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At least 1,315 records · Page 73Linked to original sources

USGS1953

Determination of traces of cobalt in soils: A field method

The growing use of geochemical prospecting methods in the search for ore deposits has led to the development of a field method for the determination of cobalt in soils. The determination is based on the fact that cobalt reacts with 2-nitroso-1-naphthol to yield a pink compound that is soluble in carbon tetrachloride. The carbon tetrachloride extract is shaken with dilute cyanide to complex interfering elements and to remove excess reagent. The cobalt content is estimated by comparing the pink color in the carbon tetrachloride with a standard series prepared from standard solutions. The cobalt 2-nitroso-1-naphtholate system in carbon tetrachloride follows Beer's law. As little as 1 p.p.m. can be determined in a 0.1-gram sample. The method is simple and fast and requires only simple equipment. More than 40 samples can be analyzed per man-day with an accuracy within 30% or better.

Analytical Chemistry↗

USGS2002

Application of classification-tree methods to identify nitrate sources in ground water

A study was conducted to determine if nitrate sources in ground water (fertilizer on crops, fertilizer on golf courses, irrigation spray from hog (Sus scrofa) wastes, and leachate from poultry litter and septic systems) could be classified with 80% or greater success. Two statistical classification-tree models were devised from 48 water samples containing nitrate from five source categories. Model I was constructed by evaluating 32 variables and selecting four primary predictor variables (??15N, nitrate to ammonia ratio, sodium to potassium ratio, and zinc) to identify nitrate sources. A ??15N value of nitrate plus potassium <18.2 indicated animal sources; a value >18.2 indicated inorganic or soil organic N. A nitrate to ammonia ratio <575 indicated inorganic fertilizer on agricultural crops; a ratio >575 indicated nitrate from golf courses. A sodium to potassium ratio <3.2 indicated septicsystem wastes; a ratio >3.2 indicated spray or poultry wastes. A value for zinc <2.8 indicated spray wastes from hog lagoons; a value >2.8 indicated poultry wastes. Model 2 was devised by using all variables except ??15N. This model also included four variables (sodium plus potassium, nitrate to ammonia ratio, calcium to magnesium ratio, and sodium to potassium ratio) to distinguish categories. Both models were able to distinguish all five source categories with better than 80% overall success and with 71 to 100% success in individual categories using the learning samples. Seventeen water samples that were not used in model development were tested using Model 2 for three categories, and all were correctly classified. Classification-tree models show great potential in identifying sources of contamination and variables important in the source-identification process.

Conference Paper↗

USGS1994

Quaternary Geologic Map of the Lake Nipigon 4 Degrees x 6 Degrees Quadrangle, United States and Canada

The Quaternary Geologic Map of the Lake Nipigon 4 degree x 6 degree Quadrangle was mapped as part of the Quaternary Geologic Atlas of the United States. The atlas was begun as an effort to depict the areal distribution of surficial geologic deposits and other materials that accumulated or formed during the past 2+ million years, the period that includes all activities of the human species. These materials are at the surface of the earth. They make up the 'ground' on which we walk, the 'dirt' in which we dig foundations, and the 'soil' in which we grow crops. Most of our human activity is related in one way or another to these surface materials that are referred to collectively by many geologists as regolith, the mantle of fragmental and generally unconsolidated material that overlies the bedrock foundation of the continent. The maps were compiled at 1:1,000,000 scale. This map is a product of collaboration of the Ontario Geological Survey, the University of Michigan, and the U.S. Geological Survey, and is designed for both scientific and practical purposes. It was prepared in two stages. First, separate maps and map explanations were prepared by the compilers. Second, the maps were combined, integrated, and supplemented by the editor. Map unit symbols were revised to a uniform system of classification and the map unit descriptions were prepared by the editor from information received from the compilers and from additional sources listed under Sources of Information. Diagrams accompanying the map were prepared by the editor. For scientific purposes, the map differentiates Quaternary surficial deposits on the basis of lithology or composition, texture or particle size, structure, genesis, stratigraphic relationships, engineering geologic properties, and relative age, as shown on the correlation diagram and indicated in the map unit descriptions. Deposits of some constructional landforms, such as kame moraine deposits, are distinguished as map units. Deposits of erosional landforms, such as outwash terraces, are not distinguished, although glaciofluvial, ice-contact, and lacustrine deposits that are mapped may be terraced. As a Quaternary geologic map it serves as a base from which a variety of maps relating Quaternary geologic history can be derived. For practical purposes, the map is a surficial materials map. Materials are distinguished on the basis of lithology or composition, texture or particle size, and other physical, chemical, and engineering characteristics. It is not a map of soils that are recognized and classified in pedology or agronomy. Rather, it is a generalized map of soils as recognized in engineering geology, or of substrata or parent materials in which pedologic or agronomic soils are formed. As a materials map it serves as a base from which a variety of maps for use in planning engineering, land use, or land management projects can be derived.

IMAP↗

USGS2021

Hydrogeology and simulation of groundwater flow in Columbia County, Wisconsin

This report describes the regional hydrogeology and groundwater resources of Columbia County, Wisconsin, and documents a regional groundwater flow model developed for the county. Regional hydrostratigraphic units include the unlithified aquifer, the upper bedrock aquifer, and the Elk Mound aquifer. The unlithified aquifer consists of deposits that range in composition from sand and gravel outwash and stream deposits to silty, sandy till. This aquifer is less than 25 ft thick in much of eastern Columbia County, but consists of permeable sand and gravel extending to over 250 ft in depth in the Wisconsin River valley bottom. The upper bedrock aquifer consists of Ordovician and upper Cambrian sedimentary formations, including sandstone, siltstone and dolomitic strata. The upper bedrock aquifer underlies the unlithified aquifer in eastern portions of the County, but is absent to the west, where these formations are largely eroded. The contact between the Tunnel City Group and Wonewoc Formation (Top of Elk Mound Group) forms the base of the upper bedrock aquifer. Bedding plane fractures are common to this aquifer, although only a portion of the observed fractures appear to be hydraulically active. The upper bedrock aquifer is a significant source of groundwater at a regional scale. Measurements of hydraulic head showed a difference of several feet across the bottom of this aquifer to the underlying Wonewoc sandstone, indicating that the basal facies of the Tunnel City Group functions as an aquitard separating the upper bedrock aquifer from the Elk Mound aquifer. Conditions vary considerably within this aquifer, depending on the local lithostratigraphy. For example, where present, the St. Lawrence Fm. and fine-grained intervals of the Tunnel City Group may be locally-extensive aquitards. The Elk Mound aquifer consists of Cambrian sandstone of the Wonewoc, Eau Claire, and Mount Simon Formations. It is thin to absent in several locations but ranges up to 600 ft in thickness over much of southern Columbia County. The variation in thickness is due in large part to the irregular topography of the underlying Precambrian crystalline rock, which generally serves as the base of the groundwater system. In neighboring counties, a fine-grained facies within the Eau Claire Fm. acts as a regionally extensive aquitard, referred to as the Eau Claire aquitard. Much of the data collected and compiled for this study suggest that shale or dolomite within the Eau Claire Fm., which is the equivalent of the Eau Claire aquitard, occurs only within southwestern Columbia County. There is little to no evidence of the Eau Claire aquitard over most of the county. Where the dolomite and shale are absent, the Elk Mound aquifer is relatively homogenous and does not include a mappable aquitard. A three-dimensional steady-state flow model presented here represents long-term, average conditions in the regional groundwater system since about 1970. The model was constructed with the U.S. Geological Survey’s MODFLOW-NWT code; it has six layers with a uniform grid of 300 ft x 300 ft cells. Layers 1 and 2 simulate the unlithified aquifer and layer 3 represents the upper bedrock aquifer. The Elk Mound aquifer is simulated by layers 4, 5 and 6, representing the Wonewoc, Eau Claire, and Mount Simon Formations, respectively. The model extends beyond the boundaries of Columbia County to ensure that hydrologic conditions simulated within the County are consistent with regional conditions. Recharge to the groundwater flow model is based on results from a GIS-based soil-water-balance model. Recharge was simulated with the unsaturated zone flow (UZF) package in MODFLOW. This approach is particularly useful for quantifying groundwater discharge to riparian wetlands because UZF tracks recharge that would lead to the simulated water table exceeding the land surface (represented by the top of model layer 1) and reroutes it to nearby stream segments. The model includes pumping from 256 wells, and 178 of these are located within Columbia County. Pumping totaled about 28 million gallons per day (mgd) on average since 1970, with 7.2 mgd of the withdrawal from within the County. Model calibration was performed with the PEST parameter estimation code. Calibration targets included approximately 3,900 head measurements and 91 stream flow measurements. Four vertical-head differences across hydrogeologic units, calculated from data collected during packer testing in wells in Columbia County, were also used in model calibration. Results from the calibrated model provide a groundwater balance for the region. About 83 percent of groundwater originates as recharge to the water table, 12 percent comes from leakage from streams, and about 5 percent of the groundwater flows into the model domain from surrounding areas. About 95 percent of the simulated groundwater discharges to steams and other surface water features, about 3 percent flows across model boundaries to surrounding areas of the groundwater system, and pumping accounts for 2 percent of discharge. Simulated flow paths are relatively local, from recharge in upland areas to discharge in nearby streams and wetlands. The model has many potential applications, including simulation of the effects of existing or proposed high-capacity wells, estimating the zone of contribution for these wells, and understanding relationships between surface water and groundwater. Future refinements to the model, such as incorporating new information about the extent and hydraulic characteristics of the Tunnel City Group, will improve its utility in understanding advective flow between the upper bedrock and Elk Mound aquifers. If seasonal or annual variations in the groundwater system are of interest, this steady-state model could be brought into a transient mode.

Wisconsin↗

USGS2006

Change in atmospheric mineral aerosols in response to climate: Last glacial period, preindustrial, modern, and doubled carbon dioxide climates

Desert dust simulations generated by the National Center for Atmospheric Research's Community Climate System Model for the current climate are shown to be consistent with present day satellite and deposition data. The response of the dust cycle to last glacial maximum, preindustrial, modern, and doubled-carbon dioxide climates is analyzed. Only natural (non-land use related) dust sources are included in this simulation. Similar to some previous studies, dust production mainly responds to changes in the source areas from vegetation changes, not from winds or soil moisture changes alone. This model simulates a +92%, +33%, and -60% change in dust loading for the last glacial maximum, preindustrial, and doubled-carbon dioxide climate, respectively, when impacts of carbon dioxide fertilization on vegetation are included in the model. Terrestrial sediment records from the last glacial maximum compiled here indicate a large underestimate of deposition in continental regions, probably due to the lack of simulation of glaciogenic dust sources. In order to include the glaciogenic dust sources as a first approximation, we designate the location of these sources, and infer the size of the sources using an inversion method that best matches the available data. The inclusion of these inferred glaciogenic dust sources increases our dust flux in the last glacial maximum from 2.1 to 3.3 times current deposition. Copyright 2006 by the American Geophysical Union.

Journal of Geophysical Research D: Atmospheres↗

USGS2010

Hydrology of the North Cascades region, Washington: 2. A proposed hydrometeorological streamflow prediction method

On the basis of a linear relationship between winter (October-April) precipitation and annual runoff from a drainage basin (Rasmussen and Tangborn, 1976) a physically reasonable model for predicting summer (May-September) streamflow from drainages in the North Cascades region was developed. This hydrometeorological prediction method relates streamflow for a season beginning on the day of prediction to the storage (including snow, ice, soil moisture, and groundwater) on that day. The spring storage is inferred from an input-output relationship based on the principle of conservation of mass: spring storage equals winter precipitation on the basin less winter runoff from the basin and less winter evapotranspiration, which is presumed to be small. The method of prediction is based on data only from the years previous to the one for which the prediction is made, and the system is revised each year as data for the previous year become available. To improve the basin storage estimate made in late winter or early spring, a short-season runoff prediction is made. The errors resulting from this short-term prediction are used to revise the storage estimate and improve the later prediction. This considerably improves the accuracy of the later prediction, especially for periods early in the summer runoff season. The optimum length for the test period appears to be generally less than a month for east side basins and between 1 and 2 months for those on the west side of the Cascade Range. The time distribution of the total summer runoff can be predicted when this test season is used so that on May 1 monthly streamflow for the May-September season can be predicted. It was found that summer precipitation and the time of minimum storage are two error sources that were amenable to analysis. For streamflow predictions in seasons beginning in early spring the deviation of the subsequent summer precipitation from a long-period average will contribute up to 53% of the prediction error. This contribution decreases to nearly zero during the summer and then rises slightly for late summer predictions. The reason for the smaller than expected effect of summer precipitation is thought to be due to the compensating effect of increased evaporative losses and increased infiltration when precipitation is greater than normal during the summer months. The error caused by the beginning winter month (assumed to be October in this study) not coinciding with the time of minimum storage was examined; it appears that October may be the best average beginning winter month for most drainages but that a more detailed study is needed. The optimum beginning of the winter season appears to vary from August to October when individual years are examined. These results demonstrate that standard precipitation and runoff measurements in the North Cascades region are adequate for constructing a predictive hydrologic model. This model can be used to make streamflow predictions that compare favorably with current multiple regression methods based on mountain snow surveys. This method has the added advantages of predicting the space and time distributions of storage and summer runoff.

Washington↗

USGS1977

Geology and ground water in Door County, Wisconsin, with emphasis on contamination potential in the Silurian dolomite

Door County, a recreational and fruit-growing area bordering Lake Michigan in northeastern Wisconsin, has had a long history of ground-water contamination from surface and near-surface sources. Contamination is most severe in late summer when fruit-canning operations and the influx of tourists create additional wastes. Silurian dolomite is the upper bedrock unit in the county and yields generally adequate supplies of very hard water with locally objectionable concentrations of iron and nitrate. Thin soil cover and well-fractured dolomitic bedrock give easy entry to ground-water contaminants throughout large parts of Door County. Many contaminants enter the dolomite by surface or near-surface seepage. There is little attenuation of contamination concentrations in the well-jointed dolomite, and contaminants may travel long distances underground in a relatively short time. The major source of ground-water contamination is bacteria, from individual waste-disposal systems, agricultural, industrial, and municipal wastes. Areas of the county underlain by contaminated zones include only a small percentage of the total ground-water system and are separated by large volumes of ground water free of contamination. (Woodard-USGS)

Open-File Report↗

USGS1984

Movement and fate of creosote waste in ground water, Pensacola, Florida; U.S. Geological Survey toxic waste--ground-water contamination program

In 1983, the U.S. Geological Survey, Office of Hazardous Waste Hydrology, selected the former American Creosote Works site near Pensacola, Florida as a national research demonstration area. Seventy-nine years (1902-81) of seepage from unlined discharge impoundments had released creosote, diesel fuel, and pentachlorophenol (since 1950) wastes into the ground-water system. A cluster of from 2 to 5 wells constructed at different depths at 9 sites yielded water which revealed contamination 600 feet downgradient and to a depth of 100 feet below land surface near the site. The best cross-sectional representation of the contaminant plume was obtained from samples collected and analyzed for oxidation-reduction sensitive inorganic chemical constituents. Energy dispersive x-ray fluorescence detected recently formed iron carbonate in soil samples from highly reducing ground-water zones. Approximately eighty specific organic contaminants were isolated from ground-water samples by gas-chromotography/mass spectrometry. Column studies indicate the dimethyl phenols are not sorbed or degraded by the sand-and-gravel aquifer materials. Five of nineteen individual phenolic and related compounds are biodegradable based on anaerobic digestor experiments with ACW site bacterial populations. The potential impacts in the nearby Pensacola Bay biotic community are being evaluated. (USGS)

Open-File Report↗

USGS1998

Natural attenuation of chlorinated-hydrocarbon contamination at Fort Wainwright, Alaska: A hydrogeochemical and microbiological investigation workplan

Natural attenuation processes include biological degradation, by which microorganisms break down contaminants into simpler product compounds; adsorption of contaminants to soil particles, which decreases the mass of contaminants dissolved in ground water; and dispersion, which decreases dissolved contaminant concentrations through dilution. The primary objectives of this study are to (1) assess the degree to which such natural processes are attenuating chlorinated-hydrocarbon contamination in ground water, and (2) evaluate the effects of ground-water/surface-water interactions on natural-attenuation processes in the area of the former East and West Quartermasters Fueling Systems for Fort Wainwright, Alaska. The study will include investigations of the hydrologic, geochemical, and microbiological processes occurring at this site that influence the transport and fate of chlorinated hydrocarbons in ground water. To accomplish these objectives, a data-collection program has been initiated that includes measurements of water-table elevations and the stage of the Chena River; measurements of vertical temperature profiles within the subsurface; characterization of moisture distribution and movement in the unsaturated zone; collection of ground-water samples for determination of both organic and inorganic chemical constituents; and collection of ground-water samples for enumeration of microorganisms and determination of their potential to mineralize contaminants. We will use results from the data-collection program described above to refine our conceptual model of hydrology and contaminant attenuation at this site. Measurements of water-table elevations and river stage will help us to understand the magnitude and direction of ground-water flow and how changes in the stage of the Chena River affect ground-water flow. Because ambient ground water and surface water typically have different temperature characteristics, temperature monitoring will likely provide further insight into ground-water/surface-water interactions in the subsurface. Characterization of the unsaturated zone will improve our understanding of interactions among ground water, the unsaturated zone, and the atmosphere. The interactions likely of importance to this study include the migration of water, dissolved contaminants, nutrients, and gases (oxygen, carbon dioxide, and methane) between the saturated and unsaturated zones. We will use the results of ground-water chemical analyses to determine the spatial and temporal distribution of (1) chlorinated-hydrocarbon contaminants and their degradation products, (2) oxidation-reduction indicators, (3) nutrients, and (4) major ground-water ions. These water-quality data will provide insight into ground-water flow directions, interactions between ground water and surface water, attenuation of contaminant concentrations caused by dispersion, and intrinsic microbiological processes. Microbiological analyses will indicate whether microorganisms at the site are capable of degrading the contaminants of interest, and will allow us to estimate their potential to attenuate existing contamination. Physical and chemical data interpreted as part of the analysis of ground water and surface water mixing will improve our understanding of the relationship between water quality and contaminant source mixing.

Alaska↗

USGS2007

The Yellowstone hotspot, Greater Yellowstone ecosystem, and human geography

Active geologic processes associated with the Yellowstone hotspot are fundamental in shaping the landscapes of the greater Yellowstone ecosystem (GYE), a high volcanic plateau flanked by a crescent of still higher mountainous terrain. The processes associated with the Yellowstone hotspot are volcanism, faulting, and uplift and are observed in the geology at the surface. We attribute the driving forces responsible for the northeastward progression of these processes to a thermal plume rising through the Earth’s mantle into the base of the southwest-moving North American plate. This progression began 16 million years ago (Ma) near the Nevada-Oregon border and arrived at Yellowstone about 2 Ma. Before arrival of the hotspot, an older landscape existed, particularly mountains created during the Laramide orogeny about 70–50 Ma and volcanic terrain formed by Absaroka andesitic volcanism mostly between 50–45 Ma. These landscapes were more muted than the present, hotspot-modified landscape because the Laramide-age mountains had worn down and an erosion surface of low relief had developed on the Absaroka volcanic terrain. The Yellowstone Plateau was built by hotspot volcanism of rhyolitic lavas and caldera-forming rhyolite tuffs (ignimbrites). Streams eroding back into the edges of this plateau have created scenic waterfalls and canyons such as the Grand Canyon of the Yellowstone and Lewis Canyon. Rhyolite is poor in plant nutrients and forms sandy, well-drained soils that support the monotonous, fire-adapted lodgepole pine forests of the Yellowstone Plateau. Non-rhyolitic rocks surround this plateau and sustain more varied vegetation, including spruce, fir, and whitebark pine forests broken by grassy meadows. Heat from the hotspot rises upward and drives Yellowstone’s famed geysers, hot springs, and mudpots. These thermal waters are home to specialized, primitive ecosystems, rich in algae and bacteria. The rock alteration associated with hydrothermal systems creates the bright colors of Yellowstone’s Grand Canyon. Basin-and-range-style faulting has accompanied migration of the hotspot to Yellowstone and formed the linear mountains and valleys that occur north and south of the hotspot track, which is the present-day eastern Snake River Plain. High rates of basin-and-range faulting occurred adjacent to the migrating Yellowstone hotspot, creating distinctive landscapes within the GYE such as the Teton Range/Jackson Hole, with characteristic rugged, forested ranges and adjacent flat-floored grassy valleys. The difference in altitude between the mountains and valleys provides a topographic gradient in which vegetation maturation advances with altitude; animal-migration patterns also follow this trend. The valleys provide natural meadows, agricultural land, town sites, and corridors for roads. Uplift of the GYE by as much as 1 km (3,000 ft) during the last 5 million years has resulted in ongoing erosion of deep, steep-walled valleys. Many prominent ecological characteristics of Yellowstone derive from this hotspot-induced uplift, including the moderate- to high- altitude terrain and associated cool temperatures and deep snowfall. Modern and Pleistocene climate and associated vegetation patterns strongly relate to the topography created by the hotspot and its track along the eastern Snake River Plain. Winter air masses from the moist northern Pacific Ocean traverse the topographic low of the Snake River Plain to where orographic rise onto the Yellowstone Plateau and adjacent mountains produces deep snow. A winter precipitation shadow forms on the lee (eastern) sides of the GYE. During Pleistocene glacial times, this moisture conduit provided by the hotspot-track-produced ice-age glaciers that covered the core of the present GYE. These glaciers sculpted bedrock and produced glacial moraines that are both forested and unforested, sand and gravel of ice-marginal streams and outwash gravels that are commonly covered with sagebrush-grassland, and silty lake sediments that are commonly covered by lush grassland such as Hayden Valley. The effects of the Yellowstone hotspot also profoundly shaped the human history in the GYE. Uplift associated with the hotspot elevates the GYE to form the Continental Divide, and streams drain radially outward like spokes from a hub. Inhabitants of the GYE 12,000–10,000 years ago, as well as more recent inhabitants, followed the seasonal green-up of plants and migrating animals up into the mountain areas. During European immigration, people settled around Yellowstone in the lower parts of the drainages and established roads, irrigation systems, and cultural associations. The core Yellowstone highland is too harsh for agriculture and inhospitable to people in the winter. Beyond this core, urban and rural communities exist in valleys and are separated by upland areas. The partitioning inhibits any physical connection of communities, which in turn complicates pursuit of common interests across the whole GYE. Settlements thus geographically isolated evolved as diverse, independent communities

Idaho, Montana, Utah, Wyoming↗

USGS1993

Biogeochemical and hydrological processes controlling the transport and fate of 1,2-dibromoethane (EDB) in soil and ground water, central Florida

Widespread contamination of ground water in central Florida by 1,2-dibromoethane (EDB) has resulted because of its heavy usage as a soil fumigant during a 20-year period, its relatively high aqueous solubility, and the low sorption capacity of the highly permeable sandy soils lacking organic matter. Two models were used to improve understanding of biogeochemical and hydrological processes that control the transport and fate of EDB in soil and ground water. First, a mass-balance model was developed to estimate the maximum concentration of EDB in ground water resulting from known application rates of EDB. Key processes that were quantified in the model included volatilization, diffusion of EDB vapor in soils, partitioning between aqueous and gaseous phases, sorption of EDB vapor on organic carbon and soil particles, chemical and biological degradation reactions, and nonreversible binding of EDB to soils. Model calculations using an EDB half-life of 0.65 year closely reproduced the maximum observed concentrations in ground water, 37 and 0.22 micrograms per liter, at downgradient sites in two study areas in central Florida. Maximum concentrations of EDB in ground water also were estimated in a second model that incorporated an analytical solution to the three-dimensional advection-dispersion equation for instantaneous point sources of EDB entering the flow systems in the two study areas. The model used an EDB half-life of 0.65 year (obtained from the mass-balance calculations), mean ground-water flow velocities of 0.6 to 1 meter per day, coefficients of longitudinal hydro-dynamic dispersion of 0.6 to 1.0 square meter per day, and coefficients of transverse hydrodynamic dispersion of 0.1 square meter per day. Peak concentrations of EDB in ground water calculated from the analytical model agreed closely with observed peak concentrations measured from 1983 through 1987.

Florida↗

USGS2002

Grid-cell-based crop water accounting for the famine early warning system

Rainfall monitoring is a regular activity of food security analysts for sub-Saharan Africa due to the potentially disastrous impact of drought. Crop water accounting schemes are used to track rainfall timing and amounts relative to phenological requirements, to infer water limitation impacts on yield. Unfortunately, many rain gauge reports are available only after significant delays, and the gauge locations leave large gaps in coverage. As an alternative, a grid-cell-based formulation for the water requirement satisfaction index (WRSI) was tested for maize in Southern Africa. Grids of input variables were obtained from remote sensing estimates of rainfall, meteorological models, and digital soil maps. The spatial WRSI was computed for the 1996–97 and 1997–98 growing seasons. Maize yields were estimated by regression and compared with a limited number of reports from the field for the 1996–97 season in Zimbabwe. Agreement at a useful level ( r = 0·80) was observed. This is comparable to results from traditional analysis with station data. The findings demonstrate the complementary role that remote sensing, modelling, and geospatial analysis can play in an era when field data collection in sub-Saharan Africa is suffering an unfortunate decline.

Hydrological Processes↗

USGS1996

Mobility of 2,2',5,5'-tetrachlorobiphenyl in model systems containing bottom sediments and water from the lower Fox River, Wisconsin

Sediment-water partitioning and diffusive transport of 2,2’,5,5’-tetrachlorobiphenyl, PCB congener IUPAC #52 (TCB52) were examined in laboratory experiments with sediments from two sites in the lower Fox River, Wisconsin. Native water was pumped at controlled flow rates through cells containing sediments amended with a known activity of carbon-14-labeled TCB52. Concentrations of TCB52 in water and sediments were determined by liquid scintillation measurements of carbon-14 activity. Sediment-water partitioning was independent of flow rate for rates up to 8 m/d. Distribution coefficients (K d ) and soil-sorption coefficients (K oc ) were found to be at maximum levels 5–10 cm below the surface, despite an absence of significant variation in the fraction of organic carbon (f oc ) through the same profile. Other factors, such as the effects of colloids and microbial activity in the sediments, are likely to be important in controlling the PCB distribution. Log K d and log K oc ranges were 4.1–4.9 and 5.3–6.1, respectively, and calculated effective diffusivities at the sediment-water interface ranged from 3 to 8 × 10 −10 cm 2 /s. Gradual increases with time in TCB52 concentrations in the water phase, possibly due to effects of microbial activity, were observed. Diffusion experiments and models showed that the TCB52 migration rate within the sediment column is 8-9 mm/yr.

Journal of Great Lakes Research↗

USGS2008

Grazed riparian management and stream channel response in southeastern Minnesota (USA) streams

The U.S. Department of Agriculture-Natural Resources Conservation Service has recommended domestic cattle grazing exclusion from riparian corridors for decades. This recommendation was based on a belief that domestic cattle grazing would typically destroy stream bank vegetation and in-channel habitat. Continuous grazing (CG) has caused adverse environmental damage, but along cohesive-sediment stream banks of disturbed catchments in southeastern Minnesota, short-duration grazing (SDG), a rotational grazing system, may offer a better riparian management practice than CG. Over 30 physical and biological metrics were gathered at 26 sites to evaluate differences between SDG, CG, and nongrazed sites (NG). Ordinations produced with nonmetric multidimensional scaling (NMS) indicated a gradient with a benthic macroinvertebrate index of biotic integrity (IBI) and riparian site management; low IBI scores associated with CG sites and higher IBI scores associated with NG sites. Nongrazed sites were associated with reduced soil compaction and higher bank stability, as measured by the Pfankuch stability index; whereas CG sites were associated with increased soil compaction and lower bank stability, SDG sites were intermediate. Bedrock geology influenced NMS results: sites with carbonate derived cobble were associated with more stable channels and higher IBI scores. Though current riparian grazing practices in southeastern Minnesota present pollution problems, short duration grazing could reduce sediment pollution if managed in an environmentally sustainable fashion that considers stream channel response. ?? 2008 Springer Science+Business Media, LLC.

Environmental Management↗

USGS2003

Characterization and statistical modeling of bacterial (Escherichia coli) outflows from watersheds that discharge into Southern Lake Michigan

Two watersheds in northwestern Indiana were selected for detailed monitoring of bacterially contaminated discharges (Escherichia coli) into Lake Michigan. A large watershed that drains an urbanized area with treatment plants that release raw sewage during storms discharges into Lake Michigan at the outlet of Burns Ditch. A small watershed drains part of the Great Marsh, a wetland complex that has been disrupted by ditching and limited residential development, at the outlet of Derby Ditch. Monitoring at the outlet of Burns Ditch in 1999 and 2000 indicated that E. coli concentrations vary over two orders of magnitude during storms. During one storm, sewage overflows caused concentrations to increase to more than 10,000 cfu/100 mL for several hours. Monitoring at Derby Ditch from 1997 to 2000 also indicated that E. coli concentrations increase during storms with the highest concentrations generally occurring during rising streamflow. Multiple regression analysis indicated that 60% of the variability in measured outflows of E. coli from Derby Ditch (n = 88) could be accounted for by a model that utilizes continuously measured rainfall, stream discharge, soil temperature and depth to water table in the Great Marsh. A similar analysis indicated that 90% of the variability in measured E. coli concentrations at the outlet of Burns Ditch (n = 43) during storms could be accounted for by a combination of continuously measured water-quality variables including nitrate and ammonium. These models, which utilize data that can be collected on a real-time basis, could form part of an Early Warning System for predicting beach closures.

Environmental Monitoring and Assessment↗

USGS1975

Water resources of the Root River watershed, southeastern Minnesota

This Hydrologic Atlas is one of a series describing the 39 watersheds in Minnesota. The Root River watershed includes Houston, Winona, and parts of the surrounding counties. The 2 ,570 square miles in the watershed varies from gently rolling prairie in the west to an area of plateaus separated by valleys deeply incised into bedrock in the north and east. The average annual water budget for 30 years shows 29.5 inches of precipitation, 7.2 inches of surface runoff, and 22.3 inches of evapotranspiration. Water use in millions of gallons for 1970 was established at 7,310 of ground water and 6,700 of surface water. Domestic supplies accounted for less than one fourth and thermoelectric power for about one half of the total use. All 33 municipalities use ground water from bedrock aquifers, and 21 of those obtain at least part of their supply from the Prairie du Chien-Jordan aquifer. Many private domestic wells are completed in a shallow limestone aquifer. The ground-water system is recharged primarily by infiltrating precipitation in upland areas Ground-water movement is indicated by water-table and potentiometric maps and section diagrams. Water from bedrock and glacial aquifers generally is of acceptable quality for domestic use, dissolved solids generally less than 400 mg/liter very hard , and locally high iron content. The Mount Simon-Red clastics aquifer is locally saline. Runoff is greatest during the spring when snowmelt occurs and the soils are generally saturated.

Minnesota↗

USGS2018

Comparative analyses of hydrological responses of two adjacent watersheds to climate variability and change using the SWAT model

Water quality problems in the Chesapeake Bay Watershed (CBW) are expected to be exacerbated by climate variability and change. However, climate impacts on agricultural lands and resultant nutrient loads into surface water resources are largely unknown. This study evaluated the impacts of climate variability and change on two adjacent watersheds in the Coastal Plain of the CBW, using the Soil and Water Assessment Tool (SWAT) model. We prepared six climate sensitivity scenarios to assess the individual impacts of variations in CO 2 concentration (590 and 850 ppm), precipitation increase (11 and 21 %), and temperature increase (2.9 and 5.0 °C), based on regional general circulation model (GCM) projections. Further, we considered the ensemble of five GCM projections (2085–2098) under the Representative Concentration Pathway (RCP) 8.5 scenario to evaluate simultaneous changes in CO 2 , precipitation, and temperature. Using SWAT model simulations from 2001 to 2014 as a baseline scenario, predicted hydrologic outputs (water and nitrate budgets) and crop growth were analyzed. Compared to the baseline scenario, a precipitation increase of 21 % and elevated CO 2 concentration of 850 ppm significantly increased streamflow and nitrate loads by 50 and 52 %, respectively, while a temperature increase of 5.0 °C reduced streamflow and nitrate loads by 12 and 13 %, respectively. Crop biomass increased with elevated CO 2 concentrations due to enhanced radiation- and water-use efficiency, while it decreased with precipitation and temperature increases. Over the GCM ensemble mean, annual streamflow and nitrate loads showed an increase of ∼ 70 % relative to the baseline scenario, due to elevated CO 2 concentrations and precipitation increase. Different hydrological responses to climate change were observed from the two watersheds, due to contrasting land use and soil characteristics. The watershed with a larger percent of croplands demonstrated a greater increased rate of 5.2 kg N ha −1 in nitrate yield relative to the watershed with a lower percent of croplands as a result of increased export of nitrate derived from fertilizer. The watershed dominated by poorly drained soils showed increased nitrate removal due do enhanced denitrification compared to the watershed dominated by well-drained soils. Our findings suggest that increased implementation of conservation practices would be necessary for this region to mitigate increased nitrate loads associated with predicted changes in future climate.

Greensboro Watershed, Tuckahoe Creek Watershed↗

USGS1999

Pesticides in stream sediment and aquatic biota: distribution, trends, and governing factors

More than 20 years after the ban of DDT and other organochlorine pesticides, pesticides continue to be detected in air, rain, soil, surface water, bed sediment, and aquatic and terrestrial biota throughout the world. Recent research suggests that low levels of some of these pesticides may have the potential to affect the development, reproduction, and behavior of fish and wildlife, and possibly humans. Pesticides in Stream Sediment and Aquatic Biota: Distribution, Trends, and Governing Factors assesses the occurrence and behavior of pesticides in bed sediment and aquatic biota-the two major compartments of the hydrologic system where organochlorine pesticides are most likely to accumulate. This book collects, for the first time, results from several hundred monitoring studies and field experiments, ranging in scope from individual sites to the entire nation. Comprehensive tables provide concise summaries of study locations, pesticides analyzed, and study outcomes. Comprehensive and extensively illustrated, Pesticides in Stream Sediment and Aquatic Biota: Distribution, Trends, and Governing Factors evaluates the sources, environmental fate, geographic distribution, and long-term trends of pesticides in bed sediment and aquatic biota. The book focuses on organochlorine pesticides, but also assesses the potential for currently used pesticides to be found in bed sediment and aquatic biota. Topics covered in depth include the effect of land use on pesticide occurrence, mechanisms of pesticide uptake and accumulation by aquatic biota, and the environmental significance of observed levels of pesticides in stream sediment and aquatic biota.

Book↗