water samples collected from the eastern Snake River Plain in southeastern Idaho. The background concentration estimated using the results of a subset of 30 ground-water samples analyzed in this reevaluation is 5.4 attocuries per liter (aCi/L; 1 aCi = 10-18 curies) and the 95-percent nonparametric confidence interval is 5.2 to 10.0 aCi/L. In a previous study, a background 129I concentration was estimated on the basis of analyses of water samples from 16 sites on or tributary to the eastern Snake River Plain. At the 99-percent confidence level, background concentrations of 129I in that study were less than or equal to 8.2 aCi/L. During 1993?94, 34 water samples from 32 additional sites were analyzed for 129I to better establish the background concentrations in surface and ground water from the eastern Snake River Plain that is presumed to be unaffected by wastedisposal practices at the Idaho National Engineering and Environmental Laboratory (INEEL). Surface water contained larger 129I concentrations than water from springs and wells contained. Because surface water is more likely to be affected by anthropogenic fallout and evapotranspiration, background 129I concentrations were estimated in the current research using the laboratory results of ground-water samples that were assumed to be unaffected by INEEL disposal practices.

Idaho↗

Identifying characteristics of actionable science for drought planning and adaptation: Final report to the North Central Climate Adaptation Science Center

Changing climate conditions can make water management planning and drought preparedness decisions more complicated than ever before. Resource managers can no longer rely solely on historical data and trends to base their actions, and are in need of science that is relevant to their specific needs and can directly inform important planning decisions. Questions remain, however, regarding the most effective and efficient methods for extending scientific knowledge and products into management and decision-making. This study analyzed two unique cases of water management to better understand how science can be translated into resource management actions and decision-making. In particular, this project sought to understand 1) the characteristics that make science actionable and useful for water resource management and drought preparedness, and 2) the ideal types of scientific knowledge or science products that facilitate the use of science in management and decision-making. The first case study focused on beaver mimicry, an emerging nature-based solution that increases the presence of wood and woody debris in rivers and streams to mimic the actions of beavers. This technique has been rapidly adopted by natural resource managers as a way to restore riparian areas, increase groundwater infiltration, and slow surface water flow so that more water is available later in the year during hotter and dryer months. The second case study focused on an established research program, Colorado Dust on Snow, that provides water managers with scientific information explaining how the movement of dust particles from the Colorado Plateau influences hydrology and the timing and intensity of snow melt and water runoff into critical water sources. This program has support from and is being used by several water conservation districts in the state. Understanding how scientific knowledge translates into action and decision-making in these cases is expected to strengthen our knowledge of actionable science in the context of drought and its impacts on ecosystems. The project team gathered qualitative data through stakeholder interviews and will conduct an extensive literature review. Findings from these efforts will also be incorporated into a broader Intermountain West synthesis effort to determine and assess commonalities and differences among socio-ecological aspects of drought adaptation and planning.

Colorado, Kansas, Montana, Nebraska, North Dakota,↗

Fluoride in thermal and non-thermal groundwater: Insights from geochemical modeling

High fluoride (F) groundwaters (>1 mg/L) have been recognized as a water quality problem for nearly a century and occur in many countries worldwide. The affected aquifers can be sedimentary, metamorphic or igneous rocks, but the process giving rise to high-F concentrations has been studied with geochemical modeling and an examination of the rock sources. The association of high-F with silicic igneous rocks such as granites and rhyolites results from magmatic differentiation (fractional crystallization, fractional melting, and crustal assimilation) wherein F is enriched in the liquid phase because of its incompatibility in the mafic minerals that crystallize early during cooling. Further development of F-rich groundwaters occurs during the evolution of Na-HCO 3 waters because of removal of Ca through ion-exchange and calcite precipitation, thereby raising the F concentration from minerals like fluorite and fluorapatite to maintain solubility equilibrium. Increasing temperatures enhance this effect because of the retrograde solubility of calcite. From geochemical modeling using the PhreeqcI code, the primary variables controlling F concentrations are DIC (dissolved inorganic carbon), salinity (ionic strength), P CO2 , and temperature. Complexing is also important but plays a more secondary role. Considering these variables, an improved set of plotting parameters, F/Cl vs. HCO 3 /Cl, are shown to be effective in interpreting groundwater analyses. This approach is demonstrated by examining case studies from the Black Creek aquifer, South Carolina, USA, the Madison regional aquifer, midwestern USA, the Mizunami Underground Research Laboratory, Japan, New Zealand thermal waters, the San Luis Valley groundwaters, Colorado, USA, and the Aquia aquifer, Maryland, USA.

Science of the Total Evironment↗

Hydrologic conditions and water quality of rainfall and storm runoff for two agricultural areas of the Oso Creek watershed, Nueces County, Texas, 2005-08

The U.S. Geological Survey, in cooperation with the Texas State Soil and Water Conservation Board, Coastal Bend Bays and Estuaries Program, and Texas AgriLife Research and Extension Center at Corpus Christi, studied hydrologic conditions and water quality of rainfall and storm runoff of two primarily agricultural subwatersheds of the Oso Creek watershed in Nueces County, Texas. One area, the upper West Oso Creek subwatershed, is about 5,145 acres. The other area, a subwatershed drained by an unnamed tributary to Oso Creek (hereinafter, Oso Creek tributary), is about 5,287 acres. Rainfall and runoff (streamflow) were continuously monitored at the outlets of the two subwatersheds during the study period October 2005-September 2008. Seventeen rainfall samples were collected and analyzed for nutrients and major inorganic ions. Twenty-four composite runoff water-quality samples (12 at West Oso Creek, 12 at Oso Creek tributary) were collected and analyzed for nutrients, major inorganic ions, and pesticides. Twenty-six discrete suspended-sediment samples (12 West Oso Creek, 14 Oso Creek tributary) and 17 bacteria samples (10 West Oso Creek, 7 Oso Creek tributary) were collected and analyzed. These data were used to estimate, for selected constituents, rainfall deposition to and runoff loads and yields from the two subwatersheds. Quantities of fertilizers and pesticides applied in the two subwatersheds were compared with quantities of nutrients and pesticides in rainfall and runoff. For the study period, total rainfall was greater than average. Most of the runoff from the two subwatersheds occurred in response to a few specific storm periods. The West Oso Creek subwatershed produced more runoff during the study period than the Oso Creek tributary subwatershed, 13.95 inches compared with 9.45 inches. Runoff response was quicker and peak flows were higher in the West Oso Creek subwatershed than in the Oso Creek tributary subwatershed. Total nitrogen runoff yield for the 3-year study period averaged 2.62 pounds per acre per year from the West Oso Creek subwatershed and 0.839 pound per acre per year from the Oso Creek tributary subwatershed. Total phosphorus yields from the West Oso Creek and Oso Creek tributary subwatersheds for the 3-year period were 0.644 and 0.419 pound per acre per year, respectively. Runoff yields of nitrogen and phosphorus were relatively small compared to inputs of nitrogen in fertilizer and rainfall deposition. Average annual runoff yield of total nitrogen (subwatersheds combined) represents about 2.5 percent of nitrogen applied as fertilizer to cropland in the watershed and nitrogen entering the subwatersheds through rainfall deposition. Average annual runoff yield of total phosphorus (subwatersheds combined) represents about 4.0 percent of the phosphorus in applied fertilizer and rainfall deposition. Suspended-sediment yields from the West Oso Creek subwatershed were more than twice those from the Oso Creek tributary subwatershed. The average suspended-sediment yield from the West Oso Creek subwatershed was 522 pounds per acre per year and from the Oso Creek tributary subwatershed was 139 pounds per acre per year. Twenty-four herbicides and eight insecticides were detected in runoff samples collected at the two subwatershed outlets. At the West Oso Creek site, 19 herbicides and 4 insecticides were detected; at the Oso Creek tributary site, 18 herbicides and 6 insecticides were detected. Fourteen pesticides were detected in only one sample at low concentrations (near the laboratory reporting level). Atrazine and atrazine degradation byproduct 2-chloro-4-isopropylamino-6-amino-s-triazine (CIAT) were detected in all samples. Glyphosate and glyphosate byproduct aminomethylphosphonic acid (AMPA) were detected in all samples collected and analyzed during water years 2006-07 but were not included in analysis for samples collected in water year 2008. Of all pesticides detected in runoff, the highest runoff yields w

Scientific Investigations Report↗

Near-surface geophysics: Environmental applications

The field of geophysics encompasses a broad and diverse compilation of methodologies that employs principles of physics to characterize properties of earth materials within the subsurface. While geophysical methods have a long history in resource exploration and studies of Earth’s interior, the subdiscipline of “near-surface geophysics” has evolved in recent decades for examination of the shallow, near-surface environment for a range of purposes ranging from archaeological or forensic investigations to assessment of geologic, hydrologic, biologic, and geochemical properties and processes. “Environmental geophysics” are near-surface geophysical studies and methods that focus on understanding natural systems (e.g., watershed hydrology, groundwater–surface water connections, biophysical processes) as well as research pertaining to anthropogenic impacts and land management, (e.g., contamination and remediation, saltwater intrusion, agricultural practices). This field can be further subdivided into subdisciplines focused on specific topics and applications, such as water resources and hydrology (hydrogeophysics) or biologic and microbial processes (biogeophysics). Studies in environmental geophysics span a range of scales, from pore-scale laboratory tests to watershed-scale or regional field experiments. Methods vary by the nature of physics employed, the specific measurement acquired, and how that data is ultimately processed and analyzed to produce interpretable results. There exists further diversity in the acquisition logistics, geometry, and timing of data collection. Geophysical data can be collected in boreholes (one-dimensional, 1-D, vertical profiles), along survey lines (two-dimensional, 2-D, cross-sections), or in dense sensor arrays or gridded profiles (three-dimensional, 3-D, models). Regarding the temporal aspect, studies can conduct one-time geophysical surveys to obtain detailed imaging of subsurface structure or use timelapse and continuous monitoring to investigate variations in subsurface properties over time. The cumulation of all possible permutations of these factors (method, acquisition geometry, survey design, and target application) results in an immense diversity among environmental geophysical studies. Nevertheless, this field remains unified in the pursuit of understanding natural and human-impacted near-surface environments through geophysical investigations. Here we highlight some key references within environmental geophysics. Resources on geophysical theory, acquisition logistics, processing and inversion workflows, and example case studies are categorized into the most common geophysical classes within Geophysical Methods. Lastly, example references for the dominant types of applications in environmental geophysical studies are catalogued in Environmental Applications.

Book chapter↗

Water-resources activities of the Louisiana District in fiscal years 1986-87

The U.S. Geological Survey conducts three types of water resources activities in Louisiana - data collection, investigations, and research. These activities are conducted, in large part, through cooperation with other Federal, State, and local agencies. Water-resources activities undertaken from October 1, 1985 to September 30, 1987 are described. Specifically, the report presents information on organization of the District Office, cooperating agencies, data-collection activities, interpretive studies and research activities, new publications of the Louisiana District, and sources of information in the U.S. Geological Survey. For each activity, the following information is presented: project title, project number, study location, cooperating agency, project chief, project duration, problem, objective, approach, progress, and plans. (USGS)

Open-File Report↗

Multi-Disciplinary Approach to Trace Contamination of Streams and Beaches

Concentrations of fecal-indicator bacteria in urban streams and ocean beaches in and around Santa Barbara occasionally can exceed public-health standards for recreation. The U.S. Geological Survey (USGS), working with the City of Santa Barbara, has used multi-disciplinary science to trace the sources of the bacteria. This research is helping local agencies take steps to improve recreational water quality. The USGS used an approach that combined traditional hydrologic and microbiological data, with state-of-the-art genetic, molecular, and chemical tracer analysis. This research integrated physical data on streamflow, ground water, and near-shore oceanography, and made extensive use of modern geophysical and isotopic techniques. Using those techniques, the USGS was able to evaluate the movement of water and the exchange of ground water with near-shore ocean water. The USGS has found that most fecal bacteria in the urban streams came from storm-drain discharges, with the highest concentrations occurring during storm flow. During low streamflow, the concentrations varied as much as three-fold, owing to variable contribution of non-point sources such as outdoor water use and urban runoff to streamflow. Fecal indicator bacteria along ocean beaches were from both stream discharge to the ocean and from non-point sources such as bird fecal material that accumulates in kelp and sand at the high-tide line. Low levels of human-specific Bacteroides, suggesting fecal material from a human source, were consistently detected on area beaches. One potential source, a local sewer line buried beneath the beach, was found not to be responsible for the fecal bacteria.

Fact Sheet↗

The natural history of Caroline Atoll, Southern Line Islands. Part I. History, physiography, botany, and isle descriptions

conclusion: Lushly wooded Caroline Atoll, with the majority of its 39 islets (399 ha of land) either in near-pristine condition or having recovered remarkably from past disturbance, is one of the least spoiled atolls in the Pacific. Uninhabited, it harbors plant ecosystems and breeding seabirds (Pt. II) of national and international importance. Its marine and terrestrial ecosystems are prime outdoor ecological laboratories for research on geological processes including ground water, sea level changes, the dynamics of motu formation, fish poisoning, and numerous facets of ecology including plant succession and Pisonia growth rates. Caroline boasts prime coral reefs thickly studded with Tridacna clams, substantial numbers of coconut crabs, breeding sites for green turtles, wintering grounds for shorebirds including the rare Bristle-thighed Curlew, ancient Tuamotuan marae, and a crystalline, unpolluted lagoon. The variety, abundance, and quality of its flora and fauna qualify it for status as an officially recognized international preserve (Pt. II, Sect. G). Efforts toward its conservation have thus far been unsuccessful: in 1992 it was leased to a private French businessman who is currently fishing the reefs for commercial profit, as well as disturbing seabird, turtle and coconut crab populations.

Atoll Research Bulletin↗

The natural history of Caroline Atoll, Southern Line Islands. Part II. Seabirds, other terrestrial animals, and conservation

conclusion: Lushly wooded Caroline Atoll, with the majority of its 39 islets (399 ha of land) either in near-pristine condition or having recovered remarkably from past disturbance, is one of the least spoiled atolls in the Pacific. Uninhabited, it harbors plant ecosystems and breeding seabirds (Pt. II) of national and international importance. Its marine and terrestrial ecosystems are prime outdoor ecological laboratories for research on geological processes including ground water, sea level changes, the dynamics of motu formation, fish poisoning, and numerous facets of ecology including plant succession and Pisonia growth rates. Caroline boasts prime coral reefs thickly studded with Tridacna clams, substantial numbers of coconut crabs, breeding sites for green turtles, wintering grounds for shorebirds including the rare Bristle-thighed Curlew, ancient Tuamotuan marae, and a crystalline, unpolluted lagoon. The variety, abundance, and quality of its flora and fauna qualify it for status as an officially recognized international preserve (Pt. II, Sect. G). Efforts toward its conservation have thus far been unsuccessful: in 1992 it was leased to a private French businessman who is currently fishing the reefs for commercial profit, as well as disturbing seabird, turtle and coconut crab populations.

Atoll Research Bulletin↗