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Assessment of Energetic Compounds, Semi-volatile Organic Compounds, and Trace Elements in Streambed Sediment and Stream Water from Streams Draining Munitions Firing Points and Impact Areas, Fort Riley, Kansas, 2007-08

An assessment of energetic compounds (explosive and propellant residues) and associated semi-volatile organic compounds (SVOCs) and trace elements in streambed sediment and stream water from streams draining munitions firing points and impact areas at Fort Riley, northeast Kansas, was performed during 2007-08 by the U.S. Geological Survey (USGS) in cooperation with the U.S. Army. Streambed sediment from 16 sampling sites and stream-water samples from 5 sites were collected at or near Fort Riley and analyzed for as many as 17 energetic compounds, 65 SVOCs, and 27 trace elements. None of the energetic compounds or SVOCs were detected in streambed sediment collected from sites within the Fort Riley Military Reservation. This may indicate that these compounds either are not transported from dispersal areas or that analytical methods are not sensitive enough to detect the small concentrations that may be transported. Concentrations of munitions-associated trace elements did not exceed sediment-quality guidelines recommended by the U.S. Environmental Protection Agency (USEPA) and are not indicative of contamination of streambed sediment at selected streambed sampling sites, at least in regards to movement from dispersal areas. Analytical results of stream-water samples provided little evidence of contamination by energetic compounds, SVOCs, or associated trace elements. Perchlorate was detected in 19 of 20 stream-water samples at concentrations ranging from an estimated 0.057 to an estimated 0.236 ug/L (micrograms per liter) with a median concentration of an estimated 0.114 ug/L, substantially less than the USEPA Interim Health Advisory criterion (15 ug/L), and is in the range of documented background concentrations. Because of these small concentrations and possible natural sources (precipitation and groundwater), it is likely that the occurrence of perchlorate in stream water is naturally occurring, although a definitive identification of the source of perchlorate in stream water at Fort Riley is difficult. The only SVOCs detected in stream-water samples were bis(2-ethylhexyl) phthalate and di-n-butyl phthalate but at concentrations substantially less than the most stringent aquatic-life criteria established by the Kansas Department of Health and Environment. All trace element concentrations in stream-water samples were less than the most stringent aquatic-life criteria. The implication of these stream-water results is that contamination arising from firing-range activities, if it exists, is so small as to be nondetectable with current analytical methods or is not distinguishable from background concentrations for constituents that also are naturally occurring. Overall, the munitions-related constituents analyzed in streambed sediment and stream water, when detected, were at concentrations that were less than regulatory criteria

Scientific Investigations Report↗

Trends in ground-water levels in Wisconsin through 1981

Hydrographs of ground-water levels in Wisconsin display fluctuations in the potentiometric surface of confined and unconfined aquifers. The graphs are plotted from periodic (weekly or monthly) measurements and from continuous recording gage records. Two hundred and ten hydrographs having periods of record of at least 5 years between 1934 and 1981 are included. The water-level changes shown represent both natural fluctuations reflecting climatic control and declines or recovery brought about by pumping or cessation of pumping of ground water.

Wisconsin↗

Evaluation of airborne thermal-infrared image data for monitoring aquatic habitats and cultural resources within the Grand Canyon

This study examined thermal-infrared (TIR) image data acquired using the airborne Advanced Thematic Mapper (ATM) sensor in the afternoon of July 25th, 2000 over a portion of the Colorado River corridor to determine the capability of these 100-cm resolution data to address some biologic and cultural resource requirements for GCMRC. The requirements investigated included the mapping of warm backwaters that may serve as fish habitats and the detection (and monitoring) of archaeological structures and natural springs that occur on land. This report reviews the procedure for calibration of the airborne TIR data to obtain surface water temperatures and shows the results for various river reaches within the acquired river corridor. With respect to mapping warm backwater areas, our results show that TIR data need to be acquired with a gain setting that optimizes the range of temperatures found within the water to increase sensitivity of the resulting data to a level of 0.1 °C and to reduce scan-line noise. Data acquired within a two-hour window around maximum solar heating (1:30 PM) is recommended to provide maximum solar heating of the water and to minimize cooling effects of late-afternoon shadows. Ground-truth data within the temperature range of the warm backwaters are necessary for calibration of the TIR data. The ground-truth data need to be collected with good locational accuracy. The derived water-temperature data provide the capability for rapid, wide-area mapping of warm-water fish habitats using a threshold temperature for such habitats. The collected daytime TIR data were ineffective in mapping (detecting) both archaeological structures and natural springs (seeps). The inability of the daytime TIR data to detect archaeological structures is attributed to the low thermal sensitivity (0.3 °C) of the collected data. The detection of subtle thermal differences between geologic materials requires sensitivities of at least 0.1 °C, which can be obtained by most TIR sensors using an appropriate gain setting. Simultaneous data collection for both land and water purposes can be achieved using sensors that collect TIR data in two separate channels, each channel using a gain setting most appropriate for land or water. The detection of archaeological structures and natural water seeps would also be improved by collection of data after sunset, which would require a separate data acquisition from that providing surface water temperature data and therefore additional cost. At this point, the cost for acquiring TIR data is quite high ($620/river-km) compared to the potential benefits of the data, unless reflected-wavelength data are also collected that can satisfy other GCMRC protocol requirements (such as mapping riparian vegetation). This is especially true if multiple data acquisitions are required during the year for temporal analyses of backwater areas. The cost for these data cannot be totally mitigated by its ability to partly replace the need for ground surveys of backwaters because calibration of the TIR data will require some ground-truth data from warm backwater areas (in addition to low-temperature main-stem data). However, the airborne data can provide a product that cannot be approached by ground surveys, that being an instantaneous (2 hour) map of surface water temperature over a 160-km stretch of the Grand Canyon.

Arizona↗

Use of the Soil and Water Assessment Tool (SWAT) for simulating hydrology and water quality in the Cedar River Basin, Iowa, 2000--10

The U.S. Geological Survey, in cooperation with the Iowa Department of Natural Resources, used the Soil and Water Assessment Tool to simulate streamflow and nitrate loads within the Cedar River Basin, Iowa. The goal was to assess the ability of the Soil and Water Assessment Tool to estimate streamflow and nitrate loads in gaged and ungaged basins in Iowa. The Cedar River Basin model uses measured streamflow data from 12 U.S. Geological Survey streamflow-gaging stations for hydrology calibration. The U.S. Geological Survey software program, Load Estimator, was used to estimate annual and monthly nitrate loads based on measured nitrate concentrations and streamflow data from three Iowa Department of Natural Resources Storage and Retrieval/Water Quality Exchange stations, located throughout the basin, for nitrate load calibration. The hydrology of the model was calibrated for the period of January 1, 2000, to December 31, 2004, and validated for the period of January 1, 2005, to December 31, 2010. Simulated daily, monthly, and annual streamflow resulted in Nash-Sutcliffe coefficient of model efficiency (E NS ) values ranging from 0.44 to 0.83, 0.72 to 0.93, and 0.56 to 0.97, respectively, and coefficient of determination (R 2 ) values ranging from 0.55 to 0.87, 0.74 to 0.94, and 0.65 to 0.99, respectively, for the calibration period. The percent bias ranged from -19 to 10, -16 to 10, and -19 to 10 for daily, monthly, and annual simulation, respectively. The validation period resulted in daily, monthly, and annual E NS values ranging from 0.49 to 0.77, 0.69 to 0.91, and -0.22 to 0.95, respectively; R 2 values ranging from 0.59 to 0.84, 0.74 to 0.92, and 0.36 to 0.92, respectively; and percent bias ranging from -16 for all time steps to percent bias of 14, 15, and 15, respectively. The nitrate calibration was based on a small subset of the locations used in the hydrology calibration with limited measured data. Model performance ranges from unsatisfactory to very good for the calibration period (January 1, 2000, to December 31, 2004). Results for the validation period (January 1, 2005, to December 31, 2010) indicate a need for an increase of measured data as well as more refined documented management practices at a higher resolution. Simulated nitrate loads resulted in monthly and annual E NS values ranging from 0.28 to 0.82 and 0.61 to 0.86, respectively, and monthly and annual R 2 values ranging from 0.65 to 0.81 and 0.65 to 0.88, respectively, for the calibration period. The monthly and annual calibration percent bias ranged from 4 to 7 and 5 to 7, respectively. The validation period resulted in all but two E NS values less than zero. Monthly and annual validation R 2 values ranged from 0.5 to 0.67 and 0.25 to 0.48, respectively. Monthly and annual validation percent bias ranged from 46 to 68 for both time steps. A daily calibration and validation for nitrate loads was not performed because of the poor monthly and annual results; measured daily nitrate data are available for intervals of time in 2009 and 2010 during which a successful monthly and annual calibration could not be achieved. The Cedar River Basin is densely gaged relative to other basins in Iowa; therefore, an alternative hydrology scenario was created to assess the predictive capabilities of the Soil and Water Assessment Tool using fewer locations of measured data for model hydrology calibration. Although the ability of the model to reproduce measured values improves with the number of calibration locations, results indicate that the Soil and Water Assessment Tool can be used to adequately estimate streamflow in less densely gaged basins throughout the State, especially at the monthly time step. However, results also indicate that caution should be used when calibrating a subbasin that consists of physically distinct regions based on only one streamflow-gaging station.

Iowa↗

Evaluating changes to reservoir rule curves using historical water-level data

Flood control reservoirs are typically managed through rule curves (i.e. target water levels) which control the storage and release timing of flood waters. Changes to rule curves are often contemplated and requested by various user groups and management agencies with no information available about the actual flood risk of such requests. Methods of estimating flood risk in reservoirs are not easily available to those unfamiliar with hydrological models that track water movement through a river basin. We developed a quantile regression model that uses readily available daily water-level data to estimate risk of spilling. Our model provided a relatively simple process for estimating the maximum applicable water level under a specific flood risk for any day of the year. This water level represents an upper-limit umbrella under which water levels can be operated in a variety of ways. Our model allows the visualization of water-level management under a user-specified flood risk and provides a framework for incorporating the effect of a changing environment on water-level management in reservoirs, but is not designed to replace existing hydrological models. The model can improve communication and collaboration among agencies responsible for managing natural resources dependent on reservoir water levels.

International Journal of River Basin Management↗

Regional Aquifer-System Analysis Program of the U.S. Geological Survey, 1978-1992

The major ground-water systems of the United States have been investigated by the U.S. Geological Survey (USGS) through its Regional Aquifer-System Analysis (RASA) Program. During the first 15 years of the program (1978-92), 25 regional aquifer systems, including the most heavily pumped aquifers in the Nation, were intensively studied. As of mid-1992, 18 of the regional aquifer studies are completed or nearly so; 7 of the regional aquifer studies are ongoing, and compilation of a national ground-water atlas is in progress. This report summarizes the status of each RASA study and briefly describes the hydrology of the 25 regional aquifer systems. Important study results and examples of applications of study results are presented for some of the completed RASA investigations. The major contributions of the RASA Program are (1) assembly of data from numerous local studies and long-time data collections into systematic regional data bases; (2) comprehensive descriptions of the geologic, hydrologic, and geochemical characteristics of the regional aquifer systems; and (3) an understanding of how the regional ground-water-flow systems function under natural (predevelopment) and current (developed) conditions. To provide the comprehensive system descriptions, many of the RASA studies present, for the first time, maps depicting the hydrogeologic frameworks, water chemistry, potentiometric surfaces, and other aspects of entire regional aquifer systems. To provide an understanding of how the flow systems function, several of the completed RASA studies provide, for the first time, hydrologic budgets for both predevelopment and developed conditions. The results of the RASA Program are contained in nearly 900 reports published by the USGS, as well as various State and local agencies, and in articles published in scientific journals. A series of U.S. Geological Survey Professional Papers are being published to summarize and synthesize the results of each RASA study.

Circular↗

Georgia's Surface-Water Resources and Streamflow Monitoring Network, 2008

Surface water provides 5 billion gallons per day, or 78 percent, of the total freshwater used (including thermoelectric) in Georgia (Fanning, 2003). Climate, geology, and landforms control the natural distribution of Georgia's water resources. Georgia is a 'headwaters' State, with most of the rivers beginning in northern Georgia and increasing in size downstream (see map at right for major watersheds). Surface water is the primary source of water in the northern one-half of the State, including the Atlanta metropolitan area, where limited ground-water resources are difficult to obtain. In Georgia, periodic droughts exacerbate competition for surface-water supplies. Many areas of Georgia also face a threat of flooding because of spring frontal thunderstorms and the potential for hurricanes from both the Atlantic Ocean and Gulf of Mexico. As the population of Georgia increases, these flood risks will increase with development in flood-risk zones, particularly in the coastal region.

Georgia↗

Water quality, hydrology, and phosphorus loading to Little St. Germain Lake, Wisconsin, with special emphasis on the effects of winter aeration and ground-water inputs

Little St. Germain Lake is a 978-acre, multibasin lake in Vilas County, Wisconsin. In the interest of protecting and improving the water quality of the lake, the Little St. Germain Lake District initiated several cooperative studies with the U.S. Geological Survey between 1991 and 2004 to (1) document the water quality and the extent of winter anoxia in the lake, (2) evaluate the success of aerators at eliminating winter anoxia, (3) develop water and nutrient budgets for the lake, and (4) assess how the water quality of the lake should respond to changes in phosphorus loading. This report presents the results of these cooperative studies with special emphasis on the water quality in the lake since 2000, including the effects of winter aeration and the importance of ground-water contributions of phosphorus to the productivity of the lake. Measurements collected during these studies indicate that the water quality in Little St. Germain Lake was consistently different among basins. The West Bay consistently had the best water quality, the South Bay had intermediate water quality, and the East and Upper East Bays consistently had the worst water quality. The water quality in each of the basins was relatively stable from 1991 to 2000; however, since 2001, the West Bay has changed from oligotrophic to mesotrophic, the South Bay has changed from mesotrophic to eutrophic, and the East and Upper East Bays have changed from eutrophic to eutrophic/hypereutrophic. Winter anoxia frequently occurred throughout most of the lake, except in the West Bay and just below the ice in the East Bay. To eliminate winter anoxia, coarse-bubble line aerators were installed and operated in the Upper East, East, and South Bays. The aerators in the Upper East and South Bays were very successful at eliminating winter anoxia; however, the aerator in the East Bay had little impact on the dissolved oxygen concentrations throughout its basin. Detailed water and phosphorus budgets computed for the lake indicated that inflow from Muskellunge Creek was the major source of phosphorus to the lake and that ground water was the secondary source. Results from a detailed ground-water-flow model indicated that ground water flows into the lake from all sides, except the south sides of the West and Second South Bays. Most of the phosphorus appears to come from natural sources, such as ground water and surface water flowing through relatively undeveloped areas surrounding Little St. Germain Lake and Muskellunge Lake. Several empirical water-quality models were used to simulate how the East and Upper East Bays of the lake should respond to reductions in phosphorus loading from Muskellunge Creek. Simulation results indicated that reductions in tributary loading could improve the water quality of the East and Upper East Bays. Improving the water quality of these bays would also improve the water quality of the South and Second South Bays because of the flow of water through the lake. However, even with phosphorus loading from Muskellunge Creek completely eliminated, most of the lake would remain borderline mesotrophic/eutrophic because of the contributions of phosphorus from ground water.

Wisconsin↗

Water quality characteristics of six small lakes in Missouri: Mo. Dept. of Natural Resources.

A study of six small lakes, representative of those in the major physiographic regions of Missouri, shows variation in physical. chemical, and biological characteristics related to their location in the Slate. For example, because of climatic differences, ice cover and winter stratification are more prevalent in northern Missouri. Summer stratification lasts about one month longer in the southern than in the northern part of the State. Because of the difference in geology. lake water in the Plains area is more mineralized than in the Ozarks. Different geology and land use generally account for more sedimentation of Plains Jakes. Lakes in the Plains area usually receive enough nutrients to be classified as mesouophic or eutrophic while those in the Ozarks receive less nutrients from natural sources and are often oligotrophic or mesotrophic. However, as seen from one of the study lakes, an oligotrophic lake can be made quite productive through the application of commercial fertilizers within the lake.

Missouri↗

Human interactions with ground-water

Ground-Water could be considered as an immense reservoir, from which only a certain amount of water can be withdrawn without affecting the quantity and quality of water. This amount is determined by the characteristics of the environment in which ground-water occurs and by the interactions of ground-water with precipitation, surface water, and people. It should be recognized that quantity and quality of ground-water are intimately related and should be considered accordingly. Quantity refers to usable water and water is usable for any specific purpose only so long as its quality has not deteriorated beyond acceptable limits. Thus an overall quantitative and qualitative management of ground water is inevitable, and its should also involve the uses of ground-water reservoirs for purposes other than water supply. The main objective of ground-water management is to ensure that ground-water resources will be available in appropriate time and in appropriate quantity and quality to meet the most important demands of our society. Traditional, and obvious uses of ground-water are the extraction of water for water supplies (domestic, municipal, agricultural, and industrial) and the natural discharge feeding lakes and maintaining base flow of streams. Not so obvious are the uses of ground-water reservoirs, the very framework within which ground-water occurs and moves, and in which other fluids or materials can be stored. In the last two decades, ground-water reservoirs have been intensively considered for many other purposes than water supplies. Diversified and very often conflicting uses need to be evaluated and dealt with in the most efficient way in order to determine the importance of each possible use, and to assign priorities of these uses. With rising competition for the use of ground-water reservoirs, we will also need to increase the potential for effective planning of ground-water development and protection. Man's development and use of ground-water necessarily modifies the natural conditions and the total natural system must be successfully blended with the unnatural stresses placed upon it. This can be accomplished by introducing new methods (such as ground-water zoning) in and by developing alternative strategies for ground-water management and protection. ?? 1983 D. Reidel Publishing Company.

GeoJournal↗

Assessment of long-term changes in surface-water extent within Klamath Marsh, south-central Oregon, 1985–2021

The annual maximum extent of surface water in Klamath Marsh has naturally fluctuated in response to periods of wet and dry conditions in the surrounding basin. Field observations during the 2010s indicate that the annual maximum extent of surface water has been declining and the marsh is not responding to hydrologic inputs as it had historically. This report describes the results of a hydrologic evaluation of Klamath Marsh to characterize and understand multi-year declines in the surface-water extent and increased intermittency of streamflow exiting the marsh. Landsat imagery collected during 1985–2021 was processed to create a time series of annual maximum surface-water extent to assess changes in surface-water inundation within the marsh. A 50-percent decrease in the mean surface area of annual total open-water extent (TOWE) during the latter half of the study period (2003–21) compared to the first half (1985–2003) was observed in this 37-year time-series dataset. The change in open-water extent was offset by a corresponding increase in dry land in the marsh. Time series of streamflow, groundwater level, total annual precipitation, annual mean temperature, and anthropogenic water use and water management were compiled and evaluated to improve understanding of the factors affecting TOWE. Statistically significant downward trends in the regional groundwater table and streamflow into and out of the marsh were identified as well as statistically significant upward trends in annual mean temperature. Statistically significant correlations among TOWE, streamflow, and groundwater level also were identified. The decreasing trends could not be attributed to changes in total annual precipitation or changing anthropogenic groundwater use within the study area. Declines in the open-water extent of Klamath Marsh since 2000 principally are due to a decoupling of the groundwater and surface-water system beneath the marsh because of regional declines in groundwater level. Regional increases in air temperature and the reestablishment of more than 55,000 acres of forested land within the study area have likely contributed to increasing evapotranspiration, leaving less water available for groundwater recharge and stream base flow and resulting in basin-wide declines in streamflow and groundwater levels.

Oregon↗

Preparing for today's and tomorrow's water-resources challenges in eastern Long Island, New York

Freshwater is a vital natural resource. Although New York is a water-rich State, the wise and economical use of water resources is needed to ensure that there is enough water of adequate quality for both human and ecological needs—both for today and for tomorrow. Nowhere in New York is this more evident than in Nassau and Suffolk Counties on Long Island, where the public water supply is obtained from the sole-source aquifers located directly beneath the nearly 3 million people who live there. In 2023, in eastern Long Island’s Suffolk County, groundwater was pumped from these aquifers by more than 1,100 public water-supply wells to meet the needs of about 1.5 million people.

New York↗

Geologic and hydrologic characterization and evaluation of the Basin and Range Province relative to the disposal of high-level radioactive waste: Part I, Introduction and guidelines

The U.S. Geological Survey's program for geologic and hydrologic evaluation of physiographic provinces to identify areas potentially suitable for locating repository sites for disposal of high-level nuclear wastes was announced to the Governors of the eight States in the Basin and Range Province on May 5, 1981. Representatives of Arizona, California, Idaho, New Mexico, Nevada, Oregon, Texas, and Utah, were invited to cooperate with the Federal Government in the evaluation process. Each Governor was requested to nominate an Earth scientist to represent the State in a province working group composed of State and U.S. Geological Survey representatives. This report, Part I of a three-part report, provides the background, introduction and scope of the study. This part also includes a discussion of geologic and hydrologic guidelines that will be used in the evaluation process and illustrates geohydrologic environments and the effect of individual factors in providing multiple natural barriers to radionuclide migration. Part II is a reconnaissance characterization of the geologic and hydrologic factors to be used in the initial screening of the Basin and Range Province. Part III will be the initial evaluation of the Province and will identify regions that appear suitable for further study. The plan for study of the Province includes a stepwise screening process by which successively smaller land units are considered in increasing detail. Each step involves characterization of the geology and hydrology and selection of subunits for more intensive characterization. Selection of subunits for further study is by evaluation of geologic and hydrologic conditions following a set of guidelines. By representation on the Province Working Group, the States participate in a consultation and review role in: (1) Establishing geologic and hydrologic guidelines, and (2) characterizing and evaluating the Province. The States also participate in compilation of geologic and hydrologic data used in characterizing the Province. The current (1983) needs for a high-level radioactive waste repository include: (1) Disposal in a mined repository; (2) retrievability of the waste for as much as 50 years; and (3) confidence of isolation of the waste from the accessible environment. Isolation of the waste needs to be assured using geologic and hydrologic conditions that: (1) Minimize risk of inadvertent future intrusions by man; (2) minimize the possibility of disturbance by processes that would expose the waste or increase its mobility; and (3) provide a system of natural barriers to the migration of waste by ground water. The guidelines adopted by the Province Working Group are designed to provide a standard with which these conditions can be compared. The guidelines can be grouped into four principal categories: (1) Potential host media, (2) ground-water conditions, (3) tectonic conditions, and. (4) occurrence of natural resources. Ideally the host medium constitutes the first natural barrier to migration of radionculides. The host medium ideally should be a rock type that prevents or retards dissolution and transport of radionuclides. Rocks in both the saturated and unsaturated zones may have desirable characteristics for host media. Rocks-other than the host-in the ground-water flow path from the repository ideally should be major barriers to radionuclide migration. Confining beds of low permeability might be present to retard the rate of flow between more permeable beds. Additionally, sorption of radionuclides by materials such as clays and zeolites in the flow path can further retard the flow of radionuclides by several orders of magnitude. Tectonic conditions in an area should not present a probable cause for exhumation or increased mobility of radioactive waste. Natural resources are a factor for consideration because of the problem of future human intrusion and exposure to radioactivity in the quest for minerals, oil, gas, water, and geothermal resources. The ultimate evaluation of the suitability of a geohydrologic environment for developing a mined repository needs to assess all geologic and hydrologic characteristics and their interaction in providing confidence that a geohydrologic environment will effectively isolate radionuclides from human access. Several hypothetical settings with typical geohydrologic conditions in the Basin and Range Province are used to illustrate the effect of multiple barriers in the isolation of radionuclides.

Arizona, California, Idaho, Nevada, New Mexico, Or↗

A pilot study for delineation of areas contributing water to wellfields at Jackson, Tennessee

The U.S. Geological Survey, in cooperation with the Tennessee Department of Health and Environment, Division of Groundwater Protection, and the Jackson Utility Division, conducted a pilot study to determine data needs and the applicability of four methods for the delineation of wellhead protection areas. Jackson Utility Division in Jackson, Madison County, Tennessee, pumps about 9 million gallons of ground water daily from two municipal wellfields that tap an unconfined sand aquifer. Under natural hydraulic gradients, ground waterflows southward toward the South Wellfield at approximately 2 to 3 feet per day; natural flow toward the North Wellfield from the east at 1 to 2 feet per day. Water quality generally is suitable for most uses. Concentrations of dissolved solids are low, and excessive iron is the only significant naturally occurring water-quality problem. However, trace concentrations of volatile organic compounds have been detected in water pumps from the South Wellfield; the highest concentration of a single compound has been 23 micrograms per liter of tetrachloroethylene. Potential sources of ground-water contamination in the Jackson area include a hazardous-waste site, municipal and industrial landfill, and underground-storage tanks. Some of the four method for delineating wellhead protection areas did not adequately describe zones contributing flow to the wellfields. Calculations based on a uniform flow equation provided a preliminary delineation of zones of contribution for the wellfields and ground-water time-of-travel contours. Limitations of the applied methods motivated the design of a more rigorous hydrogeologic investigation.

Tennessee↗

Water-quality characteristics and ground water quantity of the Fraser River watershed, Grand County, Colorado, 1998-2001

The U.S. Geological Survey, in cooperation with the Grand County Board of County Commissioners, conducted a 4-year study to assess ground- and surface-water-quality conditions and ground-water quantity in the 302-square-mile Fraser River watershed in north-central Colorado. The Fraser River flows north about 28 miles from the headwaters near the Continental Divide, through the towns of Winter Park, Fraser, Tabernash, and Granby, and is one of the major tributaries to the Upper Colorado River. Increasing urban development, as well as the seasonal influx of tourists, is placing more demands on the water resources in the Fraser River watershed. A ground-water sampling network of 11 wells was established to represent different aquifer systems (alluvial, Troublesome Formation, Precambrian granite), land uses (urban, nonurban), and areas with or without individual septic disposal system use. The well network was sampled for ground-water quality on a semiannual basis from August 1998 through September 2001. The sampling included field properties and the collection of water samples for analysis of major ions, trace elements, nutrients, dissolved organic carbon, bacteria, methylene blue active substances, and radon-222. One surface-water site, on the Fraser River just downstream from the town of Tabernash, Colorado, was sampled bimonthly from August 1998 through September 2001 to assess the cumulative effects of natural and human processes on water quality in the upper part of the Fraser River watershed. Surface-water-quality sampling included field properties and the collection of water-quality samples for analysis of major ions, trace elements, nutrients, organic carbon, and bacteria. Ground water was a calcium-bicarbonate type water and is suitable as a drinking-water, domestic, municipal, industrial, and irrigation source. In general, no widespread ground-water-quality problems were indicated. All pH values and concentrations of dissolved solids, chloride, fluoride, sulfate, nitrite, and nitrate in the ground-water samples met or were substantially less than U.S. Environmental Protection Agency drinking-water standards and health advisories or State of Colorado water-quality standards. Federal standards for turbidity and concentrations of iron, manganese, methylene blue active substances, and radon-222 were not met in water samples from at least one well. The only ground-water-quality concern assessed by this study is radon-222, which was detected in all radon- analyzed samples from 10 wells at levels exceeding the proposed U.S. Environmental Protection Agency drinking-water standard of 300 picocuries per liter. Concentrations of chloride, magnesium, and sulfate were statistically different (higher) in ground-water samples from wells completed in the alluvial aquifer, urbanized areas, and areas with individual septic disposal system use than those from wells completed in the Troublesome Formation, nonurban areas, and areas without individual septic disposal system use. Dissolved organic carbon concentrations were statistically higher in ground-water samples from wells completed in the alluvial aquifer and areas without individual septic disposal system use than those from wells completed in the Troublesome Formation and areas with individual septic disposal system use. Differences in dissolved organic-carbon concentrations between the latter category and areas without septic systems likely had no environmental significance. Surface water at the site Fraser River below Crooked Creek at Tabernash was a calcium-bicarbonate type water and is suitable as a drinking-water, residential, commercial, and irrigation resource. All pH values and concentrations of dissolved oxygen were within the State of Colorado instream water-quality standards, and all concentrations of chloride, sulfate, iron, manganese, un-ionized ammonia, nitrite, nitrate, and fecal coliform bacteria met State standards. Seasonal changes in the values or conc

Colorado↗

Preliminary assessment of injection, storage, and recovery of freshwater in the lower Hawthorn aquifer, Cape Coral, Florida

A preliminary assessment of subsurface injection, storage and recovery of fresh canal water was made in the naturally brackish lower Hawthorn aquifer in Cape Coral, southwestern Florida. A digital modeling approach was used for this preliminary assessment, incorporating available data on hydrologic conditions, aquifer properties, and water quality to simulate density-dependent ground-water flow and advective-dispersive transport of a conservative ground-water solute (chloride ion). A baseline simulation was used as reference to compare the effects of changing various operational factors on the recovery efficiency. A recovery efficiency of 64 percent was estimated for the baseline simulation. Based on the model, the recovery efficiency increases if the injection rate and recovery rates are increased and if the ratio of recovery rate to injection rate is increased. Recovery efficiency decreases if the amount of water injected is increased; slightly decreases if the storage time is increased; is not changed significantly if the water is injected to a specific flow zone; increases with successive cycles of injection, storage, and recovery; and decreases if the chloride concentrations in either the injection water or native aquifer water are increased. In everal hypothetical tests, the recovery efficiency fluctuated between 22 and about 100 percent. Two successive cycles could bring the recovery efficiency from 60 to about 80 percent. Interlayer solute mass movement across the upper and lower boundaries seems to be the most important factor affecting the recovery efficiency. A sensitivity analysis was performed applying a technique in which the change in the various factors and the corresponding model responses are normalized so that meaningful comparisons among the responses could be made. The general results from the sensitivity analysis indicated that the permeabilities of the upper and lower flow zones were the most important factors that produced the greatest changes in the relative sensitivity of the recovery efficiency. Almost equally significant changes occurred in the relative sensitivity of the recovery efficiency when all porosity values of the upper and lower flow zones and the leaky confining units and the vertical anisotropy ratio were changed. The advective factors are the most important in the Cape Coral area according to the sensitivity analysis. However, the dispersivity values used in the model were extrapolated from studies conducted at the nearby Lee County Water Treatment Plant, and these values might not be representative of the actual dispersive characteristics of the lower Hawthorn aquifer in the Cape Coral area.

Florida↗

Field screening of water quality, bottom sediment, and biota associated with irrigation drainage in the Yuma Valley, Arizona, 1995

Because of concerns expressed by the U.S. Congress and the environmental community, the Department of the Interior began a program in late 1985 to identify the nature and extent of water-quality problems induced by irrigation that might exist in the western States. Surface water, bottom sediment, and biota were collected from March through September 1995 along the lower Colorado River and in agricultural drains at nine sites in the Yuma Valley, Arizona, and analyzed for selected inorganic and organic constituents. Analyses of water, bottom sediment, and biota were completed to determine if irrigation return flow has caused, or has the potential to cause, harmful effects on human health, fish, and wildlife in the study area. Concentrations of dissolved solids in surface-water samples collected in March generally did not vary substantially from surface-water samples collected in June. Concentrations of dissolved solids ranged from 712 to 3,000 milligrams per liter and exceeded the U.S. Environmental Protection Agency secondary maximum contaminant level of 500 milligrams per liter for drinking water. Concentrations of chloride in 9 of 18 water samples and concentrations of sulfate in 16 of 18 water samples exceeded the U.S. Environmental Protection Agency secondary maximum contaminant level of 250 milligrams per liter for drinking water. Calcium and sodium were the dominant cations, and chloride and sulfate were the dominant anions. The maximum selenium concentration of 8 micrograms per liter exceeded the U.S. Environmental Protection Agency aquatic-life chronic criterion of 5 micrograms per liter. Concentrations of lead in 7 of 18 water samples and concentrations of mercury in 4 of 18 water samples exceeded the aquatic-life cronic criteria of 3.2 and 0.012 micrograms per liter, respectively. Concentrations of antimony, beryllium, cadmium, and silver in the water samples were below analytical reporting limits. Arsenic was detected in 3 of 9 bottom-sediment samples, and concentrations ranged from 11 to 16 micrograms per gram. Concentrations ofaluminum, beryllium, boron, copper, lead, and zinc were highest in samples from Main Drain at southerly international boundary near San Luis, Arizona. Selenium was detected in all bottom-sediment samples, and concentrations ranged from 0.1 to 0.7 micrograms per gram. Concentrations of cadmium, europium, homium, mercury, molybdenum, silver, tantalum, tin, and uranium were below analytical reporting limits in the bottom-sediment samples. Concentrations of trace elements in bottom-sediment samples were within the ranges found in a study of soils of the western United States and did not indicate a significant accumulation of these constituents. p,p'Dichlorodiphenyldichloroethylene (commonly referred to as p,-p'-DDE) was detected in one bottom-sediment sample at a concentration of 1.4 micrograms per gram. No other organochlorine compounds were detected in the bottom-sediment samples. DDE was present in all fish and bird samples. Almost one-half of the fish samples contained DDE residues that were two times higher than the mean calculated for a national study in 1984-85. Twenty-tree percent of the fish contained more than three times the national mean. Fish from downstream parts of the Main Drain had the highest concentrations of DDE. Although concentrations of DDE in fish and in bird carcasses and eggs were above background levels, residues generally were below thresholds associated with chronic poisoning and reproductive problems in figh and wildlife. Concentrations of 18 trace elements were detected in cattail (Typha sp.) roots, freshwater clam (Corbicula fluminea), fish, and bird samples. Selenium in most fish and in livers of red-winged (Agelaius phoeniceus) and yellow-headed (Xanthocephalus xanthocephalus) blackbirds was above background concentrations but below toxic concentrations. In contrast, selenium was present in a killdeer (Charadrium vociferus) liver sample at potentially toxic con

Water-Resources Investigations Report↗

Science for Stewardship of California's Water Resources

The U.S. Geological Survey (USGS) is the primary Federal agency responsible for scientific evaluation of the natural resources of the United States, including its water. To meet the demands of a growing California, the U.S. Geological Survey's California Water Science Center provides essential science to help Federal, State, and local water agencies evaluate and manage California's critical water resources; adapt to a changing climate; assess, predict, and mitigate natural hazards, such as mudslides and debris flows; and protect the health of rivers, forests, wetlands, and other habitats. The following are some of the ways the USGS is working with other agencies to protect California's water resources and assure that Californians have safe and reliable water supplies for now and in the future.

Fact Sheet↗