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Mineral chemistry perspective on remobilization of stored magma at Kamakai'a Hills, Southwest Rift Zone of Kilauea, Island of Hawai'i, USA

Differentiated magmas stored in the rift zones of Kīlauea have received more attention in recent years following eruption of andesite during the early phase of 2018 lower East Rift Zone activity. Despite this growing interest, some of the most voluminous eruptions of differentiated rift zone magmas remain poorly studied. One such eruption, and the most voluminous exposed differentiated flow field at Kīlauea, is the Kamakaiʻa Hills. This eruption took place in the Southwest Rift Zone of Kīlauea, a region that is hypothesized to contain a long-lived rift zone reservoir. The Kamakaiʻa Hills flow field encompasses >250 × 10 6 m 3 of basaltic andesite and basalt compositions with a mineral assemblage of orthopyroxene + clinopyroxene + plagioclase during its early ʻaʻā phase and clinopyroxene + plagioclase + olivine during its late pāhoehoe phase. To better understand storage conditions and magma accumulation, this study focuses on major, minor, and trace elements from the mineral assemblage present within the early ʻaʻā and late pāhoehoe phases. The diversity of clinopyroxene and plagioclase compositions within the early ʻaʻā and late pāhoehoe phases, as well as diverse compositions of plagioclase and orthopyroxene within the early ʻaʻā phase, suggest multiple magma bodies and limited pre-eruption magma mixing within the broader Kamakaiʻa Hills reservoir. Oscillatory zoning patterns (particularly in clinopyroxene) imply processes such as recharge events, magma mixing or mingling, or convection within a differentially cooling, chemically stratified reservoir over protracted time intervals, whereas only limited resorbed mineral textures indicate incomplete mixing of heat and chemically distinct magmas during the dike intrusion that triggered the eruption. Mineral-mineral and mineral-melt thermobarometry indicate predominantly shallow (≤2.5 km depth) crustal storage conditions of the cooled, differentiated magma (∼1100 °C and cooler for the basaltic andesites) to hotter temperatures for the basalts (all >1100 °C). Despite the known large standard errors estimated for mineral-melt and mineral-mineral barometry (10s to >100 MPa), the calculated pressures and depths broadly correspond with earthquake swarm depths beneath the Kamakaiʻa Hills, and drill core and fluid inclusion barometry storage depths of differentiated magmas within the lower East Rift Zone. The Kamakaiʻa Hills differentiated magmas have H 2 O contents (∼0.5 wt%, using plagioclase-melt hygrometry) equivalent to typical Kīlauea basalts. Our data and interpretations demonstrate a complex, long-lived rift zone storage system that consisted of multiple magma bodies and was mobilized into eruption through intrusion of a hotter and more primitive summit-derived (uprift) magma.

Hawaii

A multidisciplinary approach that considers occurrence, geochemistry, bioavailability, and toxicity to prioritize critical minerals for environmental research

Critical minerals (or critical elements) are minerals or elements that are essential to global security and development and have supply chains vulnerable to disruption. In general, knowledge of the environmental behavior and health effects of critical elements is needed to support the development of safe and environmentally responsible supplies. This knowledge includes identifying potential consequences of increased critical element production and use, alternative critical element sources such as mine wastes, and adverse effects of critical elements on ecosystem condition and organismal health. Here we identify significant data gaps in the understanding of critical elements in surficial and aquatic environments, and the need, given the large number of commodities (50) identified on the 2022 critical minerals list for the United States, for an approach to prioritize them for study of their environmental fate and effects. We propose a multidisciplinary approach for this prioritization, considering measures of occurrence, geochemistry, bioavailability, and toxicity. We describe relatively easy-to-obtain metrics for each of these topic areas and demonstrate the utility of this integrated prioritization approach using indium and zinc as examples. This approach facilitates prioritizing research with a focus on those critical elements that are most mobile in the environment, bioavailable, toxic, or simply lacking data in these categories.

Environmental Science & Technology

Hyperspectral (VNIR-SWIR) analysis of roll front uranium host rocks and industrial minerals from Karnes and Live Oak Counties, Texas Coastal Plain

VNIR-SWIR (400–2500 nm) reflectance measurements were made on the surfaces of various cores, cuttings and sample splits of sedimentary rocks from the Tertiary Jackson Group, and Catahoula, Oakville and Goliad Formations. These rocks vary in composition and texture from mudstone and claystone to sandstone and are known host rocks for roll front uranium occurrences in Karnes and Live Oak Counties, Texas. Spectral reflectance profiles, 569 in total, were reduced to 125 representative spectral signatures, which were analyzed using the U.S. Geological Survey's (USGS) Material Identification and Characterization Algorithm (MICA). MICA uses an automated continuum-removal procedure together with a least-squares linear regression to determine the fit of observed sample spectral absorption features to those of reference mineral standards in a spectral library. The reference minerals include various clay, mica, carbonate, ferric and ferrous iron minerals and their mixtures. In addition, absorption feature band-depth analysis was done to identify rock surfaces exhibiting absorption features related to uranium and zeolite minerals, which were not included in the command files used to execute MICA. Rocks from each of the four geologic units produced broadly similar spectral signatures as a result of comparable mineral compositions, but there were some notable differences. For example, Ca- and Na-montmorillonite was matched most frequently to the spectral absorption features in 2-μm (∼2000–2500 nm) wavelengths, while goethite occurred often at 1-μm (∼400–1000 nm) wavelengths. The latter is related to limonitic iron-staining in and around oxidized zones of the uranium roll front as described in previous papers. Rocks of the Jackson Group differed from those of the Catahoula, Oakville and Goliad units in that the former exhibited spectral features we interpret as being due to the presence of lignite-bearing mudstone layers. Goliad rocks exhibit spectral features related to dolomite, gypsum, anhydrite, and an unidentified green clay mineral that is possibly glauconite . Jackson Group rocks also exhibit weak but well-resolved absorption features at 964 and 1157 nm related to either or both zeolite minerals clinoptilolite and heulandite. These zeolite minerals and a few spectra exhibiting hydrous silica absorption features are indicative of alteration of volcanic glass in tuffaceous mudstone and claystone layers. A few sample spectra exhibited strong absorption features at around 1135 nm related to the uranium mineral coffinite. Both the 1135 nm coffinite and 1157 nm zeolite absorption features overlap somewhat, potentially making them difficult to distinguish without additional hyperspectral field, laboratory or remote sensing data. The results of this study were compared to mixtures of minerals described for ore, gangue and alteration minerals in deposit models for sandstone-hosted uranium, sedimentary bentonite and sedimentary zeolite. Use of these spectra can help facilitate mapping of both waste materials from the legacy mining of the above commodities, as well as future exploration and resource assessment activities.

Texas

Synergy between geology and geophysics in graphite mineral resource assessment

Graphite is designated as a critical mineral by the U.S. Government due to its essential role in modern technology and its vulnerability to supply chain disruption. To evaluate domestic graphite resources, the U.S. Geological Survey (USGS) conducted two airborne electromagnetic (AEM) surveys as part of the Earth Mapping Resources Initiative (Earth MRI) over prospective areas in the southern Appalachians of Alabama and the Seward Peninsula of Alaska. These surveys aimed to refine areas of interest by revealing subsurface electrical resistivity patterns indicative of graphite-bearing rocks. The results of the AEM surveys were integrated with existing geological knowledge and supplemented by field observations to assess the likelihood of undiscovered resources in these regions. This multidisciplinary approach combined geophysical techniques with traditional geological methods, enhancing the understanding of graphite potential in areas that may have been previously overlooked. The findings from this initiative are expected to contribute significantly to the ongoing efforts to secure a reliable domestic supply of graphite, thereby reducing import reliance and supporting national interests in mineral resource management.

Conference Paper

Alteration mapping in granitic gneiss using handheld geophysical and geochemical instruments: Implications for iron oxide-apatite and rare earth elements exploration

The Adirondack Mountains of New York, U.S.A. contain iron oxide-apatite (IOA) mineral deposits with variable concentrations of rare earth elements (REE). The IOA mineral deposits are typically hosted in the Lyon Mountain Granite Gneiss and are spatially correlated with extensive Na metasomatism (albitization) of the surrounding country rocks, although some mineral deposits also occur in metagabbro, paragneiss, and anorthosite hosts. The location of albitization zones is key to finding new IOA mineral deposits and better understanding the mineralization processes associated with their genesis. However, the Na alteration zones are generally not visibly identifiable in outcrop or hand specimens because the color and textural changes are subtle and are thus difficult to map. Here, we discuss the results from testing two spectroscopic techniques (handheld, field gamma-ray spectroscopy, and portable X-ray fluorescence (pXRF)) to characterize albitization zones surrounding IOA mineral deposits. The gamma-ray and pXRF spectrometers successfully distinguished the relative intensity of alteration in the Lyon Mountain Granite Gneiss based on the K abundance. The measured K content decreases towards the IOA mineral deposits, and the magnitude and width of the gradient are similar along the strike of each mineral deposit. Elevated Th and U values are present in host rocks adjacent to REE-bearing IOA mineral deposits. The pXRF and gamma-ray spectrometer K values are remarkably consistent with laboratory-based, whole-rock XRF compositional data and, therefore, useful for semi-quantitative analysis. Notably, albitization aureoles are consistent around REE-rich and REE-poor mineral deposits, suggesting that saline fluids are essential for the petrogenesis of IOA mineral deposits but may not be critical to REE mineralization. Ultimately, this study demonstrates the utility of handheld gamma-ray and pXRF spectrometry for identifying otherwise cryptic albitization gradients associated with IOA mineral deposits in granitic gneiss.

New York

Evidence of mineral alteration in a salt marsh subterranean estuary: Implications for carbon and trace element cycling

Subterranean estuaries (STE) in salt marshes are biogeochemically active zones where interactions between terrestrial groundwater and seawater drive complex cycling of carbon and trace elements, influenced by mineral dissolution. These systems, characterized by fine-grained organic-rich peat overlying permeable coastal aquifers, play a crucial role as a blue carbon sink, yet their geochemical dynamics remain poorly understood. We investigated dissolved trace elements, carbon, silica, and radium isotopes in a salt marsh STE (Sage Lot Pond, Waquoit Bay, MA) over seasonal and annual cycles. Our results reveal that groundwater and estuarine water circulation through marsh peat and aquifer sediments leads to enrichments of dissolved organic and inorganic carbon (DOC and DIC), Si, Ba, and Mn, with variable source/sink behavior of Fe and net removal of U. Submarine groundwater discharge dominated Ba fluxes, whereas pore water drainage from marsh peat acted as the main sink for U and source of Si. Fe cycling was variable, with terrestrial Fe largely removed as groundwater passed through the STE, consistent with Fe-sulfide and amorphous phase formation. Radium isotope ratios identified two distinct subsurface flow pathways, influenced by metal-oxide cycling and organic matter breakdown. Si production was decoupled from DIC, suggesting Si originates from mineral alteration, whereas DIC results from both mineral weathering and microbial respiration. Silicate mineral alteration, coupled with marsh pore water drainage, accounts for up to 16% of annual DIC exports (66 g C m −2 y −1 ), highlighting the importance of STEs in coastal carbon and trace element cycling, especially as marshes face environmental change.

Massachusetts

Developments in African industrial minerals for renewable energy

Introduction Africa is emerging as a leading source for minerals used in the manufacture of batteries for electric vehicles and in other renewable energy applications. New graphite, lithium, and rare-earth mines have or could be opened in African countries from 2017 through 2026. Estimates of production capacities for graphite, lithium, and rare-earth mines for 2023 and beyond are based upon supply-side assumptions, such as announced plans for new capacity construction and bankable feasibility studies, as well as projected trends that could affect current producing facilities in 2023 and planned new facilities projected to come online by 2026. Forward-looking information, including estimates of future production capacities, graphite flake distributions, and timing of the start of operations, are subject to risk factors and uncertainties that could cause actual events or results to differ significantly from expected outcomes. Projects listed in this report are presented as an indication of industry plans and are not a U.S. Geological Survey (USGS) prediction of what will take place. Only projects with planned startup dates are included in this report; ther graphite, lithium, and rare-earth projects in Africa without startup dates were known to be in various stages of development but are not included in this fact sheet.

Fact Sheet

Paleoproterozoic vein graphite mineralization caused by decarbonation in the Ruby Range, Montana, USA

Hydrothermal graphite veins are a possible source for modern battery materials and require better understanding of their carbon source(s) and absolute timing to develop mapable criteria for exploration models. We present new observations of graphite vein and alteration paragenesis and U-Pb LA-ICP-MS titanite age data from the Ruby prospect, Montana, USA, that constrain mineralization timing and source. The graphite veins cut high-temperature metamorphic rocks of the lower Christensen Range suite and are associated with intense diopside (Di0.69Hd0.27Jo0.04) alteration of marble. The oldest titanite ages in fresh marble and partially altered calc-silicate gneiss are ca. 2,500 – 2,450 Ma, show elevated REE values, and Eu/Eu* <1.5, consistent with growth during early regional metamorphism. Titanite in diopside-graphite alteration, interpreted as part of the hydrothermal vein-forming episode, cluster around 1,750 Ma, are characterized by lower REE values, and show Eu/Eu* >2; suggesting a low fO 2 fluid generated from metamorphism during the Big Sky orogeny. Our paragenetic observations and titanite ages indicate graphite vein formation via skarnoid decarbonation reactions in marble late in regional orogenesis. Granulite-facies, carbonate-bearing, supracrustal rock terranes are thus favorable for hydrothermal graphite vein deposits.

Montana

AAPG Energy and Minerals Division Tight Oil and Gas Committee Activities and Commodity Report for 2021-2022: Tuscaloosa Marine Shale, Gulf Coast basin, Louisiana and Mississippi

The Upper Cretaceous Tuscaloosa marine shale (TMS) potential production area encompasses 20.4 million acres across central Louisiana (LA), southern Mississippi (MS), southwestern Alabama (AL), and a small southwestern section of the Florida panhandle (Hackley et al., 2018). It remains a minor and largely undeveloped unconventional shale oil play with production from the TMS confined along the east-west LA-MS State boundary (Fig. 1). The mean undiscovered, technically recoverable resources in the TMS are estimated at 1.5 billion barrels of oil and 4.6 trillion cubic feet of gas (Hackley et al., 2018). Geochemical analyses of source rock solvent extracts and oil samples indicate that, in the play area, the TMS is the primary source of shale oil produced from the TMS as well as of accumulated oils in the underlying conventional reservoirs of the lower Tuscaloosa (Hackley et al., 2020). The API gravity of TMS oils ranges from approximately 34 to 46 degrees (Hackley et al., 2020; Croke et al., 2020).

AAPG Wiki

A time-space model of graphite mineral systems

Increasing demand for graphite in energy storage systems warrants review of graphite ore genesis in a mineral systems framework. Orogenic graphite encompasses the metamorphic and orogenic mineral systems that produce flake graphite and hydrothermal vein (lump and chip) graphite deposits, respectively. A common feature of orogenic graphite deposits is an association with upper amphibolite- to granulite-facies metasedimentary rocks in continent-continent or continent-island arc collisional orogens. Orogenic flake graphite deposits form primarily through graphitization of organic carbon during regional metamorphism, but strain localization and partial melting of pelitic protoliths are likely important processes for graphite grade and quality enrichment. Orogenic vein graphite deposits precipitate from hydrothermal fluids, possibly derived from metamorphism or anatexis at depth. Decarbonation reactions in mixed calcareous-carbonaceous metasedimentary sequences are the most likely carbon sources for the veins. In contrast, intrusion-related graphite includes magmatic-hydrothermal and metamorphic mineral systems that form primarily in continental arc settings via the interaction of magmas with carbonaceous sedimentary packages. Magmatic-hydrothermal flake graphite deposits are hosted in plutonic and volcanic rocks, and result from the exsolution of CO 2 -CH 4 -rich fluids from melts contaminated by such packages. Contact metamorphism of carbonaceous sedimentary rocks by plutons produces some microcrystalline (amorphous) graphite deposits, including many in China. Compilation of geologic data from known graphite deposits globally suggests that pulses of carbon deposition in the Paleoproterozoic, Mesoproterozoic, and Neoproterozoic provided source carbon material. Subsequent supercontinent orogenesis at ca. 2,100 to 1,700 Ma (Columbia), ca. 1,300 to 1,000 Ma (Rodinia), and ca. 650 to 500 Ma (Gondwana) resulted in the genesis of orogenic flake and vein graphite deposits, where favorable geologic components overlapped with organic ± carbonate carbon-rich strata. Cryogenian deposition of graphite protoliths and Cryogenian – Cambrian metamorphic mineralization account for nearly 75% of all known resources globally and coincide with profound carbon isotope excursions and climate variability, implying a link with the global carbon budget. Comparatively few graphite deposits are associated with Pangea-forming orogens, attributed to less exhumation and/or denudation. High-temperature metasedimentary belts containing organic carbon-rich protoliths are most favorable for hosting orogenic flake graphite deposits, whereas sequences that also contain carbonate protoliths are favorable for orogenic graphite veins. Continent-scale orogenic belts may host both deposit types along with vanadium deposits. Use of a time-space mineral systems framework for graphite deposits can improve exploration models needed to ensure future supply of this critical mineral and provide insights into Earth’s long-term carbon cycle.

Mineralium Deposita

Petrogenesis and mineralization potential of spinifex komatiitic basalts in the Bradley Peak greenstone terrane, Wyoming Province

Komatiitic volcanic rocks are important hosts of Ni sulfide mineralization and record early Earth evolution; however, those in the well-studied Archean Wyoming Province have received little attention. Here, we elucidate the timing and petrogenesis of the Bradley Peak komatiitic volcanic rocks using field and textural observations, geochronology, and geochemistry. Detrital and igneous zircon U-Pb ages for two samples from previously undated units support published age determinations, placing the eruption age at 2.72 Ga. Stratigraphy of the volcanic flows was mapped and 36 samples including cumulates, greenschists, and spinifex-textured rocks were collected. Whole-rock geochemistry was used to classify the spinifex-textured samples as Al-undepleted komatiitic basalts (11–17 wt% MgO). Platinum-group element concentrations (n = 25) are like those in global Al-undepleted komatiitic basalts, and PGE/Ti ratios do not indicate the volcanic flows likely host sulfide mineralization. Initial ε Nd values of −0.5 to +4.7 (n = 16), indicate that these lavas were derived from a depleted mantle source and have negligible evolved crust contamination. The primary magma to the komatiitic basalt flows is estimated to have had 19 wt% MgO and be derived from ∼15 to 25 % mantle partial melting at 3–4 GPa. Trace element chemistry and thermodynamic modeling suggest the primary melt assimilated local banded iron formation. Although the Bradley Peak komatiitic basalts do not contain positive evidence of magmatic sulfide deposits, depleted Au in the flows suggests they could be source rocks for nearby orogenic gold deposits.

Wyoming

System characterization report on the Earth Surface Mineral Dust Source Investigation (EMIT) sensor

Executive Summary This report addresses system characterization of the Earth Surface Mineral Dust Source Investigation (EMIT) sensor, an imaging spectrometer developed by the National Aeronautics and Space Administration. This report is part of a series of system characterization reports produced and delivered by the U.S. Geological Survey Earth Resources Observation and Science Cal/Val Center of Excellence. These reports present and detail the methodology and procedures for characterization; present technical and operational information about the specific sensing system being evaluated; and provide a summary of test measurements, data retention practices, data analysis results, and conclusions. The Earth Resources Observation and Science Cal/Val Center of Excellence system characterization team completed data analyses to characterize the geometric (interior and exterior) and radiometric performances. Results of these analyses indicate that the EMIT sensor has a band-to-band geometric performance in the range of −0.355 to 0.210 pixel with a few exceptions of shortwave infrared channels. Geometric offset relative to the Landsat 8 Operational Land Imager ranged from −15.966 meters (−0.266 pixel) to 43.844 meters (0.731 pixel). Offset of a radiometric comparison ranged from −0.016 to 0.025, and slope of a radiometric comparison ranged from 0.837 to 0.985. EMIT agreed with Radiometric Calibration Network measurements within 5 percent across most of the spectral channels.

Open-File Report

From critical minerals to food security, the benefits of data collaboration

The volume of data in the public geoscience sphere is rapidly and continually expanding. At Geoscience Australia (GA) we saw an over 500% increase in data points within our relational databases between 2018 and 2024, over the life of the Exploring for the Future (EFTF) program. With the Resourcing Australia’s Prosperity initiative, a continued increase in data quantity will be seen for the next 10 to 35 years. At the same time, a broadening audience for geoscience data is increasing the desire to enhance the diversity of delivery streams. This ranges from data-dense highly technical outputs for geoscience specialists to curated interpretive products for people who are non-geoscientists. Development of these curated outputs has contributed to our awareness of the need for data to be collected and compiled in a way that ensures its reuse, with a focus on quality metadata and data provenance.

Conference Paper

Development of vegetation based soil quality indices for mineralized terrane in arid and semi-arid regions

Soil quality indices (SQIs) are often management driven and attempt to describe key relationships between above- and below-ground parameters. In terrestrial systems, indices that were initially developed and modified for agroecosystems have been applied to non-agricultural systems in increasing number. We develop an SQI in arid and semi-arid ecosystems of the Western US impacted by different types of geologic mineralization using the relationship between vegetation community parameters and soil abiotic and biotic properties. We analyze these relations in soils associated with three different mineralization types: podiform chromite, Cu/Mo porphyry, and acid-sulfate gold vein systems at four different sites in California and Nevada. Soil samples were collected from undisturbed soils in both mineralized and nearby unmineralized substrates as well as from waste rock and tailings. Aboveground net primary productivity (ANPP), canopy cover and shrub density were measured for the vegetative communities. Minimum data sets were developed based on correlations between the soil and vegetation parameters, refined using principal components analysis, scored using non-linear functions, and combined into an overall SQI. The indices are comprised of one or two microbial parameters and three to six abiotic parameters, the latter consisting of nutrients and metals. Given the preliminary development of this approach, the parameters and combinations to arrive at an SQI for a given site cannot at this time be correlated or compared with that of another site. This SQI approach provides a means of quantifying disturbed ecosystem recovery resulting from mining, and could be applied to other disturbances in a way that readily distills the information for potential use by land managers. However, severely disturbed areas with little to no aboveground biomass, such as unreclaimed tailings, have likely crossed an ecological threshold that precludes the use of this type of monitoring tool.

California

Kiloyear cycles of carbonate and Mg-silicate replacement at Von Damm hydrothermal vent field

The Von Damm vent field (VDVF) on the Mid-Cayman Rise in the Caribbean Sea is unique among modern hydrothermal systems in that the chimneys and mounds are almost entirely composed of talc. We analyzed samples collected in 2020 and report that in addition to disordered talc of variable crystallinity, carbonates are a major class of mineral at VDVF. The carbonate minerals include aragonite, calcite, magnesium-rich calcite, and dolomite. Talc and carbonate mineral textures indicate that, rather than replacing volcanic host rock, they precipitate from the mixing of hydrothermal fluids and seawater at the seafloor, occurring in chimneys and surrounding rubble. Alternating precipitation of this mineral assemblage is pervasive, with carbonate minerals typically being succeeded by talc, and with indications that in some cases talc and carbonate minerals replace one another. Stable carbon isotopic data indicate the carbonate minerals originate from the mixing of seawater and hydrothermal fluid, which is supported by U-Th data. Radiocarbon calcite ages and talc 234 U- 230 Th isochron ages indicate mineral ages spanning over thousands to tens of thousands of years. Analyses of these samples illustrate a dynamic system that transitions from carbonate-dominated to Mg-silicate−dominated precipitation over time scales of thousands of years. Our observations raise questions regarding the eventual fate of seafloor precipitates and whether carbonate and silicate minerals in such settings are sequestered and represented in the rock record.

Geology

Airborne geophysics for geologic mapping of critical mineral systems in the United States southern midcontinent

The increased demand for clean energy technology and a significant reliance on foreign supply chains have given impetus to understanding critical mineral systems and locating potential resources within the United States. At least thirteen critical mineral-bearing systems have been identified throughout the U.S. southern Midcontinent (Hofstra and Kreiner, 2020) but much of the region’s geologic framework is concealed by vegetation and sedimentary cover that hinder traditional geologic mapping efforts. Airborne geophysical data provide an effective way to overcome these obstacles and to provide additional insight into the deeper structures that underlie shallow mineralization. However, legacy airborne magnetic and radiometric data were collected using now-outdated instruments and methods, inconsistent survey parameters, and large flight-line spacings resulting in low-resolution data that present challenges to regional-scale study and interpretation. Over the last decade, the U.S. Geological Survey Earth Mapping Resources Initiative (EMRI) and National Cooperative Geologic Mapping Program have conducted a series of high-resolution airborne magnetic and radiometric surveys across the southern Midcontinent (Fig. 1) as part of an effort to improve understanding of the geophysical framework and natural resource potential in the region. These surveys are designed using modern survey methods and instruments with consistent parameters for flight-line spacing and flight height relative to magnetic sources. The EMRI airborne surveys are planned in collaboration with State geological surveys based on focus areas (Dicken et al., 2022) according to the presence of or potential for critical mineral deposits. High-resolution airborne magnetic and radiometric data cover focus areas such as the southeast Missouri iron metallogenic province and South-Central iron-oxide-apatite (IOA) – iron-oxide-copper-gold (IOCG) province, the Magnet Cove alkaline-carbonatite complex, the Midwest Permian ultramafic dike district, the Illinois-Kentucky fluorspar district, and several Mississippi Valley-type lead-zinc deposits and districts (Fig. 1). These focus areas represent known deposits or prospective host systems of critical minerals including rare earth elements (REEs), platinum-group elements (PGEs), cobalt, lithium, fluorspar, niobium, titanium, vanadium, lead, zinc, gallium, germanium, and many more. Other significant geologic and geophysical features covered include the Reelfoot rift, the New Madrid seismic zone, the Illinois basin, the Arkoma basin, the South-Central magnetic lineament, and the Kentucky-Tennessee magnetic anomaly (Fig. 1). This presentation focuses on new airborne magnetic and radiometric data with continuous coverage across parts of six states, preliminary interpretations, examples of geologic mapping applications, and discussion of newly discovered magnetic anomalies and follow-up investigations.

Conference Paper

Do bighorn sheep use desert tortoise burrow spoil piles as mineral licks in southern California?

In a previous study, bighorn sheep ( Ovis canadensis ) were periodically photographed by trail cameras when they visited desert tortoise ( Gopherus agassizii ) burrows in the San Bernardino Mountains near Palm Springs, California, USA. The authors suggested that bighorn sheep may utilize the excavated spoil material from burrows as a mineral lick. To test that supposition, we collected soil samples from the spoil piles and undisturbed surface soil up to 1 m away at two desert tortoise study sites with bighorn sheep at the aforementioned site and another nearby site. We hypothesized that sodium concentrations would be greater in spoil than in nearby surface soil samples. Common major cations were quantified in soil samples using inductively coupled plasma-mass spectrometry following microwave-assisted digestion to solubilize the fraction of elements that could become biologically or environmentally available. Mean sodium concentrations were greater in burrow spoil samples than in undisturbed soil samples at both sites, likely due to aqueous leaching of sodium from surface to subsurface soil horizons. Although we did not collect evidence of geophagy by bighorn sheep, the behavior is well known. However, trail camera photographs of bighorn sheep with their head next to the entrance of tortoise burrows suggests that they may periodically utilize sodium and other elements brought to the surface by desert tortoises that are otherwise unavailable to bighorn sheep on the surface.

California