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Chloroform in the hydrologic system--sources, transport, fate, occurrence, and effects on human health and aquatic organisms

Chloroform is one of the volatile organic compounds (VOCs) detected most frequently in both ground and surface water. Because it is also one of the four trihalomethanes (THMs) produced in the highest concentrations during the chlorination of drinking water and wastewater, the frequent detection of this compound in ground and surface water of the United States is presumed to be caused primarily by the input of chlorinated water to the hydrologic system. Although anthropogenic sources of the compound are substantial, they are currently estimated to constitute only 10 percent of the total global input to the hydrologic system. Natural sources of the compound include volcanic gases, biomass burning, marine algae, and soil microorganisms. Under most conditions (except in the presence of unusually high bromide concentrations), chloroform is the THM produced in the highest concentrations during chlorination. Furthermore, in most cases where more than one THM is produced from chlorination, the relative concentrations among the different compounds usually decrease with increasing bromination (chloroform > dichlorobromomethane > chlorodibromomethane > bromoform). This phenomenon is presumed to be responsible for the common observation that when more than one THM is detected during investigations of the occurrence of these compounds in the hydrologic system, this same trend is typically observed among their relative concentrations or, for a uniform reporting limit, their relative frequencies of detection. This pattern could provide a valuable means for distinguishing between chlorinated water and other potential sources of chloroform in the environment. Chloroform has been widely detected in national, regional, and local studies of VOCs in ground, surface, source, and drinking waters. Total THM (TTHM) concentrations of the compound, however, were typically less than the Maximum Contaminant Level (MCL) of 80 ?g/L (micrograms per liter) established by the U.S. Environmental Protection Agency (USEPA) for TTHMs. In the studies that compared land-use settings, frequencies of detection of chloroform were higher beneath urban and residential areas than beneath agricultural or undeveloped areas. Because chloroform is a suspected human carcinogen, its presence in drinking water is a potential human health concern. Liver damage, however, is known to occur at chloroform exposures lower than those required to cause cancer, an observation that has been considered by the USEPA as the basis for setting a new, non-zero Maximum Contaminant Level Goal of 70 ?g/L for the compound. As part of its National Water-Quality Assessment Program, the U.S. Geological Survey has been assembling and analyzing data on the occurrence of VOCs (including chloroform) in ground and surface water on a national scale from studies conducted between 1991 and the present. This report presents a summary of current (2004) information on the uses, sources, formation, transport, fate, and occurrence of chloroform, as well as its effects on human health and aquatic organisms.

Scientific Investigations Report↗

Modeling seawater intrusion along the Alabama coastline using physical and machine learning models to evaluate the effects of multiscale natural and anthropogenic stresses

Seawater intrusion threatens groundwater resources in coastal regions, including southern Baldwin County, Alabama, where the freshwater-saltwater interface dynamics remain poorly understood. To address this gap, this study uses combined physics-based and machine-learning models to quantify seawater intrusion caused by natural (storm surges) and anthropogenic (human activities) perturbations. The long short-term memory network and wavelet analysis were used to assess vertical aquifer vulnerabilities, revealing that the shallow part of the Coastal lowlands aquifer system (CL1) in the southern Baldwin County region is more susceptible to sea level rise and groundwater extraction than deeper aquifers. Based on these findings, a cross-sectional numerical model (physics approach) for the CL1 aquifer was developed to evaluate tidal and storm surge effects, using Tropical Storm Claudette (June 2021) as a case study. Results showed that tidal fluctuations had a minimal impact on the saltwater-freshwater interface location, whereas storm surges caused substantial inland movement, with effects lasting for nine months. The steady-state version of the three-dimensional (3D) physical model predicted seawater intrusion across the entire area, and convolutional neural network-based modeling further validated the model results. The 3D physical model was also applied to a smaller area to assess human impact on the saltwater interface due to two groundwater pumping scenarios (± 50% of the baseline pumping rate). Results revealed that a 50% increase in groundwater withdrawals caused seawater to advance ~ 320 m inland, whereas a 50% reduction led to a ~ 270-meter retreat. This study highlights the vulnerability of Alabama’s shallow coastal aquifers to seawater intrusion due to storm surges and human activities, and demonstrates that combining physics-based models with machine learning approaches can improve groundwater predictions, though its accuracy depends on the availability of site-specific data.

Alabama↗

Bathymetric and sediment facies maps for China Bend and Marcus Flats, Franklin D. Roosevelt Lake, Washington, 2008 and 2009

The U.S. Geological Survey (USGS) created bathymetric and sediment facies maps for portions of two reaches of Lake Roosevelt in support of an interdisciplinary study of white sturgeon (Acipenser transmontanus) and their habitat areas within Franklin D. Roosevelt Lake, Washington. In October 2008, scientists from the USGS used a boat-mounted multibeam echo sounder (MBES) to describe bathymetric data to characterize surface relief at China Bend and Marcus Flats, between Northport and Kettle Falls, Washington. In March 2009, an underwater video camera was used to view and record sediment facies that were then characterized by sediment type, grain size, and areas of sand deposition. Smelter slag has been identified as having the characteristics of sand-sized black particles; the two non-invasive surveys attempted to identify areas containing black-colored particulate matter that may be elements and minerals, organic material, or slag. The white sturgeon population in Lake Roosevelt is threatened by the failure of natural recruitment, resulting in a native population that consists primarily of aging fish and that is gradually declining as fish die and are not replaced by nonhatchery reared juvenile fish. These fish spawn and rear in the riverine and upper reservoir reaches where smelter slag is present in the sediment of the river lake bed. Effects of slag on the white sturgeon population in Lake Roosevelt are largely unknown. Two recent studies demonstrated that copper and other metals are mobilized from slag in aqueous environments with concentrations of copper and zinc in bed sediments reaching levels of 10,000 and 30,000 mg/kg due to the presence of smelter slag. Copper was found to be highly toxic to 30-day-old white sturgeon with 96-h LC50 concentrations ranging from 3 to 5 (u or mu)g copper per liter. Older juvenile and adult sturgeons commonly ingest substantial amounts of sediment while foraging. Future study efforts in Lake Roosevelt should include sampling of bottom material to confirm the presence or absence of slag material indicated on the map. In addition, follow-up acoustic work to determine stream velocities at varying discharges, in conjunction with sediment mapping, would be helpful to more accurately identify areas of scour and areas of sediment deposition where slag deposits may accumulate within the Marcus Flats and China Bend reaches. MBES mapping could also be used to determine changes in bed elevation and sedimentation in the study reaches and could help evaluate annual deposition and provide estimates on fine-sediment thickness.

Washington↗

Groundwater quality and the relation between pH values and occurrence of trace elements and radionuclides in water samples collected from private wells in part of the Kickapoo Tribe of Oklahoma Jurisdictional Area, central Oklahoma, 2011

From 1999 to 2007, the Indian Health Service reported that gross alpha-particle activities and concentrations of uranium exceeded the Maximum Contaminant Levels for public drinking-water supplies in water samples from six private wells and two test wells in a rural residential neighborhood in the Kickapoo Tribe of Oklahoma Jurisdictional Area, in central Oklahoma. Residents in this rural area use groundwater from Quaternary-aged terrace deposits and the Permian-aged Garber-Wellington aquifer for domestic purposes. Uranium and other trace elements, specifically arsenic, chromium, and selenium, occur naturally in rocks composing the Garber-Wellington aquifer and in low concentrations in groundwater throughout its extent. Previous studies have shown that pH values above 8.0 from cation-exchange processes in the aquifer cause selected metals such as arsenic, chromium, selenium, and uranium to desorb (if present) from mineral surfaces and become mobile in water. On the basis of this information, the U.S. Geological Survey, in cooperation with the Kickapoo Tribe of Oklahoma, conducted a study in 2011 to describe the occurrence of selected trace elements and radionuclides in groundwater and to determine if pH could be used as a surrogate for laboratory analysis to quickly and inexpensively identify wells that might contain high concentrations of uranium and other trace elements. The pH and specific conductance of groundwater from 59 private wells were measured in the field in an area of about 18 square miles in Lincoln and Pottawatomie Counties. Twenty of the 59 wells also were sampled for dissolved concentrations of major ions, trace elements, gross alpha-particle and gross beta-particle activities, uranium, radium-226, radium-228, and radon-222 gas. Arsenic concentrations exceeded the Maximum Contaminant Level of 10 micrograms per liter in one sample having a concentration of 24.7 micrograms per liter. Selenium concentrations exceeded the Maximum Contaminant Level of 50 micrograms per liter in one sample having a concentration of 147 micrograms per liter. Both samples had alkaline pH values, 8.0 and 8.4, respectively. Uranium concentrations ranged from 0.02 to 383 micrograms per liter with 5 of 20 samples exceeding the Maximum Contaminant Level of 30 micrograms per liter; the five wells with uranium concentrations exceeding 30 micrograms per liter had pH values ranging from 8.0 to 8.5. Concentrations of uranium and radon-222 and gross alpha-particle activity showed a positive relation to pH, with the highest concentrations and activity in samples having pH values of 8.0 or above. The groundwater samples contained dissolved oxygen and high concentrations of bicarbonate; these characteristics are also factors in increasing uranium solubility. Concentrations of radium-226 and radium-228 (combined) ranged from 0.03 to 1.7 picocuries per liter, with a median concentration of 0.45 picocuries per liter for all samples. Radon-222 concentrations ranged from 95 to 3,600 picocuries per liter with a median concentration of 261 picocuries per liter. Eight samples having pH values ranging from 8.0 to 8.7 exceeded the proposed Maximum Contaminant Level of 300 picocuries per liter for radon-222. Eight samples exceeded the 15 picocuries per liter Maximum Contaminant Level for gross alpha-particle activity at 72 hours (after sample collection) and at 30 days (after the initial count); those samples had pH values ranging from 8.0 to 8.5. Gross beta-particle activity increased in 15 of 21 samples during the interval from 72 hours to 30 days. The increase in gross beta-particle activity over time probably was caused by the ingrowth and decay of uranium daughter products that emit beta particles. Water-quality data collected for this study indicate that pH values above 8.0 are associated with potentially high concentrations of uranium and radon-222 and high gross alpha-particle activity in the study area. High pH values also are associated with potentially high concentrations of arsenic, chromium, and selenium in groundwater when these elements occur in the aquifer matrix along groundwater-flow paths.

Oklahoma↗

Peak-, mean-, and low-streamflow regional-regression equations for natural streamflow in central and western Colorado, 2019

The U.S. Geological Survey (USGS), in cooperation with the Colorado Department of Transportation, developed peak-, mean-, and low-streamflow regional-regression equations for estimating various statistics for natural streamflow in hydrologic regions of central and western Colorado. The peak-streamflow regression equations were developed using data from 418 streamgages, consisting of 15,202 years of record and a mean of approximately 36 years of record per streamgage. The mean- and low-streamflow regional-regression equations were developed using data from 323 streamgages where daily streamflow data were collected year-round. The annual exceedance-probability discharges for each streamgage were computed using the USGS software program PeakFQ. Mean monthly and 7-day minimum and maximum streamflows were computed using the USGS software program SWToolbox. Streamflow-duration values were computed using an R script. The regional-regression equations were determined using data for the period of record for a given streamgage through water year 2019. Geographic information systems datasets were used to develop 55 basin and 42 climatic characteristics, which were evaluated as candidate explanatory variables in the regression analysis. For the peak-streamflow regional-regression equations, the study area was divided into four hydrologic regions based on mean basin elevation, including the Plateau (less than 8,014 feet), Mid-Elevation (8,015 feet to 9,492 feet), Sub-Alpine (9,493 feet to 10,490 feet), and Alpine (greater than 10,490 feet) regions. For the peak-streamflow equations, the selection of basin and climatic characteristics was based on the 1-percent annual exceedance-probability discharge for each hydrologic region. For the mean streamflow, streamflow-duration values, and 7-day minimum and maximum streamflows, the study area was divided into four hydrologic regions based on river basin, including the (1) Colorado-East Slope Headwaters, (2) Green River, (3) Rio Grande, and (4) San Juan-Dolores. For mean streamflows, basin and climatic characteristics were evaluated separately for the annual period and each month for each hydrologic region. Regional regression equations published in this report are available for use in the USGS web-based program StreamStats.

Colorado↗

Quality of streams in Johnson County, Kansas, 2002--10

Stream quality in Johnson County, northeastern Kansas, was assessed on the basis of land use, hydrology, stream-water and streambed-sediment chemistry, riparian and in-stream habitat, and periphyton and macroinvertebrate community data collected from 22 sites during 2002 through 2010. Stream conditions at the end of the study period are evaluated and compared to previous years, stream biological communities and physical and chemical conditions are characterized, streams are described relative to Kansas Department of Health and Environment impairment categories and water-quality standards, and environmental factors that most strongly correlate with biological stream quality are evaluated. The information is useful for improving water-quality management programs, documenting changing conditions with time, and evaluating compliance with water-quality standards, total maximum daily loads (TMDLs), National Pollutant Discharge Elimination System (NPDES) permit conditions, and other established guidelines and goals. Constituent concentrations in water during base flow varied across the study area and 2010 conditions were not markedly different from those measured in 2003, 2004, and 2007. Generally the highest specific conductance and concentrations of dissolved solids and major ions in water occurred at urban sites except the upstream Cedar Creek site, which is rural and has a large area of commercial and industrial land less than 1 mile upstream on both sides of the creek. The highest base-flow nutrient concentrations in water occurred downstream from wastewater treatment facilities. Water chemistry data represent base-flow conditions only, and do not show the variability in concentrations that occurs during stormwater runoff. Constituent concentrations in streambed sediment also varied across the study area and some notable changes occurred from previously collected data. High organic carbon and nutrient concentrations at the rural Big Bull Creek site in 2003 decreased to at least one-fourth of those concentrations in 2007 and 2010 likely because of the reduction in upstream wastewater discharge contributions. The highest concentrations of trace metals in 2010 occurred at urban sites on Mill and Indian Creeks. Zinc was the only metal to exceed the probable effects concentration in 2010, which occurred at a site on Indian Creek. In 2007, chromium and nickel at the upstream urban Cedar Creek site exceeded the probable effects concentrations, and in 2003, no metals exceeded the probable effects concentrations. Of 72 organic compounds analyzed in streambed sediment, 26 were detected including pesticides, polycyclic aromatic hydrocarbons (PAHs), fuel products, fragrances, preservatives, plasticizers, manufacturing byproducts, flame retardants, and disinfectants. All 6 PAH compounds analyzed were detected, and the probable effects concentrations for 4 of the 6 PAH compounds analyzed were exceeded in 2010. Only five pesticide compounds were detected in streambed sediment, including carbazole and four pyrethroid compounds. Chronic toxicity guidelines for pyrethroid compounds were exceeded at five sites. Biological conditions reflected a gradient in urban land use, with the less disturbed streams located in rural areas of Johnson County. About 19 percent of sites in 2010 (four sites) were fully supporting of aquatic life on the basis of the four metrics used by Kansas Department of Health and Environment to categorize sites. This is a notable difference compared to previous years when no sites (in 2003 and 2004) or just one site (in 2007) was fully supporting of aquatic life. Multimetric macroinvertebrate scores improved at the Big Bull Creek site where wastewater discharges were reduced in 2007. Environmental variables that consistently were highly negatively correlated with biological conditions were percent impervious surface and percent urban land use. In addition, density of stormwater outfall points adjacent to streams was significantly negatively correlated with biological conditions. Specific conductance of water and sum of PAH concentrations in streambed sediment also were significantly negatively correlated with biological conditions. Total nitrogen in water and total phosphorus in streambed sediment were correlated with most of the invertebrate variables, which is a notable difference from previous analyses using smaller datasets, in which nutrient relations were weak or not detected. The most important habitat variables were sinuosity, length and continuity of natural buffers, riffle substrate embeddedness, and substrate cover diversity, each of which was correlated with all invertebrate metrics including a 10-metric combined score. Correlation analysis indicated that if riparian and in-stream habitat conditions improve then so might invertebrate communities and stream biological quality. Sixty-two percent of the variance in macroinvertebrate community metrics was explained by the single environmental factor, percent impervious surface. Invertebrate responses to urbanization in Johnson County indicated linearity rather than identifiable thresholds. Multiple linear regression models developed for each of the four macroinvertebrate metrics used to determine aquatic-life-support status indicated that percent impervious surface, as a measure of urban land use, explained 34 to 67 percent of the variability in biological communities. Results indicate that although multiple factors are correlated with stream quality degradation, general urbanization, as indicated by impervious surface area or urban land use, consistently is determined to be the fundamental factor causing change in stream quality. Effects of urbanization on Johnson County streams are similar to effects described in national studies that assess effects of urbanization on stream health. Individually important environmental factors such as specific conductance of water, PAHs in streambed sediment, and stream buffer conditions, are affected by urbanization and, collectively, all contribute to stream impairments. Policies and management practices that may be most important in protecting the health of streams in Johnson County are those minimizing the effects of impervious surface, protecting stream corridors, and decreasing the loads of sediment, nutrients, and toxic chemicals that directly enter streams through stormwater runoff and discharges.

Kansas↗

Geohydrology, geochemistry, and numerical simulation of groundwater flow and land subsidence in the Bicycle Basin, Fort Irwin National Training Center, California

Groundwater pumping from Bicycle Groundwater Basin (referred to as Bicycle Basin) in the Fort Irwin National Training Center, California, began in 1967. From 1967 to December 2010, about 46,000 acre-feet of water had been pumped from the basin and transported to the Irwin Basin. During this time, not only did water levels in the basin decline by as much as 100 feet, the quality of the groundwater pumped from the basin also deteriorated in some wells. The U.S. Geological Survey collected geohydrologic data from existing wells, test holes, and 16 additional monitoring wells installed at 6 sites in Bicycle Basin during 1992–2011 to determine the quantity and quality of groundwater available in the basin. Geophysical surveys, including electrical, gravity, and seismic refraction surveys, were completed to help determine the geometry of the structural basin, delineate depths to the interface between Quaternary and Tertiary rocks, map the depth to the water table, and used to develop a geohydrologic framework and groundwater-flow model for Bicycle Basin. Water samples were used to determine the groundwater quality in the basin and to delineate potential sources of poor-quality groundwater. Analysis of stable isotopes of oxygen and hydrogen in groundwater indicated that presentday precipitation is not a major source of recharge to the basin. Tritium and carbon-14 data indicated that most of the groundwater in the basin was recharged prior to 1952 and had an apparent age of 15,625–39,350 years. Natural recharge to the basin was not sufficient to replenish the groundwater pumped from the basin. Interferograms from synthetic aperture radar data (InSAR), analyzed to evaluate land-surface subsidence between 1993 and 2010, showed 0.23 to 1.1 feet of subsidence during this period near one production well north of Bicycle Lake (dry) playa. A groundwater-flow model of Bicycle Basin was developed and calibrated using groundwater levels for 1964– 2010, and a subsidence model using land-surface deformation data for 1993–2010. Between January 1967 and December 2010, the simulated total recharge from precipitation runoff and underflow from adjacent basins was about 5,100 acre-feet and pumpage from the Bicycle Basin was about 47,000 acrefeet of water. Total outflows exceeded natural recharge during this period, resulting in a net loss of about 42,100 acre-feet of groundwater storage in the basin. The Fort Irwin National Training Center is considering various groundwater-management options in the Bicycle Basin. The groundwater-flow model was used to (1) evaluate changes in groundwater levels and subsidence with the addition of capture and recharge of simulated runoff in retention basins (scenario 1) for predevelopment through 2010; (2) simulate a base case (scenario 2) for reference; and (3) compare projections of alternative future pumping strategies for 2011–60 (scenarios 3–5). Model results from the runoff-capture simulation (scenario 1) indicated that total recharge, including runoff captured using retention basins, locally increased water levels, which partially offset, but did not mitigate, groundwater depletion associated with pumping. Groundwater-storage depletion in scenario 1 was about 14 percent less than without runoff capture. Simulated-drawdown results in model layer 1 in the eastern part of the basin indicated that, because of the captured runoff, simulated heads were as much as 100 feet higher in December 2010 than prior to the onset of development in 1967. In contrast, simulated drawdown for model without runoff capture indicated that, without captured runoff, simulated heads for December 2010 in this area were 80–90 feet lower than during the predevelopment period. Subsidence was mitigated slightly in scenario 1 compared to without runoff capture; the largest decrease in subsidence at observation sites was about 0.07 feet.

California↗

Estimating the Probability of Elevated Nitrate Concentrations in Ground Water in Washington State

Logistic regression was used to relate anthropogenic (manmade) and natural variables to the occurrence of elevated nitrate concentrations in ground water in Washington State. Variables that were analyzed included well depth, ground-water recharge rate, precipitation, population density, fertilizer application amounts, soil characteristics, hydrogeomorphic regions, and land-use types. Two models were developed: one with and one without the hydrogeomorphic regions variable. The variables in both models that best explained the occurrence of elevated nitrate concentrations (defined as concentrations of nitrite plus nitrate as nitrogen greater than 2 milligrams per liter) were the percentage of agricultural land use in a 4-kilometer radius of a well, population density, precipitation, soil drainage class, and well depth. Based on the relations between these variables and measured nitrate concentrations, logistic regression models were developed to estimate the probability of nitrate concentrations in ground water exceeding 2 milligrams per liter. Maps of Washington State were produced that illustrate these estimated probabilities for wells drilled to 145 feet below land surface (median well depth) and the estimated depth to which wells would need to be drilled to have a 90-percent probability of drawing water with a nitrate concentration less than 2 milligrams per liter. Maps showing the estimated probability of elevated nitrate concentrations indicated that the agricultural regions are most at risk followed by urban areas. The estimated depths to which wells would need to be drilled to have a 90-percent probability of obtaining water with nitrate concentrations less than 2 milligrams per liter exceeded 1,000 feet in the agricultural regions; whereas, wells in urban areas generally would need to be drilled to depths in excess of 400 feet.

Scientific Investigations Report↗

Methods for estimating selected low-flow frequency statistics and mean annual flow for ungaged locations on streams in North Georgia

The U.S. Geological Survey, in cooperation with the Georgia Department of Natural Resources, Environmental Protection Division, developed regional regression equations for estimating selected low-flow frequency and mean annual flow statistics for ungaged streams in north Georgia that are not substantially affected by regulation, diversions, or urbanization. Selected low-flow frequency statistics and basin characteristics for 56 streamgage locations within north Georgia and 75 miles beyond the State’s borders in Alabama, Tennessee, North Carolina, and South Carolina were combined to form the final dataset used in the regional regression analysis. Because some of the streamgages in the study recorded zero flow, the final regression equations were developed using weighted left-censored regression analysis to analyze the flow data in an unbiased manner, with weights based on the number of years of record. The set of equations includes the annual minimum 1- and 7-day average streamflow with the 10-year recurrence interval (referred to as 1Q10 and 7Q10), monthly 7Q10, and mean annual flow. The final regional regression equations are functions of drainage area, mean annual precipitation, and relief ratio for the selected low-flow frequency statistics and drainage area and mean annual precipitation for mean annual flow. The average standard error of estimate was 13.7 percent for the mean annual flow regression equation and ranged from 26.1 to 91.6 percent for the selected low-flow frequency equations. The equations, which are based on data from streams with little to no flow alterations, can be used to provide estimates of the natural flows for selected ungaged stream locations in the area of Georgia north of the Fall Line. The regression equations are not to be used to estimate flows for streams that have been altered by the effects of major dams, surface-water withdrawals, groundwater withdrawals (pumping wells), diversions, or wastewater discharges. The regression equations should be used only for ungaged sites with drainage areas between 1.67 and 576 square miles, mean annual precipitation between 47.6 and 81.6 inches, and relief ratios between 0.146 and 0.607; these are the ranges of the explanatory variables used to develop the equations. An attempt was made to develop regional regression equations for the area of Georgia south of the Fall Line by using the same approach used during this study for north Georgia; however, the equations resulted with high average standard errors of estimates and poorly predicted flows below 0.5 cubic foot per second, which may be attributed to the karst topography common in that area. The final regression equations developed from this study are planned to be incorporated into the U.S. Geological Survey StreamStats program. StreamStats is a Web-based geographic information system that provides users with access to an assortment of analytical tools useful for water-resources planning and management, and for engineering design applications, such as the design of bridges. The StreamStats program provides streamflow statistics and basin characteristics for U.S. Geological Survey streamgage locations and ungaged sites of interest. StreamStats also can compute basin characteristics and provide estimates of streamflow statistics for ungaged sites when users select the location of a site along any stream in Georgia.

Georgia↗

Suwannee river basin and estuary integrated science workshop: September 22-24, 2004 Cedar Key, Florida

In response to the growing number of environmental concerns in the mostly pristine Suwannee River Basin and the Suwannee River Estuary system, the States of Florida and Georgia, the Federal government, and other local organizations have identified the Suwannee River as an ecosystem in need of protection because of its unique biota and important water resources. Organizations with vested interests in the region formed a coalition, the Suwannee Basin Interagency Alliance (SBIA), whose goals are to promote coordination in the identification, management, and scientific knowledge of the natural resources in the basin and estuary. To date, an integrated assessment of the physical, biological, and water resources has not been completed. A holistic, multi-disciplinary approach is being pursued to address the research needs in the basin and estuary and to provide supportive data for meeting management objectives of the entire ecosystem. The USGS is well situated to focus on the larger concerns of the basin and estuary by addressing specific research questions linking water supply and quality to ecosystem function and health across county and state boundaries. A strategic plan is being prepared in cooperation with Federal, State, and local agencies to identify and implement studies to address the most compelling research issues and management questions, and to conduct fundamental environmental monitoring studies. The USGS, Suwannee River Water Management District and the Florida Marine Research Institute are co-sponsoring this scientific workshop on the Suwannee River Basin and Estuary to: Discuss current and past research findings, Identify information gaps and research priorities, and Develop an action plan for coordinated and relevant research activities in the future. This workshop builds on the highly successful basin-wide conference sponsored by the Suwannee Basin Interagency Alliance that was held three years ago in Live Oak, Florida. This years workshop will focus on identifying information needs and priorities and developing partnerships. The USGS is seeking to define the role of the USGS Florida Integrated Science Center (FISC) in conducting integrated research in the Suwannee River Basin, and to establish a cooperative program with other agencies. Participants interested in river, floodplain, springs, estuary, or basin-wide issues are encouraged to attend. Topics for this years workshop include: Water quality and geochemistry: nutrient enrichment, reduction of nutrient loading to ground water, contaminants, and land use, Hydrogeology: interactions among ground water, surface water and ecosystem, modeling, and baseline mapping, Ecosystem dynamics: structure, process, species, and habitats (estuarine, riverine, floodplain, and wetland), and Information management: data sharing, database development, geographic information system (GIS), and basin-wide models.

Open-File Report↗

Channel change and bed-material transport in the Lower Chetco River, Oregon

The lower Chetco River is a wandering gravel-bed river flanked by abundant and large gravel bars formed of coarse bed-material sediment. Since the early twentieth century, the large gravel bars have been a source of commercial aggregate for which ongoing permitting and aquatic habitat concerns have motivated this assessment of historical channel change and sediment transport rates. Analysis of historical channel change and bed-material transport rates for the lower 18 kilometers shows that the upper reaches of the study area are primarily transport zones, with bar positions fixed by valley geometry and active bars mainly providing transient storage of bed material. Downstream reaches, especially near the confluence of the North Fork Chetco River, are zones of active sedimentation and channel migration. Multiple analyses, supported by direct measurements of bedload during winter 2008–09, indicate that since 1970 the mean annual flux of bed material into the study reach has been about 40,000–100,000 cubic meters per year. Downstream tributary input of bed-material sediment, probably averaging 5–30 percent of the influx coming into the study reach from upstream, is approximately balanced by bed-material attrition by abrasion. Probably little bed material leaves the lower river under natural conditions, with most net influx historically accumulating in wider and more dynamic reaches, especially near the North Fork Chetco River confluence, 8 kilometers upstream from the Pacific Ocean. The year-to-year flux, however, varies tremendously. Some years may have less than 3,000 cubic meters of bed material entering the study area; by contrast, some high-flow years, such as 1982 and 1997, likely have more than 150,000 cubic meters entering the reach. For comparison, the estimated annual volume of gravel extracted from the lower Chetco River for commercial aggregate during 2000–2008 has ranged from 32,000 to 90,000 cubic meters and averaged about 59,000 cubic meters per year. Mined volumes probably exceeded 140,000 cubic meters per year for several years in the late 1970s. Repeat surveys and map analyses indicate a reduction in bar area and sinuosity between 1939 and 2008, chiefly in the period 1965–95. Repeat topographic and bathymetric surveys show channel incision for substantial portions of the study reach, with local areas of bed lowering by as much as 2 meters. A specific gage analysis at the upstream end of the study reach indicates that incision and narrowing followed aggradation culminating in the late 1970s. These observations are all consistent with a reduction of sediment supply relative to transport capacity since channel surveys in the late 1970s, probably owing to a combination of (1) bed sediment removal and (2) transient river adjustments to large sediment volumes brought by floods such as those in 1964 and, to a lesser extent, 1996.

Oregon↗

Development of the Hydroecological Integrity Assessment Process for Determining Environmental Flows for New Jersey Streams

The natural flow regime paradigm and parallel stream ecological concepts and theories have established the benefits of maintaining or restoring the full range of natural hydrologic variation for physiochemical processes, biodiversity, and the evolutionary potential of aquatic and riparian communities. A synthesis of recent advances in hydroecological research coupled with stream classification has resulted in a new process to determine environmental flows and assess hydrologic alteration. This process has national and international applicability. It allows classification of streams into hydrologic stream classes and identification of a set of non-redundant and ecologically relevant hydrologic indices for 10 critical sub-components of flow. Three computer programs have been developed for implementing the Hydroecological Integrity Assessment Process (HIP): (1) the Hydrologic Indices Tool (HIT), which calculates 171 ecologically relevant hydrologic indices on the basis of daily-flow and peak-flow stream-gage data; (2) the New Jersey Hydrologic Assessment Tool (NJHAT), which can be used to establish a hydrologic baseline period, provide options for setting baseline environmental-flow standards, and compare past and proposed streamflow alterations; and (3) the New Jersey Stream Classification Tool (NJSCT), designed for placing unclassified streams into pre-defined stream classes. Biological and multivariate response models including principal-component, cluster, and discriminant-function analyses aided in the development of software and implementation of the HIP for New Jersey. A pilot effort is currently underway by the New Jersey Department of Environmental Protection in which the HIP is being used to evaluate the effects of past and proposed surface-water use, ground-water extraction, and land-use changes on stream ecosystems while determining the most effective way to integrate the process into ongoing regulatory programs. Ultimately, this scientifically defensible process will help to quantify the effects of anthropogenic changes and development on hydrologic variability and help planners and resource managers balance current and future water requirements with ecological needs.

Scientific Investigations Report↗

Temporal Differences in Flow Depth and Velocity Distributions and Hydraulic Microhabitats Near Bridges of the Lower Platte River, Nebraska, 1934-2006

As part of a collaborative study of the cumulative impacts on stream and riparian ecology of water and channel management practices in the lower Platte River, Nebraska, this report describes a study by the U.S. Geological Survey in cooperation with the Lower Platte South Natural Resources District that summarizes: (1) temporal differences in distribution of streamflow depth, velocity, and microhabitats among five discrete 11-water-year periods 1934-44, 1951-61, 1966-76, 1985-95, and 1996-2006, and (2) the effects of bridge proximity on distribution of streamflow depth, velocity, and microhabitat of the Platte River when cross sections were measured at a similar discharge. The scope of the study included the four presently (2008) active streamflow-gaging stations located near bridges over the lower Platte River at North Bend, near Leshara, near Ashland, and at Louisville, Nebraska, and the most downstream streamflow-gaging station within the central Platte River segment near Duncan, Nebraska. Generally, in cases where temporal differences in streamflow depth and velocity were evident, at least one of the water-year periods from 1934 through 1995 had deeper streamflow than the recent water-year period (1996-2006). Temporal differences in distributions of streamflow depth were not strongly associated with differences in either climatic conditions or the maximum peak flow that occurred prior to the latest discharge measurement during each period. The relative cross-sectional area of most hydraulic niches did not differ among the water-year periods. Part of this apparent uniformity likely was an artifact of the broad microhabitat classification used for this study. In cases where temporal differences in relative cross-sectional area of hydraulic niches were evidenced, the differences occurred during high- and low-flow conditions, not during median flow conditions. The temporal differences in relative cross-sectional area were found more frequently for hydraulic niches defined by moderate and fast velocities than for hydraulic niches defined by slow velocities. Generally, any significant increase or decrease in the relative cross-sectional areas of hydraulic niches during the water-year periods from 1934 through 1995 had disappeared during the most recent water-year period, 1996-2006. Deep-Swift niche was the predominant hydraulic niche for all near-bridge sites on the lower Platte River for high- and median-flow conditions. The Deep-Swift niche also was the predominant niche for the near-bridge sites near Ashland and at Louisville for low-flow conditions; for the near-bridge sites at North Bend and near Leshara, streamflow cross-sectional areas during low-flow conditions were shared among the Shallow-Moderate, Intermediate-Moderate, Intermediate-Swift, and Deep-Swift hydraulic niches. For the near-bridge site near Duncan, the site farthest downstream in the central Platte River system, the Deep-Swift hydraulic niche was predominant only during high-flow conditions; during median- and low-flow conditions the relative cross-sectional area was shared among the Shallow-Slow, Shallow-Moderate, Intermediate-Moderate, and Intermediate-Swift hydraulic niches. Significant temporal differences in the relative cross-sectional area of the Deep-Swift hydraulic niche were found for sites near the two farthest downstream bridges near Ashland and at Louisville, but only for low-flow conditions. The Deep-Swift microhabitat was of special interest because it is the preferred hydraulic habitat during the adult life of the endangered pallid sturgeon (Scaphirhynchus albus). Temporal differences in relative cross-sectional areas of the Glide low-flow geomorphic microhabitat that contained the Deep-Swift hydraulic niche also indicated that relative cross-sectional areas of the Glide during the 1951-61 and 1996-2006 water-year periods were lower than during the 1966-76 period. The temporal differences indicated that any significant temporal chang

Scientific Investigations Report↗

Water-resources activities of the U.S. Geological Survey in Texas; fiscal years 1982-84

The U.S. Geological Survey (USGS) was established by an act of Congress on March 3, 1879, to provide a permanent Federal agency to conduct the systematic and scientific classification of the public lands, and examination of the geological structure, mineral resources, and products of national domain. An integral part of that original mission includes publishing and disseminating the earth-science information needed to understand, to plan the use of, and to manage the Nation's energy, land, mineral, and water resources. Since 1879, the research and fact-finding role of the USGS has grown and been modified to meet the changing needs of the Nation it serves. As part of that evolution, the USGS has become the Federal Government's largest earth-science research agency, the Nation's largest civilian mapmaking agency, the primary source of data on the Nation's surface- and ground-water resources, and the employer of the largest number of professional earth scientists. Today's programs serve a diversity of needs and users. Programs include: Conducting detailed assessments of the energy and mineral potential of the Nation's land and offshore areas. Investigating and issuing warnings of earthquakes, volcanic eruptions, landslides, and other geologic and hydrologic hazards. Conducting research on the geologic structure of the Nation. Studying the geologic features, structure, processes, and history of the other planets of our solar system. Conducting topographic surveys of the Nation and preparing topographic and thematic maps and related cartographic products. Developing and producing digital cartographic data bases and products. Collecting data on a routine basis to determine the quantity, quality, and use of surface and ground water. Conducting water-resources appraisals in order to describe the consequences of alternative plans for developing land and water resources. Conducting research in hydraulics and hydrology and coordinating all Federal water-data acquisition. Using remotely sensed data to develop new cartographic, geologic, and hydrologic research techniques for natural resources planning and management. Providing earth-science information through an extensive publications program and a network of public access points. Along with its continuing commitment to meet the growing and changing earthscience information needs of the Nation, the USGS remains dedicated to its original mission to collect, analyze, interpret, publish, and disseminate information about the natural resources of the Nation providing "earth science in the public service."

Open-File Report↗

Land area change in coastal Louisiana: A multidecadal perspective (from 1956 to 2006)

The U.S. Geological Survey (USGS) analyzed changes in the configuration of land and water in coastal Louisiana by using a sequential series of 14 data sets summarizing land and water areas from 1956 to 2006. The purpose of this study is to provide a spatially and temporally consistent source of quantitative information on land area across coastal Louisiana, broken into three physiographic provinces (the term 'coastal Louisiana' is used to present data on the collective area). The land-water data sets used in this study are interpreted through spatial analysis and by linear regression analysis. The spatial depictions of land area change reveal a complex and interwoven mosaic of loss and gain patterns caused by natural and human-induced processes operating at varied temporal and spatial scales, resulting in fluctuating contributions to coastal loss. The linear regression analysis provides a robust estimate of recent change trends by comparing land area over time for all data sets from 1985 to 2004 and from 1985 to 2006 by physiographic province across coastal Louisiana. The 1956 to 2006 map showing multidecadal changes, along with the linear regressions of land area change presented in this study, provide a comprehensive and concise presentation of historical trends and rates of land area change in coastal Louisiana. Taking a broad historical view provides an in-depth understanding of land area changes over time. For example, one observation provided by our historical review is that the majority of the widespread, nontransitory land gains depicted on the map over the past 50 years, with the exception of the progradation of the Atchafafalaya River and Wax Lake deltas, are primarily related to sediment placement and landward migration of barrier islands. Another point revealed by our historical approach is that recent land losses caused by hurricanes sometimes commingled with or exacerbated older losses formed during the 1956 to 1978 period. Furthermore, our analyses also show how the immediate impacts of extreme storms can alter the long-term, time-averaged trends of landscape change, thus limiting the range of projections for the future. For this reason, this study does not include trend projections beyond 2015 because of uncertainties related to recovery from the 2005 hurricane season and the potential for other episodic events that could skew future rates of change.

Louisiana↗

Maps of elevation of top of Pierre Shale and surficial deposit thickness with hydraulic properties from borehole geophysics and aquifers tests within and near Ellsworth Air Force Base, South Dakota, 2020–21

The U.S. Geological Survey, in cooperation with the U.S. Air Force Civil Engineer Center, collected borehole geophysical data and completed simple aquifer tests to estimate the thickness and hydraulic properties of surficial deposits. The purpose of data collection was to create generalized contour maps of Pierre Shale elevation and surficial deposit thickness within and near Ellsworth Air Force Base (study area). Natural gamma and electromagnetic induction data were collected to refine or determine surficial deposit thickness at selected wells. Additionally, data from previous geophysical studies and driller logs were compiled and combined with results from natural gamma and electromagnetic induction data to provide a more spatially complete image of the subsurface. Borehole nuclear magnetic resonance (bNMR) data were collected to estimate hydraulic conductivity and water content of surficial deposits overlying Pierre Shale. Simple aquifer tests using water slugs (slug tests) were completed to estimate hydraulic conductivity of surficial deposits, and results were compared to hydraulic conductivity estimates from bNMR data. All data used to construct maps and estimate hydraulic properties are provided in an accompanying U.S. Geological Survey data release (available at https://doi.org/10.5066/P9FLR79F ). Generalized contour maps were constructed using results from 26 borehole geophysical logs, 35 geophysical transects from previous studies, and 304 wells with driller logs. Pierre Shale elevation generally followed land-surface topography, sloping from high elevations in the north to lower elevations in the south. Topographic highs of Pierre Shale, where present, could act as groundwater divides that potentially affect groundwater flow direction. Surficial deposit thickness varied spatially and ranged from 0 to 86 feet. Surficial deposits generally were thickest in higher elevation areas near ephemeral streams in the northern part of the study area. Hydraulic conductivity estimated from bNMR results using two analytical methods ranged from 0.1 to 2,314 feet per day, whereas hydraulic conductivity estimated from slug tests ranged from 0.001 to 193 feet per day. Hydraulic conductivity estimates from slug tests were plotted with surficial deposit thickness contours instead of bNMR estimates because bNMR estimates were determined to overestimate hydraulic conductivity. Hydraulic conductivity values generally were greater in the southwestern part of study area than the northeastern part.

South Dakota↗

Water resources of Sweetwater County, Wyoming

Sweetwater County is located in the southwestern part of Wyoming and is the largest county in the State. A study to quantify the availability and describe the chemical quality of surface-water and ground-water resources in Sweetwater County was conducted by the U.S. Geological Survey in cooperation with the Wyoming State Engineer’s Office. Most of the county has an arid climate. For this reason a large amount of the flow in perennial streams within the county is derived from outside the county. Likewise, much of the ground-water recharge to aquifers within the county is from flows into the county, and occurs slowly. Surface-water data were not collected as part of the study. Evaluations of streamflow and stream-water quality were limited to analyses of historical data and descriptions of previous investigations. Forty-six new ground-water-quality samples were collected as part of the study and the results from an additional 782 historical ground-water-quality samples were reviewed. Available hydrogeologic characteristics for various aquifers throughout the county also are described. Flow characteristics of streams in Sweetwater County vary substantially depending on regional and local basin characteristics and anthropogenic factors. Because precipitation amounts in the county are small, most streams in the county are ephemeral, flowing only as a result of regional or local rainfall or snowmelt runoff. Flows in perennial streams in the county generally are a result of snowmelt runoff in the mountainous headwater areas to the north, west, and south of the county. Flow characteristics of most perennial streams are altered substantially by diversions and regulation. Water-quality characteristics of selected streams in and near Sweetwater County during water years 1974 through 1983 were variable. Concentrations of dissolved constituents, suspended sediment, and bacteria generally were smallest at sites on the Green River because of resistant geologic units, increased vegetative cover, large diluting streamflows, and large reservoirs. Concentrations of dissolved constituents, suspended sediment, and bacteria generally were largest at sites in the Big Sandy River and Bitter Creek Basins. Some nutrient concentrations and bacteria counts exceeded various State and Federal water-quality criteria. Historical and recent anthropogenic activities contributed to natural sources of many dissolved constituents and suspended sediment. Both water-table and artesian conditions occur in aquifers within the county. Shallow ground water is available throughout the county, although much of it is only marginally suitable or is unsuitable for domestic and irrigation uses mainly because of high total dissolved solids (TDS) concentrations. Suitable ground water for livestock use can be found in most areas of the county. Ground-water quality tends to deteriorate with increasing distance from recharge areas and with increasing depth below land surface. Ground water from depths of greater than a few thousand feet tends to have TDS concentrations that make it moderately saline to briny. In some areas even shallow ground water has moderately saline TDS concentrations. Specific constituents in parts of some aquifers in the county occur in relatively high concentrations when compared to U.S. Environmental Protection Agency drinking-water standards. Relatively high concentrations of sulfate, fluoride, boron, iron, and manganese were found in several aquifers. Many ground-water samples from the Battle Spring aquifer in the Great Divide Structural Basin had high radionuclide concentrations. The estimated mean daily water use in Sweetwater County in 2000 was 170.73 million gallons per day. Irrigation was the largest single use of water in the county with an estimated mean use of more than 92 million gallons per day. Surface water irrigation accounted for nearly 90 percent of the total irrigation water used in 2000. Although ground water is used to a much lesser extent than surface water, in many areas of the county it is the only source of water available.

Wyoming↗

Relations between well-field pumping and induced canal leakage in east-central Miami-Dade County, Florida, 2010-2011

An extensive canal and water management system exists in south Florida to prevent flooding, replenish groundwater, and impede saltwater intrusion. The unconfined Biscayne aquifer, which underlies southeast Florida and provides water for millions of residents, interacts with the canal system. The Biscayne aquifer is composed of a highly transmissive karst limestone; therefore, canal stage and flow may be affected by production well pumping, especially in locations where production wells and canals are in proximity. The U.S. Geological Survey developed a local-scale, transient, numerical groundwater flow model of a well field in Miami-Dade County to (1) quantify relations between well-field pumping and C-2 Canal (herein referred to as the Snapper Creek Canal) leakage, (2) determine primary controls on canal leakage variability, and (3) summarize results that could simplify characterization of canal/well-field interactions in other locations. In addition to the groundwater model development, stable isotope data from water-quality samples were used to characterize the relations between production well pumping and canal leakage. The results from the groundwater model and the isotope data were used to refine the conceptual flow model of the study area. The groundwater flow model MODFLOW-NWT was used for simulating groundwater flow and quantifying interactions between pumping from the well field and Snapper Creek Canal leakage. Input data for the groundwater model included precipitation, evapotranspiration, pumping, canal stage, and regional groundwater elevation. The inverse modeling tool UCODE and groundwater data from June 2010 to July 2011 were used to calibrate the model. Parameter sensitivity analyses were performed with UCODE. Model sensitivities to geologic heterogeneity, non-laminar flow, and changes in the regional flow boundary were evaluated. The groundwater model generally fits the calibration criteria well within estimated error ranges for groundwater elevations and canal leakage values. The mean average error for heads simulated with the model was 0.19 meter, and head residuals were generally randomly distributed. The model simulated groundwater flow under ambient conditions without production well pumping to establish background leakage. Groundwater flow also was simulated with production well pumping to estimate induced leakage from the Snapper Creek Canal that occurs in response to pumping. Canal leakage was quantified as a percentage of total canal leakage. The percentage of leakage during pumping increased non-linearly with pumping rate, indicating a decreasing sensitivity of canal leakage to pumping at relatively large pumping magnitudes. The results for Snapper Creek Canal may serve as an upper limit for well-field interaction with surface-water features in Miami-Dade County, given the proximity (about 50 meters) of the pumping wells in this study to the Snapper Creek Canal. The isotopic compositions of hydrogen (H) and oxygen (O) in groundwater samples were used to distinguish sources for groundwater within the study area and to assess the extent of natural mixing and pumping-induced mixing with water in the Snapper Creek Canal. Water-level data and water-quality samples were collected from monitoring well clusters, production wells, and the Snapper Creek Canal during discrete sampling events under ambient and pumping conditions. Trends in the isotope data generally follow the regional west-to-east hydraulic gradient across the study area. Data collected within the monitoring-well clusters in closest proximity to the canal indicate that groundwater/surface-water interactions are greatest within the shallow flow zone of the aquifer, especially during pumping conditions. The isotopic composition of samples collected within the study area indicates that the shallow, highly transmissive preferential flow zone receives substantial recharge from the canal. The isotope data from the production wells which are open to the deeper flow zone within the aquifer, indicate only traces of mixing with a 2 H- and 18 O-enriched source, suggesting little canal admixture with waters of the deeper flow zone. Results from the groundwater model and the stable isotope data analysis indicate the importance of considering geologic heterogeneity when investigating the relations between pumping and canal leakage, not only at this site, but also at other sites with similar heterogeneous geology. The model results were consistently sensitive to the hydrogeologic framework and changes in hydraulic conductivities. The model and the isotope data indicate that the majority of the groundwater/surface-water interactions occurred within the shallow flow zone. A relatively lower-permeability geologic layer occurring between the shallowest and deep preferential flow zones lessens the interactions between the production wells and the canal.

Florida↗