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At least 127 records · Page 7Linked to original sources

Ground-water quality data in the southeast San Joaquin Valley, 2005–2006— Results from the California GAMA program

Ground-water quality in the approximately 3,800 square-mile Southeast San Joaquin Valley study unit (SESJ) was investigated from October 2005 through February 2006 as part of the Priority Basin Assessment Project of Ground-Water Ambient Monitoring and Assessment (GAMA) Program. The GAMA Statewide Basin Assessment project was developed in response to the Ground-Water Quality Monitoring Act of 2001 and is being conducted by the California State Water Resources Control Board (SWRCB) in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory (LLNL). The SESJ study was designed to provide a spatially unbiased assessment of raw ground-water quality within SESJ, as well as a statistically consistent basis for comparing water quality throughout California. Samples were collected from 99 wells in Fresno, Tulare, and Kings Counties, 83 of which were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study area (grid wells), and 16 of which were sampled to evaluate changes in water chemistry along ground-water flow paths or across alluvial fans (understanding wells). The ground-water samples were analyzed for a large number of synthetic organic constituents (volatile organic compounds [VOCs], pesticides and pesticide degradates, and pharmaceutical compounds), constituents of special interest (perchlorate, N-nitrosodimethylamine, and 1,2,3-trichloropropane), naturally occurring inorganic constituents (nutrients, major and minor ions, and trace elements), radioactive constituents, and microbial indicators. Naturally occurring isotopes (tritium, and carbon-14, and stable isotopes of hydrogen, oxygen, nitrogen, and carbon), and dissolved noble gases also were measured to help identify the source and age of the sampled ground water. Quality-control samples (blanks, replicates, samples for matrix spikes) were collected at approximately 10 percent of the wells, and the results for these samples were used to evaluate the quality of the data for the ground-water samples. Assessment of the quality-control data resulted in censoring of less than 1 percent of the detections of constituents measured in ground-water samples. This study did not attempt to evaluate the quality of drinking water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, and (or) blended with other waters to maintain acceptable drinking-water quality. Regulatory thresholds apply to the treated water that is served to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with regulatory and other health-based thresholds established by the U.S. Environmental Protection Agency and California Department of Public Health (CDPH) and thresholds established for aesthetic concerns by CDPH. Two VOCs were detected above health-based thresholds: 1,2-dibromo-3-chloropropane (DBCP), and benzene. DBCP was detected above the U.S. Environmental Protections Agency’s maximum contaminant level (MCL-US) in three grid wells and five understanding wells. Benzene was detected above the CDPH’s maximum contaminant level (MCL-CA) in one grid well. All pesticide detections were below health-based thresholds. Perchlorate was detected above its maximum contaminate level for California in one grid well. Nitrate was detected above the MCL-US in six samples from understanding wells, of which one was a public supply well. Two trace elements were detected above MCLs-US: arsenic and uranium. Arsenic was detected above the MCL-US in four grid wells and two understanding wells; uranium was detected above the MCL-US in one grid well and one understanding well. Gross alpha radiation was detected above MCLs-US in five samples; four of them understanding wells, and uranium isotope activity was greater than the MCL-US for one understanding well. Radon-222 was detected above the proposed MCL-US in all wells sampled. Total coliforms were detected in two wells and somatic coliphage was detected in one well.

California

Organic Compounds in Truckee River Water Used for Public Supply near Reno, Nevada, 2002-05

Organic compounds studied in this U.S. Geological Survey (USGS) assessment generally are man-made, including, in part, pesticides, solvents, gasoline hydrocarbons, personal care and domestic-use products, and refrigerants and propellants. Of 258 compounds measured, 28 were detected in at least 1 source water sample collected approximately monthly during 2002-05 at the intake of the Chalk Bluff Treatment Plant, on the Truckee River upstream of Reno, Nevada. The diversity of compounds detected indicate various sources and uses (including wastewater discharge, industrial, agricultural, domestic, and others) and different pathways (including point sources from treated wastewater outfalls upstream of the sampling location, overland runoff, and groundwater discharge) to drinking-water supply intakes. Three compounds were detected in more than 20 percent of the source-water intake samples at low concentrations (less than 0.1 microgram per liter), including caffeine, p-cresol (a wood preservative), and toluene (a gasoline hydrocarbon). Sixteen of the 28 compounds detected in source water also were detected in finished water (after treatment, but prior to distribution; 2004-05). Additionally, two disinfection by-products not detected in source water, bromodichloromethane and dibromochloromethane, were detected in all finished water samples. Two detected compounds, cholesterol and 3-beta-coprostanol, are among five naturally occurring biochemicals analyzed in this study. Concentrations for all detected compounds in source and finished water generally were less than 0.1 microgram per liter and always less than human-health benchmarks, which are available for about one-half of the compounds. Seven compounds (toluene, chloroform, bromodichloromethane, dibromodichloromethane, bisphenol A, cholesterol, and 3-beta-coprostanol) were measured at concentrations greater than 0.1 microgram per liter. On the basis of this screening-level assessment, adverse effects to human health are expected to be negligible (subject to limitations of available human-health benchmarks).

Fact Sheet

Status of groundwater quality in the California Desert Region, 2006-2008: California GAMA Priority Basin Project

Groundwater quality in six areas in the California Desert Region (Owens, Antelope, Mojave, Coachella, Colorado River, and Indian Wells) was investigated as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory. The six Desert studies were designed to provide a spatially unbiased assessment of the quality of untreated groundwater in parts of the Desert and the Basin and Range hydrogeologic provinces, as well as a statistically consistent basis for comparing groundwater quality to other areas in California and across the Nation. Samples were collected by the USGS from September 2006 through April 2008 from 253 wells in Imperial, Inyo, Kern, Los Angeles, Mono, Riverside, and San Bernardino Counties. Two-hundred wells were selected using a spatially distributed, randomized grid-based method to provide a spatially unbiased representation of the study areas (grid wells), and fifty-three wells were sampled to provide additional insight into groundwater conditions (additional wells). The status of the current quality of the groundwater resource was assessed based on data from samples analyzed for volatile organic compounds (VOCs), pesticides, and inorganic constituents such as major ions and trace elements. Water-quality data from the California Department of Public Health (CDPH) database also were incorporated in the assessment. The status assessment is intended to characterize the quality of untreated groundwater resources within the primary aquifer systems of the Desert Region, not the treated drinking water delivered to consumers by water purveyors. The primary aquifer systems (hereinafter, primary aquifers) in the six Desert areas are defined as that part of the aquifer corresponding to the perforation intervals of wells listed in the CDPH database. Relative-concentrations (sample concentration divided by the benchmark concentration) were used as the primary metric for evaluating groundwater quality for those constituents that have Federal and (or) California benchmarks. A relative-concentration (RC) greater than (>) 1.0 indicates a concentration above a benchmark, and an RC less than or equal to (≤) 1.0 indicates a concentration equal to or below a benchmark. Organic and special-interest constituent RCs were classified as “low” (RC ≤ 0.1), “moderate” (0.1 < RC ≤ 1.0), or “high” (RC > 1.0). Inorganic constituent RCs were classified as “low” (RC ≤ 0.5), “moderate” (0.5 < RC ≤ 1.0), or “high” (RC > 1.0). A lower threshold value RC was used to distinguish between low and moderate RCs for organic constituents because these constituents are generally less prevalent and have smaller RCs than inorganic constituents. Aquifer-scale proportion was used as the primary metric for evaluating regional-scale groundwater quality. High aquifer-scale proportion was defined as the percentage of the area of the primary aquifers with an RC greater than 1.0 for a particular constituent or class of constituents; percentage is based on an areal rather than a volumetric basis. Moderate and low aquifer-scale proportions were defined as the percentage of the primary aquifers with moderate and low RCs, respectively. Two statistical approaches—grid-based and spatially weighted—were used to evaluate aquifer-scale proportions for individual constituents and classes of constituents. Grid-based and spatially weighted estimates were comparable in the Desert Region (within 90 percent confidence intervals). The status assessment determined that one or more inorganic constituents with health-based benchmarks had high RCs in 35.4 percent of the Desert Region’s primary aquifers, moderate RCs in 27.4 percent, and low RCs in 37.2 percent. The inorganic constituents with health-based benchmarks having the largest high aquifer-scale proportions were arsenic (17.8 percent), boron (11.4 percent), fluoride (8.9 percent), gross-alpha radioactivity (6.6 percent), molybdenum (5.7 percent), strontium (3.7 percent), vanadium (3.6 percent), uranium (3.2 percent), and perchlorate (2.4 percent). Inorganic constituents with non-health-based benchmarks were also detected at high RCs in 18.6 percent and at moderate RCs in 16.0 percent of the Desert Region’s primary aquifers. In contrast, organic constituents had high RCs in only 0.3 percent of the Desert Region’s primary aquifers, moderate in 2.0 percent, low in 48.0 percent, and were not detected in 49.7 percent of the primary aquifers in the Desert Region. Of 149 organic constituents analyzed for all six study areas, 42 constituents were detected. Six organic constituents, carbon tetrachloride, chloroform, 1,2-dichloropropane, dieldrin, 1,2-dichloroethane, and tetrachloroethene, were found at moderate RCs in one or more of the grid wells. One constituent, N -nitrosodimethylamine, a special-interest VOC, was detected at a high RC in one well. Thirty-nine organic constituents were detected only at low concentrations. Three organic constituents were frequently detected (in more than 10 percent of samples from grid wells): chloroform, simazine, and deethylatrazine.

California

Status of groundwater quality in the Southern, Middle, and Northern Sacramento Valley study units, 2005-08: California GAMA Priority Basin Project

Groundwater quality in the Southern, Middle, and Northern Sacramento Valley study units was investigated as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study units are located in California’s Central Valley and include parts of Butte, Colusa, Glenn, Placer, Sacramento, Shasta, Solano, Sutter, Tehama, Yolo, and Yuba Counties. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey and the Lawrence Livermore National Laboratory. The three study units were designated to provide spatially-unbiased assessments of the quality of untreated groundwater in three parts of the Central Valley hydrogeologic province, as well as to provide a statistically consistent basis for comparing water quality regionally and statewide. Samples were collected in 2005 (Southern Sacramento Valley), 2006 (Middle Sacramento Valley), and 2007–08 (Northern Sacramento Valley). The GAMA studies in the Southern, Middle, and Northern Sacramento Valley were designed to provide statistically robust assessments of the quality of untreated groundwater in the primary aquifer systems that are used for drinking-water supply. The assessments are based on water-quality data collected by the USGS from 235 wells in the three study units in 2005–08, and water-quality data from the California Department of Public Health (CDPH) database. The primary aquifer systems (hereinafter, referred to as primary aquifers) assessed in this study are defined by the depth intervals of the wells in the CDPH database for each study unit. The quality of groundwater in shallow or deep water-bearing zones may differ from quality of groundwater in the primary aquifers; shallow groundwater may be more vulnerable to contamination from the surface. The status of the current quality of the groundwater resource was assessed by using data from samples analyzed for volatile organic compounds (VOC), pesticides, and naturally occurring inorganic constituents, such as major ions and trace elements. This status assessment is intended to characterize the quality of groundwater resources within the primary aquifers of the three Sacramento Valley study units, not the treated drinking water delivered to consumers by water purveyors. Relative-concentrations (sample concentrations divided by benchmark concentrations) were used for evaluating groundwater quality for those constituents that have Federal or California regulatory or non-regulatory benchmarks for drinking-water quality. A relative-concentration greater than 1.0 indicates a concentration greater than a benchmark. For organic (volatile organic compounds and pesticides) and special-interest (perchlorate) constituents, relative-concentrations were classified as high (greater than 1.0); moderate (equal to or less than 1.0 and greater than 0.1); or low (equal to or less than 0.1). For inorganic (major ion, trace element, nutrient, and radioactive) constituents, the boundary between low and moderate relative-concentrations was set at 0.5. Aquifer-scale proportions were used in the status assessment for evaluating regional-scale groundwater quality. High aquifer-scale proportion is defined as the percentage of the area of the primary aquifers that have a relative-concentration greater than 1.0 for a particular constituent or class of constituents; percentage is based on an areal rather than a volumetric basis. Moderate and low aquifer-scale proportions were defined as the percentage of the primary aquifers that have moderate and low relative-concentrations, respectively. Two statistical approaches—grid-based, which used one value per grid cell, and spatially-weighted, which used the full dataset—were used to calculate aquifer-scale proportions for individual constituents and classes of constituents. High and moderate aquifer-scale proportions were significantly greater for inorganic constituents than organic constituents in all three study units. In the Southern Sacramento Valley study unit, relative-concentrations for one or more inorganic constituents with health-based benchmarks (HBBs) were high in 30 percent (%), moderate in 30%, and low in 40% of the primary aquifer. In the Middle Sacramento Valley study unit, aquifer-scale proportions for inorganic constituents with HBBs were high in 24%, moderate in 38%, and low in 38% of the primary aquifer. Arsenic, boron, and nitrate were detected at high relative-concentrations in the Southern and Middle Sacramento Valley study units. In the Northern Sacramento Valley study unit, high, moderate, and low relative-concentrations of inorganic constituents relative to HBBs were 2.1, 12, and 86% of the primary aquifer, respectively. Arsenic was the only constituent detected at high relative-concentrations. The high aquifer-scale proportions for inorganic constituents with non-health-based benchmarks were 32, 27, and 4.6% of the primary aquifer for the Southern, Middle, and Northern Sacramento Valley study units, respectively. The high aquifer-scale proportions for organic constituents with HBBs were less than 1% in the Southern, Middle, and Northern Sacramento Valley study units. Organic constituents were detected at moderate relative-concentrations in about 3% of the Southern and Middle Sacramento Valley study units and in 1% of the Northern Sacramento Valley study unit. Of the 227 organic constituents analyzed for, 86 were detected, and of those detected, 56 have HBBs. Six organic constituents (atrazine, bentazon, chloroform, simazine, tetrachloroethene, and trichloroethene) were detected in 10% or more of the sampled wells in one or more of the three Sacramento Valley study units.

California

Status and understanding of groundwater quality in the central-eastside San Joaquin Basin, 2006: California GAMA Priority Basin Project

Groundwater quality in the approximately 1,695-square-mile Central Eastside San Joaquin Basin (Central Eastside) study unit was investigated as part of the Priority Basin Project (PBP) of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA PBP was developed in response to the California Groundwater Quality Monitoring Act of 2001, and is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey and the Lawrence Livermore National Laboratory. The GAMA Central Eastside study unit was designed to provide a spatially unbiased assessment of untreated-groundwater quality, as well as a statistically consistent basis for comparing water quality throughout California. During March through June 2006, samples were collected from 78 wells in Stanislaus and Merced Counties, 58 of which were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study unit (grid wells), and 20 of which were sampled to evaluate changes in water chemistry along groundwater-flow paths (understanding wells). Water-quality data from the California Department of Public Health (CDPH) database also were used for the assessment. An assessment of the current status of the groundwater quality included collecting samples from wells for analysis of anthropogenic constituents such as volatile organic compounds (VOCs) and pesticides, as well as naturally occurring constituents such as major ions and trace elements. The assessment of status is intended to characterize the quality of untreated-groundwater resources within the primary aquifer system, not the treated drinking water delivered to consumers by water purveyors. The primary aquifer system (hereinafter, primary aquifer) is defined as that part of the aquifer corresponding to the perforation interval of wells listed in the CDPH database for the Central Eastside study unit. The quality of groundwater in shallower or deeper water-bearing zones may differ from that in the primary aquifer; shallower groundwater may be more vulnerable to surficial contamination. The primary aquifer is represented by the grid wells, of which 90 percent had depths to the tops of their perforations of about 80 to 330 feet and depths to bottom of about 100 to 670 feet. Relative-concentrations (sample concentration divided by benchmark concentration) were used as the primary metric for assessing the status of water quality for those constituents that have Federal and (or) California human health or aesthetic benchmarks. A relative-concentration greater than (>) 1.0 indicates a concentration above a benchmark, and less than or equal to (≤) 1.0 indicates a concentration equal to or below a benchmark. For organic and special interest constituents, relative-concentrations were classified as high (>1.0), moderate (≤1.0 and >0.1), or low (≤0.1). For inorganic constituents, relative-concentrations were classified as high (>1.0), moderate (≤1.0 and >0.5), or low (≤0.5). The threshold between low and moderate classifications was lower for organic and special interest constituents than for inorganic constituents because organic constituents generally are less prevalent and have smaller relative-concentrations than inorganic constituents. Grid-based and spatially-weighted approaches, the latter incorporating data from all CDPH wells, were used to evaluate the proportion of the primary aquifer (aquifer-scale proportions) with high, moderate, or low relative-concentrations. For individual constituents or classes of constituents, the aquifer-scale high proportion is the percentage of the area of the study unit having high relative-concentrations within the depth-zones of the primary aquifer. Aquifer-scale moderate and low proportions are defined similarly. Spatially-weighted aquifer-scale high proportions nearly always fell within the 90-percent confidence interval of grid-based aquifer-scale high proportions, indicating that the grid-based approach yielded statistically equivalent results to the spatially-weighted approach incorporating CDPH data. The status assessment for inorganic constituents showed that inorganic constituents (one or more) were high, relative to human-health benchmarks, in 18.0 percent of the primary aquifer, moderate in 44.0 percent, and low in 38.0 percent. Of inorganic constituents with human-health benchmarks, arsenic, vanadium, and nitrate were detected at high relative-concentrations in 15.6 percent, 3.6 percent, and 2.1 percent, respectively, of the primary aquifer. Of inorganic constituents with secondary maximum contaminant levels (SMCL), manganese, iron, and TDS were detected at high relative-concentrations in 4.5 percent, 2.2 percent, and 1.7 percent, respectively, of the primary aquifer. The status assessment for organic constituents showed that organic constituents (one or more) were high, relative to human-health benchmarks, in a smaller proportion of the primary aquifer (1.2 percent) than inorganic constituents (18.0 percent). Organic constituents had moderate relative-concentrations in 14.3 percent, and had low relative-concentrations or were not detected in 84.5 percent, of the primary aquifer. The proportion of the primary aquifer with high relative-concentrations of organic constituents reflected high proportions of the discontinued soil fumigant 1,2-dibromo-3-chlororopane (DBCP; 1.0 percent) and the solvent tetrachloroethene (PCE; 0.2 percent). Most of the organic and special interest constituents detected in groundwater in the Central Eastside study unit have human-health benchmarks. Of the 205 organic and special interest constituents analyzed for, 36 constituents were detected. Of these constituents, 32 were detected only at low relative-concentrations. Four constituents, chloroform, carbon tetrachloride, DBCP, and perchlorate, were detected at moderate relative-concentrations in grid wells. Nine organic and special-interest constituents were detected frequently (detected in greater than 10 percent of samples): the trihalomethanes chloroform, bromoform, bromodichloromethane, and dibromochloromethane; the solvent PCE; the herbicides atrazine, simazine, and metolachlor, and special-interest constituent perchlorate. An assessment of understanding of the groundwater quality included sampling of understanding wells, some of which were perforated in shallower or deeper portions of the aquifer system than the primary aquifer, and analysis of correlations of groundwater quality with land use, depth, age classification, and other potential explanatory factors. The understanding assessment indicated that the concentrations of many constituents were related to depth and groundwater age. However, concentrations of individual constituents or constituent classes also were sometimes related to geochemical conditions, lateral position in the flow system, or land use. High and moderate relative-concentrations of uranium, nitrate, and total dissolved solids (TDS) were detected in some wells where the tops of perforations are within the upper 200 feet of the aquifer system. In wells with the depth to the top of perforations below this depth, concentrations were low. A similar pattern occurred for the sum of herbicide concentrations. These vertical water-chemistry patterns are consistent with the hydrogeologic setting, in which return flows from agricultural and urban land use are the major source of recharge, and withdrawals for irrigation and urban supply are the major source of discharge, resulting in substantial vertical components of groundwater flow. The decrease in concentrations of many constituents with depth reflects in part that groundwater gets older with depth. Tritium, helium-isotopes, and carbon-14 data were used to classify the predominant age of groundwater samples into three categories: modern (water that has entered the aquifer in the last 50 years), pre-modern (water that entered the aquifer more than 50 years, up to tens of thousands of years, ago), and mixed (mixtures of waters with modern and pre-modern ages). Uranium, nitrate, and herbicide concentrations were significantly higher in groundwater having modern- and mixed-ages than pre-modern ages, indicating that these constituents may be affected by anthropogenic activities in the last 50 years. Other patterns in the distribution of nitrate, uranium, and TDS are evident. Isotopic and geochemical data are consistent with partial denitrification of nitrate in some reducing groundwaters in the western and deeper parts of the flow system. Uranium and TDS concentrations increase from east to west across the valley, along the direction of regional lateral groundwater flow. High and moderate relative-concentrations of arsenic can be attributed to reductive dissolution of manganese or iron oxides, or to desorption by high pH waters. Arsenic concentrations also increased with increasing depth and groundwater age. High to moderate relative-concentrations of vanadium primarily are related to high pH under oxic conditions. The frequency of detections of DBCP was greater in areas with orchard-vineyard land use >40 percent and at depths <200 feet. THMs and solvents were correlated positively with percent urban land use. Herbicide concentrations were correlated negatively with percent natural land use. Perchlorate concentrations were significantly greater in waters having modern and mixed ages than waters having pre-modern ages and were significantly and positively correlated with two land uses—percent orchard/vineyard land use and percent urban land use.

California

Organic compounds in Potomac River water used for public supply near Washington, D.C., 2003-05

Organic compounds studied in this U.S. Geological Survey (USGS) assessment generally are man-made, including, in part, pesticides, solvents, gasoline hydrocarbons, personal care and domestic-use products, and refrigerants and propellants. A total of 85 of 277 compounds were detected at least once among the 25 samples collected approximately monthly during 2003-05 at the intake of the Washington Aqueduct, one of several community water systems on the Potomac River upstream from Washington, D.C. The diversity of compounds detected indicate a variety of different sources and uses (including wastewater discharge, industrial, agricultural, domestic, and others) and different pathways (including treated wastewater outfalls located upstream, overland runoff, and ground-water discharge) to drinking-water supplies. Seven compounds were detected year-round in source-water intake samples, including selected herbicide compounds commonly used in the Potomac River Basin and in other agricultural areas across the United States. Two-thirds of the 26 compounds detected most commonly in source water (in at least 20 percent of the samples) also were detected most commonly in finished water (after treatment but prior to distribution). Concentrations for all detected compounds in source and finished water generally were less than 0.1 microgram per liter and always less than human-health benchmarks, which are available for about one-half of the detected compounds. On the basis of this screening-level assessment, adverse effects to human health are expected to be negligible (subject to limitations of available human-health benchmarks).

Maryland, Virginia

Cleaner cuts: Farmed fish and skin-off fillets are lower in per- and polyfluoroalkyl substances (PFAS)

The ubiquitous occurrence and persistence of per- and polyfluoroalkyl substances (PFAS) in all environmental matrices and biota poses significant health risks to humans. Fish consumption is one of the main pathways humans are exposed to PFAS, yet general patterns in factors influencing PFAS content in fish fillets remain unknown. We assembled information on PFAS content (total quantified PFAS, PFOS, PFOA, and others) in fish fillets to assess the effect of fish origin (marine, freshwater, wild, or farmed), fillet type (skin-on or skin-off), and lipid content on PFAS variation across environments at a global scale. We found that these factors influenced PFAS contents in fish fillets, with concentrations reaching up to 2149 ng•g wet mass −1 (WM). Specifically, PFOS and PFOA in skin-off fillets were consistently lower in farmed than wild fish across freshwater and marine environments. In freshwater wild fish, PFOS was lower in skin-off fillets than skin-on fillets at group and species levels, and multiple PFAS showed an inverse relationship with the lipid content of skin-off fillets, though the slopes showed varying steepness depending on the carbon chain length and functional group of the PFAS. However, the high variability of PFAS content across sites in aquatic environments and the complexity of PFAS bioaccumulation mechanisms in fish tissues may lead to variable results at a fine scale (i.e. , species level); this highlights general patterns of factors influencing PFAS bioaccumulation that may inform the management of human exposure to PFAS through dietary consumption.

Science of the Total Environment

Global recreational consumption of non-native inland fish: Higher economic benefits, but lower nutritional value and climate resilience

Inland recreational fisheries are globally significant leisure pursuits, with well-documented benefits to human health and well-being, but also one of the principal drivers of non-native fish introductions to enhance fishing opportunities, whether for sport or sustenance. In this study, we assess the relative reliance of global inland recreational fisheries on non-native versus native species for harvest. We further examine how this reliance varies by economic and nutritional value as well as the climate vulnerability of the species involved. We demonstrate that, of the 1,325,851 t of inland recreational fishes recreationally harvested for consumption worldwide in 2021, non-native fish were a small proportion (4 %; 53,651 t). On a global scale, non-native fish contributed a net positive 38.2 % economic value to inland recreational harvest. However, they also contributed a net negative −21.9 % nutritional value to inland recreational harvest. Non-native fishes were also more climate vulnerable (i.e., higher average climate vulnerability index values) and thus proportionally increased overall estimates of climate vulnerability with a net positive of 70.9 %. Our results quantitatively demonstrate that non-native species play a more important role in inland consumptive recreational fisheries than their mere harvest volume would suggest. However, many nuances were seen on the continent and country scale, which reflect the complexity of fisher behavior, fish distribution and socio-economic factors. Our findings help unravel the complex effects of non-native species on human activities and underscore the need to evaluate their global impacts holistically.

Science of the Total Environment

Monitoring that matters

Monitoring is a critically important activity for assessing the status of a system, such as the health of an individual, the balance in one's checking account, profits and losses of a business, the economic activity of a nation, or the size of an animal population. Monitoring is especially vital for evaluating changes in the system associated with specific known impacts occurring to the system. It is also valuable for detecting unanticipated changes in the system and identifying plausible causes of such changes, all in time to take corrective action. Before proceeding, we should define "monitoring." One definition of "monitor" (Microsoft Corporation 2009) is "to check something at regular intervals in order to find out how it is progressing or developing." The key point here is "at regular intervals," suggesting a continuing process. Some definitions do not indicate the repetitive nature of monitoring and are basically synonymous with "observing." Most monitoring, in the strict sense of the word, is intended to persist for long periods of time, perhaps indefinitely or permanently. Similarly, Thompson et al. (1998: 3) referred to the "repeated assessment of status" of something, but noted that the term "monitor" is sometimes used for analogous activities such as collecting baseline information or evaluating projects for either implementation or effectiveness. For their purposes, they restricted the term to involve repeated measurements collected at a specified frequency of time units. Let us adopt that definition, recognizing that repeated measurements imply collecting comparable information on each occasion.

Book chapter

Managing macropods without poisoning ecosystems

A recent review of the management of hyperabundant macropods in Australia proposed that expanded professional shooting is likely to lead to better biodiversity and animal welfare outcomes. While the tenets of this general argument are sound, it overlooks one important issue for biodiversity and animal health and welfare: reliance on toxic lead-based ammunition. Lead poisoning poses a major threat to Australia's wildlife scavengers. Current proposals to expand professional macropod shooting would see tonnes of an extremely toxic and persistent heavy metal continue to be introduced into Australian environments. This contrasts with trends in many other countries, where lead ammunition is, through legislation or voluntary programs, being phased out. Fortunately, there are alternatives to lead ammunition that could be investigated and adopted for improved macropod management. A transition to lead-free ammunition would allow the broad environmental and animal welfare goals desired from macropod management to be pursued without secondarily and unintentionally poisoning scavengers. Through this article, we hope to increase awareness of this issue and encourage discussion of this potential change.

Ecological Management & Restoration

Pathogenic human viruses in coastal waters

This review addresses both historical and recent investigations into viral contamination of marine waters. With the relatively recent emergence of molecular biology-based assays, a number of investigations have shown that pathogenic viruses are prevalent in marine waters being impacted by sewage. Research has shown that this group of fecal-oral viral pathogens (enteroviruses, hepatitis A viruses, Norwalk viruses, reoviruses, adenoviruses, rotaviruses, etc.) can cause a broad range of asymptomatic to severe gastrointestinal, respiratory, and eye, nose, ear, and skin infections in people exposed through recreational use of the water. The viruses and the nucleic acid signature survive for an extended period in the marine environment. One of the primary concerns of public health officials is the relationship between the presence of pathogens and the recreational risk to human health in polluted marine environments. While a number of studies have attempted to address this issue, the relationship is still poorly understood. A contributing factor to our lack of progress in the field has been the lack of sensitive methods to detect the broad range of both bacterial and viral pathogens. The application of new and advanced molecular methods will continue to contribute to our current state of knowledge in this emerging and

Clinical Microbiology Reviews

Isolation and characterization of the fall Chinook aquareovirus

Background Salmon are paramount to the economy, ecology, and history of the Pacific Northwest. Viruses constitute one of the major threats to salmon health and well-being, with more than twenty known virus species that infect salmon. Here, we describe the isolation and characterization of the fall Chinook aquareovirus, a divergent member of the species Aquareovirus B within the family Reoviridae . Methods The virus was first found in 2014 as part of a routine adult broodstock screening program in which kidney and spleen tissue samples from healthy-appearing, adult fall Chinook salmon ( Oncorhynchus tshawytscha ) returning to a hatchery in Washington State produced cytopathic effects when inoculated onto a Chinook salmon embryo cell line (CHSE-214). The virus was not able to be confirmed by an RT-PCR assay using existing aquareovirus pan-species primers, and instead was identified by metagenomic next-generation sequencing. Metagenomic next-generation sequencing was used to recover the full genome and completed using 3′ RACE. Results The genome of the fall Chinook aquareovirus contains 11 segments of double-stranded RNA totaling 23.3 kb, with each segment flanked by the canonical sequence termini found in the aquareoviruses. Sequence comparisons and a phylogenetic analysis revealed a nucleotide identity of 63.2% in the VP7 gene with the Green River Chinook virus, placing the new isolate in the species Aquareovirus B . A qRT-PCR assay was developed targeting the VP2, which showed rapid growth of the isolate during the initial 5 days in culture using CHSE-214 cells. Conclusions This sequence represents the first complete genome of an Aquareovirus B species. Future studies will be required to understand the potential pathogenicity and epidemiology of the fall Chinook aquareovirus.

Virology Journal

Phosphorus and the Chesapeake Bay: Lingering issues and emerging concerns for agriculture

Hennig Brandt's discovery of phosphorus (P) occurred during the early European colonization of the Chesapeake Bay region. Today, P, an essential nutrient on land and water alike, is one of the principal threats to the health of the bay. Despite widespread implementation of best management practices across the Chesapeake Bay watershed following the implementation in 2010 of a total maximum daily load (TMDL) to improve the health of the bay, P load reductions across the bay's 166,000‐km 2 watershed have been uneven, and dissolved P loads have increased in a number of the bay's tributaries. As the midpoint of the 15‐yr TMDL process has now passed, some of the more stubborn sources of P must now be tackled. For nonpoint agricultural sources, strategies that not only address particulate P but also mitigate dissolved P losses are essential. Lingering concerns include legacy P stored in soils and reservoir sediments, mitigation of P in artificial drainage and stormwater from hotspots and converted farmland, manure management and animal heavy use areas, and critical source areas of P in agricultural landscapes. While opportunities exist to curtail transport of all forms of P, greater attention is required toward adapting P management to new hydrologic regimes and transport pathways imposed by climate change.

Delaware, Maryland, Virginia

Water quality at Miami International Airport, Miami, Florida, 1971–72

The quality of water, sediment, and biota was determined at four sites in canals and drainage ditches at Miami International Airport (MIA) during high- and low-water periods and during summer and winter 1971–72. Concentrations of common ions, such as calcium, sodium, chloride, and magnesium, tended to be above average for fresh water because of periodic salt-water intrusion. Nitrogen, phosphorus, and pesticides were in higher concentrations than typical for undisturbed areas of south Florida, but not higher than usual for the urban coastal area, so it is not known to what extent these chemicals are attributable to surrounding urbanization. Heavy metals, oil and grease, and PCB's (polychlorinated biphenyls) were the best indicators of the effects of MIA on water quality. Concentations of the above were quite variable, high values for each were recorded and were probably associated with recent discharges from industrial sources. Arsenic, lead, iron, and chromium all exceeded, in one or more samples, the U.S. Public Health Service's recommended upper limits for metals in water. Only iron normally exceeds these standards in the natural waters of south Florida. PCB's were detected in most samples and were in concentrations up to 1,000 micrograms per kilogram in fish. In addition to pesticides and PCB's, another group of persistant chlorinated compounds, PCN's (polychlorinated naphthalenes) were detected in water, sediment, and fish. This is the first known detection of these compounds in the environment.

Open-File Report

Quality of water and sediment in streams affected by historical mining, and quality of Mine Tailings, in the Rio Grande/Rio Bravo Basin, Big Bend Area of the United States and Mexico, August 2002

The U.S. Geological Survey, in cooperation with the International Boundary and Water Commission - U.S. and Mexican Sections, the National Park Service, the Texas Commission on Environmental Quality, the Secretaria de Medio Ambiente y Recursos Naturales in Mexico, the Area de Proteccion de Flora y Fauna Canon de Santa Elena in Mexico, and the Area de Proteccion de Flora y Fauna Maderas del Carmen in Mexico, collected samples of stream water, streambed sediment, and mine tailings during August 2002 for a study to determine whether trace elements from abandoned mines in the area in and around Big Bend National Park have affected the water and sediment quality in the Rio Grande/Rio Bravo Basin of the United States and Mexico. Samples were collected from eight sites on the main stem of the Rio Grande/Rio Bravo, four Rio Grande/Rio Bravo tributary sites downstream from abandoned mines or mine-tailing sites, and 11 mine-tailing sites. Mines in the area were operated to produce fluorite, germanium, iron, lead, mercury, silver, and zinc during the late 1800s through at least the late 1970s. Moderate (relatively neutral) pHs in stream-water samples collected at the 12 Rio Grande/Rio Bravo main-stem and tributary sites indicate that water is well mixed, diluted, and buffered with respect to the solubility of trace elements. The highest sulfate concentrations were in water samples from tributaries draining the Terlingua mining district. Only the sample from the Rough Run Draw site exceeded the Texas Surface Water Quality Standards general-use protection criterion for sulfate. All chloride and dissolved solids concentrations in water samples were less than the general-use protection criteria. Aluminum, copper, mercury, nickel, selenium, and zinc were detected in all water samples for which each element was analyzed. Cadmium, chromium, and lead were detected in samples less frequently, and silver was not detected in any of the samples. None of the sample concentrations of aluminum, cadmium, chromium, nickel, selenium, and zinc exceeded the Texas Surface Water Quality Standards criteria for aquatic life-use protection or human health. The only trace elements detected in the water samples at concentrations exceeding the Texas Surface Water Quality Standards criterion for human health (fish consumption use) was lead at one site and mercury at 10 of 12 sites. Relatively high mercury concentrations distributed throughout the area might indicate sources of mercury in addition to abandoned mining areas. Streambed-sediment samples were collected from 12 sites and analyzed for 44 major and trace elements. In general, the trace elements detected in streambed-sediment samples were low in concentration, interpreted as consistent with background concentrations. Concentrations at two sites, however, were elevated compared to Texas Commission on Environmental Quality criteria. Concentrations of antimony, arsenic, cadmium, lead, silver, and zinc in the sample from San Carlos Creek downstream from La Esperanza (San Carlos) Mine exceeded the Texas Commission on Environmental Quality screening levels for sediment. The sample from Rough Run Draw, downstream from the Study Butte Mine, also showed elevated concentrations of arsenic, cadmium, and lead, but these concentrations were much lower than those in the San Carlos Creek sample and did not exceed screening levels. Elevated concentrations of multiple trace elements in streambed-sediment samples from San Carlos Creek and Rough Run Draw indicate that San Carlos Creek, and probably Rough Run Draw, have been adversely affected by mining activities. Fourteen mine-tailing samples from 11 mines were analyzed for 25 major and trace elements. All trace elements except selenium and thallium were detected in one or more samples. The highest lead concentrations were detected in tailings samples from the Boquillas, Puerto Rico, La Esperanza (San Carlos), and Tres Marias Mines, as might be expected because the tailings ar

Scientific Investigations Report

Water balance monitoring for two bioretention gardens in Omaha, Nebraska, 2011–14

Bioretention gardens are used to help mitigate stormwater runoff in urban settings in an attempt to restore the hydrologic response of the developed land to a natural predevelopment response in which more water is infiltrated rather than routed directly to urban drainage networks. To better understand the performance of bioretention gardens in facilitating infiltration of stormwater in eastern Nebraska, the U.S. Geological Survey, in cooperation with the Douglas County Environmental Services and the Nebraska Environmental Trust, assessed the water balance of two bioretention gardens located in Omaha, Nebraska by monitoring the amount of stormwater entering and leaving the gardens. One garden is on the Douglas County Health Center campus, and the other garden is on the property of the Eastern Nebraska Office on Aging. For the Douglas County Health Center, bioretention garden performance was evaluated on the basis of volume reduction by comparing total inflow volume to total outflow volume. The bioretention garden reduced inflow volumes from a minimum of 33 percent to 100 percent (a complete reduction in inflow volume) depending on the size of the event. Although variable, the percent reduction of the inflow volume tended to decrease with increasing total event rainfall. To assess how well the garden reduces stormwater peak inflow rates, peak inflows were plotted against peak outflows measured at the bioretention garden. Only 39 of the 255 events had any overflow, indicating 100 percent peak reduction in the other events. Of those 39 events having overflow, the mean peak reduction was 63 percent. No overflow events were recorded at the bioretention garden at the Eastern Nebraska Office on Aging; therefore, data were not available for an event-based overflow analysis.Monitoring period summary of the water balance at both bio-retention gardens indicates that most of the stormwater in the bioretention gardens is stored in the subsurface. Evapotranspiration was attributed to a small percentage of the outputs on an annual basis (3 percent at Douglas County Health Center site and 5 percent at Eastern Nebraska Office onAging site), which indicates that vegetative water uptake is not a primary factor in the water budget.

Nebraska

Groundwater-quality data for the Madera/Chowchilla–Kings shallow aquifer study unit, 2013–14: Results from the California GAMA Program

Groundwater quality in the 2,390-square-mile Madera/Chowchilla–Kings Shallow Aquifer study unit was investigated by the U.S. Geological Survey from August 2013 to April 2014 as part of the California State Water Resources Control Board Groundwater Ambient Monitoring and Assessment Program’s Priority Basin Project. The study was designed to provide a statistically unbiased, spatially distributed assessment of untreated groundwater quality in the shallow aquifer systems of the Madera, Chowchilla, and Kings subbasins of the San Joaquin Valley groundwater basin. The shallow aquifer system corresponds to the part of the aquifer system generally used by domestic wells and is shallower than the part of the aquifer system generally used by public-supply wells. This report presents the data collected for the study and a brief preliminary description of the results. Groundwater samples were collected from 77 wells and were analyzed for organic constituents, inorganic constituents, selected isotopic and age-dating tracers, and microbial indicators. Most of the wells sampled for this study were private domestic wells. Unlike groundwater from public-supply wells, the groundwater from private domestic wells is not regulated for quality in California and is rarely analyzed for water-quality constituents. To provide context for the sampling results, however, concentrations of constituents measured in the untreated groundwater were compared with regulatory and non-regulatory benchmarks established for drinking-water quality by the U.S. Environmental Protection Agency, the State of California, and the U.S. Geological Survey. Of the 319 organic constituents assessed in this study (90 volatile organic compounds and 229 pesticides and pesticide degradates), 17 volatile organic compounds and 23 pesticides and pesticide degradates were detected in groundwater samples; concentrations of all but 2 were less than the respective benchmarks. The fumigants 1,2-dibromo-3-chloropropane (DBCP) and 1,2-dibromoethane (EDB) were detected at concentrations above their respective regulatory benchmarks in samples from a total of four wells. Most detections of inorganic constituents were at concentrations or activities less than the respective benchmark levels. Five inorganic constituents were detected in groundwater samples from one or more wells at concentrations or activities greater than their respective regulatory, health-based benchmarks: arsenic, uranium, nitrate, adjusted gross alpha particle activity, and gross beta particle activity. Four inorganic constituents were detected in samples from one or more wells at concentrations or activities greater than their respective non-regulatory, health-based benchmarks: manganese, molybdenum, vanadium, and radon-222. Three inorganic constituents were detected in groundwater samples from one or more wells at concentrations greater than their respective non-regulatory, aesthetic-based benchmarks: iron, sulfate, and total dissolved solids. Microbial indicators ( Escherichia coli , total coliform, and enterococci) were analyzed for presence or absence. The presence of Escherichia coli ( E. coli ) was not detected; the presence of total coliform was detected in samples from 10 of the 72 grid wells for which it was analyzed, and the presence of enterococci was detected in samples from 5 of the 73 grid wells analyzed.

California

Island of misfit tortoises: Waif gopher tortoise health assessment following translocation

Translocation, the intentional movement of animals from one location to another, is a common management practice for the gopher tortoise ( Gopherus polyphemus ). Although the inadvertent spread of pathogens is a concern with any translocation effort, waif tortoises—individuals that have been collected illegally, injured and rehabilitated or have unknown origins—are generally excluded from translocation efforts due to heightened concerns of introducing pathogens and subsequent disease to naïve populations. However, repurposing these long-lived animals for species recovery is desirable when feasible, and introducing waif tortoises may bolster small populations facing extirpation. The objective of this study was to assess the health of waif tortoises experimentally released at an isolated preserve in Aiken County, SC, USA. Our assessments included visual examination, screening for 14 pathogens using conventional or quantitative polymerase chain reaction (qPCR) and haematological evaluation. Of the 143 individuals assessed in 2017 and 2018, most individuals (76%; n = 109 of 143) had no overt clinical evidence of disease and, when observed, clinical findings were mild. In both years, we detected two known tortoise pathogens, Mycoplasma agassizii and Mycoplasma testudineum , at a prevalence of 10.2–13.9% and 0.0–0.8%, respectively. Additionally, we found emydid Mycoplasma , a bacterium commonly found in box turtles ( Terrapene spp . ), in a single tortoise that showed no clinical evidence of infection. The presence of nasal discharge was an important, but imperfect, predictor of Mycoplasma spp. infection in translocated tortoises. Hemogram data were comparable with wild populations. Our study is the first comprehensive effort to assess pathogen prevalence and hemogram data of waif gopher tortoises following translocation. Although caution is warranted and pathogen screening necessary, waif tortoises may be an important resource for establishing or augmenting isolated populations when potential health risks can be managed.

Conservation Physiology