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USGS2001

Precise K-Ar, 40Ar/39Ar, Rb-Sr and U/Pb mineral ages from the 27.5 Ma fish canyon tuff reference standard

The accuracy of ages measured using the 40Ar/39Ar technique is affected by uncertainties in the age of radiation fluence-monitor minerals. At present, there is lack of agreement about the ages of certain minerals used as fluence monitors. The accuracy of the age of a standard may be improved if the age can be measured using different decay schemes. This has been done by measuring ages on minerals from the Oligocene Fish Canyon Tuff (FCT) using the K-Ar, 40Ar/39Ar. Rb-Sr and U/Pb methods. K-Ar and 40Ar/39Ar total fusion ages of sanidine, biotite and hornblende yielded a mean age of 27.57 ?? 0.36 Ma. The weighted mean 40Ar/39Ar plateau age of sanidine and biotite is 27.57 ?? 0.18 Ma. A biotite-feldspar Rb-Sr isochron yielded an age of 27.44 ?? 0.16 Ma. The U-Pb data for zircon are complex because of the presence of Precambrian zircons and inheritance of radiogenic Pb. Zircons with 207Pb/235U < 0.4 yielded a discordia line with a lower concordia intercept of 27.52 ?? 0.09 Ma. Evaluation of the combined data suggests that the best age for FCT is 27.51 Ma. Published by Elsevier Science B.V.

Chemical Geology↗

USGS2014

Specific yield determined from a Thiem's Pumping‐Test

The specific yield of a water-bearing formation is defined as the ratio of (1) the volume of water, which after being saturated, it will yield by gravity to (2) its own volume (O. E. Meinzer, Outline of ground-water hydrology, U.S. Geol. Sur. Water-Supply Paper 494, p. 28, 1923). It is a measure of the quantity of water that a formation will yield when it is drained by lowering of the water-table. The determination of the specific yield is essential in many quantitative ground-water investigations. In 1931 a pumping-test was made in the Platte River Valley, in Nebraska, to determine by Thiem's method the permeability of the water-bearing sand and gravel that underlie the Valley. This test, which constitutes a part of a cooperative investigation by the Conservation and Survey Department of the University of Nebraska and the United States Geological Survey, was briefly described in the 1932 Transactions of the American Geophysical Union (p. 393). The well was pumped continuously for 48 hours, and measurements of the discharge were made every 30 minutes. During the period of pumping and after pumping stopped about 5,000 measurements were made of the depths to the water-surfaces in 80 observation-wells, which were located on lines radiating from the pumped well to distances up to 1,200 feet. Instrumental levels were run to the measuring points on each of the wells so that the altitudes of the water-surfaces could be determined for any time. From the data obtained in this test the average coefficient of permeability was computed to be about 700. In the present paper a method is presented for determining the specific yield of the water-bearing material from the data collected in this test, and the results of the computations are given. This method for determining specific yield was suggested by Meinzer (O. E. Meinzer, Outline of methods for estimating ground-water supplies, U.S. Geol. Sur. water-Supply Paper 638-c, p. 136, 1932).

Eos, Transactions, American Geophysical Union↗

USGS2020

Dust deposited on snow cover in the San Juan Mountains, Colorado, 2011-2016: Compositional variability bearing on snow-melt effects

Light-absorbing particles in atmospheric dust deposited on snow cover (dust-on-snow, DOS) diminish albedo and accelerate the timing and rate of snow melt. Identification of these particles and their effects are relevant to snow-radiation modeling and thus water-resource management. Laboratory-measured reflectance of DOS samples from the San Juan Mountains (USA) were compared with DOS mass loading, particle sizes, iron mineralogy, carbonaceous matter type and content, and chemical compositions. Samples were collected each spring for water years 2011-2016, when individual dust layers had merged into one (all layers merged) at the snow surface. Average reflectance values of the six samples were 0.2153 (sd, 0.0331) across the visible wavelength region (0.4-0.7 µm) and 0.3570 (sd, 0.0498) over the full-measurement range (0.4-2.50 µm). Reflectance values correlated inversely to concentrations of ferric oxide, organic carbon (1.4-10 wt. %), magnetite (0.05-0.13 wt. %), and silt (PM63-3.9; median grain sizes averaged 21.4 µm) but lacked correspondence to total iron and PM10 contents. Measurements of reflectance and Mössbauer spectra and magnetic properties indicated that microcrystalline hematite and nano-size goethite were primarily responsible for diminished visible reflectance. Positive correlations between organic carbon and metals attributed to fossil-fuel combustion, with observations from electron microscopy, indicated that some carbonaceous matter occurred as black carbon. Magnetite was a surrogate for related light-absorbing minerals, dark rock particles, and contaminants. Similar analyses of DOS from other areas would help evaluate the influences of varied dust sources, wind-storm patterns, and anthropogenic inputs on snow melt and water resources in and beyond the Colorado River basin.

Colorado↗

USGS2019

Measurement of sounds emitted by certain high-resolution geophysical survey systems

Scientific questions regarding the impact of anthropomorphic noise in the marine environment have resulted in an increasing number of regulatory requirements and precautionary mitigation strategies to reduce the risks associated with high-resolution marine geophysical surveys performed in waters subjected to government jurisdiction. An example of regulatory frameworks includes the Marine Mammal Protection Act in the United States and the Marine Strategy Framework Directive 2008/56/EC in the European Union. Regulatory compliance often requires an assessment of the potential ecological risks before initiating a marine geophysical survey. However, the acoustic source data needed to estimate the risk associated with the operation of a given high-resolution survey system are frequently lacking. A comprehensive measurement program was performed to quantify the characteristics of sounds radiated by a variety of commercial marine geophysical survey systems, including boomers, sparkers, airguns, chirp sub-bottom profilers, sidescan sonars, and swath-bathymetric sonars [Crocker and Fratantonio, “Characteristics of high-frequency sounds emitted during high-resolution marine geophysical surveys,” Naval Undersea Warfare Center, Newport, RI, USA, NUWC-NPT Tech. Rep. 12, 203, 2016]. Calibrated acoustic source data, including source levels, source spectra, and beam patterns, were acquired for a total of 18 different marine geophysical survey systems. The data support modeling to estimate the potential ecological impacts resulting from the operation of certain high-resolution marine geophysical survey systems.

IEEE Journal of Oceanic Engineering↗

USGS2016

Potential distribution of the viral haemorrhagic septicaemia virus in the Great Lakes region

Viral haemorrhagic septicaemia virus (VHSV) genotype IVb has been responsible for large-scale fish mortality events in the Great Lakes of North America. Anticipating the areas of potential VHSV occurrence is key to designing epidemiological surveillance and disease prevention strategies in the Great Lakes basin. We explored the environmental features that could shape the distribution of VHSV, based on remote sensing and climate data via ecological niche modelling. Variables included temperature measured during the day and night, precipitation, vegetation, bathymetry, solar radiation and topographic wetness. VHSV occurrences were obtained from available reports of virus confirmation in laboratory facilities. We fit a Maxent model using VHSV-IVb reports and environmental variables under different parameterizations to identify the best model to determine potential VHSV occurrence based on environmental suitability. VHSV reports were generated from both passive and active surveillance. VHSV occurrences were most abundant near shore sites. We were, however, able to capture the environmental signature of VHSV based on the environmental variables employed in our model, allowing us to identify patterns of VHSV potential occurrence. Our findings suggest that VHSV is not at an ecological equilibrium and more areas could be affected, including areas not in close geographic proximity to past VHSV reports.

Great Lakes↗

USGS1982

Hydrologic data from Naval Oil Shale Reserves, Parachute Creek basin, northwestern Colorado, 1975-79

This report summarizes data collected by the U.S. Geological Survey for the U.S. Department of Energy, Naval Petroleum, and Oil Shale Reserves in the Parachute Creek drainage basin of western Colorado. It includes data from five surface-water gages, two automatic sediment samplers and two water-quality monitors. Instantaneous streamflow measurements were made at 63 sites on Parachute Creek tributaries to determine gain or loss of flow. Thirteen springs and nine surface-water sites were sampled and chemical analyses of these sites are included. From 1975 to 1979, 88 spring sites were inventoried; conductivity, temperature, pH, and discharge were measured. Climate data include maximum, minimum, and total daily solar radiation. Daily total precipitation is reported for three stations and snow-course data is reported for one site.

Open-File Report↗

USGS2019

Airborne radiometric maps of Mountain Pass, California

Geophysical investigations of Mountain Pass and vicinity were begun as part of an effort to study regional crustal structures as an aid to understanding the geologic framework and mineral resources of the eastern Mojave Desert. The study area encompasses Mountain Pass, host to one of the world’s largest rare earth element carbonatite deposits. The deposit is found along a north-northwest-trending, fault-bounded block that extends along the eastern parts of the Clark Mountain Range, Mescal Range, and Ivanpah Mountains. This Paleoproterozoic block is composed of a 1.7-Ga metamorphic complex of gneiss and schist that underwent widespread metamorphism and associated plutonism during the Ivanpah orogeny. The Paleoproterozoic rocks were intruded by a Mesoproterozoic (1.4 Ga) ultrapotassic alkaline intrusive suite and carbonatite body. The intrusive rocks include, from oldest to youngest, shonkinite, mesosyenite, syenite, quartz syenite, potassic granite, carbonatite, carbonatite dikes, and late shonkinite dikes. The diverse physical properties of rocks that underlie the study area are well suited to geophysical investigations. Contrasts in radiogenic signatures between Paleoproterozoic crystalline basement, rocks of the Mesoproterozoic carbonatite body and the associated alkaline intrusive suite, Paleozoic carbonate rocks, Mesozoic granitoids, Tertiary volcanic rocks, and unconsolidated alluvium, for example, produce a distinctive pattern of radiometric anomalies that can aid in understanding the geologic framework and mineral resource potential of the eastern Mojave Desert. A high-resolution radiometric survey of Mountain Pass was flown by helicopter over parts of the Clark Mountain Range, Mescal Range, and Ivanpah Mountains. Aeroradiometric surveys measure the intensity and energy spectrum of gamma-ray radiation from the three most common naturally occurring radioelements: potassium ( 40 K), thorium ( 232 Th), and uranium ( 238 U). For 232 Th and 238 U, the source of the gamma-rays comes from their thallium ( 208 Tl) and bismuth ( 214 Bi) decay products, respectively, and, thus, concentrations for Th and U are referred to as “equivalent concentration,” assuming radioactive equilibrium. The concentrations of these radioelements can be used together to estimate changes in geochemistry and lithology. Carbonatite deposits typically have distinctive geophysical signatures because they are relatively dense, magnetic, and radiogenic. Specifically, the carbonatite and alkaline intrusive suite at Mountain Pass is ultrapotassic and contains relatively significant amounts of K, Th, and U, which can be delineated using airborne radiometric surveys.

California↗

USGS2023

Development of an integrated hydrologic flow model of the Rio San Jose Basin and surrounding areas, New Mexico

The Rio San Jose Integrated Hydrologic Model (RSJIHM) was developed to provide a tool for analyzing the hydrologic system response to historical water use and potential changes in water supplies and demands in the Rio San Jose Basin. The study area encompasses about 6,300 square miles in west-central New Mexico and includes the communities of Grants, Bluewater, and San Rafael and three Native American Tribal lands: the Acoma and Laguna Pueblos and the Navajo Nation. Perennial surface water features are sparse in the study area and most water resources consist of groundwater pumped from sedimentary and basalt aquifers. Calibration of the RSJIHM was performed using PEST++ (version 4.3.20) and BeoPEST (version 13.6). Model parameter values were adjusted during calibration to fit model simulated values to the measured or estimated values for several observation groups: (1) solar radiation, (2) potential evapotranspiration, (3) actual evapotranspiration, (4) precipitation and minimum and maximum air temperature, (5) snow water equivalent, (6) snow-covered area, (7) streamflow, (8) hydraulic head, (9) springflow at Ojo del Gallo, (10) springflow at Horace Springs, (11) surface-water releases from Bluewater Lake, and (12) surface-water diversions for irrigation within the Bluewater-Toltec Irrigation District. The simulated average annual hydrologic budget from 1950 through 2018 indicated that the majority (greater than 98 percent) of precipitation within the basin was consumed by evapotranspiration, leaving 1.2 percent to recharge the groundwater system, 0.47 percent to direct runoff to streams, and 0.20 percent to infiltrate the soil zone and interflow to streams. The average annual recharge to the groundwater system and runoff to streams simulated by the RSJIHM was about 28,000 and 11,000 acre-feet, respectively. The RSJIHM simulated about 590,000 acre-feet of cumulative aquifer storage depletion from 1950 through 2018. Additional work that could improve the simulation capability of the RSJIHM includes (1) further data collection (streamflow, head, springflow) in the southwestern subbasin that includes the El Malpais National Monument, (2) incorporating temporally variable vegetation parameters, (3) spatial downscaling of the hydrometeorological input datasets, (4) incorporating additional spatial variability to hydraulic property parameters on the basis of new data collection, and (5) using environmental tracers to verify and calibrate model parameters.

New Mexico↗

USGS2022

Comparison of sediment composition by smear slides to quantitative shipboard data: A case study on the utility of smear slide percent estimates, IODP Expedition 353, northern Indian Ocean

Smear slide petrography has been a standard technique during scientific ocean drilling expeditions to characterize sediment composition and classify sediment types, but presentation of these percent estimates to track downcore trends in sediment composition has become less frequent over the past 2 decades. We compare semi-quantitative smear slide composition estimates to physical property (natural gamma radiation, NGR) and solid-phase geochemical (calcium carbonate, CaCO3 %) measurements from a range of marine depositional environments in the northern Indian Ocean (Bay of Bengal, Andaman Sea, Ninetyeast Ridge) collected during International Ocean Discovery Program (IODP) Expedition 353. We show that presenting smear slide estimates as percentages, rather than abundance categories, reveals similar downcore variation in composition to the more quantitative core analyses. Overall downcore trends in total calcareous components from smear slides (foraminifers + nannofossils + shell fragments + authigenic carbonate) follow similar downcore trends to samples measured by CaCO3 coulometry. Total lithogenic components (clay + mica + quartz + feldspars + lithic grains + vitric grains + glauconite + heavy minerals + iron oxides) and clay from smear slides track reasonably well with NGR measurements. Comparison of site averages of absolute percentages of total calcium carbonate from coulometry and total calcareous components from smear slide observations reveals an overestimation in carbonate percentages in smear slides (likely due in part to underestimation of the clay fraction), especially in sediments rich in smectite clays. Differences in sediment color between sites and settling of clay particles during slide preparation may contribute to this discrepancy. Although smear slide estimates range in accuracy depending on the training of the operator, we suggest that sedimentologists describing cores obtained during scientific drilling can use the percent estimates of sedimentary components in smear slides to identify trends and cyclicity in marine sediment records.

Scientific Drilling↗

USGS2025

Introduction to the special section on improving measurements of earthquake source parameters

Earthquake source parameters such as magnitude, seismic moment, source dimension, stress drop, and radiated energy are fundamental to understanding earthquake physics, and are also key ingredients in earthquake ground‐motion modeling, rupture simulation, and statistical seismology. However, the uncertainties in these parameters estimated from the radiated seismic wavefield are large due to variability in approaches, including site and attenuation characterizations, and so estimates for an individual earthquake made by different studies can vary greatly. Estimating spectral source parameters remains a popular topic, due to a combination of their intrinsic importance and their apparent ease of measurement, but also a controversial one, due to many sources of variability and large uncertainty. The available methods coupled with necessary parameter choices and assumptions in the analysis make it challenging for researchers to apply methods or understand the reliability in results or reported source parameters. This Special Section on Improving Measurements of Earthquake Source Parameters showcasing comparisons between methods and studies seeks to alleviate some of these difficulties to help the community identify the important components and trade‐offs of decomposing recorded seismograms into their source, path, and site components.

Bulletin of the Seismological Society of America↗

USGS2017

Advances in ice radar studies of a temperate alpine glacier, South Cascade Glacier, Washington, U.S.A.

South Cascade Glacier, Washington, U.S.A., is one of the most extensively studied glaciers in the Western Hemisphere. In addition to mass-balance measurements, which date to 1958, numerous hydrological investigations have been carried out during the last three decades, and repeated ice-thickness determinations have been made using a variety of techniques. In the late 1960s, the basal topography was initially determined by gravitimetric methods. In the mid-1970s some of the first depth measurements using radar on temperate ice were made. The basal topography was remapped soon after from a series of point radar measurements and boreholes drilled to the glacier bottom. During the 1990s, the ice thickness was remapped using digital recording of continuous profiles that obtained over 5000 ice-thickness measurements. Profiles have been corrected for the finite beamwidth of the antenna radiation pattern and reflections in steep terrain, resulting in a significantly improved depiction of the basal surface and internal structures. The map based on our recent radar profiles confirms the large-scale features of the basal topography previously depicted and reveals more structural detail. A bright reflector was detected at the base of the glacier and could be traced in adjacent profiles. Comparison with results from water-level measurements in boreholes drilled to the bed indicates that the reflector is a subglacial conduit.

Washington↗

USGS1983

Multiwavelength EDM measurements in southern California

We installed a precise geodetic network along the San Andreas fault near Pearblossom, California in November, 1980. The network is within the region frequently referred to as the "Palmdale Uplift" and consists of 13 lines radiating from a central benchmark. The lines range in length from 3.2 to 8.1 km are generally measured several times each week. The multiwavelength distance measuring (MWDM) instrument is located at the central benchmark and is housed in a small protective shelter. The MWDM instrument has demonstrated a capability to make measurements to a precision of 1 part in 10 million. Using a coordinate system whose x-axis is parallel to the local trace of the San Andreas fault the following strain rates were observed during the first 10 months of this effort: ɛ xx = -0.180 ± 0.025 μ str / yr ɛ yy = -0.031± 0.029 μ str / yr ɛ xx = +0.077 ± 0.024 μ str / yr △ -0.213 ± 0.039 μ str / yr The observed strain rates do not appear to be constant in time, much of the deformation occurs in fairly well defined episodes. These changes in strain rate are particularly obvious in the ɛ yy component.

California↗

USGS2011

Volcanic plume height measured by seismic waves based on a mechanical model

In August 2008 an unmonitored, largely unstudied Aleutian volcano, Kasatochi, erupted catastrophically. Here we use seismic data to infer the height of large eruptive columns such as those of Kasatochi based on a combination of existing fluid and solid mechanical models. In so doing, we propose a connection between a common, observable, short-period seismic wave amplitude to the physics of an eruptive column. To construct a combined model, we estimate the mass ejection rate of material from the vent on the basis of the plume height, assuming that the height is controlled by thermal buoyancy for a continuous plume. Using the estimated mass ejection rate, we then derive the equivalent vertical force on the Earth through a momentum balance. Finally, we calculate the far-field surface waves resulting from the vertical force. The model performs well for recent eruptions of Kasatochi and Augustine volcanoes if v , the velocity of material exiting the vent, is 120-230 m s -1 . The consistency between the seismically inferred and measured plume heights indicates that in these cases the far-field ~1 s seismic energy radiated by fluctuating flow in the volcanic jet during the eruption is a useful indicator of overall mass ejection rates. Thus, use of the model holds promise for characterizing eruptions and evaluating ash hazards to aircraft in real time on the basis of far-field short-period seismic data. This study emphasizes the need for better measurements of eruptive plume heights and a more detailed understanding of the full spectrum of seismic energy radiated coeruptively.

Journal of Geophysical Research B: Solid Earth↗

USGS2004

Reconciling different observations of the CO2 ice mass loading of the Martian north polar cap

The GRS measurements of the peak mass loading of the north polar CO 2 ice cap on Mars are about 60% lower than those calculated from MGS TES radiation data and those inferred from the MOLA cap thicknesses. However, the GRS data provide the most accurate measurement of the mass loading. We show that the TES and MOLA data can be reconciled with the GRS data if (1) subsurface heat conduction and atmospheric heat transport are included in the TES mass budget calculations, and (2) the density of the polar deposits is ∼600 kg m −3 . The latter is much less than that expected for slab ice (∼1600 kg m −3 ) and suggests that processes unique to the north polar region are responsible for the low cap density.

Geophysical Research Letters↗

USGS2026

Thermal and dielectric properties of Juno’s regolith at one millimeter wavelength

We present the modeling results of the thermal lightcurve of asteroid (3) Juno at the wavelength of λ = 1.3 mm measured by the Atacama Large Millimeter-submillimeter Array. A thermophysical model together with a radiative transfer model suggests a thermal inertia of 13 ± 10 [J m −2 K −1 s −0.5 ], an equivalent emissivity of 0.8 ± 0.1, a loss tangent of 0.4 ± 0.3, and an index of refraction 1.8 ± 0.3. Based on previous laboratory measurements, the modeled index of refraction suggests a regolith porosity of about 45%. However, thermal inertia models using the material parameters of ordinary chondrite indicate a grain size of ∼10 μ m and require a high porosity of ∼90% to explain the low thermal inertia. In order to explain such a contradiction, we postulate that some repulsive mechanism might be in effect to reduce the contact of grains and therefore the thermal inertia. The loss tangent of Juno’s regolith corrected for the modeled thermal skin depth is in the order of 0.5, much higher than that of the lunar regolith and indicating an electrical skin depth of L = 0.1–1.4 mm that is within the thermal skin depth. The shape of the rotational lightcurve of Juno in the millimeter wavelengths is dominated by its irregular shape, but rotational variations in the thermal and/or dielectric properties cannot be ruled out. Our results demonstrate that millimeter-wavelength observations of asteroids provide an extra dimension of constraints to the porosity and grain size of asteroid regolith compared to the thermal infrared observations.

Planetary Science Journal↗

USGS2008

Characterization of errors in a coupled snow hydrology-microwave emission model

Traditional approaches to the direct estimation of snow properties from passive microwave remote sensing have been plagued by limitations such as the tendency of estimates to saturate for moderately deep snowpacks and the effects of mixed land cover within remotely sensed pixels. An alternative approach is to assimilate satellite microwave emission observations directly, which requires embedding an accurate microwave emissions model into a hydrologic prediction scheme, as well as quantitative information of model and observation errors. In this study a coupled snow hydrology [Variable Infiltration Capacity (VIC)] and microwave emission [Dense Media Radiative Transfer (DMRT)] model are evaluated using multiscale brightness temperature (TB) measurements from the Cold Land Processes Experiment (CLPX). The ability of VIC to reproduce snowpack properties is shown with the use of snow pit measurements, while TB model predictions are evaluated through comparison with Ground-Based Microwave Radiometer (GBMR), air-craft [Polarimetric Scanning Radiometer (PSR)], and satellite [Advanced Microwave Scanning Radiometer for the Earth Observing System (AMSR-E)] TB measurements. Limitations of the model at the point scale were not as evident when comparing areal estimates. The coupled model was able to reproduce the TB spatial patterns observed by PSR in two of three sites. However, this was mostly due to the presence of relatively dense forest cover. An interesting result occurs when examining the spatial scaling behavior of the higher-resolution errors; the satellite-scale error is well approximated by the mode of the (spatial) histogram of errors at the smaller scale. In addition, TB prediction errors were almost invariant when aggregated to the satellite scale, while forest-cover fractions greater than 30% had a significant effect on TB predictions. ?? 2008 American Meteorological Society.

Journal of Hydrometeorology↗

USGS2020

Quantifying gas emissions associated with the 2018 rift eruption of Kīlauea Volcano using ground-based DOAS measurements

Starting on 3 May 2018, a series of eruptive fissures opened in Kīlauea Volcano’s lower East Rift Zone (LERZ). Over the course of the next 3 months, intense degassing accompanied lava effusion from these fissures. Here, we report on ground-based observations of the gas emissions associated with Kīlauea’s 2018 eruption. Visual observations combined with radiative transfer modeling show that ultraviolet light could not efficiently penetrate the gas and aerosol plume in the LERZ, complicating SO 2 measurements by differential optical absorption spectroscopy (DOAS). By applying a statistical method that integrates a radiative transfer model with the DOAS retrievals, we were able to calculate sulfur dioxide (SO 2 ) emission rates along with estimates of their uncertainty. We find that sustained SO 2 emissions were highest in June and early July, when approximately 200 kt SO 2 were emitted daily. At the 68% confidence interval, we estimate that 7.1–13.6 Mt SO 2 were released from the LERZ during the entire May to September eruptive episode. Scaling our results with in situ measurements of plume composition, we calculate that 11–21 Mt H 2 O and 1.5–2.8 Mt CO 2 were also emitted. The gas and aerosol emissions caused hazardous conditions in areas proximal to the active vents, but plume dispersion modeling shows that the eruption also significantly impacted air quality hundreds of kilometers downwind. Combined with petrologic studies of the erupted lavas, our measurements indicate that 1.1–2.3 km 3 dense-rock equivalent of lava were erupted from the LERZ, which is approximately twice the concomitant collapse volume of the volcano’s summit.

Hawaii↗

USGS2011

Early in-flight detection of SO 2 via Differential Optical Absorption Spectroscopy: A feasible aviation safety measure to prevent potential encounters with volcanic plumes

Volcanic ash constitutes a risk to aviation, mainly due to its ability to cause jet engines to fail. Other risks include the possibility of abrasion of windshields and potentially serious damage to avionic systems. These hazards have been widely recognized 5 since the early 1980s, when volcanic ash provoked several incidents of engine failure in commercial aircraft. In addition to volcanic ash, volcanic gases also pose a threat. Prolonged and/or cumulative exposure to sulphur dioxide (SO 2 ) or sulphuric acid (H 2 SO 4 ) aerosols potentially affects e.g. windows, air frame and may cause permanent damage to engines. SO 2 receives most attention among the gas species commonly found in 10 volcanic plumes because its presence above the lower troposphere is a clear proxy for a volcanic cloud and indicates that fine ash could also be present. Up to now, remote sensing of SO 2 via Differential Optical Absorption Spectroscopy (DOAS) in the ultraviolet spectral region has been used to measure volcanic clouds from ground based, airborne and satellite platforms. Attention has been given to vol- 15 canic emission strength, chemistry inside volcanic clouds and measurement procedures were adapted accordingly. Here we present a set of experimental and model results, highlighting the feasibility of DOAS to be used as an airborne early detection system of SO 2 in two spatial dimensions. In order to prove our new concept, simultaneous airborne and ground-based measurements of the plume of Popocatepetl volcano, Mexico, were conducted in April 2010. The plume extended at an altitude around 5250 m above sea level and was approached and traversed at the same altitude with several forward looking DOAS systems aboard an airplane. These DOAS systems measured SO 2 in the flight direction and at ±40 mrad (2.3◦) angles relative to it in both, horizontal and vertical directions. The approaches started at up to 25 km distance to 25 the plume and SO 2 was measured at all times well above the detection limit. In combination with radiative transfer studies, this study indicates that an extended volcanic cloud with a concentration of 1012 molecules cm−3 at typical flight levels of 10 km can be detected unambiguously at distances of up to 80 km away. This range provides enough time (approx. 5 min) for pilots to take action to avoid entering a volcanic cloud in the flight path, suggesting that this technique can be used as an effective aid to prevent dangerous aircraft encounters with potentially ash rich volcanic clouds.

Popocatepetl volcano↗