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User's Manual for the New England Water-Use Data System (NEWUDS)

Water is used in a variety of ways that need to be understood for effective management of water resources. Water-use activities need to be categorized and included in a database management system to understand current water uses and to provide information to water-resource management policy decisionmakers. The New England Water-Use Data System (NEWUDS) is a complex database developed to store water-use information that allows water to be tracked from a point of water-use activity (called a 'Site'), such as withdrawal from a resource (reservoir or aquifer), to a second Site, such as distribution to a user (business or irrigator). NEWUDS conceptual model consists of 10 core entities: system, owner, address, location, site, data source, resource, conveyance, transaction/rate, and alias, with tables available to store user-defined details. Three components--site (with both a From Site and a To Site), a conveyance that connects them, and a transaction/rate associated with the movement of water over a specific time interval form the core of the basic NEWUDS network model. The most important step in correctly translating real-world water-use activities into a storable format in NEWUDS depends on choosing the appropriate sites and linking them correctly in a network to model the flow of water from the initial From Site to the final To Site. Ten water-use networks representing real-world activities are described--three withdrawal networks, three return networks, two user networks, two complex community-system networks. Ten case studies of water use, one for each network, also are included in this manual to illustrate how to compile, store, and retrieve the appropriate data. The sequence of data entry into tables is critical because there are many foreign keys. The recommended core entity sequence is (1) system, (2) owner, (3) address, (4) location, (5) site, (6) data source, (7) resource, (8) conveyance, (9) transaction, and (10) rate; with (11) alias and (12) user-defined detail subject areas populated as needed. After each step in data entry, quality-assurance queries should be run to ensure the data are correctly entered so that it can be retrieved accurately. The point of data storage is retrieval. Several retrieval queries that focus on retrieving only relevant data to specific questions are presented in this manual as examples for the NEWUDS user.

Open-File Report↗

Ecotoxicology of Wild Mammals

An international group of 32 scientists has critically reviewed the scientific literature on exposure and effects of environmental contaminants in wild mammals. The underlying theme of this text is encompassed by the following four questions: What exactly do we know about environmental contaminants in mammals? What are the commonalities and differences between mammal orders/species in the effects that contaminants have? How and to what degree of accuracy can we predict the adverse effects of environmental contaminants on mammalian wildlife? How significant are contaminant insults compared with other density-independent and -dependent factors such as habitat loss, climatic factors and disease? The book is organized three topical sections including introductory chapters that provide a background on environmental contaminants and the mammalian orders, eight taxonomic chapters discussing all aspects of the exposure to and effects of contaminants in mammalian orders, and four thematic chapters that review and discuss generic issues including biomarkers, prediction and extrapolation of exposure and effects, hazard and risk assessment, and the relative significance of contaminants on mammals compared with other commonly encountered stressors. A final a summary chapter identifies phylogenetic trends, critical data gaps, and overarching research needs. Although the absolute number of toxicological studies in domesticated and wild mammals eclipses that wildlife species, a detailed examination of our knowledge base reveals that information for 'wild' birds is actually greater than that for 'wild' mammals. Of the various mammalian taxa, ecotoxicological data is most noticeably lacking for marsupials and monotremes. In contrast, rodents (comprising 43% of all mammal species) have been studied extensively, despite evidence of their tolerance to some organochlorine compounds, rodenticides, and even radionuclides. Mammalian species at greatest risk of exposure include those that consume a high percentage of their body weight on a daily basis. Aquatic mammals tend to bioaccumulate tremendous burdens of lipophilic contaminants, although storage in their fat depots may actually limit toxicity. Carnivores appear to be more sensitive to adverse effects of environmental contaminants than herbivores. Remarkably few of the thousands of compounds manufactured worldwide have been toxicologically evaluated in wild mammals, and concentrations of even fewer have been monitored in tissues.

Ecological & Environmental Toxicology Series.↗

Preliminary evaluation of the behavior and movements of adult spring Chinook salmon in the Chehalis River, southwestern Washington, 2014

Recent interest in flood control and restoration strategies in the Chehalis River Basin has increased the need to understand the current status and ecology of spring Chinook salmon ( Oncorhynchus tshawytscha ). Spring Chinook salmon have the longest exposure of all adult Chinook salmon life histories to the low-flow and high water temperature conditions that typically occur during summer. About 100 adult spring Chinook salmon were found dead in the Chehalis River in July and August 2009. Adult Chinook salmon are known to hold in cool-water refugia during warm summer months, but the extent to which spring Chinook salmon might use thermal refugia in the Chehalis River is unknown. A preliminary evaluation of the movements and temperature exposures of adult spring Chinook salmon following their return to the Chehalis River was conducted using radiotelemetry and transmitters equipped with temperature sensors. A total of 12 spring Chinook salmon were captured, radio-tagged, and released in the main-stem Chehalis River between May and late June 2014. Tagged fish were monitored from freshwater entry through the spawning period using a combination of fixedsite monitoring locations and mobile tracking. Water temperature and flow conditions in the main-stem Chehalis River during 2014 were atypical compared to historical averages. Mean monthly water temperatures between March and August 2014 were higher than any decade since 1960 and mean monthly discharge was 90–206 percent of the discharge in previous years. Overall, 92 percent of the tagged fish were detected, with a mean of 102 d in the detection history of tagged fish. Seven tagged fish (58 percent) moved upstream, either shortly after release (5–8 d, 57 percent), or within about a month (34–35 d, 29 percent). One fish (14 percent) remained near the release location for 98 d before moving upstream. The final fates for the seven fish that moved upstream following release included six fish that were assigned a fate of spawner and one fish with an unknown fate. Tagged fish showed limited movements during the peak water temperatures in July and August, and were not frequently detected at sites where water temperatures exceeded 21 °C . The mouths of the Skookumchuck and Newaukum Rivers were commonly used by tagged fish for extended periods during peak water temperatures and study fish with a fate of spawner were last detected in these tributaries. This pilot study represents a substantial contribution to the understanding of spring Chinook salmon in the Chehalis River Basin, and provides information for the design and execution of future evaluations. The water temperatures and flow conditions during the 2014 study period were not typical of the historical conditions in the basin and the numbers of tagged fish monitored was relatively low, so results should be interpreted with those cautions in mind.

Washington↗

Geologic map of MTM -40252 and -40257 quadrangles, Reull Vallis region of Mars

Mars Transverse Mercator (MTM) quadrangles -40252 and -40257 cover a portion of the highlands of Promethei Terra northeast of the Hellas basin. The map area consists of heavily cratered ancient highland materials of moderate to high relief, isolated knobs and massifs of rugged mountainous materials, extensive tracts of smooth and channeled plains, and other surficial deposits. Reull Vallis, an approximately 1,500 km-long outflow channel system, cuts through the southeast corner of the map area. Regional slopes are to the southwest, toward the Hellas basin, as indicated by Martian topographic maps and the orientations of channels along the northeast rim of the Hellas basin. The Martian highlands cover more than 60 percent of the planet's surface and are primarily in the southern hemisphere. Most of the highlands consist of rugged, densely cratered terrains believed to represent the final phase of heavy bombardment in the inner solar system about 4.0 billion years ago. Parts of the Martian highlands show evidence of extensive degradation and modification. The map area shows landforms created by numerous geologic processes, including tectonism, fluvial activity, and mass wasting. The occurrence of fluvial features, such as outflow channels and valley networks, has significant implications for past Martian conditions. Determining the geology of the highlands northeast of the Hellas basin provides a better understanding of the role and timing of volatile-driven activity in the evolution of the highlands. Photogeologic mapping at 1:500,000 scale from analysis of Viking Orbiter images complements geomorphic studies of Reull Vallis and other highland outflow systems, of drainage networks, and of highland debris aprons and regional geologic mapping studies of the highlands at the 1:2,000,000 scale and 1:1,000,000 scale. Crater size-frequency distributions have been compiled to constrain the relative ages of geologic units and determine the timing and extents of the observed geologic processes.

IMAP↗

Zeolitization of Tertiary tuffs in lacustrine and alluvial deposits in the Ray-San Manuel area, Final and Gila Counties, Arizona

Specimens of tuff in the Ray-San Manuel area, southeastern Arizona, have been X-rayed to determine the present approximate mineralogic composition and the type and degree of alteration of the tuffs. Some of the tuffs consist largely of glass or have been partly or completely altered to calcium montmorillonite; many of them have been almost completely zeolitized or contain a zeolite and some clay. Only three zeolitized specimens contain a little glass. With four exceptions, the zeolitie is clinoptilolite; the exceptions are one altered to chabazite, one to mordenite, one to erionite, and one to erionite, clinoptilolite, and chabazite. The tuffs are mostly of airfall origin and of rhyolitic or probable rhyolitic composition and generally contain negligible percentages of crystal and lithic fragments. Two specimens are tuffaceous sedimentary rocks, and two are ash-flow tuffs. The tuffs range in age from early Pliocene or late Miocene to Oligocene. Some were deposited in lacustrine or playa environments; others were deposited in freshwater alluvial environments. All the beds examined in the lower Miocene and older formations have been zeolitized. Zeolitization of beds in younger formations depends on the environment of deposition. Zeolitized tuffs that contain at least 80 percent zeolite and are in beds more than one-third meter thick are considered potentially minable.

Arizona↗

Final project memorandum: Southeast Climate Adaptation Science Center Project

Low-lying public lands along the northern Gulf of Mexico coast are vulnerable to sea-level rise. Coastal planners and resource managers in the region have requested customized information that can be used to concisely communicate local sea-level rise scenarios and identify potential impacts to the missions of management agencies. In this project, researchers worked with the Northern Gulf of Mexico Sentinel Site Cooperative to develop information sheets outlining potential sea-level rise scenarios for the region through 2100 including their potential impact on the missions of federally-managed lands. Researchers drew from existing information on regional and global sea-level rise scenarios to develop customized information sheets for 54 federally-managed lands in the region (e.g., National Wildlife Refuges, National Park Service lands, National Estuarine Research Reserves) (Chivoiu et al. 2020). This project was developed in response to a request for customized sea-level rise scenario products from partners at the Northern Gulf of Mexico Sentinel Site Cooperative and the U.S. Fish and Wildlife Service’s Gulf Restoration Program. The results of this project support the conservation stewardship missions of the U.S. Fish and Wildlife Service and National Park Service by providing science to inform management of their lands along the Gulf of Mexico.

Alabama, Florida, Louisiana, Mississippi, Texas↗

Digital database of the Holocene tephras of the Mono-Inyo Craters, California

This digital product comprises a collection of age and isopach data for the Holocene tephras of the Mono-Inyo Craters, California. Data on the most recent eruptions from this volcanic chain are relatively comprehensive, getting less so the further back in time. For the most recent eruptions to about 1,500 years ago, tephra beds within separate eruptive sequences have been studied and isopached. Before this, from about 2,000 years ago to about 5,000 years ago, there are insufficient data for isopaching. However, one isolated tephra of about 9,000 years ago was studied and isopached in detail. Regarding ages, there are many tens of radiocarbon ages that have been obtained on the Holocene Mono-Inyo volcanic products. The vast majority of these radiocarbon dates are associated with tephras at locales that can be considered distal (basically where the primary tephra is less than several centimeters (cm) thick). These dates represent carbon that was sequestered perhaps within several hundred years of the eruption but do not represent the ages of separate eruptive pulses. There are two reasons for this. In some cases, it is clear that the dated material is not associated with the eruption products. This is the case in some lake strata where carbon is either not physically close to a given tephra layer or where an age for a tephra layer was obtained by interpolation assuming a sedimentation rate. In other cases, it is not clear that a given tephra layer represents a primary tephra; in such cases the layer could instead be redeposited. At most distal localities (beyond about 5 kilometers (km) from the chain), there was no record made of whether tephra was primary or redeposited, and at these distances where tephra is thin, it is generally redeposited during later events such as fires or thunderstorms. These age data are not appropriate for use in dating the eruptive history of the volcanic chain, and are therefore not included in the present contribution. The carbon age data in the present contribution were obtained by careful consideration of the material being collected. In the best instances, carbon was collected from new growth on plants that were probably killed by an eruption event through burning and burial. Slightly poorer data were collected from burned and buried forest duff that is renewed frequently. Finally, some dates for older Holocene tephra layers at Black Lake, Nevada, downwind of the Mono-Inyo Craters, appear to allow correlation of the layers to proximal occurrences. In cases where these poorer data were collected but yielded ages statistically indistinguishable from better data, the poorer data were included in the analysis. In the most difficult cases, usually the furthest back in time, poorer data that were nevertheless statistically indistinguishable were weighted together to generate the age estimate. There are some known Holocene eruptions from the Mono-Inyo Craters that are not included in this tabulation, as so far a tephra has not been associated with the eruptions. A good example of this is the Java blocks. The Java block eruption, from a vent underlying the northwestern corner of Negit Island in Mono Lake, expelled numerous blocks that were rafted within the lake and that are mostly deposited on the southwestern and northern lakeshore. No tephra that can be correlated to this deposit has been found, and therefore the eruption is not included in this tabulation.

California↗

Remote sensing survey of Chinese tallow tree in the Toledo Bend Reservoir area, Louisiana and Texas

We applied Hyperion sensor satellite data acquired by the National Aeronautics and Space Administration’s Earth Observing-1 (EO-1) satellite in conjunction with reconnaissance surveys to map the occurrences of the invasive Chinese tallow tree (Triadica sebifera) in the Toledo Bend Reservoir study area of northwestern Louisiana and northeastern Texas. The rationale for application of high spectral resolution EO-1 Hyperion data was based on the successful use of Hyperion data in the mapping of Chinese tallow tree in southwestern Louisiana in 2005. In contrast to the single Hyperion image used in the 2005 project, more than 20 EO-1 Hyperion and Advanced Land Imager (ALI) images of the study area were collected in 2009 and 2010 during the fall senescence when Chinese tallow tree leaves turn red. Atmospherically corrected reflectance spectra of Hyperion imagery collected at ground and aerial observation locations provided the input datasets used in the program for spectral discrimination analysis. Discrimination analysis was used to identify spectral indicator sets to best explain variance contained in the input databases. The expectation was that at least one set of Hyperion-based indicator spectra would uniquely identify occurrences of red-leaf Chinese tallow tree; however, no combination of Hyperion-based reflectance datasets produced a unique identifier. The inability to discover a unique spectral indicator resulted primarily from relatively sparse coverage by red-leaf Chinese tallow tree within the study area (percentage of coverage was less than 5 percent per 30- by 30-meter Hyperion pixel). To enhance the performance of the spectral discrimination analysis, leaf and canopy spectra of Chinese tallow tree were added to the input datasets to guide the indicator selection. In addition, input databases were segregated by land class obtained from an ALI-based landcover classification in order to reduce the input variance and to promote spectral discrimination of red-leaf Chinese tallow tree. Although no unique spectral identifier for red-leaf Chinese tallow tree was uncovered with these enhanced methods, in some cases predicted spatial patterns throughout the Hyperion images revealed alignment with vegetation associations within each land class that was often observed to contain Chinese tallow trees. These instances were associated particularly with the addition of helicopter-based spectra to the input databases. It was attempted to extend such predictions of likely occurrences of Chinese tallow tree by mapping six of the nine Hyperion swaths and four of the nine land classes, but this attempt produced uncertain results that could not be fully evaluated for accuracy. Even though the final mapping showed promise in identifying likely Chinese tallow tree occurrences, the low percentage of occurrences hindered mapping performance and validation. Results of the mapping suggested that successful detection of Chinese tallow tree in the study area would require a spectral sensor similar to the Hyperion but with a higher ground-level spatial resolution. Although the Hyperion-based spectral mapping did not provide the desired results, the associated field (ground and aerial) surveys did provide for a qualitative assessment of the overall Chinese tallow tree distribution within the study area. Ground and aerial surveys suggested that Chinese tallow tree occurrences were uncommon and were without an observed pattern in relation to proximity to the Toledo Bend Reservoir. Although uncommon and scattered, Chinese tallow trees and shrubs most commonly existed along forest edges, water edges, and fence lines, probably most in line with seed dispersal by birds. Chinese tallow trees were observed to be more densely dispersed within some scrublands and grasslands than were observed in pine, hardwood, and mixed forests.

Louisiana;Texas↗

Depth-dependent groundwater quality sampling at City of Tallahassee test well 32, Leon County, Florida, 2013

Public-supply wells sometimes produce water of less than desirable quality because contaminants can migrate to the open interval of wells through preferential pathways. If these pathways can be identified, zones that produce poor quality water can be excluded during the well-construction process. The U.S. Geological Survey has developed geophysical testing methods that can be used to delineate zones of high permeability in test wells. Once the highly permeable zones are identified, water-quality data can be collected from each zone to identify whether any of the zones produce water of poor quality. The zones producing poor quality water can then be cased off in the final well design so that they do not contribute flow to the production well, reducing subsequent water-treatment costs. A test well was drilled by the City of Tallahassee to assess the suitability of the site for the installation of a new well for public water supply. The test well is in Leon County in north-central Florida. The U.S. Geological Survey delineated high-permeability zones in the Upper Floridan aquifer, using borehole-geophysical data collected from the open interval of the test well. A composite water sample was collected from the open interval during high-flow conditions, and three discrete water samples were collected from specified depth intervals within the test well during low-flow conditions. Water-quality, source tracer, and age-dating results indicate that the open interval of the test well produces water of consistently high quality throughout its length. The cavernous nature of the open interval makes it likely that the highly permeable zones are interconnected in the aquifer by secondary porosity features.

Florida↗

Regression Analysis of Stage Variability for West-Central Florida Lakes

The variability in a lake's stage depends upon many factors, including surface-water flows, meteorological conditions, and hydrogeologic characteristics near the lake. An understanding of the factors controlling lake-stage variability for a population of lakes may be helpful to water managers who set regulatory levels for lakes. The goal of this study is to determine whether lake-stage variability can be predicted using multiple linear regression and readily available lake and basin characteristics defined for each lake. Regressions were evaluated for a recent 10-year period (1996-2005) and for a historical 10-year period (1954-63). Ground-water pumping is considered to have affected stage at many of the 98 lakes included in the recent period analysis, and not to have affected stage at the 20 lakes included in the historical period analysis. For the recent period, regression models had coefficients of determination (R2) values ranging from 0.60 to 0.74, and up to five explanatory variables. Standard errors ranged from 21 to 37 percent of the average stage variability. Net leakage was the most important explanatory variable in regressions describing the full range and low range in stage variability for the recent period. The most important explanatory variable in the model predicting the high range in stage variability was the height over median lake stage at which surface-water outflow would occur. Other explanatory variables in final regression models for the recent period included the range in annual rainfall for the period and several variables related to local and regional hydrogeology: (1) ground-water pumping within 1 mile of each lake, (2) the amount of ground-water inflow (by category), (3) the head gradient between the lake and the Upper Floridan aquifer, and (4) the thickness of the intermediate confining unit. Many of the variables in final regression models are related to hydrogeologic characteristics, underscoring the importance of ground-water exchange in controlling the stage of karst lakes in Florida. Regression equations were used to predict lake-stage variability for the recent period for 12 additional lakes, and the median difference between predicted and observed values ranged from 11 to 23 percent. Coefficients of determination for the historical period were considerably lower (maximum R2 of 0.28) than for the recent period. Reasons for these low R2 values are probably related to the small number of lakes (20) with stage data for an equivalent time period that were unaffected by ground-water pumping, the similarity of many of the lake types (large surface-water drainage lakes), and the greater uncertainty in defining historical basin characteristics. The lack of lake-stage data unaffected by ground-water pumping and the poor regression results obtained for that group of lakes limit the ability to predict natural lake-stage variability using this method in west-central Florida.

Scientific Investigations Report↗

Hydrogeologic setting and simulation of groundwater flow near the Canterbury and Leadville Mine Drainage Tunnels, Leadville, Colorado

The Leadville mining district is historically one of the most heavily mined regions in the world producing large quantities of gold, silver, lead, zinc, copper, and manganese since the 1860s. A multidisciplinary investigation was conducted by the U.S. Geological Survey, in cooperation with the Colorado Department of Public Health and Environment, to characterize large-scale groundwater flow in a 13 square-kilometer region encompassing the Canterbury Tunnel and the Leadville Mine Drainage Tunnel near Leadville, Colorado. The primary objective of the investigation was to evaluate whether a substantial hydraulic connection is present between the Canterbury Tunnel and Leadville Mine Drainage Tunnel for current (2008) hydrologic conditions. Altitude in the Leadville area ranges from about 3,018 m (9,900 ft) along the Arkansas River valley to about 4,270 m (14,000 ft) along the Continental Divide east of Leadville, and the high altitude of the area results in a moderate subpolar climate. Winter precipitation as snow was about three times greater than summer precipitation as rain, and in general, both winter and summer precipitation were greatest at higher altitudes. Winter and summer precipitation have increased since 2002 coinciding with the observed water-level rise near the Leadville Mine Drainage Tunnel that began in 2003. The weather patterns and hydrology exhibit strong seasonality with an annual cycle of cold winters with large snowfall, followed by spring snowmelt, runoff, and recharge (high-flow) conditions, and then base-flow (low-flow) conditions in the fall prior to the next winter. Groundwater occurs in the Paleozoic and Precambrian fractured-rock aquifers and in a Quaternary alluvial aquifer along the East Fork Arkansas River, and groundwater levels also exhibit seasonal, although delayed, patterns in response to the annual hydrologic cycle. A three-dimensional digital representation of the extensively faulted bedrock was developed and a geophysical direct-current resistivity field survey was performed to evaluate the geologic structure of the study area. The results show that the Canterbury Tunnel is located in a downthrown structural block that is not in direct physical connection with the Leadville Mine Drainage Tunnel. The presence of this structural discontinuity implies there is no direct groundwater pathway between the tunnels along a laterally continuous bedrock unit. Water-quality results for pH and major-ion concentrations near the Canterbury Tunnel showed that acid mine drainage has not affected groundwater quality. Stable-isotope ratios of hydrogen and oxygen in water indicate that snowmelt is the primary source of groundwater recharge. On the basis of chlorofluorocarbon and tritium concentrations and mixing ratios for groundwater samples, young groundwater (groundwater recharged after 1953) was indicated at well locations upgradient from and in a fault block separate from the Canterbury Tunnel. Samples from sites downgradient from the Canterbury Tunnel were mixtures of young and old (pre-1953) groundwater and likely represent snowmelt recharge mixed with older regional groundwater that discharges from the bedrock units to the Arkansas River valley. Discharge from the Canterbury Tunnel contained the greatest percentage of old (pre-1953) groundwater with a mixture of about 25 percent young water and about 75 percent old water. A calibrated three-dimensional groundwater model representing high-flow conditions was used to evaluate large-scale flow characteristics of the groundwater and to assess whether a substantial hydraulic connection was present between the Canterbury Tunnel and Leadville Mine Drainage Tunnel. As simulated, the faults restrict local flow in many areas, but the fracture-damage zones adjacent to the faults allow groundwater to move along faults. Water-budget results indicate that groundwater flow across the lateral edges of the model controlled the majority of flow in and out of the aquifer (79 percent and 63 percent of the total water budget, respectively). The largest contributions to the water budget were groundwater entering from the upper reaches of the watershed and the hydrologic interaction of the groundwater with the East Fork Arkansas River. Potentiometric surface maps of the simulated model results were generated for depths of 50, 100, and 250 m. The surfaces revealed a positive trend in hydraulic head with land-surface altitude and evidence of increased control on fluid movement by the fault network structure at progressively greater depths in the aquifer. Results of advective particle-tracking simulations indicate that the sets of simulated flow paths for the Canterbury Tunnel and the Leadville Mine Drainage Tunnel were mutually exclusive of one another, which also suggested that no major hydraulic connection was present between the tunnels. Particle-tracking simulations also revealed that although the fault network generally restricted groundwater movement locally, hydrologic conditions were such that groundwater did cross the fault network at many locations. This cross-fault movement indicates that the fault network controls regional groundwater flow to some degree but is not a complete barrier to flow. The cumulative distributions of adjusted age results for the watershed indicate that approximately 30 percent of the flow pathways transmit groundwater that was younger than 68 years old (post-1941) and that about 70 percent of the flow pathways transmit old groundwater. The particle-tracking results are consistent with the apparent ages and mixing ratios developed from the chlorofluorocarbon and tritium results. The model simulations also indicate that approximately 50 percent of the groundwater flowing through the study area was less than 200 years old and about 50 percent of the groundwater flowing through the study area is old water stored in low-permeability geologic units and fault blocks. As a final examination of model response, the conductance parameters of the Canterbury Tunnel and Leadville Mine Drainage Tunnel were manually adjusted from the calibrated values to determine if altering the flow discharge in one tunnel affects the hydraulic behavior in the other tunnel. The examination showed no substantial hydraulic connection. The multidisciplinary investigation yielded an improved understanding of groundwater characteristics near the Canterbury Tunnel and the Leadville Mine Drainage Tunnel. Movement of groundwater between the Canterbury Tunnel and Leadville Mine Drainage Tunnel that was central to this investigation could not be evaluated with strong certainty owing to the structural complexity of the region, study simplifications, and the absence of observation data within the upper sections of the Canterbury Tunnel and between the Canterbury Tunnel and the Leadville Mine Drainage Tunnel. There was, however, collaborative agreement between all of the analyses performed during this investigation that a substantial hydraulic connection did not exist between the Canterbury Tunnel and the Leadville Mine Drainage Tunnel under natural flow conditions near the time of this investigation.

Colorado↗

Compositional and stable carbon isotopic fractionation during non-autocatalytic thermochemical sulfate reduction by gaseous hydrocarbons

The possibility of autocatalysis during thermochemical sulfate reduction (TSR) by gaseous hydrocarbons was investigated by examination of previously reported laboratory and field data. This reaction was found to be a kinetically controlled non-autocatalytic process, and the apparent lack of autocatalysis is thought to be due to the absence of the required intermediate species. Kinetic parameters for chemical and carbon isotopic fractionations of gaseous hydrocarbons affected by TSR were calculated and found to be consistent with experimentally derived values for TSR involving long-chain hydrocarbons. Model predictions based on these kinetic values indicate that TSR by gaseous hydrocarbon requires high-temperature conditions. The oxidation of C 2–5 hydrocarbons by sulfate reduction is accompanied by carbon isotopic fractionation with the residual C 2–5 hydrocarbons becoming more enriched in 13 C. Kinetic parameters were calculated for the stable carbon isotopic fractionation of gaseous hydrocarbons that have experienced TSR. Model predictions based on these kinetics indicate that it may be difficult to distinguish the effects of TSR from those of thermal maturation at lower levels of hydrocarbon oxidation; however, unusually heavy δ 13 C 2+ values (>−10‰) can be diagnostic of high levels of conversion (>50%). Stoichiometric and stable carbon isotopic data show that methane is stable under the investigated reaction conditions and is likely a product of TSR by other gaseous hydrocarbons rather than a significant reactant. These results indicate that the overall TSR reaction mechanism for oxidation of organic substrates containing long-chain hydrocarbons involves three distinct phases as follows: (1) an initial slow and non-autocatalytic stage characterized by the reduction of reactive sulfate by long-chain saturated hydrocarbons; (2) a second autocatalytic reaction phase dominated by reactions involving reduced sulfur species and partially oxidized hydrocarbons; (3) and a final, or late-stage, TSR reaction in which hydrocarbon oxidation continues at a slower rate via the non-autocatalytic reduction of sulfate by gaseous hydrocarbons.

Geochimica et Cosmochimica Acta↗

Simulating potential structural and operational changes for Detroit Dam on the North Santiam River, Oregon-Interim Results

Prior to operational changes in 2007, Detroit Dam on the North Santiam River in western Oregon had a well-documented effect on downstream water temperature that was problematic for endangered salmonid fish species. In this U.S. Geological Survey study, done in cooperation with the U.S. Army Corps of Engineers, an existing calibrated CE-QUAL-W2 model of Detroit Lake (the impounded waterbody behind Detroit Dam) was used to determine how changes in dam operation or changes to the structural release points of Detroit Dam might affect downstream water temperatures under a range of historical hydrologic and meteorological conditions. Many combinations of environmental, operational, and structural options were explored with the model. Two downstream temperature targets were used along with three sets of environmental forcing conditions representing normal, hot/dry, and cool/wet conditions. Three structural options were modeled, including the use of existing outlets, one hypothetical variable-elevation outlet such as a sliding gate, and a hypothetical combination of a floating outlet and a fixed-elevation outlet. Finally, four sets of operational guidelines were explored to gain an understanding of the effects of imposing different downstream minimum streamflows or managing the level of the lake with different timelines in autumn. Several conclusions can be made from these interim model scenarios: * Temperature targets just downstream of Detroit Dam can be met through a combination of new dam outlets or a delayed drawdown of the lake in autumn. * Spring and summer dam operations greatly affect the available release temperatures and operational flexibility later in the autumn. Releasing warm water during mid-summer tends to keep more cool water available for release in autumn. * The ability to meet downstream temperature targets during spring depends on the characteristics of the available outlets. Under existing conditions, for example, although warm water sometimes is present at the lake surface, such water may not be available for release if the lake level is either well below or well above the spillway crest in spring and early summer. * Managing lake releases to meet downstream temperature targets depends on having outlet structures that can access both (warm) lake surface water and (cold) deeper lake water throughout the year. The existing outlets at Detroit Dam do not allow near-surface waters to be released during times when the lake surface level is below the spillway (spring and autumn). * Model simulations indicate that delayed drawdown of Detroit Lake in autumn would result in better control over release temperatures. * Compared to the existing outlets at Detroit Dam, floating or sliding-gate outlet structures can provide greater control over release temperatures because they provide better access to warm water at the lake surface and cooler water at depth. This report provides interim study results to the U.S. Army Corps of Engineers. The full study will be completed in 2012.

Open-File Report↗

Map depicting susceptibility to landslides triggered by intense rainfall, Puerto Rico

Landslides in Puerto Rico range from nuisances to deadly events. Centuries of agricultural and urban modification of the landscape have perturbed many already unstable hillsides on the tropical island. One of the main triggers of mass wasting on the island is the high-intensity rainfall that is associated with tropical atmospheric systems. Puerto Rico’s geographic position and rugged topography render millions of residents vulnerable to widespread landslide events. In this study, a high-resolution (5 meters), high-intensity rainfall-induced landslide susceptibility model was produced using the frequency-ratio method. Datasets utilized in the model included a complete-island landslide inventory created from imagery obtained after Hurricanes Irma and María impacted the island during September 2017, slope inclination, land-surface curvature, soil type, geologic terrane, mean annual precipitation, land use, soil moisture, and distance to roadways and streams. The final data product (plate 1) is a statistically viable representation of where landslides are likely to initiate during or soon after intense rainfall, with a robust receiver operating characteristic area-under-curve value of 0.87. The model output raster pixel values were binned into 100 equal-area quantiles and then classified into Low, Moderate, High, Very High, and Extremely High classes of susceptibility. The Extremely High susceptibility classification represents the most vulnerable 1 percent of the island, whereas Very High, High, Moderate, and Low classifications cover 9, 20, 30, and 40 percent of the island, respectively. The susceptibility map is intended to assist in planning future development, mitigation measures, and post-event emergency response; however, it is not a substitute for site-specific, slope-stability assessments performed by licensed geologists and engineers. Additionally, the map does not portray locations where landslide material may travel after mobilization, and which may be at extreme risk; nor does it necessarily portray where landslides may occur during earthquakes or mass wasting triggered by prolonged, relatively low-intensity rainfall.

Puerto Rico↗

Is the extraction of thorium onto MnO 2 -coated filter cartridges uniform?

Large-volume (i.e., 10 2 - 10 3 L) seawater samples are traditionally required to study the partitioning of particle-reactive radionuclides between solution and size-fractionated particulate matter. One of the most frequently used methods to preconcentrate the short-lived isotopes of Th ( 234 Th and 228 Th) from such large volumes of water involves the effective extraction of Th onto two MnO 2 -coated polypropylene cartridges. Determination of dissolved Th activities assumes that the two MnO 2 -coated filter cartridges extract Th uniformly (same extraction efficiency), but this assumption has not been rigorously validated. Any variability in the extraction efficiency of the two cartridges connected in series will directly introduce an error in the determination of final dissolved Th activity. In this article, we evaluated the variability in the extraction efficiency of MnO 2 -coated filter cartridges that were prepared under varying conditions. Thorium-234-spiked seawater was filtered in series through a manifold consisting of six MnO 2 -coated cartridges. From the activities of 234 Th retained in each cartridge, the relative (calculated from the activities in two successive cartridges) and absolute (ratio of 234 Th activity retained to the activity entered) extraction efficiency for each of the cartridges was calculated. At a constant flow rate and constant KMnO 4 saturation, the absolute extraction efficiency varied by -40% (from 54.1 to 93.8%) within the first two filter cartridges, and over 50% (from 32.3 to 89.3%) on all six MnO 2 cartridges. Our results confirm that a uniform extraction efficiency using two filters connected in series is rarely achieved. Using the average extraction efficiency of all cartridges, we propose a new approach that assumes a constant extraction efficiency. This method will reduce the error introduced by the assumption of uniform extraction efficiency in the determination of dissolved Th activities.

Open-File Report↗

Magnitude and Frequency of Rural Floods in the Southeastern United States, through 2006: Volume 2, North Carolina

Reliable estimates of the magnitude and frequency of floods are required for the economical and safe design of transportation and water-conveyance structures. A multistate approach was used to update methods for estimating the magnitude and frequency of floods in rural, ungaged basins in North Carolina, South Carolina, and Georgia that are not substantially affected by regulation, tidal fluctuations, or urban development. In North Carolina, annual peak-flow data available through September 2006 were available for 584 sites; 402 of these sites had a total of 10 or more years of systematic record that is required for at-site, flood-frequency analysis. Following data reviews and the computation of 20 physical and climatic basin characteristics for each station as well as at-site flood-frequency statistics, annual peak-flow data were identified for 363 sites in North Carolina suitable for use in this analysis. Among these 363 sites, 19 sites had records that could be divided into unregulated and regulated/ channelized annual peak discharges, which means peak-flow records were identified for a total of 382 cases in North Carolina. Considering the 382 cases, at-site flood-frequency statistics are provided for 333 unregulated cases (also used for the regression database) and 49 regulated/channelized cases. The flood-frequency statistics for the 333 unregulated sites were combined with data for sites from South Carolina, Georgia, and adjacent parts of Alabama, Florida, Tennessee, and Virginia to create a database of 943 sites considered for use in the regional regression analysis. Flood-frequency statistics were computed by fitting logarithms (base 10) of the annual peak flows to a log-Pearson Type III distribution. As part of the computation process, a new generalized skew coefficient was developed by using a Bayesian generalized least-squares regression model. Exploratory regression analyses using ordinary least-squares regression completed on the initial database of 943 sites resulted in defining five hydrologic regions for North Carolina, South Carolina, and Georgia. Stations with drainage areas less than 1 square mile were removed from the database, and a procedure to examine for basin redundancy (based on drainage area and periods of record) also resulted in the removal of some stations from the regression database. Flood-frequency estimates and basin characteristics for 828 gaged stations were combined to form the final database that was used in the regional regression analysis. Regional regression analysis, using generalized least-squares regression, was used to develop a set of predictive equations that can be used for estimating the 50-, 20-, 10-, 4-, 2-, 1-, 0.5-, and 0.2-percent chance exceedance flows for rural ungaged, basins in North Carolina, South Carolina, and Georgia. The final predictive equations are all functions of drainage area and the percentage of drainage basin within each of the five hydrologic regions. Average errors of prediction for these regression equations range from 34.0 to 47.7 percent. Discharge estimates determined from the systematic records for the current study are, on average, larger in magnitude than those from a previous study for the highest percent chance exceedances (50 and 20 percent) and tend to be smaller than those from the previous study for the lower percent chance exceedances when all sites are considered as a group. For example, mean differences for sites in the Piedmont hydrologic region range from positive 0.5 percent for the 50-percent chance exceedance flow to negative 4.6 percent for the 0.2-percent chance exceedance flow when stations are grouped by hydrologic region. Similarly for the same hydrologic region, median differences range from positive 0.9 percent for the 50-percent chance exceedance flow to negative 7.1 percent for the 0.2-percent chance exceedance flow. However, mean and median percentage differences between the estimates from the previous and curre

North Carolina↗

Overview of the Southern San Andreas Fault Model

This appendix summarizes the data and methodology used to generate the source model for the southern San Andreas fault. It is organized into three sections, 1) a section by section review of the geological data in the format of past Working Groups, 2) an overview of the rupture model, and 3) a manuscript by Biasi and Weldon (in review Bulletin of the Seismological Society of America) that describes the correlation methodology that was used to help develop the ?geologic insight? model. The goal of the Biasi and Weldon methodology is to quantify the insight that went into developing all A faults; as such it is in concept consistent with all other A faults but applied in a more quantitative way. The most rapidly slipping fault and the only known source of M~8 earthquakes in southern California is the San Andreas fault. As such it plays a special role in the seismic hazard of California, and has received special attention in the current Working Group. The underlying philosophy of the current Working Group is to model the recurrence behavior of large, rapidly slipping faults like the San Andreas from observed data on the size, distribution and timing of past earthquakes with as few assumptions about underlying recurrence behavior as possible. In addition, we wish to carry the uncertainties in the data and the range of reasonable extrapolations from the data to the final model. To accomplish this for the Southern San Andreas fault we have developed an objective method to combine all of the observations of size, timing, and distribution of past earthquakes into a comprehensive set of earthquake scenarios that each represent a possible history of earthquakes for the past ~1400 years. The scenarios are then ranked according to their overall consistency with the data and then the frequencies of all of the ruptures permitted by the current Working Group?s segmentation model are calculated. We also present 30-yr conditional probabilities by segment and compare to previous results. A distinctive aspect of the current model is that the probability is higher at both ends of the fault and that the ends have a much greater fraction of smaller events. There is a significant difference in the likelihood of large (M 7.7-8.0) earthquakes along the fault from north to south, with large 1857-like events common on the northern half of the southern San Andreas fault but relatively few M 7.7-8.0 expected on the southern half.

Open-File Report↗

Effects of surface coal mining and reclamation on the geohydrology of six small watersheds in west-central Indiana

The watersheds studied include mined and reclaimed; mined and unreclaimed; and unmined, agricultural land uses, and are each < 3 sq mi in area. Surface water, groundwater, and meteorologic data for the 1981 and 1982 water years were used to describe and compare hydrologic systems of the six watersheds and to identify hydrologic effects of mining and reclamation. Peak discharges were greater at the agricultural watersheds than at the unreclaimed watersheds, primarily because of large final-cut lakes in the unreclaimed watersheds. Annual runoff was greatest at the unreclaimed watersheds, intermediate at the agricultural watersheds, and least at the reclaimed watersheds. Hydrologic effects of mining were identified by comparing the hydrologic systems at mined and unreclaimed watersheds with those at unmined, agricultural watersheds. Comparisons of the hydrologic systems of these watersheds indicate that surface coal mining without reclamation has the potential to increase annual runoff, base flow, and groundwater recharge to the bedrock; reduce peak flow rates and variation in flow; lower the water table in upland areas; change the relation between surface water and groundwater divides; and create numerous, local flow systems in the shallow groundwater. Hydrologic effects of reclamation were identified by comparing the hydrologic systems at mined and reclaimed watersheds with those at mined and unreclaimed watersheds. Reclamation has the potential to decrease annual runoff, base flow, and recharge to the bedrock; increase peak flow rates, variation in flow, and response to thunderstorms; reestablish the premining relation between surface and groundwater divides; and create fewer local flow systems in the shallow groundwater.

Indiana↗