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Report of the Interagency biological methods workshop

The U.S. Geological Survey hosted the Interagency Biological Methods Workshop in Reston, Virginia, during June 22-23, 1993. The purposes of the workshop were to (1) promote better communication among Federal agencies that are using or developing biological methods in water-quality assessment programs for streams and rivers, and (2) facilitate the sharing of data and interagency collaboration. The workshop was attended by 45 biologists representing numerous Federal agencies and programs, and a few regional and State programs that were selected to provide additional perspectives. The focus of the workshop was community assessment methods for fish, invertebrates, and algae; physical habitat characterization; and chemical analyses of biological tissues. Charts comparing program objectives, design features, and sampling methods were compiled from materials that were provided by participating agencies prior to the workshop and formed the basis for small workgroup discussions. Participants noted that differences in methods among programs were often necessitated by differences in program objectives. However, participants agreed that where programs have identified similar data needs, the use of common methods is beneficial. Opportunities discussed for improving data compatibility and information sharing included (1) modifying existing methods, (2) adding parameters, (3) improving access to data through shared databases (potentially with common database structures), and (4) future collaborative efforts that range from research on selected protocol questions to followup meetings and continued discussions.

Open-File Report↗

Water-quality assessment and macroinvertebrate data for the Upper Yampa River watershed, Colorado, 1975 through 2009

A study was initiated in 2009 by the U.S. Geological Survey (USGS), in cooperation with Routt County, the Colorado Water Conservation Board, and the City of Steamboat Springs, to compile and analyze historic water-quality data and assess water-quality conditions in the Upper Yampa River watershed (UYRW) in northwestern Colorado. Water-quality data for samples collected by federal, state, and local agencies for various periods from 1975 through 2009 were compiled and assessed for streams, lakes, reservoirs, and groundwater in the UYRW, including the Elkhead Creek subwatershed and the Yampa River watershed that is upstream from Elkhead Creek. For selected physical-property and chemical-constituent data for samples collected from surface-water sites and groundwater wells in the UYRW, this report: (1) characterizes available data through statistical summaries, (2) analyzes the spatial and temporal distribution of water-quality conditions, (3) identifies temporal trends in water quality, where possible, (4) provides comparisons to federal and state water-quality standards and recommendations, and (5) identifies factors affecting the quality of water. In addition, the availability and characteristics of macroinvertebrate data collected in the UYRW are described.

Colorado↗

Geohydrology and quality of water in aquifers in Lucas, Sandusky, and Wood counties, northwestern Ohio

The hydrology and quality of ground water were evaluated for the surficial sand and carbonate aquifers in northwestern Ohio. A locally important surficial sand aquifer in western Lucas County was evaluated on the basis of data from 10 wells completed in undeveloped and developed areas. The carbonate aquifer in Silurian and Devonian bedrock at its northernmost extent on the Ohio mainland was evaluated on the basis of data from previous studies and data from 466 wells and 11 springs. Most data are for the period 1985-88. The unconfined surficial sand aquifer is less than 50 ft. (feet) thick. Clay-rich drift, which restricts vertical movement of water, underlines the aquifer. Recharge is from precipitation, and discharge is by evapotranspiration and by flow to local streams and drainage ditches. Water levels are generally 2 to 8 ft. below land surface and fluctuate a total of about 3.5 ft. seasonally in a forested area. Concentrations of iron and manganese in ground water are excessive in some areas. Waters from shallow drive-point wells in residential areas contained larger concentrations of dissolved solids, hardness, sodium, and chloride than did waters from identical wells in undeveloped areas. The presence of nitrate nitrogen an other selected constituents in ground water in residential areas, and the absence of these constituents in ground water in undeveloped areas, indicate that the surficial sand aquifer has been affected by development. In carbonate aquifer, fractures, bedding-plane joints, and other secondary openings are the principal water-bearing zones. These zones can be areally and stratigraphically separated by low-permeability rock. Leaky artesian or semiconfined conditions predominate beneath most of the 1,400-mi? study area. The aquifer is confined by relatively impermeable underlying shale of Silurian age and overlying clay-rich drift of Quaternary age. Unproductive strata, including evaporites, within the sequence of carbonate rocks also confine some water-bearing zones. The carbonate aquifer is part of a regional ground-water-flow system; however, subsystems such as the eastern karst and central outcrops are locally important. The potentiometric surface indicates that recharge from areas south and west of the study area flows toward discharge areas along major rivers (Maumee, Portage, and Sandusky) , to a buried bedrock valley in central Sandusky County, and to springs and flowing wells. The potentiometric surface flattens markedly near the southern shore of Lake Erie, where ground-water levels approximate those of the lake, indicating a hydraulic connection between the lake and the aquifer. Hydrogeologic characteristics and water-quality data indicate that Lake Erie is not a major source of recharge to the aquifer. Ground-water ages inferred from tritium concentrations and potentiometric-surface maps indicate that recharge from precipitation enters the aquifer by subsurface drainage in karstified strata in eastern Sandusky County and by infiltration in shallow bedrock areas where drift is less than 20 ft. thick. The quality of water in the carbonate aquifer is described with reference to 52 properties and constituents that characterize chemical, radiochemical, bacteriologic, and physical conditions. Ground-water samples from 135 wells and 11 springs are used in the characterization. On the basis of these data, water from the aquifer is generally suitable for drinking and for most domestic purposes. The most areally widespread aesthtic factors limiting the use of ground water are hardness, concentrations of dissolved solids, sulfate and iron, and the presence of hydrogen sulfide. Selected bacteria are commonly present and may compromise the potability of water from the aquifer. Coliform bacteria from surface sources were found in 47 of 143 water samples. Analyses for total coliform bacteria indicate that 36 of the 125 samples from wells maintained for potable supply have bacteria counts of 4

Water-Resources Investigations Report↗

Seasonal and interannual variations of atmospheric CO2 and climate

Interannual variations of atmospheric CO 2 concentrations at Mauna Loa are almost masked by the seasonal cycle and a strong trend; at the South Pole, the seasonal cycle is small and is almost lost in the trend and interannual variations. Singular-spectrum analysis (SSA) is used here to isolate and reconstruct interannual signals at both sites and to visualize recent decadal changes in the amplitude and phase of the seasonal cycle. Analysis of the Mauna Loa CO 2 series illustrates a hastening of the CO 2 seasonal cycle, a close temporal relation between Northern Hemisphere (NH) mean temperature trends and the amplitude of the seasonal CO 2 cycle, and tentative ties between the latter and seasonality changes in temperature over the NH continents. Variations of the seasonal CO 2 cycle at the South Pole differ from those at Mauna Loa: it is phase changes of the seasonal cycle at the South Pole, rather than amplitude changes, that parallel hemispheric and global temperature trends. The seasonal CO 2 cycles exhibit earlier occurrences of the seasons by 7 days at Mauna Loa and 18 days at the South Pole. Interannual CO 2 variations are shared at the two locations, appear to respond to tropical processes, and can be decomposed mostly into two periodicities, around (3 years) -1 and (4 years) -1 , respectively. Joint SSA analyses of CO 2 concentrations and tropical climate indices isolate a shared mode with a quasi-triennial (QT) period in which the CO 2 and sea-surface temperature (SST) participation are in phase opposition. The other shared mode has a quasi-quadrennial (QQ) period and CO 2 variations are in phase with the corresponding tropical SST variations throughout the tropics. Together these interannual modes exhibit a mean lag between tropical SSTs and CO 2 variations of about 6–8 months, with SST leading. Analysis of the QT and QQ signals in global gridded SSTs, joint SSA of CO 2 and δ13C isotopic ratios, and SSA of CO 2 and NH-land temperatures indicate that the QT variations in CO 2 mostly reflect upwelling variations in the eastern tropical Pacific. QQ variations are dominated by the CO 2 signature of terrestrial-ecosystem response to global QQ climate variations. Climate variations associated with these two interannual components of tropical variability have very different effects on global climate and, especially, on terrestrial ecosystems and the carbon cycle.

Tellus, Series B: Chemical and Physical Meteorolog↗

A first-order analysis of the potential role of CO2 fertilization to affect the global carbon budget: A comparison of four terrestrial biosphere models

We compared the simulated responses of net primary production, heterotrophic respiration, net ecosystem production and carbon storage in natural terrestrial ecosystems to historical (1765 to 1990) and projected (1990 to 2300) changes of atmospheric CO2 concentration of four terrestrial biosphere models: the Bern model, the Frankfurt Biosphere Model (FBM), the High-Resolution Biosphere Model (HRBM) and the Terrestrial Ecosystem Model (TEM). The results of the model intercomparison suggest that CO2 fertilization of natural terrestrial vegetation has the potential to account for a large fraction of the so-called 'missing carbon sink' of 2.0 Pg C in 1990. Estimates of this potential are reduced when the models incorporate the concept that CO2 fertilization can be limited by nutrient availability. Although the model estimates differ on the potential size (126 to 461 Pg C) of the future terrestrial sink caused by CO2 fertilization, the results of the four models suggest that natural terrestrial ecosystems will have a limited capacity to act as a sink of atmospheric CO2 in the future as a result of physiological constraints and nutrient constraints on NPP. All the spatially explicit models estimate a carbon sink in both tropical and northern temperate regions, but the strength of these sinks varies over time. Differences in the simulated response of terrestrial ecosystems to CO2 fertilization among the models in this intercomparison study reflect the fact that the models have highlighted different aspects of the effect of CO2 fertilization on carbon dynamics of natural terrestrial ecosystems including feedback mechanisms. As interactions with nitrogen fertilization, climate change and forest regrowth may play an important role in simulating the response of terrestrial ecosystems to CO2 fertilization, these factors should be included in future analyses. Improvements in spatially explicit data sets, whole-ecosystems experiments and the availability of net carbon exchange measurements across the globe will also help to improve future evaluations of the role of CO2 fertilization on terrestrial carbon storage.

Tellus, Series B: Chemical and Physical Meteorolog↗

The sensitivity of terrestrial carbon storage to historical climate variability and atmospheric CO2 in the United States

We use the Terrestrial Ecosystem Model (TEM, Version 4.1) and the land cover data set of the international geosphere-biosphere program to investigate how increasing atmospheric CO2 concentration and climate variability during 1900-1994 affect the carbon storage of terrestrial ecosystems in the conterminous USA, and how carbon storage has been affected by land-use change. The estimates of TEM indicate that over the past 95 years a combination of increasing atmospheric CO2 with historical temperature and precipitation variability causes a 4.2% (4.3 Pg C) decrease in total carbon storage of potential vegetation in the conterminous US, with vegetation carbon decreasing by 7.2% (3.2 Pg C) and soil organic carbon decreasing by 1.9% (1.1 Pg C). Several dry periods including the 1930s and 1950s are responsible for the loss of carbon storage. Our factorial experiments indicate that precipitation variability alone decreases total carbon storage by 9.5%. Temperature variability alone does not significantly affect carbon storage. The effect of CO2 fertilization alone increases total carbon storage by 4.4%. The effects of increasing atmospheric CO2 and climate variability are not additive. Interactions among CO2, temperature and precipitation increase total carbon storage by 1.1%. Our study also shows substantial year-to-year variations in net carbon exchange between the atmosphere and terrestrial ecosystems due to climate variability. Since the 1960s, we estimate these terrestrial ecosystems have acted primarily as a sink of atmospheric CO2 as a result of wetter weather and higher atmospheric CO2 concentrations. For the 1980s, we estimate the natural terrestrial ecosystems, excluding cropland and urban areas, of the conterminous US have accumulated 78.2 Tg C yr-1 because of the combined effect of increasing atmospheric CO2 and climate variability. For the conterminous US, we estimate that the conversion of natural ecosystems to cropland and urban areas has caused a 18.2% (17.7 Pg C) reduction in total carbon storage from that estimated for potential vegetation. The carbon sink capacity of natural terrestrial ecosystems in the conterminous US is about 69% of that estimated for potential vegetation.

Tellus, Series B: Chemical and Physical Meteorolog↗

Appalachian Piedmont landscapes from the Permian to the Holocene

Between the Potomac and Susquehanna Rivers and from the Blue Ridge to the Fall Zone, landscapes of the Piedmont are illustrated for times in the Holocene, Late Wisconsin, Early Miocene, Early Cretaceous, Late Triassic, and Permian. Landscape evolution took place in tectonic settings marked by major plate collisions (Permian), arching and rifting (Late Triassic) and development of the Atlantic passive margin by sea floor spreading (Early Cretaceous). Erosion proceeded concurrently with tectonic uplift and continued after cessation of major tectonic activity. Atlantic Outer Continental Shelf sediments record three major erosional periods: (1) Late Triassic-Early Jurassic; (2) Late Jurassic-Early Cretaceous; and (3) Middle Miocene-Holocene. The Middle Miocene-Holocene pulse is related to neotectonic activity and major climatic fluctuations. In the Piedmont upland the Holocene landscape is interpreted as an upland surface of low relief undergoing dissection. Major rivers and streams are incised into a landscape on which the landforms show a delicate adjustment to rock lithologies. The Fall Zone has apparently evolved from a combination of warping, faulting, and differential erosion since Late Miocene. The periglacial environment of the Late Wisconsin (and earlier glacial epochs) resulted in increased physical erosion and reduced chemical weathering. Even with lowered saprolitization rates, geochemical modeling suggests that 80 m or more of saprolite may have formed since Late Miocene. This volume of saprolite suggests major erosion of upland surfaces and seemingly contradicts available field evidence. Greatly subdued relief characterized the Early Miocene time, near the end of a prolonged interval of tropical morphogenesis. The ancestral Susquehanna and Potomac Rivers occupied approximately their present locations. In Early Cretaceous time local relief may have been as much as 900 m, and a major axial river draining both the Piedmont and Appalachians flowed southeast past Baltimore. The Late Triassic landscape was influenced by rift basin development. Streams drained into a hydrologically closed basin: no through-flowing rivers seem to have been present. A limestone escarpment along the Blue Ridge may have existed as a consequence of a semi-arid climate. The Permian may have been a time of Himalayan-like mountains and mountain glaciers. Streams (and glaciers) generally flowed southwest and west. ?? 1989.

Geomorphology↗

Risk analysis for biological hazards: What we need to know about invasive species

Risk analysis for biological invasions is similar to other types of natural and human hazards. For example, risk analysis for chemical spills requires the evaluation of basic information on where a spill occurs; exposure level and toxicity of the chemical agent; knowledge of the physical processes involved in its rate and direction of spread; and potential impacts to the environment, economy, and human health relative to containment costs. Unlike typical chemical spills, biological invasions can have long lag times from introduction and establishment to successful invasion, they reproduce, and they can spread rapidly by physical and biological processes. We use a risk analysis framework to suggest a general strategy for risk analysis for invasive species and invaded habitats. It requires: (1) problem formation (scoping the problem, defining assessment endpoints); (2) analysis (information on species traits, matching species traits to suitable habitats, estimating exposure, surveys of current distribution and abundance); (3) risk characterization (understanding of data completeness, estimates of the “potential” distribution and abundance; estimates of the potential rate of spread; and probable risks, impacts, and costs); and (4) risk management (containment potential, costs, and opportunity costs; legal mandates and social considerations and information science and technology needs).

Risk Analysis↗

The potassic sedimentary rocks in Gale Crater, Mars, as seen by ChemCam Onboard Curiosity

The Mars Science Laboratory rover Curiosity encountered potassium-rich clastic sedimentary rocks at two sites in Gale Crater, the waypoints Cooperstown and Kimberley. These rocks include several distinct meters thick sedimentary outcrops ranging from fine sandstone to conglomerate, interpreted to record an ancient fluvial or fluvio-deltaic depositional system. From ChemCam Laser-Induced Breakdown Spectroscopy (LIBS) chemical analyses, this suite of sedimentary rocks has an overall mean K 2 O abundance that is more than 5 times higher than that of the average Martian crust. The combined analysis of ChemCam data with stratigraphic and geographic locations reveals that the mean K 2 O abundance increases upward through the stratigraphic section. Chemical analyses across each unit can be represented as mixtures of several distinct chemical components, i.e., mineral phases, including K-bearing minerals, mafic silicates, Fe-oxides, and Fe-hydroxide/oxyhydroxides. Possible K-bearing minerals include alkali feldspar (including anorthoclase and sanidine) and K-bearing phyllosilicate such as illite. Mixtures of different source rocks, including a potassium-rich rock located on the rim and walls of Gale Crater, are the likely origin of observed chemical variations within each unit. Physical sorting may have also played a role in the enrichment in K in the Kimberley formation. The occurrence of these potassic sedimentary rocks provides additional evidence for the chemical diversity of the crust exposed at Gale Crater.

Journal of Geophysical Research↗

Feeding response of sport fish after electrical immobilization, chemical sedation, or both

Fishery managers frequently capture wild fish for a variety of fishery management activities. Though some activities can be accomplished without immobilizing the fish, others are accomplished more readily, humanely, and safely (for both the handler and the fish) when fish are immobilized by physical (e.g., electrical immobilization) or chemical sedation. A concern regarding the use of chemical sedatives is that chemical residues may remain in the fillet tissue after the fish recovers from sedation. If those residues are harmful to humans, there is some risk that a postsedated fish released to public waters may be caught and consumed by an angler. To characterize this risk, a series of four trials were conducted. Three trials assessed feeding activity after hatchery-reared fish were electrically immobilized, chemically sedated, or both, and one trial assessed the likelihood of an angler catching a wild fish that had been electrically immobilized and chemically sedated. Results from the first trial indicated that the feeding activity of laboratory habituated fish was variable among and within species after electrical immobilization, chemical sedation, or both. Results from the second trial indicated that the resumption of feeding activity was rapid after being mildly sedated for 45 min. Results from the third trial indicated that the feeding activity of outdoor, hatchery-reared fish was relatively aggressive after fish had been chemically sedated. Results from the fourth trial indicated that the probability of capturing wild fish in a more natural environment by angling after fish had been electrically immobilized and chemically sedated is not likely, i.e., in a group of five fish caught, 3 out of 100 times one would be a fish that had been sedated.

North American Journal of Fisheries Management↗

Reactive solute transport in streams: 1. Development of an equilibrium- based model

An equilibrium-based solute transport model is developed for the simulation of trace metal fate and transport in streams. The model is formed by coupling a solute transport model with a chemical equilibrium submodel based on MINTEQ. The solute transport model considers the physical processes of advection, dispersion, lateral inflow, and transient storage, while the equilibrium submodel considers the speciation and complexation of aqueous species, precipitation/dissolution and sorption. Within the model, reactions in the water column may result in the formation of solid phases (precipitates and sorbed species) that are subject to downstream transport and settling processes. Solid phases on the streambed may also interact with the water column through dissolution and sorption/desorption reactions. Consideration of both mobile (water-borne) and immobile (streambed) solid phases requires a unique set of governing differential equations and solution techniques that are developed herein. The partial differential equations describing physical transport and the algebraic equations describing chemical equilibria are coupled using the sequential iteration approach.

Water Resources Research↗

Index of surface-water stations in Texas, January 1987

As of January 1, 1987, the surface-water data-collection network in Texas included 376 continuous streamflow, 76 continuous or daily reservoir-content, 34 gage height, 16 crest-stage partial-record, 8 periodic discharge through range, 33 floodhydrograph partial-record, 9 flood-profile partial-record, 36 low-flow partial-record, 46 daily chemical-quality, 19 continuous-recording water-quality, 84 periodic biological, 17 lake surveys, 162 periodic organic and (or) nutrient, 3 periodic insecticide, 42 periodic pesticide, 19 automatic sampler, 141 periodic minor elements, 130 periodic chemical-quality, 78 periodic physical-organic, 22 continuous-recording three- or four-parameter water-quality, 34 periodic sediment, 22 continuous-recording temperature, and 30 national stream-quality accounting network stations. Plate 1 shows the location of surface-water streamflow or reservoir-content and chemical-quality or sediment'stations in Texas. Plate 2 shows the location of partial-record surfacewater stations. This index shows the station number and name, latitude and longitude, type of data collected, and the office principally responsible for the data collection (table 1). An 8-digit permanent numerical designation for gaging stations has been adopted on a nationwide basis; stations are numbered and listed in downstream order. In the downstream direction along the main stem, all stations on a tributary entering above a main-stem station are listed before that station. A tributary entering between two main-stem stations is listed between them. A similar order is followed in listing stations on first rank, second rank, and other ranks of tributaries. To indicate the rank of any tributary on which a gaging station is situated and the stream to which it is an immediate tributary, each indention in the listing of gaging stations represent one rank. This downstream order and system of indention show which gaging stations are on tributaries between any two stations on a main stem and the rank of the tributary on which each gaging station is situated. On plates 1 and 2, the 8-digit station number is abbreviated because of space limitation.

Texas↗

Hydrologic and climatologic data for the Lehigh area, southeastern Oklahoma, May 1977 to January 1982

Hydrologic and climatologic data were collected in the Lehigh area in southeastern Oklahoma during an investigation of the hydrologic effects of coal strip-mining. The purpose of the study was to assess the probable effects of surface mining for coal and subsequent reclamation on the hydrologic characteristics of the basin. This report presents all the data collected between 1977 and 1982. The data include: (1) greater than four years of daily and selected unit streamflow, daily suspended-sediment discharge, analyses of periodic samples for chemical quality, and daily temperature, pH, specific conductance, and dissolved oxygen at the Coal Creek near Lehigh gaging stations; (2) partial record discharge data and analyses of periodic samples for chemical quality and sediment for two tributaries of Coal Creek; (3) climatologic data for four sites; (4) soil moisture at 13 measurements sites; (5) continuous record of the water level in one well; (6) periodic record of water level in a second well; (7) water-level records for 43 wells and springs including on-site measurement of physical parameters; and (8) complete chemical analyses of water samples from eleven wells and one spring.

Oklahoma↗

Geologic and hydrologic data for the municipal solid waste landfill facility, U.S. Army Air Defense Artillery Center and Fort Bliss, El Paso County, Texas

Geologic and hydrologic data for the Municipal Solid Waste Landfill Facility on the U.S. Army Air Defense Artillery Center and Fort Bliss in El Paso County, Texas, were collected by the U.S. Geological Survey in cooperation with the U.S. Department of the Army. The 106.03-acre landfill has been in operation since January 1974. The landfill contains household refuse, Post solid wastes, bulky items, grass and tree trimmings from family housing, refuse from litter cans, construction debris, classified waste (dry), dead animals, asbestos, and empty oil cans. The depth of the filled areas is about 30 feet and the cover, consisting of locally derived material, is 2 to 3 feet thick. Geologic and hydrologic data were collected at or adjacent to the landfill during (1) drilling of 10 30- to 31-foot boreholes that were completed with gas-monitoring probes, (2) drilling of a 59-foot borehole, (3) drilling of a 355-foot borehole that was completed as a ground-water monitoring well, and (4) in situ measurements made on the landfill cover. After completion, the gas- monitoring probes were monitored on a quarterly basis (1 year total) for gases generated by the landfill. Water samples were collected from the ground-water monitoring well for chemical analysis. Data collection is divided into two elements: geologic data and hydrologic data. Geologic data include lithologic descriptions of cores and cuttings, geophysical logs, soil- gas and ambient-air analyses, and chemical analyses of soil. Hydrologic data include physical properties, total organic carbon, and pH of soil and sediment samples; soil-water chloride and soil-moisture analyses; physical properties of the landfill cover; measurements of depth to ground water; and ground-water chemical analyses. Interpretation of data is not included in this report.

Texas↗

One-Dimensional Transport with Equilibrium Chemistry (OTEQ) - A reactive transport model for streams and rivers

OTEQ is a mathematical simulation model used to characterize the fate and transport of waterborne solutes in streams and rivers. The model is formed by coupling a solute transport model with a chemical equilibrium submodel. The solute transport model is based on OTIS, a model that considers the physical processes of advection, dispersion, lateral inflow, and transient storage. The equilibrium submodel is based on MINTEQ, a model that considers the speciation and complexation of aqueous species, acid-base reactions, precipitation/dissolution, and sorption. Within OTEQ, reactions in the water column may result in the formation of solid phases (precipitates and sorbed species) that are subject to downstream transport and settling processes. Solid phases on the streambed may also interact with the water column through dissolution and sorption/desorption reactions. Consideration of both mobile (waterborne) and immobile (streambed) solid phases requires a unique set of governing differential equations and solution techniques that are developed herein. The partial differential equations describing physical transport and the algebraic equations describing chemical equilibria are coupled using the sequential iteration approach. The model's ability to simulate pH, precipitation/dissolution, and pH-dependent sorption provides a means of evaluating the complex interactions between instream chemistry and hydrologic transport at the field scale. This report details the development and application of OTEQ. Sections of the report describe model theory, input/output specifications, model applications, and installation instructions. OTEQ may be obtained over the Internet at http://water.usgs.gov/software/OTEQ.

Techniques and Methods↗

Chronobiologic approach to aquaculture

Diel and seasonal changes in the environment directly or indirectly control many biological functions. Chronobiology, the study of biological functions in relation to time of day, time of year, lunar phases, and other consistent cues, could have important applications in aquaculture. Physiological conditions that vary seasonally include feeding time, tolerance of fish to stress, the state of gonad development, lipid and water content of muscle tissue, and the dress‐out weight of food fish. The quality of cultured fish may vary with the time of day when fish are fed, seined, graded, treated with therapeutic chemicals, injected with hormones, or physically disturbed. Efficiency of production and quality of aquacultural products might be improved if the activities of fish husbandry were timed to coincide with the biological rhythms of fish.

Transactions of the American Fisheries Society↗

Aurorite, argentian todorokite, and hydrous silver-bearing lead manganese oxide

During a study of hypogene manganese minerals, three silver-bearing manganese oxides were identified in "black calcite" associated with silver ores at the Aurora mine (Treasure Hill), Hamilton, Nevada. Specifically these are: (1) argentian chalcophanite (aurorite) (Ag 2 Ba,Ca,Pb,-K 2 ,Cu,Mn (super +2) )Mn 3 (super +4) O 7 . 3H 2 O; (2) argentian todorokite (Ag 2 ,K 2 ,Ca,Ba,-Na 2 ,Cu,Pb)Mn 4 (super +4) O 9 . 5H 2 O; and (3) hydrous silver-bearing lead manganese oxide (Pb,Cu,Ba,Sb,Ag 2 ,Ca,K 2 )Mn 5 (super +4) O 11 . 5H 2 O. Based on the large concentration of silver in argentian chalcophanite (7.50% Ag 2 O) and the low zinc content (0.25% ZnO) this mineral is recognized as a new species and named "aurorite."Physical and optical properties, and chemical analyses of the three minerals are presented together with X-ray powder diffraction data for aurorite and argentian todorokite. All chemical analyses were done with the electron microprobe analyzer. Due to extremely small particle size and textural relations, no X-ray powder data were obtained for the hydrous silver-bearing lead manganese oxide. Associated minerals include cryptomelane, pyrolusite, birnessite(?), cerargyrite, native silver, quartz, and manganoan calcite. Although the general uniform dark color of the "black calcite" and apparent uniform distribution of the inclusions suggests contemporaneous formation, examination of polished sections at high magnifications shows a definite paragenetic sequence. Manganoan calcite is replaced by fine-grained intergrowths of cryptomelane, pyrolusite, birnessite(?), and cerargyrite. Native silver formed early and the silver-bearing manganese oxides formed late in the sequence; aurorite fills microfractures that cut through all other minerals.These three silver-bearing manganese oxides were recognized only at the Aurora mine, Hamilton, Nevada, although black calcite veins were studied from numerous areas in the western United States. The geologic features of silver-bearing black calcites are described by Hewett and Radtke in the preceding paper.

Nevada↗

Investigation of drivers and sources of potential harmful algal blooms in Lake Anna, Virginia, 2023-24

Algal blooms in freshwater reservoirs are an increasing concern because of the risk to aquatic ecosystem health, recreational use, and water quality. Among the taxa that comprise an algal bloom, cyanobacteria are of particular concern due to the potential to produce toxic compounds which can cause acute and chronic illness in humans if ingested through contaminated water or shellfish. When toxins are above a toxin-specific threshold in the water column, the Commonwealth of Virginia categorizes the bloom as a harmful algal bloom (HAB), distinguishing it from an algal bloom without toxins present. Toxins are of particular concern in bodies of water which serve as major recreational areas, such as Lake Anna in central Virginia. Lake Anna is a 27 km-long and 47 km2 reservoir in central Virginia. Since the Commonwealth of Virginia revised the HAB monitoring framework in 2018, algal bloom advisories for potentially toxigenic blooms have been issued in the western, riverine zone of the reservoir. There were detections of microcystin and anatoxin production but no detections of cylindrospermopsin and saxitoxin production in Lake Anna; however, toxin concentrations were low, at values less than 0.65 µg/L. In 2023, the U.S. Geological Survey, in cooperation with Virginia Department of Environmental Quality, initiated a 19-month intensive and extensive study of western Lake Anna and its tributaries (North Anna River and Pamunkey Creek) to (1) characterize the algal community, biomass, and toxin production; (2) identify potential drivers leading to algal bloom initiation, persistence, and decline; and (3) assess the primary sources of the drivers contributing to algal blooms. Continuous and discrete monitoring of water quality within the lake, watershed inputs, meteorological conditions, and algal communities were monitored. Multiple modeling scenarios identified that the formation and persistence of algal blooms in Lake Anna are driven by interactions among chemical, macro- and micronutrient, and physical factors. Key drivers include total nitrogen, total phosphorus, water temperature, suspended sediment concentration, wind speed, copper, iron, molybdenum, nickel, sodium, and alkalinity. During this study, winter stormflow events delivered the highest loading of macro- and micronutrients from the tributaries to the lake. The lake is a sink for these nutrients in the water column or in the lake-bed sediments. During high-occupancy and recreation periods on the lake in the summer months, boating activity can promote internal loading by the resuspension of the lake-bed sediments, thereby increasing the nutrient availability for algal uptake. Thermal stratification and hypoxic conditions were observed, which can contribute to the passive release of nutrients into the water column, further facilitating algal bloom proliferation. These processes may create a positive feedback loop that supports the formation, persistence, and annual recurrence of algal blooms in the western region of Lake Anna. Continued water-quality monitoring of early warning indicators may improve the detection and forecasting of algal growth in the lake and help managers proactively manage water quality and algal growth.

EarthArXiv↗