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At least 127 records · Page 7Linked to original sources
USGS1982

Geologic, geophysical, and in situ stress investigations in the vicinity of the Dining Car Chimney, Dining Car/Hybla gold tunnels, Nevada Test Site, with sections on geologica investigations, geophysical investigations, and in situ stress investigations

The Hybla Gold experiment was conducted in the U12e.20 drifts of the E-tunnel complex beneath the surface of Rainier Mesa at the Nevada Test Site. Though the proximity of the Hybla Gold working point to the chimney of the Dining Car event was important to the experiment, the observable geologic effects from Dining Car on the Hybla Gold site were minor. Overburden above the working point is approximately 385 m (1,263 ft). The pre-Tertiary surface, probably quartzite, lies approximately 254 m (833 ft) below the working point. The drifts are mined in zeolitized ash-fall tuffs of tunnel bed 4, subunits K and J, all of Miocene age. The working point is in subunit 4J. Geologic structure in the region around the working point is not complex. The U12e.20 main drift follows the axis of a shallow depositional syncline. A northeast-dipping fault with displacement of approximately 3 m (10 ft) passes within 15.2 m (50 ft) of the Hybla Gold working point. Three faults of smaller displacement pass within 183-290 m (600-950 ft) of the working point, and are antithetic to the 3-m (10-ft) fault. Three exploratory holes were drilled to investigate the chimney of the nearby Dining Car event. Four horizontal holes were drilled during the construction of the U12e.20 drifts to investigate the geology of the Hybla Gold working point.

Open-File Report↗
USGS1982

Mineralogy of fine-grained alluvium from borehole U11g, expl. 1, northern Frenchman Flat area, Nevada Test Site

The mineralogy of matrix fines in alluvium from borehole Ullg, expl. 1, north of Frenchman Flat, Nevada Test Site, has been examined for evidence of past variations in water table elevation. Although greater abundance of zeolite and slightly more expanded basal spacings in smectite clays suggest effects of increased hydration of material up to 50 m above the present water table, these differences might also be related to provenance of environment of deposition. The relative uniformity of clay hydration properties in the 50 meters above the current water table suggest long-term stability near the present level. (USGS)

Open-File Report↗
USGS1983

Sourcebook of locations of geophysical surveys in tunnels and horizontal holes including results of seismic-refraction surveys, Rainier Mesa, Aqueduct Mesa, and Area 16, Nevada Test Site

Seismic refraction surveys have been obtained sporadically in tunnels in zeolitized tuff at the Nevada Test Site since the late 1950's. Commencing in 1967 and continuing to date (1982), extensive measurements of shear- and compressional-wave velocities have been made in five tunnel complexes in Rainier and Aqueduct Mesas and in one tunnel complex in Shoshone Mountain. The results of these surveys to 1980 are compiled in this report. In addition, extensive horizontal drilling was initiated in 1967 in connection with geologic exploration in these tunnel complexes for sites for nuclear weapons tests. Seismic and electrical surveys were conducted in the majority of these holes. The type and location of these tunnel and borehole surveys are indexed in this report. Synthesis of the seismic refraction data indicates a mean compressional-wave velocity near the nuclear device point (WP) of 23 tunnel events of 2,430 m/s (7,970 f/s) with a range of 1,846-2,753 m/s (6,060-9,030 f/s). The mean shear-wave velocity of 17 tunnel events is 1,276 m/s (4,190 f/s) with a range of 1,140-1,392 m/s (3,740-4,570 f/s). Experience indicates that these velocity variations are due chiefly to the extent of fracturing and (or) the presence of partially saturated rock in the region of the survey.

Nevada↗
USGS1993

The U. S. Geological Survey, Digital Spectral Library: Version 1 (0.2 to 3.0um)

We have developed a digital reflectance spectral library, with management and spectral analysis software. The library includes 498 spectra of 444 samples (some samples include a series of grain sizes) measured from approximately 0.2 to 3.0 um . The spectral resolution (Full Width Half Maximum) of the reflectance data is <= 4 nm in the visible (0.2-0.8 um) and <= 10 nm in the NIR (0.8-2.35 um). All spectra were corrected to absolute reflectance using an NIST Halon standard. Library management software lets users search on parameters (e.g. chemical formulae, chemical analyses, purity of samples, mineral groups, etc.) as well as spectral features. Minerals from borate, carbonate, chloride, element, halide, hydroxide, nitrate, oxide, phosphate, sulfate, sulfide, sulfosalt, and the silicate (cyclosilicate, inosilicate, nesosilicate, phyllosilicate, sorosilicate, and tectosilicate) classes are represented. X-Ray and chemical analyses are tabulated for many of the entries, and all samples have been evaluated for spectral purity. The library also contains end and intermediate members for the olivine, garnet, scapolite, montmorillonite, muscovite, jarosite, and alunite solid-solution series. We have included representative spectra of H2O ice, kerogen, ammonium-bearing minerals, rare-earth oxides, desert varnish coatings, kaolinite crystallinity series, kaolinite-smectite series, zeolite series, and an extensive evaporite series. Because of the importance of vegetation to climate-change studies we have include 17 spectra of tree leaves, bushes, and grasses. The library and software are available as a series of U.S.G.S. Open File reports. PC user software is available to convert the binary data to ascii files (a separate U.S.G.S. open file report). Additionally, a binary data files are on line at the U.S.G.S. in Denver for anonymous ftp to users on the Internet. The library search software enables a user to search on documentation parameters as well as spectral features. The analysis system includes general spectral analysis routines, plotting packages, radiative transfer software for computing intimate mixtures, routines to derive optical constants from reflectance spectra, tools to analyze spectral features, and the capability to access imaging spectrometer data cubes for spectral analysis. Users may build customized libraries (at specific wavelengths and spectral resolution) for their own instruments using the library software. We are currently extending spectral coverage to 150 um. The libraries (original and convolved) will be made available in the future on a CD-ROM.

Open-File Report↗
USGS1996

Hydrothermal alteration mineralogy of SOH drill holes, Kilauea East Rift Zone geothermal area, Hawaii

Thirty-eight hydrothermal minerals were identified from 356 drill-core specimens that were obtained from three Scientific Observation Holes (SOH-1, SOH-2, and SOH-4) drilled along the lower East Rift Zone (ERZ) of Kilauea Volcano, Hawaii. The minerals formed during alteration of basaltic rocks and glass by hot, circulating, waters in aquifers consisting of variable mixtures of meteoric water and sea water. Several zeolites, hydrated calcium silicates, carbonates, clays, silicates, sulfates, sulfides, and other minerals were found filling open spaces of vesicles, fractures, and between breccia fragments of the recovered drill core; many specimens that originally consisted of glass are completely altered to some of these minerals, especially clays. Several hydrothermal minerals (erionite, mordenite, truscottite, smectite, chlorite-smectite, chalcedony, anhydrite, and hematite), occur in the SOH drill holes at higher measured temperatures than the same minerals are found in geothermal drill holes of Iceland or other geothermal areas, suggesting that temperatures within the ERZ geothermal system have increased since the minerals formed. Fluid-inclusion freezing data for quartz, anhydrite, and calcite from the three SOH holes show that composition of the inclusion fluids ranges from dilute meteoric water to highly modified sea water concentrated by boiling. Comparison of measured drill-hole temperatures with fluid-inclusion homogenization-temperature data indicates that only about 15% of the fluid inclusions could have formed under the present thermal conditions. The majority of fluid inclusions studied apparently formed during one or more temperature fluctuations associated with the emplacement of nearby dikes and their subsequent cooling. Bacteria-like particles at 1734.6 m depth in SOH-4 could be very significant because the particles occurred at much hotter temperatures (about 265°C) than the generally accepted 110°C limit for survival of bacteria. The presence of Cl in the particles suggests that they might have lived in a saline environment and did not result from contamination by the fresh water drilling fluids. We reccomend that future drilling and subsequent handling of drill hole specimens in the ERZ and elsewhere employ controls to minimize and(or) recognize bacterial contamination.

Open-File Report↗
USGS1999

Magnetotelluric study of the Pahute Mesa and Oasis Valley regions, Nye County, Nevada

Magnetotelluric data delineate distinct layers and lateral variations above the pre-Tertiary basement. On Pahute Mesa, three resistivity layers associated with the volcanic rocks are defined: a moderately resistive surface layer, an underlying conductive layer, and a deep resistive layer. Considerable geologic information can be derived from the conductive layer which extents from near the water table down to a depth of approximately 2 km. The increase in conductivity is probably related to zeolite zonation observed in the volcanic rock on Pahute Mesa, which is relatively impermeable to groundwater flow unless fractured. Inferred faults within this conductive layer are modeled on several profiles crossing the Thirsty Canyon fault zone. This fault zone extends from Pahute Mesa into Oasis Valley basin. Near Colson Pond where the basement is shallow, the Thirsty Canyon fault zone is several (~2.5) kilometers wide. Due to the indicated vertical offsets associated with the Thirsty Canyon fault zone, the fault zone may act as a barrier to transverse (E-W) groundwater flow by juxtaposing rocks of different permeabilities. We propose that the Thirsty Canyon fault zone diverts water southward from Pahute Mesa to Oasis Valley. The electrically conductive nature of this fault zone indicates the presence of abundant alteration minerals or a dense network of open and interconnected fractures filled with electrically conductive groundwater. The formation of alteration minerals require the presence of water suggesting that an extensive interconnected fracture system exists or existed at one time. Thus, the fractures within the fault zone may be either a barrier or a conduit for groundwater flow, depending on the degree of alteration and the volume of open pore space. In Oasis Valley basin, a conductive surface layer, composed of alluvium and possibly altered volcanic rocks, extends to a depth of 300 to 500 m. The underlying volcanic layer, composed mostly of tuffs, fills the basin with about 3-3.5 km of relief on basement. A fault zone, related to the southern margin of the basin, appears to extend up to a depth of about 500 m. The path of groundwater encountering this fault zone is uncertain but may be either to the southwest towards Beatty or to the south towards Crater Flat.

Nevada↗
USGS1979

Clay mineralogy of Pleistocene Lake Tecopa, Inyo County, California

Pleistocene Lake Tecopa in southeastern Inyo County, Calif., was formed when the Amargosa River was blocked at the southern end of its valley. The lake acted as a settling basin for detrital material being transported by the river. This detritus consisted of clays, quartz, feldspars, and micas which became mudstones and siltstones. These mudstones and siltstones, much eroded and dissected after the draining of the lake, extend over the entire basin and are interbedded with tuffs formed by the intermittent deposition of volcanic ashfalls in the former lake waters. These lightcolored mudstones and siltstones are tough and well indurated and break with a conchoidal fracture. The predominant clay mineral in these detrital beds is a lithiumbearing saponite, which is found not only in the lake beds but also in the area beyond the boundaries of the lake, especially in fluvial deposits in the drainage basin of the Amargosa River to the north. This saponite does not contain enough lithium to be classified as a hectorite, and we have observed no indications that this clay consists of a mixture of two phases, such as hectorite and a diluent. Some authigenic dioctahedral montmorillonite, found only in small quantities close to the tuffs, was formed by alteration of the volcanic glass of the tuffs and was then admixed with the overlying or underlying detrital clays. The only authigenic clay-type mineral found in any significant quantity is sepiolite, found near the edges of the lake basin and stratigraphically located mainly within a meter of the two uppermost tuffs. This sepiolite probably was precipitated when silica became available to the magnesium-bearing lake water through dissolution of the volcanic ash. Precipitation of sepiolite probably did not occur within the tuffs owing to the presence of alumina in solution. Zeolites were produced there and sepiolite formed outside the margins of the tuffs. Also formed by the high-pH lake waters were water-soluble minerals, which were found widely dispersed in crusts or streaks on the clays. Much of the calcite was likely precipitated from the lake waters, especially near the north end of the lake where calciumbearing fresh water came into contact with the C02-rich lake waters. Magadiite, a sodium silicate mineral reported only twice previously in the United States, was found in small quantities in the southern end of the basin. This mineral is indicative of a minimum pH of 8.5. The authigenic minerals formed in the lake reflect the presence of silica-rich tuffs and the high-pH, alkaline character of the lake waters.

Professional Paper↗
USGS1980

Composition and properties of the Pierre Shale and equivalent rocks, northern Great Plains region

The Pierre Shale and equivalent rocks of Late Cretaceous age consist in the east-central Dakotas of several hundred feet of offshore-marine shale and minor marl; in west-central Montana near the sediment source the equivalents of the Pierre Shale consist of several thousand feet of volcanic-rich and mostly nonmarine sediments; and in the area between, both types of rock are separated by tongues of nearshore-marine siltstone and sandstone that mark three major transgressions of the sea across the area. The major-, minor-, and trace-element composition was determined for 226 samples of these rocks, and the mineralogical composition was determined for 1,350 samples. Slurry pH, Atterberg limits, and grain and bulk densities were determined on some samples. The arithmetic mean, in percent, and standard deviation (in parentheses) of major and minor elements, mostly in shale and siltstone and excluding the 23 chemically analyzed bentonite samples, are as follows: SiO2 60.8 (7.9) Al2O3 14.4 (2.5) Fe2O3 3.4 (1.4) FeO 1.1 (1.2) MgO 2.2 (1.0) CaO 2.7 (0.48) Na2O 1.1 (0.56) K2O 2.4 (0.57) H2O- 3.2 (1.3) H2O+ 4.3 (1.2) TiO2 0.58 (0.12) P2O5 0.14 (0.073) S 0.37 (1.1) F 0.71 (0.15) Cl 0.16 (0.024) CO2 2.1 (7.0) C, organic 0.94 (1.8) The mean and standard deviation of minerals as determined by X-ray methods, excluding bentonite samples, is as follows: clay minerals, 53 (20); quartz, 24 (13); cristobalite, 1 (5); potassium-feldspar, 1 (2); plagioclase, 6 (7); anorthite content from 20 to 40 percent; calcite, 5 (14); dolomite, 4 (7); organic matter, 1 (2); and sparsely scattered gypsum, jarosite, pyrite, zeolites, augite, siderite, and probably minor amounts of hydrated iron-manganese (Fe-Mn) oxides. The mean and standard deviation of the clay-mineral fraction is as follows: mixed-layer illite-smectite, 70 (20); illite, 16 (9); chlorite, 3 (6); and kaolinite, 9 (13). The mixed-layer clay, except in the Montana disturbed belt, is a random interlayering of 20 to 60 percent illite-type layers, about 35 percent beidelite-type layers, and the remainder montmorillonite-type layers; chlorite or vermiculite layers are rare. Most bentonite differs from shale in its small quartz content, rarely more than a few percent, in the more calcic composition and hightemperature thermal state of its plagioclase, and in its rare kaolinite, near absence of chlorite, and lack of illite-either free or mixed layered with smectite. Bentonite commonly consists of more than 90 percent smectite in which montmorillonite is interlayered with a smaller amount of beidellite. The clay-mineral composition of marine rock, including proportions of layers in the dominant illite-smectite, averages about the same as in the nonmarine rock, though in the latter the composition is more variable. The average content of major chemical constituents also is closely similar, partly because the large clay content of fine-grained offshore-marine shale is balanced by the small clay content of nearshore-marine siltstone and sandstone. In addition, the alumina and alkalic elements in an average of 10 percent more clay in marine rock are partly balanced by these constituents in the 5 percent more feldspar in nonmarine rock. Much of the observed regional and stratigraphic variation in maj or constituents is the result of the three major east-west migrations of the depositional sites of nearshore-marine sandstone and siltstone. Dolomite is found almost exclusively in relatively coarse-grained rock, particularly in nearshore-marine siltstone where diagenetic dolomite is expected, but it is found almost as frequently in nonmarine siltstone. Amounts of minor constituents are nearly equal in marine and nonmarine rocks, except that pyrite and consequently sulfur are relatively sparse in nonmarine rock. Average amounts of organic matter found in marine and nonmarine rocks are nearly identical. However, organic matter in nonmarine rock occurs almost entirely in volumetric

North Dakota, South Dakota, Montana↗
USGS1984

Igneous activity and related ore deposits in the western and southern Tushar Mountains, Marysvale volcanic field, west-central Utah

PART A: Igneous activity in the Marysvale volcanic field of western Utah can be separated into many episodes of extrusion, intrusion, and hydrothermal activity. The rocks of the western Tushar Mountains, near the western part of the volcanic field, include intermediate-composition, calc-alkalic volcanic rocks erupted from scattered volcanoes in Oligocene through earliest Miocene time and related monzonitic intrusions emplaced 24-23 m.y. ago. Beginning 22-21 m.y. ago and extending through much of the later Cenozoic, a bimodal basalt-rhyolite assemblage was erupted widely throughout the volcanic field. Only volcanic and intrusive rocks belonging to the rhyolitic end member of this bimodal assemblage are present in the western Tushar Mountains; most of these rocks either fill the Mount Belknap caldera (19 m.y. old) or are part of the rhyolite of Gillies Hill (9---8 m.y. old). Episodic hydrothermal activity altered and mineralized rocks at many places in the western Tushar Mountains during Miocene time. The earliest activity took place in and adjacent to monzonitic calcalkalic intrusions emplaced in the vicinity of Indian Creek and Cork Ridge. These rocks were widely propylitized, and gold-bearing quartz-pyrite-carbonate veins formed in local fractures. Hydrothermal activity associated with the Mount Belknap caldera mobilized and redeposited uranium contained in the caldera-fill rocks and formed primary concentrations of lithophile elements (including molybdenum and uranium) in the vicinity of intrusive bodies. Hydrothermal activity associated with the rhyolite of Gillies Hill altered and mineralized rocks at several places along the fault zone that marks the western margin of the Tushar Mountains; the zoned alunite and gold deposits at Sheep Rock, the gold deposit at the Sunday Mine, and an alunite deposit near Indian Creek were thus produced. Resetting of isotopic ages suggests that another center of hydrothermally altered rocks associated with a buried pluton about 16 m.y. old may exist near Indian Creek just west of the Mount Belknap caldera. Geophysical evidence confirms the probability of a buried pluton near Indian Creek, and also indicates that another buried pluton probably exists beneath the 9-m.y.-old mineralized area at Sheep Rock. The mineral potential of the different hydrothermal systems, and the types of minerals deposited probably vary considerably from one period of mineralization to another and from one depth environment to another within a given system. PART B: The Big John caldera, on the western flank of the Tushar Mountains in the Marysvale volcanic field in west-central Utah, formed 23-22 m.y. ago in response to ash-flow eruptions of the Delano Peak Tuff Member of the Bullion Canyon Volcanics. These eruptions were near the end of the period of Oligocene-early Miocene calc-alkalic igneous activity that built a broad volcanic plateau in this part of Utah. About 22 m.y. ago, the composition of rocks erupted changed to a bimodal assemblage of mafic and silicic volcanics that was erupted episodically through the remainder of Cenozoic time. The alkali rhyolites are uranium rich in part, and are associated with all the known uranium deposits in the Marysvale volcanic field. The Big John caldera was a broad drained basin whose floor was covered by a layer of stream gravels when ash flows from the western source area of the Mount Belknap Volcanics filled the caldera with the Joe Lott Tuff Member about 19 m.y. ago. Devitrified and zeolitized rocks in the caldera fill have lost one-quarter to one-half of the uranium contained in the original magma. This mobilized uranium probably moved into the hydrologic regime, and some may have been redeposited in stream gravels underlying the Joe Lott within the caldera, or in gravels filling the original drainage channel that extended south from the caldera.

Utah↗
USGS1989

Studies of geology and hydrology in the Basin and Range Province, Southwestern United States, for isolation of high-level radioactive waste - Basis of characterization and evaluation

The geologic and hydrologic factors in selected regions of the Basin and Range province were examined to identify prospective areas for further study that may provide isolation of high-level radioactive waste from the accessible environment. The six regions selected for study were characterized with respect to the following guidelines: (1) Potential repository media; (2) Quaternary tectonic conditions; (3) climatic change and geomorphic processes; (4) ground-water conditions; (5) ground-water quality; and (6) mineral and energy resources. The repository medium will function as the first natural barrier to radionuclide travel by virtue of associated slow ground-water velocity. The principal rock types considered as host media include granitic, intermediate, and mafic intrusive rocks; argillaceous rocks; salt and anhydrite; volcanic mudflow (laharic) breccias; some intrusive rhyolitic plugs and stocks; partially zeolitized tuff; and metamorphic rocks. In the unsaturated zone, the permeability and hydrologic properties of the rocks and the hydrologic setting are more important than the rock type. Media ideally should be permeable to provide drainage and should have a minimal water flux The ground-water flow path from a repository to the accessible environment needs to present major barriers to the transport of radionuclides. Factors considered in evaluating the ground-water conditions include ground-water traveltimes and quality, confining beds, and earth materials favorable for retardation of radionuclides. Ground-water velocities in the regions were calculated from estimated hydraulic properties of the rocks and gradients. Because site-specific data on hydraulic properties are not available, data from the literature were assembled and synthesized to obtain values for use in estimating ground-water velocities. Hydraulic conductivities for many rock types having granular and fracture permeability follow a log-normal distribution. Porosity for granular and very weathered crystalline rock tends to be normally distributed; porosity of fractured crystalline rock probably follows a log-normal distribution. The tectonic setting needs to prevent an increase in radionuclides to the accessible environment. Data on historic seismicity and heat flow, Quaternary faults, volcanism, and uplift were used to assess the tectonic conditions. Long-term late Cenozoic rates of vertical crustal movement in the Basin and Range province range from less than 2 meters per 104 years to greater than 20 meters per 104 years. Shortterm rates of vertical movement may be more than an order of magnitude greater, based on geodetic leveling. Changes in tectonic and climatic processes may potentially cause changes in hydrologic conditions and geomorphology that could affect the integrity of a deep, mined repository either adversely or beneficially. The transition from a full-glacial climate to the current interglacial condition has occurred within the past 15,000 years. Reconstructions of the last full-glacial climate indicate that, at that time, there was greater water availability for runoff and vegetation growth than there is now. Based on the increased water availability and depending on seasonal distribution of precipitation, on soil characteristics, on topography, and on other characteristics, ground-water recharge during the full-glacial climate is estimated to have been possibly 2 to 10 or more times the modern rate. During the full-glacial climate, more than 100 lakes occupied closed basins in the province. Any increase in ground-water recharge and refilling of Pleistocene lakes will tend to decrease the distance of ground-water flow and its time of travel. The unsaturated zone this zone is considered a potential host medium where the thickness is greater than 150 m will be decreased by these changes. In contrast, incision of streams and other geomorphic, tectonic, or climatically induced changes that lower the ground-water discharge level will tend to increase the thickness of the unsaturated zone. Aggradation in basinal troughs may either decrease or increase the thickness of the unsaturated zone. Aggradation in basins that causes the ground-water discharge level to rise will tend to decrease the thickness of unsaturated zone in the adjacent uplands; aggradation in basins where the ground-water discharge level remains the same or is lowered will increase the unsaturated thickness of basin fill. Records show that, throughout late Cenozoic time in the Basin and Range province, continued vertical crustal movements have tended to maintain mountain ranges and closed basins, whereas aggradation of the basins and erosion of the mountain ranges have tended to decrease the topographic relief. Maximum rates of denudation for small basins in areas climatically similar to the Basin and Range province are about 2 meters per 104 years. For sites unaffected by stream incision and scarp retreat, a conservative estimate of erosion affecting long-term changes in depth of burial would appear to be 2 meters per 104 years, or, equal to the long-term rate of vertical crustal movement where greater than 2 meters per 104 years. The response of the ground-water conditions to climatic and geomorphically induced boundary conditions is significant from the points of: (1) The potential maximum change in the ground-water flow system; (2) the time of response of the ground-water system; and (3) the present state of the ground-water system as a result of past changes. Effects of longterm climatic and tectonic changes on hydrologic and geomorphic conditions differ from area to area, and rates of change of geomorphic and hydrologic conditions may vary significantly. Therefore, sitespecific studies need to be made to assess the long-term integrity of deep, mined repositories.

Arizona, California, Idaho, Nevada, New Mexico, Te↗
USGS1930

Shorter contributions to general geology, 1929

Thin beds that consist almost wholly of euhedral analcite crystals occur at five or more horizons in the upper half of the Green River formation of Utah and Colorado, a series of Eocene lake beds that contain large deposits of oil shale. Most of these beds contain also minute crystals of apophyllite. The analcite crystals in some beds are cemented only by chalcedony, but in other beds that have less analcite the matrix is tuffaceous and consists of chalcedony in which are embedded splinters of feldspar, hornblende, and quartz, laths of biotite, and euhedral crystals of sanidine, apatite, and zircon. Analcite occurs plentifully also, disseminated in many of the oil-shale beds, and locally makes up as much as 16 per cent of weight of the rock. In these beds the analcite is accompanied by apophyllite, euhedral crystals of sanidine and orthoclase, angular fragments of quartz, and a little volcanic glass. The rocks associated with the beds of analcite and analcite-bearing oil shale contain salt-crystal cavities, that strongly suggest the former presence of glauberite and anhydrite. Both clastic and hydrothermal hypotheses for the origin of the zeolites are considered and dismissed in the paper. The field and microscopic evidence presented leads to the conclusion that all the analcite and apophyllite formed in place on the lake bottom as a result of interactions between salts dissolved in the lake water and the dissolution products of volcanic ash that fell into the lake. Meerschaum, or fibrous sepiolite, occurs in several thin beds near the top of the Green River formation in Duchesne County, Utah. It is mixed with structureless organic matter like that in the oil shale and apparently formed in place on the lake bottom. Chemical analyses of the analcite rock and of the sepiolite are given.

Professional Paper↗
USGS2017

Lithium

Lithium, the lightest of all metals, is used in air treatment, batteries, ceramics, glass, metallurgy, pharmaceuticals, and polymers. Rechargeable lithium-ion batteries are particularly important in efforts to reduce global warming because they make it possible to power cars and trucks from renewable sources of energy (for example, hydroelectric, solar, or wind) instead of by burning fossil fuels. Today, lithium is extracted from brines that are pumped from beneath arid sedimentary basins and extracted from granitic pegmatite ores. The leading producer of lithium from brine is Chile, and the leading producer of lithium from pegmatites is Australia. Other potential sources of lithium include clays, geothermal brines, oilfield brines, and zeolites. Worldwide resources of lithium are estimated to be more than 39 million metric tons, which is enough to meet projected demand to the year 2100. The United States is not a major producer at present but has significant lithium resources.

Professional Paper↗
USGS1993

Preliminary hydrogeologic assessment of boreholes UE-25c #1, UE-25c #2, and UE-25c #3, Yucca Mountain, Nye County, Nevada

Boreholes UE-25c #1, UE-25c #2, and UE-25c #3 (collectively called the C-holes) each were drilled to a depth of 914.4 meters at Yucca Mountain, on the Nevada Test Site, in 1983 and 1984 for the purpose of conducting aquifer and tracer tests. Each of the boreholes penetrated the Paintbrush Tuff and the tuffs and lavas of Calico Hills and bottomed in the Crater Flat Tuff. The geologic units penetrated consist of devitrified to vitrophyric, nonwelded to densely welded, ash-flow tuff, tuff breccia, ash-fall tuff, and bedded tuff. Below the water table, which is at an average depth of 401.6 meters below land surface, the rocks are argillic and zeolitic. The geologic units at the C-hole complex strike N. 2° W. and dip 15° to 21° NE. They are cut by several faults, including the Paintbrush Canyon Fault, a prominent normal fault oriented S. 9° W., 52.2° NW. The rocks at the C-hole complex are fractured extensively, with most fractures oriented approximately perpendicular to the direction of regional least horizontal principal stress. In the Crater Flat Tuff and the tuffs and lavas of Calico Hills, fractures strike predominantly between S. 20° E. and S. 20° W. and secondarily between S. 20° E. and S. 60° E. In the Topopah Spring Member of the Paintbrush Tuff, however, southeasterly striking fractures predominate. Most fractures are steeply dipping, although shallowly dipping fractures occur in nonwelded and reworked tuff intervals of the Crater Flat Tuff. Mineral-filled fractures are common in the tuff breccia zone of the Tram Member of the Crater Flat Tuff, and, also, in the welded tuff zone of the Bullfrog Member of the Crater Flat Tuff. The fracture density of geologic units in the C-holes was estimated to range from 1.3 to 7.6 fractures per cubic meter. Most of these estimates appear to be the correct order of magnitude when compared to transect measurements and core data from other boreholes 1.3 orders of magnitude too low. Geophysical data and laboratory analyses were used to determine matrix hydrologic properties of the tuffs and lavas of Calico Hills and the Crater Flat Tuff in the C-holes. The porosity ranged from 12 to 43 percent and, on the average, was larger in nonwelded to partially welded, ash-flow tuff, ashfall tuff, and reworked tuff than in moderately to densely welded ash-flow tuff. The pore-scale horizontal permeability of nine samples ranged from 5.7x10 -3 to 2.9 millidarcies, and the pore-scale vertical permeability of these samples ranged from 3.7x10 -3 to 1.5 millidarcies. Ratios of pore-scale horizontal to vertical permeability generally ranged from 0.7 to 2. Although the number of samples was small, values of pore-scale permeability determined were consistent with samples from other boreholes at Yucca Mountain. The specific storage of nonwelded to partially welded ash-flow tuff, ash-fall tuff, and reworked tuff was estimated from porosity and elasticity to be 2x10 -6 per meter, twice the specific storage of moderately to densely welded ash-flow tuff and tuff breccia. The storativity of geologic units, based on their average thickness (corrected for bedding dip) and specific storage, was estimated to range from 1x10 -5 to 2x10 -4 .

Nevada↗
USGS2009

Making fired bricks with spent equilibrium catalyst-a technical feasibility study

Fluid catalytic cracking in an oil refinery uses a catalyst, such as an alumino-silicate zeolite, in the conversion of heavy hydrocarbons to light hydrocarbons. A small fraction of the catalyst is continually replaced with fresh catalyst to maintain activity. In North America, more than 400 tons of spent alumino-silicate equilibrium catalyst (spent e-cat), and worldwide, more than 1,100 tons, are generated daily, most of which is disposed of in landfills (municipal and on-site facilities). In this study, three spent e-cat samples were tested in a value-added application that would utilize this waste in the manufacturing of fired bricks. The results of this study indicate that spent e-cat is a technically feasible raw material substitute for the clay and shale commonly used in fired brick production. Fired bricks produced with up to 30 wt% of spent e-cat showed good physical appearance and their water absorption properties met the ASTM C 62 specifications for building bricks of either the moderate- or severe-weathering grade.

Journal of Solid Waste Technology and Management↗
USGS2001

Standard Reference Material (SRM 1990) for Single Crystal Diffractometer Alignment

An international project was successfully completed which involved two major undertakings: (1) a round-robin to demonstrate the viability of the selected standard and (2) the certification of the lattice parameters of the SRM 1990, a Standard Reference Material?? for single crystal diffractometer alignment. This SRM is a set of ???3500 units of Cr-doped Al2O3, or ruby spheres [(0 420.011 mole fraction % Cr (expanded uncertainty)]. The round-robin consisted of determination of lattice parameters of a pair of crystals' the ruby sphere as a standard, and a zeolite reference to serve as an unknown. Fifty pairs of crystals were dispatched from Hauptman-Woodward Medical Research Institute to volunteers in x-ray laboratories world-wide. A total of 45 sets of data was received from 32 laboratories. The mean unit cell parameters of the ruby spheres was found to be a=4.7608 A?? ?? 0.0062 A??, and c=12.9979 A?? ?? 0.020 A?? (95 % intervals of the laboratory means). The source of errors of outlier data was identified. The SRM project involved the certification of lattice parameters using four well-aligned single crystal diffractometers at (Bell Laboratories) Lucent Technologies and at NRC of Canada (39 ruby spheres), the quantification of the Cr content using a combined microprobe and SEM/EDS technique, and the evaluation of the mosaicity of the ruby spheres using a double-crystal spectrometry method. A confirmation of the lattice parameters was also conducted using a Guinier-Ha??gg camera. Systematic corrections of thermal expansion and refraction corrections were applied. These rubies_ are rhombohedral, with space group R3c. The certified mean unit cell parameters are a=4.76080 ?? 0.00029 A??, and c=12 99568 A?? ?? 0.00087 A?? (expanded uncertainty). These certified lattice parameters fall well within the results of those obtained from the international round-robin study. The Guinier-Ha??gg transmission measurements on five samples of powdered rubies (a=4.7610 A?? ?? 0.0013 A??, and c=12.9954 A?? ?? 0.0034 A??) agreed well with the values obtained from the single crystal spheres.

Journal of Research of the National Institute of S↗
USGS1984

Hydrothermal minerology of research drill hole Y-3, Yellowstone National Park, Wyoming

The approximate paragenetic sequence of hydrothermal minerals in the Y-3 U. S. Geological Survey research diamond-drill hole in Lower Geyser Basin, Yellowstone National Park, Wyoming, is: hydrothermal chalcedony, hematite, pyrite, quartz, clay minerals (smectite and mixed-layer illite-smectite), calcite, chlorite, fluorite, pyrite, quartz, zeolite minerals (analcime, dachiardite, laumontite, stilbite, and yugawaralite), and clay minerals (smectite and mixed-layer illite-smectite). A few hydrothermal minerals that were identified in drill core Y-3 (lepidolite, aegirine, pectolite, and truscottite) are rarely found in modern geothermal areas. The alteration minerals occur primarily as vug and fracture fillings that were deposited from cooling thermal water. Refs.

Wyoming↗
USGS1991

Chemical, isotopic, and dissolved gas compositions of the hydrothermal system in Twin Falls and Jerome counties, Idaho

The chemical, isotopic, and gas compositions of the hydrothermal system in Twin Falls and Jerome counties, Idaho, change systematically as the water moves northward from the Idaho-Nevada boundary toward the Snake River. Sodium, chloride, fluoride, alkalinity, dissolved helium, and carbon-13 increase as calcium and carbon-14 decrease. Water-rock reactions may result in dissolution of plagioclase or volcanic glass and calcite, followed by precipitation of zeolites and clays. On the basis of carbon-14 age dating, apparent water ages range from 2,000 to more than 26,000 years; most apparent ages range from about 4,000 to 10,000 years. The older waters, north of the Snake River, are isotopically depleted in deuterium and are enriched in chloride relative to waters to the south. Thermal waters flowing northward beneath the Snake River may join a westward flow of older thermal water slightly north of the river. The direction of flow in the hydrothermal system seems to parallel the surface drainage.

Geothermal Resources Council Transactions↗
USGS1991

Distribution of rubidium, strontium, and zirconium in tuff from two deep coreholes at Yucca Mountain, Nevada

Variations in concentrations of trace elements Rb, Sr, and Zr within the sequence of high-silica tuff and dacitic lava beneath Yucca Mountain reflect both primary composition and secondary alteration. Rb and K concentrations have parallel trends. Rb concentrations are significantly lower within intervals containing zeolitic nonwelded to partially welded and bedded tuffs and are higher in thick moderately to densely welded zones. Sr concentrations increase with depth from about 30 ppm in the Topopah Spring Member of the Paintbrush Tuff to almost 300 ppm in the older tuffs. Zr concentrations are about 100 ppm in the Topopah Spring Member and also increase with depth to about 150 ppm in the Lithic Ridge Tuff and upper part of the older tuffs. Conspicuous local high concentrations of Sr in the lower part of the Tram Member, in the dacite lava, and in unit c of the older tuffs in USW G-1, and in the densely welded zone of the Bullfrog Member in USW GU-3/G-3 closely correlate with high concentrations of less-mobile Zr and may reflect either primary composition or elemental redistribution resulting largely from smectitic alteration. Initial 87Sr/86Sr values from composite samples increase upward in units above the Bullfrog Member of the Crater Flat Tuff. The progressive tenfold increase in Sr with depth coupled with the similarity of initial 87Sr/86Sr values within the Bullfrog Member and older units to those of Paleozoic marine carbonates are consistent with a massive influx of Sr from water derived from a Paleozoic carbonate aquifer.

Conference Paper↗