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At least 1,369 records · Page 76Linked to original sources

Ground-water, surface-water, and water-chemistry data, Black Mesa area, northeastern Arizona — 2002-03

The N aquifer is the major source of water in the 5,400-square-mile area of Black Mesa in northeastern Arizona. Availability of water is an important issue in this area because of continued industrial and municipal use, a growing population, and precipitation of about 6 to 14 inches per year. The monitoring program in the Black Mesa area has been operating since 1971 and is designed to determine the long-term effects of ground-water withdrawals from the N aquifer for industrial and municipal uses. The monitoring program includes measurements of (1) ground-water pumping, (2) ground-water levels, (3) spring discharge, (4) surface-water discharge, (5) ground-water chemistry, and (6) periodic testing of ground-water withdrawal meters. In 2002, total ground-water withdrawals were 8,000 acre-feet, industrial use was 4,640 acre-feet, and municipal use was 3,360 acre-feet. From 2001 to 2002, total withdrawals increased by 4 percent, industrial use increased by 2 percent, and municipal use increased by 7 percent. Flowmeter testing was completed for 32 municipal wells in 2003. The median difference between pumping rates for the permanent meter and a test meter for all the sites tested was -2.0 percent. Values ranged from -13.7 percent at Hopi High School no. 2 to +12.9 percent at Shonto PM3. From 2002 to 2003, water levels declined in 5 of 13 wells in the unconfined part of the aquifer, and the median change was 0.0 foot. Water levels declined in 8 of 13 wells in the confined part of the aquifer, and the median change was -1.1 feet. From the prestress period (prior to 1965) to 2003, the median water-level change for 26 wells was -8.3 feet. Median water-level changes were -0.4 foot for 13 wells in the unconfirned part of the aquifer and -60.3 feet for 13 wells in the confined part. Discharges were measured once in 2002 and once in 2003 at four springs. Discharge decreased by 16 percent at Pasture Canyon Spring, increased 10 percent at Moenkopi Spring and 90 percent at an unnamed spring near Dennehotso, and did not change at Burro Spring. For the past 11 years, discharges from the four springs have fluctuated; however, an increasing or decreasing trend is not apparent. Continuous records of surface-water discharge have been collected from 1976 to 2002 at Moenkopi Wash, 1996 to 2002 at Laguna Creek, 1993 to 2002 at Dinnebito Wash, and 1994 to 2002 at Polacca Wash. Median flows for November, December, January, and February of each water year were used as an index of ground-water discharge to those streams. Since 1995, the median winter flows have decreased for Moenkopi Wash, Dinnebito Wash, and Polacca Wash. Since the first continuous record of surface-water discharge in 1997, there is no consistent trend in the median winter flow for Laguna Creek. In 2003, water samples were collected from 12 wells and 4 springs and analyzed for selected chemical constituents. Dissolved-solids concentrations ranged from 118 to 642 milligrams per liter. Water samples from 10 of the wells and from all of the springs had less than 500 milligrams per liter of dissolved solids. There are no appreciable time trends in the chemistry of water samples from 7 wells and 4 springs; 7 wells had more than 8 years of data, and the 4 springs had more than 10 years of data.

Arizona↗

Ground-water, surface-water, and water-chemistry data, Black Mesa area, northeastern Arizona — 2003–04

The N aquifer is the major source of water in the 5,400-square-mile area of Black Mesa in northeastern Arizona. Availability of water is an important issue in this area because of continued industrial and municipal use, a growing population, and precipitation of about 6 to 14 inches per year. The monitoring program in the Black Mesa area has been operating since 1971 and is designed to determine the long-term effects of ground-water withdrawals from the N aquifer for industrial and municipal uses. The monitoring program includes measurements of (1) ground-water pumping, (2) ground-water levels, (3) spring discharge, (4) surface-water discharge, (5) ground-water chemistry, and (6) periodic testing of ground-water withdrawal meters. In 2003, total ground-water withdrawals were 7,240 acre-feet, industrial withdrawals were 4,450 acre-feet, and municipal withdrawals were 2,790 acre-feet. From 2002 to 2003, total withdrawals decreased by 10 percent, industrial withdrawals decreased by 4 percent, and municipal withdrawals decreased by 20 percent. Flowmeter testing was completed for 24 municipal wells in 2004. The median difference between pumping rates for the permanent meter and a test meter for all the sites tested was -2.9 percent. Values ranged from -10.9 percent at Forest Lake NTUA 1 to +7.8 percent at Rough Rock NTUA 2. From 2003 to 2004, water levels declined in 6 of 12 wells in the unconfined part of the aquifer, and the median change was -0.1 foot. Water levels declined in 7 of 11 wells in the confined part of the aquifer, and the median change was -2.7 feet. From the prestress period (prior to 1965) to 2003, the median water-level change for 26 wells was -23.2 feet. Median water-level change were -6.1 feet for 14 wells in the unconfined parts of the aquifer and and -72.1 feet for 12 wells in the confined part. Discharges were measured once in 2003 and once in 2004 at four springs. Discharge stayed the same at Pasture Canyon Spring, increased 9 percent at Moenkopi Spring, decreased 26 percent at an unnamed spring near Dennehotso, and decreased 50 percent at Burro Spring. For the past 12 years, discharges from the four springs have fluctuated; however, an increasing or decreasing trend is not apparent. Continuous records of surface-water discharge have been collected from 1976 to 2003 at Moenkopi Wash, 1996 to 2003 at Laguna Creek, 1993 to 2003 at Dinnebito Wash, and 1994 to 2003 at Polacca Wash. Median flows for November, December, January, and February of each water year were used as an index of ground-water discharge to those streams. Since 1995, the median winter flows have decreased for Moenkopi Wash, Dinnebito Wash, and Polacca Wash. Since the first continuous record of surface-water discharge in 1997, there is no consistent trend in the median winter flow for Laguna Creek. In 2004, water samples were collected from 12 wells and 4 springs and analyzed for selected chemical constituents. Dissolved-solids concentrations ranged from 100 to 649 milligrams per liter. Water samples from 11 of the wells and from all the springs had less than 500 milligrams per liter of dissolved solids. There are no appreciable time trends in the chemistry of water samples from 7 wells and 2 springs; increasing trends in dissolved-solids and chloride concentrations were evident from the more than 10 years of data for 2 springs.

Arizona↗

Ground-water, surface-water, and water-chemistry data, Black Mesa area, northeastern Arizona — 2004–05

The N aquifer is the major source of water in the 5,400-square-mile area of Black Mesa in northeastern Arizona. Availability of water is an important issue in this area because of continued industrial and municipal use, a growing population, and precipitation of about 6 to 14 inches per year. The monitoring program in the Black Mesa area has been operating since 1971 and is designed to determine the long-term effects of ground-water withdrawals from the N aquifer for industrial and municipal uses. The monitoring program includes measurements of (1) ground-water pumping, (2) ground-water levels, (3) spring discharge, (4) surface-water discharge, (5) ground-water chemistry, and (6) periodic testing of ground-water withdrawal meters. In 2004, total ground-water withdrawals were 7,210 acre-feet, industrial withdrawals were 4,370 acre-feet, and municipal withdrawals were 2,840 acre-feet. From 2003 to 2004, total withdrawals decreased by less than 1 percent, industrial withdrawals decreased by 2 percent, and municipal withdrawals increased by 2 percent. From 2004 to 2005, annually measured water levels declined in 6 of 13 wells in the unconfined areas of the aquifer, and the median change was -0.1 foot. Water levels declined in 8 of 12 wells in the confined area of the aquifer, and the median change was -1.2 feet. From the prestress period (prior to 1965) to 2005, the median water-level change for 33 wells was -9.0 feet. Median water-level changes were -0.6 foot for 16 wells in the unconfined areas and -32.0 feet for 17 wells in the confined area. Discharges were measured once in 2004 and once in 2005 at four springs. Discharge increased by 8 percent at Pasture Canyon Spring, decreased by 5 percent at Moenkopi School Spring, increased by 71 percent at an unnamed spring near Dennehotso, and stayed the same at Burro Spring. For the period of record at each spring, discharges from the four springs have fluctuated; however, an increasing or decreasing trend is not apparent. Continuous records of surface-water discharge have been collected from 1976 to 2004 at Moenkopi Wash, 1996 to 2004 at Laguna Creek, 1993 to 2004 at Dinnebito Wash, 1994 to 2004 at Polacca Wash, and August 2004 to December 2004 at Pasture Canyon Spring. Median flows for November, December, January, and February of each water year were used as an index of ground-water discharge to those streams. Since 1995, the median winter flows have decreased for Moenkopi Wash, Dinnebito Wash, and Polacca Wash. Since the first continuous record of surface-water discharge in 1997, there is no consistent trend in the median winter flow for Laguna Creek. In 2005, water samples were collected from 11 wells and 4 springs and analyzed for selected chemical constituents. Dissolved-solids concentrations ranged from 122 to 639 milligrams per liter. Water samples from 9 of the wells and from all the springs had less than 500 milligrams per liter of dissolved solids. There are some long-term trends in the chemistry of water samples from 7 wells having more than 10 years of data and from 2 springs. Rough Rock PM5, Keams Canyon PM2, Second Mesa PM2, and Kayenta PM2 show an increasing trend in dissolved solids; Forest Lake NTUA1 and PWCC 2 show a decreasing trend in dissolved solids; and Kykostmovi PM2 shows a steady trend. Increasing trends in dissolved-solids and chloride concentrations were evident from the more than 11 years of data for 2 springs.

Arizona↗

Hydrogeologic setting and ground water flow beneath a section of Indian River Bay, Delaware

The small bays along the Atlantic coast of the Delmarva Peninsula (Delaware, Maryland, and Virginia) are a valuable natural resource, and an asset for commerce and recreation. These coastal bays also are vulnerable to eutrophication from the input of excess nutrients derived from agriculture and other human activities in the watersheds. Ground water discharge may be an appreciable source of fresh water and a transport pathway for nutrients entering the bays. This paper presents results from an investigation of the physical properties of the surficial aquifer and the processes associated with ground water flow beneath Indian River Bay, Delaware. A key aspect of the project was the deployment of a new technology, streaming horizontal resistivity, to map the subsurface distribution of fresh and saline ground water beneath the bay. The resistivity profiles showed complex patterns of ground water flow, modes of mixing, and submarine ground water discharge. Cores, gamma and electromagnetic-induction logs, and in situ ground water samples collected during a coring operation in Indian River Bay verified the interpretation of the resistivity profiles. The shore-parallel resistivity lines show subsurface zones of fresh ground water alternating with zones dominated by the flow of salt water from the estuary down into the aquifer. Advective flow produces plumes of fresh ground water 400 to 600 m wide and 20 m thick that may extend more than 1 km beneath the estuary. Zones of dispersive mixing between fresh and saline ground water develop on the upper, lower, and lateral boundaries of the the plume. the plumes generally underlie small incised valleys that can be traced landward to stream draining the upland. The incised valleys are filled with 1 to 2 m of silt and peat that act as a semiconfining layer to restrict the downward flow of salt water from the estuary. Active circulation of both the fresh and saline ground water masses beneath the bay is inferred from the geophysical results and supported by geochemical data.

Delaware↗

Utilization of ground water in the Santa Maria Valley area, California

Overdraft in the Santa Maria Valley ground-water basin since about 1946 has resulted in a significant decline in water levels throughout the basin as ground water has been removed from storage. In 1959 approximately 2,200,000 acre-feet of ground water was in storage above sea level in the ground-water reservoir. Estimates of storage depletion are not consistent with estimates of groundwater recharge and discharge. The natural perennial yield of the basin probably is about 50.000 acre-feet, on the basis of estimated recharge and natural discharge. The augmented perennial yield probably is about 70,000 acre-feet and includes 21,200 acre-feet of water per year released at Twitchell Dam. Storage depletion, not estimated in the seaward ends of the aquifers, will result as the fresh watersea water interface moves landward in response to the continuing decrease in hydraulic gradient in the aquifer system. Evidence of sea-water intrusion into the basin has not been observed, but limited sea-water encroachment may have occurred at the offshore ends of the aquifers. Additional observation wells will be necessary to provide supplemental data to insure that hydraulic heads and gradients in the deeper aquifers are properly monitored.

Water Supply Paper↗

A summary of ground-water pumpage in the Central Valley, California, 1961-77

In the Central Valley of California, a great agricultural economy has been developed in a semiarid environment. This economy is supported by imported surface water and 9 to 15 million acre-feet per year of ground water. Estimates of ground-water pumpage computed from power consumption have been compiled and summarized. Under ideal conditions, the accuracy of the methods used is about 3 percent. This level of accuracy is not sustained over the entire study area. When pumpage for the entire area is mapped, the estimates seem to be consistent areally and through time. A multiple linear-regression model was used to synthesize data for the years 1961 through 1977, when power data were not available. The model used a relation between ground-water pumpage and climatic indexes to develop a full suite of pumpage data to be used as input to a digital ground-water model, one of the products of the Central Valley Aquifer Project. Statistical analysis of well-perforation data from drillers ' logs and water-temperature data was used to determine the percentage of pumpage that was withdrawn from each of two horizontal layers. (USGS)

Water-Resources Investigations Report↗

Use of ground water for irrigation in Seward County, Nebraska in 1971

Use of ground water for irrigation in Seward County west of the Big Blue River increased tremendously from 1945 to 1971. During that period, the number of irrigation wells increased from 5 to 614. Ground-water withdrawals prior to 1971 are estimated to have reduced ground-water storage by about 270,000 acre-feet, and withdrawals during 1971 continued to reduce storage. The values for changes in storage were computed from weighted-average net differences in ground-water levels. In 1971, average pumpage from the 32 wells for which well yield and hours of pumping were recorded indicates that pumpage from all wells totaled about 83,000 acre-feet.

Nebraska↗

Recovery of Ground-Water Levels From 1988 to 2003 and Analysis of Potential Water-Supply Management Options in Critical Area 1, East-Central New Jersey

Water levels in four confined aquifers in the New Jersey Coastal Plain within Water Supply Critical Area 1 have recovered as a result of reductions in ground-water withdrawals initiated by the State in the late 1980s. The aquifers are the Wenonah-Mount Laurel, the Upper and Middle Potomac-Raritan-Magothy, and Englishtown aquifer system. Because of increased water demand due to increased development in Monmouth, Ocean, and Middlesex Counties, five base and nine alternate management models were designed for the four aquifers to evaluate the effects resulting from potential reallocation of part of the Critical Area 1 reductions in withdrawals. The change in withdrawals and associated water-level changes in the aquifers for 1988-2003 are discussed. Generally, withdrawals decreased 25 to 30 Mgal/d (million gallons per day), and water levels increased 0 to 80 ft (feet). The Regional Aquifer-System Analysis (RASA) ground-water-flow model of the New Jersey Coastal Plain developed by the U.S. Geological Survey was used to simulate ground-water flow and optimize withdrawals using the Ground-Water Management Process (GWM) for MODFLOW. Results of the model were used to evaluate the effects of several possible water-supply management options in order to provide the information to water managers. The optimization method, which provides a means to set constraints that support mandated hydrologic conditions, then determine the maximum withdrawals that meet the constraints, is a more cost-effective approach than simulating a range of withdrawals to determine the effects on the aquifer system. The optimization method is particularly beneficial for a regional-scale study of this kind because of the large number of wells to be evaluated. Before the model was run, a buffer analysis was done to define an area with no additional withdrawals that minimizes changes in simulated streamflow in aquifer outcrop areas and simulated movement of ground water toward the wells from areas of possible high chloride concentrations in the northern and southern parts of the Critical Area. Five base water-supply management models were developed. Each management model has an objective function, decision variables, and constraints. Two of the five management models were test cases: clean slate option and reallocation from the Wenonah-Mount Laurel aquifer and Englishtown aquifer system to small volume wells for potable water use. Nine other models also were developed as part of a trade-off analysis between withdrawal amounts and constraint values. The 14 management models included current (2003) or regularly spaced well locations with variations on the constraints of ground-water head, drawdown, velocity at the 250-mg/L (milligram per liter) isochlor, and withdrawal rate. Results of each management model were evaluated in terms of withdrawals, heads, saltwater intrusion, and source of water by aquifer. Each trade-off curve was defined by using six to nine separate management model runs. Results of the management models designed in this study indicate that a withdrawal reallocation of 5 to 20 Mgal/d within Critical Area 1 would increase the area of heads below -30 ft and the velocity at the 250-mg/L isochlor by up to 4 times that of the simulated 2003 results; the range of values are 0 to 521 square miles and 1 to 20 feet per year, respectively. The increase in area of heads below -30 ft was larger in the Middle Potomac-Raritan-Magothy aquifer than in other aquifers because that area was negligible in 2003. The range of modeled withdrawals is closely tied to management-model design. Interpretation of management model results is provided as well as a discussion of limitations.

Scientific Investigations Report↗

Ground water investigations in Utah to June 30, 1936: A part of Chapter 8 in Twentieth biennial report of the State Engineer to the governor of Utah: 1935-1936

During the past few years of drouth the importance of ground-water supplies has become more fully appreciated. During this time, because of subnormal replenishment of the ground-water reservoirs and the increased withdrawals from wells, the ground-water levels have declined in most developed areas in the State, a condition which has made the well owners acutely aware that ground water is not inexhaustible. Numerous cases of contention between well owners resulted in increased demands for adequate regulation of the appropriation and use of ground water. Realizing that more information concerning the ground water of the State was imperative, not only to administer the ground-water regulations but to prepare for the conservation and replenishment of existing supplies and development of new supplies, the State Legislature enacted, during its 1935 session, Senate Bill 206, which authorized the State Engineer to make an investigation of the ground water of the State. To provide for the expenses of the investigation, the bill allotted /$10,000 to the State Engineer, this sum to be matched by a State or Federal organization, and the investigation to be carried out co-operatively during the biennium beginning July 1, 1935. A co-operative agreement between the State Engineer and the United States Geological Survey was made on July 1, 1935.

Utah↗

Ground-water, surface-water, and water-chemistry data, Black Mesa area, northeastern Arizona: 1998

The Black Mesa monitoring program is designed to document long-term effects of ground-water pumping from the N aquifer by industrial and municipal users. The N aquifer is the major source of water in the 5,400-square-mile Black Mesa area, and the ground water occurs under confined and unconfined conditions. Monitoring activities include continuous and periodic measurements of (1) ground-water pumpage from the confined and unconfined parts of the aquifer, (2) ground-water levels in the confined and unconfined parts of the aquifer, (3) surface-water discharge, (4) flowmeter tests, and (5) ground-water and surface-water chemistry. In 1998, ground-water withdrawals for industrial and municipal use totaled about 7,060 acre-feet, which is less than a 1 percent decrease from 1997. Pumpage from the confined part of the aquifer decreased by less than 1 percent to 5,470 acre-feet, and pumpage from the unconfined part of the aquifer increased by less than 1 percent to 1,590 acre-feet. Water-level declines in the confined part of the aquifer were recorded in 10 of 14 wells during 1998, and the median change from 1997 was a decline of 3.0 feet as opposed to a rise of 0.2 feet for the change from 1996 to 1997. Water-level declines in the unconfined part of the aquifer were recorded in 9 of 16 wells, and the median change from 1997 was 0.0 feet, which is the same as the median change from 1996 to 1997. Of the 35 pumpage meters on municipal wells that were tested, the difference between metered and tested discharge ranged from +6.3 to -19.6 percent. The average difference was about -3.4 percent. Five of the meters exceeded the allowable difference (10 percent) and should be repaired or replaced. The low-flow discharge at the Moenkopi streamflow-gaging station ranged from 2.6 to 4.7 cubic feet per second in 1998. Streamflow-discharge measurements also were made at Laguna Creek, Dinnebito Wash, and Polacca Wash during 1998. The low-flow discharge ranged from 0.41 to 5.1 cubic feet per second at Laguna Creek, 0.32 to 0.44 cubic feet per second at Dinnebito Wash, and 0.13 to 0.36 cubic feet per second at Polacca Wash. Discharge was measured at four springs. Discharge from Moenkopi School Spring decreased by about 1.1 gallons per minute from the measurement in 1997. Discharge from an unnamed spring near Dennehotso decreased by 4.6 gallons per minute from the measurement made in 1997. Discharge increased slightly at Burro Spring and decreased by about 1 gallon per minute at Pasture Canyon Spring. Regionally, long-term water-chemistry data for wells and springs have remained stable.

Arizona↗

Reconnaissance of the ground-water resources of the upper Fremont River valley, Wayne County, Utah

This report presents the results of an investigation of the ground-water resources of the upper Fremont River valley, Utah, which was carried out during the period July 1966-June 1967, by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights. The purpose of the investigation was to determine: the source, occurrence, availability, approximate quantity, movement, and chemical quality of ground water in the valley; the recharge to and discharge from the ground-water reservoir; the extent and effects of use and development on the ground-water resources; the relation of ground water to streamflow; and if and where additional studies are needed. The report is concerned primarily with ground water in the valley fill and adjacent volcanic rocks and secondarily with the general hydrology of the upper Fremont River valley drainage basin. The field investigation was made mostly during the summer and fall of 1966. Data were collected for 63 wells and 16 springs in the valley. Records for wells and springs are given in table 4; drillers' logs of selected wells are given in table 5, and well locations are shown in figure 5. All the wells (except a few small-discharge wells) and all major springs were visited. The specific conductance of water was determined at most wells and springs; chemical analyses were made of water from selected wells and springs. Conductance data are included in table 4 and chemical analyses are given in table 6. The yield of water from wells and the water levels or artesian pressures were measured or estimated. Water-level measurements were made at monthly intervals 6 at 10 selected wells. Altitudes of the land surface at wells and springs were estimated from topographic maps or by hand leveling or determined by altimeter. Aerial photographs were used in the field to locate wells, boundaries of meadows or cultivated areas, edge of valley fill, and other features.

Utah↗

Nitrate and selected pesticides in ground water of the Mid-Atlantic region

Data from more than 850 sites were compiled and analyzed to document the occurrence of nitrate and pesticides in ground water of the Mid-Atlantic region as part of the Mid-Atlantic Integrated Assessment program of the U.S. Environmental Protection Agency. Only those data collected by the U.S. Geological Survey as part of regional networks between October 1985 and September 1996 (inclusive) were used in the analyses, and the data were examined to ensure analytical results are not biased toward sites at the same location or sites sampled multiple times during this period. Regional data are available for most of the Mid-Atlantic region but large spatial gaps in available data do exist. Nitrate was detected in nearly three-quarters of the samples for which it was analyzed, commonly at levels that suggest anthropogenic sources. Ten percent of samples contained nitrate at concentrations exceeding the Federal Maximum Contaminant Level (MCL) of 10 milligrams per liter as nitrogen. Pesticide compounds (including atrazine, metolachlor, prometon, simazine, and desethylatrazine, an atrazine degradate) were detected in about half of the samples for which they were analyzed, but rarely at concentrations exceeding established MCL?s. The most commonly detected pesticide compounds were desethylatrazine and atrazine. The occurrence of nitrate and pesticides in ground water of the Mid-Atlantic region is related to land cover and rock type. Likely sources of nitrate and pesticides to ground water include agricultural and urban land-use practices; rock type affects the movement of these compounds into and through the ground-water system. Nitrate concentrations in the compiled data set are significantly higher in ground water in agricultural areas than in urban or forested areas, but concentrations in areas of row crops are statistically indistinguishable from those in areas of pastures. Detection frequencies of atrazine, desethylatrazine, and simazine are indistinguishable among urban areas, row crops, and pastures. Prometon was most commonly detected in ground water in urban areas. Ground-water samples from forested areas typically contained the lowest concentrations of nitrate and detection frequencies of pesticides. Concentrations of nitrate and detection frequencies of pesticides were significantly higher in samples from carbonate rocks than in those from any other rock type. Most areas of the Mid-Atlantic region that are underlain by carbonate rocks have been developed for agricultural or urban use and the solution channels that are typical of carbonate rocks allow for relatively rapid transport of surficial contaminants throughout the ground-water system. Nitrate concentrations in unconsolidated aquifers were among the lowest for all rock types, possibly because of denitrification in organic-rich subsoils and shallow sediments.

Water-Resources Investigations Report↗

Hydrology and ground-water quality in the mine workings within the Picher Mining District, Northeastern Oklahoma, 2002-03

The Picher mining district of northeastern Ottawa County, Oklahoma, was a major site of mining for lead and zinc ores in the first half of the 20th century. The primary source of lead and zinc were sulfide minerals disseminated in the cherty limestones and dolomites of the Boone Formation of Mississippian age, which comprises the Boone aquifer. Ground water in the aquifer and seeping to surface water in the district has been contaminated by sulfate, iron, lead, zinc, and several other metals. The U.S. Geological Survey, in cooperation with the Oklahoma Department of Environmental Quality, investigated hydrology and ground-water quality in the mine workings in the mining district, as part of the process to aid water managers and planners in designing remediation measures that may restore the environmental quality of the district to pre-mining conditions. Most ground-water levels underlying the mining district had similar altitudes, indicating a large degree of hydraulic connection in the mine workings and overlying aquifer materials. Recharge-age dates derived from concentrations of chlorofluorocarbons and other dissolved gases indicated that water in the Boone aquifer may flow slowly from the northeast and southeast portions of the mining district. However, recharge-age dates may have been affected by the types of sites sampled, with more recent recharge-age dates being associated with mine-shafts, which are more prone to atmospheric interactions and surface runoff than the sampled airshafts. Water levels in streams upstream from the confluence of Tar and Lytle Creeks were several feet higher than those in adjacent portions of the Boone aquifer, perhaps due to low-permeability streambed sediments and indicating the streams may be losing water to the aquifer in this area. From just upstream to downstream from the confluence of Tar and Lytle Creeks, surface-water elevations in these streams were less than those in the surrounding Boone aquifer, indicating that seepage from the aquifer to downstream portions of Tar Creek was much more likely. Water properties and major-ion concentrations indicate that water in the mining area was very hard, with large concentrations of dissolved solids that increased from areas of presumed recharge toward areas with older ground water. Most of the ground-water samples, particularly those from the airshafts, had dissolved-oxygen concentrations less than 1.0 milligram per liter. Small concentrations of dissolved oxygen may have been introduced during the sampling process. The small dissolved-oxygen concentrations were associated with samples containing large iron concentrations that indicates possible anoxic conditions in much of the aquifer. Ground water in the mining district was dominated by calcium, magnesium, and sulfate. Sodium concentrations tended to increase relative to calcium and magnesium concentrations. Ground-water samples collected in 2002-03 had large concentrations of many trace elements. Larger concentrations of metals and sulfate occurred in ground water with smaller pHs and dissolved-oxygen concentrations. Iron was the metal with the largest concentrations in the ground-water samples, occurring at concentrations up to 115,000 micrograms per liter. Cadmium, lead, manganese, zinc, and the other analyzed metals occurred in smaller concentrations in ground water than iron. However, larger cadmium concentrations appeared to be associated with sites that have small iron concentrations and more oxygenated waters. This is noteworthy because the small sulfate and iron concentrations in these waters could lead to conclusions that the waters are less contaminated than waters with large sulfate and iron concentrations. Ground-water quality in the mining district was compared with subsets of samples collected in 1983-85 and in 2002.

Oklahoma↗

Probability of detecting atrazine/desethyl-atrazine and elevated concentrations of nitrate (NO2+NO3-N) in ground water in the Idaho part of the upper Snake River basin

Draft Federal regulations may require that each State develop a State Pesticide Management Plan for the herbicides atrazine, alachlor, cyanazine, metolachlor, and simazine. This study developed maps that the Idaho State Department of Agriculture might use to predict the probability of detecting atrazine and desethyl-atrazine (a breakdown product of atrazine) in ground water in the Idaho part of the upper Snake River Basin. These maps can be incorporated in the State Pesticide Management Plan and help provide a sound hydrogeologic basis for atrazine management in the study area. Maps showing the probability of detecting atrazine/desethyl-atrazine in ground water were developed as follows: (1) Ground-water monitoring data were overlaid with hydrogeologic and anthropogenic data using a geographic information system to produce a data set in which each well had corresponding data on atrazine use, depth to ground water, geology, land use, precipitation, soils, and well depth. These data then were downloaded to a statistical software package for analysis by logistic regression. (2) Individual (univariate) relations between atrazine/desethyl-atrazine in ground water and atrazine use, depth to ground water, geology, land use, precipitation, soils, and well depth data were evaluated to identify those independent variables significantly related to atrazine/ desethyl-atrazine detections. (3) Several preliminary multivariate models with various combinations of independent variables were constructed. (4) The multivariate models which best predicted the presence of atrazine/desethyl-atrazine in ground water were selected. (5) The multivariate models were entered into the geographic information system and the probability maps were constructed. Two models which best predicted the presence of atrazine/desethyl-atrazine in ground water were selected; one with and one without atrazine use. Correlations of the predicted probabilities of atrazine/desethyl-atrazine in ground water with the percent of actual detections were good; r-squared values were 0.91 and 0.96, respectively. Models were verified using a second set of groundwater quality data. Verification showed that wells with water containing atrazine/desethyl-atrazine had significantly higher probability ratings than wells with water containing no atrazine/desethylatrazine (p <0.002). Logistic regression also was used to develop a preliminary model to predict the probability of nitrite plus nitrate as nitrogen concentrations greater than background levels of 2 milligrams per liter. A direct comparison between the atrazine/ desethyl-atrazine and nitrite plus nitrate as nitrogen probability maps was possible because the same ground-water monitoring, hydrogeologic, and anthropogenic data were used to develop both maps. Land use, precipitation, soil hydrologic group, and well depth were significantly related with atrazine/desethyl-atrazine detections. Depth to water, land use, and soil drainage were signifi- cantly related with elevated nitrite plus nitrate as nitrogen concentrations. The differences between atrazine/desethyl-atrazine and nitrite plus nitrate as nitrogen relations were attributed to differences in chemical behavior of these compounds in the environment and possibly to differences in the extent of use and rates of their application.

Idaho↗

Design, revision, and application of ground-water flow models for simulation of selected water-management scenarios in the coastal area of Georgia and adjacent parts of South Carolina and Florida

Ground-water flow models of the Floridan aquifer system in the coastal area of Georgia and adjacent parts of South Carolina and Florida, were revised and updated to ensure consistency among the various models used, and to facilitate evaluation of the effects of pumping on the ground-water level near areas of saltwater contamination. The revised models, developed as part of regional and areal assessments of ground-water resources in coastal Georgia, are--the Regional Aquifer-System Analysis (RASA) model, the Glynn County area (Glynn) model, and the Savannah area (Savannah) model. Changes were made to hydraulic-property arrays of the RASA and Glynn models to ensure consistency among all of the models; results of theses changes are evidenced in revised water budgets and calibration statistics. Following revision, the three models were used to simulate 32 scenarios of hypothetical changes in pumpage that ranged from about 82 million gallons per day (Mgal/d) lower to about 438 Mgal/d higher, than the May 1985 pumping rate of 308 Mgal/d. The scenarios were developed by the Georgia Department of Natural Resources, Environmental Protection Division and the Chatham County-Savannah Metropolitan Planning Commission to evaluate water-management alternatives in coastal Georgia. Maps showing simulated ground-water-level decline and diagrams presenting changes in simulated flow rates are presented for each scenario. Scenarios were grouped on the basis of pumping location--entire 24-county area, central subarea, Glynn-Wayne-Camden County subarea, and Savannah-Hilton Head Island subarea. For those scenarios that simulated decreased pumpage, the water level at both Brunswick and Hilton Head Island rose, decreasing the hydraulic gradient and reducing the potential for saltwater contamination. Conversely, in response to scenarios of increased pumpage, the water level at both locations declined, increasing the hydraulic gradient and increasing the potential for saltwater contamination. Pumpage effects on ground-water levels and related saltwater contamination at Brunswick and Hilton Head Island generally diminish with increased distance from these areas. Additional development of the Upper Floridan aquifer may be possible in parts of the coastal area without affecting saltwater contamination at Brunswick or Hilton Head Island, due to the presence of two hydrologic boundaries--the Gulf Trough, separating the northern and central subareas; and the hypothesized Satilla Line, separating the central and southern subareas. These boundaries diminish pumpage effects across them; and may enable greater ground-water withdrawal in areas north of the Gulf Trough and south of the Satilla Line without producing appreciable drawdown at Brunswick or Hilton Head Island.

Florida, Georgia, South Carolina↗

Ammonia in ground water from the Mississippi River alluvium, Fort Madison, Iowa

The U.S. Geological Survey, in cooperation with the City of Fort Madison, conducted a study of the potential sources and possible processes that might produce ammonia in ground water from the Mississippi River alluvium near Fort Madison, Iowa. High ammonia concentrations of 3.0 to 6.4 milligrams per liter were detected in water produced from municipal well Fort Madison #4 from 1992 through 1996. Total organic carbon concentrations of about 5 milligrams per liter were also reported during the same time period. Water-level measurements from two municipal wells and one well at Iowa State Penitentiary were used to determine that the general direction of ground-water flow during the two days of sampling was from northeast to southwest toward wells Fort Madison #4 and Fort Madison #5. Continuous pumping of other nearby wells probably influenced the direction of ground-water flow on these days. Because of a till confining unit separating the Mississippi River and the alluvial aquifer, it is uncertain to what extent induced recharge occurs to the alluvial aquifer from the river. Water samples were collected from three municipal wells, two industrial wells, one watersupply well at the Iowa State Penitentiary, one domestic well, two creeks, and the Mississippi River. Tritium analytical results indicate that the time of recharge was after 1953 for water from the municipal wells (where tritium samples were collected). The ammonia concentration, 5.1 milligrams per liter, was considerably higher in ground water collected from well Fort Madison #4 compared to samples collected from other wells. The dissolved organic carbon concentration was also highest in ground water collected from well Fort Madison #4 (5.5 milligrams per liter) although samples from other wells were also relatively high, 2.6 to 5.3 milligrams per liter. The most likely process producing the high ammonia concentration in ground water in the vicinity of well Fort Madison #4 is decomposition of organic matter (ammonification). Nitrogen isotope values, when compared to nitrogen isotope values found in ground water in the vicinity of some of the other wells, indicate the possibility that a higher percentage of the ammonia found in ground water in the vicinity of well Fort Madison #4 may be from human and(or) other animal wastes. Higher concentrations of dissolved phosphorus, orthophosphate, and a higher chloride-to-sodium mole ratio found in ground water sampled from well Fort Madison #4 could be indicative of a sewage or septic source. Potential sources include existing or abandoned septic systems, leaking sanitary sewer lines, commercial or residential waste-disposal sites, and agricultural runoff upgradient from well Fort Madison #4, or possibly, bed sediments of the Mississippi River.

Iowa↗

Studying ground water under Delmarva coastal bays using electrical resistivity

Fresh ground water is widely distributed in subsurface sediments below the coastal bays of the Delmarva Peninsula (Delaware, Maryland, and Virginia). These conditions were revealed by nearly 300 km of streamer resistivity surveys, utilizing a towed multichannel cable system. Zones of high resistivity displayed by inversion modeling were confirmed by vibradrilling investigations to correspond to fresh ground water occurrences. Fresh water lenses extended from a few hundred meters up to 2 km from shore. Along the western margins of coastal bays in areas associated with fine-grained surficial sediments, high-resistivity layers were widespread and were especially pronounced near tidal creeks. Fresh ground water layers were less common along the eastern barrier-bar margins of the bays, where sediments were typically sandy. Mid-bay areas in Chincoteague Bay, Maryland, did not show evidence of fresh water. Indian River Bay, Delaware, showed complex subsurface salinity relationships, including an area with possible hypersaline brines. The new streamer resistivity system paired with vibradrilling in these investigations provides a powerful approach to recovering information required for extension of hydrologic modeling of shallow coastal aquifer systems into offshore areas.

Delaware, Maryland, Virginia↗

The relation between fresh and salty ground water in southern Nassau and southeastern Queens counties, Long Island, New York

An investigation of the geology and ground - water conditions in a part of southwestern Long Island , including the construction of 8 deep and 5 shallow test and observation wells, has been completed by the Geological Survey in cooperation with the Nassau County Department of Public Works and the New York State Water Power and Control Commission. In this area are four main water -bearing units of Late Cretaceous and Pleistocene age. Ground water having a higher than normal salt content is encountered in some wells that penetrate the upper three units. Although the presence of this water constitutes a potential threat, existing fresh - water supplies apparently are in little immediate danger under present conditions. The " salty " ground water has chloride concentrations ranging from about 40 to 18,000 ppm (parts per million), generally more than about 2,000 ppm. It occurs in several bodies, seaward of and beneath the fresh water in the respective aquifers, and is in contact with the fresh water through zones of diffusion. The largest salt- water body, confined under artesian pressure, is in the Jameco gravel and the Magothy (?) formation beneath extreme southwestern Nassau County and adjoining southeastern Queens County . This body is thought to have occupied a substantial part of its present extent since at least 1895. It probably has been and is now encroaching, very slowly, because of increased pumping from the fresh - water bodies and possibly as a result of a postglacial rise of sea level. The rate of encroachment under present conditions probably is less than 100 feet per year. Application of the Ghyben-Herzberg principle to compute depths to the contact between salty and fresh ground water was found to give erroneous results. More accurate depths and a clearer understanding of the relation between heads in adjoining bodies of fresh and salty ground water are obtained by use of a formula adapted from one given by M. King Hubbert.

New York↗