Search USGS⌕ Search

SEARCH · Search USGS

Results for “Spectroscopy”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 127 records · Page 7Linked to original sources
USGS1969

The determination of nanogram amounts of Chromium in urine by x-ray fluorescence spectroscopy

Nanogram amounts of chromium can be extracted as oxinate into chloform. By treatment of the chloroform layer 3 M hydrochloric acid, oxinates of other elements and excess of reagent are removed, leaving a chloroform solution of the chromium chelate only. This solution is concentrated and transferred to the top of a small brass rod acting as sample holder. The intensity of the X-ray fluorescence of the Cr Kα line is measured with curved crystal optics. Chromium amounts greater than 5 ng can be detected. The application of the procedure to the analysis of the chromium content of urine is demonstrated.

Analytica Chimica Acta↗
USGS1982

An improved method for the determination of trace levels of arsenic and antimony in geological materials by automated hydride generation–Atomic absorption spectroscopy

An improved, automated method for the determination of arsenic and antimony in geological materials is described. After digestion of the material in sulfuric, nitric, hydrofluoric and perchloric acids, a hydrochloric acid solution of the sample is automatically mixed with reducing agents, acidified with additional hydrochloric acid, and treated with a sodium tetrahydroborate solution to form arsine and stibine. The hydrides are decomposed in a heated quartz tube in the optical path of an atomic absorption spectrometer. The absorbance peak height for arsenic or antimony is measured. Interferences that exist are minimized to the point where most geological materials including coals, soils, coal ashes, rocks and sediments can be analyzed directly without use of standard additions. The relative standard deviation of the digestion and the instrumental procedure is less than 2% at the 50 μg l -1 As or Sb level. The reagent-blank detection limit is 0.2 μg l -1 As or Sb.

Analytica Chimica Acta↗
USGS2018

Investigation into the effect of heteroatom content on kerogen structure using advanced 13C solid-state nuclear magnetic resonance spectroscopy

To elucidate how different extreme heteroatom concentrations in oil shale kerogen may present and contribute to various structural features, three shale samples, containing kerogen with high oxygen content, low heteroatom content, and high sulfur content, were analyzed using advanced 13 C solid-state nuclear magnetic resonance (NMR) techniques, including multiple cross-polarization/magic angle spinning (multiCP/MAS), dipolar dephasing (multiCP/DD), and 2D 1 H– 13 C heteronuclear correlation (2D HETCOR). We found that oxygen in Estonian kukersite was present mostly in aromatic C–O structures and that nonprotonated aromatic carbons bonded to oxygen and alkyl chains led to more diverse aromatic signal distributions and structures in the kukersite organic matter than were observed in the other shales. The low-heteroatom kerogen present in Australian Glen Davis torbanite had the simplest structural pattern and the lowest aromaticity, despite having a lower atomic H/C ratio than the kerogens present in the other shales. The organic sulfur-rich Ghareb marinite from Jordan contained the highest aromaticity and most diverse alkyl structures among the three shales. 2D HETCOR with 1 H spin diffusion showed that the structural heterogeneity of the Glen Davis kerogen was <1 nm, indicating the preservation of structures present in precursor organic matter. Like previous NMR studies of shales and kerogens, this analysis of organic matter in whole shale samples with unusual heteroatom content demonstrates that structural characteristics in organic matter are not necessarily captured by kerogen typing based solely on elemental ratios (H/C, O/C) or programmed pyrolysis parameters and that NMR provides deeper insights into kerogen structure.

Energy & Fuels↗
USGS2018

Examining natural attenuation and acute toxicity of petroleum-derived dissolved organic matter with optical spectroscopy

Groundwater samples containing petroleum-derived dissolved organic matter (DOM HC ) originating from the north oil body within the National Crude Oil Spill Fate and Natural Attenuation Research Site near Bemidji, MN, USA were analyzed by optical spectroscopic techniques (i.e., absorbance and fluorescence) to assess relationships that can be used to examine natural attenuation and toxicity of DOM HC in contaminated groundwater. A strong correlation between the concentration of dissolved organic carbon (DOC) and absorbance at 254 nm ( a 254 ) along a transect of the DOM HC plume indicates that a 254 can be used to quantitatively assess natural attenuation of DOM HC . Fluorescence components, identified by parallel factor (PARAFAC) analysis, show that the composition of the DOM HC beneath and adjacent to the oil body is dominated by aliphatic, low O/C compounds (“protein-like” fluorescence) and that the composition gradually evolves to aromatic, high O/C compounds (“humic-/fulvic-like” fluorescence) as a function of distance downgradient from the oil body. Finally, a direct, positive correlation between optical properties and Microtox acute toxicity assays demonstrates the utility of these combined techniques in assessing the spatial and temporal natural attenuation and toxicity of the DOM HC in petroleum-impacted groundwater systems.

Environmental Science & Technology↗
USGS2009

Environmental mapping of the World Trade Center area with imaging spectroscopy after the September 11, 2001 attack

The Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) was flown over the World Trade Center area on September 16, 18, 22, and 23, 2001. The data were used to map the WTC debris plume and its contents, including the spectral signatures of asbestiform minerals. Samples were collected and used as ground truth for the AVARIS mapping. A number of thermal hot spots were observed with temperatures greater than 700 &deg;C. The extent and temperatures of the fires were mapped as a function of time. By September 23, most of the fires observed by AVIRIS had been eliminated or reduced in intensity. The mineral absorption features mapped by AVARIS only indicated the presence of serpentine mineralogy and not if the serpentine has asbestiform.

Book chapter↗
USGS2010

Structural features of a bituminous coal and their changes during low-temperature oxidation and loss of volatiles investigated by advanced solid-state NMR spectroscopy

Quantitative and advanced 13 C solid-state NMR techniques were employed to investigate (i) the chemical structure of a high volatile bituminous coal, as well as (ii) chemical structural changes of this coal after evacuation of adsorbed gases, (iii) during oxidative air exposure at room temperature, and (iv) after oxidative heating in air at 75 ??C. The solid-state NMR techniques employed in this study included quantitative direct polarization/magic angle spinning (DP/MAS) at a high spinning speed of 14 kHz, cross polarization/total sideband suppression (CP/TOSS), dipolar dephasing, CH, CH 2 , and CH n selection, 13 C chemical shift anisotropy (CSA) filtering, two-dimensional (2D) 1 H- 13 C heteronuclear correlation NMR (HETCOR), and 2D HETCOR with 1 H spin diffusion. With spectral editing techniques, we identified methyl CCH 3 , rigid and mobile methylene CCH 2 C, methine CCH, quaternary C q , aromatic CH, aromatic carbons bonded to alkyls, small-sized condensed aromatic moieties, and aromatic C-O groups. With direct polarization combined with spectral-editing techniques, we quantified 11 different types of functional groups. 1 H- 13 C 2D HETCOR NMR experiments indicated spatial proximity of aromatic and alkyl moieties in cross-linked structures. The proton spin diffusion experiments indicated that the magnetization was not equilibrated at a 1 H spin diffusion time of 5 ms. Therefore, the heterogeneity in spatial distribution of different functional groups should be above 2 nm. Recoupled C-H long-range dipolar dephasing showed that the fraction of large charcoal-like clusters of polycondensed aromatic rings was relatively small. The exposure of this coal to atmospheric oxygen at room temperature for 6 months did not result in obvious chemical structural changes of the coal, whereas heating at 75 ??C in air for 10 days led to oxidation of coal and generated some COO groups. Evacuation removed most volatiles and caused a significant reduction in aliphatic signals in its DP/MAS spectrum. DP/MAS, but not CP/MAS, allowed us to detect the changes during low-temperature oxidation and loss of volatiles. These results demonstrate the applicability of advanced solid-state NMR techniques in chemical characterization of coal. ?? 2010 American Chemical Society.

Conference Paper↗
USGS2002

Spectroscopy and decay dynamics of several methyl-and fluorine-substituted benzene radical cations

Spectra of several fluorobenzene cation radicals containing 1-3 methyl substituents were observed in solid Ne matrix and analyzed. Comparisons between these compounds and other fluorobenzenes studied previously as well as comparisons between the Β ~ state lifetimes in the gas phase and in the matrix are used to gain a deeper insight into the Β ~ state decay dynamics.

Journal of the American Chemical Society↗
USGS2002

Dust coatings on basaltic rocks and implications for thermal infrared spectroscopy of Mars

Thin coatings of atmospherically deposited dust can mask the spectral characteristics of underlying surfaces on Mars from the visible to thermal infrared wavelengths, making identification of substrate and coating mineralogy difficult from lander and orbiter spectrometer data. To study the spectral effects of dust coatings, we acquired thermal emission and hemispherical reflectance spectra (5–25 μm; 2000–400 cm −1 ) of basaltic andesite coated with different thicknesses of air fall‐deposited palagonitic soils, fine‐grained ceramic clay powders, and terrestrial loess. The results show that thin coatings (10–20 μm) reduce the spectral contrast of the rock substrate substantially, consistent with previous work. This contrast reduction continues linearly with increasing coating thickness until a “saturation thickness” is reached, after which little further change is observed. The saturation thickness of the spectrally flat palagonite coatings is ∼100–120 μm, whereas that for coatings with higher spectral contrast is only ∼50–75 μm. Spectral differences among coated and uncoated samples correlate with measured coating thicknesses in a quadratic manner, whereas correlations with estimated surface area coverage are better fit by linear functions. Linear mixture modeling of coated samples using the rock substrate and coating materials as end‐members is also consistent with their measured coating thicknesses and areal coverage. A comparison of ratios of Thermal Emission Spectrometer (TES) spectra of dark and bright intracrater and windstreak deposits associated with Radau crater suggests that the dark windstreak material may be coated with as much as 90% areal coverage of palagonitic dust. The data presented here also will help improve interpretations of upcoming mini‐TES and Thermal Emission Imaging System (THEMIS) observations of coated Mars surface materials.

Journal of Geophysical Research E: Planets↗
USGS2002

Thermal infrared spectroscopy of experimentally shocked anorthosite and pyroxenite: Implications for remote sensing of Mars

The feldspar and pyroxene mineralogies on Mars revealed by the Thermal Emission Spectrometer (TES) on Mars Global Surveyor likely record a variety of shock effects, as suggested by petrologic analyses of the Martian meteorites and the abundance of impact craters on the planet's surface. To study the effects of shock pressures on thermal infrared spectra of these minerals, we performed shock recovery experiments on orthopyroxenite and anorthosite samples from the Stillwater Complex (Montana) over peak pressures from 17 to 63 GPa. We acquired emissivity and hemispherical reflectance spectra (350–1400 cm −1 ; ∼7–29 μm) of both coherent chips and fine-grained powders of shocked and unshocked samples. These spectra are more directly comparable to remotely sensed data of Mars (e.g., TES) than previously acquired absorption or transmission spectra of shocked minerals. The spectra of experimentally shocked feldspar show systematic changes with increasing pressure due to depolymerization of the silica tetrahedra. For the spectra of chips, this includes the disappearance of small bands in the 500–650 cm −1 region and a strong band at 1115 cm −1 , and changes in positions of a strong band near 940 cm −1 and the Christiansen feature near 1250 cm −1 . Spectra of the shocked powders show the gradual disappearance of a transparency feature near 830 cm −1 . Fewer changes are observed in the pyroxene spectra at pressures as high as 63 GPa. Spectra of experimentally shocked minerals will help identify more precisely the mineralogy of rocks and soils not only from TES but also from Mars instruments such as miniTES and THEMIS.

Journal of Geophysical Research E: Planets↗
USGS2023

Calibration and validation for the Surface Biology and Geology (SBG) mission concept: Recommendations for a multi-sensor system for imaging spectroscopy and thermal imagery

The primary objective of the National Aeronautics and Space Administration (NASA) Surface Biology and Geology (SBG) mission is to measure biological, physical, chemical, and mineralogical features of the Earth's surface, realizing a key conceptual component of the envisioned NASA Earth System Observatory (ESO). SBG is planned to launch as a two-platform mission in the late 2020s, the first of the ESO satellites. Targeted science and applications objectives based on observations of the Earth's SBG helped to define the mission architecture and instrument capabilities for the SBG mission concept. These objectives further drove the need for enabling change detection and trending of surface biological and geological features. These needs implied fundamental calibration goals to achieve the necessary science data quality characteristics. To meet those goals, calibration and validation pre-launch and on-orbit methods formed a basis of the calibration and validation concept, including the combined use of on-board references, vicarious techniques, and routine lunar imaging. International collaboration with space agencies in other countries, an important feature of the recommended SBG mission architecture, uncovered and emphasized the need for inter-calibration techniques that underscored the importance of collaborative instrument characterization data sharing and the use of common calibration references that are International System of Units (SI) traceable in pre-launch and post-launch on orbit calibration mission phases. International collaboration through the use of terrestrial and aquatic networks on six continents for vicarious calibration and validation activities will further assure necessary science data quality while in orbit.

JGR Biogeosciences↗
USGS2025

Multi-scale spectroscopy to map intertidal microbial biofilm community and trait diversity

Intertidal microbial biofilms, or microphytobenthos, support estuarine biogeochemical cycling, the physical stability of mudflats, and food webs, particularly those of migratory shorebirds. Photosynthetic biofilms dominated by diatoms, cyanobacteria, and chlorophytes represent a significant fraction of biofilm biomass and contain pigments that can be detected with remote sensing. These diverse biofilm community types vary in indicator pigments and functional traits related to biogeochemical cycling and nutritional quality. We modeled and mapped spatial variation in intertidal biofilm distribution, quantity, diversity, and functional traits using multi-scale spectroscopic data collected within southern San Francisco Bay, California, USA (South SFB). We developed a new biofilm index (B-index) from 5 mm HySpex spectra to detect biofilm presence. We developed single and multiple response partial least squares regression (PLS) models of chlorophyll -a (chl -a ; biomass indicator), indicator pigments: fucoxanthin and diadinoxanthin (diatoms), zeaxanthin (cyanobacteria), and chl -b (chlorophytes), and functional traits: carbohydrates, lipids, and total organic carbon from paired in situ biofilm data and field spectra. The B-index and PLS models were scaled to South SFB with a 3.7 m AVIRIS-NG hyperspectral image. The model %RMSE calculated from AVIRIS-NG test samples ranged from 12.7% for chl -a to 49% for chl -b ; for six of the eight models, %RMSE was 23% or below. Mapped community types differed in mapped traits, with average lipid concentrations three times higher in areas indicated as diatoms compared to other groups. Available maps depict for the first time the spatial variation of an important shorebird food resource and inform the contribution of intertidal biofilm in carbon and nutrient cycling.

California↗
USGS2005

Near-infrared (0.8-4.0 m) spectroscopy of mimas, enceladus, tethys, and rhea

Spectral measurements from the ground in the time leading up to the Cassini mission at Saturn provide important context for the interpretation of the forthcoming spacecraft data. Whereas ground-based observations cannot begin to approach the spatial scales Cassini will achieve, they do possess the benefits of better spectral resolution, a broader possible time baseline, and unique veiewing geometries not obtained by spacecraft (i.e., opposition). In this spirit, we present recent NIR reflectance spectra of four icy satellites of Saturn measured with the SpeX instrument at the IRTF. These measurements cover the range 0.8-4.0 m of both the leading and trailing sides of Tethys and the leading side of Rhea. The L -band region (2.8-4.0 m) offers new opportunities for searches of minor components on these objects. Additionally, these data include 0.8-2.5 m spectra of both the leading and trailing sides of Mimas and of the (mostly) trailing side of Enceladus. The spectrum of Enceladus shows activity near 2.25 m that we interpret as a possible signature of NH 3 ice. The presence of ammonia in the Saturn system is not unexpected, and may help explain the apparent recent geologic activity of Enceladus. Analysis of leading/trailing differences in H 2 O band depths, spectral slopes, and albedo imply a separate regime of surface modification for Mimas and Enceladus than for the more distant icy satellites (Tethys, Dione, Rhea). Aside from the potential NH 3 on Enceladus, no other minor constituents are detected in these icy surfaces.

Astronomy and Astrophysics↗
USGS2015

Carbon isotope analysis of dissolved organic carbon in fresh and saline (NaCl) water via continuous flow cavity ring-down spectroscopy following wet chemical oxidation

This work examines the performance and limitations of a wet chemical oxidation carbon analyser interfaced with a cavity ring-down spectrometer (WCO-CRDS) in a continuous flow (CF) configuration for measuring &delta; 13 C of dissolved organic carbon ( &delta; 13 C-DOC) in natural water samples. Low-chloride matrix (<5 g Cl/L) DOC solutions were analysed with as little as 2.5 mg C/L in a 9 mL aliquot with a precision of 0.5 &permil;. In high-chloride matrix (10&ndash;100 g Cl/L) DOC solutions, bias towards lighter &delta; 13 C-DOC was observed because of incomplete oxidation despite using high-concentration oxidant, extended reaction time, or post-wet chemical oxidation gas-phase combustion. However, through a combination of dilution, chloride removal, and increasing the oxidant:sample ratio, high-salinity samples with sufficient DOC (>22.5 &micro;g C/aliquot) may be analysed. The WCO-CRDS approach requires more total carbon (&micro;g C/aliquot) than conventional CF-isotope ratio mass spectrometer, but is nonetheless applicable to a wide range of DOC concentration and water types, including brackish water, produced water, and basinal brines.

Isotopes in Environmental and Health Studies↗
USGS2006

Attenuated total reflectance spectroscopy of plant leaves: A tool for ecological and botanical studies

??? Attenuated total reflectance (ATR) spectra of plant leaves display complex absorption features related to organic constituents of leaf surfaces. The spectra can be recorded rapidly, both in the field and in the laboratory, without special sample preparation. ??? This paper explores sources of ATR spectral variation in leaves, including compositional, positional and temporal variations. Interspecific variations are also examined, including the use of ATR spectra as a tool for species identification. ??? Positional spectral variations generally reflected the abundance of cutin and the epicuticular wax thickness and composition. For example, leaves exposed to full sunlight commonly showed more prominent cutin- and wax-related absorption features compared with shaded leaves. Adaxial vs. abaxial leaf surfaces displayed spectral variations reflecting differences in trichome abundance and wax composition. Mature vs. young leaves showed changes in absorption band position and intensity related to cutin, polysaccharide, and possibly amorphous silica development on and near the leaf surfaces. ??? Provided that similar samples are compared (e.g. adaxial surfaces of mature, sun-exposed leaves) same-species individuals display practically identical ATR spectra. Using spectral matching procedures to analyze an ATR database containing 117 individuals, including 32 different tree species, 83% of the individuals were correctly identified. ?? The Authors (2006).

New Phytologist↗
USGS1991

Galileo infrared imaging spectroscopy measurements at Venus

During the 1990 Galileo Venus flyby, the Near Infrared Mapping Spectrometer investigated the night-side atmosphere of Venus in the spectral range 0.7 to 5.2 micrometers. Multispectral images at high spatial resolution indicate substantial cloud opacity variations in the lower cloud levels, centered at 50 kilometers altitude. Zonal and meridional winds were derived for this level and are consistent with motion of the upper branch of a Hadley cell. Northern and southern hemisphere clouds appear to be markedly different. Spectral profiles were used to derive lower atmosphere abundances of water vapor and other species.

Science↗