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USGS2010

Seasonal ice and hydrologic controls on dissolved organic carbon and nitrogen concentrations in a boreal-rich fen

[1] Boreal wetland carbon cycling is vulnerable to climate change in part because hydrology and the extent of frozen ground have strong influences on plant and microbial functions. We examined the response of dissolved organic carbon (DOC) and total dissolved nitrogen (TDN) across an experimental manipulation of water table position (both raised and lowered water table treatments) in a boreal-rich fen in interior Alaska. DOC and TDN responses to water table manipulation exhibited an interaction with seasonal ice dynamics. We observed consistently higher DOC and TDN concentrations in the lowered water table treatment (71.7 ± 6.5 and 3.0 ± 0.3 mg−L) than in both the control (55.6 ± 5.1 and 2.3 ± 0.2 mg−L) and raised (49.1 ± 4.3 and 1.9 ± 0.1 mg L−1, respectively) water table treatments. Across all plots, pore water DOC concentrations at 20 cm increased as the depth to water table increased (R2 = 0.43, p < 0.001). DOC concentrations also increased as the seasonal thaw depth increased, with solutes increasing most rapidly in the drained plot (R2 = 0.62, p < 0.001). About half of the TDN pool was composed of dissolved organic N (DON). Inorganic N and DON were both highly correlated with changes in DOC, and their respective constraints to mineralization are discussed. These results demonstrate that a declining water table position and dryer conditions affect thaw depth and peat temperatures, and interactions among these ecosystem properties will likely increase DOC and TDN loading and potential for export in these systems.

Alaska↗

USGS2025

Effects of river floods and sedimentation on a naturally dynamic Great Lakes estuary

Some of the most biologically diverse coastal wetlands and estuaries are found along the Great Lakes, but the spatial extent and timing of river-related inundation and sedimentation vary greatly among natural and altered systems. We used hydrologic data, geomorphic change detection, and satellite imagery to study inundation and sedimentation patterns in the naturally dynamic estuary of the Bad River ( Mashkiiziibii ) that flows into Lake Superior ( Anishinaabeg-gichigami ), and the Kakagon River ( Ogaakaagaang-ziibii ) that flows into a sheltered bay ( Chi-Kaamigong ). In 2016, an extreme summer flood (annual exceedance probability < 0.2 %) caused total inundation of the 46-km 2 estuary. Floods from the sediment-rich Bad River, with an annual exceedance probability of ≤ 50 %, have overflowed into the upper wetlands and channels of the Kakagon River about 60 times over the last 75 years, including 20 floods during the most recent 10-year wet period. Sedimentation patterns were associated with proximity to river channels, shoreline erosion, and wind action. Early winter ice-up coupled with a storm surge and an early spring snowmelt into the iced-over bay changed inundation duration and sedimentation patterns. Climate-change projections for more intense rainfall and warmer temperatures will likely cause more frequent flooding and sedimentation; however, patterns may differ depending on the timing of the floods relative to storm surges and ice formation, or other factors. The approach of integrating readily available data helped give a broader temporal and spatial context to the possible causes for inundation and sedimentation, some expected and others not, in natural and restored estuaries of the Great Lakes.

Wisconsin↗

USGS2021

Dominant Sonoran Desert plant species have divergent phenological responses to climate change

The southwestern U.S. is a global hotspot of climate change. Models project that temperatures will continue to rise through the end of the 21st century, accompanied by significant changes to the hydrological cycle. Within the Sonoran Desert, a limited number of studies have documented climate change impacts on the phenology of native plant species. Much of this phenological work to understand climate change impacts to phenology builds on research conducted nearly three decades ago to define flowering triggers and developmental requirements for native keystone Sonoran Desert woody species. Here we expand on the drivers and explore recent phenological trends for six species using a unique 36-year observational data set. We use statistical models to determine which aspects of climate influence the probability of flowering, and how flowering time may respond to climate change. We move beyond traditional models of phenology by incorporating different metrics of moisture availability in addition to temperature, weather, and climate at several time scales, including daily, weekly, seasonal, and antecedent conditions. Our results provide evidence of a trend towards earlier flowering (on the order of 1–4 days per decade) for five of the six species analyzed, and no trend for one species. The species we evaluated had contrasting phenological responses to different aspects of climate, suggesting individualistic changes in phenology and the potential of divergent plant community flowering patterns under future climate change. Understanding recent changes in flowering phenology and their climatic triggers is important to anticipating whether plant species can attract pollinators, reproduce, and persist within the community under continued climate change.

Arizona↗

USGS2007

The role of headwater streams in downstream water quality

Knowledge of headwater influences on the water-quality and flow conditions of downstream waters is essential to water-resource management at all governmental levels; this includes recent court decisions on the jurisdiction of the Federal Clean Water Act (CWA) over upland areas that contribute to larger downstream water bodies. We review current watershed research and use a water-quality model to investigate headwater influences on downstream receiving waters. Our evaluations demonstrate the intrinsic connections of headwaters to landscape processes and downstream waters through their influence on the supply, transport, and fate of water and solutes in watersheds. Hydrological processes in headwater catchments control the recharge of subsurface water stores, flow paths, and residence times of water throughout landscapes. The dynamic coupling of hydrological and biogeochemical processes in upland streams further controls the chemical form, timing, and longitudinal distances of solute transport to downstream waters. We apply the spatially explicit, mass-balance watershed model SPARROW to consider transport and transformations of water and nutrients throughout stream networks in the northeastern United States. We simulate fluxes of nitrogen, a primary nutrient that is a water-quality concern for acidification of streams and lakes and eutrophication of coastal waters, and refine the model structure to include literature observations of nitrogen removal in streams and lakes. We quantify nitrogen transport from headwaters to downstream navigable waters, where headwaters are defined within the model as first-order, perennial streams that include flow and nitrogen contributions from smaller, intermittent and ephemeral streams. We find that first-order headwaters contribute approximately 70% of the mean-annual water volume and 65% of the nitrogen flux in second-order streams. Their contributions to mean water volume and nitrogen flux decline only marginally to about 55% and 40% in fourth- and higher-order rivers that include navigable waters and their tributaries. These results underscore the profound influence that headwater areas have on shaping downstream water quantity and water quality. The results have relevance to water-resource management and regulatory decisions and potentially broaden understanding of the spatial extent of Federal CWA jurisdiction in U.S. waters. ?? 2007 American Water Resources Association.

Journal of the American Water Resources Associatio↗

USGS2010

Source water controls on the character and origin of dissolved organic matter in streams of the Yukon River basin, Alaska

Climate warming and permafrost degradation at high latitudes will likely impact watershed hydrology, and consequently, alter the concentration and character of dissolved organic carbon (DOC) in northern rivers. We examined seasonal variation of DOC chemistry in 16 streams of the Yukon River basin, Alaska. Our primary objective was to evaluate the relationship between source water (shallow versus deep groundwater flow paths) and DOC chemical composition. Using base cation chemistry and principal component analysis, we observed high contributions of deep groundwater to glacial and clearwater streams, whereas blackwater streams received larger contributions from shallow groundwater sources. DOC concentration and specific ultraviolet absorbance peaked during spring snowmelt in all streams, and were consistently higher in blackwater streams than in glacial and clearwater streams. The hydrophobic acid fraction of DOC dominated across all streams and seasons, comprising between 35% and 56% of total DOC. The hydrophilic acid fraction of DOC was more prominent in glacial (23% ± 3%) and clearwater streams (19% ± 1%) than in blackwater streams (16% ± 1%), and was enriched during winter base flow (29% ± 1%) relative to snowmelt and summer base flow. We observed that an increase in the contribution of deep groundwater to streamflow resulted in decreased DOC concentration, aromaticity, and DOC-to-dissolved organic nitrogen ratio, and an increase in the proportion of hydrophilic acids relative to hydrophobic acids. Our findings suggest that future permafrost degradation and higher contributions of groundwater to streamflow may result in a higher fraction of labile DOM in streams of the Yukon basin.

Journal of Geophysical Research G: Biogeosciences↗

USGS2016

Sediment supply versus local hydraulic controls on sediment transport and storage in a river with large sediment loads

The Rio Grande in the Big Bend region of Texas, USA, and Chihuahua and Coahuila, Mexico, undergoes rapid geomorphic changes as a result of its large sediment supply and variable hydrology; thus, it is a useful natural laboratory to investigate the relative importance of flow strength and sediment supply in controlling alluvial channel change. We analyzed a suite of sediment transport and geomorphic data to determine the cumulative influence of different flood types on changing channel form. In this study, physically based analyses suggest that channel change in the Rio Grande is controlled by both changes in flow strength and sediment supply over different spatial and temporal scales. Channel narrowing is primarily caused by substantial deposition of sediment supplied to the Rio Grande during tributary-sourced flash floods. Tributary floods have large suspended-sediment concentrations, occur for short durations, and attenuate rapidly downstream in the Rio Grande, depositing much of their sediment in downstream reaches. Long-duration floods on the mainstem have the capacity to enlarge the Rio Grande, and these floods, released from upstream dams, can either erode or deposit sediment in the Rio Grande depending upon the antecedent in-channel sediment supply and the magnitude and duration of the flood. Geomorphic and sediment transport analyses show that the locations and rates of sand erosion and deposition during long-duration floods are most strongly controlled by spatial changes in flow strength, largely through changes in channel slope. However, spatial differences in the in-channel sediment supply regulate sediment evacuation or accumulation over time in long reaches (greater than a kilometer).

Big Bend National Park↗

USGS2018

Changes in long-term water quality of Baltimore streams are associated with both gray and green infrastructure

The steadily rising global urban population has placed substantial strain on urban water quality, and this strain is projected to increase for the foreseeable future. Considerable attention has been given to the hydrological and physico-chemical effects of urbanization on stream ecosystems. However, due to the relative infancy of the field of urban ecology, long-term water quality analyses in urban streams are sparse. Using a 15-year stream chemistry monitoring record from Baltimore, MD, USA, we quantified long-term trends in nitrate, phosphate, total nitrogen, total phosphorus, chloride, and sulfate export at several sites along a rural-urban gradient. We found no significant change in solute export at most sites, although we did find specific patterns of interest for certain solutes. For example, nitrogen export declined at the most headwater urban site, while phosphorus export declined at the most downstream urban site. Coupling long-term monitoring with data on gray and green infrastructure management throughout the landscape, we established relationships between solute export at the most downstream urban monitoring site and sanitary sewer overflows (SSOs), best management practice (BMP) implementation, and road salt application rates. Phosphorus export was correlated with BMP implementation in the watershed, whereas nitrogen export was related to SSOs. Despite highly urbanized watersheds, water quality does not appear to be declining at most of these sites, suggesting that current management may have limited further impairment. Results of our study suggest that both gray and green infrastructure are key for maintaining and improving water quality in this highly urbanized watershed.

Maryland↗

USGS2019

Permeability anisotropy and relative permeability in sediments from the National Gas Hydrate Program Expedition 02, offshore India

Gas and water permeability through hydrate-bearing sediments essentially governs the economic feasibility of gas production from gas hydrate deposits. Characterizing a reservoir’s permeability can be difficult because even collocated permeability measurements can vary by 4-5 orders of magnitude, due partly to differences between how various testing methods inherently measure permeability in different directions and at different scales. This study uses a customized flow anisotropy cell to investigate geomechanical and hydrological properties of hydrate-bearing sediments focusing on permeability anisotropy (i.e., horizontal, kh, to vertical, kv, permeability ratio) and relative permeability. Two cores recovered during India’s National Gas Hydrate Program Expedition 02 (NGHP-02) are tested in this study. Near in situ effective vertical stress, ~ 2MPa, the permeability anisotropy is approximately kh/kv = 1.86 for the “seal core” (from a fine-grained non-reservoir overburden sedimentary section) and kh/kv = 4.24 for the gas hydrate reservoir score with tetrahydrofuran (THF) hydrate saturation Sh = 0.8. Permeability anisotropy increases exponentially with effective vertical stress, as described by kh/kv = α(σv/MPa)^β, with α = 1.6, β = 0.22 for seal sediment and α = 3, β = 0.5 for THF hydrate-bearing sediment. Results imply the measured permeability from permeameter tests with vertical flow may underestimate the reservoir’s flow performance, which is mainly horizontal (radial) toward a vertical well. Hydrates in sediment increase the gas-entry pressure and residual water saturation, but decrease the water retention curve’s shape factor (m), resulting in a steeper curve. Distributions of available pore space sizes for flow in sediment with and without THF hydrate (Sh = 0.8) follow a log-normal distribution. Hydrate formation decreases the apparent mean pore size from ~10 µm to ~2 µm, without evidently changing the pore size distribution's standard deviation. Gas hydrate dissociation increases effective permeability and relative permeability to gas.

Journal of Marine and Petroleum Geology↗

USGS2009

Hydrologic characterization of desert soils with varying degrees of pedogenesis: 2. Inverse modeling for eff ective properties

To understand their relation to pedogenic development, soil hydraulic properties in the Mojave Desert were investi- gated for three deposit types: (i) recently deposited sediments in an active wash, (ii) a soil of early Holocene age, and (iii) a highly developed soil of late Pleistocene age. Eff ective parameter values were estimated for a simplifi ed model based on Richards' equation using a fl ow simulator (VS2D), an inverse algorithm (UCODE-2005), and matric pressure and water content data from three ponded infi ltration experiments. The inverse problem framework was designed to account for the eff ects of subsurface lateral spreading of infi ltrated water. Although none of the inverse problems converged on a unique, best-fi t parameter set, a minimum standard error of regression was reached for each deposit type. Parameter sets from the numerous inversions that reached the minimum error were used to develop probability distribu tions for each parameter and deposit type. Electrical resistance imaging obtained for two of the three infi ltration experiments was used to independently test fl ow model performance. Simulations for the active wash and Holocene soil successfully depicted the lateral and vertical fl uxes. Simulations of the more pedogenically developed Pleistocene soil did not adequately replicate the observed fl ow processes, which would require a more complex conceptual model to include smaller scale heterogeneities. The inverse-modeling results, however, indicate that with increasing age, the steep slope of the soil water retention curve shitis toward more negative matric pressures. Assigning eff ective soil hydraulic properties based on soil age provides a promising framework for future development of regional-scale models of soil moisture dynamics in arid environments for land-management applications. ?? Soil Science Society of America.

Vadose Zone Journal↗

USGS2003

Automated calibration of a stream solute transport model: Implications for interpretation of biogeochemical parameters

The hydrologic processes of advection, dispersion, and transient storage are the primary physical mechanisms affecting solute transport in streams. The estimation of parameters for a conservative solute transport model is an essential step to characterize transient storage and other physical features that cannot be directly measured, and often is a preliminary step in the study of reactive solutes. Our study used inverse modeling to estimate parameters of the transient storage model OTIS (One dimensional Transport with Inflow and Storage). Observations from a tracer injection experiment performed on Uvas Creek, California, USA, are used to illustrate the application of automated solute transport model calibration to conservative and nonconservative stream solute transport. A computer code for universal inverse modeling (UCODE) is used for the calibrations. Results of this procedure are compared with a previous study that used a trial-and-error parameter estimation approach. The results demonstrated 1) importance of the proper estimation of discharge and lateral inflow within the stream system; 2) that although the fit of the observations is not much better when transient storage is invoked, a more randomly distributed set of residuals resulted (suggesting non-systematic error), indicating that transient storage is occurring; 3) that inclusion of transient storage for a reactive solute (Sr2+) provided a better fit to the observations, highlighting the importance of robust model parameterization; and 4) that applying an automated calibration inverse modeling estimation approach resulted in a comprehensive understanding of the model results and the limitation of input data.

Journal of the North American Benthological Societ↗

USGS2018

Cumulative spring discharge and survey effort influence occupancy and detection of a threatened freshwater mussel, the Suwannee Moccasinshell

Freshwater mussels (Unionidae) are among the most imperiled groups of organisms in the world, and the lack of information regarding species distributions, life-history characteristics, and ecological and biological requirements may limit the protection of remaining mussel populations. We examined the influence of hydrologic factors on the occurrence of the Suwannee Moccasinshell Medionidus walkeri, a federally threatened freshwater mussel species, endemic to the Suwannee River Basin in Georgia and Florida. We also evaluated the influence of survey effort on detection of Suwannee Moccasinshell during field surveys. We compiled all recent (2013–2016) mussel survey records in the Suwannee River Basin. We calculated cumulative discharge contributed by upstream springs for each of 220 survey locations. We combined the spring discharge predictor variable with Suwannee Moccasinshell detection and nondetection data from each survey location to develop a suite of occupancy models. Modeling results indicated that detection of Suwannee Moccasinshell during surveys was strongly and positively related to survey effort. Modeling results also indicated that sites with cumulative spring discharge inputs exceeding ∼28 cubic meters per second were most likely (i.e., predicted occupancy probabilities >0.5) to support Suwannee Moccasinshell populations. However, occupancy declined in the lowermost reaches of the Suwannee mainstem despite high spring discharge inputs, presumably due to greater tidal influences and differences in physicochemical habitat conditions. Historical localities where Suwannee Moccasinshell has presumably been extirpated are all devoid of springs in their upstream watersheds. We hypothesize that springs may buffer extremely tannic, and at times polluted, surface waters, in addition to maintaining adequate flows during periods of drought, thereby promoting the persistence of Suwannee Moccasinshell populations. Our study suggests that springs are a critical resource for Suwannee Moccasinshell and may be more important for conservation planning than was previously recognized.

Florida↗

USGS2015

Abundance, stable isotopic composition, and export fluxes of DOC, POC, and DIC from the Lower Mississippi River during 2006–2008

Sources, abundance, isotopic compositions, and export fluxes of dissolved inorganic carbon (DIC), dissolved and colloidal organic carbon (DOC and COC), and particulate organic carbon (POC), and their response to hydrologic regimes were examined through monthly sampling from the Lower Mississippi River during 2006–2008. DIC was the most abundant carbon species, followed by POC and DOC. Concentration and δ 13 C of DIC decreased with increasing river discharge, while those of DOC remained fairly stable. COC comprised 61 ± 3% of the bulk DOC with similar δ 13 C abundances but higher percentages of hydrophobic organic acids than DOC, suggesting its aromatic and diagenetically younger status. POC showed peak concentrations during medium flooding events and at the rising limb of large flooding events. While δ 13 C-POC increased, δ 15 N of particulate nitrogen decreased with increasing discharge. Overall, the differences in δ 13 C between DOC or DIC and POC show an inverse correlation with river discharge. The higher input of soil organic matter and respired CO 2 during wet seasons was likely the main driver for the convergence of δ 13 C between DIC and DOC or POC, whereas enhanced in situ primary production and respiration during dry seasons might be responsible for their isotopic divergence. Carbon export fluxes from the Mississippi River were estimated to be 13.6 Tg C yr −1 for DIC, 1.88 Tg C yr −1 for DOC, and 2.30 Tg C yr −1 for POC during 2006–2008. The discharge-normalized DIC yield decreased during wet seasons, while those of POC and DOC increased and remained constant, respectively, implying variable responses in carbon export to the increasing discharge.

Louisiana↗

USGS2022

Flow–recruitment relationships for Shoal Chub and implications for managing environmental flows

Objective Regulation of river flow regimes by dams and diversions impacts aquatic biota and ecosystems globally. However, our understanding of the ecological consequences of flow alteration and ecological benefits of flow restoration lags behind our ability to manipulate flows, and there is a need for broader development of flow–ecology relationships. Approaches for establishing flow–ecology relationships have recently shifted away from state-based methods that analyze snapshots of ecological conditions and towards rate-based methods focused on mechanisms that link hydrology with dynamics of important ecological components and processes. Methods We used a rate-based approach to validate environmental flow standards developed for the lower Brazos River, Texas, by analyzing the relationship between flow regime components and recruitment strength of imperiled Shoal Chub Macrhybopsis hyostoma , a fluvial specialist and pelagic-broadcast-spawning fish. We collected 254 age-0 Shoal Chub (9–40 mm total length), extracted their otoliths to estimate age in days, and used a generalized additive model to regress the number of captured recruits that hatched on a calendar date against flow regime metrics, such as pulse magnitude, flow rate of change, and pulse timing in relation to environmental flow standards proposed by a science advisory committee (Brazos Basin and Bay Area Expert Science Team). Result The model revealed that flow magnitude, rate of change, and timing were all significant predictors that collectively explained 60% of variation in the recruitment strength index. Hindcasting for 1919–2020 showed a general reduction in recruitment strength following commencement of flow regulation in the lower Brazos River and revealed that high recruitment correlated with years in which most or all proposed flow tiers were attained, whereas low recruitment correlated with years when less than half of the targeted tiers were attained. Conclusion Our work represents an effective validation method for environmental flow recommendations and reveals specific flow regimes that benefit an imperiled fish species.

New Mexico, Texas↗

USGS2013

Representing the effects of alpine grassland vegetation cover on the simulation of soil thermal dynamics by ecosystem models applied to the Qinghai-Tibetan Plateau

Soil surface temperature is a critical boundary condition for the simulation of soil temperature by environmental models. It is influenced by atmospheric and soil conditions and by vegetation cover. In sophisticated land surface models, it is simulated iteratively by solving surface energy budget equations. In ecosystem, permafrost, and hydrology models, the consideration of soil surface temperature is generally simple. In this study, we developed a methodology for representing the effects of vegetation cover and atmospheric factors on the estimation of soil surface temperature for alpine grassland ecosystems on the Qinghai-Tibetan Plateau. Our approach integrated measurements from meteorological stations with simulations from a sophisticated land surface model to develop an equation set for estimating soil surface temperature. After implementing this equation set into an ecosystem model and evaluating the performance of the ecosystem model in simulating soil temperature at different depths in the soil profile, we applied the model to simulate interactions among vegetation cover, freeze-thaw cycles, and soil erosion to demonstrate potential applications made possible through the implementation of the methodology developed in this study. Results showed that (1) to properly estimate daily soil surface temperature, algorithms should use air temperature, downward solar radiation, and vegetation cover as independent variables; (2) the equation set developed in this study performed better than soil surface temperature algorithms used in other models; and (3) the ecosystem model performed well in simulating soil temperature throughout the soil profile using the equation set developed in this study. Our application of the model indicates that the representation in ecosystem models of the effects of vegetation cover on the simulation of soil thermal dynamics has the potential to substantially improve our understanding of the vulnerability of alpine grassland ecosystems to changes in climate and grazing regimes.

Qinghai;Tibet↗

USGS2012

Hydrologic effects on water level changes associated with episodic fault creep near Parkfield, California

As part of the Parkfield, California, earthquake prediction experiment, water level is monitored in a well 460 m from the main trace of the San Andreas fault on Middle Mountain, in the preparation zone of the anticipated Parkfield earthquake. The well configuration allows water level to be monitored in two fluid reservoirs at depths of 85 and 250 m below land surface. During 1987, water level changes were recorded during 12 of the 18 episodes of accelerated fault creep detected by a creep meter spanning the fault trace 750 m northwest of the well. The creep-related water level changes in the shallow reservoir have durations of less than 1 day, whereas in the deeper reservoir the changes persist for as long as 2 months. These data suggest that the transient nature of the water level changes in the shallow interval is due to vertical flow to the water table and is not evidence that creep events propagate past the well. Phase leads of earth tidal constituents in the water level data from the shallow interval relative to the same constituents in the local volume strain tide support the interpretation of significant flow to the water table at periods of 1 day or less. The form of the water level changes in the deep interval is affected by horizontal flow to the well bore. This effect can be removed from the water level records using a theoretical response curve constrained by the phases of earth tidal constituents in the deep interval relative to the local volume strain tide. For the events where the signal in the shallow interval has been large enough to measure, the sizes of the simultaneous water level changes in the two reservoirs are consistent with the same amounts of volume strain occurring at both depths.

Journal of Geophysical Research Solid Earth↗

USGS2009

Hydrologic characterization of desert soils with varying degrees of pedogenesis: 1. field experiments evaluating plant-relevant soil water behavior

To assess the eff ect of pedogenesis on the soil moisture dynamics infl uencing the character and quality of ecological habitat, we conducted infi ltration and redistribution experiments on three alluvial deposits in the Mojave National Preserve: (i) recently deposited active wash sediments, (ii) a soil of early Holocene age, and (iii) a highly developed soil of late Pleistocene age. At each, we ponded water in a 1-m-diameter infi ltration ring for 2.3 h and monitored soil water content and matric pressure during and atier infi ltration, using probes and electrical resistivity imaging (ERI). Infi ltration and downward fl ow rates were greater in younger material, favoring deep-rooted species. Deep-rooted species tend to colonize the margins of washes, where they are unaff ected by sediment transport that inhibits colonization. The ERI results support important generalizations, for example that shallower than 0.5 m, infi ltrated water persists longer in highly developed soil, favoring shallow-rooted species. Soil moisture data for the two youngest soils suggested that saturation overshoot, which may have signifi cant but unexplored hydroecologic and pedogenic eff ects, occurred at the horizontally advancing weting front. Spatial heterogeneity of soil properties generally increased with pedogenic development. Evidence suggested that some early-stage developmental processes may promote uniformity; the intermediate- age soil appeared to have the least heterogeneity in terms of textural variation with depth, and also the least anisotropy. Lateral heterogeneity was pronounced in older soil, having a multitude of eff ects on the distribution and retention of soil water, and may facilitate certain water-conserving strategies of plants over what would be possible in a laterally homogeneous soil. ?? Soil Science Society of America.

California↗

USGS2019

Residence time controls on the fate of nitrogen in flow‐through lakebed sediments

For many glacial lakes with highly permeable sediments, water exchange rates control hydrologic residence times within the sediment‐water interface (SWI) and the removal of reactive compounds such as nitrate, a common pollutant in lakes and groundwater. Here we conducted a series of focused tracer injection experiments in the upper 20 cm of the naturally downwelling SWI in a flow‐through lake on Cape Cod, MA. We systematically varied residence time and reactant controls on nitrate processing, using isotopically labeled 15 N nitrate to monitor the effect of these changes on nitrate removal via denitrification. The addition of acetate, a labile carbon compound, triggered the lake SWI to switch from net production to net removal of nitrate. When acetate was combined with increased residence time created by controlled reductions in water flux, we observed a fivefold increase in nitrate removal, a 26‐fold increase in N 2 production, and a 42‐fold increase in N 2 O production. We demonstrate that water residence time is an important control on the fate of nitrate in these lake SWIs and illustrate that seasonal conditions that alter lake exchange rates and variability in lake carbon may predict dynamic nitrate removal across the SWI. Additionally, observed N 2 O production during the oxic pore water experiments paired with geophysical characterization of the sediment porosity revealed that the lake SWI has less mobile pores occupying upward of 50% of the total porosity volume, which function as reactive microzones for nitrate processing.

Journal of Geophysical Research: Biogeosciences↗

USGS2007

Effects of multi-scale environmental characteristics on agricultural stream biota in eastern Wisconsin

The U.S. Geological Survey examined 25 agricultural streams in eastern Wisconsin to determine relations between fish, invertebrate, and algal metrics and multiple spatial scales of land cover, geologic setting, hydrologic, aquatic habitat, and water chemistry data. Spearman correlation and redundancy analyses were used to examine relations among biotic metrics and environmental characteristics. Riparian vegetation, geologic, and hydrologic conditions affected the response of biotic metrics to watershed agricultural land cover but the relations were aquatic assemblage dependent. It was difficult to separate the interrelated effects of geologic setting, watershed and buffer land cover, and base flow. Watershed and buffer land cover, geologic setting, reach riparian vegetation width, and stream size affected the fish IBI, invertebrate diversity, diatom IBI, and number of algal taxa; however, the invertebrate FBI, percentage of EPT, and the diatom pollution index were more influenced by nutrient concentrations and flow variability. Fish IBI scores seemed most sensitive to land cover in the entire stream network buffer, more so than watershed-scale land cover and segment or reach riparian vegetation width. All but one stream with more than approximately 10 percent buffer agriculture had fish IBI scores of fair or poor. In general, the invertebrate and algal metrics used in this study were not as sensitive to land cover effects as fish metrics. Some of the reach-scale characteristics, such as width/depth ratios, velocity, and bank stability, could be related to watershed influences of both land cover and geologic setting. The Wisconsin habitat index was related to watershed geologic setting, watershed and buffer land cover, riparian vegetation width, and base flow, and appeared to be a good indicator of stream quality. Results from this study emphasize the value of using more than one or two biotic metrics to assess water quality and the importance of environmental characteristics at multiple scales.

Wisconsin↗